JP2017113011A - Emulsified fragrance composition for alcoholic drink - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an emulsified fragrance composition for alcoholic drink not generating floating matters and precipitated matters, keeping a stable emulsified state, giving a transparent appearance to the alcoholic drink, and not damaging the flavor and fragrance of the alcoholic drink even if mixing with a concentrated syrup having a concentration several times that of an alcoholic drink in a manufacturing process of the alcohol drink.SOLUTION: The emulsified fragrance composition for alcoholic drink comprises an oil-soluble constituent (a) containing a fragrance material, polyglyceryl fatty acid ester (b) having a transmittance of a 1 mass% aqueous solution at 600 nm of not less than 65%, and lecithin (c). The lecithin is favorably the one not subjected to enzymolysis, and the polyglyceryl fatty acid ester is favorably an ester of decaglycerol with a fatty acid selected from stearic acid, oleic acid, and a combination of these. The emulsified fragrance composition for alcoholic drink favorably contains 20-135 pts.mass of lecithin to 100 pts.mass of polyglyceryl fatty acid ester.SELECTED DRAWING: None

Description

The present invention relates to an emulsified fragrance composition for alcoholic beverages, an alcoholic beverage containing the same, and a concentrated syrup for alcoholic beverages containing a high concentration of alcohol.

As a method for imparting flavor and flavor to beverages, emulsified flavors obtained by emulsifying oil-soluble flavors are widely used. The emulsified fragrance can impart a persistent flavor and flavor different from the water-soluble fragrance. In recent years, in addition to soft drinks such as sports drinks and fruit juice drinks, emulsified flavors have been used more frequently in alcoholic drinks with a clear appearance such as chu-hi, sour, cocktail, sweet fruit wine, other miscellaneous drinks, and liqueurs. Yes. Since these products have a transparent appearance and are part of the product value, the emulsified flavor added for the purpose of imparting flavor and flavor must be transparently dispersed.
In addition, emulsified flavors used in alcoholic beverages need to be added to concentrated syrups that are several times the concentration of alcoholic beverages in the production process of alcoholic beverages. Sex is required. Usually, the concentration ratio is about 4 to 6 times, and when the alcohol concentration of the alcoholic beverage is 7%, the alcohol concentration of the 5-fold concentrated syrup is 35%.
In general, it is known that ethanol contained in alcoholic beverages adversely affects emulsion stability. This is because ethanol dissolves both in the oil phase and in the water phase, so (i) the interface becomes unclear, (ii) the emulsifier orientation is blocked and droplets cannot be maintained, (iii) due to mutual dissolution It is believed that this is because the mass transfer promotes oil / water two-layer separation. For this reason,
Even if there is no problem in emulsification stability when emulsified fragrance is used in soft drinks, sufficient emulsification stability may not be obtained in a high-concentration alcohol solution. May not be suitable. Therefore, in order to obtain an emulsified flavor for alcoholic beverages, it is necessary to consider the production process of alcoholic beverages. That is,
Emulsification stability in a high concentration alcohol solution is required.
As an emulsifying flavor and emulsification stability that can retain the flavor of alcoholic beverage products or carbonated beverage products, 0.1 to 2% by mass of enzyme-decomposed lecithin, 3 to 10% by mass of polyglycerol fatty acid ester, and sucrose 1 to 5% by mass of fatty acid ester and 5 of polyhydric alcohol
An emulsified composition containing 0 to 85% by mass, 1 to 10% by mass of water, and 1 to 10% by mass of a fragrance has been proposed (Japanese Patent No. 4563438, Patent Document 1). Also, it has high transparency, acid,
As an emulsified fragrance having resistance to heat and alcohol, an emulsified fragrance composition containing a hydrophilic polyglycerin fatty acid ester having an HLB of 10 or more, a lipophilic polyglycerin fatty acid ester having an HLB of 8 or less, and lysolecithin has been proposed. (Patent 55880
48, Patent Document 2).
However, these emulsified compositions or emulsified perfume compositions do not have the emulsion stability required in high-concentration alcohol solutions, give the alcoholic beverage a transparent appearance, and the flavor / It was not sufficient as an emulsifying fragrance that is required not to impair the flavor.

Japanese Patent No. 4563438 Japanese Patent No. 5588048

Under such circumstances, even when mixed with concentrated syrup having an alcohol concentration several times that of alcoholic beverages in the production process of alcoholic beverages, suspended solids and precipitates are not generated, and a stable emulsified state is maintained and the alcoholic beverages have a transparent appearance. There is a need to provide an emulsified flavor for alcoholic beverages that does not impair the flavor and flavor of the alcoholic beverage.

As a result of intensive studies to solve the above problems, the present inventor has found that it is desirable to use a combination of a polyglycerin fatty acid ester and lecithin as an emulsifier for an oil-soluble component containing a fragrance. Furthermore, HLB (Hydrophilic-Lipophilic Balance) is generally used as a measure for indicating the properties of surfactants such as polyglycerin fatty acid esters. However, desirable polyglycerin fatty acid esters for solving the above-mentioned problems are determined by HLB. The present inventors have found that it is desirable to use a polyglycerin fatty acid ester having a transmittance of 65% or more at 600 nm of a 1% by mass aqueous solution, and the present invention has been completed.

That is, this invention provides the emulsified fragrance | flavor composition for alcoholic beverages shown below, the alcoholic beverage which contains it, concentrated syrup for alcoholic beverages, etc.
[1] (a) an oil-soluble component containing a fragrance,
(B) An emulsified fragrance composition for alcoholic beverages comprising a polyglycerin fatty acid ester having a transmittance of 65% or more at 600 nm of a 1% by mass aqueous solution, and (c) lecithin.
[2] The emulsified fragrance composition for alcoholic beverages according to [1], wherein (c) lecithin is not enzymatically decomposed.
[3] (b) The polyglycerin fatty acid ester is an ester of decaglycerin and a fatty acid selected from stearic acid, oleic acid, or a combination thereof [1] or [2
] The emulsified fragrance | flavor composition for alcoholic beverages of description.
[4] (c) 2 (c) lecithin with respect to 100 parts by mass of polyglycerin fatty acid ester
The emulsified fragrance composition for alcoholic beverages according to any one of [1] to [3], comprising 0 to 135 parts by mass.
[5] An alcoholic beverage comprising the emulsified fragrance composition according to any one of [1] to [4].
[6] A concentrated syrup for alcoholic beverages, comprising the emulsified fragrance composition according to any one of [1] to [4].
[7] The alcohol concentration of the concentrated syrup for alcoholic beverages is 20% by volume or more, [6]
Concentrated syrup for alcoholic beverages according to 1.
[8] A method for producing an alcoholic beverage by diluting the concentrated syrup according to [6] or [7].

By using the emulsified fragrance composition for alcoholic beverages of the present invention, the oil-soluble fragrance can be transparently dispersed in the alcoholic beverage. According to a preferred embodiment of the present invention, by using the emulsified fragrance composition for alcoholic beverages of the present invention, it is possible to provide an alcoholic beverage with high palatability without impairing the flavor and flavor of the alcoholic beverage product. Further, according to a preferred embodiment of the present invention, the emulsified fragrance composition for alcoholic beverages of the present invention produces suspended matters and precipitates even when mixed with concentrated syrup having a concentration several times that of alcoholic beverages in the production process of alcoholic beverages. Therefore, a stable emulsified state can be maintained.

The emulsified fragrance composition for alcoholic beverages of the present invention comprises (a) an oil-soluble component containing a fragrance, (b) 1
A polyglycerin fatty acid ester having a transmittance of 65% or more at 600 nm of a mass% aqueous solution and (c) lecithin is contained. The emulsified fragrance composition for an alcoholic beverage of the present invention can disperse the oil-soluble fragrance transparently in the alcoholic beverage by including the above-mentioned (a) component, (b) component and (c) component. The emulsification stability inside can be made excellent. Hereinafter, each component contained in the emulsified fragrance composition for alcoholic beverages of the present invention will be described in detail.

(A) Oil-soluble component containing a fragrance The emulsified fragrance composition for an alcoholic beverage of the present invention includes (a) an oil-soluble component containing a fragrance.
(A) The fragrance used in the oil-soluble component containing the fragrance is not particularly limited as long as it is generally used in foods or beverages. For example, esters, alcohols,
Examples include synthetic fragrances such as aldehydes, ketones, acetals, phenols, ethers, lactones, furans, hydrocarbons, acids, and natural fragrances.

Examples of the esters include acrylic acid esters (methyl, ethyl, etc.), acetoacetic acid esters (methyl, ethyl, etc.), anisic acid esters (methyl, ethyl, etc.), benzoic acid esters (allyl, isoamyl, ethyl, Geranyl, linalyl, phenylethyl, hexyl, cis-3-hexenyl, benzyl, methyl, etc.), anthranilate (cinnamyl, cis-3-hexenyl, methyl, ethyl, linalyl, isobutyl, etc.), N-
Methyl anthranilate (methyl, ethyl, etc.), isovalerate (amyl,
Allyl, isoamyl, isobutyl, isopropyl, ethyl, octyl, geranyl, cyclohexyl, citronellyl, terpenyl, linalyl, cinnamyl, phenylethyl, butyl, propyl, hexyl, benzyl, methyl, rosinyl, etc.), isobutyric acid ester (isoamyl, geranyl, Citronellyl, terpenyl, cinnamyl, octyl, neryl, phenylethyl, phenylpropyl, phenoxyethyl, butyl, propyl, isopropyl, hexyl, benzyl, methyl, ethyl, linalyl, rosinyl, etc.), undecylenate (allyl, isoamyl, butyl) , Ethyl, methyl, etc.), octanoic acid ester (allyl,
Isoamyl, ethyl, octyl, hexyl, butyl, methyl, linalyl, etc.), octenoic acid ester (methyl, ethyl, etc.), octynecarboxylic acid ester (methyl, ethyl, etc.), caproic acid ester (allyl, amyl, isoamyl, Methyl, ethyl, isobutyl,
Propyl, hexyl, cis-3-hexenyl, trans-2-hexenyl, linalyl, geranyl, cyclohexyl, etc.), hexenoic acid ester (methyl, ethyl, etc.), valeric acid ester (amyl, isopropyl, isobutyl, ethyl, cis- 3-hexenyl, trans-2-hexenyl, cinnamyl, phenylethyl, methyl, etc.), formate (anisyl, isoamyl, isopropyl, ethyl, octyl, geranyl, citronellyl, cinnamyl, cyclohexyl, terpinyl, phenylethyl, butyl, propyl, Hexyl, cis-3-hexenyl, benzyl, linalyl, rosinyl, etc.), crotonic acid ester (isobutyl, ethyl, cyclohexyl, etc.), cinnamic acid ester (allyl, ethyl, methyl, isopropyl, propyl, 3- Phenylpropyl, benzyl, cyclohexyl, methyl, etc.), succinate (monomenthyl, diethyl, dimethyl, etc.), acetate (anisyl, amyl, α-amylcinnamyl, isoamyl, isobutyl, isopropyl, isopregyl, isobornyl, isoeugenyl, eugenyl, 2-ethylbutyl, ethyl, 3-
Octyl, carbyl, dihydrocarbyl, p-cresyl, o-cresyl, geranyl, α-
Or β-santalyl, cyclohexyl, cycloneryl, dihydrocuminyl, dimethylbenzylcarbinyl, cinnamyl, styryl, decyl, dodecyl, terpinyl, guanyl, neryl, nonyl, phenylethyl, phenylpropyl, butyl, furfuryl, propyl, hexyl, cis- 3-hexenyl, trans-2-hexenyl, cis-3-nonenyl,
Cis-6-nonenyl, cis-3, cis-6-nonadienyl, 3-methyl-2-butenyl,
Menthyl, heptyl, benzyl, bornyl, milcenyl, dihydromyrcenyl, miltenyl, methyl, 2-methylbutyl, menthyl, linalyl, rosinyl, etc.), salicylic acid ester (allyl, isoamyl, phenyl, phenylethyl, benzyl, ethyl, methyl, ), Cyclohexyl alkanoic acid esters (ethyl cyclohexyl acetate, allyl cyclohexylpropionate, allyl cyclohexylbutyrate, allyl cyclohexylsexanoate, allyl cyclohexyldecanoate, allyl cyclohexylvalerate, etc.), stearic acid esters (ethyl, propyl, butyl, etc.) ), Sebacate (diethyl, dimethyl, etc.),
Decanoic acid esters (isoamyl, ethyl, butyl, methyl, etc.), dodecanoic acid esters (
Isoamyl, ethyl, butyl, etc.), lactate ester (isoamyl, ethyl, butyl, etc.)
, Nonanoic acid ester (ethyl, phenylethyl, methyl, etc.), nonenoic acid ester (allyl, ethyl, methyl, etc.), hydroxyhexanoic acid ester (ethyl, methyl, etc.), phenylacetic acid ester (isoamyl, isobutyl, ethyl, Geranyl, citronellyl, cis-3-hexenyl, methyl, etc.), phenoxyacetic acid ester (allyl, ethyl, methyl,
Etc.), furan carboxylate (ethyl furan carboxylate, methyl furan sulfonate, hexyl furan carboxylate, isobutyl furan propionate, etc.), propionate (anisyl, allyl, ethyl, amyl, isoamyl, propyl, butyl, isobutyl, Isopropyl, benzyl, geranyl, cyclohexyl, citronellyl, cinnamyl, tetrahydrofurfuryl, tricyclodecenyl, heptyl, bornyl, methyl, menthyl,
Linalyl, terpinyl, α-methylpropionyl, β-methylpropionyl, etc.), heptanoic acid ester (allyl, ethyl, octyl, propyl, methyl, etc.), heptine carboxylic acid ester (allyl, ethyl, propyl, methyl, etc.) , Myrcytic acid ester (isopropyl, ethyl, methyl, etc.), phenylglycidic acid ester (ethyl phenylglycidate, ethyl 3-methylphenylglycidate, ethyl p-methyl-β-phenylglycidate, etc.), 2-methylbutyric acid ester (methyl, ethyl, octyl, phenylethyl, butyl, hexyl, benzyl, etc.), 3-methylbutyric acid ester (methyl, ethyl, etc.), butyric acid ester (anisyl, amyl, allyl, isoamyl, methyl, Ethyl, propyl, octyl, guanyl, linalyl, Alkenyl, cyclohexyl, citronellyl, cinnamyl, neryl, terpenyl, phenylpropyl, beta-phenylethyl, butyl, hexyl, cis -
3-hexenyl, trans-2-hexenyl, benzyl, rosinyl, etc.), hydroxybutyric acid ester (methyl 3-ethylbutyrate, methyl, menthyl, etc.) and the like are used.

Examples of alcohols include aliphatic alcohols (isoamyl alcohol, isopulegol, 2-ethylhexanol, 1-octanol, 3-octanol, 1-octen-3-ol, 1-decanol, 1-dodecanol, 2,6-nonadienol. , Nonanol, 2-nonanol, cis-6-nonenol, trans-2, cis-6-nonadienol, cis-3, cis-6-nonadienol, butanol, hexanol, cis-3-hexenol, trans-2-hexenol, 1 -Undecanol, heptanol, 2-heptanol, 3-methyl-1-pentanol, etc.), terpene alcohol (carveol, borneol, isoborneol, carbeol, piperitol, geraniol, α- or β-santalol, citronello , 4-tuanol, terpineol, 4-terpineol, nerol, myrcenol, myrtenol, menthol, dihydromyrcenol, tetrahydromyrcenol, nerolidol, hydroxycitronellol, farnesol,
Perilla alcohol, rosinol, linalool, 1-menthol, etc.), aromatic alcohol (
Anis alcohol, α-amyl cinnamic alcohol, isopropyl pendyl carbinol, carvacrol, cumin alcohol, dimethyl pendyl carbinol, cinnamic alcohol, phenyl allyl alcohol, phenyl ethyl carbinol, β-phenyl ethyl alcohol, 3-phenyl propi Preferred examples thereof include alcohol, pendyl alcohol, and the like.

Examples of aldehydes include aliphatic aldehydes (octanal, nonanal, decanal, undecanal, 2,6-dimethyl-5-hebutanal, 3,5,5-trimethylhexanal, cis-3, cis-6-nonadienal, trans -2, cis-6-nonadienal, valeraldehyde, propanal, isopropanal, hexanal, trans-2-hexenal, cis-3-hexenal, 2-pentenal, dodecanal,
Tetradecanal, trans-4-decenal, trans-2-tridecenal, trans-2-dodecenal, trans-2-undecenal, 2,4-hexadienal, cis-6-nonenal, trans-2-nonenal, 2- Methylbutanal, etc.), aromatic aldehydes (anisaldehyde, α-amylcinnamic aldehyde, α-methylcinnamic aldehyde, cyclamenaldehyde, p-isopropylphenylacetaldehyde, ethyl vanillin, cuminaldehyde, salicylaldehyde, cinnamaldehyde,
o-, m- or p-tolylaldehyde, vanillin, viveronal, phenylacetaldehyde, heliotropin, benzaldehyde, 4-methyl-2-phenyl-2-pentenal, p-methoxycinnamic aldehyde, p-methoxypenzaldehyde, etc.) Terpene aldehyde (geranial, citral, citronellal, α-sinensal, β
-Sinensal, Perilaldehyde, Hydroxycitronellal, Tetrahydrocitral, Miltenal, Cyclocitral, Isocyclocitral, Citronellyloxyacetaldehyde, Neral, α-Methylenecitronellal, Mylacaldehyde, Bernaldehyde, Safranal, etc.) Can be preferably mentioned.

Examples of the ketones include cyclic ketones (menton, isomentone, carvone, dihydrocarvone, pulegone, piperiton, 1-acetyl-3,3-dimethyl-1-cyclohexene, cis-jasmon, α-, β- or γ-iron. , Ethyl maltol, cycloten,
Dihydronootkatone, 3,4-dimethyl-1,2-cyclopentadione, sotron, α
-, Β-, γ- or δ-Damascon, α-, β- or γ-Damacenone, Nootkaton, 2
-Sec-ptylcyclohexanone, maltol, α-, β- or γ monoionone, α-, β
-Or γ-methyl ionone, α-, β- or γ-isomethyl ionone, furaneol, camphor, etc.), aromatic ketone (acetonaphthone, acetophenone, anisylideneacetone, raspberry ketone, p-methylacetophenone, anisylacetone, p-methoxyacetophenone ) Etc.) Chain type ketones (diacetyl, 2-nonanone, diacetyl, 2-hebutanone, 2
, 3-Heptanedione, 2-pentanone, methyl amyl ketone, methyl nonyl ketone, β
-Methyl naphthyl ketone, methyl hebutanone, 3-heptanone, 4-heptanone, 3-octanone, 2,3-hexanedione, 2-undecanone, dimethyloctenone, 6-methyl-5-heptin-3-one, etc.) Etc. can be preferably exemplified.

Examples of acetals include acetaldehyde diethyl acetal, acetaldehyde diamyl acetal, acetaldehyde dihexyl acetal, acetaldehyde propylene reglycol acetal, acetaldehyde ethyl cis-3-hexenyl acetal, benzaldehyde glycerin acetal, benzaldehyde propylene glycol acetal, citral dimethyl acetal, citral diethyl Acetal, citral propylene glycol acetal, citral ethylene glycol acetal, phenylacetaldehyde dimethyl acetal, citronellyl methyl acetal, acetaldehyde phenylethyl propyl acetal, hexanal dimethyl acetal, hexanal dihexyl acetal, hex Sanal propylene glycol acetal, trans-
2-hexenal diethyl acetal, trans-2-hexenal propylene glycol acetal, cis-3-hexenal diethyl acetal, heptanal diethyl acetal, heptanal ethylene glycol acetal, octanal dimethyl acetal, nonanal dimethyl acetal, decanal dimethyl acetal, deca Preferred examples include nal diethyl acetal, 2-methylundecanal dimethyl acetal, citronellal dimethyl acetal, amber sage (manufactured by Givaudan), ethyl acetoacetate ethylene glycol acetal and 2-phenylpropanal dimethyl acetal.

Examples of phenols include eugenol, isoeugenol, and 2-methoxy-4.
-Preferred examples include vinylphenol, thymol, carvacrol, guaiacol and cabicol.

Examples of ethers include anethole, 1,4-cineol, 1,8-cineole, dibenzyl ether, linalool oxide, limonene oxide, nerol oxide, rose oxide, methyl isoeugenol, methyl chabicol, isoamyl phenyl ethyl ether. , Β-naphthyl methyl ether, phenylpropyl ether, p-cresyl methyl ether, vanillyl butyl ether, α-terpinyl methyl ether, citronellyl ethyl ether, geranyl ethyl ether, rose furan, theasviran, decyl methyl ether and methylphenyl Methyl ether and the like are listed as preferred examples.

Examples of lactones include γ- or δ-decalactone, γ-heptalactone, γ-
Nonalactone, γ- or δ-hexalactone, γ- or δ-octalactone, γ- or δ
-Undecalactone, δ-dodecalactone, δ-2-decenolactone, methyl lactone,
Preferable examples include 5-hydroxy-8-undecenoic acid δ-lactone, jasmine lactone, mentalactone, dihydrocoumarin, octahydrocoumarin and 6-methylcoumarin.

Examples of furans include furan, 2-methylfuran, 3-methylfuran, 2-ethylfuran, 2,5-diethyltetrahydrofuran, 3-hydroxy-2-methyltetrahydrofuran, 2- (methoxymethyl) furan, 2, 3-dihydrofuran, mentholfuran,
Furfural, 5-methylfurfural, 3- (2-furyl) -2-methyl-2-propenal, 5- (hydroxymethyl) furfural, 2,5-dimethyl-4-hydroxy-
3 (2H) -furanone (furaneol), 4,5-dimethyl-3-hydroxy-2 (5H
) -Furanone (sotron), 2-ethyl-4-hydroxy-5-methyl-3 (2H) -furanone (homofuranool), 5-ethyl-3-hydroxy-4-methyl-2 (5H) furanone (homosotron) ), 3-methyl-1,2-cyclopentanedione (cyclotenes)
2 (5H) -furanone, 4-methyl-2 (5H) -furanone, 5-methyl-2 (5H)
-Furanone, 2-methyl-3 (2H) -furanone, 5-methyl-3 (2H) -furanone,
2-acetylfuranone, 2-acetyl-5-methylfuran, furfuryl alcohol, 2-
Preferred examples include methyl furancarboxylate, ethyl 2-furancarboxylate, and furfuryl acetate.

Examples of the hydrocarbons include α- or β-bizaborane, β-caryophyllene, p-cymene, terpinene, terpinolene, kadinene, farnesene, limonene, osymene,
Preferred examples include myrcene, α- or β-pinene, 1,3,5-undecatriene and valencene.

Examples of the acids include octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, gellanic acid, dodecanoic acid, myristic acid, stearic acid, lactic acid, phenylacetic acid, pyruvic acid, trans-2-methyl-2- Pentenoic acid, 2-methyl-cis-3-pentenoic acid, 2-methyl-4-pentenoic acid, cyclohexane carboxylic acid and the like can be preferably exemplified.

Furthermore, examples of natural fragrances include anise, orange, lemon, lime, mandarin, petit grain, bergamot, lemon balm, grapefruit, Elemi, olibanum, lemongrass, neroli, marjoram, angelica root, star anise, basil, bay, caramas. , Chamomile, caraway, cardamom, casscha, cinnamon, peppermint, spearmint, mint, penny royal, pepper, perilla, cypress, oregano,
Cascarilla, ginger, parsley, pine needle, sage, hyssop, tea tree,
Mustard, Horseradish, Clarisage, Clove, Cognac, Coriander, Estragon, Eucalyptus, Fennel, Guayacwood, Dill, Kayapute, Worm Seed, Pimento, Juniper, Fenegreek, Garlic, Laurel, Mace, Mill, Nutmeg, Spruce, Geranium, Citronella , Lavender, lavandin, palmarosa, rose, rosemary, sandalwood, oak moss, cedarwood, vetiver, linaloe, boad rose, patchouli, lovedanum, cumin, thyme, ylang ylang, birch, capsicum, celery, troutsum, gene, immortel, benzoin , Jasmine, Cassie, Chobelose, Reseda, Marigold, Mimosa, Opoponax, Oris, Vanilla and Rico Vinegar and the like. The fragrance | flavor component contained in these natural fragrance | flavors can also be used.

(A) The oil-soluble component may contain at least a fragrance, but may contain other oil-soluble components in addition to the fragrance. As oil-soluble components other than fragrances, those generally used in foods or beverages can be used, for example, various vegetable oils such as palm oil, coconut oil, corn oil, rapeseed oil, beef tallow, lard, and milk fat. And oils and fats; oil-soluble natural pigments such as medium chain fatty acid triglycerides having 8 to 12 carbon atoms, β-carotene, publica pigments, anato pigments and chlorophylls; fat-soluble vitamins such as vitamin A, vitamin D and vitamin E; antioxidants ;
Examples include vegetable resins such as rosin, copal, dammar, elemi, and ester gum.
Although the compounding quantity of the fragrance | flavor in an emulsified fragrance | flavor composition can be suitably adjusted with the intensity | strength of the fragrance of the fragrance | flavor, it is 0.1-10 mass% normally, Preferably it is 0.1-5 mass% is there.

(B) Polyglycerin fatty acid ester The emulsified fragrance composition for alcoholic beverages of the present invention comprises (b) a polyglycerin fatty acid ester whose transmittance at 600 nm of a 1% by mass aqueous solution is 65% or more. The polyglycerol fatty acid ester is obtained by esterifying a fatty acid into one or more of the hydroxy groups of the polyglycerol obtained by polymerizing glycerol. The degree of polymerization of glycerol, the number of fatty acids (esterification degree) and There are various types of fatty acids. In the present invention, among them, a polyglycerin fatty acid ester having a transmittance of 65% or more at 600 nm of a 1% by mass aqueous solution is used. By using the polyglycerin fatty acid ester having the above transmittance, a stable emulsified state can be maintained even when the emulsified fragrance composition for alcoholic beverages of the present invention is mixed with a concentrated syrup containing a high concentration of alcohol. The transmittance of the polyglycerol fatty acid ester is 65% or more, preferably 70% to 100%.

In the present invention, as the polyglycerol constituting the polyglycerol fatty acid ester,
The average degree of polymerization is preferably 6 to 10, and more preferably decaglycerin having an average degree of polymerization of 10.

The fatty acid constituting the polyglycerin fatty acid ester is preferably one having 14 to 18 carbon atoms, and more preferably stearic acid, oleic acid or a combination thereof.

Moreover, as esterification degree of polyglycerol fatty acid ester, polyglycerol fatty acid ester which esterified 0.1-2 mol of fatty acid with respect to 1 mol of polyglycerol is preferable, and polyglycerol which esterified 1 mol of fatty acid. Mono fatty acid esters are more preferred.

Examples of the polyglycerol fatty acid ester particularly preferably used in the present invention include decaglycerol monostearate, decaglycerol monooleate, or a combination thereof.

Various types of polyglycerol fatty acid esters are commercially available. Among them, the transmittance at 600 nm of the 1% by mass aqueous solution preferably used in the present invention is 6
As polyglycerol fatty acid ester which is 5% or more, for example, Decaglyn 1
-SVEX (trade name, manufactured by Nikko Chemicals Co., Ltd.), Decaglyn 1-OVEX (
Trade name, manufactured by Nikko Chemicals Co., Ltd.).

In the present invention, the transmittance of the polyglycerol fatty acid ester is measured as follows. First, polyglycerin fatty acid ester is dispersed in ion-exchanged water so as to be 1% by mass and stirred for 30 minutes while heating in a hot water bath at 80 ° C. to obtain a uniform aqueous solution. Then, the obtained polyglycerol fatty acid ester aqueous solution is cooled to 25 ° C. to obtain a test solution. Using this test solution as a control solution, the transmittance at 600 nm is measured using a cell having an optical path length of 1 cm. The transmittance is measured using a normal spectrophotometer. 2 polyglycerol fatty acid esters
When using more than one kind, they are mixed according to their mass ratio, and prepared so as to be 1% by mass as a polyglycerin fatty acid ester.

If the blending amount of the polyglycerin fatty acid ester in the emulsified fragrance composition is too large relative to the oil-soluble component, precipitation or suspended matter is likely to occur when dispersed in a concentrated syrup with a high alcohol concentration, and if it is too small, the drinking concentration The turbidity at may become strong. For this reason, the compounding quantity in the emulsified fragrance | flavor composition of polyglycerol fatty acid ester is (a) oil-soluble component 10 containing a fragrance | flavor.
1-200 mass parts is preferable with respect to 0 mass part, 5-150 mass parts is more preferable, 5-
120 parts by mass is more preferable.

(C) Lecithin The emulsified fragrance composition for alcoholic beverages of the present invention further comprises (c) lecithin. The (c) lecithin used in the present invention is not particularly limited as long as it is generally used in foods or beverages. For example, soy lecithin, rapeseed lecithin, sunflower lecithin, egg yolk lecithin and enzyme-decomposed lecithin Can be used. Among them, it is preferable to use lecithin that has not been enzymatically decomposed, since increasing the amount of enzymatically decomposed lecithin may deteriorate the flavor of the product and increase bitterness. In particular, soybean lecithin, rapeseed lecithin and sunflower lecithin which are not enzymatically degraded are preferred. Examples of such lecithin include Nisshin Lecithin DX (trade name, manufactured by Nisshin Oilio Co., Ltd.) (soy lecithin), G
IRALEC Premium (trade name, manufactured by Lasernor) (sunflower lecithin) and the like are preferable.

If the amount of lecithin in the emulsified fragrance composition is too small relative to the polyglycerin fatty acid ester, precipitation or suspended matter is likely to occur when dispersed in a concentrated syrup having a high alcohol concentration, and if too large, Turbidity may increase. For this reason, the compounding quantity in the emulsion composition of a lecithin is 5 with respect to 100 mass parts of (b) polyglycerol fatty acid ester.
-200 mass parts is preferable, 10-150 mass parts is more preferable, 20-135 mass parts is further more preferable.

In addition, if the amount of lecithin in the emulsified fragrance composition is too small relative to the oil-soluble component, precipitation or suspension tends to occur when dispersed in a concentrated syrup with a high alcohol concentration. The turbidity of may become strong. For this reason, the amount of lecithin in the emulsified composition is preferably 1 to 150 parts by mass with respect to 100 parts by mass of the (a) oil-soluble component,
80 mass parts is more preferable, and 8-80 mass parts is further more preferable.

In the emulsified fragrance composition for alcoholic beverages of the present invention, the blending amount of (a) oil-soluble component, (b) polyglycerin fatty acid ester and (c) lecithin is 0.1 to the total mass of the emulsified fragrance composition. 45 mass% is preferable, 0.1-22.5 mass parts is more preferable,
15 parts by mass is more preferable.

(D) Water-soluble solvent The emulsified fragrance composition for alcoholic beverages of the present invention contains (d) a water-soluble solvent in addition to (a) an oil-soluble component, (b) a polyglycerin fatty acid ester and (c) lecithin. Examples of the water-soluble solvent (d) used in the present invention include water and polyhydric alcohols.
The polyhydric alcohol is not particularly limited as long as it is generally used in foods or beverages, and examples thereof include glycerin, propylene glycol, 1,3-butylene glycol, D-sorbitol and the like. Of these, glycerin is preferable.
What is necessary is just to determine suitably in order to adjust the density | concentrations, such as an oil-soluble component, in the emulsification fragrance | flavor composition of a water-soluble solvent, and it does not restrict | limit in particular.

In the emulsified fragrance composition for alcoholic beverages of the present invention, in addition to the above components, water-soluble fragrances, water-soluble pigments such as caramel pigments, thickening polysaccharides, fructose glucose liquid sugar, etc. Saccharides, dietary fibers such as pectin, and high-sweetness sweeteners such as aspartame may further be included.

The emulsified fragrance composition for alcoholic beverages of the present invention can be produced by utilizing a known technique used for preparing an emulsified preparation. Specifically, a method of stirring and mixing the oil-soluble component and the water-soluble component using a stirring device such as a homomixer and a high-pressure homogenizer can be mentioned. During stirring and mixing, cooling or heating may be optionally performed.

By using the emulsified fragrance composition for alcoholic beverages of the present invention, the oil-soluble fragrance can be transparently dispersed in the alcoholic beverage. Here, the “alcoholic beverage” means a beverage composition having an alcohol concentration of 1% by volume or more. The beverage composition may be a concentrated syrup for alcoholic beverages, and the concentrated syrup for alcoholic beverages may then be appropriately diluted to prepare an alcoholic beverage having a desired alcohol concentration.
As an alcoholic beverage of this invention, it is preferable that alcohol concentration is 1-80 volume%, It is more preferable that it is 1-60 volume%, It is further more preferable that it is 1-50 volume%. Particularly preferred is an alcohol concentration of less than 10% by volume, that is, 1 to 10% by volume.
The alcohol concentration of the concentrated syrup for alcoholic beverages is not particularly limited as long as it is appropriately determined in consideration of the purpose of use, etc., but is generally preferably 20% by volume or more.
It is more preferably 0 to 60% by volume, and further preferably 20 to 50% by volume.

Examples of the alcoholic beverage obtained by adding the emulsified flavor composition for alcoholic beverages of the present invention include sour, strawberry high, cocktail, sweet fruit liquor, other miscellaneous sake, liqueur and the like. In the present invention, the alcoholic beverage may contain carbonic acid or fruit juice.

The addition amount of the emulsified flavor composition for alcoholic beverages of the present invention may be appropriately determined in consideration of the purpose of use and the like, and is not particularly limited, but is 0.01% with respect to the total amount of alcoholic beverages to be obtained.
-0.5 mass% is preferable, and 0.03-0.2 mass% is more preferable.

In the present invention, the emulsified fragrance composition for alcoholic beverages of the present invention may be added directly to the alcoholic beverage, or in the alcoholic beverage manufacturing process, it may be added to the concentrated syrup for alcoholic beverages in which the alcoholic beverage is concentrated. it can. According to a preferred embodiment of the present invention,
Even when the emulsified fragrance composition for alcoholic beverages of the present invention is added to such a concentrated syrup having a high alcohol concentration, suspended solids and precipitates are not generated, and a stable emulsified state can be maintained.
When the emulsion composition for alcoholic beverages of the present invention is added to an alcohol concentrated syrup,
A desired alcoholic beverage can be prepared by diluting the obtained syrup solution with a water-soluble solvent such as water and carbonated water.

EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not restrict | limited to these Examples at all. In addition, the transmittance | permeability of polyglycerol fatty acid ester was measured with the following method.
<Measurement of transmittance of polyglycerol fatty acid ester>
First, polyglycerin fatty acid ester is dispersed in ion-exchanged water so as to be 1% by mass,
The mixture was stirred for 30 minutes while heating in a hot water bath at 80 ° C. to obtain a uniform aqueous solution. Thereafter, the obtained polyglycerol fatty acid ester aqueous solution was cooled to 25 ° C. to obtain a test solution. Using this test solution as a control solution, the transmittance at 600 nm was measured using a cell having an optical path length of 1 cm. The transmittance was measured using an ultraviolet-visible spectrophotometer UV-1700 manufactured by Shimadzu Corporation. When using 2 or more types of polyglycerol fatty acid ester, it mixed by the mass ratio, and prepared and measured so that it might become 1 mass% as a polyglycerol fatty acid ester.

[Example 1]
Polyglycerol fatty acid ester (trade name: Decaglyn 1-SVEX / manufactured by Nikko Chemicals Co., Ltd., decaglycerol monostearate, HLB: 12.5) having a transmittance of 85.5% at 600 nm of a 1% by mass aqueous solution 7 0.5 g was dissolved by heating in 219.6 g of glycerin (trade name: purified glycerin / Kao Corporation) and 62.4 g of water. While stirring the resulting solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 7.5 g of lemon lime flavor (manufactured by Takasago Fragrance Industry) and soybean lecithin (trade name: Nisshin Lecithin DX / Nisshin Oilio) Co., Ltd.) 3 g previously mixed and homogenized was further added and emulsified at 9000 rpm for 10 minutes to prepare an emulsified fragrance composition.

[Example 2]
The transmittance of polyglycerin fatty acid ester at 600 nm of a 1% by mass aqueous solution is 73.
. An emulsified fragrance composition was prepared in the same manner as in Example 1 except that the trade name was Decaglyn 1-OVEX (manufactured by Nikko Chemicals, decaglycerin monooleate, HLB: 12.0).

[Example 3]
An emulsified fragrance composition was prepared in the same manner as in Example 1 except that the blending amounts of water and soybean lecithin were changed as shown in Table 1.

[Example 4]
An emulsified fragrance composition was prepared in the same manner as in Example 1 except that the blending amounts of water and soybean lecithin were changed as shown in Table 1.

[Example 5]
An emulsified fragrance composition was prepared in the same manner as in Example 1 except that the blending amounts of the polyglycerol fatty acid ester and water were changed as shown in Table 1.

[Comparative Example 1]
Polyglycerol fatty acid ester (trade name: Decaglyn 1-SVEX / manufactured by Nikko Chemicals Co., Ltd., decaglycerol monostearate, HLB: 12.5) having a transmittance of 85.5% at 600 nm of a 1% by mass aqueous solution 7 .5 g was dissolved by heating in 219.6 g of glycerin (trade name: purified glycerin / Kao Corporation) and 65.4 g of water. While stirring the resulting solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 7.5 g of lemon lime fragrance (manufactured by Takasago Fragrance Industry) was added, and 9000 r.
An emulsification treatment was performed at pm for 10 minutes to prepare an emulsified fragrance composition.

[Comparative Example 2]
The transmittance of polyglycerin fatty acid ester at 600 nm of a 1% by mass aqueous solution is 60
. An emulsified fragrance composition was prepared in the same manner as in Example 1 except that the trade name was Decaglyn 1-SVF (manufactured by Nikko Chemicals Co., Ltd., decaglycerin monostearate ester, HLB: 12.0).

[Comparative Example 3]
The transmittance of polyglycerol fatty acid ester at 600 nm of a 1% by mass aqueous solution is 39.
. Product name: Poem J-0381V (manufactured by Riken Vitamin Co., Ltd., decaglycerin monooleate, HLB: 14.0) was prepared in the same manner as in Example 1 except that the product was 2%.

  Table 1 shows the composition (mass%) of the emulsified fragrance compositions of Examples 1 to 5 and Comparative Examples 1 to 3.

[Test Example 1] Stability of emulsified state [1] Preparation of 5-fold concentrated syrup Add water to 368 ml of 95% ethanol, 230 g of fructose-glucose liquid sugar, 18 g of citric acid and 4 g of sodium citrate to make 1000 ml. A double concentrated syrup (alcohol concentration 35% by volume) was prepared. To the 5-fold concentrated syrup, 0.5% by mass of the emulsified fragrance composition prepared in Example 1 and Comparative Examples 1 and 2 was added.

[2] Evaluation Method Five-fold concentrated syrups to which the emulsion compositions of Examples 1 to 5 and Comparative Examples 1 to 3 were added were stored at room temperature for 1 week, and the syrup state was observed. The evaluation results are shown in Table 2.

The emulsified fragrance compositions of Examples 1 to 5 showed uniform and good emulsification stability even after 1 week when added to a 5-fold concentrated syrup. On the other hand, the emulsified fragrance compositions of Comparative Examples 1 to 3 were in a non-uniform state because they were added to a 5-fold concentrated syrup and a cotton-like white suspended matter was formed after 1 week.

[Test Example 2] Evaluation of Transparency when Diluted to Drinking Concentration In Test Example 1, a 5-fold concentrated syrup evaluated after 1 week (Examples 1, 2, 3, 4
And 5) were diluted 5 times with water to prepare an alcoholic beverage. Then, the transparency was evaluated by visual observation and measurement of transmittance. The results are shown in Table 3.

Even when the emulsified fragrance composition prepared in Examples 1 to 5 was added to a 5-fold concentrated syrup and stored at room temperature for 1 week, and diluted 5-fold with water, an alcoholic beverage having a uniform and transparent appearance was obtained. .

[Example 6]
Polyglycerin fatty acid ester (trade name: Decaglyn 1-SVEX / manufactured by Nikko Chemicals, decaglycerin monostearate, HLB: 12.5) 13 having a transmittance of 85.5% at 600 nm of a 1% by mass aqueous solution 13 0.5 g was dissolved by heating in 212.1 g of glycerin (trade name: purified glycerin / Kao Corporation) and 53.1 g of water. While stirring the resulting solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 15 g of lemon fragrance (manufactured by Takasago International Corporation), soybean lecithin (trade name: Nisshin Lecithin DX / Nisshin Oilio Co., Ltd.) 6 g and 0.3 g of vitamin E (manufactured by Eisai Co., Ltd.) previously mixed and homogenized were added and emulsified at 9000 rpm for 20 minutes to prepare an emulsified fragrance composition.

[Example 7]
Polyglycerin fatty acid ester (trade name: Ryoto Polyglycerin M-7D / Mitsubishi Chemical Foods, Inc., decaglycerin monomyristic acid ester, HLB: 16 having a transmittance of 99.2% at 600 nm of a 1% by mass aqueous solution ) 15 g and 6 g of sucrose fatty acid ester (trade name: DK Ester SS / Daiichi Kogyo Seiyaku Co., Ltd.) were dissolved by heating in 231 g of glycerin (trade name: purified glycerin / Kao Corporation) and 29.7 g of water. . While stirring the resulting solution with a high-speed stirrer homomixer MARK II (manufactured by Primix Co., Ltd.), 15 g of lemon fragrance (manufactured by Takasago Kagaku Kogyo Co., Ltd.), 3 g of enzymatically decomposed lecithin (trade name: Emultop / manufactured by Cargill Japan KK) and vitamins E (manufactured by Eisai Co., Ltd.) 0.3 g previously mixed and homogenized was added and emulsified at 9000 rpm for 20 minutes to prepare an emulsified fragrance composition.

[Comparative Example 4]
As polyglycerin fatty acid ester, 15 g of trade name: Decaglyn 1-M (manufactured by Nikko Chemicals Co., Ltd., decaglycerin monomyristate ester, HLB: 14),
Product name: Decaglyn 1-OV (manufactured by Nikko Chemicals Co., Ltd., decaglycerin monooleate, HLB: 12.0) 3 g, and product name: Ryoto polyglycerate O-50D (manufactured by Mitsubishi Chemical Foods Co., Ltd., decaglycerin) Oleate,
HLB: 7) Three types of 0.3 g were used and dissolved by heating in 210 g of glycerin (trade name: purified glycerin / Kao Corporation) and 55.2 g of water. While stirring the resulting solution with a high-speed stirrer, 15 g of lemon fragrance (manufactured by Takasago International Corporation), enzyme-decomposed lecithin (trade name: Em
Ultop / Cargill Japan Co., Ltd.) 0.6 g, Vitamin E (Eisai Co., Ltd.) 0.3 g, and medium chain fatty acid triglyceride (trade name: Skoray / Nisshin Oilio Co., Ltd.) 0.6 g were mixed and homogenized in advance. Add a high-speed stirrer (Homomixer MARK
II, manufactured by Primix Co., Ltd.) was used for emulsification treatment at 9000 rpm for 20 minutes to prepare an emulsified fragrance composition.
In addition, when 3 types of polyglycerin fatty acid ester was made into 1 mass% aqueous solution by the said compounding ratio, 6
The transmittance at 00 nm was 55.8%.

[Comparative Example 5]
Polyglycerol fatty acid ester (trade name: Decaglyn 1-SVF / manufactured by Nikko Chemicals, Decaglycerin monostearate, HLB: 12.0) 13 having a transmittance of 60.2% at 600 nm of a 1% by mass aqueous solution. .5 g and 3 g of sucrose fatty acid ester (trade name: DK Ester SS / Daiichi Kogyo Seiyaku Co., Ltd.) are dissolved by heating in 237.3 g of glycerin (trade name: purified glycerin / Kao Corporation) and 29.7 g of water. I let you. While stirring the resulting solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 15 g of lemon fragrance (manufactured by Takasago Fragrance Industry), enzymatically decomposed lecithin (
Brand name: Emultop / Cargill Japan Co., Ltd.) 1.2 g and Vitamin E (Eisai Co., Ltd.) 0.3 g were added in advance and mixed, and the mixture was emulsified at 9000 rpm for 20 minutes to give an emulsified fragrance composition. Prepared.

  Table 4 shows the compositions (mass%) of the emulsified fragrance compositions of Examples 6 and 7 and Comparative Examples 4 and 5.

[Test Example 3] Stability of emulsified state The stability of the emulsified state was evaluated in the same manner as in Test Example 1 using the emulsified fragrance compositions of Examples 6 and 7 and Comparative Examples 4 and 5. The evaluation results are shown in Table 5.

The emulsified fragrance compositions of Example 6 and Example 7 showed uniform and good emulsification stability even after 1 week after being added to the 5-fold concentrated syrup. On the other hand, the emulsified fragrance composition of Comparative Example 4 was added to the 5-fold concentrated syrup, and after 1 week, the oil floated on top of the syrup, and was in a non-uniform state. In addition, the emulsified fragrance composition of Comparative Example 5 was in a non-uniform state because a white flocculent product was formed after one week had elapsed after being added to the 5-fold concentrated syrup.

[Test Example 4] Evaluation of Transparency when Diluted to Drinking Concentration In Test Example 3, the 5-fold concentrated syrup (Examples 6 and 7) evaluated one week later was further diluted 5-fold with water. An alcoholic beverage was prepared. The transparency was evaluated by visual observation and transmittance measurement. The results are shown in Table 6.

The emulsified fragrance composition prepared in Example 6 can be added to a 5-fold concentrated syrup, stored for 1 week at room temperature, and then diluted 5-fold with water to make an alcoholic beverage with a uniform and transparent appearance. there were. On the other hand, when the emulsified fragrance composition prepared in Example 7 is added to a 5-fold concentrated syrup and stored at room temperature for 1 week and then diluted 5-fold with water, it becomes a uniform but slightly turbid appearance alcoholic beverage. I have.

[Test Example 5] Evaluation of flavor and flavor of alcoholic beverages to which an emulsified flavor composition was added 140 ml of vodka with 50% alcohol content, 3.6 g of citric acid and 0.8 g of sodium citrate, 0.1 g of vitamin C, acesulfame potassium Water was added to 13 g and 0.016 g of sucralose to make 1000 ml, and an alcoholic beverage having an alcohol content of 7% was prepared. Each of the emulsified fragrance compositions prepared in Examples 6 and 7 and Comparative Example 4 was 0.1% by mass.
In addition, an alcoholic beverage containing an emulsified fragrance composition was prepared.
Sensory evaluation was performed using these alcoholic beverages.

<Method>
According to the company's 8 expert panelists, 1 is the least bitter and 5 is the most bitter.
Evaluation was performed in five stages. Table 7 summarizes the evaluation results of eight people as average values.

The alcoholic beverage containing the emulsified fragrance composition prepared in Example 7 and Comparative Example 4 contains the emulsified fragrance composition prepared in Example 6 while the bitterness is strong and the flavor and flavor of the alcoholic beverage are impaired. The alcoholic beverages had a weak bitterness and did not impair the flavor and flavor of the alcoholic beverages.

[Example 8]
Polyglycerol fatty acid ester (trade name: Decaglyn 1-SVEX / manufactured by Nikko Chemicals Co., Ltd., decaglycerol monostearate, HLB: 12.5) having a transmittance of 85.5% at 600 nm of a 1% by mass aqueous solution 0 .9 g was dissolved by heating in 244.2 g of glycerin (trade name: purified glycerin / Kao Corporation) and 42.9 g of water. While stirring the obtained solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 10.8 g of ume fragrance (manufactured by Takasago International Corporation) containing 0.9 g of medium chain fatty acid triglyceride, sunflower lecithin (trade name: GILAREC Premium / La
Senor 0.9g and extracted tocopherol (trade name: RIKEN E Oil Super 8)
0N / RIKEN Vitamin Co., Ltd.) Add 0.3g of premixed and homogenized, 9000r
An emulsification treatment was performed at pm for 10 minutes to prepare an emulsified fragrance composition. Table 8 shows the composition (mass%) of the emulsified fragrance composition of Example 8.

[Test Example 6] Stability of emulsified state Using the emulsified fragrance composition of Example 8, the stability of the emulsified state was evaluated in the same manner as in Test Example 1, and after addition to a 5-fold concentrated syrup, one week passed. Also showed uniform and good emulsification stability.

[Test Example 7] Evaluation of Transparency when Diluted to Drinking Concentration In Test Example 6, the 5-fold concentrated syrup (Example 8) evaluated after 1 week was further diluted 5-fold with water to obtain an alcoholic beverage. Was prepared. And when the transparency was evaluated by visual observation and measurement of transmittance, the appearance was transparent and the transmittance was 95.5%. The emulsified fragrance composition prepared in Example 8 was added to a 5-fold concentrated syrup and stored at room temperature for 1 week.
Even when the dilution was doubled, an alcoholic beverage having a uniform and transparent appearance was obtained.

[Example 9]
Polyglycerol fatty acid ester (trade name: Decaglyn 1-SVEX / manufactured by Nikko Chemicals, Decaglycerin monostearate, HLB: 12.5) 1 having a transmittance of 85.5% at 600 nm of a 1% by mass aqueous solution 1 0.8 g was dissolved by heating in 231.6 g of glycerin (trade name: purified glycerin / Kao Corporation) and 57.9 g of water. While stirring the obtained solution with a high-speed stirrer (Homomixer MARK II, manufactured by Primix Co., Ltd.), 6.0 g of orange fragrance (manufactured by Takasago International Corporation) and sunflower lecithin (trade name: manufactured by GILAREC Premium / Laseror) 4 g and 0.3 g of vitamin E (manufactured by Eisai Co., Ltd.) previously mixed and homogenized were added and emulsified at 9000 rpm for 10 minutes to prepare an emulsified fragrance composition. Table 9 shows the composition (mass%) of the emulsified fragrance composition of Example 9.

[Test Example 8] Stability in emulsified state Add 526 ml of 95% ethanol, 280 g of fructose-glucose liquid sugar, 16 g of citric acid and 4.5 g of sodium citrate to 1000 ml to make a 1000-fold concentrated syrup of alcoholic beverage (alcohol concentration 50 Volume%) was prepared. 0.15% by mass of the emulsified fragrance composition prepared in Example 9 was added to this 5-fold concentrated syrup, and uniform and good emulsification stability was exhibited even after 1 week.

[Test Example 9] Evaluation of Transparency when Diluted to Drinking Concentration In Test Example 8, the 5-fold concentrated syrup (Example 9) evaluated after 1 week was further diluted 5-fold with water to obtain an alcoholic beverage Was prepared. And when the transparency was evaluated by visual observation and measurement of transmittance, the appearance was transparent and the transmittance was 98.9%. The emulsified fragrance composition prepared in Example 9 was added to a 5-fold concentrated syrup and stored at room temperature for 1 week.
Even when the dilution was doubled, an alcoholic beverage having a uniform and transparent appearance was obtained.

As described above, the emulsified fragrance composition for alcoholic beverages of the present invention gives a transparent appearance with high palatability when blended with an alcoholic beverage, and even when mixed with a concentrated syrup for alcoholic beverages containing a high concentration of alcohol, Precipitation does not occur and a stable emulsified state can be maintained.
Moreover, according to the preferable aspect of this invention, the emulsified fragrance | flavor composition for alcoholic beverages of this invention does not impair the flavor and flavor of alcoholic beverage products. Therefore, the emulsified fragrance composition for alcoholic beverages of the present invention is useful as an emulsified fragrance composition for alcoholic beverages.

By using the emulsified fragrance composition for alcoholic beverages of the present invention, it is possible to provide an alcoholic beverage and a concentrated syrup for alcoholic beverages having a transparent appearance and flavor / flavor with high palatability.

Claims (8)

(A) an oil-soluble component containing a fragrance,
(B) An emulsified fragrance composition for alcoholic beverages comprising a polyglycerin fatty acid ester having a transmittance of 65% or more at 600 nm of a 1% by mass aqueous solution, and (c) lecithin. (C) The emulsified fragrance composition for alcoholic beverages according to claim 1, wherein lecithin is not enzymatically decomposed. (B) The emulsified fragrance composition for alcoholic beverages according to claim 1 or 2, wherein the polyglycerin fatty acid ester is an ester of decaglycerin and a fatty acid selected from stearic acid, oleic acid, or a combination thereof. (B) 20 to 1 (c) lecithin with respect to 100 parts by mass of the polyglycerol fatty acid ester
The emulsified fragrance composition for alcoholic beverages according to any one of claims 1 to 3, comprising 35 parts by mass.   An alcoholic beverage comprising the emulsified fragrance composition according to any one of claims 1 to 4. The concentrated syrup for alcoholic drinks containing the emulsified fragrance | flavor composition as described in any one of Claim 1 to 4. The concentrated syrup for alcoholic beverages according to claim 6, wherein the concentrated syrup for alcoholic beverages has an alcohol concentration of 20% by volume or more. A method for producing an alcoholic beverage by diluting the concentrated syrup according to claim 6 or 7.