JP2017111417A - Colored composition for color filter and color filter - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a colored composition for a color filter excellent in storage stability, and a color filter having no generation of foreign substances in a coating film, showing strong adhesiveness with a transparent substrate such as glass, and having high heat resistance and solvent resistance and excellent alkali solubility.SOLUTION: The colored composition for a color filter comprises a salt-forming compound (D) of an acrylic resin (B) described below and an anionic dye (C): the acrylic resin (B) is a block resin comprising an A-block having a cationic group in a side chain and a B-block having no cationic group but a thermally crosslinkable functional group.SELECTED DRAWING: None

Description

The present invention relates to a colored composition for a color filter used for manufacturing a color filter used for a color liquid crystal display device, a color image pickup tube element, and the like, and a color filter including a filter segment formed using the same. is there.

In recent years, liquid crystal display devices have been evaluated for space saving, light weight, power saving, and the like due to their thinness, and recently they have been rapidly spread to television applications. For television applications, it is required to further improve the performance such as brightness and contrast, and further improvement of the transmittance and enhancement of the contrast are desired for the color filter which is a member of the color liquid crystal display device. ing.

As a method for producing the color filter, after forming a pattern with a photoresist, a dyeing method for dyeing the pattern, or by forming a transparent electrode of a predetermined pattern in advance, and using a pigment-containing resin dissolved and dispersed in a solvent by voltage application Electrodeposition method for ionization and pattern formation, printing method such as offset printing using ink containing thermosetting resin or ultraviolet curable resin, pigment dispersion using color resist agent in which colorant such as pigment is dispersed in photoresist material Recently, the pigment dispersion method has become mainstream. However, a color filter using a pigment as a colorant disturbs the degree of polarization controlled by the liquid crystal due to light scattering by the pigment particles, resulting in a decrease in brightness and contrast of the color liquid crystal display device. There is a problem that it is easy.

As a technique for solving this problem, the practical application of a dye-based curable composition using a dye that can exist in a dissolved state in a medium of the curable composition as a colorant has been studied and proposed (for example, patents). Reference 1). However, the dye used for the color resist agent has problems of heat resistance, light resistance, and solubility in the resin and the organic solvent used for the resin.

Therefore, in order to increase solubility, a color filter using a salt of an anionic dye and a cationic surfactant as a colorant has been proposed (for example, see Patent Documents 2 and 3). Generally, it is known that the solubility of an anionic dye in an organic solvent is increased by changing the sodium sulfonate group (—SO ₃ Na) of the anionic dye into an organic amine salt. In the above colorant, the solubility of the anionic dye in an organic solvent is increased by changing the sodium sulfonate group of the anionic dye to the base salt of the cationic surfactant. However, in these methods, sufficient solubility cannot be obtained in the solvent used in the preparation of the color filter, and the compatibility with the resin is poor. It is difficult to give strong adhesion between a film and a transparent substrate such as glass, and at the same time, it is impossible to solve important problems in color filters such as solvent resistance and alkali developability of the coating film. It was.

Further, as salt forming compounds of anionic dyes, those using a cationic resin as a counter have been studied as crystalline aqueous coloring materials (see, for example, Patent Document 4). In color filter applications that require use in a dissolved state, detailed studies have not been made.

On the other hand, a colored resin composition in which an anionic dye is added to a copolymer solution obtained by copolymerizing a monomer having an amide structure has also been proposed (see, for example, Patent Document 5). This is because the amide structure acts as a dyeing point with the anionic dye, thereby stabilizing the dye in the coating film and improving the resistance. However, the method disclosed here has a problem in that since a copolymer and an anionic dye are mixed in an organic solvent, a highly polar dye is not sufficiently dissolved and foreign matter is generated.

On the other hand, in order to improve heat resistance and light resistance, a coloring composition in which a dye is chemically bonded to a polymer has been proposed (for example, see Patent Document 6). However, the solvent resistance and resistance are insufficient only by simply combining the polymer and the dye, and the recent required level of alkali developability could not be satisfied.

JP 1994-75375 A JP 1993-333207 JP 2004-307391 A JP-A-2005-350648 JP 2000-352819 A JP 2000-162429 A JP 2011-242752 A JP 2013-33194 A

The object of the present invention is a color filter coloring composition having excellent storage stability, as well as no foreign matter generated on the coating film, and has strong adhesion with a transparent substrate such as glass, heat resistance, The object is to provide a color filter having high solvent resistance and excellent alkali solubility.

As a result of intensive studies to solve the above problems, the present inventors have found that the A block having a cationic group in the side chain and the B block having no cationic group and having a thermally crosslinkable functional group A color filter coloring composition containing a salt-forming compound (D) of an acrylic resin (B) and an anionic dye (C), characterized in that it is a block resin comprising a high storage stability, It has been found that no foreign matter is generated on the coating film, has excellent adhesion, and exhibits high heat resistance in a heat resistance test, and the present invention has been made based on this finding.
The use of a block resin as a salt-forming dye is disclosed in Japanese Patent Application Laid-Open No. 2011-242752, and a salt-forming dye using a high tg, crosslinkable resin is exemplified in Japanese Patent Application Laid-Open No. 2013-33194. .

That is, the present invention is a color filter coloring composition comprising at least a colorant (A), a binder resin, and an organic solvent,
The colorant (A) contains a salt-forming compound (D) of a resin (B) having a cationic group in the side chain and an anionic dye (C),
The resin (B) having a cationic group in the side chain is an acrylic resin containing a structural unit represented by the following general formula (1), and the acrylic resin is:
For a color filter, characterized in that it is a block resin comprising an A block having a cationic group represented by the following general formula (1) and a B block not having a cationic group and having a thermally crosslinkable functional group The present invention relates to a coloring composition.
(In general formula (1), R ₁ represents a hydrogen atom or a substituted or unsubstituted alkyl group. R _{2 to} R ₄ each independently represents a hydrogen atom, an optionally substituted alkyl group, or a substituted group. Represents an alkenyl group which may be substituted, or an aryl group which may be substituted, and _two of R _{2 to} R ₄ may be bonded to each other to form a ring, Q is an alkylene group, an arylene group, —CONH —R ₅ —, —COO—R ₅ —, wherein R ₅ represents an alkylene group, and Y ⁻ represents an inorganic or organic anion.)

Furthermore, the present invention relates to the coloring composition for a color filter, wherein the thermally crosslinkable functional group is at least one selected from the group consisting of a hydroxyl group and a carboxyl group.

Furthermore, the present invention provides an acrylic resin in which the block resin having a cationic group includes a structural unit represented by the general formula (1), and the structural unit represented by the general formula (1) is a resin composition. It is a block resin containing 3 to 90% by weight of the total 100% by weight of the above-mentioned color filter coloring composition.

Furthermore, this invention relates to the coloring composition for said color filters characterized by the ammonium salt value of acrylic resin containing the structural unit represented by the said General formula (1) being 10-200 mgKOH / g.

Furthermore, the present invention relates to the colored composition for a color filter as described above, wherein the organic solvent contains propylene glycol monomethyl ether acetate as a main component.

Furthermore, the present invention relates to the color composition for color filters, wherein the colorant further contains a pigment.

Furthermore, the present invention provides the color filter, wherein the anionic dye (C) contains at least one selected from acid red 52, acid red 289, and a compound represented by the following general formula (2). The present invention relates to a coloring composition.

General formula (2)

[X1 and X3 represent a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms which may have a substituent.
X2 and X4 represent a monovalent aromatic hydrocarbon group which may have a substituent, and at least one of them has a sulfo group. ]

Furthermore, this invention relates to the coloring composition for said color filters characterized by containing a photopolymerizable monomer and / or a photoinitiator further.

Furthermore, the present invention comprises mixing an anionic dye (C) with a resin (B) having a cationic group in the side chain in an aqueous solution, and the counter anion and anionic property of the resin (B) having a cationic group in the side chain. The salt comprising a counter cation of the dye (C) is removed to obtain a salt-forming compound (D), and the method for producing a colored composition for a color filter according to any one of claims 1 to 7.

Moreover, this invention relates to the color filter formed with the said coloring composition for color filters.

The present invention is characterized in that it is a block resin comprising a block having a cationic group in the side chain, that is, a block having a cationic group and a B block having no cationic group and having a thermally crosslinkable functional group. By using a coloring composition for a color filter containing a salt-forming compound (D) of an acrylic resin (B) and an anionic dye (C), it has high storage stability and foreign matter during coating film formation It is possible to obtain a color filter which is free from generation, excellent in adhesiveness, high heat resistance and solvent resistance, and excellent alkali development.

Hereinafter, the present invention will be described in detail.
The coloring composition for a color filter of the present invention does not have a cationic group in the side chain and a cationic group in a colorant carrier containing a binder resin and an organic solvent, and has a thermally crosslinkable functional group. A colored composition for a color filter comprising a salt-forming compound (D) comprising a resin (B) having a block resin comprising a B block and an anionic dye (C).
First, the resin (B), which is a block resin composed of an A block having a cationic group in the side chain and a B block having no cationic group and having a thermally crosslinkable functional group, will be described.

<Resin having a cationic group in the side chain (B)
The resin (B) having a cationic group in the side chain of the present invention is a block resin comprising an A block having a cationic group in the side chain and a B block having no cationic group and having a thermally crosslinkable functional group. It is characterized by being.
The salt-forming compound (D) of the present invention can be obtained by forming a salt with the anionic group of the anionic dye (C).

[A block having a cationic group]
The A block having a cationic group of the present invention is characterized by having a cationic group represented by the following general formula (1).

(In general formula (1), R ₁ represents a hydrogen atom or a substituted or unsubstituted alkyl group. R _{2 to} R ₄ each independently represents a hydrogen atom, an optionally substituted alkyl group, or a substituted group. Represents an alkenyl group which may be substituted, or an aryl group which may be substituted, and _two of R _{2 to} R ₄ may be bonded to each other to form a ring, Q is an alkylene group, an arylene group, —CONH _{-R 5 -, - COO-R} 5 - represents, .Y R ₅ is representative of the alkylene group ^- represents an inorganic or organic anion).

In general formula (1), R ₁ represents a hydrogen atom or a substituted or unsubstituted alkyl group. Examples of the alkyl group for R ₁ include a methyl group, an ethyl group, a propyl group, an n-butyl group, an i-butyl group, a t-butyl group, an n-hexyl group, and a cyclohexyl group. As this alkyl group, a C1-C12 alkyl group is preferable, a C1-C8 alkyl group is more preferable, and a C1-C4 alkyl group is especially preferable.

When the alkyl group represented by R ₁ has a substituent, examples of the substituent include a hydroxyl group and an alkoxyl group.

Among the above, R ₁ is most preferably a hydrogen atom or a methyl group.

In general formula (1), R _{2 to} R ₄ are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, or an optionally substituted aryl group. Can be mentioned.

Here, as the alkyl group in R _{2 to} R ₄ , for example, a linear alkyl group (methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-octyl, n-decyl, n-dodecyl, n -Tetradecyl, n-hexadecyl, n-octadecyl, etc.), branched alkyl groups (isopropyl, isobutyl, sec-butyl, tert-butyl, isopentyl, neopentyl, tert-pentyl, isohexyl, 2-ethylhexyl and 1,1,3,3) -Tetramethylbutyl etc.), cycloalkyl groups (cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl etc.) and bridged cyclic alkyl groups (norbornyl, adamantyl and pinanyl etc.). As this alkyl group, a C1-C18 alkyl group is preferable, More preferably, it is a C1-C8 alkyl group.

Examples of the alkenyl group in R _{2 to} R ₄ include linear or branched alkenyl groups (vinyl, allyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1 -Propenyl, 1-methyl-2-propenyl, 2-methyl-1-propenyl, 2-methyl-2-propenyl and the like) and cycloalkenyl groups (such as 2-cyclohexenyl and 3-cyclohexenyl). As this alkenyl group, a C2-C18 alkenyl group is preferable, More preferably, it is a C2-C8 alkenyl group.

Examples of the aryl group in R _{2 to} R ₄ include monocyclic aryl groups (such as phenyl), condensed polycyclic aryl groups (such as naphthyl, anthracenyl, phenanthrenyl, anthraquinolyl, fluorenyl, and naphthoquinolyl) and aromatic heterocyclic hydrocarbons. Groups (thienyl (group derived from thiophene)), furyl (group derived from furan), pyranyl (group derived from pyran), pyridyl (group derived from pyridine), 9-oxoxanthenyl (from xanthone) Derived groups) and 9-oxothioxanthenyl (groups derived from thioxanthone) and the like.

When the alkyl group, alkenyl group, or aryl group represented by R _{2 to} R ₄ has a substituent, examples of the substituent include a halogen atom, a hydroxyl group, an alkoxyl group, an aryloxy group, an alkenyl group, an acyl group, Examples include a substituent selected from an alkoxycarbonyl group, a carboxyl group, a phenyl group, and the like. Among these substituents, a halogen atom, a hydroxyl group, an alkoxyl group, and a phenyl group are particularly preferable.

R _{2 to} R ₄ are preferably an alkyl group which may be substituted from the viewpoint of stability, and more preferably an unsubstituted alkyl group.

_Two of R _{2 to} R ₄ may be bonded to each other to form a ring.

In general formula (1), the component of Q that connects the acrylic moiety and the ammonium base represents an alkylene group, an arylene group, —CONH—R ₅ —, —COO—R ₅ —, and R ₅ represents an alkylene group, Among these, —CONH—R ₅ — and —COO—R ₅ — are preferable because of polymerizability and availability. R ₅ is more preferably a methylene group, an ethylene group, a propylene group, or a butylene group, and particularly preferably an ethylene group.

The component Y ⁻ in the general formula (1) constituting the counter anion of the resin may be an inorganic or organic anion. As the counter anion, known ones can be used without limitation. Specifically, hydroxide ions; halogen ions such as chloride ions, bromide ions, and iodide ions; carboxylate ions such as formate ions and acetate ions; Carbonate ions, bicarbonate ions, nitrate ions, sulfate ions, sulfite ions, chromate ions, dichromate ions, phosphate ions, cyanide ions, permanganate ions, and even hexacyanoferrate (III) ions And complex ions. From the viewpoint of synthesis suitability and stability, halogen ions and carboxylate ions are preferable, and halogen ions are most preferable. When the counter anion is an organic acid ion such as a carboxylate ion, the organic acid ion may be covalently bonded in the resin to form an inner salt.

In order to obtain an acrylic resin containing the structural unit represented by the general formula (1), not only a method of copolymerizing an ethylenically unsaturated monomer having an ammonium base as a monomer component but also having an amino group After obtaining an acrylic resin having an amino group copolymerized with an ethylenically unsaturated monomer as a monomer component, it may be obtained by reacting an onium chlorinating agent and ammonium chloride.

Specific examples of the ethylenically unsaturated monomer having an ammonium base, the ethylenically unsaturated monomer having an amino group, and an onium chlorinating agent are shown below. In addition, in this specification, when showing either or both of "acryl, methacryl", it may describe as "(meth) acryl". Similarly, when one or both of “acryloyl and methacryloyl” are indicated, it may be described as “(meth) acryloyl”.

Examples of the ethylenically unsaturated monomer having an ammonium base include (meth) acryloyloxyethyltrimethylammonium chloride, (meth) acryloyloxyethyltriethylammonium chloride, (meth) acryloyloxyethyldimethylbenzylammonium chloride, and (meth) acryloyl. Alkyl (meth) acrylate quaternary ammonium salts such as oxyethylmethylmorpholino ammonium chloride, (meth) acryloylaminopropyltrimethylammonium chloride, (meth) acryloylaminoethyltriethylammonium chloride, (meth) acryloylaminoethyldimethylbenzylammonium chloride Alkyl (meth) acryloylamide quaternary ammonium salts such as dimethyl Allyl ammonium methyl sulfate, trimethyl vinyl phenyl ammonium chloride.

Examples of the ethylenically unsaturated monomer having an amino group include dimethylaminoethyl (meth) acrylate, diethylaminoethyl (meth) acrylate, dipropylaminoethyl (meth) acrylate, diisopropylaminoethyl (meth) acrylate, and dibutylamino. Ethyl (meth) acrylate, diisobutylaminoethyl (meth) acrylate, di-t-butylaminoethyl (meth) acrylate, dimethylaminopropyl (meth) acrylamide, diethylaminopropyl (meth) acrylamide, dipropylaminopropyl (meth) acrylamide, diisopropyl Aminopropyl (meth) acrylamide, dibutylaminopropyl (meth) acrylamide, diisobutylaminopropyl (meth) acrylamide, di-t-butyl Examples include (meth) acrylic acid esters having a dialkylamino group such as minopropyl (meth) acrylamide or (meth) acrylamide, and styrenes having a dialkylamino group such as dimethylaminostyrene and dimethylaminomethylstyrene, diallylmethylamine, diallylamine And amino group-containing aromatic vinyl monomers such as N-vinylpyrrolidine, N-vinylpyrrolidone and N-vinylcarbazole.

Examples of the onium chloride agent include alkyl sulfates such as dimethyl sulfate, diethyl sulfate, or dipropyl sulfate, sulfonate esters such as methyl p-toluenesulfonate, or methyl benzenesulfonate, methyl chloride, ethyl chloride, propyl chloride, or Examples thereof include alkyl chlorides such as octyl chloride, alkyl bromides such as methyl bromide, ethyl bromide, propyl bromide, and octyl chlorobromide, benzyl chloride, and benzyl bromide.

The reaction between the ethylenically unsaturated monomer having an amino group and the onium chlorinating agent is usually performed by dropping an equimolar amount or less of the onium chlorinating agent into the amino group-containing ethylenically unsaturated monomer solution. Can be done. The temperature during the ammonium chlorination reaction is about 90 ° C. or less, and particularly when the vinyl monomer is ammonium chlorinated, it is preferably about 30 ° C. or less, and the reaction time is about 1 to 4 hours.

Alternatively, an alkoxycarbonylalkyl halide can also be used as the onium chlorinating agent. The alkoxycarbonylalkyl halide is represented by the following general formula (3).

Z—R ⁶ —COOR ⁷ general formula (3)

(In the general formula (3), Z is chlorine or halogen such as bromine, preferably bromine, R ⁶
Is an alkylene group having 1 to 6 carbon atoms, preferably 1 to 5 carbon atoms, more preferably 1 to 3 carbon atoms, and R ⁷ is a lower alkyl group having 1 to 6 carbon atoms, preferably 1 to 3 carbon atoms. )

Reaction of the ethylenically unsaturated monomer and alkoxycarbonylalkyl halide with an amino group, after equimolar following alkoxycarbonylalkyl halide was reacted in the same manner as in the above onium chloride agent to an amino group, a -COOR ⁷ It is obtained by hydrolysis and conversion to carboxylate ions (—COO ⁻ ). Thereby, the ethylenically unsaturated monomer which has a carboxybetaine structure shown by General formula (3), and has an ammonium base can be obtained.

[B block having thermally crosslinkable functional group]
The B block of the present invention is characterized by containing a thermally crosslinkable functional group.

(Crosslinkable functional group)
The acrylic resin having a thermally crosslinkable functional group of the present invention forms a crosslink with an acrylic resin having a thermally crosslinkable functional group or a binder resin in a heating step in the production of a color filter. Thereby, a strong film is formed, color change of the film can be prevented, that is, heat resistance can be improved, and solvent resistance is also improved.

The preferred structure of the thermally crosslinkable functional group is not particularly limited, and examples thereof include a hydroxyl group, a carboxyl group, a carboxylic anhydride, a primary or secondary amino group, an imino group, an oxetanyl group, a t-butyl group, and an epoxy. Group, mercapto group, isocyanate group, allyl group, (meth) acryl group and the like.
Among these, from the viewpoint of storage stability and reactivity with other materials in the use of a coloring composition for a color filter, a hydroxyl group, a carboxyl group, an oxetanyl group, a t-butyl group, an isocyanate group, and a (meth) acryl group are preferable. In particular, it preferably has a hydroxyl group.
Moreover, it is preferable to have a carboxyl group from a viewpoint of alkali developability.

One method for introducing a thermally crosslinkable functional group into the B block in the resin (B) having a cationic group in the side chain used in the present invention is to use an ethylenically unsaturated monomer having a thermally crosslinkable functional group. This is a method of copolymerization.

Examples of the ethylenically unsaturated monomer having a hydroxyl group are not particularly limited. For example, 2-hydroxyethyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, Examples thereof include glycerol mono (meth) acrylate, 4-hydroxyvinylbenzene, 2-hydroxy-3-phenoxypropyl acrylate or caprolactone adducts of these monomers (addition mole number is preferably 1 to 5).

Examples of the ethylenically unsaturated monomer having a carboxyl group include acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, crotonic acid, etc., and ethylenic having a carboxylic anhydride group. Examples of the unsaturated monomer include maleic anhydride and itaconic anhydride.

Examples of the ethylenically unsaturated monomer having an oxetanyl group include 3- (acryloyloxymethyl) 3-methyloxetane, 3- (methacryloyloxymethyl) 3-methyloxetane, 3- (acryloyloxymethyl) 3-ethyloxetane, 3- (methacryloyloxymethyl) 3-ethyloxetane, 3- (acryloyloxymethyl) 3-butyloxetane, 3- (methacryloyloxymethyl) 3-butyloxetane, 3- (acryloyloxymethyl) 3-hexyloxetane and 3- (Methacryloyloxymethyl) 3-hexyloxetane and the like.

Examples of the ethylenically unsaturated monomer having a t-butyl group include t-butyl acrylate and t-butyl methacrylate.

Examples of the ethylenically unsaturated monomer having an isocyanate group include 2-isocyanate ethyl methacrylate, 2-isocyanate ethyl acrylate, 4-isocyanate butyl methacrylate, 4-isocyanate butyl acrylate, and the like.

The isocyanate group in the present invention includes a blocked isocyanate group and can be preferably used. Under normal conditions, the blocked isocyanate group can protect the isocyanate group with other functional groups to suppress the reactivity of the isocyanate group, and can be deprotected by heating to regenerate the active isocyanate group. The isocyanate block body is shown.

Examples of commercially available ethylenically unsaturated monomers having such a blocked isocyanate group include 2-[(3,5-dimethylpyrazolyl) carboxyamino] ethyl methacrylate (Karenz MOI-BP, Showa Denko); Examples include 2- (0- [1′methylpropylideneamino] carboxyamino) ethyl methacrylate (Karenz MOI-BM, manufactured by Showa Denko).

Moreover, as an ethylenically unsaturated monomer which has a block isocyanate group, a commercial item can be used, and it can also prepare and use by a well-known method. For example, an isocyanate compound having an ethylenically unsaturated bond and a blocking agent are stirred in a solvent at a temperature of about 0 to 200 ° C., and known separation and purification means such as concentration, filtration, extraction, crystallization and distillation are performed. It can obtain by separating using.

Another method for introducing the thermally crosslinkable functional group in the resin (B) having a cationic group in the side chain used in the present invention into the acrylic resin is to obtain the acrylic resin, In this method, a functional group capable of reacting with the functional group is reacted with a compound having a thermally crosslinkable functional group. For example, by reacting a glycidyl group of an ethylenically unsaturated monomer having a glycidyl group with a carboxyl group in an acrylic resin having a carboxyl group, an acrylic resin having a (meth) acryloyl group as a thermally crosslinkable functional group is obtained. Can be obtained.

At least one kind of the heat-crosslinkable functional group needs to be contained in the resin, and two or more kinds may be contained.

Furthermore, when two or more types of thermally crosslinkable functional groups are contained, there is a preferable combination among the thermally crosslinkable functional groups. This is a combination in which heat-crosslinkable functional groups are more likely to react with each other when heated. In this case, the effect of crosslinking is improved. For example, it is effective to use an oxetanyl group and a carboxyl group at the same time. Similarly, since a t-butyl group becomes a carboxyl group when heated, a combination of an oxetanyl group and a t-butyl group is also effective. A combination of a hydroxyl group, a blocked isocyanate group and an isocyanate group is also effective. In particular, the combination of a hydroxyl group and a carboxyl group is most preferable because not only a strong film can be obtained by thermal crosslinking, but also in the alkali development step before thermal crosslinking, alkali developability is improved by the presence of carboxyl groups.

Then, the glass transition temperature of resin (B) which has a cationic group in a side chain used for this invention is demonstrated.

(Glass-transition temperature)
When synthesizing the resin (B) having a cationic group in the side chain used in the present invention, the glass transition temperature (hereinafter abbreviated as Tg) is 50 ° C. by selecting the ethylenically unsaturated monomer to be used. The above acrylic resin can be obtained. It is possible to control the Tg of the acrylic resin by appropriately selecting the ethylenically unsaturated monomer to be used within a range that does not affect other physical properties. Since Tg of the acrylic resin directly affects the heat resistance of the color filter, when this Tg is less than 50 ° C. and does not have a thermally crosslinkable functional group, a color change at high temperature, that is, poor heat resistance occurs.

Considering use in the field of electronics such as a color filter having a heating step of 200 ° C. or higher, the Tg of the acrylic part is more preferably 70 ° C. or higher. The upper limit of Tg is not particularly limited, but if it exceeds 150 ° C., there may be practically problems in workability and film-forming property, so that it is preferably less than 150 ° C.

The Tg of the acrylic resin of the present invention indicates a value calculated by the Fox formula shown below from the Tg of each homopolymer of the ethylenically unsaturated monomer to be copolymerized.
Fox formula 1 / Tg = W1 / Tg1 + W2 / Tg2 +... + Wn / Tgn
W1 to Wn represent the weight fraction of the monomer used, and Tg1 to Tgn represent the glass transition temperature of the monomer homopolymer (unit is absolute temperature “K”).
Tg (glass transition temperature) of the homopolymer of the main monomer used for calculation is illustrated below.
Ethyl acrylate: -22 ° C (251K)
Butyl acrylate: -54 ° C (219K)
Benzyl methacrylate: 55 ° C (328K)
Acrylic acid: 106 ° C (379K)
Methyl methacrylate: 105 ° C (378K)
n-butyl methacrylate: 20 ° C. (293 K)
2-ethylhexyl methacrylate: -10 ° C (263K)
Hydroxyethyl methacrylate: 55 ° C (328K)
Methacrylic acid: 130 ° C (403K)
3- (Methacryloyloxymethyl) 3-ethyloxetane: 105 ° C. (378 K)
2-isocyanatoethyl methacrylate: 60 ° C. (333 K)
t-butyl methacrylate: 107 ° C. (380 K)
Dimethylaminoethyl methyl chloride salt: 58 ° C (331K)

For example, when the calculation is performed by the above method, the glass transition temperature of the vinyl polymer portion obtained by radical polymerization of an ethylenically unsaturated monomer synthesized using 90 parts by weight of methyl methacrylate and 10 parts by weight of ethyl acrylate is 86.8. It becomes ℃.

In order to increase Tg, it is necessary to contain an ethylenically unsaturated monomer having a high Tg of the homopolymer in the copolymer composition. Among the ethylenically unsaturated monomers, the following are high in Tg and are effective for increasing the Tg of the acrylic resin.
Monomers with relatively high Tg of homopolymer are listed.
Methyl methacrylate: 105 ° C (378K)
t-butyl methacrylate: 107 ° C. (380 K)
Methacrylic acid: 130 ° C (403K)
Acrylic acid: 106 ° C (379K)
3- (Methacryloyloxymethyl) 3-ethyloxetane: 105 ° C. (378 K)
Isobornyl acrylate: 94 ° C (367K)
Isobornyl methacrylate: 180 ° C (453K)
Dicyclopentanyl acrylate: 120 ° C (393K)
Dicyclopentanyl methacrylate: 175 ° C (448K)
Adamantyl acrylate: 153 ° C (426K)
Adamantyl methacrylate: 250 ° C (523K)
Among these, t-butyl methacrylate and methacrylic acid are particularly preferable because they can increase the Tg and introduce a thermally crosslinkable functional group. Further, methyl methacrylate is preferable from the viewpoint of versatility.

Other examples of the ethylenically unsaturated monomer that can be used other than the ethylenically unsaturated monomer include (meth) acrylic acid esters, crotonic acid esters, vinyl esters, maleic acid diesters, Preference is given to fumaric acid diesters, itaconic acid diesters, (meth) acrylamides, vinyl ethers, esters of vinyl alcohol, styrenes, (meth) acrylonitrile and the like.

Specific examples of such vinyl monomers include the following compounds.

Examples of (meth) acrylic acid esters include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, and n-butyl (meth) acrylate. , Isobutyl (meth) acrylate, t-butyl (meth) acrylate, n-hexyl (meth) acrylate, cyclohexyl (meth) acrylate, t-butylcyclohexyl (meth) acrylate, (meth) acrylic acid 2- Ethylhexyl, t-octyl (meth) acrylate, dodecyl (meth) acrylate, octadecyl (meth) acrylate, acetoxyethyl (meth) acrylate, phenyl (meth) acrylate, 2-methoxyethyl (meth) acrylate, (Meth) acrylic acid 2-ethoxyethyl, (meth) acrylic acid 2- (2-methoxyethyl) Xyl) ethyl, benzyl (meth) acrylate, (meth) acrylic acid diethylene glycol monomethyl ether, (meth) acrylic acid diethylene glycol monoethyl ether, (meth) acrylic acid triethylene glycol monomethyl ether, (meth) acrylic acid triethylene glycol mono Ethyl ether, (meth) acrylic acid polyethylene glycol monomethyl ether, (meth) acrylic acid polyethylene glycol monoethyl ether, (meth) acrylic acid β-phenoxyethoxyethyl, (meth) acrylic acid nonylphenoxy polyethylene glycol, (meth) acrylic acid Dicyclopentenyl, dicyclopentenyloxyethyl (meth) acrylate, trifluoroethyl (meth) acrylate, octafluoropentyl (meth) acrylate , Perfluorooctylethyl (meth) acrylate, dicyclopentanyl (meth) acrylate, tribromophenyl (meth) acrylate, tribromophenyloxyethyl (meth) acrylate, and the like.

Examples of crotonic acid esters include butyl crotonate and hexyl crotonate.

Examples of vinyl esters include vinyl acetate, vinyl propionate, vinyl butyrate, vinyl methoxyacetate, vinyl benzoate, and the like. Examples of maleic acid diesters include dimethyl maleate, diethyl maleate, and dibutyl maleate.

Examples of the fumaric acid diesters include dimethyl fumarate, diethyl fumarate, and dibutyl fumarate.

Examples of itaconic acid diesters include dimethyl itaconate, diethyl itaconate, and dibutyl itaconate.

Examples of (meth) acrylamides include (meth) acrylamide, N-methyl (meth) acrylamide, N-ethyl (meth) acrylamide, N-propyl (meth) acrylamide, N-isopropyl (meth) acrylamide, Nn -Butyl acryl (meth) amide, Nt-butyl (meth) acrylamide, N-cyclohexyl (meth) acrylamide, N- (2-methoxyethyl) (meth) acrylamide, N, N-dimethyl (meth) acrylamide, N , N-diethyl (meth) acrylamide, N-phenyl (meth) acrylamide, N-benzyl (meth) acrylamide, (meth) acryloylmorpholine, diacetone acrylamide and the like.

Examples of vinyl ethers include methyl vinyl ether, butyl vinyl ether, hexyl vinyl ether, and methoxyethyl vinyl ether. Examples of styrenes include styrene, methyl styrene, dimethyl styrene, trimethyl styrene, ethyl styrene, isopropyl styrene, butyl styrene, hydroxy styrene, methoxy styrene, butoxy styrene, acetoxy styrene, chlorostyrene, dichlorostyrene, bromostyrene, chloromethyl Examples thereof include styrene, hydroxystyrene protected with a group that can be deprotected by an acidic substance (for example, t-Boc and the like), methyl vinylbenzoate, and α-methylstyrene.

(Block resin)
The block resin of the present invention can be obtained by copolymerizing an ethylenically unsaturated monomer.
A block resin comprising an A block having a cationic group represented by the general formula (1) of the present invention and a B block having no cationic group represented by the general formula (1) is an AB block, A B-A-B block or A-B-A is preferable, and an AB block or a B-A-B block can be used more preferably.
Such a block copolymer is prepared, for example, by the living polymerization method shown below. Here, the living polymerization is a polymerization method in which side reactions occurring in general radical polymerization are suppressed, and further, the growth of the polymerization occurs uniformly, so that a block polymer or a resin having a uniform molecular weight is easily synthesized. Depending on the charge ratio of the polymerization initiator and vinyl monomer added during polymerization, the molecular weight of the polymer and the ratio of monomers copolymerized with the block can be freely controlled, including block polymers, gradient polymers, star polymers, comb polymers, Can be used for the production of terminal functional polymers and the like.

The block copolymer of the present invention can be synthesized by a known radical living polymerization method. As specific examples, the methods listed below have been developed, and extensive research and development has been conducted. Nitroxide mediated polymerization (NMP method) using dissociation and bonding of amine oxide radicals (see Reference 1). Atom transfer radical polymerization (ATRP method) using a heavy metal such as copper, ruthenium, nickel and iron and a ligand that forms a complex with the heavy metal as a starting compound (Atom transfer radical polymerization: ATRP method) (Reference 2, Reference 3 and Reference 4). Reversible addition-fragmentation chain transfer (RAFT method) in which dithiocarboxylic acid ester or xanthate compound is used as the starting compound and polymerized using an addition polymerizable monomer and a radical initiator (references) 5) and Macromolecular Designvia Interchange of Xanthate (MADIX method) (see Reference 6). A method using a heavy metal such as organic tellurium, organic bismuth, organic antimony, antimony halide, organic germanium, and germanium halide (Degenerative transfer: DT method) (see Reference 7 and Reference 8).

(Reference 1) Chemical Review (2001) 101, 3661
(Reference 2) JP 2000-500516 A (Reference 3) JP 2000-514479 A (Reference 4) Chemical Review (2001) 101, 3687
(Reference 5) JP 2000-515181 (Reference 6) Pamphlet of International Publication No. 1999-05099 (Reference 7) JP 2007-277533 (Reference 8) JournalofAmerican Chemical Society (2002) 124, 2874

Among these radical living polymerizations, the atom transfer radical polymerization method (ATRP method) in which an organic halide or a sulfonyl halide compound is used as an initiator and a metal complex having a transition metal as a central metal as a catalyst is used for the molecular weight of the polymer. This is preferable not only in terms of controlling the molecular weight distribution, but also in that it can be applied to a wide range of monomers and a polymerization temperature that can be applied to existing equipment.

In the atom transfer radical polymerization method, a transition metal complex such as copper, ruthenium, iron and nickel is used as a redox polymerization catalyst. Specific examples of the transition metal complex include low-valent transition metal halides such as copper (I) chloride and copper (I) bromide.

An organic ligand is used for the fiber metal complex. Organic ligands are used to allow for reversibility of the solubility in the polymerization solvent and the redox polymerization catalyst. Examples of the coordination atom of the transition metal include a nitrogen atom, an oxygen atom, a phosphorus atom, and a sulfur atom.

As the initiator used in the atomic radical polymerization method, known initiators can be used, and mainly organic halides having a highly reactive carbon halogen bond, halogenated sulfonyl compounds, and the like are used. Specific examples include ethyl bromoisobutyrate, ethyl bromobutyrate, ethyl chloroisobutyrate, ethyl chlorobutyrate, paratoluenesulfonic acid chloride, 1-bromoethylbenzene, chloroethylbenzene, and the like. These are used alone or in combination.

The content of the partial structure (A block) having a cationic group represented by the general formula (1) in the side chain with respect to the block copolymer solid content is preferably 1 to 99% by weight, and further 3 It is preferably contained in an amount of from 90% by weight to 90% by weight, particularly preferably from 5% by weight to 30% by weight. When the A block contains 20 wt% to 30 wt%, the remaining 70 wt% to 80 wt% constitutes the B block. Therefore, when the B block has an affinity for the solvent as the dispersion medium, the salt-forming compound can be stably present in the dispersion medium, and the stability over time is improved.

The block copolymer used in the present invention may be an AB block copolymer or a B-A-B block copolymer, and the A block / B block ratio (weight) constituting the copolymer. The ratio is usually in the range of 1/99 or more, especially 20/80 or more, and usually 80/20 or less, especially 60/40 or less. Outside this range, it may not be possible to achieve both good stability over time and solvent resistance.

The block copolymer of the present invention preferably has an ammonium salt value of 10 to 200 mgKOH / g, more preferably 20 to 130 mgKOH / g. When the ammonium salt value is less than 10 mgKOH / g, the ratio of the anionic dye (C) to be reacted is reduced, so that the coloring power is lowered, and more salt-forming compound (D) is required in the resist material. Therefore, the binder resin, the curable resin, or the like originally added to the resist material is reduced, and the glass adhesion of the resist film may be deteriorated or the coating film resistance of the resist film may be deteriorated. On the other hand, when it exceeds 200 mgKOH / g, the solvent solubility of the salt-forming compound (D) deteriorates and precipitates as a foreign substance in the resist material.
In order for the ammonium salt value of the resin to satisfy the above range, the preferred content of the structural unit having a quaternary ammonium base is 4 to 74% by weight in a total of 100% by weight of the structural units constituting the resin, A more preferred range is 8 to 48% by weight.

In addition, the block copolymer of the present invention makes it easier for the dye salted to the A block having a cationic group to form an association between the dyes than to salt with the random body, and as a result, the heat resistance of the dye is reduced. It is thought to improve.

Moreover, the molecular weight of the block copolymer of the present invention is preferably a range of 1,000 or more and 100,000 or less in terms of polystyrene weight average. When the molecular weight of the block copolymer is less than 1,000, the aging stability of the salt-forming compound is lowered, and when it exceeds 100,000, the solvent resistance tends to be lowered.

In the step of producing the resin (B) having a cationic group in the side chain, a solvent can be used or no solvent. Examples of the solvent include ethyl acetate, n-butyl acetate, isobutyl acetate, hexane, toluene, xylene, acetone, methyl ethyl ketone, methoxypropyl acetate, cyclohexanone, propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, ethylene glycol monoethyl. Ether acetate, ethylene glycol monobutyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, or the like is used, but is not particularly limited, and can be arbitrarily selected from applications, costs, and the like. Two or more kinds of polymerization solvents may be mixed and used.

The amount of the solvent used is preferably 0 to 300 parts by weight, more preferably 0 to 100 parts by weight, based on 100 parts by weight of the ethylenically unsaturated monomer. The solvent used can be removed by an operation such as distillation after completion of the reaction, or can be used as it is as a part of the product of the dispersant.

(Anionic dye (C))
Next, the anionic dye (C) for obtaining the salt-forming compound (D) of the present invention will be described. The anionic dye (C) may be a colored compound having an anionic group that is ionically bonded to the cationic group described above. Such a coloring compound is not particularly limited as long as it has a carboxylic acid group, a sulfonic acid group, a phenolic hydroxyl group, a phosphoric acid group, or a metal salt thereof in the molecule, and an organic solvent or developer. Can be appropriately selected in consideration of all the required performance such as solubility in water, salt-forming property, absorbance, interaction with other components in the composition, light resistance, heat resistance and the like.

Examples of the anionic dye (C) include anthraquinone anionic dyes, monoazo anionic dyes, disazo anionic dyes, oxazine anionic dyes, amino ketone anionic dyes, xanthene anionic dyes, and quinoline anions. Dyes, triphenylmethane anionic dyes and the like. Below, the specific example of the anionic dye which can be used for the synthesis | combination of a salt-forming compound (D) is shown by a color index number.

Examples of red dyes include C.I. I. Acid Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 22, 23, 24, 25, 25: 1, 26, 26: 1, 26: 2, 27, 29, 30, 31, 32, 33, 34, 35, 36, 37, 39, 40, 41, 42, 43, 44, 45, 47, 50, 52, 53, 54, 55, 56, 57, 59, 60, 62, 64, 65, 66, 67, 68, 70, 71, 73, 74, 76, 76: 1, 80, 81, 82, 83, 85, 86, 87, 88, 89, 91, 92, 93, 97, 99, 102, 104, 106, 107, 108, 110, 111, 113, 114, 115, 116, 120, 123, 125, 127, 128, 131, 132, 133, 134, 135, 37, 138, 141, 142, 143, 144, 148, 150, 151, 152, 154, 155, 157, 158, 160, 161, 163, 164, 167, 170, 171, 172, 173, 175, 176, 177, 181, 229, 231, 237, 239, 240, 241, 242, 249, 252, 253, 255, 257, 260, 263, 264, 266, 267, 274, 276, 280, 286, 289, 299, 306, 309, 311, 323, 333, 324, 325, 326, 334, 335, 336, 337, 340, 343, 344, 347, 348, 350, 351, 353, 354, 356, 388 and the like.

In addition, C.I. I. Direct Red 1, 2, 2: 1, 4, 5, 6, 7, 8, 10, 10: 1, 13, 14, 15, 16, 17, 18, 21, 22, 23, 24, 26, 26: 1, 28, 29, 31, 33, 33: 1, 34, 35, 36, 37, 39, 42, 43, 43: 1, 44, 46, 49, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 67, 67: 1, 68, 72, 72: 1, 73, 74, 75, 77, 78, 79, 81, 81: 1, 85, 86, 88, 89, 90, 97, 100, 101, 101: 1, 107, 108, 110, 114, 116, 117, 120, 121, 122, 122: 1, 124, 125, 127, 127: 1, 127: 2, 128, 129, 130, 132, 134, 135, 136, 137, 1 8, 140, 141, 148, 149, 150, 152, 153, 154, 155, 156, 169, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 186, 189, 204, 211, 213, 214, 217, 222, 224, 225, 226, 227, 228, 232, 236, 237, 238, etc. can also be used.

Examples of yellow dyes include C.I. I. Acid Yellow 2, 3, 4, 5, 6, 7, 8, 9, 9: 1, 10, 11, 11: 1, 12, 13, 14, 15, 16, 17, 17: 1, 18, 20, 21, 22, 23, 25, 26, 27, 29, 30, 31, 33, 34, 36, 38, 39, 40, 40: 1, 41, 42, 42: 1, 43, 44, 46, 48, 51, 53, 55, 56, 60, 63, 65, 66, 67, 68, 69, 72, 76, 82, 83, 84, 86, 87, 90, 94, 105, 115, 117, 122, 127, 131, 132, 136, 141, 142, 143, 144, 145, 146, 149, 153, 159, 166, 168, 169, 172, 174, 175, 178, 180, 183, 187, 188, 189, 190, 191, 192, 199 etc. And the like.

In addition, C.I. I. Direct yellow 1, 2, 4, 5, 12, 13, 15, 20, 24, 25, 26, 32, 33, 34, 35, 41, 42, 44, 44: 1, 45, 46, 48, 49, 50, 51, 61, 66, 67, 69, 70, 71, 72, 73, 74, 81, 84, 86, 90, 91, 92, 95, 107, 110, 117, 118, 119, 120, 121, 126, 127, 129, 132, 133, 134, etc. can also be used.

Examples of orange dyes include C.I. I. Acid Orange 1, 1: 1, 4, 5, 6, 7, 8, 9, 10, 12, 14, 16, 17, 18, 19, 20, 20: 1, 22, 23, 24, 24: 1 25, 27, 28, 28: 1, 30, 31, 33, 35, 36, 37, 38, 41, 45, 49, 50, 51, 54, 55, 56, 59, 79, 83, 94, 95, 102, 106, 116, 117, 119, 128, 131, 132, 134, 136, 138 and the like.
In addition, C.I. I. Direct Orange 1, 2, 3, 4, 5, 6, 7, 8, 10, 13, 17, 19, 20, 21, 24, 25, 26, 29, 29: 1, 30, 31, 32, 33, 43, 49, 51, 56, 59, 69, 72, 73, 74, 75, 76, 79, 80, 83, 84, 85, 87, 88, 90, 91, 92, 95, 96, 97, 98, 101, 102, 102: 1, 104, 108, 112, 114, etc. can also be used.

Examples of blue dyes include C.I. I. Acid Blue 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 13, 14, 15, 17, 19, 21, 22, 23, 24, 25, 26, 27, 29, 34, 35, 37, 40, 41, 41: 1, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 62, 62: 1, 63, 64, 65, 68, 69, 70, 73, 75, 78, 79, 80, 81, 83, 8485, 86, 88, 89, 90, 90: 1, 91, 92, 93, 95, 96, 99, 100, 103, 104, 108, 109, 110, 111, 112, 113, 114, 116, 117, 118, 119, 120, 123, 124, 127, 127: 1, 128, 129, 135, 137, 138, 143, 145, 147, 1 0, 155, 159, 169, 174, 175, 176, 183, 198, 203, 204, 205, 206, 208, 213, 227, 230, 231, 232, 233, 235, 239, 245, 247, 253, 257, 258, 260, 261, 262, 264, 266, 269, 271, 272, 273, 274, 277, 278, 280 and the like.

In addition, C.I. I. Direct Blue 1, 2, 3, 4, 6, 7, 8, 8: 1, 9, 10, 12, 14, 15, 16, 19, 20, 21, 21: 1, 22, 23, 25, 27, 29, 31, 35, 36, 37, 40, 42, 45, 48, 49, 50, 53, 54, 55, 58, 60, 61, 64, 65, 67, 79, 96, 97, 98: 1, 101, 106, 107, 108, 109, 111, 116, 122, 123, 124, 128, 129130, 130: 1, 132, 136, 138, 140, 145, 146, 149, 152, 153, 154, 156, 158, 158: 1, 164, 165, 166, 167, 168, 169, 170, 174, 177, 181, 184, 185, 188, 190, 192, 193, 206, 207, 209, 213 215,225,226,229,230,231,242,243,244,253,254,260,263 and the like can also be used.

Examples of purple dyes include C.I. I. Acid Violet 1, 2, 3, 4, 5, 5: 1, 6, 7, 7: 1, 9, 11, 12, 13, 14, 15, 16, 17, 19, 20, 21, 23, 24, 25, 27, 29, 30, 31, 33, 34, 36, 38, 39, 41, 42, 43, 47, 49, 51, 63, 67, 72, 76, 96, 97, 102, 103, 109, etc. Is mentioned.

In addition, C.I. I. Direct violet 1, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 16, 17, 18, 21, 22, 25, 26, 27, 28, 29, 30, 31, 32, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 45, 51, 52, 54, 57, 58, 61, 62, 63, 64, 71, 72, 77, 78, 79, 80, 81, 82, 83, 85, 86, 87, 88, 93, 97, etc. can also be used.

Examples of the green dye include C.I. I. Acid Green 2, 3, 5, 6, 7, 8, 9, 10, 11, 13, 14, 15, 16, 17, 18, 19, 20, 22, 25, 25: 1, 27, 34, 36, 37, 38, 40, 41, 42, 44, 54, 55, 59, 66, 69, 70, 71, 81, 84, 94, 95 and the like.
In addition, C.I. I. Direct green 11, 13, 14, 24, 30, 34, 38, 42, 49, 55, 56, 57, 60, 78, 79, 80, etc. can also be used.

Moreover, the dye represented by General formula (2) is mentioned.

General formula (2)
[X1 and X3 represent a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms which may have a substituent.
X2 and X4 represent a monovalent aromatic hydrocarbon group which may have a substituent, and at least one of them has a sulfo group. ]

In particular, acid red 52, acid 289, and the dye represented by the general formula (2) are preferable.

(Salt formation)
The salt-forming compound (D) of the present invention is prepared by stirring or vibrating an aqueous solution in which a resin (B) having a cationic group in the side chain and an anionic dye (C) are dissolved, or cationic in the side chain. It can be easily obtained by mixing an aqueous solution of the resin (B) having a group and an aqueous solution of the anionic dye (C) under stirring or vibration. In the aqueous solution, the cationic group of the resin and the anionic group of the dye are ionized, these are ionically bonded, and the ion-bonded portion becomes water-insoluble and precipitates. On the contrary, the salt composed of the counter anion of the resin and the counter cation of the acidic dye is water-soluble and can be removed by washing or the like. As the resin (B) having a cationic group in the side chain to be used and the anionic dye (C), only a single type or a plurality of types having different structures may be used.

As an aqueous solution used at the time of salt formation, a mixed solution of water and a water-soluble organic solvent may be used in order to dissolve the resin (B) having a cationic group in the side chain and an anionic dye. Examples of the water-soluble organic solvent include methanol, ethanol, n-propanol, isopropanol, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, n-butanol, isobutanol, 2- (methoxymethoxy) ethanol, 2- Butoxyethanol, 2- (isopentyloxy) ethanol, 2- (hexyloxy) ethanol, ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene Glycol, propylene glycolic monomethyl ether acetate, dipropylene glycol, dipropylene glycol Monomethyl ether, dipropylene glycol monoethyl ether, triethylene glycol, triethylene glycol monomethyl ether, polyethylene glycol, glycerin, tetraethylene glycol, dipropylene glycol, acetone, diacetone alcohol, aniline, pyridine, ethyl acetate, isopropyl acetate, methyl ethyl ketone , N, N-dimethylformamide, dimethyl sulfoxide, tetrahydrofuran (THF), dioxane, 2-pyrrolidone, 2-methylpyrrolidone, N-methyl-2-pyrrolidone, 1,2-hexanediol, 2,4,6-hexanetriol , Tetrafurfuryl alcohol, 4-methoxy-4-methylpentanone and the like. These water-soluble organic solvents are preferably used in an amount of 5 to 50% by weight, and most preferably 5 to 20% by weight, based on the total weight of the aqueous solution (100% by weight).

The ratio of the resin (B) having a cationic group in the side chain and the anionic dye (C) is such that the molar ratio of the total cationic unit of the resin to the total anionic group of the anionic dye (C) is 10/1. The salt-forming compound (D) of the present invention can be suitably adjusted if it is in the range of ˜¼, and more preferably in the range of 2/1 to ½.

<Pigment>
The coloring composition for a color filter of the present invention can be used as a coloring composition for a color filter by further adding a pigment.
As the pigment, organic or inorganic pigments can be used alone or in admixture of two or more. The pigment is preferably a pigment having a high color developability and a high heat resistance, particularly a pigment having a high heat decomposition resistance, and an organic pigment is usually used. Below, the specific example of the organic pigment which can be used for the coloring composition for color filters is shown by a color index number.

Examples of the red coloring composition for forming the red filter segment include C.I. I. Pigment Red 7, 9, 14, 41, 48: 1, 48: 2, 48: 3, 48: 4, 57: 1, 81, 81: 1, 81: 2, 81: 3, 81: 4, 97, 122, 123, 146, 149, 150, 168, 169, 176, 177, 178, 180, 184, 185, 187, 192, 200, 202, 208, 209, 210, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 242, 246, 254, 255, 264, 268, 270, 272, 273, 274, 276, 277, 278, 279, 280, 281, 282, 283, 284, 285, Red pigments such as 286 or 287 can be used. The red coloring composition includes C.I. I. Pigment Orange 36, 38, 43, 51, 55, 59, 61, 71, or 73, and / or C.I. I. Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14, 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 17 It can be used in combination with yellow pigments such as 177,179,180,181,182,185,187,188,193,194,198,199,213,214,218,219,220 or 221,.

Examples of the green coloring composition for forming the green filter segment include C.I. I. Green pigments such as CI Pigment Green 7, 10, 36, 37, and 58 can be used. The green coloring composition includes C.I. I. Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12,
13, 14, 15, 16, 17, 18, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 93, 94, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 126, 127, 128, 129, 138, 139, 147, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194, 198 199,213,214,218,219,220, or a yellow pigment 221 and the like can be used in combination.

Examples of the blue coloring composition for forming the blue filter segment include C.I. I. Pigment Blue 1, 1: 2, 1: 3, 2, 2: 1, 2: 2, 3, 8, 9, 10, 10: 1, 11, 12, 15, 15: 1, 15: 2, 15: 3, 15: 4, 15: 6, 16, 18, 19, 22, 24, 24: 1, 53, 56, 56: 1, 57, 58, 59, 60, 61, 62, 64, etc. Can be used. The blue coloring composition includes C.I. I. Purple violet pigments such as CI Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42, and 50 can be used in combination. It is also preferable to use an aluminum phthalocyanine pigment, and aluminum phthalocyanine pigments described in JP-A No. 2004-333817, Japanese Patent No. 4893859 and the like can also be used.

Examples of the cyan coloring composition for forming the cyan filter segment include C.I. I. Blue pigments such as CI Pigment Blue 15: 1, 15: 2, 15: 4, 15: 3, 15: 6, 16, and 81 can be used alone or in combination.

Examples of magenta colored compositions for forming magenta color filter segments include C.I. I. Pigment violet 1, 19, C.I. I. Purple pigments such as CI Pigment Red 144, 146, 177, 169, 81, and red pigments can be used alone or in combination. A yellow pigment can be used in combination with the magenta composition.

Inorganic pigments include titanium oxide, barium sulfate, zinc white, lead sulfate, yellow lead, zinc yellow, red bean (red iron (III) oxide), cadmium red, ultramarine, bitumen, chromium oxide green, cobalt green, amber And synthetic iron black. Inorganic pigments are used in combination with organic pigments in order to ensure good coatability, sensitivity, developability and the like while maintaining a balance between saturation and lightness.

(Miniaturization of pigment)
The pigment added to the coloring composition of the present invention is preferably refined by a salt milling process or the like in order to correspond to high transmittance and high contrast. The primary particle diameter of the pigment is preferably 10 nm or more because of good dispersion in the colorant carrier. Moreover, since a filter segment with high contrast can be formed, it is preferable that it is 80 nm or less. A particularly preferred range is 20 to 60 nm.

Salt milling is a process in which a mixture of pigment, water-soluble inorganic salt and water-soluble organic solvent is heated using a kneader such as a kneader, two-roll mill, three-roll mill, ball mill, attritor, or sand mill. After kneading, the water-soluble inorganic salt and the water-soluble organic solvent are removed by washing with water. The water-soluble inorganic salt serves as a crushing aid, and the pigment is crushed using the high hardness of the inorganic salt during salt milling. By optimizing the conditions for salt milling the pigment, it is possible to obtain a pigment having a sharp particle size distribution with a very fine primary particle diameter and a wide distribution range.

As the water-soluble inorganic salt, sodium chloride, barium chloride, potassium chloride, sodium sulfate and the like can be used, but sodium chloride (salt) is preferably used from the viewpoint of cost. The water-soluble inorganic salt is preferably used in an amount of 50 to 2000% by weight, and most preferably 300 to 1000% by weight based on the total weight of the pigment (100% by weight) from the viewpoint of both processing efficiency and production efficiency.

The water-soluble organic solvent functions to wet the pigment and the water-soluble inorganic salt, and is not particularly limited as long as it dissolves (mixes) in water and does not substantially dissolve the inorganic salt to be used. However, a high boiling point solvent having a boiling point of 120 ° C. or higher is preferable from the viewpoint of safety because the temperature rises during salt milling and the solvent is easily evaporated. For example, 2-methoxyethanol, 2-butoxyethanol, 2- (isopentyloxy) ethanol, 2- (hexyloxy) ethanol, diethylene glycol, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, Liquid polyethylene glycol, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, liquid polypropylene glycol and the like are used. The water-soluble organic solvent is preferably used in an amount of 5 to 1000% by weight, and most preferably 50 to 500% by weight, based on the total weight of the pigment (100% by weight).

When the salt is milled, a resin may be added as necessary. The type of resin used is not particularly limited, and natural resins, modified natural resins, synthetic resins, synthetic resins modified with natural resins, and the like can be used. The resin used is solid at room temperature, preferably insoluble in water, and more preferably partially soluble in the organic solvent. The amount of resin used is preferably in the range of 5 to 200% by weight based on the total weight of the pigment (100% by weight).

<Binder resin>
The binder resin is one that disperses a colorant, particularly a salt-forming compound (D) and a pigment, or one that dyes and penetrates a salt-forming compound, and examples thereof include thermoplastic resins and thermosetting resins.

Examples of the thermoplastic resin include acrylic resin, butyral resin, styrene-maleic acid copolymer, chlorinated polyethylene, chlorinated polypropylene, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, polyvinyl acetate, and polyurethane resin. Polyester resins, vinyl resins, alkyd resins, polystyrene resins, polyamide resins, rubber resins, cyclized rubber resins, celluloses, polyethylene (HDPE, LDPE), polybutadiene, polyimide resins, and the like.

Examples of the thermosetting resin include epoxy resins, benzoguanamine resins, rosin-modified maleic acid resins, rosin-modified fumaric acid resins, melamine resins, urea resins, and phenol resins.

The binder resin is preferably a resin having a spectral transmittance of preferably 80% or more, more preferably 95% or more in the entire wavelength region of 400 to 700 nm in the visible light region. Moreover, since the coloring composition for color filters of the present invention is in the form of an alkali development type colored resist material, it is preferable to use an alkali-soluble vinyl resin obtained by copolymerizing an acidic group-containing ethylenically unsaturated monomer.

Examples of the alkali-soluble resin obtained by copolymerizing an acidic group-containing ethylenically unsaturated monomer include resins having an acidic group such as a carboxyl group and a sulfone group. Specific examples of the alkali-soluble resin include an acrylic resin having an acidic group, an α-olefin / (anhydrous) maleic acid copolymer, a styrene / styrene sulfonic acid copolymer, an ethylene / (meth) acrylic acid copolymer, or Examples include isobutylene / (anhydrous) maleic acid copolymer. Among these, at least one resin selected from an acrylic resin having an acidic group and a styrene / styrene sulfonic acid copolymer, particularly an acrylic resin having an acidic group, is preferably used because of its high heat resistance and transparency.

In order to improve the photosensitivity of the alkali-soluble resin copolymerized with the acidic group-containing ethylenic non-monomer, an energy beam curable resin having an ethylenically unsaturated active double bond can also be used. In addition, it is preferable to use an active energy ray-curable resin having an ethylenically unsaturated double bond in the side chain because it has an effect of improving the solvent resistance of the resist material.

Examples of the active energy ray-curable resin having an ethylenically unsaturated double bond include resins having an unsaturated ethylenic double bond introduced by the following methods (a) and (b).

[Method (a)]
As the method (a), for example, a side chain epoxy group of a copolymer obtained by copolymerizing an unsaturated ethylenic monomer having an epoxy group and one or more other monomers is used. Then, the carboxyl group of the unsaturated monobasic acid having an unsaturated ethylenic double bond is subjected to an addition reaction, and the resulting hydroxyl group is reacted with a polybasic acid anhydride to convert the unsaturated ethylenic double bond and the carboxyl group into There is a way to introduce.

Examples of the unsaturated ethylenic monomer having an epoxy group include glycidyl (meth) acrylate, methyl glycidyl (meth) acrylate, 2-glycidoxyethyl (meth) acrylate, 3,4 epoxybutyl (meth) acrylate, And 3,4 epoxy cyclohexyl (meth) acrylates, and these may be used alone or in combination of two or more. From the viewpoint of reactivity with the unsaturated monobasic acid in the next step, glycidyl (meth) acrylate is preferred.

Examples of unsaturated monobasic acids include (meth) acrylic acid, crotonic acid, o-, m-, p-vinylbenzoic acid, α-haloalkyl of (meth) acrylic acid, alkoxyl, halogen, nitro, cyano substituted products, etc. Monocarboxylic acid etc. are mentioned, These may be used independently or may use 2 or more types together.

Examples of polybasic acid anhydrides include tetrahydrophthalic anhydride, phthalic anhydride, hexahydrophthalic anhydride, succinic anhydride, maleic anhydride, etc., and these may be used alone or in combination of two or more. It doesn't matter. If necessary, use a tricarboxylic anhydride such as trimellitic anhydride or a tetracarboxylic dianhydride such as pyromellitic dianhydride to increase the number of carboxyl groups. The group can also be hydrolyzed. Moreover, when an etrahydrophthalic anhydride or maleic anhydride having an unsaturated ethylenic double bond is used as the polybasic acid anhydride, the number of unsaturated ethylenic double bonds can be increased.

As a method similar to the method (a), for example, a side chain of a copolymer obtained by copolymerizing an unsaturated ethylenic monomer having a carboxyl group and one or more other monomers. There is a method in which an unsaturated ethylenic monomer having an epoxy group is added to a part of a carboxyl group to introduce an unsaturated ethylenic double bond and a carboxyl group.

[Method (b)]
As the method (b), an unsaturated ethylenic monomer having a hydroxyl group is used, and an unsaturated monobasic acid monomer having another carboxyl group or another monomer is copolymerized. There is a method of reacting an isocyanate group of an unsaturated ethylenic monomer having an isocyanate group with a side chain hydroxyl group of the obtained copolymer.

Examples of the unsaturated ethylenic monomer having a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2- or 3-hydroxypropyl (meth) acrylate, 2- or 3- or 4-hydroxybutyl (meth) acrylate, and glycerol Examples thereof include hydroxyalkyl (meth) acrylates such as (meth) acrylate or cyclohexanedimethanol mono (meth) acrylate, and these may be used alone or in combination of two or more. Further, polyether mono (meth) acrylate obtained by addition polymerization of ethylene oxide, propylene oxide, and / or butylene oxide to the above hydroxyalkyl (meth) acrylate, (poly) γ-valerolactone, (poly) ε-caprolactone And / or (poly) 12-hydroxystearic acid added (poly) ester mono (meth) acrylate can also be used. From the viewpoint of suppressing foreign matter on the coating film, 2-hydroxyethyl (meth) acrylate or glycerol (meth) acrylate is preferable.

Examples of the unsaturated ethylenic monomer having an isocyanate group include 2- (meth) acryloyloxyethyl isocyanate, 1,1-bis [(meth) acryloyloxy] ethyl isocyanate, and the like. In addition, two or more types can be used in combination.

The weight average molecular weight (Mw) of the binder resin is preferably in the range of 10,000 to 100,000, more preferably in the range of 10,000 to 80,000 in order to disperse the colorant preferably. The number average molecular weight (Mn) is preferably in the range of 5,000 to 50,000, and the value of Mw / Mn is preferably 10 or less.

The binder resin has an affinity for a colorant adsorbing group and a carboxyl group acting as an alkali-soluble group during development, a colorant carrier, and a solvent from the viewpoints of dispersibility, penetrability, developability, and heat resistance of the pigment and salt-forming compound. The balance between the aliphatic group and aromatic group acting as a functional group is important for the dispersibility, penetrability, developability and durability of the pigment and salt-forming compound, and a resin having an acid value of 20 to 300 mgKOH / g is used. It is preferable. When the acid value is less than 20 mgKOH / g, the solubility in the developing solution is poor and it is difficult to form a fine pattern. When it exceeds 300 mgKOH / g, no fine pattern remains.

The binder resin is preferably used in an amount of 30% by weight or more based on the total weight of the colorant (100% by weight) because the film formability and various resistances are good, and the colorant concentration is high and good. Since color characteristics can be expressed, it is preferably used in an amount of 500 wt% or less.

<Organic solvent>
In the coloring composition of the present invention, the colorant is sufficiently dispersed and permeated in the colorant carrier, and is applied on a substrate such as a glass substrate so that the dry film thickness is 0.2 to 5 μm. An organic solvent can be included to facilitate the formation.

Examples of the organic solvent include ethyl lactate, benzyl alcohol, 1,2,3-trichloropropane, 1,3-butanediol, 1,3-butylene glycol, 1,3-butylene glycol diacetate, 1,4-dioxane, 2-heptanone, 2-methyl-1,3-propanediol, 3,5,5-trimethyl-2-cyclohexen-1-one, 3,3,5-trimethylcyclohexanone, ethyl 3-ethoxypropionate, 3-methyl -1,3-butanediol, 3-methoxy-3-methyl-1-butanol, 3-methoxy-3-methylbutyl acetate, 3-methoxybutanol, 3-methoxybutyl acetate, 4-heptanone, m-xylene, m -Diethylbenzene, m-dichlorobenzene, N, N-dimethylacetamide, N, N- Methylformamide, n-butyl alcohol, n-butylbenzene, n-propyl acetate, o-xylene, o-chlorotoluene, o-diethylbenzene, o-dichlorobenzene, p-chlorotoluene, p-diethylbenzene, sec-butylbenzene, tert-butylbenzene, γ-butyrolactone, isobutyl alcohol, isophorone, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monoethyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monotertiary butyl ether, Ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol Monopropyl ether, ethylene glycol monohexyl ether, ethylene glycol monomethyl ether, ethylene glycol monomethyl ether acetate, diisobutyl ketone, diethylene glycol diethyl ether, diethylene glycol dimethyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, diethylene glycol monobutyl ether acetate , Diethylene glycol monomethyl ether, cyclohexanol, cyclohexanol acetate, cyclohexanone, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monoethyl ether Dipropylene glycol monobutyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monomethyl ether, diacetone alcohol, triacetin, tripropylene glycol monobutyl ether, tripropylene glycol monomethyl ether, propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol mono Ethyl ether, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether propionate, benzyl alcohol, Louis Seo ketone, methyl cyclohexanol, acetic acid n- amyl acetate n- butyl, isoamyl acetate, isobutyl acetate, propyl acetate, and dibasic acid esters.

Among them, since the dispersion and dissolution of the pigment of the present invention and the salt-forming compound (D) are good, ethyl lactate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether It is preferable to use glycol acetates such as acetate, aromatic alcohols such as benzyl alcohol, and ketones such as cyclohexanone. In particular, propylene glycol monomethyl ether acetate is more preferable from the viewpoint of health and safety and low viscosity.

These organic solvents can be used individually by 1 type or in mixture of 2 or more types. In the case of using two or more kinds of mixed solvents, it is preferable that the above-mentioned preferable organic solvent is contained in an amount of 65 to 95% by weight.

In addition, since the organic solvent can adjust the colored composition to an appropriate viscosity to form a filter segment having a desired uniform film thickness, it is 800 to 4000 weights based on the total weight of the colorant (100 weight%). % Is preferably used.

<Dispersion>
The colored composition of the present invention comprises a salt-forming compound (D) obtained by reacting a resin (B) having a cationic group in the side chain with an anionic dye (C), the binder resin and a solvent. When the colorant carrier further contains a pigment, it is preferably finely dispersed together with a dispersing aid such as a dye derivative, using various dispersing means such as a three-roll mill, a two-roll mill, a sand mill, a kneader, or an attritor. Can be manufactured. The colored composition of the present invention can also be produced by mixing pigments, salt-forming compounds (D), and other colorants separately dispersed in a colorant carrier.

(Dispersing aid)
When dispersing the colorant in the colorant carrier, a dispersion aid such as a pigment derivative, a resin-type dispersant, and a surfactant can be appropriately used. The dispersion aid is excellent in dispersion of the colorant and has a large effect of preventing reaggregation of the colorant after dispersion. Therefore, a dispersion composition is used to disperse the colorant in the colorant carrier using the dispersion aid. When used, a color filter having a high spectral transmittance can be obtained.
In the present invention, the salt-forming compound (D) is also expected to play a role as a pigment dispersion aid.

Examples of the dye derivative include a compound obtained by introducing a basic substituent, an acidic substituent, or a phthalimidomethyl group which may have a substituent into an organic pigment, anthraquinone, acridone, or triazine. 63-305173, JP-B-57-15620, JP-B-59-40172, JP-B-63-17102, JP-B-5-9469, etc. can be used. These can be used alone or in combination of two or more.

The blending amount of the dye derivative is preferably 0.5% by weight or more, more preferably 1% by weight or more, most preferably from the viewpoint of improving the dispersibility of the additive pigment, based on the total amount of the additive pigment (100% by weight). 3% by weight or more. Further, from the viewpoint of heat resistance and light resistance, the total amount of the additive pigment is preferably 40% by weight or less, more preferably 35% by weight or less, based on the total amount (100% by weight).

The resin-type dispersant has a pigment-affinity part that has the property of adsorbing to the additive pigment and a part that is compatible with the colorant carrier, and adsorbs to the additive pigment to stabilize dispersion in the colorant carrier. It works. Specific examples of resin-type dispersants include polycarboxylic acid esters such as polyurethane and polyacrylate, unsaturated polyamides, polycarboxylic acids, polycarboxylic acid (partial) amine salts, polycarboxylic acid ammonium salts, and polycarboxylic acid alkylamine salts. , Polysiloxane, long-chain polyaminoamide phosphate, hydroxyl group-containing polycarboxylic acid ester, modified products thereof, amides formed by reaction of poly (lower alkyleneimine) and polyester having a free carboxyl group, and salts thereof Oil-soluble dispersants such as, (meth) acrylic acid-styrene copolymer, (meth) acrylic acid- (meth) acrylic acid ester copolymer, styrene-maleic acid copolymer, polyvinyl alcohol, polyvinylpyrrolidone, etc. Resin, water-soluble polymer, polyester, modified poly Acrylate-based, ethylene oxide / propylene oxide adduct, phosphoric ester or the like is used, they may be used alone or in combination, it is not necessarily limited thereto.

Commercially available resin-type dispersants include Disperbyk-101, 103, 107, 108, 110, 111, 116, 130, 140, 154, 161, 162, 163, 164, 165, 166, and 170 manufactured by Big Chemie Japan. 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2025, 2050, 2070, 2095, 2150, 2155 or Anti-Terra-U, 203, 204, or BYK- P104, P104S, 220S, 6919, or SOLPERSE-3000, 9000, 13000, 13240, 13650, 13940, 1600 manufactured by Nihon Lubrizol Corporation, such as Lactimon, Lactimon-WS, or Bykumen. 17000, 18000, 20000, 21000, 24000, 26000, 27000, 28000, 31845, 32000, 32500, 32550, 33500, 32600, 34750, 35100, 36600, 38500, 41000, 41090, 53095, 55000, 76500, etc., BASF Japan EFKA-46, 47, 48, 452, 4008, 4009, 4010, 4015, 4020, 4047, 4050, 4055, 4060, 4080, 4400, 4401, 4402, 4403, 4406, 4408, 4300, 4310, 4320 , 4330, 4340, 450, 451, 453, 4540, 4550, 4560, 4800, 5010, 5065, 5066, 5070, 7500, 7 54,1101,120,150,1501,1502,1503, etc., Ajinomoto Fine-Techno Co., Ltd. of AJISPER PA111, PB711, PB821, PB822, PB824, and the like.

Surfactants include sodium lauryl sulfate, polyoxyethylene alkyl ether sulfate, sodium dodecylbenzene sulfonate, alkali salt of styrene-acrylic acid copolymer, sodium stearate, sodium alkyl naphthalene sulfonate, sodium alkyl diphenyl ether disulfonate Anionic surfactants such as lauryl sulfate monoethanolamine, lauryl sulfate triethanolamine, ammonium lauryl sulfate, monoethanolamine stearate, monoethanolamine of styrene-acrylic acid copolymer, polyoxyethylene alkyl ether phosphate; Polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene Nonionic surfactants such as alkyl ether phosphates, polyoxyethylene sorbitan monostearate and polyethylene glycol monolaurate; chaotic surfactants such as alkyl quaternary ammonium salts and their ethylene oxide adducts; alkyldimethylamino Examples include amphoteric surfactants such as alkylbetaines such as betaine acetate and alkylimidazolines, and these can be used alone or in admixture of two or more, but are not necessarily limited thereto.

The amount of the resin-type dispersant and surfactant added is preferably 0.1 to 55% by weight, more preferably 0.1 to 45% by weight, based on the total amount of the added pigment (100% by weight). It is. When the blending amount of the resin-type dispersant and the surfactant is less than 0.1% by weight, it is difficult to obtain the added effect. When the blending amount is more than 55% by weight, the dispersion is adversely affected by the excessive dispersant. May affect.

<Photopolymerizable monomer>
The colored composition of the present invention can be used as a photosensitive colored composition for a color filter by further adding a photopolymerizable monomer and / or a photopolymerization initiator.

The photopolymerizable monomer of the present invention includes monomers or oligomers that are cured by ultraviolet rays or heat to produce a transparent resin, and these can be used alone or in combination of two or more. The amount of the monomer is preferably 5 to 400% by weight based on the total weight of the colorant (100% by weight), and more preferably 10 to 300% by weight from the viewpoint of photocurability and developability. preferable.

Examples of monomers and oligomers that are cured by ultraviolet rays or heat to produce a transparent resin include methyl (meth) acrylate, ethyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, and 2-hydroxypropyl (meth) acrylate. , Cyclohexyl (meth) acrylate, β-carboxyethyl (meth) acrylate, polyethylene glycol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, triethylene glycol di (meth) acrylate, tripropylene glycol di ( (Meth) acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, 1,6-hexanediol diglycy Luether di (meth) acrylate, bisphenol A diglycidyl ether di (meth) acrylate, neopentyl glycol diglycidyl ether di (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol penta (meth) acrylate, tricyclodeca Nyl (meth) acrylate, ester acrylate, methylolated melamine (meth) acrylate ester, epoxy (meth) acrylate, urethane acrylate and other acrylic esters and methacrylate esters, (meth) acrylic acid, styrene, vinyl acetate, Hydroxyethyl vinyl ether, ethylene glycol divinyl ether, pentaerythritol trivinyl ether, (meth) acrylamide, N-hydroxymethyl Examples include, but are not necessarily limited to, til (meth) acrylamide, N-vinylformamide, acrylonitrile and the like.

<Photopolymerization initiator>
The colored composition for a color filter of the present invention is a solvent development type or alkali development type colored resist material added with a photopolymerization initiator or the like when the composition is cured by ultraviolet irradiation and a filter segment is formed by a photolithographic method. It can be prepared in the form of The blending amount when using the photopolymerization initiator is preferably 5 to 200% by weight based on the total amount of the colorant, and 10 to 150% by weight from the viewpoint of photocurability and developability. More preferred.

Examples of the photopolymerization initiator include 4-phenoxydichloroacetophenone, 4-t-butyl-dichloroacetophenone, diethoxyacetophenone, 1- (4-isopropylphenyl) -2-hydroxy-2-methylpropan-1-one, 1- Hydroxycyclohexyl phenyl ketone, 2-methyl-1- [4- (methylthio) phenyl] -2-morpholinopropan-1-one, 2- (dimethylamino) -2-[(4-methylphenyl) methyl] -1 -[4
Acetophenone compounds such as-(4-morpholinyl) phenyl] -1-butanone or 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butan-1-one; benzoin, benzoin methyl ether, Benzoin compounds such as benzoin ethyl ether, benzoin isopropyl ether, or benzyldimethyl ketal; benzophenone, benzoylbenzoic acid, methyl benzoylbenzoate, 4-phenylbenzophenone, hydroxybenzophenone, acrylated benzophenone, 4-benzoyl-4'-methyldiphenyl Benzophenone compounds such as sulfide or 3,3 ′, 4,4′-tetra (t-butylperoxycarbonyl) benzophenone; thioxanthone, 2-chlorothioxanthone, 2-methyl Thioxanthone compounds such as thioxanthone, isopropylthioxanthone, 2,4-diisopropylthioxanthone, or 2,4-diethylthioxanthone; 2,4,6-trichloro-s-triazine, 2-phenyl-4,6-bis (trichloromethyl) -S-triazine, 2- (p-methoxyphenyl) -4,6-bis (trichloromethyl) -s-triazine, 2- (p-tolyl) -4,6-bis (trichloromethyl) -s-triazine, 2-piperonyl-4,6-bis (trichloromethyl) -s-triazine, 2,4-bis (trichloromethyl) -6-styryl-s-triazine, 2- (naphth-1-yl) -4,6- Bis (trichloromethyl) -s-triazine, 2- (4-methoxy-naphth-1-yl) -4,6-bis (trick Triazine compounds such as (romethyl) -s-triazine, 2,4-trichloromethyl- (piperonyl) -6-triazine, or 2,4-trichloromethyl- (4′-methoxystyryl) -6-triazine; -Octanedione, 1- [4- (phenylthio)-, 2- (O-benzoyloxime)], or O- (acetyl) -N- (1-phenyl-2-oxo-2- (4'-methoxy- Oxime ester compounds such as naphthyl) ethylidene) hydroxylamine; phosphine compounds such as bis (2,4,6-trimethylbenzoyl) phenylphosphine oxide or 2,4,6-trimethylbenzoyldiphenylphosphine oxide; 9,10- Quinone compounds such as phenanthrenequinone, camphorquinone and ethylanthraquinone Borate compounds; carbazole compounds; imidazole compounds; or titanocene compounds.

These photopolymerization initiators can be used alone or in combination of two or more at any ratio as required. These photopolymerization initiators are preferably 5 to 200% by weight based on the total amount of the colorant in the color filter coloring composition (100% by weight), and 10 from the viewpoint of photocurability and developability. More preferably, it is -150 weight%.

<Sensitizer>
Furthermore, the coloring composition for a color filter of the present invention can contain a sensitizer.

Sensitizers include chalcone derivatives, unsaturated ketones such as dibenzalacetone, 1,2-diketone derivatives such as benzyl and camphorquinone, benzoin derivatives, fluorene derivatives, naphthoquinone derivatives, anthraquinone derivatives , Xanthene derivatives, thioxanthene derivatives, xanthone derivatives, thioxanthone derivatives, coumarin derivatives, ketocoumarin derivatives, cyanine derivatives, merocyanine derivatives, oxonol derivatives, and other polymethine dyes, acridine derivatives, azine derivatives, thiazine derivatives, oxazine derivatives, indoline derivatives, Azulene derivatives, azurenium derivatives, squarylium derivatives, porphyrin derivatives, tetraphenylporphyrin derivatives, triarylmethane derivatives, tetrabenzoporphyrin derivatives, Trapirazinoporphyrazine derivatives, phthalocyanine derivatives, tetraazaporphyrazine derivatives, tetraquinoxalyloporphyrazine derivatives, naphthalocyanine derivatives, subphthalocyanine derivatives, pyrylium derivatives, thiopyrylium derivatives, tetraphylline derivatives, annulene derivatives, spiropyran derivatives, spirooxazine Derivatives, thiospiropyran derivatives, metal arene complexes, organoruthenium complexes, or Michler's ketone derivatives, α-acyloxy esters, acylphosphine oxides, methylphenylglyoxylate, benzyl, 9,10-phenanthrenequinone, camphorquinone, ethyl Anthraquinone, 4,4'-diethylisophthalophenone, 3,3 'or 4,4'-tetra (t-butylperoxycarbonyl) benzophen Non, 4,4′-diethylaminobenzophenone and the like.

More specifically, edited by Shin Okawara et al., “Dye Handbook” (1986, Kodansha), edited by Shin Okawara et al., “Chemistry of Functional Dye” (1981, CMC), edited by Tadasaburo Ikemori et al. Examples include, but are not limited to, sensitizers described in "Special Functional Materials" (1986, CMC). In addition, a sensitizer that absorbs light from the ultraviolet region to the near infrared region can also be contained.

Two or more kinds of sensitizers may be used in any ratio as required. The blending amount when using the sensitizer is preferably 3 to 60% by weight based on the total weight of the photopolymerization initiator contained in the colored composition (100% by weight). From the viewpoint of developability, it is more preferably 5 to 50% by weight.

<Amine compound>
Moreover, the coloring composition of this invention can be made to contain the amine compound which has a function which reduces the dissolved oxygen.

Such amine compounds include triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, isoamyl 4-dimethylaminobenzoate, 2-dimethylaminobenzoate. Examples include ethyl, 2-ethylhexyl 4-dimethylaminobenzoate, and N, N-dimethylparatoluidine.

<Leveling agent>
In order to improve the leveling property of the composition on the transparent substrate, it is preferable to add a leveling agent to the colored composition of the present invention. As the leveling agent, dimethylsiloxane having a polyether structure or a polyester structure in the main chain is preferable. Specific examples of dimethylsiloxane having a polyether structure in the main chain include FZ-2122 manufactured by Toray Dow Corning, BYK-333 manufactured by Big Chemie. Specific examples of dimethylsiloxane having a polyester structure in the main chain include BYK-310 and BYK-370 manufactured by BYK Chemie. Dimethylsiloxane having a polyether structure in the main chain and dimethylsiloxane having a polyester structure in the main chain can be used in combination. In general, the leveling agent content is preferably 0.003 to 0.5% by weight based on the total weight of the coloring composition (100% by weight).

Particularly preferred as a leveling agent is a kind of so-called surfactant having a hydrophobic group and a hydrophilic group in the molecule, having a hydrophilic group but low solubility in water, and when added to a coloring composition, It has the characteristics of low surface tension reduction ability, and it is useful to have good wettability to the glass plate despite its low surface tension reduction ability. Those that can sufficiently suppress the chargeability can be preferably used. As a leveling agent having such preferable characteristics, dimethylpolysiloxane having a polyalkylene oxide unit can be preferably used. Examples of the polyalkylene oxide unit include a polyethylene oxide unit and a polypropylene oxide unit, and dimethylpolysiloxane may have both a polyethylene oxide unit and a polypropylene oxide unit.

In addition, the bonding form of the polyalkylene oxide unit with dimethylpolysiloxane includes a pendant type in which the polyalkylene oxide unit is bonded in the repeating unit of dimethylpolysiloxane, a terminal-modified type in which the end of dimethylpolysiloxane is bonded, and dimethylpolysiloxane. Any of linear block copolymer types in which they are alternately and repeatedly bonded may be used. Dimethylpolysiloxane having a polyalkylene oxide unit is commercially available from Toray Dow Corning Co., Ltd., for example, FZ-2110, FZ-2122, FZ-2130, FZ-2166, FZ-2191, FZ-2203, FZ. -2207, but is not limited thereto.

An anionic, cationic, nonionic or amphoteric surfactant can be supplementarily added to the leveling agent. Two or more kinds of surfactants may be mixed and used.

Anionic surfactants added to the leveling agent as auxiliary agents include polyoxyethylene alkyl ether sulfate, sodium dodecylbenzene sulfonate, alkali salt of styrene-acrylic acid copolymer, sodium alkyl naphthalene sulfonate, alkyl diphenyl ether disulfonic acid Sodium, lauryl sulfate monoethanolamine, lauryl sulfate triethanolamine, ammonium lauryl sulfate, monoethanolamine stearate, sodium stearate, sodium lauryl sulfate, monoethanolamine of styrene-acrylic acid copolymer, polyoxyethylene alkyl ether phosphate Examples include esters.

Examples of the chaotic surfactant that is supplementarily added to the leveling agent include alkyl quaternary ammonium salts and their ethylene oxide adducts. Nonionic surfactants added to the leveling agent as auxiliary agents include polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene alkyl ether phosphate ester, polyoxyethylene sorbitan monostearate And amphoteric surfactants such as alkyl dimethylamino acetic acid betaine and alkylimidazolines, and fluorine-based and silicone-based surfactants.

<Curing agent, curing accelerator>
Moreover, in order to assist hardening of a thermosetting resin, the coloring composition of this invention may contain the hardening | curing agent, the hardening accelerator, etc. as needed. As the curing agent, phenolic resins, amine compounds, acid anhydrides, active esters, carboxylic acid compounds, sulfonic acid compounds and the like are effective, but are not particularly limited to these, and thermosetting resins. Any curing agent may be used as long as it can react with the. Among these, a compound having two or more phenolic hydroxyl groups in one molecule and an amine curing agent are preferable. Examples of the curing accelerator include amine compounds (for example, dicyandiamide, benzyldimethylamine, 4- (dimethylamino) -N, N-dimethylbenzylamine, 4-methoxy-N, N-dimethylbenzylamine, 4-methyl). -N, N-dimethylbenzylamine etc.), quaternary ammonium salt compounds (eg triethylbenzylammonium chloride etc.), blocked isocyanate compounds (eg dimethylamine etc.), imidazole derivative bicyclic amidine compounds and salts thereof (eg Imidazole, 2-methylimidazole, 2-ethylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, 4-phenylimidazole, 1-cyanoethyl-2-phenylimidazole, 1- (2-cyanoethyl) -2- D Ru-4-methylimidazole, etc.), phosphorus compounds (eg, triphenylphosphine, etc.), guanamine compounds (eg, melamine, guanamine, acetoguanamine, benzoguanamine, etc.), S-triazine derivatives (eg, 2,4-diamino-6) -Methacryloyloxyethyl-S-triazine, 2-vinyl-2,4-diamino-S-triazine, 2-vinyl-4,6-diamino-S-triazine isocyanuric acid adduct, 2,4-diamino-6 Methacryloyloxyethyl-S-triazine / isocyanuric acid adduct, etc.) can be used. These may be used alone or in combination of two or more. As content of the said hardening accelerator, 0.01 to 15 weight% is preferable with respect to the thermosetting resin whole quantity.

<Other additive components>
The colored composition of the present invention can contain a storage stabilizer in order to stabilize the viscosity of the composition over time. Moreover, in order to improve adhesiveness with a transparent substrate, adhesion improving agents, such as a silane coupling agent, can also be contained.

Examples of storage stabilizers include quaternary ammonium chlorides such as benzyltrimethyl chloride and diethylhydroxyamine, organic acids such as lactic acid and oxalic acid, and methyl ethers thereof, t-butylpyrocatechol, tetraethylphosphine, and tetraphenylphosphine. Organic phosphines, phosphites and the like can be mentioned. The storage stabilizer can be used in an amount of 0.1 to 10% by weight based on the total amount of the colorant (100% by weight).

Examples of the adhesion improver include vinyl silanes such as vinyltris (β-methoxyethoxy) silane, vinylethoxysilane and vinyltrimethoxysilane, (meth) acrylsilanes such as γ-methacryloxypropyltrimethoxysilane, β- (3, 4-epoxycyclohexyl) ethyltrimethoxysilane, β- (3,4-epoxycyclohexyl) methyltrimethoxysilane, β- (3,4-epoxycyclohexyl) ethyltriethoxysilane, β- (3,4-epoxycyclohexyl) Epoxysilanes such as methyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropyltriethoxysilane, N-β (aminoethyl) γ-aminopropyltrimethoxysilane, N-β (amino Ethyl) γ-aminopropyltrie Xisilane, N-β (aminoethyl) γ-aminopropylmethyldiethoxysilane, γ-aminopropyltriethoxysilane, γ-aminopropyltrimethoxysilane, N-phenyl-γ-aminopropyltrimethoxysilane, N-phenyl Examples include silane coupling agents such as aminosilanes such as -γ-aminopropyltriethoxysilane, and thiosilanes such as γ-mercaptopropyltrimethoxysilane and γ-mercaptopropyltriethoxysilane. The adhesion improver can be used in an amount of 0.01 to 10% by weight, preferably 0.05 to 5% by weight, based on the total amount of the colorant in the coloring composition (100% by weight).

<Removal of coarse particles>
The coloring composition of the present invention is mixed with coarse particles of 5 μm or more, preferably coarse particles of 1 μm or more, more preferably 0.5 μm or more and coarse particles by means of centrifugation, sintered filter, membrane filter or the like. It is preferable to remove dust. Thus, it is preferable that a coloring composition does not contain a particle | grain of 0.5 micrometer or more substantially. More preferably, it is 0.3 μm or less.

<Color filter>
Next, the color filter of the present invention will be described. The color filter of this invention comprises the filter segment formed using the coloring composition for color filters of this invention. Examples of the color filter include those having a red filter segment, a green filter segment, and a blue filter segment, or those having a magenta filter segment, a cyan filter segment, and a yellow filter segment.

As the transparent substrate, glass plates such as soda lime glass, low alkali borosilicate glass and non-alkali alumino borosilicate glass, and resin plates such as polycarbonate, polymethyl methacrylate, and polyethylene terephthalate are used. In addition, a transparent electrode made of indium oxide, tin oxide, or the like may be formed on the surface of the glass plate or the resin plate in order to drive the liquid crystal after forming the panel.

<Color filter manufacturing method>
The color filter of the present invention can be produced by a printing method or a photolithography method.

The formation of filter segments by printing methods allows patterning by simply printing and drying the colored composition prepared as a printing ink, making it a low cost and excellent mass productivity as a color filter manufacturing method. Yes. Furthermore, it is possible to print a fine pattern having high dimensional accuracy and smoothness by the development of printing technology. In order to perform printing, it is preferable that the ink does not dry and solidify on the printing plate or on the blanket. Further, it is important to control the fluidity of the ink on the printing press, and the viscosity of the ink can be adjusted with a dispersant or extender pigment.

When the filter segment is formed by photolithography, the colored composition prepared as a solvent developing type or alkali developing type colored resist material is applied on a transparent substrate by spray coating, spin coating, slit coating, roll coating or the like. By a method, it applies so that a dry film thickness may be set to 0.2-5 micrometers. If necessary, the dried film is exposed to ultraviolet light through a mask having a predetermined pattern provided in contact with or non-contact with the film. Then, after immersing in a solvent or alkali developer or spraying the developer by spraying or the like to remove the uncured portion to form a desired pattern, the same operation is repeated for other colors to produce a color filter. be able to. Furthermore, in order to accelerate the polymerization of the colored resist material, heating can be performed as necessary. According to the photolithography method, a color filter with higher accuracy than the above printing method can be manufactured.

In development, an aqueous solution such as sodium carbonate or sodium hydroxide is used as an alkali developer, and an organic alkali such as dimethylbenzylamine or triethanolamine can also be used. Moreover, an antifoamer and surfactant can also be added to a developing solution. In order to increase the UV exposure sensitivity, after coating and drying the colored resist material, a water-soluble or alkaline water-soluble resin such as polyvinyl alcohol or water-soluble acrylic resin is applied and dried to form a film that prevents polymerization inhibition by oxygen. Then, ultraviolet exposure can be performed.

The color filter of the present invention can be produced by an electrodeposition method, a transfer method, etc. in addition to the above method, but the colored composition of the present invention can be used in any method. The electrodeposition method is a method for producing a color filter by using a transparent conductive film formed on a substrate and forming each color filter segment on the transparent conductive film by electrophoresis of colloidal particles. . The transfer method is a method in which a filter segment is formed in advance on the surface of a peelable transfer base sheet, and this filter segment is transferred to a desired substrate.

A black matrix can be formed in advance before forming each color filter segment on a transparent substrate or a reflective substrate. As the black matrix, a chromium, chromium / chromium oxide multilayer film, an inorganic film such as titanium nitride, or a resin film in which a light-shielding agent is dispersed is used, but is not limited thereto. In addition, a thin film transistor (TFT) may be formed in advance on the transparent substrate or the reflective substrate, and then each color filter segment may be formed. In addition, an overcoat film, a transparent conductive film, or the like is formed on the color filter of the present invention as necessary.

Hereinafter, the present invention will be described based on examples, but the present invention is not limited thereto. Unless otherwise specified, “parts” means “parts by weight”.

First, it demonstrates from the manufacturing method of the binder resin used for the Example and the comparative example, the refinement | purification pigment, resin (B) which has a cationic group in a side chain, and a salt-forming compound (D).

<Method for preparing binder resin solution>
(Preparation of binder resin solution 1)
A reaction vessel equipped with a separable four-necked flask equipped with a thermometer, a cooling tube, a nitrogen gas introduction tube, and a stirrer was charged with 70.0 parts of cyclohexanone, heated to 80 ° C., and the inside of the reaction vessel was purged with nitrogen. 13.3 parts of n-butyl methacrylate, 4.6 parts of 2-hydroxyethyl methacrylate, 4.3 parts of methacrylic acid, 7.4 parts of paracumylphenol ethylene oxide modified acrylate (“Aronix M110” manufactured by Toagosei Co., Ltd.), A mixture of 0.4 part of 2,2′-azobisisobutyronitrile was added dropwise over 2 hours. After completion of the dropwise addition, the reaction was further continued for 3 hours to obtain an acrylic resin solution having a weight average molecular weight of 26000. After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the nonvolatile content. The methoxypropyl acetate was added to the previously synthesized resin solution so that the nonvolatile content was 20% by weight. The binder resin solution 1 was prepared by adding.
Here, the weight average molecular weight (Mw) of the binder resin was measured by gel permeation chromatography (GPC) using polystyrene as a standard substance.

(Preparation of binder resin solution 2)
207 parts of cyclohexanone was charged into a separable four-necked flask equipped with a thermometer, a cooling pipe, a nitrogen gas introduction pipe, a dropping pipe, and a stirring device, heated to 80 ° C., and the flask was purged with nitrogen. 20 parts of acid, 20 parts of paracumylphenol ethylene oxide modified acrylate (Aronix M110 manufactured by Toa Gosei Co., Ltd.), 45 parts of methyl methacrylate, 8.5 parts of 2-hydroxyethyl methacrylate, and 2,2′-azobisisobutyronitrile 1.33 parts of the mixture was added dropwise over 2 hours. After completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a copolymer solution.
Next, after the nitrogen gas was stopped and stirred while injecting dry air for 1 hour with respect to the total amount of the copolymer solution obtained, the mixture was cooled to room temperature, and then 2-methacryloyloxyethyl isocyanate (Karenz manufactured by Showa Denko KK). MOI) A mixture of 6.5 parts, 0.08 part dibutyltin laurate and 26 parts cyclohexanone was added dropwise at 70 ° C. over 3 hours.
About 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. Then, cyclohexanone was added to the previously synthesized resin solution so that the non-volatile content was 20% by weight. Prepared. The weight average molecular weight (Mw) was 18000.

(Preparation of binder resin solution 3)
207 parts of cyclohexanone was charged into a separable four-necked flask equipped with a thermometer, a cooling pipe, a nitrogen gas introduction pipe, a dropping pipe, and a stirring device, heated to 80 ° C., and the flask was purged with nitrogen. 20 parts of acid, 20 parts of paracumylphenol ethylene oxide modified acrylate (Aronix M110 manufactured by Toagosei Co., Ltd.), 45 parts of methyl methacrylate, 8.5 parts of glycerol monomethacrylate, and 2,2′-azobisisobutyronitrile 1.3
3 parts of the mixture was added dropwise over 2 hours. After completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a copolymer solution.
Next, after the nitrogen gas was stopped and stirred while injecting dry air for 1 hour with respect to the total amount of the copolymer solution obtained, after cooling to room temperature, 6.5 parts of 2-methacryloyloxyl ethyl isocyanate, A mixture of 0.08 part dibutyltin laurate and 26 parts cyclohexanone was added dropwise at 70 ° C. over 3 hours.
About 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. Then, cyclohexanone was added to the previously synthesized resin solution so that the non-volatile content was 20% by weight. Prepared. The weight average molecular weight (Mw) was 19000.

(Preparation of binder resin solution 4)
A separable four-necked flask equipped with a thermometer, a cooling pipe, a nitrogen gas introduction pipe, a dropping pipe and a stirring device was charged with 370 parts of cyclohexanone, heated to 80 ° C., and the atmosphere in the flask was replaced with nitrogen. 18 parts of milphenol ethylene oxide modified acrylate (Aronix M110 manufactured by Toagosei Co., Ltd.), 10 parts of benzyl methacrylate, 18.2 parts of glycidyl methacrylate, 25 parts of methyl methacrylate, and 2,2′-azobisisobutyronitrile 2.0 Part of the mixture was added dropwise over 2 hours. After dropping, the reaction was further carried out at 100 ° C. for 3 hours, and then 1.0 part of azobisisobutyronitrile dissolved in 50 parts of cyclohexanone was added, and the reaction was further continued at 100 ° C. for 1 hour. Next, the inside of the container is replaced with air, and 0.5 part of trisdimethylaminophenol and 0.1 part of hydroquinone are put into 9.3 parts of acrylic acid (100% of glycidyl group) and the container is placed at 120 ° C. The reaction was continued for 6 hours, and the reaction was terminated when the solid content acid value reached 0.5 to obtain a copolymer solution. Further, 19.5 parts of tetrahydrophthalic anhydride (100% of the generated hydroxyl group) and 0.5 parts of triethylamine were added and reacted at 120 ° C. for 3.5 hours to obtain a carboxyl group and a copolymer solution.
After cooling to room temperature, about 2 g of the resin solution was sampled, heated and dried at 180 ° C. for 20 minutes to measure the nonvolatile content, and cyclohexanone was added to the previously synthesized resin solution so that the nonvolatile content was 20% by weight. Thus, a binder resin solution 4 was prepared. The weight average molecular weight (Mw) was 19000.

<Production method of fine pigment>
(Blue refined pigment (P-1))
Phthalocyanine blue pigment C.I. I. Pigment Blue 15: 6 (Toyocolor “Lionol Blue ES”) 100 parts, ground salt 800 parts, and diethylene glycol 100 parts were charged in a stainless steel 1 gallon kneader (Inoue Seisakusho) and kneaded at 70 ° C. for 12 hours. did. The mixture was added to 3000 parts of warm water, stirred at a high speed mixer for about 1 hour while being heated to about 70 ° C. to form a slurry, filtered and washed repeatedly to remove salt and solvent, and then at 80 ° C. for 24 hours. It dried and obtained 98 parts of blue refinement | purification pigments (P-1). The average primary particle diameter of the obtained pigment was 28.3 nm.

Here, the average primary particle diameter of the pigment was determined by a transmission electron microscope (“JEM-1200 manufactured by JEOL Ltd.).
EX ”) was used to measure the primary particle diameter of all pigment particles in the observation sample at 50,000 times, and the average value was used. In addition, when the particle shape was not spherical, the major axis and the minor axis were measured, and the value obtained by (major axis + minor axis) / 2 was defined as the particle diameter.

(Purple refined pigment (P-2))
Dioxazine-based purple pigment C.I. I. 120 parts of Pigment Violet 23 (“FastViolet RL” manufactured by Clariant), 1600 parts of ground sodium chloride, and 100 parts of diethylene glycol were charged into a 1 gallon kneader (manufactured by Inoue Seisakusho) and kneaded at 90 ° C. for 18 hours. The mixture was poured into 5000 parts of warm water, stirred at a high speed mixer for about 1 hour while being heated to about 70 ° C. to form a slurry, filtered and washed repeatedly to remove salt and solvent, and then at 80 ° C. for 24 hours. It dried and obtained 118 parts purple refinement | purification pigment (P-2). The average primary particle diameter of the obtained pigment was 26.4 nm.

(Red fine pigment (P-3))
Diketopyrrolopyrrole red pigment C.I. I. 200 parts of Pigment Red 254 ("IRGAZINRED2030" manufactured by BASF Japan), 1400 parts of ground sodium chloride, and 360 parts of diethylene glycol were charged into a stainless 1 gallon kneader (manufactured by Inoue Seisakusho) and kneaded at 80 ° C for 6 hours. The mixture was poured into 8000 parts of warm water, heated to about 80 ° C., stirred with a high speed mixer for about 2 hours to form a slurry, filtered and washed repeatedly to remove salt and solvent, then at 85 ° C. for 24 hours. It dried and obtained 190 parts of red fine pigments (P-3). The average primary particle diameter of the obtained pigment was 24.8 nm.

(Red fine pigment (P-4))
Red pigment C.I. I. Pigment Red 242 ("NOVOPERMS" manufactured by Clariant)
200 parts of CARLET4RF ”, 1400 parts of crushed salt, and 360 parts of diethylene glycol were charged into a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho) and kneaded at 80 ° C. for 6 hours. The mixture is poured into 8000 parts of warm water, stirred for 2 hours with a high speed mixer while being heated to about 80 ° C. to form a slurry, filtered and washed repeatedly to remove salt and solvent, and then dried at 85 ° C. for 24 hours. 190 parts of red fine pigment (P-4) were obtained. The average primary particle diameter of the obtained pigment was 28.5 nm.

<Preparation method of resin (B) having cationic group in side chain>
(Production Example 1; Preparation of resin B-1 having a cationic group in the side chain)

In a reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 18.2 parts of methyl methacrylate, 27.3 parts of n-butyl methacrylate, 27.3 parts of 2-ethylhexyl methacrylate, and 15-hydroxyethyl methacrylate 15 And 1.6 parts of tetramethylethylenediamine were charged, and the mixture was stirred at 50 ° C. for 1 hour while flowing nitrogen, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9200 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. In this way, a block resin (B-1) having a quaternary ammonium salt value of 33 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

Here, the weight average molecular weight (Mw) of the resin having a cationic group in the side chain was measured by gel permeation chromatography (GPC) using polystyrene as a standard substance. The ammonium salt value of the resin (B) having a cationic group in the side chain was determined by titrating with a 0.1N silver nitrate aqueous solution using 5% potassium chromate aqueous solution as an indicator, and then the equivalent of potassium hydroxide. It is the converted value and indicates the ammonium salt value of the solid content.

(Production Example 2; Preparation of resin B-2 having a cationic group in the side chain)

In a reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 8.2 parts of methyl methacrylate, 25.3 parts of n-butyl methacrylate, 25.3 parts of 2-ethylhexyl methacrylate, and 15-hydroxyethyl methacrylate 15 And 1.6 parts of tetramethylethylenediamine were charged, and the mixture was stirred at 50 ° C. for 1 hour while flowing nitrogen, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 26.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to this reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9000 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. In this way, a block resin (B-2) having a quaternary ammonium salt value of 71 mg KOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 3; Preparation of resin B-3 having a cationic group in the side chain)

In a reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 35.5 parts of methyl methacrylate, 30 parts of n-butyl methacrylate, 12.3 parts of 2-ethylhexyl methacrylate, 10 parts of 2-hydroxyethyl methacrylate, 1.6 parts of tetramethylethylenediamine was charged and stirred at 50 ° C. for 1 hour while flowing nitrogen, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content. Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9500 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. Thus, a block resin (B-3) having a quaternary ammonium salt value of 33 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 4; Preparation of resin B-4 having a cationic group in the side chain)

A reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer was charged with 22.4 parts of methyl methacrylate, 16.7 parts of n-butyl methacrylate, 27.3 parts of 2-ethylhexyl methacrylate, 15.0 parts of hydroxyethyl methacrylate. Parts, 2.5 parts of methacrylic acid, 1.3 parts of t-butyl methacrylate, 1.3 parts of isobutyl methacrylate, 1.3 parts of cyclohexyl methacrylate, 1.6 parts of tetramethylethylenediamine, and 1 at 50 ° C. while flowing nitrogen. The system was stirred for a period of time, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9000 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. In this way, a block resin (B-4) having a quaternary ammonium salt value of 33 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 5; Preparation of resin B-5 having a cationic group in the side chain)

A reactor equipped with a gas inlet tube, a condenser, a stirring blade, and a thermometer was charged with 34.7 parts of isobornyl methacrylate, 1.7 parts of n-butyl methacrylate, 30.0 parts of hydroxyethyl methacrylate, 2.5 parts of methacrylic acid. Parts, 16.3 parts of t-butyl methacrylate, 1.3 parts of isobutyl methacrylate, 1.3 parts of cyclohexyl methacrylate, and 1.6 parts of tetramethylethylenediamine are stirred at 50 ° C. for 1 hour while flowing nitrogen. Replaced with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9200 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. Thus, a block resin (B-5) having a quaternary ammonium salt value of 33 mg KOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 6; Preparation of resin B-6 having a cationic group in the side chain)

In a reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 22.5 parts of isobornyl methacrylate, 1.7 parts of n-butyl methacrylate, 30.0 parts of hydroxyethyl methacrylate, 2.5 of methacrylic acid were added. Parts, 16.3 parts of t-butyl methacrylate, 1.3 parts of isobutyl methacrylate, 1.3 parts of cyclohexyl methacrylate, and 1.6 parts of tetramethylethylenediamine are stirred at 50 ° C. for 1 hour while flowing nitrogen. Replaced with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 24.4 parts of dimethylaminoethylmethyl methacrylate methacrylate as the second block monomer were added to this reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9200 and Mw / Mn = 1.5, and the reaction conversion rate was 98.5%. Thus, a block resin (B-6) having a quaternary ammonium salt value of 66 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 7; Preparation of resin B-7 having a cationic group in the side chain)

In a reaction apparatus equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 50.0 parts of methyl methacrylate, 30.0 parts of n-butyl methacrylate, 15 parts of 2-hydroxyethyl methacrylate, 2.5 parts of methacrylic acid, 1.6 parts of tetramethylethylenediamine was charged and stirred at 50 ° C. for 1 hour while flowing nitrogen, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 2.5 parts of dimethylaminoethyl methyl methacrylate methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9100 and Mw / Mn = 1.5, and the reaction conversion rate was 98.8%. Thus, a block resin (B-7) having a quaternary ammonium salt value of 7 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 8; Preparation of resin B-8 having a cationic group in the side chain)

In a reactor equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer, 60.0 parts of methyl methacrylate, 17.8 parts of n-butyl methacrylate, 10.0 parts of 2-isocyanatoethyl methacrylate, tetramethylethylenediamine 1 .6 parts were charged, and the mixture was stirred at 50 ° C. for 1 hour while flowing nitrogen, and the system was purged with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9800 and Mw / Mn = 1.6, and the reaction conversion rate was 98.3%. Thus, a block resin (B-8) having a quaternary ammonium salt value of 33 mgKOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

(Production Example 9; Preparation of resin BC-1 having a cationic group in the side chain)
74.1 parts of isopropyl alcohol was charged into a four-necked separable flask equipped with a thermometer, a stirrer, a distillation tube and a condenser, and the temperature was raised to 75 ° C. under a nitrogen stream. Separately dissolved in 17.8 parts of methyl methacrylate, 60.0 parts of n-butyl methacrylate, 10.0 parts of 2-hydroxyethyl methacrylate, 12.2 parts of dimethylaminoethyl methyl chloride salt, and 23.4 parts of methyl ethyl ketone. 2,2′-azobis (2,4-
7.0 parts of (dimethylvaleronitrile) were made uniform, charged into a dropping funnel, attached to a four-necked separable flask, and dropped over 2 hours. Two hours after the completion of the dropwise addition, it was confirmed that the polymerization yield was 98% or more from the solid content and the weight average molecular weight (Mw) was 8330, and the mixture was cooled to 50 ° C. Thereafter, 14.3 parts of methanol was added to obtain Resin BC-1 having a Tg of 40 ° C. having a cationic group in the side chain of 40% by weight of the resin component. The ammonium salt value of the obtained resin was 33 mgKOH / g.

(Production Example 10; Preparation of resin BC-2 having a cationic group in the side chain)
A reactor equipped with a gas introduction tube, a condenser, a stirring blade, and a thermometer was charged with 17.8 parts of methyl methacrylate, 70.0 parts of n-butyl methacrylate, and 1.6 parts of tetramethylethylenediamine, and 50 was added while flowing nitrogen. The mixture was stirred at 0 ° C. for 1 hour, and the atmosphere in the system was replaced with nitrogen. Next, 2.1 parts of ethyl bromoisobutyrate, 1.9 parts of cuprous chloride and 62.3 parts of propylene glycol monomethyl ether were charged, and the temperature was raised to 100 ° C. under a nitrogen stream to start polymerization of the first block. did. After polymerization for 4 hours, the polymerization solution was sampled and the solid content was measured, and it was confirmed that the polymerization conversion was 98% or more in terms of non-volatile content.
Next, 8.1 parts of propylene glycol monomethyl ether and 12.2 parts of dimethylaminoethyl methyl chloride methacrylate as the second block monomer were added to the reactor, and the mixture was stirred while maintaining a nitrogen atmosphere at 100 ° C. The reaction continued. After 2 hours from the introduction of dimethylaminoethyl methyl chloride salt, the polymerization solution is sampled to measure the solid content, and converted from the nonvolatile content to confirm that the polymerization conversion rate of the second block is 98% or more. The solution was cooled to room temperature to stop the polymerization.
As a result of GPC measurement, the polymer had Mw 9100 and Mw / Mn = 1.5, and the reaction conversion rate was 98.4%. Thus, a block resin (BC-2) having a quaternary ammonium salt value of 33 mg KOH / g per solid content was obtained.
After cooling to room temperature, about 2 g of the resin solution was sampled and heated and dried at 180 ° C. for 20 minutes to measure the non-volatile content. A block resin solution having a salt was obtained.

The following monomers were used in Table 1. Shown with glass transition temperature.
Dimethylaminoethyl methyl chloride salt:
Light ester DQ-100 (manufactured by Kyoeisha Chemical Co., Ltd.) (58 ° C)
MMA: Methyl methacrylate (105 ° C)
n-BMA: n-butyl methacrylate (20 ° C.)
2-EHMA: 2-ethylhexyl methacrylate (−10 ° C.)
2-EHA: 2-ethylhexyl acrylate (-85 ° C)
HEMA: hydroxyethyl methacrylate (55 ° C)
MAA: Methacrylic acid (130 ° C)
t-BMA: t-butyl methacrylate (107 ° C.)
IBMA: Isobutyl methacrylate (67 ° C)
CHMA: cyclohexyl methacrylate (66 ° C)
IBX: Isobornyl methacrylate (180 ° C.)
MOI: 2-isocyanatoethyl methacrylate (60 ° C)

The value of Tg in Table 1 is a value calculated using the above formula.

<Production of anionic dye (C)>
(Anionic dye 1)
Anionic dyes 1 to 4 are compounds represented by the following general formula (2).

General formula (2)
Table 2 shows X _{1 to} X ₄ in the general formula (2).

Here, * indicates a bond with N.

Anionic dyes 1-4 were synthesized by the following method.
(Synthesis of anionic dye 1)
C. I. 45.0 parts of Acid Red 289, 45.3 parts of 1-iodopropane and 36.8 parts of potassium carbonate were added to 280 parts of N-methylpyrrolidone and stirred at 90 ° C. for 6 hours. The resulting reaction solution was cooled to room temperature, then added to 3000 parts of ethyl acetate and stirred at room temperature for 1 hour, whereupon crystals precipitated. The precipitated crystals were collected by filtration, washed with 2500 parts of ethyl acetate, and then dried under reduced pressure at 60 ° C. overnight to obtain 47.6 parts of anionic dye 1.

(Synthesis of anionic dye 2)
C. I. 45.0 parts of Acid Red 289, 56.6 parts of 2-iodopropane, and 46.0 parts of potassium carbonate were added to 360 parts of N-methylpyrrolidone and stirred at 85 ° C. for 12 hours. The obtained reaction solution was cooled to room temperature, added to 3600 parts of ethyl acetate, and stirred at room temperature for 1 hour, whereby crystals were deposited. The precipitated crystals were collected by filtration, washed with 3000 parts of ethyl acetate, and dried overnight at 60 ° C. under reduced pressure to obtain 43.0 parts of anionic dye 2.

(Synthesis of anionic dye 3)
The same operation as the synthesis method of anionic dye 1 was performed except that 45.3 parts of 1-iodopropane was changed to 71.4 parts of 1-iododecane, to obtain 53.2 parts of anionic dye 3.

(Synthesis of anionic dye 4)
20.0 parts of the compound represented by the formula (20) and 8.5 parts of sulfanilic acid were added to 180 parts of N-methylpyrrolidone and stirred at 100 ° C. for 2 hours. Next, 10.0 parts of aniline was added and stirred at 120 degrees for 4 hours. After cooling the obtained reaction liquid to room temperature, 2000 parts of ethyl acetate was added and stirred at room temperature for 1 hour, whereby crystals were deposited. The precipitated crystals were separated by filtration and dried overnight under reduced pressure to obtain 25.7 parts of Intermediate 1.
25.0 parts of Intermediate 1, 28.2 parts of 1-iodopropane and 23.0 parts of potassium carbonate were added to 200 parts of N-methylpyrrolidone and stirred at 90 ° C. for 4 hours. The obtained reaction solution was cooled to room temperature, then added to 2000 parts of ethyl acetate and stirred at room temperature for 1 hour, whereby crystals were deposited. The precipitated crystals were collected by filtration, washed with 1500 parts of ethyl acetate, and then dried under reduced pressure at 60 ° C. overnight to obtain 26.7 parts of anionic dye 4.

Formula (20)

<Method for Producing Salt-Forming Compound (D)>
(Production Example 11; Preparation of Salt-Forming Compound D-1) C.I. I. Acid Red 289 and resin B-1 having a cationic group in the side chain
A salt-forming compound (D-1) consisting of

The resin B-1 having a cationic group in the side chain of 51 parts is added to 2000 parts of water, and after sufficiently stirring and mixing, the mixture is heated to 60 ° C. On the other hand, 10 parts of C.I. in 90 parts of water. I. An aqueous solution in which Acid Red 289 is dissolved is prepared and added dropwise little by little to the previous resin solution. After dropping, the mixture is stirred at 60 ° C. for 120 minutes to sufficiently react. In order to confirm the end point of the reaction, the reaction solution was dropped onto the filter paper, and it was judged that the salt-forming compound was obtained with the point where the bleeding disappeared as the end point. After cooling to room temperature with stirring, a counter anion of the resin having a cationic group in the side chain and C.I. I. After removing the salt composed of acid red 289 counter cation, the salt-forming compound remaining on the filter paper was dried by removing moisture with a dryer, and 32 parts of C.I. I. A salt-forming compound D-1 between Acid Red 289 and resin B-1 having a cationic group in the side chain was obtained.

(Production Examples 13-15, 18-19, 21-23, 26-27, 29-31, 34-43; salt-forming compounds D-3-5, 8-9, 11-13, 16-17, 19- 21, Preparation of 24-33)
Hereinafter, salt-forming compounds D-3 to 5, 8 to 9, 11 to 13, and 16 were prepared in the same manner as in Production Example 11 except that the resins and dyes having a cationic group in the side chain were changed to those shown in Table 3. -17, 19-21, 24-30 were produced.
(Production Examples 12, 20, 28; Preparation of salt-forming compounds D-2, 10, 18)
Hereinafter, salt-forming compounds D-2, 10, and 18 were produced in the same manner as in Production Example 11 except that 24 parts of resin B-2 having a cationic group in the side chain was used.
(Production Examples 16, 24, 32; Preparation of salt-forming compounds D-6, 14, 22)
Hereinafter, salt-forming compounds D-6, 14, and 32 were produced in the same manner as in Production Example 11 except that 25.5 parts of resin B-6 having a cationic group in the side chain was used.
(Production Examples 17, 25, 33; Preparation of salt-forming compounds D-7, 15, 23)
Hereinafter, salt-forming compounds D-7, 15, and 23 were produced in the same manner as in Production Example 11 except that 249.4 parts of Resin B-7 having a cationic group in the side chain was used.

[Examples 1 to 34, Comparative Examples 1 to 16]
[Example 1]
(Preparation of blue coloring composition (DB-1))
After the following mixture was stirred and mixed to be uniform, it was dispersed for 5 hours with an Eiger mill (“Mini Model M-250MKII” manufactured by Eiger Japan) using zirconia beads having a diameter of 0.5 mm, and then 5.0 μm Filtration through a filter produced a pigment dispersion (DB-1). Salt Formation Compound (D-1) 4.0 parts Refined Pigment (P-1) 7.0 parts Binder Resin Solution 140.0 parts Cyclohexanone 10.0 parts Propylene Glycol Monomethyl Ether Acetate (PGMAC) 38.0 parts Resin Mold 1.0 part of dispersant ("EFKA4300" manufactured by BASF Japan)

[Examples 2-34, Comparative Examples 1-16]
(Blue coloring composition (DB-2-25, DB-35-41), purple coloring composition (DB-26-28, DB-42-44), red coloring composition (DB-29-34, DB-) 45-50))
A colored composition (DB-2 to 50) was produced in the same manner as in Example 1 except that the salt-forming compound and the fine pigment were changed to the compositions shown in Table 4.

About the obtained coloring composition (DB-1-50), the heat resistance evaluation of a coating film, a foreign material test, and the test regarding the temporal storage stability of a coloring composition were done with the following method. Table 4 shows the test results.

(Evaluation of heat resistance of coating film)
The coloring composition (DB-1 to 50) is applied on a glass substrate having a size of 100 mm × 100 mm and a thickness of 1.1 mm using a spin coater, then dried at 70 ° C. for 20 minutes, and then at 220 ° C. for 30 minutes. The coated substrate was prepared by heating and allowing to cool. The coating film substrate thus prepared was subjected to heat treatment at 220 ° C., and the spin coater coating rotation speed was adjusted so that the film thickness was 2.0 μm. The chromaticity ([L * (1), a * (1), b * (1)]) of the obtained coating film with a C light source was measured with a microspectrophotometer ("OSP-SP100" manufactured by Olympus Optical Co., Ltd.) And measured. Further, as a heat resistance test, the sample was heated at 230 ° C. for 1 hour, and the chromaticity ([L * (2), a * (2), b * (2)]) with a C light source was measured. The color difference ΔEab * was determined.
ΔEab * = √ ((L * (2)-L * (1)) ² + (a * (2)-a * (1)) ² + (b * (2)-b * (1)) ² )
If ΔEab * is less than 2.0, there is no practical problem as a color filter, ΔEab is more preferably 1.5 or less, and most preferably 1.0 or less.

(Test on storage stability over time)
The coloring composition (DB-1 to 50) stored for half a year under a cold-reserving condition at 10 ° C. is applied on a glass substrate of 100 mm × 100 mm, 1.1 mm thickness using a spin coater, and then 20 ° C. at 70 ° C. The film was dried for a while, then heated at 220 ° C. for 30 minutes and allowed to cool to produce a coated substrate, and this coated substrate was observed at 500 times using an optical microscope.
<Evaluation criteria>
◎: Generation of foreign matter is not recognized at all ○: Generation of foreign matter is recognized but allowable range ×: Generation of foreign matter is large and out of the allowable range

(Coating foreign material test method)
A test substrate was prepared with the colored composition (DB-1 to 50) immediately after preparation, and the evaluation was performed by counting the number of particles. First, a colored composition is applied on a 100 mm × 100 mm, 1.1 mm thick transparent glass substrate with a spin coater so that the film thickness after drying is about 2.0 μm, and heated in an oven at 230 ° C. for 20 minutes. A test substrate was obtained. Then, surface observation was performed using a metal microscope “BX60” manufactured by Olympus System (magnification is 500 times), and the number of particles that can be observed in any five visual fields by transmission was counted and evaluated according to the following criteria. did. In the evaluation results, ◎ and ○ are good with a small number of foreign matters, △ is a level where there is a large number of foreign matters, but there is no problem in use, and × is a state where it cannot be used because uneven coating due to foreign matters occurs. Equivalent to.
◎: Less than 5 ○: 5 or more, less than 20 Δ: 20 or more, less than 100 ×: 100 or more

AR289: C.I. I. Acid Red 289
AR52: C.I. I. Acid Red 52

Examples 1-34 contain the salt-forming compound (D) of the resin (B) having a cationic group in the side chain and the anionic dye (C), and the resin having the cationic group is a cationic group. Since the block resin is composed of an A block having a cation group and a B block having no heat-crosslinkable functional group, the heat resistance is good, and ΔEab is 1.0 or less. Moreover, it was excellent in storage stability, and the coating film foreign matter was in a range that can be used as a color filter.
On the other hand, in Comparative Example 1, the resin having a cationic group does not have a block structure, and in Comparative Examples 2 to 16, since the resin having a cationic group does not have a thermally crosslinkable functional group, both have heat resistance. Unfortunately, ΔEab exceeded 2.5.

[Example 35]
(Preparation of blue photosensitive coloring composition (R-1))
After stirring and mixing the following mixture uniformly, it is filtered through a 1.0 μm filter,
An alkali developing resist material R-1 was prepared.
Blue colored composition (DB-1) 60.0 parts Binder resin solution 111.0 parts Trimethylolpropane triacrylate 4.2 parts ("NK ester ATMPT" manufactured by Shin-Nakamura Chemical Co., Ltd.)
Photopolymerization initiator (BASF Japan "Irgacure 907") 1.2 parts sensitizer (Hodogaya Chemical "EAB-F") 0.4 parts cyclohexanone 5.2 parts propylene glycol monomethyl ether acetate (PGMAC) 18.0 parts

[Examples 36 to 60, Comparative Examples 17 to 32]
(Blue photosensitive coloring composition (R-2-17, R-27-33), Purple photosensitive coloring composition (R-18-20, R-34-36), Red photosensitive coloring composition (R- 21-26, production of R-37-42))
Alkaline-developable photosensitive coloring compositions (R-2 to 36) were produced in the same manner as in Example 35 except that the coloring composition and the binder resin solution were changed to the coloring compositions shown in Table 5.

(Evaluation of photosensitive coloring composition)
About the obtained photosensitive coloring composition (R-1 to 42), heat resistance evaluation of coating film, foreign matter test, storage stability with time, test on adhesion to a transparent substrate such as glass, solvent resistance test An alkali developability test was conducted. A foreign matter test, an adhesion test with a transparent substrate such as glass, a solvent resistance test, and an alkali developability test method were performed by the following methods. About the method of evaluation / test other than that, it carried out similarly to the content described in Examples 1-34 and Comparative Examples 1-16.

(Coating foreign material test method)
A test substrate was prepared with the photosensitive coloring composition (R-1 to 42) immediately after preparation, and evaluation was performed by counting the number of particles. First, a photosensitive coloring composition was applied on a 100 mm × 100 mm, 1.1 mm thick transparent glass substrate with a spin coater so that the film thickness after drying was about 2.0 μm, dried at 70 ° C. for 20 minutes, UV exposure is performed with an integrated light quantity of 150 mJ / cm ² using an ultrahigh pressure mercury lamp through a photomask having a stripe-shaped opening having a width of 100 μm, and unexposed with a 0.05% potassium hydroxide aqueous solution containing a surfactant. The part was washed off and developed, and placed in a hot air oven at 230 ° C. for 20 minutes to form a stripe pattern having a width of 100 μm on the substrate to obtain a test substrate. Then, surface observation was performed using a metal microscope “BX60” manufactured by Olympus System (magnification is 500 times), and the number of particles that can be observed in any five visual fields by transmission was counted and evaluated according to the following criteria. did. In the evaluation results, ◎ and ○ are good with a small number of foreign matters, △ is a level where there is a large number of foreign matters, but there is no problem in use, and × is a state where it cannot be used because uneven coating due to foreign matters occurs. Equivalent to.
◎: Less than 5 ○: 5 or more, less than 20 Δ: 20 or more, less than 100 ×: 100 or more

(Glass adhesion test method)
Evaluation was performed by forming a test substrate in the same procedure as the coating film foreign matter test and confirming the chemical resistance. The obtained test substrate was immersed in a 5% aqueous sodium hydroxide solution at 25 ° C. for 30 minutes, and the adhesion to the glass before and after immersion was evaluated in three stages by visual observation.
◯: No peeling at all Δ: Slight peeling is observed ×: Peeling is recognized

(Solvent resistance test)
The test substrate obtained by the same procedure as the above-mentioned coating film foreign matter test was immersed in an N-methylpyrrolidone solution for 30 minutes, then washed with ion-exchanged water, air-dried, and the pattern on the 100 μm photomask portion was examined using an optical microscope. Evaluation was made by observation. The rank of evaluation is as follows.
◎: Appearance and color are good without change ○: Some wrinkles are generated, but color is good without change Δ: Slight color loss is generated ×: Peeling or color loss is generated

(Alkali developability test)
The photosensitive coloring composition (R-1 to 27) was applied on a 100 mm × 100 mm, 1.1 mm thick transparent glass substrate with a spin coater so that the film thickness after drying was about 2.0 μm, at 70 ° C. After drying for 20 minutes, UV exposure was performed with an integrated light amount of 150 mJ / cm ² using a super high pressure mercury lamp through a photomask having a stripe-shaped opening having a width of 100 μm. When developing with a 0.05% aqueous potassium hydroxide solution containing a surfactant, the unexposed area is washed away, the development is performed at an appropriate development time of +10 seconds and +20 seconds, and the developed glass surface is subjected to a microspectrophotometer ( Measured using “OSP-SP200” manufactured by Olympus Optical Co., Ltd., and alkali developability was determined by the presence or absence of residue.
◎: No residue at proper development time ○: No residue at proper development time + 10 seconds △: No residue at proper development time + 20 seconds ×: Residue at proper development time + 20 seconds

As in Examples 35 to 60, the resin containing the salt-forming compound (D) of the resin (B) having a cationic group in the side chain and the anionic dye (C), and the resin having the cationic group is a cation Since the block resin is composed of an A block having a functional group and a B block having no thermal group and having a heat-crosslinkable functional group, both have good heat resistance and ΔEab is 1.0 or less. It was. Moreover, it was excellent in storage stability, the coating-film foreign material was in the range which can be used as a color filter, and it was a result with favorable glass adhesiveness, solvent resistance, and alkali developability.
On the other hand, Comparative Example 17 resulted in poor heat resistance because the resin having the cationic group was not in a block structure. Moreover, since Comparative Examples 18-32 did not have a thermally crosslinkable functional group, the heat resistance exceeded ΔEab of 2.5, and the solvent resistance was poor.

<Production of color filter>
In combination with the photosensitive coloring composition of the present invention, a red photosensitive coloring composition, a blue photosensitive coloring composition and a green photosensitive coloring composition used for the preparation of a color filter were prepared.

(Preparation of red photosensitive coloring composition (RR-1))
After stirring and mixing the mixture having the following composition to be uniform, Eiger Mill (“Mini Model M-250MKII” manufactured by Eiger Japan Co., Ltd.) was used using zirconia beads having a diameter of 0.5 mm.
) For 5 hours, and then filtered through a 5.0 μm filter to prepare a red colored composition (DR-1).
9.6 parts of red pigment (CI Pigment Red 254) 2.4 parts of red pigment (CI Pigment Red 177) 1.0 part of resin type dispersant ("EFKA4300" manufactured by BASF Japan) 1.0 part of binder resin solution 135.0 parts propylene glycol monomethyl ether acetate 52.0 parts

Subsequently, a mixture having the following composition was stirred and mixed so as to be uniform, and then filtered through a 1.0 μm filter to prepare a red photosensitive coloring composition (RR-1).

Red coloring composition (DR-1) 42.0 parts Binder resin solution 113.2 parts Photopolymerizable monomer ("Aronix M400" manufactured by Toagosei Co., Ltd.) 2.8 parts Photopolymerization initiator (BASF Japan ""Irgacure907") 2.0 parts sensitizer ("EAB-F" manufactured by Hodogaya Chemical Co., Ltd.) 0.4 parts ethylene glycol monomethyl ether acetate 39.6 parts

(Preparation of blue photosensitive coloring composition (RB-1))
After stirring and mixing the mixture having the following composition to be uniform, Eiger Mill (“Mini Model M-250MKII” manufactured by Eiger Japan Co., Ltd.) was used using zirconia beads having a diameter of 0.5 mm.
) For 5 hours and filtered through a 5.0 μm filter to prepare a blue colored composition (DB-100).

Blue pigment (CI Pigment Blue 15: 6) 7.2 parts Purple Pigment (CI Pigment Violet 23) 4.8 parts Resin Type Dispersant (BASF Japan "EFKA4300") 1.0 part Binder Resin solution 117.5 parts Propylene glycol monomethyl ether acetate 69.5 parts

Then, after stirring and mixing the mixture of the following composition so that it might become uniform, it filtered with a 1.0 micrometer filter, and produced the blue photosensitive coloring composition (RB-1).

Blue coloring composition (DB-100) 34.0 parts Binder resin solution 17.6 parts Photopolymerizable monomer (“Aronix M400” manufactured by Toagosei Co., Ltd.) 3.3 parts Photopolymerization initiator (manufactured by BASF Japan “ "Irgacure 907") 2.0 parts sensitizer ("EAB-F" manufactured by Hodogaya Chemical Co., Ltd.) 0.4 parts ethylene glycol monomethyl ether acetate 52.7 parts

(Preparation of green photosensitive coloring composition (RG-1))
After stirring and mixing the mixture having the following composition to be uniform, Eiger Mill (“Mini Model M-250MKII” manufactured by Eiger Japan Co., Ltd.) was used using zirconia beads having a diameter of 0.5 mm.
) For 5 hours and then filtered through a 5.0 μm filter to prepare a green colored composition (DG-1).

Green pigment (CI Pigment Green 58) 12.0 parts Resin-type dispersant ("EFKA4300" manufactured by BASF Japan) 1.0 part Binder resin solution 135.0 parts Propylene glycol monomethyl ether acetate 52.0 parts

Subsequently, the mixture having the following composition was stirred and mixed so as to be uniform, and then filtered through a 1.0 μm filter to prepare a green photosensitive coloring composition (RG-1).
Green coloring composition (DG-1) 34.0 parts Binder resin solution 115.2 parts Photopolymerizable monomer (“Aronix M400” manufactured by Toagosei Co., Ltd.) 3.3 parts Photopolymerization initiator (manufactured by BASF Japan “ Irgacure 907 "2.0 parts sensitizer (" EAB-F "manufactured by Hodogaya Chemical Co., Ltd.) 0.4 parts ethylene glycol monomethyl ether acetate 45.1 parts

A black matrix was patterned on a glass substrate, and a red photosensitive coloring composition (RR-1) was applied on the substrate with a spin coater to a thickness of x = 0.640 to form a colored film. The film was irradiated with ultraviolet rays of 300 mJ / cm 2 through a photomask using an ultrahigh pressure mercury lamp. Next, spray development was performed with an alkaline developer composed of a 0.2% by weight aqueous sodium carbonate solution to remove unexposed portions, followed by washing with ion-exchanged water. The substrate was heated at 230 ° C. for 20 minutes to obtain a red filter segment. Formed. By the same method, a blue filter segment is formed so that the film thickness of the blue photosensitive coloring composition (R-2) of the present invention is 2.0 μm, and then the green photosensitive coloring composition (RG-1) is formed. ) To form a green color filter segment to obtain a color filter.

Similarly, using the red photosensitive coloring composition (R-15), blue photosensitive coloring composition (RB-1), and green photosensitive coloring composition (RG-1) of the present invention, a color filter is used. Got.

By using the photosensitive coloring composition of the present invention, the heat resistance of the color filter, the foreign matter test, the adhesion to a transparent substrate such as glass, the solvent resistance, and the alkali developability are improved and preferably used. I was able to.

Claims (10)

A color filter coloring composition comprising at least a colorant (A), a binder resin, and an organic solvent,
The colorant (A) contains a salt-forming compound (D) of a resin (B) having a cationic group in the side chain and an anionic dye (C),
The resin (B) having a cationic group in the side chain is an acrylic resin containing a structural unit represented by the following general formula (1), and the acrylic resin is:
For a color filter, characterized in that it is a block resin comprising an A block having a cationic group represented by the following general formula (1) and a B block not having a cationic group and having a thermally crosslinkable functional group Coloring composition.


(In general formula (1), R ₁ represents a hydrogen atom or a substituted or unsubstituted alkyl group. R _{2 to} R ₄ each independently represents a hydrogen atom, an optionally substituted alkyl group, or a substituted group. Represents an alkenyl group which may be substituted, or an aryl group which may be substituted, and _two of R _{2 to} R ₄ may be bonded to each other to form a ring, Q is an alkylene group, an arylene group, —CONH —R ₅ —, —COO—R ₅ —, wherein R ₅ represents an alkylene group, and Y ⁻ represents an inorganic or organic anion.) The colored composition for a color filter according to claim 1, wherein the thermally crosslinkable functional group is at least one selected from the group consisting of a hydroxyl group and a carboxyl group. The resin (B) having a cationic group in the side chain is a block resin further comprising 3 to 90% by weight of the structural unit of the general formula (1) out of a total of 100% by weight of the resin composition. The coloring composition for a color filter according to claim 1 or 2. The coloring composition for a color filter according to any one of claims 1 to 3, wherein an ammonium salt value of the acrylic resin containing the structural unit represented by the general formula (1) is 10 to 200 mgKOH / g. . The colored composition for a color filter according to any one of claims 1 to 4, wherein the organic solvent contains propylene glycol monomethyl ether acetate as a main component. The coloring composition for a color filter according to any one of claims 1 to 5, wherein the colorant further contains a pigment. The anionic dye (C) contains at least one selected from acid red 52, acid red 289, and a compound represented by the following general formula (2). Coloring compositions for color filters.

General formula (2)

[X1 and X3 represent a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms which may have a substituent.
X2 and X4 represent a monovalent aromatic hydrocarbon group which may have a substituent, and at least one of them has a sulfo group. ] Furthermore, the coloring composition for color filters in any one of Claims 1-7 containing a photopolymerizable monomer and / or a photoinitiator. A resin (B) having a cationic group in the side chain and an anionic dye (C) are mixed in an aqueous solution, and a counter anion of the resin (B) having a cationic group in the side chain and an anionic dye (C) pair The method for producing a colored composition for a color filter according to any one of claims 1 to 8, wherein a salt comprising a cation is removed to obtain a salt-forming compound (D). The color filter formed with the coloring composition for color filters in any one of Claims 1-8.