JP2017066208A - Coloring composition, inkjet ink, fabric printing method, and dyed or printed fabric - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a coloring composition having excellent light resistance and excellent storage stability, inkjet ink comprising the coloring composition, a fabric printing method, and a dyed or printed fabric.SOLUTION: The present invention provides a coloring composition comprising a triarylmethane compound represented by formula (1) and the like, inkjet ink comprising the coloring composition, a fabric printing method, and a dyed or printed fabric.SELECTED DRAWING: None

Description

  The present invention relates to a coloring composition, an ink jet ink, a method for printing a fabric, and a dyed or printed fabric.

A technique for dyeing a fabric using a triarylmethane dye has been studied in the past. For example, when dyeing polyamide such as silk or nylon, Acid Blue 7 (AB7) or Acid Blue 9 (AB9) has been used.
So far, screen printing, roller printing, transfer printing, and the like have been performed as industrial dyeing methods for dyeing fabrics. These methods are dyeing techniques that are completed only after a series of processes such as design pattern planning, engraving or plate making, creation of printing paste, and preparation of fabrics are integrated.
On the other hand, ink jet textile printing using an ink jet method capable of directly supplying a dye to a cloth has been proposed. Unlike conventional textile printing, inkjet textile printing has the advantage that it is not necessary to prepare a plate and can quickly form an image with excellent gradation. It has merits such as no. Further, since only a necessary amount of ink is used as a formed image, it can be said that this is an excellent image forming method having environmental advantages such as less waste liquid compared to the conventional method.
On the other hand, Patent Document 1 describes a triarylmethane compound having a heterocycle. Using a coloring composition containing this compound, printing is performed on paper by an ink jet method, and hue, light resistance, and the like. It is being considered.

JP 2003-73358 A

However, AB7 and AB9 have a problem that light resistance is insufficient.
Moreover, although the triarylmethane compound which has the heterocyclic ring described in patent document 1 has light resistance, patent document 1 has a subject (especially light resistance) at the time of setting it as the use which dye | stains a fabric. Has not been considered.
Furthermore, in inkjet textile printing, there is a step of ejecting ink containing a dye from a nozzle of a recording head of an inkjet printer onto a fabric. That is, it is desirable to have excellent storage stability.

  An object of the present invention is to provide a coloring composition having excellent light resistance and excellent storage stability. Another object of the present invention is to provide an inkjet ink containing the coloring composition, a method for printing a fabric, and a dyed or printed fabric.

  The above-described problems of the present invention are solved by the following means.

[1]
A colored composition containing a compound represented by any one of the following general formulas (1) to (3), wherein all cations except for a cation of a cationic chromophore moiety contained in the colored composition The coloring composition whose 10 mol% or more of is lithium ion.

In general formula (1), R ¹⁰¹ and R ¹⁰³ each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰² and R ¹⁰⁴ each independently represents an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ each independently represent a substituent, and X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom. However, at least one of X _{101 to} X ₁₀₃ represents CH. In the case where X _{101 to} X ₁₀₃ represent CH, a hydrogen atom may be removed and R ¹⁰⁹ may be bonded. n ¹⁰¹ and n ¹⁰² each independently represents an integer of 0 to 4, and n ¹⁰³ represents an integer of 0 to 3. When n ¹⁰¹ , n ^102, and n ¹⁰³ each represent an integer of 2 or more, the plurality of R ¹⁰⁷ , R ^108, and R ¹⁰⁹ may be the same or different. R ¹⁰⁷ and R ¹⁰⁸ may combine to form a ring. The compound represented by the general formula (1) has at least two ionic hydrophilic groups. The compound represented by the general formula (1) has a counter anion in the molecule.

In general formula (2), R ¹¹¹ and R ¹¹³ each independently represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹¹² and R ¹¹⁴ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ and R ¹¹⁹ each independently represent a substituent, and X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom. However, at least one of X _{111 to} X ₁₁₃ represents CH. When X _{111 to} X ₁₁₃ represent CH, a hydrogen atom may be removed and R ¹¹⁷ may be bonded. Ar ¹¹¹ and Ar ¹¹² each independently represent a benzene ring, a naphthalene ring, or a heterocyclic ring. n ¹¹¹ and n ¹¹² each independently represents an integer of 0 to 4, n ¹¹³ represents an integer of 0 to 5, and n ¹¹⁴ and n ¹¹⁵ each independently represents an integer of 0 or more. When n ¹¹¹ , n ¹¹² , n ¹¹³ , n ^114, and n ¹¹⁵ each represent an integer of 2 or more, a plurality of R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ^118, and R ¹¹⁹ are the same or different. Also good. R ¹¹⁵ and R ¹¹⁶ may combine to form a ring. The compound represented by the general formula (2) has at least two ionic hydrophilic groups. The compound represented by the general formula (2) has a counter anion in the molecule.

In General Formula (3), L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ and L ¹²⁵ each independently represent a divalent linking group, and T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ¹²⁵ are each independent. Represents a hydrogen atom or a group represented by any one of the following general formulas (T-1) to (T-8). However, at least one of T ¹²¹ , T ¹²² , T ¹²³ , T ^124, and T ¹²⁵ represents a group represented by any one of the general formulas (T-1) to (T-8). R ¹²¹ , R ¹²² and R ¹²³ each independently represent a substituent, and X ₁₂₁ , X ₁₂₂ and X ₁₂₃ each independently represent CH or a nitrogen atom. However, at least one of X _{121 to} X ₁₂₃ represents CH. If X ₁₂₁ to X ₁₂₃ represents CH, ^{R 123} or ^{(L 125)} n 126 ^{-T 125} off the hydrogen atoms may be bonded. n ¹²¹ and n ¹²² each independently represent an integer of 0 to 4, and n ¹²³ represents an integer of 0 to 5. n ¹²⁴ , n ¹²⁵ , n ¹²⁶ , n ^127, and n ¹²⁸ each independently represent 0 or 1. When n ¹²¹ , n ¹²² , and n ¹²³ each represent an integer of 2 or more, the plurality of R ¹²¹ , R ^122, and R ¹²³ may be the same or different. R ¹²¹ and R ¹²² may combine to form a ring. The compound represented by the general formula (3) has at least two ionic hydrophilic groups. The compound represented by the general formula (3) has a counter anion in the molecule.

R ²⁰¹ , R ²⁰² , R ²⁰⁴ and R ²⁰⁷ each independently represents an alkyl group. R ²⁰⁵ and R ²⁰⁸ each independently represent a hydrogen atom or an alkyl group. R ²⁰⁹ and R ²¹⁰ each independently represents a hydrogen atom, an alkyl group or an alkoxy group. R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ each independently represent a substituent. L ²⁰¹ represents a ^p103- valent linking group. R ²¹⁴ represents a hydrogen atom, an oxygen radical (—O ·), a hydroxy group, an alkyl group or an alkoxy group. R ²¹⁵ and R ²¹⁶ each independently represents an alkyl group. R ²¹⁵ and R ²¹⁶ may combine with each other to form a ring. R ²¹⁸ and R ²¹⁹ each independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group. R ²¹⁸ and R ²¹⁹ may combine with each other to form a ring. X ²⁰² represents an oxygen atom or a nitrogen atom. X ²⁰³ represents a carbon atom or a nitrogen atom. R ²¹² represents an aryl group, a heterocyclic group, or a group that is linked to X ²⁰² to form an aryl group or a heterocyclic group. Ar ²⁰¹ represents an aryl group or a heterocyclic group. p ¹⁰¹ represents 0 to ^{3, p 102} and ^{p 104} each independently represent 0 to ^{2, p 103} represents 2 or ^{3, p 106} represents 1-3. p ¹⁰⁵ and ^{p 107} each independently represent a 0-4. p ¹⁰⁸ represents the 2-3. X ²⁰¹ represents an oxygen atom or NR ²²⁰ , and R ²²⁰ represents a hydrogen atom or an alkyl group. ^However, if ^{the X 201} represents ^NH, at least one of ^{R 209} and ^{R 210} represents an alkyl group or an alkoxy group. When p ¹⁰¹ , p ¹⁰² , p ¹⁰⁴ , p ¹⁰⁵ and p ¹⁰⁷ each represent a number of 2 or more, a plurality of R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ are the same or different. Also good.
In addition, each group represented by any one of the general formulas (T-1) to (T-8) has L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ removed from any one hydrogen atom in the formula. Or it is combined with ^L125 . However, the hydrogen atom shown as * 1 is not detached and bonded, and when R ²¹⁴ in the general formula (T-6) is a hydrogen atom, it is not detached and bonded.
[2]
It contains a compound represented by the general formula (3), and at least one of the above T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ^{125 in} the general formula (3) is the above general formula (T-1 ), (T-3), (T-4), (T-5) or a colored composition according to [1], which represents a group represented by (T-6).
[3]
The compound represented by the general formula (3) is contained, and at least one of the T ¹²¹ , T ¹²² , T ¹²³ , T ^124, and T ^{125 in} the general formula (3) is the above general formula (T-4). [1] or [2], wherein the general formula (T-4) is represented by the following general formula (T-41), (T-42) or (T-43) The coloring composition as described.

R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ each independently represent a substituent. R ⁴⁰⁶ and R ⁴⁰⁷ each independently represents an aryl group or a heterocyclic group. p ⁴⁰¹ , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each independently represent 0-4, and p ⁴⁰² represents 0-5. When p ⁴⁰¹ , p ⁴⁰² , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each represent a number of 2 or more, a plurality of R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ may be the same or different. Also good. * 1 Hydrogen atoms shown are not detached and bonded.
[4]
The colored composition according to any one of [1] to [3], wherein 25 mol% or more of all cations except for the cation of the cationic chromophore moiety contained in the colored composition are lithium ions. .
[5]
The colored composition according to any one of [1] to [4], wherein the compound represented by any one of the general formulas (1) to (3) has at least three sulfo groups.
[6]
The coloring composition according to any one of [1] to [5] for dyeing or printing.
[7]
Ink for inkjets containing the coloring composition of any one of [1]-[5].
[8]
A textile printing method including the following steps (1) to (4).
(1) Step of adjusting the color paste by adding the coloring composition according to [6] to a liquid containing at least a polymer compound and water (2) Printing the color paste of (1) on a fabric Step (3) Step of applying steam to the printed fabric (4) Step of washing and drying the printed fabric [9]
A textile printing method comprising the following steps (11) to (14).
(11) A step of applying a paste containing at least a polymer compound and water to the fabric (12) A step of printing the ink-jet ink according to [7] on the fabric by an ink-jet method (13) Steam is applied to the printed fabric. Step (14) A step of washing and drying the printed fabric [10]
The textile printing method according to [8] or [9], wherein the fabric contains polyamide.
[11]
A fabric dyed or printed using the coloring composition according to [6].
[12]
A fabric printed by the printing method according to any one of [8] to [10].

  According to the present invention, it is possible to provide a colored composition having excellent light resistance and excellent storage stability. Moreover, the inkjet ink containing the said coloring composition, the method of printing a fabric, and the dyed or printed fabric can be provided.

FIG. 6 is a graph showing aqueous solution absorption spectra of Compound 59 and Compound 65. FIG. 6 is a graph showing aqueous solution absorption spectra of Compound 110 and Compound 105. It is a figure which shows the absorption spectrum of 6 nylon fabric dye | stained with the compound 59 and the compound 65. FIG.

Hereinafter, the present invention will be described in detail.
First, specific examples of the substituent in the present invention are defined as a substituent group A.

(Substituent group A)
Halogen atom, alkyl group, aralkyl group, alkenyl group, alkynyl group, aryl group, heterocyclic group, cyano group, hydroxyl group, nitro group, alkoxy group, aryloxy group, silyloxy group, heterocyclic oxy group, acyloxy group, carbamoyl Oxy group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, aryloxycarbonylamino group, sulfamoylamino group, alkyl or arylsulfonylamino group, mercapto Group, alkylthio group, arylthio group, heterocyclic thio group, sulfamoyl group, alkyl or arylsulfinyl group, alkyl or arylsulfonyl group, acyl group, aryloxycarbonyl group, Job aryloxycarbonyl group, a carbamoyl group, an aryl or heterocyclic azo group, an imido group, a phosphino group, phosphinyl group, phosphinyloxy group, phosphinylamino group, a silyl group, an ionic hydrophilic group mentioned as an example. These substituents may be further substituted, and examples of the further substituent include a group selected from the substituent group A described above.

  As a halogen atom, a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom is mentioned, for example.

Examples of the alkyl group include linear, branched, and cyclic substituted or unsubstituted alkyl groups, and include cycloalkyl groups, bicycloalkyl groups, and tricyclo structures having many ring structures. An alkyl group (for example, an alkyl group of an alkoxy group or an alkylthio group) in a substituent described below also represents such an alkyl group.
As the alkyl group, an alkyl group having 1 to 30 carbon atoms such as a methyl group, an ethyl group, an n-propyl group, an i-propyl group, a t-butyl group, an n-octyl group, an eicosyl group, 2- Examples thereof include a chloroethyl group, a 2-cyanoethyl group, a 2-ethylhexyl group, etc. The cycloalkyl group is preferably a substituted or unsubstituted cycloalkyl group having 3 to 30 carbon atoms, such as a cyclohexyl group, a cyclopentyl group, 4 -N-dodecylcyclohexyl group and the like, and the bicycloalkyl group is preferably a substituted or unsubstituted bicycloalkyl group having 5 to 30 carbon atoms, that is, one hydrogen atom from a bicycloalkane having 5 to 30 carbon atoms. Removed monovalent groups such as bicyclo [1,2,2] heptan-2-yl group, bicyclo [2,2 2] octan-3-yl group.

  Examples of the aralkyl group include a substituted or unsubstituted aralkyl group, and the substituted or unsubstituted aralkyl group is preferably an aralkyl group having 7 to 30 carbon atoms. For example, a benzyl group and a 2-phenethyl group can be mentioned.

Examples of the alkenyl group include linear, branched, and cyclic substituted or unsubstituted alkenyl groups, and include cycloalkenyl groups and bicycloalkenyl groups.
Preferred examples of the alkenyl group include substituted or unsubstituted alkenyl groups having 2 to 30 carbon atoms such as vinyl group, allyl group, prenyl group, geranyl group, and oleyl group. Preferred examples of the cycloalkenyl group include Is a substituted or unsubstituted cycloalkenyl group having 3 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom of a cycloalkene having 3 to 30 carbon atoms, such as a 2-cyclopenten-1-yl group, 2-cyclohexen-1-yl group and the like. As the bicycloalkenyl group, a substituted or unsubstituted bicycloalkenyl group, preferably a substituted or unsubstituted bicycloalkenyl group having 5 to 30 carbon atoms, that is, a double bond A monovalent group obtained by removing one hydrogen atom from a bicycloalkene having one of, for example, bicyclo [2,2,1] Hept-2-en-1-yl group, a bicyclo [2,2,2] oct-2-en-4-yl group and the like.

  The alkynyl group is preferably a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms such as an ethynyl group, a propargyl group, and a trimethylsilylethynyl group.

  The aryl group is preferably a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, such as a phenyl group, a p-tolyl group, a naphthyl group, an m-chlorophenyl group, an o-hexadecanoylaminophenyl group, and the like. Can be mentioned.

  The heterocyclic group is preferably a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound, and more preferably a carbon number. Examples thereof include 3 to 30 5- or 6-membered aromatic heterocyclic groups such as a 2-furyl group, a 2-thienyl group, a 2-pyrimidinyl group, and a 2-benzothiazolyl group. Examples of non-aromatic heterocyclic groups include morpholinyl groups.

  The alkoxy group is preferably a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, such as a methoxy group, an ethoxy group, an isopropoxy group, a t-butoxy group, an n-octyloxy group, or a 2-methoxyethoxy group. Etc.

  The aryloxy group is preferably a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, such as a phenoxy group, 2-methylphenoxy group, 4-t-butylphenoxy group, 3-nitrophenoxy group, 2 -Tetradecanoylaminophenoxy group etc. are mentioned.

  Preferred examples of the silyloxy group include substituted or unsubstituted silyloxy groups having 0 to 20 carbon atoms such as a trimethylsilyloxy group and a diphenylmethylsilyloxy group.

  Preferred examples of the heterocyclic oxy group include substituted or unsubstituted heterocyclic oxy groups having 2 to 30 carbon atoms, such as a 1-phenyltetrazole-5-oxy group and a 2-tetrahydropyranyloxy group.

  The acyloxy group is preferably a formyloxy group, a substituted or unsubstituted alkylcarbonyloxy group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyloxy group having 6 to 30 carbon atoms, such as an acetyloxy group, Examples include a pivaloyloxy group, a stearoyloxy group, a benzoyloxy group, and a p-methoxyphenylcarbonyloxy group.

  The carbamoyloxy group is preferably a substituted or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, such as N, N-dimethylcarbamoyloxy group, N, N-diethylcarbamoyloxy group, morpholinocarbonyloxy group, N , N-di-n-octylaminocarbonyloxy group, Nn-octylcarbamoyloxy group and the like.

  The alkoxycarbonyloxy group is preferably a substituted or unsubstituted alkoxycarbonyloxy group having 2 to 30 carbon atoms, such as a methoxycarbonyloxy group, an ethoxycarbonyloxy group, a t-butoxycarbonyloxy group, or an n-octylcarbonyloxy group. Etc.

  The aryloxycarbonyloxy group is preferably a substituted or unsubstituted aryloxycarbonyloxy group having 7 to 30 carbon atoms, such as phenoxycarbonyloxy group, p-methoxyphenoxycarbonyloxy group, pn-hexadecyloxy. Examples include phenoxycarbonyloxy group.

  The amino group includes an alkylamino group, an arylamino group, and a heterocyclic amino group, preferably an amino group, a substituted or unsubstituted alkylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted group having 6 to 30 carbon atoms. Examples of the substituted anilino group include a methylamino group, a dimethylamino group, an anilino group, an N-methyl-anilino group, a diphenylamino group, and a triazinylamino group.

  The acylamino group is preferably a formylamino group, a substituted or unsubstituted alkylcarbonylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted arylcarbonylamino group having 6 to 30 carbon atoms, such as an acetylamino group, Examples include pivaloylamino group, lauroylamino group, benzoylamino group, 3,4,5-tri-n-octyloxyphenylcarbonylamino group, and the like.

  The aminocarbonylamino group is preferably a substituted or unsubstituted aminocarbonylamino group having 1 to 30 carbon atoms, such as a carbamoylamino group, N, N-dimethylaminocarbonylamino group, or N, N-diethylaminocarbonylamino group. And a morpholinocarbonylamino group.

  The alkoxycarbonylamino group is preferably a substituted or unsubstituted alkoxycarbonylamino group having 2 to 30 carbon atoms, such as methoxycarbonylamino group, ethoxycarbonylamino group, t-butoxycarbonylamino group, n-octadecyloxycarbonylamino. Group, N-methyl-methoxycarbonylamino group and the like.

  The aryloxycarbonylamino group is preferably a substituted or unsubstituted aryloxycarbonylamino group having 7 to 30 carbon atoms, such as phenoxycarbonylamino group, p-chlorophenoxycarbonylamino group, mn-octyloxyphenoxy. Examples thereof include a carbonylamino group.

  The sulfamoylamino group is preferably a substituted or unsubstituted sulfamoylamino group having 0 to 30 carbon atoms, such as a sulfamoylamino group, N, N-dimethylaminosulfonylamino group, Nn- Examples include octylaminosulfonylamino group.

The alkyl or arylsulfonylamino group is preferably a substituted or unsubstituted alkylsulfonylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfonylamino group having 6 to 30 carbon atoms, such as a methylsulfonylamino group. Butylsulfonylamino group, phenylsulfonylamino group, 2,3,5-trichlorophenylsulfonylamino group, p-methylphenylsulfonylamino group, and the like.
Preferred examples of the alkylthio group include substituted or unsubstituted alkylthio groups having 1 to 30 carbon atoms, such as a methylthio group, an ethylthio group, and an n-hexadecylthio group.

  Preferred examples of the arylthio group include substituted or unsubstituted arylthio groups having 6 to 30 carbon atoms such as a phenylthio group, a p-chlorophenylthio group, and an m-methoxyphenylthio group.

  Preferred examples of the heterocyclic thio group include substituted or unsubstituted heterocyclic thio groups having 2 to 30 carbon atoms, such as a 2-benzothiazolylthio group and a 1-phenyltetrazol-5-ylthio group.

  The sulfamoyl group is preferably a substituted or unsubstituted sulfamoyl group having 0 to 30 carbon atoms, such as N-ethylsulfamoyl group, N- (3-dodecyloxypropyl) sulfamoyl group, N, N-dimethylsulfuryl group. Examples include a famoyl group, an N-acetylsulfamoyl group, an N-benzoylsulfamoyl group, and an N- (N′-phenylcarbamoyl) sulfamoyl group.

  The alkyl or arylsulfinyl group is preferably a substituted or unsubstituted alkylsulfinyl group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfinyl group having 6 to 30 carbon atoms, such as a methylsulfinyl group or an ethylsulfinyl group. , Phenylsulfinyl group, p-methylphenylsulfinyl group and the like.

  The alkyl or arylsulfonyl group is preferably a substituted or unsubstituted alkylsulfonyl group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfonyl group having 6 to 30 carbon atoms, such as a methylsulfonyl group or an ethylsulfonyl group. , Phenylsulfonyl group, p-methylphenylsulfonyl group and the like.

  The acyl group is preferably a formyl group, a substituted or unsubstituted alkylcarbonyl group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyl group having 7 to 30 carbon atoms, a substituted or unsubstituted group having 2 to 30 carbon atoms. Heterocyclic carbonyl groups bonded to carbonyl groups at substituted carbon atoms, such as acetyl, pivaloyl, 2-chloroacetyl, stearoyl, benzoyl, pn-octyloxyphenylcarbonyl, 2-pyridyl Examples thereof include a carbonyl group and a 2-furylcarbonyl group.

  The aryloxycarbonyl group is preferably a substituted or unsubstituted aryloxycarbonyl group having 7 to 30 carbon atoms, such as phenoxycarbonyl group, o-chlorophenoxycarbonyl group, m-nitrophenoxycarbonyl group, pt- A butylphenoxycarbonyl group etc. are mentioned.

  The alkoxycarbonyl group is preferably a substituted or unsubstituted alkoxycarbonyl group having 2 to 30 carbon atoms, such as a methoxycarbonyl group, an ethoxycarbonyl group, a t-butoxycarbonyl group, and an n-octadecyloxycarbonyl group.

  The carbamoyl group is preferably a substituted or unsubstituted carbamoyl group having 1 to 30 carbon atoms, such as a carbamoyl group, an N-methylcarbamoyl group, an N, N-dimethylcarbamoyl group, or an N, N-di-n-octyl group. Examples thereof include a carbamoyl group and an N- (methylsulfonyl) carbamoyl group.

  The aryl or heterocyclic azo group is preferably a substituted or unsubstituted arylazo group having 6 to 30 carbon atoms, a substituted or unsubstituted heterocyclic azo group having 3 to 30 carbon atoms, such as a phenylazo group or p-chlorophenylazo group. Group, 5-ethylthio-1,3,4-thiadiazol-2-ylazo group and the like.

  Preferred examples of the imide group include an N-succinimide group and an N-phthalimide group.

  The phosphino group is preferably a substituted or unsubstituted phosphino group having 0 to 30 carbon atoms, such as a dimethylphosphino group, a diphenylphosphino group, a methylphenoxyphosphino group, and the like.

  The phosphinyl group is preferably a substituted or unsubstituted phosphinyl group having 0 to 30 carbon atoms, such as a phosphinyl group, a dioctyloxyphosphinyl group, a diethoxyphosphinyl group, and the like.

  Preferred examples of the phosphinyloxy group include substituted or unsubstituted phosphinyloxy groups having 0 to 30 carbon atoms such as a diphenoxyphosphinyloxy group and a dioctyloxyphosphinyloxy group.

  The phosphinylamino group is preferably a substituted or unsubstituted phosphinylamino group having 0 to 30 carbon atoms, such as a dimethoxyphosphinylamino group or a dimethylaminophosphinylamino group.

  Preferred examples of the silyl group include substituted or unsubstituted silyl groups having 0 to 30 carbon atoms such as a trimethylsilyl group, a t-butyldimethylsilyl group, and a phenyldimethylsilyl group.

  Examples of the ionic hydrophilic group include a sulfo group, a carboxyl group, a thiocarboxyl group, a sulfino group, a phosphono group, a dihydroxyphosphino group, and a quaternary ammonium group. Particularly preferred are a sulfo group and a carboxyl group. The ionic hydrophilic group may be in a state containing a cation or an anion (also referred to as “salt state”). The carboxyl group, phosphono group, and sulfo group may be in a state containing a cation. Examples of the cation that forms a salt state include ammonium ion, alkali metal ion (eg, lithium ion, sodium ion, potassium ion) and Organic cation (eg, tetramethylammonium ion, tetramethylguanidinium ion, tetramethylphosphonium) is included, lithium ion, sodium ion, potassium ion, ammonium ion is preferable, lithium ion or sodium ion is more preferable, lithium ion Is most preferred. Moreover, it may contain a plurality of cations, and when it contains a plurality of cations, the lithium ion content is preferably maximized.

  In the present invention, when the compound is a salt, the salt is dissociated into ions in the water-soluble ink.

[Compound represented by any one of the general formulas (1) to (3)]
When the compound represented by any one of the general formulas (1) to (3) is used as a coloring composition for dyeing or printing, a fabric dyed from cyan to blue can be obtained. Improvement in light resistance was observed in the colored portion of the dyed fabric. Although the mechanism of action is unknown, it is considered that the compound represented by the general formula (1) or (2) has improved light resistance because it shields a site that is easily photodegradable. In addition, the compound represented by the general formula (3) has an anti-fading site introduced to the dye via a covalent bond, so that the dye does not lightly fade and exists in the immediate vicinity of the dye. It is considered that the prevention site functions and the light resistance is improved.
Further, when dyeing or printing was performed using the compound represented by the general formula (3), improvement in chlorine resistance was recognized. Although the mechanism of action is unknown, in general formula (3), a site that is easily oxidized, such as phenol, is introduced, so that the dye is not oxidized in chlorine water, and that portion is oxidized, resulting in improved chlorine resistance. I guess that.

  First, the compound represented by the general formula (1) will be described.

In general formula (1), R ¹⁰¹ and R ¹⁰³ each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰² and R ¹⁰⁴ each independently represents an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ each independently represent a substituent, and X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom. However, at least one of X _{101 to} X ₁₀₃ represents CH. In the case where X _{101 to} X ₁₀₃ represent CH, a hydrogen atom may be removed and R ¹⁰⁹ may be bonded. n ¹⁰¹ and n ¹⁰² each independently represents an integer of 0 to 4, and n ¹⁰³ represents an integer of 0 to 3. When n ¹⁰¹ , n ^102, and n ¹⁰³ each represent an integer of 2 or more, the plurality of R ¹⁰⁷ , R ^108, and R ¹⁰⁹ may be the same or different. R ¹⁰⁷ and R ¹⁰⁸ may combine to form a ring. The compound represented by the general formula (1) has at least two ionic hydrophilic groups. The compound represented by the general formula (1) has a counter anion in the molecule.

When R ¹⁰¹ , R ¹⁰² , R ¹⁰³ and R ^{104 in the} general formula (1) represent an alkyl group, an aryl group or a heterocyclic group, these may have a substituent.
R ¹⁰⁵ and R ¹⁰⁶ are alkyl groups, alkoxy groups, acyloxy groups, carbamoyloxy groups, alkoxycarbonyloxy groups, amino groups, acylamino groups, aminocarbonylamino groups, alkoxycarbonylamino groups, sulfamoylamino groups, alkylsulfonylamino groups. , An alkylthio group, a sulfamoyl group, an alkylsulfinyl group, an alkylsulfonyl group, an acyl group, an alkoxycarbonyl group, a carbamoyl group, or an imide group, these may have a substituent.
Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.

R ¹⁰¹ and R ¹⁰³ are preferably a hydrogen atom, an alkyl group which may have a substituent, or an aryl group which may have a substituent.
R ¹⁰² and R ¹⁰⁴ are preferably an alkyl group which may have a substituent, or an aryl group which may have a substituent, and has an alkyl group which has a substituent or a substituent. An aryl group that may be present is more preferred.

As the alkyl group for R ¹⁰¹ , R ¹⁰² , R ¹⁰³ and R ¹⁰⁴ , an alkyl group having 1 to 6 carbon atoms is preferable, an alkyl group having 1 to 3 carbon atoms is more preferable, and a methyl group or an ethyl group is still more preferable. When R ¹⁰² and R ¹⁰⁴ are alkyl groups, a methyl group substituted with a phenyl group is most preferred. The methyl group substituted with the phenyl group may further have a substituent.

The aryl group for R ¹⁰¹ , R ¹⁰² , R ¹⁰³ and R ¹⁰⁴ is preferably a phenyl group or a naphthyl group, and more preferably a phenyl group. When ^R102 and ^R104 represent an aryl group, ^R101 and ^R103 preferably represent a hydrogen atom.

R ¹⁰⁵ and R ¹⁰⁶ are preferably a halogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, an acyloxy group which may have a substituent, or a substituent. The sulfamoyl group which may have a group, the acyl group which may have a substituent, the alkoxycarbonyl group which may have a substituent, or a sulfo group is represented.
R ¹⁰⁵ and R ¹⁰⁶ are more preferably an alkyl group which may have a substituent, or a halogen atom, and the halogen atom is preferably a chlorine atom.

Examples of the substituent represented by R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ include a substituent selected from the above substituent group A, and preferably an alkyl group, a sulfo group, an optionally substituted sulfamoyl group, a halogen atom , An alkoxy group which may have a substituent, an aryloxy group which may have a substituent, a heterocyclic oxy group which may have a substituent, an acyloxy group which may have a substituent, a substituent An alkylamino group which may have a substituent, an arylamino group which may have a substituent, a heterocyclic amino group which may have a substituent, an acylamino group which may have a substituent, and a substituent. An optionally substituted aminocarbonylamino group, an optionally substituted alkoxycarbonylamino group, an optionally substituted aryloxycarbonylamino group, an optionally substituted alkyl or aryl A rusulfonylamino group, preferably an alkyl group, a sulfo group, an alkylamino group which may have a substituent, and an arylamino group which may have a substituent.

n ¹⁰¹ and R ¹⁰² preferably represent 0-2. n ¹⁰³ preferably represents 0-1.

X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom, and preferably represents CH. When X ₁₀₁ , X ₁₀₂ and X ₁₀₃ represent CH, a hydrogen atom may be removed and a substituent R ¹⁰⁹ may be bonded.

The compound represented by the general formula (1) has at least two ionic hydrophilic groups. The compound represented by the general formula (1) has at least two ionic hydrophilic groups, which is preferable from the viewpoint of ink storage stability and dyeability to fibers. The ionic hydrophilic group is preferably an anionic ionic hydrophilic group (an ionic hydrophilic group that generates an anion when dissociated), a sulfo group, a carboxyl group, a thiocarboxyl group, a sulfino group, A phosphono group, a dihydroxyphosphino group, etc. are mentioned, Especially preferably, they are a sulfo group and a carboxyl group, Most preferably, it is a sulfo group.
The compound represented by the general formula (1) preferably has 2 or more and 5 or less ionic hydrophilic groups, and more preferably 2 or more and 4 or less.
In particular, the compound represented by any one of the general formulas (1) to (3) preferably has at least three sulfo groups.

The compound represented by the general formula (1) has a counter anion in the molecule.
In general, a triphenylmethane compound is an ionic compound and has a resonance structure. For example, in Acid Blue 7, the following (A) to (C) represent the same compound.

  The general formula (1) is preferably represented by the following general formula (1-1) or (1-2), and more preferably represented by the general formula (1-2).

In General Formula (1-1), R ¹⁰¹ and R ¹⁰³ each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ^102a , R ^104a , R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ each independently represent a substituent, and X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom. However, at least one of X _{101 to} X ₁₀₃ represents CH. In the case where X _{101 to} X ₁₀₃ represent CH, a hydrogen atom may be removed and R ¹⁰⁹ may be bonded. n ¹⁰¹ and n ¹⁰² each independently represents an integer of 0 to 4, n ¹⁰³ represents an integer of 0 to 3, and n ¹⁰⁴ and n ¹⁰⁵ each independently represents an integer of 0 to 5. The hydrogen atom in General formula (1-1) may remove | deviate and the substituent may couple | bond. When n ¹⁰¹ , n ¹⁰² , n ¹⁰³ , n ¹⁰⁴ and n ¹⁰⁵ each represent an integer of 2 or more, a plurality of R ¹⁰⁷ , R ¹⁰⁸ , R ¹⁰⁹ , R ^102a and R ^104a may be the same or different. Also good. The compound represented by the general formula (1-1) has at least two ionic hydrophilic groups. The compound represented by the general formula (1-1) has a counter anion.

In formula (1-2), R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group. , Aminocarbonylamino group, alkoxycarbonylamino group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group Represents a group. R ¹¹² and R ¹¹⁴ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ^102b , R ^104b , R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ each independently represent a substituent, and X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom. However, at least one of X _{101 to} X ₁₀₃ represents CH. In the case where X _{101 to} X ₁₀₃ represent CH, a hydrogen atom may be removed and R ¹⁰⁹ may be bonded. n ¹⁰¹ and n ¹⁰² each independently represents an integer of 0 to 4, and n ¹⁰³ represents an integer of 0 to 3. n ¹⁰⁴ and n ¹⁰⁵ each independently represents an integer of 0 to 5. The hydrogen atom in General formula (1-2) may remove | deviate and the substituent may couple | bond. When n ¹⁰¹ , n ¹⁰² , n ¹⁰³ , n ^104, and n ¹⁰⁵ each represent an integer of 2 or more, the plurality of R ¹⁰⁷ , R ¹⁰⁸ , R ¹⁰⁹ , R ^102b, and R ^104b are the same or different. Also good. The compound represented by the general formula (1-2) has at least two ionic hydrophilic groups. The compound represented by the general formula (1-2) has a counter anion.

In the general formula ^(1-1), specific examples and preferred ranges of ^{R 101} and ^{R 103} are the same as ^{R 101} and ^{R 103} in formula (1).
In the general formula (1-1) and ^{(1-2), R 105, R} 106, specific examples and preferred ranges of R ^{107, R 108} and ^{R 109} independently represent, ^R 105 in the general formula ^{(1), R 106, R 107} , R ¹⁰⁸ and R ¹⁰⁹ are the same.
In general formulas (1-1) and (1-2), preferred ranges of X ₁₀₁ , X ₁₀₂ , X ₁₀₃ , n ¹⁰¹ , n ^102, and n ¹⁰³ are X ₁₀₁ , X ₁₀₂ , X in general formula (1). ₁₀₃ , n ¹⁰¹ , n ¹⁰² and n ¹⁰³ are the same.
In general formulas (1-1) and (1-2), specific examples and preferred ranges of R ^102a , R ^104a , R ^102b , and R ^102b are the same as those of R ¹⁰⁷ , R ^108, and R ¹⁰⁹ .
In the general formula ^(1-2), specific examples and preferred ranges of ^{R 112} and ^{R 114} are the same as ^{R 112} and ^{R 114} in formula (2) described later.
In the general formulas (1-1) and (1-2), ⁿ¹⁰⁴ and ⁿ¹⁰⁵ preferably represent 1 to 3.
The compound represented by the general formula (1-1) or (1-2) has at least two ionic hydrophilic groups. Specific examples and preferred ranges of the ionic hydrophilic groups are described in the general formula (1). Is the same as

  Next, the compound represented by the general formula (2) will be described.

In general formula (2), R ¹¹¹ and R ¹¹³ each independently represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹¹² and R ¹¹⁴ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ and R ¹¹⁹ each independently represent a substituent, and X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom. However, at least one of X _{111 to} X ₁₁₃ represents CH. When X _{111 to} X ₁₁₃ represent CH, a hydrogen atom may be removed and R ¹¹⁷ may be bonded. Ar ¹¹¹ and Ar ¹¹² each independently represent a benzene ring, a naphthalene ring, or a heterocyclic ring. n ¹¹¹ and n ¹¹² each independently represents an integer of 0 to 4, n ¹¹³ represents an integer of 0 to 5, and n ¹¹⁴ and n ¹¹⁵ each independently represents an integer of 0 or more. When n ¹¹¹ , n ¹¹² , n ¹¹³ , n ^114, and n ¹¹⁵ each represent an integer of 2 or more, a plurality of R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ^118, and R ¹¹⁹ are the same or different. Also good. R ¹¹⁵ and R ¹¹⁶ may combine to form a ring. The compound represented by the general formula (2) has at least two ionic hydrophilic groups. The compound represented by the general formula (2) has a counter anion in the molecule.

When R ¹¹¹ and R ¹¹³ represent an alkyl group, an aryl group, or a heterocyclic group, these may have a substituent.
R ¹¹² and R ¹¹⁴ are alkyl groups, alkoxy groups, acyloxy groups, carbamoyloxy groups, alkoxycarbonyloxy groups, amino groups, acylamino groups, aminocarbonylamino groups, alkoxycarbonylamino groups, sulfamoylamino groups, alkylsulfonylamino groups. , An alkylthio group, a sulfamoyl group, an alkylsulfinyl group, an alkylsulfonyl group, an acyl group, an alkoxycarbonyl group, a carbamoyl group, or an imide group, these may have a substituent.
Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.

R ¹¹¹ and R ¹¹³ are preferably a hydrogen atom or an alkyl group which may have a substituent, and more preferably a hydrogen atom.

R ¹¹² and R ¹¹⁴ have a halogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, an acyloxy group which may have a substituent, or a substituent. A sulfamoyl group which may have a substituent, an acyl group which may have a substituent, an alkoxycarbonyl group which may have a substituent, a carbamoyl group or a sulfo group, and preferably a substituent. A good alkyl group or a halogen atom is more preferred. As the halogen atom, a chlorine atom is preferable.

The alkyl group for R ¹¹¹ , R ¹¹² , R ¹¹³ and R ¹¹⁴ is preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 3 carbon atoms, still more preferably a methyl group or an ethyl group, The group is particularly preferred.

Examples of the substituent represented by R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ^118, and R ¹¹⁹ include a substituent selected from the above substituent group A, and an alkyl group, a sulfo group, and a sulfamoyl group that may have a substituent. Group, halogen atom, alkoxy group which may have a substituent, aryloxy group which may have a substituent, heterocyclic oxy group which may have a substituent, acyloxy which may have a substituent Group, optionally substituted amino group, optionally substituted alkylamino group, optionally substituted arylamino group, optionally substituted heterocyclic amino group , An acylamino group which may have a substituent, an aminocarbonylamino group which may have a substituent, an alkoxycarbonylamino group which may have a substituent, an aryloxycarbonyl which may have a substituent Mino group, optionally substituted alkyl or arylsulfonylamino group, optionally substituted alkylthio group, optionally substituted alkylsulfonyl group, optionally substituted alkyl An aminocarbonyl group is preferred, preferably an alkyl group, a sulfo group, an alkylamino group which may have a substituent, or an arylamino group which may have a substituent. Examples of the substituent in the case where the alkylamino group and the arylamino group have a substituent include a substituent selected from the substituent group A, and an alkyl group, a halogen atom, an alkoxycarbonyl group, and a sulfo group are preferable.
The alkyl group represented by R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ and R ¹¹⁹ is preferably an alkyl group having 1 to 10 carbon atoms, more preferably an alkyl group having 1 to 6 carbon atoms, a methyl group, an ethyl group, An isopropyl group or a tert-butyl group is more preferable. From the viewpoint of light resistance, an ethyl group is more preferable than a methyl group, and an isopropyl group is more preferable than an ethyl group.
The substitution position on the aromatic ring of R ¹¹⁵ and R ¹¹⁶ is preferably the ortho position as viewed from the nitrogen atom.

Ar ¹¹¹ and Ar ¹¹² are preferably a benzene ring or a naphthalene ring, and more preferably a benzene ring.

n ¹¹¹ and ^{n 112} is preferably a 0-2. n ¹¹³ preferably represents 0-3. n ¹¹⁴ and ^{R 115} preferably represents 0-5.

X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom, and preferably represents CH. When X ₁₁₁ , X ₁₁₂ and X ₁₁₃ represent CH, a hydrogen atom may be removed and a substituent R ¹¹⁷ may be bonded.
The general formula (2) is preferably represented by the following general formula (2-1) or (2-2), and more preferably represented by the general formula (2-2).

In the general formula (2-1), R ^112a , R ^112b , R ^114a and R ^114b are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group. , Amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl Represents a group, an imide group or a sulfo group. R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ and R ¹¹⁹ each independently represent a substituent, and X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom. However, at least one of X _{111 to} X ₁₁₃ represents CH. When X _{111 to} X ₁₁₃ represent CH, a hydrogen atom may be removed and R ¹¹⁷ may be bonded. n ¹¹¹ and n ¹¹² each independently represents an integer of 0 to 4, n ¹¹³ represents an integer of 0 to 5, and n ¹¹⁶ and n ¹¹⁷ each independently represents an integer of 0 to 3. The hydrogen atom in General formula (2-1) may remove | deviate and the substituent may couple | bond. When n ¹¹¹ , n ¹¹² , n ¹¹³ , n ^116, and n ¹¹⁷ each represent an integer of 2 or more, a plurality of R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ^118, and R ¹¹⁹ are the same or different. Also good. The compound represented by the general formula (2-1) has at least two ionic hydrophilic groups. The compound represented by the general formula (2-1) has a counter anion in the molecule.

In General Formula (2-1), specific examples and preferred ranges of R ^112a , R ^112b , R ^114a and R ^114b are the same as R ¹¹² and R ¹¹⁴ in General Formula (2).
In the general formula ^{(2-1), R 115, R} 116, R 117, R 118, specific examples and preferred ranges of ^{R 119} may, ^R 115 in the general formula ^{(2), R 116, R} 117, R 118, Same as ^R119 .
In the general formula _(2-1), the preferred range of ^{_{X 111, X 112, X 113}} , n 111, n 112, and ^{n 113} _{is, ^{X 111, X 112, X 113}} , n 111, n 112, and ^{n 113} Is the same.
n ¹¹⁶ and ^{n 117} is preferably a 0-2.

In the general formula (2-2), R ^112a , R ^112b , R ^114a , R ^114b , R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy Group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group Represents an alkoxycarbonyl group, a carbamoyl group, an imide group or a sulfo group. R ¹¹⁵ , R ¹¹⁶ , R ^117a , R ¹¹⁸ and R ¹¹⁹ each independently represent a substituent, and X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom. However, at least one of X _{111 to} X ₁₁₃ represents CH. When X _{111 to} X ₁₁₃ represent CH, a hydrogen atom may be removed and R ¹¹⁷ may be bonded. n ¹¹¹ and n ¹¹² each independently represents an integer of 0 to 4, and n ¹¹⁶ , n ¹¹⁷ and n ¹¹⁸ each independently represents an integer of 0 to 3. The hydrogen atom in General formula (2-2) may remove | deviate and the substituent may couple | bond. When n ¹¹¹ , n ¹¹² , n ¹¹⁶ , n ¹¹⁷ and n ¹¹⁸ each represent an integer of 2 or more, a plurality of R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁸ , R ¹¹⁹ and R ^117a may be the same or different. Also good. The compound represented by the general formula (2-2) has at least two ionic hydrophilic groups. The compound represented by the general formula (2-2) has a counter anion in the molecule.

In General Formula (2-2), specific examples and preferred ranges of R ^112a , R ^112b , R ^114a and R ^114b are the same as R ¹¹² and R ¹¹⁴ in General Formula (2).
In General Formula (2-2), specific examples and preferred ranges of R ¹¹⁵ , R ¹¹⁶ , R ^117a , R ¹¹⁸ , and R ¹¹⁹ are R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ , and General Formula (2). Same as ^R119 .
In the general formula _(2-2), the preferred range of _{X 111, X 112, X 113} , n 111, and ^{n 112} _are the same as _{X 111, X 112, X 113} , n 111, and ^{n 112.}
n ¹¹⁶ and ^{n 117} is preferably a 0-2. n ¹¹⁸ preferably represents 0 to 1.
The compound represented by the general formula (2), (2-1) or (2-2) has at least two ionic hydrophilic groups. Specific examples and preferred ranges of the ionic hydrophilic groups are represented by the general formula ( The same as described in 1).

  Next, the compound represented by the general formula (3) will be described.

In General Formula (3), L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ and L ¹²⁵ each independently represent a divalent linking group, and T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ¹²⁵ are each independent. Represents a hydrogen atom or a group represented by any one of the following general formulas (T-1) to (T-8). However, at least one of T ¹²¹ , T ¹²² , T ¹²³ , T ^124, and T ¹²⁵ represents a group represented by any one of the general formulas (T-1) to (T-8). R ¹²¹ , R ¹²² and R ¹²³ each independently represent a substituent, and X ₁₂₁ , X ₁₂₂ and X ₁₂₃ each independently represent CH or a nitrogen atom. However, at least one of X _{121 to} X ₁₂₃ represents CH. If X ₁₂₁ to X ₁₂₃ represents CH, ^{R 123} or ^{(L 125)} n 126 ^{-T 125} off the hydrogen atoms may be bonded. n ¹²¹ and n ¹²² each independently represent an integer of 0 to 4, and n ¹²³ represents an integer of 0 to 5. n ¹²⁴ , n ¹²⁵ , n ¹²⁶ , n ^127, and n ¹²⁸ each independently represent 0 or 1. When n ¹²¹ , n ¹²² , and n ¹²³ each represent an integer of 2 or more, the plurality of R ¹²¹ , R ^122, and R ¹²³ may be the same or different. R ¹²¹ and R ¹²² may combine to form a ring. The compound represented by the general formula (3) has at least two ionic hydrophilic groups. The compound represented by the general formula (3) has a counter anion in the molecule.

R ²⁰¹ , R ²⁰² , R ²⁰⁴ and R ²⁰⁷ each independently represents an alkyl group. R ²⁰⁵ and R ²⁰⁸ each independently represent a hydrogen atom or an alkyl group. R ²⁰⁹ and R ²¹⁰ each independently represents a hydrogen atom, an alkyl group or an alkoxy group. R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ each independently represent a substituent. L ²⁰¹ represents a ^p103- valent linking group. R ²¹⁴ represents a hydrogen atom, an oxygen radical (—O ·), a hydroxy group, an alkyl group or an alkoxy group. R ²¹⁵ and R ²¹⁶ each independently represents an alkyl group. R ²¹⁵ and R ²¹⁶ may combine with each other to form a ring. R ²¹⁸ and R ²¹⁹ each independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group. R ²¹⁸ and R ²¹⁹ may combine with each other to form a ring. X ²⁰² represents an oxygen atom or a nitrogen atom. X ²⁰³ represents a carbon atom or a nitrogen atom. R ²¹² represents an aryl group, a heterocyclic group, or a group that is linked to X ²⁰² to form an aryl group or a heterocyclic group. Ar ²⁰¹ represents an aryl group or a heterocyclic group. p ¹⁰¹ represents 0 to ^{3, p 102} and ^{p 104} each independently represent 0 to ^{2, p 103} represents 2 or ^{3, p 106} represents 1-3. p ¹⁰⁵ and ^{p 107} each independently represent a 0-4. p ¹⁰⁸ represents the 2-3. X ²⁰¹ represents an oxygen atom or NR ²²⁰ , and R ²²⁰ represents a hydrogen atom or an alkyl group. ^However, if ^{the X 201} represents ^NH, at least one of ^{R 209} and ^{R 210} represents an alkyl group or an alkoxy group. When p ¹⁰¹ , p ¹⁰² , p ¹⁰⁴ , p ¹⁰⁵ and p ¹⁰⁷ each represent a number of 2 or more, a plurality of R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ are the same or different. Also good.
In addition, each group represented by any one of the general formulas (T-1) to (T-8) has L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ removed from any one hydrogen atom in the formula. Or it is combined with ^L125 . However, the hydrogen atom shown as * 1 is not detached and bonded, and when R ²¹⁴ in the general formula (T-6) is a hydrogen atom, it is not detached and bonded.

Specific examples of the divalent linking group in the case where L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ and L ¹²⁵ represent a divalent linking group include an alkylene group, an arylene group, a heteryl group, an ether bond,- NH-, a thioether bond, a carbonyl group, a sulfonyl group, and a divalent linking group obtained by combining at least two of these may be mentioned. These linking groups may have a substituent. Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.

It is preferable that any one to four of T ¹²¹ , T ¹²² , T ¹²³ , T ^124, and T ¹²⁵ is a group represented by any one of the general formulas (T-1) to (T-8). It is more preferable that any one to three are groups represented by any one of the general formulas (T-1) to (T-8), and any one to two are the general formulas (T-1) to (T It is more preferable that it is a group represented by any of -8). As the number of groups represented by any one of the general formulas (T-1) to (T-8) increases, the effect tends to be obtained with respect to light resistance and chlorine resistance.

Examples of the substituent represented by R ¹²¹ , R ¹²² and R ¹²³ include a substituent selected from the above substituent group A, and include an alkyl group, a sulfo group, an optionally substituted sulfamoyl group, a halogen atom, An alkoxy group that may have a group, an aryloxy group that may have a substituent, a heterocyclic oxy group that may have a substituent, an acyloxy group that may have a substituent, and a substituent. An alkylamino group which may have a substituent, an arylamino group which may have a substituent, a heterocyclic amino group which may have a substituent, an acylamino group which may have a substituent, and a substituent An optionally substituted aminocarbonylamino group, an optionally substituted alkoxycarbonylamino group, an optionally substituted aryloxycarbonylamino group, an optionally substituted alkyl or arylsulfur A phonylamino group is preferred. An alkyl group, a sulfo group, an alkylamino group which may have a substituent, or an arylamino group which may have a substituent is preferable.

n ¹²¹ and ^{n 122} is preferably a 0-2. n ¹²³ preferably represents 0-3.
n ¹²⁴ , n ¹²⁵ , n ¹²⁶ , n ^127, and n ¹²⁸ each independently represent 0 or 1. In the groups represented by any one of the general formulas (T-1) to (T-8), any one hydrogen atom in the formula is removed and L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ . However, when n ¹²⁴ , n ¹²⁵ , n ¹²⁶ , n ^127, and n ¹²⁸ represent 0, the group represented by any one of the general formulas (T-1) to (T-8) is bonded to a nitrogen atom. To do.

X ₁₂₁ , X ₁₂₂ and X ₁₂₃ each independently represent CH or a nitrogen atom, and preferably represents CH. When X ₁₂₁ , X ₁₂₂ and X ₁₂₃ represent CH, a hydrogen atom may be removed and a substituent may be bonded. Examples of the substituent include — (L ¹²⁵ ) n ¹²⁸ -T ¹²⁵ or R ^123. .

In General Formulas (T-1) to (T-3), when R ²⁰¹ , R ²⁰² , R ²⁰⁴ , R ²⁰⁵ , R ²⁰⁷ and R ²⁰⁸ represent an alkyl group, the alkyl group may have a substituent. Good.
When ^R209 and ^R210 represent an alkyl group or an alkoxy group, these may have a substituent.
Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.

X ²⁰¹ represents an oxygen atom or NR ²²⁰ , and R ²²⁰ represents a hydrogen atom or an alkyl group which may have a substituent. The alkyl group of R ^220, an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms, specifically a methyl group, an ethyl group, a propyl group.
The alkyl group of ^{R 201, R 202, R 204} , R 205, R 209 and ^{R 210,} preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms, a methyl group, ethyl A group, isopropyl group, and tert-butyl group are more preferable.
However, when X ²⁰¹ is NH, at least one of R ²⁰⁹ and R ²¹⁰ represents an alkyl group or an alkoxy group.
The alkyl group for R ²⁰⁷ and R ²⁰⁸ is preferably an alkyl group having 1 to 10 carbon atoms, more preferably an alkyl group having 1 to 6 carbon atoms, and a methyl group, an ethyl group, a propyl group, a butyl group, an isobutyl group, or a hexyl group. Groups are more preferred.
The alkoxy group R ²⁰⁹ and ^{R 210,} preferably an alkoxy group having 1 to 6 carbon atoms, more preferably an alkoxy group having 1 to 3 carbon atoms, a methoxy group, an ethoxy group more preferred.

The divalent linking group of L ²⁰¹ is the same as L ¹²¹ , L ¹²³ , L ¹²³ , L ¹²⁴ and L ¹²⁵ . Examples of the trivalent linking group include a triazine linking group and a cyanuric acid linking group. L ²⁰¹ preferably represents a divalent linking group.
Examples of the substituent represented by R ²⁰³ , R ²⁰⁶ and R ²¹¹ include a substituent selected from the above substituent group A.
p ¹⁰¹ represents 0 to 3, preferably 0 to 1. p ¹⁰² and ^{p 104} represents 0-2, preferably a 0-1.
Preferred forms when general formulas (T-1) and (T-3) are linked are shown below. Means binding to L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ via *.

In General Formula (T-4), the aryl group or heterocyclic group represented by R ²¹² and the aryl group or heterocyclic group formed by linking to X ²⁰² may have a substituent.
Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.
R ²¹² preferably represents an aryl group. ^Examples of the aryl group for R ²¹² include a phenyl group and a naphthyl group, and a phenyl group is preferable.
R ²¹² is preferably linked to X ²⁰² to form a heterocyclic group. Examples of the ring formed include a benzotriazole ring, a triazole ring, a triazine ring, and a pyrimidine ring.
^Examples of the substituent for R213 include a substituent selected from Substituent Group A. p ¹⁰⁵ represents 0 to 4, preferably 0 to 2.

The general formula (T-4) is preferably represented by the following general formula (T-41), (T-42) or (T-43). However, the hydrogen atom indicated by * 1 is not detached and bonded to L ¹²¹ , L ¹²² , L ¹²³ , L ^124, or L ¹²⁵ .

R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ each independently represent a substituent. R ⁴⁰⁶ and R ⁴⁰⁷ each independently represents an aryl group or a heterocyclic group. p ⁴⁰¹ , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each independently represent 0-4, and p ⁴⁰² represents 0-5. When p ⁴⁰¹ , p ⁴⁰² , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each represent a number of 2 or more, a plurality of R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ may be the same or different. Also good. * 1 Hydrogen atoms shown are not detached and bonded.

R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ each independently represent a substituent. Examples of the substituent include a substituent selected from the above substituent group A.
R ⁴⁰⁶ and R ⁴⁰⁷ each independently represents an aryl group or a heterocyclic group. R ⁴⁰⁶ and R ⁴⁰⁷ are preferably phenyl groups.
p ⁴⁰¹ , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ preferably represent 0-2. p ⁴⁰² preferably represents 0-2.

The preferable form when general formula (T-4) connects is shown below. Means binding to L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ via *.

R ^406a and R ^407a each independently represent a substituent. The preferred range of R ^406a and R ^407a is the same as R ⁴⁰⁵ . p ⁴⁰⁶ and p ⁴⁰⁷ each independently represent 0-5. When p ⁴⁰⁶ and p ⁴⁰⁷ each represent a number of 2 or more, the plurality of R ^406a and R ^407a may be the same or different.

In General Formula (T-5), the aryl group or heterocyclic group represented by Ar ²⁰¹ may have a substituent. Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.
Ar ²⁰¹ preferably represents an aryl group. Examples of the aryl group of Ar ²⁰¹ include a phenyl group and a naphthyl group, and a phenyl group is preferable.
p ¹⁰⁶ represents 1-3, preferably a 1-2.
The preferable form when general formula (T-5) connects is shown below. Means binding to L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ via *.

In General Formula (T-6), the alkyl group of R ²¹⁴ , the alkoxy group, and the alkyl group of R ²¹⁵ may have a substituent. Examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A.
R ²¹⁴ is preferably a hydrogen atom or an alkyl group. The alkyl group for R ²¹⁴ is preferably an alkyl group having 1 to 6 carbon atoms, more preferably 1 to 4 carbon atoms, and still more preferably a methyl group, an ethyl group, a propyl group, or a butyl group.
The alkyl group for R ²¹⁵ and R ²¹⁶ is preferably a branched alkyl group, more preferably a secondary alkyl group having 1 to 10 carbon atoms or a tertiary alkyl group having 1 to 10 carbon atoms. Specific examples of the secondary alkyl group include an isopropyl group, a s-butyl group, and a cyclohexyl group. Specific examples of the tertiary alkyl group include a tert-butyl group and a tert-amyl group. R ²¹⁵ and R ²¹⁶ may combine with each other to form a ring. When forming a ring, 2-20 are preferable and, as for carbon number of the ring formed, 2-10 are more preferable. Examples of the ring formed include an aziridine ring, piperidine ring, pyrrolidine ring and the like. Of ^{these, R 215} and ^{R 216} represent a tertiary ^{alkyl, embodiments R 215} and ^{R 216} are joined to form a piperidine ring together are preferred.
The general formula (T-6) is preferably represented by the following general formula (T-61).

The preferable form when general formula (T-6) connects is shown below. Means binding to L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ via *.

In General Formula (T-7), examples of the substituent for R ²¹⁷ include a substituent selected from the above substituent group A.
p ¹⁰⁷ represents 0 to 4, preferably 0 to 2. p ¹⁰⁸ represents the 2-3.

In General Formula (T-8), the alkyl group, aryl group, and heterocyclic group represented by R ²¹⁸ and R ²¹⁹ may have a substituent.
R ²¹⁸ and R ²¹⁹ preferably represent a hydrogen atom, an alkyl group or an aryl group. As an alkyl group of ^R218 and ^R219, a C1-C6 alkyl group is preferable, C1-C4 is more preferable, and a methyl group, an ethyl group, a propyl group, and a butyl group are still more preferable. ^Examples of the aryl group for R ²¹⁸ and R ²¹⁹ include a phenyl group and a naphthyl group, and a phenyl group is preferable.
R ²¹⁸ and R ²¹⁹ may be bonded to each other to form a ring, and in this case, the ring may contain a hetero atom such as a nitrogen atom.

The preferable form when general formula (T-8) connects is shown below. Means binding to L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ or L ¹²⁵ via *.

At least one of T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ¹²⁵ is represented by the general formula (T-1), (T-3), (T-4), (T-5) or (T-6). It is preferable to represent the group represented by.

The compound represented by any one of the general formulas (1) to (3) preferably has at least one sulfo group.
The counter anion of the cation in the general formulas (1) to (3) is preferably a sulfo group (—SO ₃ ⁻ ) present in the molecule.

  In addition, from the viewpoint of storage stability of the colored composition, 10 mol% or more of the cation contained in the ionic hydrophilic group of the compound represented by any one of the general formulas (1) to (3) is lithium ion. It is preferable that 25 mol% or more is lithium ion, and 50 mol% or more is more preferably lithium ion.

  Hereinafter, specific examples of the dye compound represented by any one of the general formulas (1) to (3) are shown. However, the present invention is not limited to these specific examples. iPr represents an isopropyl group, and Ac represents an acetyl group.

(Synthesis method)
A method for synthesizing the compound represented by any one of the general formulas (1) to (3) will be described.
It can be synthesized according to a conventionally known method for synthesizing triarylmethane dyes. For example, a compound of the general formulas (1) to (2) can be obtained by condensation reaction of 2 equivalents of an aniline derivative and 1 equivalent of a benzaldehyde derivative, followed by oxidation. The compound represented by the general formula (3) may be synthesized in the same manner by condensing an aniline derivative and / or a benzaldehyde derivative into which a substituent is introduced in advance, or a triarylmethane compound is synthesized by a known synthesis method. Then, a substituent may be introduced by an addition reaction or the like. In the latter case, a commercially available triarylmethane compound may be used.
Since the manufacturing method of the compounds represented by the general formulas (1) to (3) can be synthesized by a known manufacturing method, it is not limited to the above method.
General synthesis method of the compound represented by the general formula (1)

  General synthesis method of the compound represented by the general formula (2)

(Coloring composition)
The colored composition of the present invention contains at least a compound represented by any one of the above general formulas (1) to (3).
The coloring composition of this invention may contain any one among the compounds represented by either of General formula (1)-(3), and may contain multiple. Moreover, only 1 type may be used for the compound represented by each general formula, and it may use it in combination of 2 or more type.
Although the coloring composition of this invention may contain only the compound represented by either of General formula (1)-(3) as a coloring agent, in the range which does not impair the effect of this invention. Furthermore, other colorants may be contained. Examples of the colorant that may be used in combination include known dyes such as dyeing notes (24th edition issued by Color Dyeing Co., Ltd.) Etc.

  The content of the compound represented by any one of the general formulas (1) to (3) in the coloring composition is preferably 1 to 20% by mass, and more preferably 1 to 10% by mass. By setting the content of the compound represented by any one of the general formulas (1) to (3) contained in the coloring composition to 1% by mass or more, the printing density of the ink on the recording medium when printing is performed. The image density can be improved and the required image density can be secured. Moreover, when it uses for an inkjet method by making the total amount of the compound represented by either of General formula (1)-(3) contained in a coloring composition into 20 mass% or less, it is a coloring composition. As a result, it is possible to improve the discharge performance and to obtain an effect such that the inkjet nozzle is not easily clogged.

  The colored composition in the present invention generally contains a solvent in addition to the compound represented by any one of the general formulas (1) to (3). The type and amount of the solvent vary depending on the type of the compound represented by any one of the general formulas (1) to (3), the dyeing concentration, and the dyeing method, but the amount of the solvent is 40 mass with respect to the total amount of the coloring composition. % Or more is preferable. As a solvent, it is preferable to contain water, and it is preferable to contain 50 mass% or more of water with respect to the solvent whole quantity. Moreover, it is preferable to contain 30 mass% or more of water with respect to the whole quantity of a coloring composition.

  Moreover, it is preferable that 10 mol% or more of all cations except the cation of the cationic chromophore portion contained in the colored composition of the present invention is lithium ions, and 25 mol% or more is lithium ions. More preferably, 50 mol% or more is lithium ion. The cationic chromophore refers to a dye mother nucleus (chromophore) having a monovalent positive charge. Specific examples are a cyanine dye mother nucleus, a triarylmethane dye mother nucleus (triarylmethane dye mother nucleus, xanthene dye mother nucleus, etc.), a diarylmethane dye mother nucleus, and the like. The lithium ion concentration in the coloring composition may be adjusted by components other than the compound represented by any one of the general formulas (1) to (3) or a salt thereof.

The recording medium for printing the colored composition of the present invention includes various fabrics, paper, coated paper coated with an ink receiving layer, a plastic film, and the like. Development of ink suitable for ink jet recording has also been performed.
The coloring composition of the present invention is used for a coloring composition for dyeing or printing on a fabric (coloring composition for dyeing or printing), an inkjet recording ink for printing on paper, a color toner, a resist for a color filter, and the like. However, it is particularly suitable as a coloring composition for dyeing or printing on fabrics.

[Coloring composition for dyeing or printing and dyeing or printing method]
The use form of the coloring composition for dyeing or printing of the present invention is not limited as long as it is a coloring composition for dyeing fibers. The dyeing method for fibers is roughly divided into a dip dyeing method and a printing method. Dipping is a process in which a dyed cloth or yarn is immersed in a dye solution in which a dye is dissolved or dispersed in a solvent, uniformly adsorbed on the fiber surface, diffused into the fiber, and dyed by bonding. is there. Textile printing is a dyeing method in which dyes or pigments are applied onto a fabric to give a pattern shape, and dyed pigments are dyed or fixed to make a dyed product with a pattern. The pattern effect is developed on the fabric to be dyed. Industrially, screen printing using a plate, roller printing, transfer printing using transfer paper, and ink-jet printing without plate making are performed.

[[Coloring composition for dip dyeing and method using the same]]
The dip dyeing comprises a step of immersing a fabric or thread in a dye solution to dye the dye, a washing step of washing away unfixed dye that is not dyed on the fiber, and a drying step. When the colorable composition of the present invention is used for dip dyeing, the colorable composition is used as a dyeing solution capable of dipping a fabric or a thread. In this case, the dyeing solution may contain a solvent, a leveling assistant, a pH adjuster, an inorganic neutral salt, a dispersant and the like in addition to the dye. In general, water is used as the solvent. As additives such as leveling assistants, known additives can be used. For example, wetting agents and penetrating agents described in pages 134 to 145 of dyeing notes, metal ion encapsulants described in pages 147 to 154 of dyeing notes, Dyeing notes described on pages 216 to 222, leveling agents described on pages 230 to 255, dyeing notes described on pages 285 to 286, and migration inhibitors described on pages 279 to 284. Dye fixing agents described in dyeing notes on pages 304 to 321; dyeing fastness improvers; and pH adjusting agents described in dyeing notes on pages 322 to 334. In order to dye the dye uniformly at a high concentration, it can be adjusted by controlling the dye concentration, dye bath pH, salt concentration, dyeing temperature, dyeing time, pressure, and liquid flow, in addition to using the additive.
In the washing step, water or hot water in the range from room temperature to 100 ° C. is generally used. The water to be washed may contain a soaping agent. By completely removing the unfixed coloring material, good results can be obtained in various water resistances such as washing fastness and sweat fastness.
Specifically, in the drying step, the washed fabric is squeezed or dehydrated and then dried or dried using a dryer, heat roll, iron, or the like.

[[Coloring composition for screen printing, roller printing, transfer printing, and printing method using the same]]
When the coloring composition of the present invention is used for screen printing, roller printing, or transfer printing, the coloring composition is used as a color paste for printing on a cloth via a plate or transfer paper.
The textile printing method of the present invention preferably includes at least the following steps (1) to (4).
(1) A step of adding a coloring composition for dyeing or printing of the present invention to a liquid containing at least a polymer compound and water and adjusting the color paste (2) Printing the color paste of (1) above on a fabric Step (3) Applying steam to the printed fabric (4) Washing and drying the printed fabric Color paste is suitable for printing on the plate, suitable for printing, dyeing, washing treatment, etc. It is preferable to satisfy the printing suitability required for the printed matter.
Therefore, for the purpose of imparting printing suitability and printing suitability, the color paste can contain a paste, a solvent, a dyeing auxiliary agent and the like in addition to the dye.
The paste is a medium for the colored composition, and a water-soluble polymer is preferably used. Examples of the water-soluble polymer include known natural water-soluble polymers such as starches, seaweeds, natural gums, cellulose derivatives, sodium alginate, protein substances, tannin substances, and lignin substances. In addition, known synthetic polymers such as polyvinyl alcohol compounds, polyethylene oxide compounds, acrylic acid-based aqueous polymers, styrene-based aqueous polymers, and maleic anhydride-based aqueous polymers are also used as the paste. For example, the paste for printing described in pages 349 to 361 of dyeing notes can be used. Further, the printing paste modifier described in Dyeing notes on pages 367 to 369 may be used in combination. Two or more kinds of pastes may be mixed and used. As the solvent, a water-soluble solvent is preferably used, and a solvent containing at least water is most preferably used.
Coloring agents such as acids and alkalis, dye solubilizers, wetting agents, hygroscopic agents, deep dyeing agents, anti-reduction agents, metal ion sealing agents, UV absorbers, dispersants, anti-dyeing agents, and discharging Agents, antiseptics, antifungal agents, antioxidants, migration inhibitors, dye fixing agents, antifoaming agents and the like.
As the dyeing assistant, known ones can be used. For example, the solubilizers and solubilizers described in the dyeing notes on pages 336 to 338, the thick dyes and leveling agents described in the dyeing notes on pages 339 to 345, Penetration agent, antifoaming agent described in dyeing notes on pages 346 to 348, metal ion sealing agent described on dyeing notes on pages 147 to 154, dispersing agent on dyeing notes on pages 216 to 222, dyeing notes on pages 370 to 374 Dyeing notes, dyeing notes described on pages 375 to 381, dyeing notes antiseptics, antifungal agents described on pages 362 to 363, migration inhibitors described on dyeing notes on pages 279 to 284, dyeing notes 426 Examples thereof include dye fixing agents described on pages 429 to 429, wet fastness improvers described in JP-A-6-166969, and light fastness improvers described in US Pat. No. 5,336,443.
A dyeing assistant is added to a paste solution in which a paste is dissolved or dispersed in a solvent, and a dye solution in which a dye is dissolved or dispersed in a solvent is added and stirred to prepare a color paste (step of preparing a color paste).

  In the printing method, unlike the dip dyeing method, after the color paste is printed on the fabric (the step of printing the color paste on the fabric), the color material printed on the fabric is dyed onto the fiber. This is called a coloring process, and there are a method using heated air, a method using normal pressure saturated steam and superheated steam, and a method using normal pressure saturated steam is preferred. In the present invention, it is preferable to perform a step of applying steam to the printed fabric. In the process of applying steam to the printed fabric, the temperature and time for treatment with steam vary depending on the type of the colored composition and the type of the fabric, but the temperature is preferably 90 ° C to 140 ° C, more preferably 100 ° C to 108 ° C. preferable. The time is preferably 1 to 60 minutes, more preferably 1 to 30 minutes. After the process of applying steam to the printed fabric, a printed product is obtained through a washing process and a drying process similar to the dip dyeing. In the present invention, the fabric preferably contains polyamide.

[[Coloring composition for inkjet printing and method using the same]]
When the coloring composition of the present invention is used in inkjet printing, the coloring composition is preferably used as an ink for inkjet printing. Compared with the conventional textile printing method, the inkjet textile printing method has the advantage of being able to quickly form an image with excellent gradation, and has the advantages of shortening the delivery time, dealing with small-lot and multi-product production, and eliminating the need for a plate making process. Yes. Further, since only a necessary amount of ink is used as a formed image, it can be said that this is an excellent image forming method having environmental advantages such as less waste liquid compared to the conventional method.
Ink for inkjet printing, when the viscosity of the ink is increased by evaporation of water or an aqueous organic solvent from the nozzle tip, or when a solid dye is deposited, the nozzle of the inkjet head is clogged. There is a need for inks with higher color development than textile printing. In addition, it is required to impart ink suitability such as ink storage stability and ejection stability, image quality such as light resistance, water resistance, and chlorine resistance, printing suitability such as bleeding prevention and contamination prevention, and the like.
“Inkjet ink” is ink used in a printing machine (inkjet printer) having a mechanism for ejecting ink from an inkjet nozzle to form an image. Among the inks for inkjet, the ink used for textile printing using inkjet is called ink for inkjet textile printing.
The inkjet textile printing method of the present invention preferably includes the following steps (11) to (14).
(11) A step of applying a paste containing at least a polymer compound and water to the fabric (12) A step of printing the ink-jet ink of the present invention on the fabric by the ink-jet method (13) A step of applying steam to the printed fabric ( 14) The process of washing and drying the printed fabric The inkjet printing method tends to cause clogging of the nozzle when the color paste used in the conventional printing method is used. It is preferable to perform a pretreatment step (a step of applying a paste containing at least a polymer compound and water to the fabric). By performing the pretreatment step, the fabric can be easily handled. Specifically, a pretreated fabric is obtained by attaching a paste solution containing a paste, a solvent and a hydrotropic agent to the fabric and drying it. In the present invention, the fabric preferably contains polyamide.
As the paste, the same paste as used in screen printing or the like can be used. As the solvent, a water-soluble solvent is preferably used, and a solvent containing at least water is most preferably used.
The hydrotropic agent generally serves to increase the color density of an image when the fabric to which the ink composition is applied is heated under steam. For example, urea, alkylurea, ethyleneurea, propyleneurea, thiourea, guanidate, halogen-valent tetraalkylammonium and the like are usually used. Moreover, a well-known thing can also be used and the dye fixing agent of dyeing | staining notes pp. 426-429, etc. are mentioned. The content of the hydrotropic agent with respect to the total solid content of the paste solution is preferably 0.01% by mass to 20% by mass.
The paste solution may further contain a pH adjuster, an aqueous (water-soluble) metal salt, a water repellent, a surfactant, a migration inhibitor, a microporous forming agent, and the like as necessary. As these additives, known ones can be used. For example, the solubilizers and solubilizers described in dyeing notes on pages 336 to 338, and the deep dyes and leveling agents described in dyeing notes on pages 339 to 345 are used. , Penetrating agent, metal ion sealing agent described in dyeing notes on pages 147 to 154, dyeing prevention agent on dyeing notes on pages 370 to 374, discharge agent on dyeing notes on pages 375 to 381, dyeing notes on pages 362 to 363 Preservatives, antifungal agents described in pages, migration inhibitors described in dyeing notes on pages 279 to 284, microporous forming agents described in JP-A-7-316991, wet fastness improvers described in JP-A-6-166969, Examples include light fastness improvers described in US Pat. No. 5,336,443. Also, those described in JP-A-2013-209786, paragraphs [0096] to [0101] can be used.
In the pretreatment, it is preferable to put the paste solution in the range of 5% to 150%, preferably 10% to 130%.
In the pretreatment, a method for incorporating the respective paste solutions into the fabric is not particularly limited, and examples include a usual dipping method, pad method, coating method, screen method, spray method, transfer method, and ink jet method. .

Next, the pretreated fabric is printed using an inkjet ink.
An ink for inkjet printing is prepared by dissolving and / or dispersing a compound (may be a mixture) represented by any one of the above general formulas (1) to (3) in an oleophilic medium or an aqueous medium. can do. Preferably, the ink uses an aqueous medium. Therefore, for the purpose of imparting appropriate ink, proper printing, and image fastness, the ink-jet printing ink can contain a solvent and a surfactant in addition to the dye.
As the solvent, the type of substituent in the compound represented by any one of the general formulas (1) to (3) used, the type of solvent component used for producing the colored composition, the type of fabric to be dyed, etc. Preferably, an aqueous medium, more preferably water or a water-soluble organic solvent is used. The solvent is prepared by dissolving and / or dispersing the compound represented by any one of the above general formulas (1) to (3) in a lipophilic solvent or a water-soluble solvent. Can do.
The organic solvent that can be contained in the ink-jet printing ink of the present invention is preferably an aqueous organic solvent. For example, in addition to polyhydric alcohols such as diethylene glycol and glycerin, amines, monohydric alcohols, polyhydric alcohols can be used. Examples thereof include alkyl ethers. Moreover, each compound mentioned as an illustration of the water-miscible organic solvent of Paragraph [0076] of Unexamined-Japanese-Patent No. 2002-371079 is suitable.

The content of the organic solvent in the ink for inkjet printing of the present invention is preferably 10% by mass or more and 60% by mass or less with respect to the total mass of the ink for inkjet printing.
As the surfactant, any of cationic, anionic, amphoteric and nonionic surfactants can be used. Examples of the cationic surfactant include aliphatic amine salts and aliphatic quaternary ammonium salts. Examples of the anionic surfactant include fatty acid soap, N-acyl-N-methylglycine salt, and the like. Examples of amphoteric surfactants include carboxybetaine type, sulfobetaine type, aminocarboxylate, imidazolinium betaine and the like. Examples of the nonionic surfactant include polyoxyethylene alkyl ether, acetylene glycol, acetylene alcohol and the like. Surfactants listed as examples of the surface tension adjusting agent described in paragraph [0073] of JP-A-2002-371079, and surfactants described in JP-A-2008-266466 and JP-A-11-269939 are preferably used. . Moreover, the ink for inkjet textile printing of this invention can contain another additive in the range which does not impair the effect of this invention as needed. Other additives include, for example, drying inhibitors (wetting agents), anti-fading agents, emulsion stabilizers, penetration enhancers, ultraviolet absorbers, infrared absorbers, antiseptics, antifungal agents, pH adjusters, surface tension. Known additives such as a regulator, an antifoaming agent, a viscosity modifier, a dispersant, a dispersion stabilizer, a rust inhibitor, a chelating agent, a reducing agent, an antioxidant, an antistatic agent, and a fluorescent brightening agent are included. . These various additives can be directly added to the ink liquid in the case of water-soluble ink. When an oil-soluble dye is used in the form of a dispersion, it is generally added to the dispersion after the preparation of the dye dispersion, but it may be added to the oil phase or the aqueous phase at the time of preparation. When making the oil-soluble dye into the form of a dispersion, a dispersant can be used. As the dispersant, for example, the dispersant described in pages 216 to 222 of the dyeing note can be used. As the anti-drying agent, anti-fading agent, ultraviolet absorber, anti-mold agent, pH adjuster, surface tension adjuster, antifoaming agent and chelating agent, those described in JP-A-2014-5462 [0224] to [0231] are applied. it can. Further, a wet fastness improving agent described in JP-A-6-166969 and a light fastness improving agent described in US Pat. No. 5,336,443 can also be contained. The penetration accelerator can be suitably used for the purpose of better penetrating and fixing the ink jet ink inside the fiber. As the penetration enhancer, known ones can be used. For example, wetting agents, penetrating agents, leveling agents, loose printing agents, ethanol, isopropanol, butanol, di (tri) ethylene described in dyeing notes on pages 223 to 255. Alcohols such as glycol monobutyl ether and 1,2-hexanediol, sodium lauryl sulfate, sodium oleate, nonionic surfactants, branched polyhydric alcohols described in WO10 / 109867 and JP-A-6-57644, etc. it can. If these are contained in the ink in an amount of 5 to 35% by mass, they are usually effective, and it is preferable to use them in a range of addition amounts that do not cause bleeding after dyeing and back leakage of the ink.
When the compound represented by any one of the general formulas (1) to (3) is dispersed in an aqueous medium, it can be dispersed by the method described in JP 2014-5462 A [0232] to [0233].
The ink for inkjet textile printing of the present invention preferably has a viscosity of 30 mPa · s or less. The surface tension is preferably 25 mN / m or more and 70 mN / m or less. Viscosity and surface tension are various additives such as viscosity modifiers, surface tension modifiers, specific resistance modifiers, film modifiers, UV absorbers, antioxidants, antifading agents, antifungal agents, and rust inhibitors. It can be adjusted by adding a dispersant and a surfactant.
The ink for inkjet textile printing of the present invention can be used not only for forming a single color image but also for forming a full color image. In order to form a full color image, a magenta hue ink, a cyan hue ink, and a yellow hue ink can be used, and a black hue ink may be further used to adjust the hue. Examples of the applicable dye include those described in JP 2014-5462 A [0237] to [0240].

  Fabrics printed by the ink jet method are dried and then subjected to a color development step, a washing step, and a drying step in the same manner as other printing methods to obtain a printed matter. A preferred method of the color development step to the drying step is the same as that for screen printing.

  The fabric used in the present invention may be pretreated if necessary. In the ink jet textile printing method, the treatment may be performed before or after the paste is attached to the fabric. Moreover, you may add and use a pre-processing agent to the paste solution adhering before dyeing | staining. Specifically, JP-A-2002-339268, JP-A-2000-54277, JP-A-7-150482, JP-A-2008-174865, JP-A-2012-154006, JP-A-2012-12730, JP-A-2-68372, JP-B-63. -31594, JP 2002-275769, JP 2001-81680, JP 2004-68208, JP 11-43873, JP 2007-217829, JP 2006-83495, JP 2005-154936, JP 2002-105875. JP-A No. 2002-348786, JP-A No. 11-81163, JP-A No. 2-61183, JP-A No. 2001-295186, JP-A No. 2004-60073, JP-A No. 2003-113583, JP-A No. 8-100399, JP-A No. 2-53976, Open 2000-226781, JP 004-292989, JP 2002-249991, JP 2002-363872, JP-A 6-341070, JP 2004-197237, JP 2008-223192, and the like pre-treatment method of JP 2011-179130 publication.

  The dyed fabric of the present invention may be subjected to flame retardant treatment described in JP-A No. 62-257464, plasma treatment described in JP-A No. 2-47378, etc., JP-A No. 60-94678, JP-A No. Light fastness, wet resistance, chlorine resistance, and other fastness improving treatments described in 2002-266236, Japanese Patent Application Laid-Open No. 2007-32247, Japanese Patent Application Laid-Open No. 3-287873, Japanese Patent Application Laid-Open No. 2004-131919, and the like may be performed. These treatments may be performed before dyeing or after dyeing.

The method for inkjet printing using the colored composition of the present invention is not limited as long as it includes a step of ejecting ink onto a fabric using an inkjet apparatus. For example, JP-A-9-296379, JP-A-11-43873, JP-A-7-70953, JP-A-7-197384, JP-A-7-70950, JP-A-3-104977, JP-A-2007-303046, JP-A-2007-313717, Japanese Laid-Open Patent Publication No. 2008-248437 and the like disclose an ink jet printing method.
Further, as an apparatus used for inkjet printing, any inkjet apparatus can be used. For example, JP-A-3-45774, JP-A-2001-277656, JP-A-2000-290882, JP-A-2001-18390, JP-A-2010-83040, and JP-A-2011-31418 are known.

[Colored compound form and fabric to be dyed]
The compound represented by any one of the above general formulas (1) to (3) of the present invention is used for the purpose of dyeing or printing a fabric as a dye. Various types of dyes can be prepared by changing the type of substituent of the compound represented by any one of the general formulas (1) to (3). When the compound represented by any one of the general formulas (1) to (3) contains at least one acidic group such as a sulfo group or a carboxyl group, as an acidic dye, protein fibers such as silk and wool, 6 nylon Polyamide fiber such as 66 nylon can be dyed. When the compound represented by any one of the general formulas (1) to (3) is an oil-soluble compound insoluble in water, it is common to dye a hydrophobic fiber such as polyester as a disperse dye, Acrylic fibers and polyamide fibers can also be dyed. When the compound represented by any one of the general formulas (1) to (3) contains at least one basic group such as an amino group, an acrylic fiber can be dyed as a cationic dye. When the compounds represented by the general formulas (1) to (3) contain at least one group that reacts with fibers, cellulose fibers such as cotton and polyamide fibers can be dyed as reactive dyes. Specific examples of the group that reacts with the fiber include a chlorotriazinyl group, a chloropyrimidyl group, a vinylsulfonyl group, a chloroethylsulfonyl group, a sulfatoethylsulfonyl group, and a thiosulfatoethylsulfonyl group.

  As the fabric, a fabric made of one type of fiber may be used, or a composite fiber made of two or more types of fibers may be used.

  The compounds represented by the general formulas (1) to (3) of the present invention are preferably acid dyes, and particularly have a high dyeing property when dyeing polyamide fibers, and Various performances as a dyed fabric such as light resistance, water resistance and chlorine resistance can be improved.

As a preferable polyamide fiber as a fabric to be dyed, a polyamide fiber may be used as long as it contains polyamide fiber, and a fabric made of polyamide alone or a fabric made of composite fiber may be used. Examples of the composite fiber include fibers described in JP-A-2008-202210, JP-A-2006-322131, JP-A-2007-100200, and the like. Among polyamide fibers, fibers containing 6 nylon and 66 nylon are preferable.
The fiber used is preferably a fabric, but the same effect can be obtained even if the yarn is dyed.

  EXAMPLES Hereinafter, although an Example is shown and this invention is demonstrated in detail, this invention is not limited to these Examples at all. Unless otherwise specified, “%” and “parts” in the examples are% by mass and parts by mass.

(Synthesis example)
(Synthesis of Compound 1)
According to the method of JP-A-8-333517, 1 equivalent of 2,6-dimethylbenzaldehyde, 2 equivalents of N- (m-sulfobenzyl) -N-ethylaniline, 2.5 L / mol of methanesulfonic acid were used for the reaction substrate synthesis. It melt | dissolved in 2 times amount of water, it condensed, and the depositing solid was wash | cleaned with isopropanol, and the intermediate body A was obtained. Next, 1 equivalent of Intermediate A was oxidized with 3 equivalents of ammonium thiosulfate and neutralized with lithium hydroxide to obtain Compound 1. The ESI-mass spectrum of the obtained crystal was measured, and a peak of 695 ([M-Li] ⁻ , 100%) was confirmed.

(Synthesis of Comparative Compound 1)
Comparative compound 1 was synthesized in the same manner as compound 1 except that 2,6-dimethylbenzaldehyde was changed to 2-methylbenzaldehyde. The ESI-mass spectrum of the obtained crystal was measured, and 681 peak ([M-Li] ⁻ , 100%) was confirmed.

(Synthesis of Compound 19)
Similar to the synthesis of Compound 1, 1 equivalent of o-sulfobenzaldehyde, 2 equivalents of N- (2,4,6-trimethylphenyl) aniline, 2.5 L / mol of methanesulfonic acid is twice the amount of reaction substrate synthesis. The product was dissolved in water and subjected to a condensation reaction, and the precipitated solid was washed with isopropanol to obtain Intermediate B. Next, 1 equivalent of Intermediate B is oxidized with 3 equivalents of ammonium thiosulfate, chlorosulfonated according to the method of Japanese Patent Application Laid-Open No. 2014-5462, then alkaline hydrolysis with sodium hydroxide, and further neutralized with aqueous hydrochloric acid. did. The neutralized product was passed through a column packed with a cation exchange resin (lithium foam) and concentrated to obtain Compound 19. The ESI-mass spectrum of the obtained crystal was measured, and 747 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Comparative Compound 2)
Comparative compound 2 was synthesized in the same manner as compound 19 except that N- (2,4,6-trimethylphenyl) aniline was changed to diphenylaniline. ESI-mass spectrum measurement of the obtained crystal was performed, and 663 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 21)
Similar to the synthesis of Compound 1, 1 equivalent of 2,6-dimethylbenzaldehyde, 2 equivalents of N- (2,4,6-trimethylphenyl) aniline and 2.5 L / mol of methanesulfonic acid were used for the reaction substrate synthesis. It melt | dissolved in double amount of water, it condensed, and the depositing solid was wash | cleaned with isopropanol. Next, an oxidation reaction was performed in the same manner as in the synthesis of Compound 19, and the salt was exchanged with potassium chloride to obtain Intermediate 21A.
The obtained intermediate 21A was chlorosulfonated according to the method of Japanese Patent Application Laid-Open No. 2014-5462, then alkaline hydrolysis with sodium hydroxide, and further neutralized with aqueous hydrochloric acid. Compound 21 was synthesized by passing the neutralized product through a column packed with an intoxicating ion exchange resin (lithium foam) and concentrating it. An ESI-mass spectrum of the obtained crystal was measured, and a peak of 695 ([M-Na] ⁻ , 100%) was confirmed.

(Synthesis of Compound 34)
Commercial Acid Blue 9 was chlorosulfonated with phosphorus oxychloride to synthesize Intermediate C. 1 equivalent of Intermediate C was reacted with 2 equivalents of 2,4-dimethoxyaniline in dimethylacetamide to obtain Intermediate D. This was further chlorosulfonylated in the same manner as in the synthesis of Compound 19, followed by alkaline hydrolysis and neutralization with lithium hydroxide to give Compound 34. The ESI-mass spectrum of the obtained crystal was measured, and 1177 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 30)
Commercially available Acid Blue 7 was dissolved in dimethylacetamide, 2,4-dimethoxyaniline was added, and Intermediate E was synthesized. This was subjected to chlorosulfonylation, followed by alkaline hydrolysis and neutralization in the same manner as in the synthesis of Compound 19, to give Compound 30. The ESI-mass spectrum of the obtained crystal was measured, and 978 peaks ([M-3Li + 2H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 29)
Compound 29 was obtained in the same manner as Compound 30 except that 2,4-dimethoxyaniline was changed to 4-amino-2,6-ditertbutylphenol. ESI-mass spectrum measurement of the obtained crystal was performed, and 966 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 32)
Commercially available Acid Blue 7 was chlorosulfonylated with phosphorus oxychloride to synthesize Intermediate F. 1 equivalent of glycine was reacted in dimethylaldehyde with respect to the intermediate F, then 1.2 equivalents of thionyl chloride was added dropwise, and the temperature was gradually raised to 23 ° C. and stirred. After confirming the completion of the reaction, a solution of 2,4-dihydroxybenzophenone dissolved in dimethylacetamide was added dropwise, and then triethylamine was added dropwise in the same manner. The reaction solution was stirred at 90 ° C., and after confirming the completion of the reaction, extraction with ethyl acetate, alkaline hydrolysis with lithium hydroxide, and neutralization further gave Compound 32. The ESI-mass spectrum of the obtained crystal was measured, and 1080 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 37)
According to the method of JP-A-8-333517, 1 equivalent of 2,4-disulfobenzaldehyde, 2 equivalents of N- (p-nitrobenzyl) -N-ethylaniline, 2.5 L / mol of methanesulfonic acid were synthesized as a reaction substrate. The product was dissolved in twice the amount of water and subjected to a condensation reaction, and the precipitated solid was washed with isopropanol to obtain Intermediate G. Next, 1 equivalent of intermediate G was oxidized with 3 equivalents of ammonium thiosulfate and neutralized with lithium hydroxide to give compound 37. An ESI-mass spectrum of the obtained crystal was measured, and a peak of 757 ([M-Li] ⁻ , 100%) was confirmed.

(Synthesis of Compound 31)
Compound 31 was obtained in the same manner as Compound 30, except that 2,4-dimethoxyaniline was changed to 4-amino-2,2,6,6, -tetrapiperidine. ESI-mass spectrum measurement of the obtained crystal was performed, and 966 peaks ([M-2Li + H] ⁻ , 100%) were confirmed.

(Synthesis of Compound 43)
Compound 43 was obtained in the same manner as Compound 30 except that 2,4-dimethoxyaniline was changed to sodium 3-mercaptopropanesulfonate. An ESI-mass spectrum of the obtained crystal was measured, and a peak of 901 ([M-3Li + 2H] ⁻ , 100%) was confirmed.

(Synthesis of Compound 44)
After commercially available Acid Blue 9 was chlorosulfonated according to the method of Japanese Patent Application Laid-Open No. 2014-5462, 2 equivalents of 2-amino-4,6-dichloropyrimidine were added, and 2 equivalents of 2,5-dimethoxyaniline were added, Body J was synthesized. The compound 44 was further chlorosulfonated, alkali hydrolyzed with lithium hydroxide, and further neutralized to obtain Compound 44. The ESI-mass spectrum of the obtained crystal was measured, and the peak of 1431 ([M-2Li + H] ⁻ , 100%) was confirmed.

(Synthesis of Compound 20)

2,4,6-Trimethylaniline 30 g, bromobenzene 34 g, t-butoxy sodium 39 g, and toluene 200 mL were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 210 mg of palladium acetate and 45 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 6 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 21 g of intermediate 20C.
Intermediate 20C (16 g), 4-formylbenzene-1,3-disulfonic acid disodium (12 g) and methanesulfonic acid (80 mL) were placed in a flask and stirred at 100 ° C. for 6 hours. The obtained reaction solution was poured into 500 mL of ice water, and the crystals of the obtained intermediate 20B were collected by filtration (20 g).
9 g of intermediate 20B, 3.4 g of chloranil, and 200 mL of methanol were mixed and stirred at 50 ° C. for 3 days. Crystals obtained by returning to room temperature were collected by filtration to obtain 7 g of Intermediate 20A.
Intermediate 20A (5 g) and sulfuric acid (20 mL) were added and stirred while cooling. To this, 25 mL of 25% fuming sulfuric acid was added dropwise over 4 hours so that the internal temperature did not exceed 5 ° C. The reaction solution was poured into 200 g of ice, and the precipitated crystals were collected by filtration. The crystals were dissolved in methanol, neutralized with lithium acetate, and purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 1 g of compound 20. Solution absorption spectrum of compound 20, λmax = 612 nm (aqueous solution)

(Synthesis of Compound 51)

  Intermediate 20A (5 g) and sulfuric acid (25 mL) were added and stirred at 50 ° C. for 4 hours. The reaction solution was poured into 80 g of ice, and the precipitated crystals were collected by filtration. The crystals were dissolved in methanol, neutralized with lithium acetate, and purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 2 g of compound 51. Solution absorption spectrum of compound 51, λmax = 613 nm (aqueous solution)

(Synthesis of Compound 56)

In the same manner as in the synthesis of Intermediate 20C, the reaction was carried out by replacing bromobenzene with 2-bromotoluene to obtain Intermediate 56C.
In the same manner as the synthesis method of the intermediate 20B, the reaction was performed by changing the intermediate 20C to the intermediate 56C to obtain an intermediate 56B.
In the same manner as the synthesis method of the intermediate 20A, the reaction was performed by changing the intermediate 20B to the intermediate 56B to obtain an intermediate 56A.
In the same manner as in the synthesis of compound 51, the reaction was carried out by changing intermediate 51A to intermediate 56A to obtain compound 56.
Solution absorption spectrum of compound 56, λmax = 616 nm (aqueous solution)

(Synthesis of Compound 58)

In the same manner as in the synthesis method of Intermediate 20C, 2,4,6-trimethylaniline was replaced with 2,6-dimethylaniline, and the reaction was performed to obtain Intermediate 58C.
In the same manner as in the synthesis of intermediate 56B, the reaction is performed by changing intermediate 56C to intermediate 58C and 4-formylbenzene-1,3-disulfonic acid disodium to sodium sulfobenzaldehyde to obtain intermediate 58B. It was.
In the same manner as the synthesis method of the intermediate 56A, the reaction was performed by changing the intermediate 56B to the intermediate 58B to obtain an intermediate 58A.
The reaction was conducted in the same manner as in the synthesis method of Compound 56 except that Intermediate 56A was replaced with Intermediate 58A to obtain Compound 58.
Solution absorption spectrum of compound 58, λmax = 603 nm (aqueous solution).

(Synthesis of Compound 59)

In the same manner as the synthesis method of the intermediate 20A, the reaction was performed by changing the intermediate 20B to the intermediate B to obtain an intermediate 59A.
The reaction was performed in the same manner as in the synthesis of Compound 51, except that Intermediate 51A was replaced with Intermediate 59A to obtain Compound 59.
Solution absorption spectrum of compound 59, λmax = 605 nm (aqueous solution).

(Synthesis of Compound 62)

In the same manner as in the synthesis of Intermediate 20C, 2,4,6-trimethylaniline was replaced with 2,6-didiethyl-4-methylaniline, and the reaction was performed to obtain Intermediate 62C.
In the same manner as the synthesis method of the intermediate 58B, the reaction was performed by changing the intermediate 58C to the intermediate 62C to obtain an intermediate 62B.
In the same manner as the synthesis method of the intermediate 56A, the reaction was performed by changing the intermediate 56B to the intermediate 62B to obtain an intermediate 62A.
The reaction was conducted in the same manner as in the synthesis method of Compound 56, except that Intermediate 56A was replaced with Intermediate 62A, and Compound 62 was obtained.

(Synthesis of Compound 65)

In the same manner as the synthesis method of the intermediate 58B, the reaction was performed by changing the intermediate 58C to the intermediate 56C to obtain an intermediate 65B.
In the same manner as the synthesis method of the intermediate 56A, the reaction was performed by changing the intermediate 56B to the intermediate 65B to obtain an intermediate 65A.
The reaction was conducted in the same manner as in the synthesis method of Compound 56 except that Intermediate 56A was replaced with Intermediate 65A to obtain Compound 65.
Solution absorption spectrum of compound 65, λmax = 611 nm (aqueous solution).

(Synthesis of Compound 67)

15 g of 25% by mass of fuming sulfuric acid was added dropwise to 15 g of sulfuric acid. This solution was cooled with ice water, and 3 g of intermediate 59A was added thereto. After stirring at 5 ° C. or lower for 3 hours, the reaction solution was poured into 150 g of ice. The obtained solution was neutralized with 50% aqueous lithium hydroxide to pH 5.5, and then the solvent was distilled off with an evaporator. The obtained crystals are dispersed in methanol, insolubles are removed by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 0.8 g of compound 67. Obtained.
Solution absorption spectrum of compound 67, λmax = 600 nm (aqueous solution)

(Synthesis of Compound 101)

1 g of Intermediate 20A was dissolved in 100 mL of water, and the pH was adjusted to 7.0 using a 0.1 M aqueous lithium hydroxide solution. The obtained solution was purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 0.8 g of Compound 101.
Solution absorption spectrum of compound 101, λmax = 614 nm (aqueous solution).

(Synthesis of Compound 102)

1 g of the intermediate 56A was dissolved in 100 mL of water, and the pH was adjusted to 7.0 using a 0.1 M aqueous lithium hydroxide solution. The resulting solution was purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 0.7 g of Compound 102.
Solution absorption spectrum of compound 102, λmax = 618 nm (aqueous solution).

(Synthesis of Compound 103)

2,4,6-Trimethylaniline (21 g), 3-bromotoluene (24 g), t-butoxy sodium (14.4 g), and toluene (200 mL) were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 45 mg of palladium acetate and 210 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 35 g of intermediate 103A.
29 g of the intermediate 103A, 10 g of sodium 2-sulfobenzaldehyde, and 100 mL of methanesulfonic acid were placed in a flask and stirred at 100 ° C. for 12 hours. The obtained reaction solution was poured into 600 mL of ice water, and the resulting crystals were collected by filtration. The crystals were dissolved in 400 mL of isopropyl alcohol, 50 mL of triethylamine was added, and the mixture was concentrated under reduced pressure. 200 mL of acetonitrile was added to the obtained residue, and the precipitated crystals were collected by filtration to obtain 23.5 g of intermediate 103B.
10 g of intermediate 103B, 4.1 g of chloranil, 50 mL of methanol, and 2 mL of concentrated hydrochloric acid were mixed and stirred at 50 ° C. for 48 hours. The obtained crystals were collected by filtration to obtain 6 g of Intermediate 103C.
Intermediate 103C 5.1 g and concentrated sulfuric acid 50 mL were mixed and stirred at room temperature for 20 hours. The reaction solution was poured into 200 g of ice water, and the precipitated crude compound 103 was collected by filtration. The crude compound 103 was dissolved in methanol, neutralized with lithium acetate, and purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 1 g of compound 103. Solution absorption spectrum of compound 103: λmax = 627 nm, ε = 68800 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 696.2 (M-Li + 2H).

(Synthesis of Compound 104)

2,4,6-Trimethylaniline 13.2 g, 2-bromoanisole 18.7 g, t-butoxy sodium 20 g, and toluene 150 mL were added to the flask and sufficiently stirred under a nitrogen stream. To this, 90 mg of palladium acetate and 340 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The resulting organic phase was dried over sodium sulfate and concentrated. 50 mL of methanol and then 10 mL of water were added to the obtained oil, and the precipitated crystals were collected by filtration to obtain 9 g of Intermediate 104A.
Intermediate 104A (1.2 g), 4-formylbenzene-1,3-disulfonic acid disodium (0.6 g), and methanesulfonic acid (8 mL) were placed in a flask and stirred at 110 ° C. for 10 hours. The obtained reaction solution was poured into 120 mL of ethyl acetate. The organic phase was removed by decantation, 50 mL of ethyl acetate was added to the resulting gummy oil and stirred, and the resulting crystals were collected by filtration to obtain 1.2 g of intermediate 104B.
7.3 g of intermediate 104B, 3 g of chloranil, and 70 mL of methanol were mixed and stirred for 1 hour. The reaction solution was neutralized with lithium hydroxide to pH = 5 and then purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 2 g of Compound 104. Solution absorption spectrum of compound 104: λmax = 650 nm (aqueous solution). ESI-mass spectrum (Posi): 728.2 (M-Li + 2H).

(Synthesis of Compound 105)

2,2.6 g of 2,4,6-trimethyl-1,3-phenylenediamine, 15.7 g of bromobenzene, 20 g of sodium t-butoxy, and 200 mL of toluene were added to the flask and sufficiently stirred under a nitrogen stream. To this, 90 mg of palladium acetate and 340 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 10 hours. The organic substance was extracted from the obtained mixture with ethyl acetate and purified by silica gel column chromatography to obtain 11.2 g of intermediate 105A as crystals.
9.6 g of intermediate 105A, 6.6 g of disodium 4-formylbenzene-1,3-disulfonate, and 100 mL of methanesulfonic acid were placed in a flask and stirred at 110 ° C. for 5 hours. The obtained reaction solution was poured into 400 mL of saturated saline. The precipitated crystals were collected by filtration to obtain 49 g of Intermediate 105B as a wet cake (containing a large amount of sodium chloride).
15 g of wet cake of intermediate 105B, 2 g of chloranil, and 100 mL of methanol were mixed and stirred at 50 ° C. for 6 hours. The precipitated crystals were filtered, the crystals were added to 50 mL of methanol, and sodium acetate was added to neutralize to pH = 5. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). By passing through the column, 1.5 g of compound 105 was obtained. Solution absorption spectrum of compound 105: λmax = 616 nm, ε = 100900 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 698.2 (M-Li + 2H).

(Synthesis of Compound 106 and Compound 107)

3-Acetylamino-2,4,6-trimethylaniline (19.2 g), bromobenzene (20.3 g), t-butoxy sodium (20 g), and toluene (200 mL) were added to the flask and sufficiently stirred under a nitrogen stream. To this, 90 mg of palladium acetate and 340 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 10 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate and concentrated. To the concentrate was added 50 mL of n-hexane, and the precipitated crystals were collected by filtration to obtain 22 g of Intermediate 106A.
5.4 g of the intermediate 106A, 3.1 g of disodium 4-formylbenzene-1,3-disulfonate, and 50 mL of methanesulfonic acid were placed in a flask and stirred at 100 ° C. for 20 hours. The obtained reaction solution was poured into 200 mL of saturated saline. The precipitated crystals were collected by filtration to obtain 25.4 g of intermediate 106B (containing a large amount of sodium chloride).
23 g of intermediate 106B (containing a large amount of sodium chloride), 3 g of chloranil, 300 mL of methanol, and 2.5 mL of concentrated hydrochloric acid were mixed and stirred at room temperature for 6 hours. Sodium acetate was added to the reaction solution to neutralize to pH = 5. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). By passing through the column, 0.3 g of Compound 106 was obtained, and 0.3 g of Compound 107 as a by-product in which one acetyl group was hydrolyzed.
Solution absorption spectrum of compound 106: λmax = 613 nm, ε = 84200 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 782.2 (M-Li + 2H).
Solution absorption spectrum of compound 107: λmax = 614 nm, ε = 82400 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 740.2 (M-Li + 2H).

(Synthesis of Compound 108)

2,6-Diethyl-4-methylaniline (65 g), 2-chlorotoluene (50 g), t-butoxy sodium (92 g), and toluene (500 mL) were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 90 mg of palladium acetate and 340 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 100 g of intermediate 108A.
8 g of intermediate 108A, 5 g of disodium 4-formylbenzene-1,3-disulfonate, and 50 mL of methanesulfonic acid were placed in a flask and stirred at 100 ° C. for 6 hours. The obtained reaction solution was poured into 400 mL of ice water, and the crystals of the obtained intermediate 108B were collected by filtration (6 g).
5 g of intermediate 108B, 1.7 g of chloranil, 80 mL of acetone and 80 mL of methanol were mixed and stirred for 5 hours. The obtained crystals were collected by filtration to obtain 7 g of a crude product of Compound 108.
7 g of Compound 108 was dissolved in methanol, neutralized with lithium acetate, and purified by column chromatography (filler: Sephadex, developing solution: methanol) to obtain 3 g of Compound 108. Solution absorption spectrum of compound 108: λmax = 620 nm, ε = 84500 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 752.3 (M-Li + 2H).
¹ H NMR: δ = 9.08 (s, 2H), 8.18 (s, 1H), 7.61 (d, 1H), 7.17 (d, 2H), 7.11 (s, 2H) , 7.07 (s, 4H), 6.92 (d, 1H), 6.08 (d, 2H), 2.41 (q, 8H), 2.26 (s, 6H), 2.10 ( s, 6H), 1.16 (t, 12H), 400 MHz in DMSO-d6

(Synthesis of Compound 109)

18 g of 2,4,6-trimethylaniline, 25 g of 1-bromo-2-ethylbenzene, 31 g of sodium t-butoxy, and 250 mL of toluene were added to the flask and sufficiently stirred under a nitrogen stream. 30 mg of palladium acetate and 115 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu ₃ P · HBPh ₄ ) were added thereto, and the reaction solution was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 30 g of intermediate 109A.
8 g of Intermediate 109A, 5 g of disodium 4-formylbenzene-1,3-disulfonate, and 50 mL of methanesulfonic acid were placed in a flask and stirred at 100 ° C. for 6 hours. The obtained reaction solution was poured into 400 mL of ice water, and the resulting crystals of intermediate 109B were collected by filtration (17 g).
7 g of intermediate 109B, 2.3 g of chloranil, 110 mL of acetone and 110 mL of methanol were mixed and stirred for 9 hours. The obtained crystals were collected by filtration to obtain 7 g of a crude product of Compound 109.
1 g of Compound 109 was obtained by dissolving 7 g of Compound 109 in methanol and neutralizing with lithium acetate, followed by purification by column chromatography (filler: Sephadex, developing solution: methanol).
Solution absorption spectrum of compound 109: λmax = 620 nm, ε = 90900 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 724.3 (M-Li + 2H).
¹ H NMR: δ = 9.14 (s, 2H), 8.18 (s, 1H), 7.60 (d, 1H), 7.20 (s, 1H), 7.17 (d, 2H) 7.05 (s, 4H), 6.95 (s, 1H), 6.94 (d, 1H), 6.09 (d, 2H), 2.67 (q, 4H), 2.29 ( s, 6H), 2.10 (s, 12H) 1.20 (t, 6H), 400 MHz in DMSO-d6

(Synthesis of Compound 110)

After adding 3.0 g of sodium hydride (60% oil dispersion) to 50 mL of N-methylpyrrolidone and stirring for 10 minutes, 10.6 g of intermediate 20C and then 11.2 g of p-toluenesulfonic acid methyl ester were added. In addition, the reaction was stirred at 100 ° C. for 2 hours. The reaction solution was cooled to room temperature and added dropwise to water. The organic substance was extracted from the obtained mixture with ethyl acetate and purified by silica gel column chromatography to obtain 6.7 g of intermediate 110A as an oil.
5.2 g of intermediate 110A, 3.6 g of disodium 4-formylbenzene-1,3-disulfonate and 25 mL of methanesulfonic acid were mixed and stirred at 100 ° C. for 3 hours. The obtained reaction liquid was poured into 120 mL of saturated brine, and the precipitated crystals were collected by filtration to obtain 16.6 g of intermediate 110B (containing a large amount of sodium chloride).
13.7 g of intermediate 110B (containing a large amount of sodium chloride), 3.5 g of chloranil, and 100 mL of methanol were mixed, and 2 mL of concentrated hydrochloric acid was added thereto. After stirring at room temperature for 1 day, sodium acetate was added until pH = 5. Insoluble matter is removed by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then passed through a column packed with cation exchange resin (lithium foam). 4 g of compound 110 was obtained. Solution absorption spectrum of compound 110: λmax = 633 nm, ε = 108000 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 696.23 (M-Li + 2H).

(Synthesis of Compound 201)

After 6.0 g of intermediate 105A was dissolved in 240 mL of acetone and cooled to 0 ° C., 7.2 g of 3,5-di-tert-butyl-4-hydroxybenzoyl chloride was added in portions. After stirring for 30 minutes, the reaction solution was concentrated and subjected to column chromatography to obtain 8.5 g of intermediate 201B.
3.3 g of 201B, 1.4 g of disodium 4-formylbenzene-1,3-disulfonate, 30 mL of acetic acid and 2 mL of methanesulfonic acid were mixed and stirred for 3 hours. The obtained reaction solution was poured into 120 g of ice water, and the precipitated crystals were collected by filtration to obtain 6.6 g of intermediate 201C (containing a large amount of sodium chloride).
6.6 g of intermediate 201C was mixed with 2.5 g of chloranil and 100 mL of methanol and stirred at room temperature for 3 hours. Sodium acetate was added to the reaction solution to neutralize to pH = 5. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). 3.8 g of compound 201 was obtained by passing through the column. The absorption spectrum of Compound 201 in an aqueous solution is: λmax = 614, ε = 6.30 · 10 ⁴ L · mol ⁻¹ · cm ⁻¹ . ESI-mass spectrum (Posi): 112.6 (M-Li + 2H). σ = 10.08 (s, 2H), 9.66 (s, 2H), 8.18 (s, 1H), 7.78 (s, 4H), 10.08 (s, 2H), 7.63 (S, 2H), 7.48 (s, 2H), 7.34 (d, 4H), 7.17 (s, 2H), 7.10 (d, 2H), 6.97 (d, 2H) 6.11 (d, 2H), 2.18 (s, 6H), 2.15 (s, 6H), 2.01 (s, 6H), 1.42 (s, 6H), 400 MHz in DMSO- d6

(Synthesis of Compound 202)

11.0 g of intermediate 105A was dissolved in 300 mL of acetone and cooled to 0 ° C., then 9.0 g of 4-nitrobenzoyl chloride was added in portions. After stirring for 30 minutes, the reaction solution was concentrated and subjected to column chromatography to obtain 12.5 g of intermediate 202B.
6.6 g of 202B, 2.8 g of disodium 4-formylbenzene-1,3-disulfonate, 60 mL of acetic acid and 4 mL of methanesulfonic acid were mixed and stirred for 3 hours. The obtained reaction solution was poured into 120 g of ice water, and the precipitated crystals were collected by filtration to obtain 6.0 g of intermediate 202C (containing a large amount of sodium chloride).
6.0 g of intermediate 202C was mixed with 2 g of chloranil and 100 mL of methanol and stirred at 0 ° C. for 6 hours. The precipitated crystals were filtered, the crystals were added to 50 mL of methanol, and sodium acetate was added to neutralize to pH = 5. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). 2.8 g of compound 202 was obtained by passing through the column. The absorption spectrum of Compound 202 in an aqueous solution is λmax = 613 nm and ε = 8.15 · 10 ⁴ L · mol ⁻¹ · cm ⁻¹ . ESI-mass spectrum (Posi): 975.3 (M-Li + 2H). σ = 10.26 (s, 1H), 10.25 (s, 1H), 10.78 (s, 1H), 10.75 (s, 1H), 8.38 (d, 4H), 8.24 (D, 4H), 8.19 (s, 1H), 7.64 (d, 1H), 7.35 (d, 4H), 7.20 (s, 2H), 7.12 (d, 2H) 6.98 (d, 1H), 6.12 (d, 2H), 2.21 (s, 6H), 2.16 (s, 6H), 2.03 (s, 6H), 400 MHz in DMSO- d6

(Synthesis of Compound 302)

13.6 g of 1,3-dimethyl-5-methoxybenzene, 19.8 g of N-bromosuccinimide and 100 mL of acetonitrile were stirred under ice-cooling, and further stirred at room temperature for 10 hours. Water was added to the resulting reaction solution, extraction was performed with ethyl acetate, and the collected organic phase was concentrated to obtain 25 g of intermediate 302A.
18.7 g of intermediate 302A, 9.2 g of aniline, 17.3 g of t-butoxy sodium, and 200 mL of toluene were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 45 mg of palladium acetate and 200 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu3P / HBPh4) were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate and concentrated, and the obtained residue was purified by silica gel column chromatography to obtain 8.0 g of intermediate 302B.
Intermediate 302B (2.3 g), 4-formylbenzene-1,3-disulfonic acid disodium (1.6 g), acetic acid (20 mL), and methanesulfonic acid (0.5 mL) were placed in a flask and stirred at room temperature for 1 hour. The obtained reaction liquid was poured into 100 mL of acetonitrile. The precipitated crystals were collected by filtration to obtain Intermediate 302C. The total amount of the obtained intermediate 302C was mixed with 1.5 g of chloranil and 100 mL of methanol and stirred at room temperature for 1 hour. Sodium acetate was added to the reaction solution to neutralize to pH = 5. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). By passing through the column, 0.8g of compound 302 was obtained. The ESI-MS (positive) of the obtained compound was 701.2 (M-Li + 2H). The absorption spectrum in the aqueous solution was λmax = 614 nm and ε = 9.56 · 10 ⁴ L · mol ⁻¹ · cm ⁻¹ .

(Synthesis of Compound 303)

J. et al. Med. Chem. , 1999, 43, 4485, and the intermediate 303A was synthesized.
Intermediate 302A (4.5 g), bromobenzene (4.3 g), t-butoxy sodium (5.3 g), and toluene (50 mL) were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 45 mg of palladium acetate and 200 mg of tri-t-butylphosphonium / tetraphenylborate complex (tBu3P / HBPh4) were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate and concentrated, and the obtained residue was purified by silica gel column chromatography to obtain 5.5 g of intermediate 303B.
Intermediate 303B (3.1 g), 4-formylbenzene-1,3-disulfonic acid disodium (2.0 g), acetic acid (25 mL), and methanesulfonic acid (0.5 mL) were placed in a flask and stirred at room temperature for 3 hours. The obtained reaction solution was poured into 300 mL of ethyl acetate. The precipitated crystals were collected by filtration to obtain Intermediate 303C. The total amount of the obtained intermediate 303C was mixed with 4.0 g of chloranil and 100 mL of methanol, and stirred for 10 minutes under reflux. The reaction solution was cooled to room temperature and neutralized to pH = 5 by adding sodium acetate. Solids are removed from the resulting mixture by filtration, and the resulting solution is purified by column chromatography (filler: Sephadex, developing solution: methanol), and then filled with a cation exchange resin (lithium foam). By passing through the column, 0.2g of compound 303 was obtained. The obtained compound had an ESI-MS (positive) of 729.2 (M-Li + 2H). The absorption spectrum in the aqueous solution was λmax = 613 nm and ε = 9.00 · 10 ⁴ L · mol ⁻¹ · cm ⁻¹ .

(Synthesis of Compound 401)

9.0 g of 2,6-diisopropylaniline, 6.3 g of 2-chlorotoluene, 11 g of t-butoxy sodium, and 75 mL of toluene were added to the flask and sufficiently stirred under a nitrogen stream. To this, 12 mg of palladium acetate and 43 mg of 1,3-bis (2,6-diisopropylphenyl) imidazolium chloride were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 12 g of intermediate 401A.
12 g of intermediate 401A, 7 g of disodium 4-formylbenzene-1,3-disulfonate, and 60 mL of methanesulfonic acid were placed in a flask and stirred at 60 ° C. for 6 hours. The obtained reaction solution was poured into 300 mL of ice water, and the crystals of the obtained intermediate 401B were collected by filtration (6 g).
5 g of intermediate 401B, 1.7 g of chloranil, and 80 mL of methanol were mixed and stirred for 5 hours. The obtained crystals were collected by filtration to obtain 5 g of a crude product of compound 108.
5 g of the crude compound 401 was dissolved in methanol, neutralized with sodium acetate, purified by column chromatography (filler: Sephadex, developing solution: methanol), and then cation exchange resin (lithium foam). Was passed through a column packed with 3 to obtain 3 g of compound 401. Solution absorption spectrum of compound 108: λmax = 618 nm, ε = 71200 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 782.3 (M-Li + 2H).
¹ H NMR: δ = 8.64 (s, 1H), 7.96 (d, 1H), 7.42-7.17 (m, 10H), 6.18 (d, 2H), 2.98 ( dt, 4H), 2.33 (s, 6H), 1.20 (t, 12H) 1.11 (t, 12H), 400 MHz in MeOH-d4

(Synthesis of Compound 402)

24 g of 2,6-dimethylaniline, 25 g of 2-chlorotoluene, 42 g of sodium t-butoxy and 300 mL of toluene were added to the flask, and the mixture was sufficiently stirred under a nitrogen stream. To this, 50 mg of palladium acetate and 170 mg of 1,3-bis (2,6-diisopropylphenyl) imidazolium chloride were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 40 g of intermediate 402A.
10 g of intermediate 402A, 13 g of disodium 4-formylbenzene-1,3-disulfonate, and 100 mL of methanesulfonic acid were placed in a flask and stirred at 60 ° C. for 6 hours. The obtained reaction solution was poured into 300 mL of ice water, and the resulting crystals of intermediate 402B were collected by filtration (6 g).
5 g of intermediate 402B, 1.7 g of chloranil, and 80 mL of methanol were mixed and stirred for 5 hours. The obtained crystals were collected by filtration to obtain 5 g of a crude product of compound 108.
5 g of the crude compound 402 was dissolved in methanol, neutralized with sodium acetate, purified by column chromatography (filler: Sephadex, developing solution: methanol), and then cation exchange resin (lithium foam). Was passed through a column packed with 3 g of Compound 402. Solution absorption spectrum of compound 108: λmax = 617 nm, ε = 73900 L · mol ⁻¹ · cm ⁻¹ (aqueous solution). ESI-mass spectrum (Posi): 670.2 (M-Li + 2H).
¹ H NMR: δ = 8.65 (s, 1H), 7.95 (d, 1H), 7.29 (m, 4H), 7.20 (m, 7H), 6.17 (d, 2H) , 2.31 (s, 6H), 2.17 (s, 12H), 400 MHz in MeOH-d4

(Synthesis of Compound 403)

2,4,6-trimethylaniline 7 g, 2-chlorotoluene 10 g, t-butoxy sodium 11 g, and toluene 75 mL were added to the flask and sufficiently stirred under a nitrogen stream. To this, 24 mg of palladium acetate and 85 mg of 1,3-bis (2,6-diisopropylphenyl) imidazolium chloride were added, and the reaction mixture was raised to 110 ° C. and stirred for 3 hours. The resulting reaction solution was cooled, poured into water, and extracted with ethyl acetate. The obtained organic phase was dried over sodium sulfate, concentrated and purified by silica gel column chromatography (developing solution: ethyl acetate / hexane = 1/20) to obtain 10 g of intermediate 403A.
10 g of the intermediate 403A, 13 g of disodium 4-formylbenzene-1,3-disulfonate, and 100 mL of methanesulfonic acid were placed in a flask and stirred at 60 ° C. for 6 hours. The obtained reaction solution was poured into 300 mL of ice water, and the resulting crystals of intermediate 403B were collected by filtration (6 g).
5 g of intermediate 403B, 1.7 g of chloranil, and 80 mL of methanol were mixed and stirred for 5 hours. The obtained crystals were collected by filtration to obtain 5 g of a crude product of compound 108.
5 g of the crude compound 403 was dissolved in methanol, neutralized with sodium acetate, purified by column chromatography (filler: Sephadex, developing solution: methanol), and then cation exchange resin (lithium foam). Was passed through a column packed with 3 g of Compound 403. Solution absorption spectrum of compound 108: λmax = 621 nm. ESI-mass spectrum (Posi): 754.3 (M-Li + 2H).
¹ H NMR: δ = 8.63 (s, 1H), 7.94 (d, 1H), 7.47 (s, 2H), 7.18 (m, 3H), 7.02 (s, 4H) , 6.18 (s, 2H), 3.20 (dt, 2H), 2.31 (s, 6H), 2.13 (s, 12H), 1.30 (dd, 12H), 400 MHz in MeOH- d4

(Synthesis of Compound 403Na and Compound 403K)

A 2 mass% compound 403 aqueous solution was prepared. This aqueous solution was passed through a column filled with a cation exchange resin (sodium foam) and then concentrated to obtain Compound 403Na.
Similarly, compound 403K was obtained using cation exchange resin (potassium foam) instead of cation exchange resin (sodium foam).

  The compounds used in the comparative examples are shown below.

[Inkjet printing evaluation]
Ink jet textile printing was performed according to the method described in JP2013-209786A.

<Pretreatment process>
About the nylon 6 jersey which is a fabric, the component shown below was mixed and the pretreatment agent A was prepared. Using the obtained pretreatment agent A, the fabric was put at a drawing ratio of 90% and naturally dried to obtain a treated fabric.

(Pretreatment agent A)
・ Glue: Guar gum [Nippon Co., Ltd., MEYPRO GUM NP] 2g
・ Hydrotropy: Urea (Wako Pure Chemical Industries) 5g
・ PH adjuster: ammonium sulfate (manufactured by Wako Pure Chemical Industries, Ltd.) 4g
・ Water 89g

<Printing process>
Next, an ink composition having the following composition was stirred for 1 hour while being heated at 30 to 40 ° C. The obtained liquid was filtered under reduced pressure through a microfilter having an average pore diameter of 0.5 μm to prepare an ink liquid for ink jet printing.
-Dye or dye mixture shown in Table 1 5% by mass
・ Glycerin [Wako Pure Chemical Industries, Ltd.] (aqueous organic solvent) 10% by mass
・ Diethylene glycol (manufactured by Wako Pure Chemical Industries, Ltd.) (aqueous organic solvent) 10% by mass
・ Orphine E1010 [manufactured by Nissin Chemical Co., Ltd.] (acetylene glycol surfactant) 1% by mass
・ 74% by mass of water

Each ink-jet printing ink solution thus obtained was set in an ink-jet printer (manufactured by Dimatics, Inc., DMP-2381), and a solid image was printed on the resulting pretreated fabric.
<Post-processing process>
After the printed fabric was dried, steam was applied in saturated steam at 100 ° C. for 20 minutes in a steam process to fix the dye to the fabric fibers. Thereafter, the fabric was washed with cold water for 1 minute and with warm water at 60 ° C. for 1 minute, and then naturally dried.

〔Evaluation method〕

1. Evaluation of light resistance Using a xenon fade meter, a dyed sample prepared according to ISO 105-B02 was irradiated with xenon light for 6 hours. Before and after irradiation with this xenon light, each sample was measured with a spectrodensitometer (X-rite 938, manufactured by X-rite), and CIE L ^* a ^* b ^* color system (International Commission on Illumination (1976)). (Or the lightness L ^* and chromaticity a ^* and b ^* in JIS standard Z8781-4: 2013) are measured, and the difference between the coordinate values L ^* , a ^* and b ^* in the L ^* a ^* b ^* color system. ΔEab was determined as the color difference between the two samples defined by ΔL ^* , Δa ^* , Δb ^* . The smaller the value, the smaller and better the behavior before and after light irradiation.
^{△ Eab = (△ L * 2} + △ a * 2 + △ b * 2) 0.5

2. Evaluation of water resistance The dyed sample prepared above was evaluated by a method based on the JIS-L0846 test method (2010 version), and judged by an evaluation method based on this test method.
A grade represents that it is so favorable that a numerical value is large.

3. Chlorine resistance evaluation The dyed sample prepared above was evaluated by a method based on the JIS-L0856 test method (2010 version), and judged by an evaluation method based on this test method.

“Li ⁺ concentration” in Table 1 represents the ratio of lithium ions with respect to all cations except for cations in the cationic chromophore portion contained in the ink in mol%.

  When the fabric was changed from nylon 6 jersey to nylon 66 jersey and the same evaluation was performed, similar results were obtained.

[Storage stability evaluation]
<Ink 1>
An ink composition having the following composition was stirred for 1 hour while being heated at 30 to 40 ° C. The obtained liquid was filtered under reduced pressure through a microfilter having an average pore diameter of 0.5 μm to prepare an ink liquid for ink jet printing.
-10% by mass of the dyes or dye mixtures shown in Tables 2 and 3
・ 90% by weight of water

<Ink 2>
-Dye or dye mixture shown in Table 2 and Table 5 5% by mass
・ Glycerin [Wako Pure Chemical Industries, Ltd.] (aqueous organic solvent) 10% by mass
・ Diethylene glycol (manufactured by Wako Pure Chemical Industries, Ltd.) (aqueous organic solvent) 10% by mass
・ Orphine E1010 [manufactured by Nissin Chemical Co., Ltd.] (acetylene glycol surfactant)
1% by mass
・ 74% by mass of water

<Ink storage test>
After the ink 1 and the ink 2 prepared above were stored at −20 ° C. for 1 week, the precipitates were observed and the viscosity was measured for the ink 1 and the ink 2, and for the ink 2, an ink jet printer (DMP, DMP −2381), ink 2 was set and a solid image was printed on plain paper. An ink having a small amount of precipitates, a small increase in viscosity, and a small amount of blur of the printed matter has good ink storage stability.

〔Evaluation method〕

1. Precipitate A: No precipitate observed B: Precipitate observed

2. Ink viscosity A: The increase in viscosity after storage is less than 10% of the viscosity before storage.
B: The increase in viscosity after storage is 10% or more and less than 25% of the viscosity before storage.
C: The increase in viscosity after storage is 25% or more of the viscosity before storage.

3. Scratch of printed matter A: There is no blur in the printed image.
B: Scratch is observed in the mark image.
C: Cannot print.

“Li ⁺ concentration” in Tables 2 and 3 represents the ratio of lithium ions to all cations, excluding cations in the cationic chromophore portion, contained in the ink in mol%.

Claims (12)

A colored composition containing a compound represented by any one of the following general formulas (1) to (3), wherein all cations except for a cation of a cationic chromophore moiety contained in the colored composition The coloring composition whose 10 mol% or more of is lithium ion.

In general formula (1), R ¹⁰¹ and R ¹⁰³ each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰² and R ¹⁰⁴ each independently represents an alkyl group, an aryl group, or a heterocyclic group. R ¹⁰⁵ and R ¹⁰⁶ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹⁰⁷ , R ¹⁰⁸ and R ¹⁰⁹ each independently represent a substituent, and X ₁₀₁ , X ₁₀₂ and X ₁₀₃ each independently represent CH or a nitrogen atom. However, at least one of X _{101 to} X ₁₀₃ represents CH. In the case where X _{101 to} X ₁₀₃ represent CH, a hydrogen atom may be removed and R ¹⁰⁹ may be bonded. n ¹⁰¹ and n ¹⁰² each independently represents an integer of 0 to 4, and n ¹⁰³ represents an integer of 0 to 3. When n ¹⁰¹ , n ^102, and n ¹⁰³ each represent an integer of 2 or more, the plurality of R ¹⁰⁷ , R ^108, and R ¹⁰⁹ may be the same or different. R ¹⁰⁷ and R ¹⁰⁸ may combine to form a ring. The compound represented by the general formula (1) has at least two ionic hydrophilic groups. The compound represented by the general formula (1) has a counter anion in the molecule.

In general formula (2), R ¹¹¹ and R ¹¹³ each independently represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. R ¹¹² and R ¹¹⁴ are each independently a halogen atom, alkyl group, cyano group, nitro group, alkoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino Represents a group, sulfamoylamino group, alkylsulfonylamino group, alkylthio group, sulfamoyl group, alkylsulfinyl group, alkylsulfonyl group, acyl group, alkoxycarbonyl group, carbamoyl group, imide group or sulfo group. R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ¹¹⁸ and R ¹¹⁹ each independently represent a substituent, and X ₁₁₁ , X ₁₁₂ and X ₁₁₃ each independently represent CH or a nitrogen atom. However, at least one of X _{111 to} X ₁₁₃ represents CH. When X _{111 to} X ₁₁₃ represent CH, a hydrogen atom may be removed and R ¹¹⁷ may be bonded. Ar ¹¹¹ and Ar ¹¹² each independently represent a benzene ring, a naphthalene ring, or a heterocyclic ring. n ¹¹¹ and n ¹¹² each independently represents an integer of 0 to 4, n ¹¹³ represents an integer of 0 to 5, and n ¹¹⁴ and n ¹¹⁵ each independently represents an integer of 0 or more. When n ¹¹¹ , n ¹¹² , n ¹¹³ , n ^114, and n ¹¹⁵ each represent an integer of 2 or more, a plurality of R ¹¹⁵ , R ¹¹⁶ , R ¹¹⁷ , R ^118, and R ¹¹⁹ are the same or different. Also good. R ¹¹⁵ and R ¹¹⁶ may combine to form a ring. The compound represented by the general formula (2) has at least two ionic hydrophilic groups. The compound represented by the general formula (2) has a counter anion in the molecule.

In General Formula (3), L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ and L ¹²⁵ each independently represent a divalent linking group, and T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ¹²⁵ are each independent. Represents a hydrogen atom or a group represented by any one of the following general formulas (T-1) to (T-8). However, at least one of T ¹²¹ , T ¹²² , T ¹²³ , T ^124, and T ¹²⁵ represents a group represented by any one of the general formulas (T-1) to (T-8). R ¹²¹ , R ¹²² and R ¹²³ each independently represent a substituent, and X ₁₂₁ , X ₁₂₂ and X ₁₂₃ each independently represent CH or a nitrogen atom. However, at least one of X _{121 to} X ₁₂₃ represents CH. If X ₁₂₁ to X ₁₂₃ represents CH, ^{R 123} or ^{(L 125)} n 126 ^{-T 125} off the hydrogen atoms may be bonded. n ¹²¹ and n ¹²² each independently represent an integer of 0 to 4, and n ¹²³ represents an integer of 0 to 5. n ¹²⁴ , n ¹²⁵ , n ¹²⁶ , n ^127, and n ¹²⁸ each independently represent 0 or 1. When n ¹²¹ , n ¹²² , and n ¹²³ each represent an integer of 2 or more, the plurality of R ¹²¹ , R ^122, and R ¹²³ may be the same or different. R ¹²¹ and R ¹²² may combine to form a ring. The compound represented by the general formula (3) has at least two ionic hydrophilic groups. The compound represented by the general formula (3) has a counter anion in the molecule.

R ²⁰¹ , R ²⁰² , R ²⁰⁴ and R ²⁰⁷ each independently represents an alkyl group. R ²⁰⁵ and R ²⁰⁸ each independently represent a hydrogen atom or an alkyl group. R ²⁰⁹ and R ²¹⁰ each independently represents a hydrogen atom, an alkyl group or an alkoxy group. R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ each independently represent a substituent. L ²⁰¹ represents a ^p103- valent linking group. R ²¹⁴ represents a hydrogen atom, an oxygen radical (—O ·), a hydroxy group, an alkyl group or an alkoxy group. R ²¹⁵ and R ²¹⁶ each independently represents an alkyl group. R ²¹⁵ and R ²¹⁶ may combine with each other to form a ring. R ²¹⁸ and R ²¹⁹ each independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group. R ²¹⁸ and R ²¹⁹ may combine with each other to form a ring. X ²⁰² represents an oxygen atom or a nitrogen atom. X ²⁰³ represents a carbon atom or a nitrogen atom. R ²¹² represents an aryl group, a heterocyclic group, or a group that is linked to X ²⁰² to form an aryl group or a heterocyclic group. Ar ²⁰¹ represents an aryl group or a heterocyclic group. p ¹⁰¹ represents 0 to ^{3, p 102} and ^{p 104} each independently represent 0 to ^{2, p 103} represents 2 or ^{3, p 106} represents 1-3. p ¹⁰⁵ and ^{p 107} each independently represent a 0-4. p ¹⁰⁸ represents the 2-3. X ²⁰¹ represents an oxygen atom or NR ²²⁰ , and R ²²⁰ represents a hydrogen atom or an alkyl group. ^However, if ^{the X 201} represents ^NH, at least one of ^{R 209} and ^{R 210} represents an alkyl group or an alkoxy group. When p ¹⁰¹ , p ¹⁰² , p ¹⁰⁴ , p ¹⁰⁵ and p ¹⁰⁷ each represent a number of 2 or more, a plurality of R ²⁰³ , R ²⁰⁶ , R ²¹¹ , R ²¹³ and R ²¹⁷ are the same or different. Also good.
In addition, each group represented by any one of the general formulas (T-1) to (T-8) has L ¹²¹ , L ¹²² , L ¹²³ , L ¹²⁴ removed from any one hydrogen atom in the formula. Or it is combined with ^L125 . However, the hydrogen atom shown as * 1 is not detached and bonded, and when R ²¹⁴ in the general formula (T-6) is a hydrogen atom, it is not detached and bonded. A compound represented by the general formula (3) is contained, and at least one of the T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ^{125 in} the general formula (3) is the general formula (T-1). ), (T-3), (T-4), (T-5) or a colored composition according to claim 1, which represents a group represented by (T-6). A compound represented by the general formula (3) is contained, and at least one of the T ¹²¹ , T ¹²² , T ¹²³ , T ¹²⁴ and T ^{125 in} the general formula (3) is the general formula (T-4). And the general formula (T-4) is represented by the following general formula (T-41), (T-42) or (T-43). Coloring composition.

R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ each independently represent a substituent. R ⁴⁰⁶ and R ⁴⁰⁷ each independently represents an aryl group or a heterocyclic group. p ⁴⁰¹ , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each independently represent 0-4, and p ⁴⁰² represents 0-5. When p ⁴⁰¹ , p ⁴⁰² , p ⁴⁰³ , p ⁴⁰⁴ and p ⁴⁰⁵ each represent a number of 2 or more, a plurality of R ⁴⁰¹ , R ⁴⁰² , R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ may be the same or different. Also good. * 1 Hydrogen atoms shown are not detached and bonded.   The colored composition according to any one of claims 1 to 3, wherein at least 25 mol% of all cations except for the cation of the cationic chromophore moiety contained in the colored composition are lithium ions.   The colored composition according to any one of claims 1 to 4, wherein the compound represented by any one of the general formulas (1) to (3) has at least three sulfo groups.   The coloring composition according to any one of claims 1 to 5 for dyeing or printing.   An ink-jet ink containing the colored composition according to claim 1. A textile printing method including the following steps (1) to (4).
(1) A step of adjusting the color paste by adding the colored composition according to claim 6 to a liquid containing at least a polymer compound and water. (2) Printing the color paste of (1) on a fabric. Step (3) Step of applying steam to the printed fabric (4) Step of washing and drying the printed fabric A textile printing method comprising the following steps (11) to (14).
(11) A step of applying a paste containing at least a polymer compound and water to the fabric. (12) A step of printing the ink-jet ink according to claim 7 on the fabric by an ink-jet method. (13) Vapor is applied to the printed fabric. (14) The process of washing and drying the printed fabric   The textile printing method according to claim 8 or 9, wherein the fabric contains polyamide.   A fabric dyed or printed with the colored composition according to claim 6.   A fabric printed by the printing method according to any one of claims 8 to 10.

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