JP2017066195A - Jet-black aqueous coating composition - Google Patents

Jet-black aqueous coating composition Download PDF

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JP2017066195A
JP2017066195A JP2015190095A JP2015190095A JP2017066195A JP 2017066195 A JP2017066195 A JP 2017066195A JP 2015190095 A JP2015190095 A JP 2015190095A JP 2015190095 A JP2015190095 A JP 2015190095A JP 2017066195 A JP2017066195 A JP 2017066195A
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JP6710033B2 (en
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由英 伊藤
Yoshihide Ito
由英 伊藤
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Aica Kogyo Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a jet-black aqueous coating composition becoming a deep black color while maintaining coating workability.SOLUTION: There is provided a jet-black aqueous coating composition which consists of an acryl resin emulsion (A), an aggregate with average particle diameter of 100 μm or more (B), a filler with average particle diameter of less than 100 μm (C), a granular pigment composition containing a nonionic surfactant additive which is an ethylene oxide addition product of C13 to C15 branched and linear alcohol of 12 to 14 pts.wt., carbon black of 75 to 85 pts.wt., at least one anionic surfactant additive based on sulfonate, sulfate, phosphonate or phosphate (D) and titanium oxide (E) with the granular pigment composition (D) of 0.3 to 3.0 pts.wt. in 100 pts.wt. of the whole jet-black aqueous coating composition.SELECTED DRAWING: None

Description

本発明は、建築物の内外壁面に意匠性を付与する一液型の水性塗材組成物であって、深い黒色と成る漆黒水系塗材組成物に関する。   The present invention relates to a one-pack type aqueous coating material composition that imparts design properties to the inner and outer wall surfaces of a building, and relates to a jet black water-based coating material composition that becomes deep black.

従来、建築分野で使用する塗材、特に内外壁面に意匠性を付与する用途として施工され、コンクリート、モルタル、ケイカル、合板、プラスターボード下地への密着性、耐久性を付与し、ホルムアルデヒド、トルエン、キシレン、パラジクロルベンゼン、エチルベンゼン、スチレンの揮発性有機化合物を使用しない環境に配慮した塗材組成物が提案されている（特許文献１）。   Conventionally, it has been constructed as a coating material used in the construction field, especially for the design of interior and exterior wall surfaces, and provides adhesion and durability to concrete, mortar, calcium, plywood, and plasterboard bases, formaldehyde, toluene, xylene An environment-friendly coating composition that does not use volatile organic compounds such as paradichlorobenzene, ethylbenzene, and styrene has been proposed (Patent Document 1).

特開２００７−２３１９４号公報JP 2007-23194 A

しかしながら該特許文献１に係る塗材組成物は、具体的には、合成樹脂エマルジョン、充填剤、顔料、増粘剤、分散剤、防カビ剤、防藻剤を少なくとも含む水系塗材であって、ホルムアルデヒド、トルエン、キシレン、パラジクロロベンゼン、エチルベンゼン、スチレンの揮発性有機化合物を含まない有機溶媒を含むことを特徴とする塗材組成物であるが、所定の塗付作業性を維持した上で顔料としてカーボンブラックを配合しても深い黒色とはならないという課題があり、深い黒色を得るためにカーボンブラックを多量に配合すると、塗材の塗付作業性が不十分となる課題がある。   However, the coating material composition according to Patent Document 1 is specifically an aqueous coating material containing at least a synthetic resin emulsion, a filler, a pigment, a thickener, a dispersant, a fungicide, and an algae. , Formaldehyde, toluene, xylene, paradichlorobenzene, ethylbenzene, and a coating composition characterized by containing an organic solvent that does not contain a volatile organic compound of styrene, while maintaining a predetermined coating workability and a pigment As a result, there is a problem that even if carbon black is blended, it does not become a deep black, and when a large amount of carbon black is blended to obtain a deep black, there is a problem that the coating workability of the coating material becomes insufficient.

本発明の課題は、塗付作業性を維持した上で、深い黒色となる漆黒水系塗材組成物を提供することにある。   The subject of this invention is providing the jet black water type coating material composition used as a deep black, maintaining a coating workability | operativity.

請求項１記載の発明は、アクリル樹脂系エマルジョン（Ａ）と、平均粒径１００μｍ以上の骨材（Ｂ）と、平均粒径１００μｍ未満の充填剤（Ｃ）と、Ｃ１３〜Ｃ１５の分枝及び直鎖アルコールのエチレンオキシド付加物である非イオン性表面活性添加剤１２〜１４重量部と、カーボンブラック７５〜８５重量部と、スルホネート、スルフェート、ホスホネートまたはホスフェートをベースとする少なくとも１種のアニオン性表面活性添加剤と、を含有する顆粒状顔料組成物（Ｄ）と、酸化チタン（Ｅ）と、から成り、顆粒状顔料組成物（Ｄ）は漆黒水系塗材組成物全体１００重量部中の０．３〜３．０重量部であることを特徴とする漆黒水系塗材組成物を提供する。   The invention according to claim 1 includes an acrylic resin emulsion (A), an aggregate (B) having an average particle size of 100 μm or more, a filler (C) having an average particle size of less than 100 μm, branches of C13 to C15, and At least one anionic surface based on 12 to 14 parts by weight of a non-ionic surface active additive which is an ethylene oxide adduct of a linear alcohol, 75 to 85 parts by weight of carbon black, and a sulfonate, sulfate, phosphonate or phosphate. The granular pigment composition (D) containing an active additive and titanium oxide (E), and the granular pigment composition (D) is 0 in 100 parts by weight of the total jet black water-based coating material composition. A jet black water-based coating material composition characterized by being 3 to 3.0 parts by weight is provided.

また、請求項２記載の発明は、前記骨材（Ｂ）は重質炭酸カルシウムであることを特徴とする請求項１又は請求項２記載の漆黒水系塗材組成物を提供する。   The invention according to claim 2 provides the jet black water-based coating composition according to claim 1 or 2, wherein the aggregate (B) is heavy calcium carbonate.

本発明の漆黒水系塗材組成物は、従来の塗材組成物と同様の塗付作業性を維持しながら、深い黒色となる効果がある。   The jet black water-based coating composition of the present invention has an effect of becoming deep black while maintaining the same coating workability as that of a conventional coating composition.

本発明の水系塗材組成物は、アクリル樹脂系エマルジョン（Ａ）と、平均粒径１００μｍ以上の骨材（Ｂ）と、平均粒径１００μｍ未満の充填剤（Ｃ）と、Ｃ１３〜Ｃ１５の分枝及び直鎖アルコールのエチレンオキシド付加物である非イオン性表面活性添加剤１２〜１４重量部と、カーボンブラック７５〜８５重量部と、スルホネート、スルフェート、ホスホネートまたはホスフェートをベースとする少なくとも１種のアニオン性表面活性添加剤と、を含有する顆粒状顔料組成物（Ｄ）と、酸化チタン（Ｅ）と、から成り、顆粒状顔料組成物（Ｄ）は漆黒水系塗材組成物全体１００重量部中の０．３〜３．０重量部であることを特徴とする漆黒水系塗材組成物であり、必要に応じて消泡剤、増粘剤、分散剤、防カビ剤、防藻剤等を配合することが出来る。   The aqueous coating material composition of the present invention comprises an acrylic resin emulsion (A), an aggregate (B) having an average particle size of 100 μm or more, a filler (C) having an average particle size of less than 100 μm, and C13 to C15. At least one anion based on 12 to 14 parts by weight of a non-ionic surface active additive which is an ethylene oxide adduct of branched and straight chain alcohols, 75 to 85 parts by weight of carbon black and sulfonate, sulfate, phosphonate or phosphate A granular pigment composition (D) containing a surface active additive, and titanium oxide (E), and the granular pigment composition (D) is in 100 parts by weight of the jet black water-based coating composition as a whole. Is a jet black water-based coating composition characterized by being 0.3 to 3.0 parts by weight of an antifoaming agent, a thickener, a dispersant, an antifungal agent, an algaeproofing agent, etc. Blending I can do it.

［アクリル樹脂系エマルジョン（Ａ）］
本発明に使用するアクリル樹脂系エマルジョン（Ａ）は、アクリレートモノマーを含む、アクリル酸、メタクリル酸、マレイン酸、フマル酸、イタコン酸等の不飽和カルボン酸、及びこれらのモノエステルや、スチレン、α−メチルスチレン、ビニルトルエン、クロロスチレン等のスチレン類、酢酸ビニル等のビニルエステル類、メチルビニルエーテル、エチルビニルエーテル、ブチルビニルエーテル等のビニルエーテル類などの不飽和基含有重合性単量体の重合によって合成され，アクリル酸エステル系共重合樹脂、酢酸ビニル・アクリル酸エステル系共重合樹脂、シリコン変性アクリル系樹脂等の水性アクリル樹脂系エマルジョンが使用できる。本発明の漆黒水系塗材組成物全体中の樹脂固形分は１．０〜１５．０重量％が好ましく、１．０重量％未満では粘着性、塗付作業性が低下し、また１５．０重量％超では粘度が低下し塗付作業性が低下すると共に表現できる意匠（パターン）数が低下する。市販のアクリル樹脂系エマルジョン（Ａ）としては、アクロナールＰＳ７４３（ＢＡＳＦ社製、固形分５５重量％）がある。 [Acrylic resin emulsion (A)]
The acrylic resin emulsion (A) used in the present invention contains an acrylate monomer, an unsaturated carboxylic acid such as acrylic acid, methacrylic acid, maleic acid, fumaric acid, and itaconic acid, and monoesters thereof, styrene, α -Synthesized by polymerization of unsaturated group-containing polymerizable monomers such as styrenes such as methylstyrene, vinyltoluene and chlorostyrene, vinyl esters such as vinyl acetate, vinyl ethers such as methyl vinyl ether, ethyl vinyl ether and butyl vinyl ether. Water-based acrylic resin emulsions such as acrylic ester copolymer resins, vinyl acetate / acrylic ester copolymer resins, and silicone-modified acrylic resins can be used. The resin solid content in the entire jet black water-based coating composition of the present invention is preferably 1.0 to 15.0% by weight, and if it is less than 1.0% by weight, the tackiness and coating workability are reduced, and 15.0%. If it exceeds wt%, the viscosity decreases, the coating workability decreases, and the number of designs (patterns) that can be expressed decreases. As a commercially available acrylic resin emulsion (A), there is Acronal PS743 (manufactured by BASF, solid content 55% by weight).

［平均粒径１００μｍ以上の骨材（Ｂ）］
本発明に使用する平均粒径１００μｍ以上の骨材（Ｂ）は，本漆黒水系塗材組成物の仕上がり表面に凹凸を付与することを目的として配合されるが，平均粒径が１００μｍ以上であればその粒子径は任意に選択することができ，例えば硅砂，ガラス，シリカ，タルク，重質炭酸カルシウムなどが使用可能である。なお本願で言う平均粒径とは重量による積算分率５０％の粒子径を言う。市販の平均粒径が２００μｍの重質炭酸カルシウムとしてはＫ−２５０（商品名，旭鉱末（株）製）がある。骨材（Ｂ）の配合量は漆黒水系塗材組成物全体に対して４０〜６５重量％であり４０重量％未満では意匠性（塗材の凹凸感）が不足し，６５重量％超では作業性が低下する。 [Aggregate with average particle size of 100 μm or more (B)]
The aggregate (B) having an average particle size of 100 μm or more used in the present invention is blended for the purpose of imparting irregularities to the finished surface of the jet black water-based coating composition, but if the average particle size is 100 μm or more. The particle size can be arbitrarily selected, for example, cinnabar sand, glass, silica, talc, heavy calcium carbonate, etc. can be used. In addition, the average particle diameter said by this application means the particle diameter of the integrated fraction 50% by weight. As a commercially available heavy calcium carbonate having an average particle size of 200 μm, there is K-250 (trade name, manufactured by Asahi Minesue Co., Ltd.). The blending amount of the aggregate (B) is 40 to 65% by weight based on the total jet black water-based coating composition, and if it is less than 40% by weight, the design property (unevenness of the coating material) is insufficient. Sex is reduced.

［平均粒径１００μｍ未満の充填剤（Ｃ）］
本発明に使用する平均粒径１００μｍ未満の充填剤（Ｃ）は，塗材粘度や塗付性の調整を目的として配合し、重質炭酸カルシウム、クレー、カオリン、タルク、沈降性硫酸バリウム、炭酸バリウム、硅砂粉等が使用できるが、重質炭酸カルシウムが安価でコスト的負担を軽減させることが出来る。充填材（Ｃ）の配合量は塗材組成物全体に対して３〜２０重量％、好ましくは５〜１２重量％であり、３重量％未満では下地の色が透けるなどの隠蔽性が不足し、２０重量％超では塗材粘度が高くなって塗付作業性が不良となる。３重量％未満では色調によっては隠蔽性が低下する場合があり、１２重量％超では冬季等の低温度下では塗付作業性が低下する傾向にある。 [Filler (C) with an average particle size of less than 100 μm]
The filler (C) having an average particle size of less than 100 μm for use in the present invention is blended for the purpose of adjusting the coating material viscosity and the coating property, and includes heavy calcium carbonate, clay, kaolin, talc, precipitated barium sulfate, and carbonate. Barium, cinnabar dust, etc. can be used, but heavy calcium carbonate is inexpensive and can reduce the cost burden. The blending amount of the filler (C) is 3 to 20% by weight, preferably 5 to 12% by weight, based on the entire coating composition, and if it is less than 3% by weight, the concealing property such as transparency of the background is insufficient. If it exceeds 20% by weight, the viscosity of the coating material becomes high and the coating workability becomes poor. If it is less than 3% by weight, the hiding property may be lowered depending on the color tone, and if it exceeds 12% by weight, the coating workability tends to be lowered at low temperatures such as in winter.

［顆粒状顔料組成物（Ｄ）］
本発明に使用する顆粒状顔料組成物（Ｄ）は、Ｃ１３〜Ｃ１５の分枝及び直鎖アルコールのエチレンオキシド付加物である非イオン性表面活性添加剤１２〜１４重量部と、カーボンブラック７５〜８５重量部と、スルホネート、スルフェート、ホスホネートまたはホスフェートをベースとする少なくとも１種のアニオン性表面活性添加剤と、を含有して成り、具体的には特許第４８００５７８号に示される顔料調整物である。 [Granular pigment composition (D)]
The granular pigment composition (D) used in the present invention comprises 12 to 14 parts by weight of a nonionic surface active additive which is an ethylene oxide adduct of C13 to C15 branched and linear alcohols, and carbon black 75 to 85. A pigment preparation comprising, by weight, and at least one anionic surface active additive based on sulfonate, sulfate, phosphonate or phosphate. Specifically, it is a pigment preparation shown in Japanese Patent No. 4800578.

該顆粒状顔料組成物（Ｄ）は、該顆粒状顔料組成物（Ｄ）が配合されていない本発明の漆黒水系塗材組成物に、直接固体のまま配合することができ、カーボンブラックの色の濃さ及び隠ぺい力が発現され、また極めてわずかなエネルギーで簡単に分散することが出来る。市販の顆粒状顔料組成物（Ｄ）としては、ＸｆａｓｔＢｌａｃｋ ００６６（商品名、ＢＡＳＦジャパン株式会社製）がある。   The granular pigment composition (D) can be directly blended into the jet black water-based coating material composition of the present invention in which the granular pigment composition (D) is not blended, and the color of carbon black Of high density and hiding power, and can be easily dispersed with very little energy. As a commercially available granular pigment composition (D), there is XfastBlack 0066 (trade name, manufactured by BASF Japan Ltd.).

顆粒状顔料組成物（Ｄ）の配合量は、本発明の漆黒水系塗材組成物全体の１００重量部中０．３〜３．０重量部が配合され、０．３重量部未満では深い黒色と成らず、３．０重量部超では組成物の粘度が上昇して塗付作業性が不十分となる。   The compounding amount of the granular pigment composition (D) is 0.3 to 3.0 parts by weight in 100 parts by weight of the total jet black water-based coating material composition of the present invention, and deep black when it is less than 0.3 parts by weight. However, if it exceeds 3.0 parts by weight, the viscosity of the composition increases and the coating workability becomes insufficient.

［酸化チタン（Ｅ）］
酸化チタン（Ｅ）は漆黒水系塗材組成物の下地隠ぺい力が保持するために顔料として配合する。配合量は漆黒水系塗材組成物全体１００重量部に対して０．５〜５.０重量％が好ましく、０．５重量％未満では下地隠ぺい力が不足し、５．０重量％超では塗付作業性が不十分と成る。市販の酸化チタン（Ｅ）としては、Ｒ−８２０（商品名、平均粒径Ｄ５０；０．２６μｍ、石原産業株式会社製）がある。 [Titanium oxide (E)]
Titanium oxide (E) is blended as a pigment in order to maintain the base concealing power of the jet black water-based coating composition. The blending amount is preferably 0.5 to 5.0% by weight with respect to 100 parts by weight of the jet black water-based coating composition as a whole. If it is less than 0.5% by weight, the base hiding power is insufficient, and if it exceeds 5.0% by weight, it is applied. Attached workability becomes insufficient. Commercially available titanium oxide (E) includes R-820 (trade name, average particle diameter D50; 0.26 μm, manufactured by Ishihara Sangyo Co., Ltd.).

本発明の漆黒水系塗材組成物は骨材を含んでいるが、施工にあたっては、パターンローラー、金鏝、吹き付けガン等を使用して、目的とする意匠となるように適切に施工器具を選択し、その意匠に適した塗付量で仕上げる。配合された水系塗材組成物の適正粘度としては、５００〜７００Ｐａ・ｓが好ましい。   The jet black water-based coating composition of the present invention contains aggregates, but in the construction, use a pattern roller, a hammer, a spray gun, etc., and select a construction tool appropriately so that the intended design is achieved. And finish with a coating amount suitable for the design. The proper viscosity of the blended aqueous coating material composition is preferably 500 to 700 Pa · s.

以下、実施例及び比較例にて具体的に説明する。   Hereinafter, it demonstrates concretely in an Example and a comparative example.

［実施例及び比較例の調製］
表１の配合に従って、実施例１乃至実施例４、及び比較例１乃至比較例３の漆黒水系塗材組成物を調製した。表１において、アクリル樹脂系エマルジョン（Ａ）はアクロナールＰＳ７４３（商品名、ＢＡＳＦ社製）を、平均粒径１００μｍ以上の骨材（Ｂ）は重質炭酸カルシウムＫ−２５０（商品名、旭鉱末（株）製）を、平均粒径１００μｍ未満の充填材（Ｃ）は重質炭酸カルシウムＢＦ−２００（商品名、平均粒径１０μｍ、備北粉化工業（株）社製）を、カーボンブラックトナーはＡＭＩ ９７００（商品名、ガーボンブラック含有量：１７重量％、大日精化工業株式会社製）を、顆粒状顔料組成物（Ｄ）はＸｆａｓｔＢｌａｃｋ ００６６を、酸化チタン（Ｅ）はＲ−８２０を使用し、その他の添加剤には消泡剤と分散剤と増粘剤、防腐剤、防カビ剤と成膜助剤を使用した。 [Preparation of Examples and Comparative Examples]
According to the composition of Table 1, jet black water-based coating material compositions of Examples 1 to 4 and Comparative Examples 1 to 3 were prepared. In Table 1, the acrylic resin emulsion (A) is Acronal PS743 (trade name, manufactured by BASF), and the aggregate (B) having an average particle size of 100 μm or more is heavy calcium carbonate K-250 (trade name, Asahi Mineral Powder). (Made by Co., Ltd.), filler (C) having an average particle size of less than 100 μm is heavy calcium carbonate BF-200 (trade name, average particle size: 10 μm, manufactured by Bihoku Flour Industry Co., Ltd.), carbon black toner Is AMI 9700 (trade name, Garbon Black content: 17% by weight, manufactured by Dainichi Seika Kogyo Co., Ltd.), granular pigment composition (D) is XfastBlack 0066, and titanium oxide (E) is R-820. Used as other additives were an antifoaming agent, a dispersant, a thickener, an antiseptic, an antifungal agent, and a film forming aid.

Figure 2017066195
Figure 2017066195


［評価項目及び評価方法］ [Evaluation items and methods]

［Ｌａｂ値］
下地としてＪＩＳ Ａ５４３０規定のフレキシブルボード（７０×７０ｍｍ厚さ８ｍｍ）を使用し、シーラーＪＳ−４１０（商品名、アイカ工業株式会社製、溶剤型塩化ゴム系シーラー）を０．８ｋｇ／ｍ２塗付して２３℃にて４時間乾燥させたのち、実施例、比較例の漆黒水系塗材組成物を０．９ｋｇ／ｍ２で金鏝で塗付し、２３℃５０ＲＨ％で１２時間乾燥後、さらに同一の漆黒水系塗材組成物を２．０ｋｇ／ｍ２で金鏝で平滑に塗付し、同様に２３℃５０Ｒｈ％にて１４日間乾燥させ試験体とする。該試験体の表面のＬ値、a値、及びｂ値を色彩色差計 ＣＲ−４１０（商品名、コニカミノルタ社製）にて測定した。Ｌ値が２６．０以下を漆黒と判断した。 [Lab value]
A flexible board (70 x 70 mm thickness 8 mm) specified in JIS A5430 is used as the base, and 0.8 kg / m 2 of sealer JS-410 (trade name, manufactured by Aika Industry Co., Ltd., solvent type chlorinated rubber sealer) is applied. Then, after drying at 23 ° C. for 4 hours, the jet black water-based coating material compositions of Examples and Comparative Examples were applied with 0.9 kg / m 2 with a hammer and dried at 23 ° C. and 50 RH% for 12 hours. Further, the same jet black water-based coating material composition was applied smoothly at 2.0 kg / m 2 with a hammer and similarly dried at 23 ° C. and 50 Rh% for 14 days to obtain a test specimen. The L value, a value, and b value of the surface of the test specimen were measured with a color difference meter CR-410 (trade name, manufactured by Konica Minolta). An L value of 26.0 or less was judged to be jet black.

［粘度及びＴ．Ｉ値］
実施例及び比較例の漆黒水系塗材組成物について、２３℃にてＢＨ型粘度計ＴＶＢ−１０（商品名、東機産業社製）にてＮｏ７ローターを用い２回転／分 時の粘度を測定した。また同様に同ローターで２０回転／分 時の粘度を測定し、２回転時の粘度を２０回転時の粘度で除して、Ｔ．Ｉ値とした。粘度は５００〜７００Ｐａ・ｓである場合を適正（塗付作業性良好）と判断し、Ｔ．Ｉ値は４．５〜８．０を適正（垂直面に塗付した際に２ｍｍ凹凸を付けてもダレが生じない）と判断した。 [Viscosity and T.W. I value]
About the jet black water system coating material composition of an Example and a comparative example, the viscosity at 2 rotations / minute was measured using the No7 rotor with BH type viscometer TVB-10 (brand name, the Toki Sangyo company make) at 23 degreeC. did. Similarly, the viscosity at 20 revolutions / minute was measured with the same rotor, and the viscosity at 2 revolutions was divided by the viscosity at 20 revolutions. I value was used. The case where the viscosity is 500 to 700 Pa · s is judged to be appropriate (good coating workability). The I value was determined to be 4.5 to 8.0 (no sagging even if 2 mm unevenness was applied when applied to a vertical surface).

評価結果を表２に記載する。   The evaluation results are shown in Table 2.

Figure 2017066195
Figure 2017066195

Claims (2)

アクリル樹脂系エマルジョン（Ａ）と、平均粒径１００μｍ以上の骨材（Ｂ）と、平均粒径１００μｍ未満の充填剤（Ｃ）と、Ｃ１３〜Ｃ１５の分枝及び直鎖アルコールのエチレンオキシド付加物である非イオン性表面活性添加剤１２〜１４重量部と、カーボンブラック７５〜８５重量部と、スルホネート、スルフェート、ホスホネートまたはホスフェートをベースとする少なくとも１種のアニオン性表面活性添加剤と、を含有する顆粒状顔料組成物（Ｄ）と、酸化チタン（Ｅ）と、から成り、顆粒状顔料組成物（Ｄ）は漆黒水系塗材組成物全体１００重量部中の０．３〜３．０重量部であることを特徴とする漆黒水系塗材組成物。   An acrylic resin emulsion (A), an aggregate (B) having an average particle size of 100 μm or more, a filler (C) having an average particle size of less than 100 μm, and an ethylene oxide adduct of C13 to C15 branched and linear alcohols. 12 to 14 parts by weight of a nonionic surface active additive, 75 to 85 parts by weight of carbon black, and at least one anionic surface active additive based on sulfonate, sulfate, phosphonate or phosphate. It consists of a granular pigment composition (D) and titanium oxide (E), and the granular pigment composition (D) is 0.3 to 3.0 parts by weight in 100 parts by weight of the total jet black water-based coating material composition. A jet black water-based coating material composition characterized by being: 前記骨材（Ｂ）は重質炭酸カルシウムであることを特徴とする請求項１又は請求項２記載の漆黒水系塗材組成物。

The jet black water-based coating composition according to claim 1 or 2, wherein the aggregate (B) is heavy calcium carbonate.

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017066196A (en) * 2015-09-28 2017-04-06 アイカ工業株式会社 Jet-black aqueous coating composition for interior

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296068A (en) * 1997-04-25 1998-11-10 Kao Corp Dispersion stabilizer for organic powder and dispersion body composition containing the same
JP2005517074A (en) * 2002-02-04 2005-06-09 ビーエーエスエフ アクチェンゲゼルシャフト Pigment preparation
JP2008285632A (en) * 2007-05-21 2008-11-27 Mikuni Color Ltd High jetness carbon black dispersion, process for producing the same, and coating material composition using the high jetness carbon black dispersion
JP2015030749A (en) * 2013-07-31 2015-02-16 アイカ工業株式会社 Aqueous coating material composition
JP2015078288A (en) * 2013-10-16 2015-04-23 アイカ工業株式会社 Sand wall-like aqueous coating composition and method for applying the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296068A (en) * 1997-04-25 1998-11-10 Kao Corp Dispersion stabilizer for organic powder and dispersion body composition containing the same
JP2005517074A (en) * 2002-02-04 2005-06-09 ビーエーエスエフ アクチェンゲゼルシャフト Pigment preparation
JP2008285632A (en) * 2007-05-21 2008-11-27 Mikuni Color Ltd High jetness carbon black dispersion, process for producing the same, and coating material composition using the high jetness carbon black dispersion
JP2015030749A (en) * 2013-07-31 2015-02-16 アイカ工業株式会社 Aqueous coating material composition
JP2015078288A (en) * 2013-10-16 2015-04-23 アイカ工業株式会社 Sand wall-like aqueous coating composition and method for applying the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017066196A (en) * 2015-09-28 2017-04-06 アイカ工業株式会社 Jet-black aqueous coating composition for interior

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