JP2016508174A5 - - Google Patents

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JP2016508174A5
JP2016508174A5 JP2015549923A JP2015549923A JP2016508174A5 JP 2016508174 A5 JP2016508174 A5 JP 2016508174A5 JP 2015549923 A JP2015549923 A JP 2015549923A JP 2015549923 A JP2015549923 A JP 2015549923A JP 2016508174 A5 JP2016508174 A5 JP 2016508174A5
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Japan
Prior art keywords
yellow
green
phosphor
illumination system
emitting
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Pending
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JP2015549923A
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Japanese (ja)
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JP2016508174A (en
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Priority claimed from PCT/CN2012/087751 external-priority patent/WO2014101073A1/en
Publication of JP2016508174A publication Critical patent/JP2016508174A/en
Publication of JP2016508174A5 publication Critical patent/JP2016508174A5/ja
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Claims (15)

(Lu 1−x−y Ce Al 12 2z を有する、セリウム賦活された黄緑〜黄色発光ルテチウムアルミネート系蛍光体であって、
AはSc、La、GaおよびTbの少なくとも1つであり、
BはMg、Sr、CaおよびBaの少なくとも1つであり、
CはF、Cl、BrおよびIの少なくとも1つであり、
0<x<0.5であり、
0.001≦y<0.2であり、
0.001≦z≦0.5である、黄緑〜黄色発光ルテチウムアルミネート系蛍光体。
Having the formula (Lu 1-x-y A x Ce y) 3 B z Al 5 O 12 C 2z, a yellow-green-yellow light lutetium aluminate-based phosphors, cerium activated,
A is at least one of Sc, La, Ga and Tb;
B is at least one of Mg, Sr, Ca and Ba,
C is at least one of F, Cl, Br and I;
0 <x <0.5,
0.001 ≦ y <0.2,
A yellow-green to yellow-emitting lutetium aluminate phosphor that satisfies 0.001 ≦ z ≦ 0.5 .
yはゼロより大きく、x+y<1である、請求項1に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 2. The yellowish green to yellow light emitting lutetium aluminate-based phosphor according to claim 1, wherein y is greater than zero and x + y <1 . Cは置換的に結晶に含まれる、請求項1または2に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 The yellow-green to yellow-emitting lutetium aluminate-based phosphor according to claim 1 or 2 , wherein C is contained in the crystal in a substitutional manner . Cは結晶格子間に含まれる、請求項1または2に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 The yellow-green to yellow-emitting lutetium aluminate phosphor according to claim 1 or 2 , wherein C is contained between crystal lattices . AはGdおよびTbの少なくとも1つである、請求項1〜4のいずれか一項に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 The yellow-green to yellow light emitting lutetium aluminate phosphor according to any one of claims 1 to 4 , wherein A is at least one of Gd and Tb . AはTbである、請求項1〜5のいずれか一項に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 The yellow-green to yellow-emitting lutetium aluminate phosphor according to any one of claims 1 to 5 , wherein A is Tb . BはSrおよびBaの少なくとも1つであり、
CはFである、請求項1〜6のいずれか一項に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。
B is at least one of Sr and Ba;
The yellowish green to yellow light emitting lutetium aluminate-based phosphor according to any one of claims 1 to 6 , wherein C is F.
前記蛍光体は、380nmから480nmの範囲の波長を有する励起放射光を吸収し、かつ550nmから565nmの範囲のピーク発光波長を有する光を発するように構成されている、請求項1〜7のいずれか一項に記載の黄緑〜黄色発光ルテチウムアルミネート系蛍光体。 The phosphor is configured to absorb an excitation radiation having a wavelength in the range of 480nm from 380 nm, and emits light having a peak emission wavelength in the range of 565nm from 550 nm, any of claims 1 to 7 yellow green-yellow light lutetium aluminate phosphor according to an item or. 白色光照明システムであって、
200nmから480nmの範囲内の発光波長を有する励起源と、
赤色発光蛍光体および緑色発光蛍光体の少なくとも一方と、
請求項1〜8のいずれか一項に記載のセリウム賦活された黄緑色〜黄色発光ルテチウムアルミネート系蛍光体と、を備える、白色光照明システム。
A white light illumination system,
An excitation source having an emission wavelength in the range of 200 nm to 480 nm;
At least one of a red light emitting phosphor and a green light emitting phosphor;
A white light illumination system comprising: the cerium-activated yellow green to yellow light emitting lutetium aluminate phosphor according to any one of claims 1 to 8 .
前記赤色発光蛍光体が600nmから660nmの範囲内の発光波長を有する、請求項に記載の白色光照明システム。 The white light illumination system of claim 9 , wherein the red-emitting phosphor has an emission wavelength in a range of 600 nm to 660 nm. 前記緑色発光蛍光体が500nmから545nmの範囲内の発光波長を有する、請求項9または10に記載の白色光照明システム。 The white light illumination system according to claim 9 or 10 , wherein the green-emitting phosphor has an emission wavelength in a range of 500 nm to 545 nm. 前記赤色発光蛍光体が窒化物である、請求項9〜11のいずれか一項に記載の白色光照明システム。 The white light illumination system according to claim 9 , wherein the red light emitting phosphor is a nitride. 前記窒化物が、(Ca,Sr)AlSiN:Eu2+、(Ca,Sr):Eu2+、及び(Ca,Sr)AlSi:Eu2+のうちの少なくとも1つである、請求項12に記載の白色光照明システム。 The nitride is at least one of (Ca, Sr) AlSiN 3 : Eu 2+ , (Ca, Sr) 2 N 5 N 8 : Eu 2+ , and (Ca, Sr) AlSi 4 N 7 : Eu 2+ The white light illumination system of claim 12 , wherein: 前記緑色発光蛍光体がシリケートである、請求項9〜13のいずれか一項に記載の白色光照明システム。 The white light illumination system according to any one of claims 9 to 13 , wherein the green light emitting phosphor is a silicate. 前記シリケートが式(Sr,Ba,Mg)SiO:Eu2+を有する、請求項14に記載の白色光照明システム。
The white light illumination system of claim 14 , wherein the silicate has the formula (Sr, Ba, Mg) 2 SiO 4 : Eu 2+ .
JP2015549923A 2012-12-28 2012-12-28 Terbium-containing aluminate-based yellow-green to yellow-emitting phosphor Pending JP2016508174A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2012/087751 WO2014101073A1 (en) 2012-12-28 2012-12-28 Yellow-green to yellow-emitting phosphors based on terbium-containing aluminates

Related Child Applications (1)

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JP2017133013A Division JP2017222868A (en) 2017-07-06 2017-07-06 Terbium-containing aluminate-based yellowish green to yellow light-emitting fluophor

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JP2016508174A JP2016508174A (en) 2016-03-17
JP2016508174A5 true JP2016508174A5 (en) 2016-04-28

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EP (1) EP2938699A4 (en)
JP (1) JP2016508174A (en)
KR (1) KR20150100724A (en)
CN (1) CN104870607A (en)
TW (1) TW201432026A (en)
WO (1) WO2014101073A1 (en)

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TWI509051B (en) * 2014-08-25 2015-11-21 Cheng En Material Tech Co Ltd Phosphor, method for production thereof, and light-emitting apparatus
CN105623661A (en) * 2014-10-29 2016-06-01 大连利德照明研发中心有限公司 Fluorescent material and preparation method and composition containing fluorescent material
CN104893724B (en) * 2015-04-27 2017-10-27 济南大学 A kind of efficient yellow fluorescent powder of new garnet-base
CN105038796A (en) * 2015-04-27 2015-11-11 济南大学 Novel pomegranate-based light-color-controllable fluorescent powder
US10066160B2 (en) 2015-05-01 2018-09-04 Intematix Corporation Solid-state white light generating lighting arrangements including photoluminescence wavelength conversion components
CN105297136A (en) * 2015-11-13 2016-02-03 孙雷 Cerium-doped gadolinium lutecium aluminate garnet crystal for laser illumination and preparation method thereof
CN106590657B (en) * 2016-11-25 2019-01-29 河北利福光电技术有限公司 A kind of lutetium aluminate green fluorescent powder and its preparation method and application
CN111995397A (en) * 2020-08-14 2020-11-27 中国科学院宁波材料技术与工程研究所 Fluorescent ceramic and preparation method and application thereof
CN115490518A (en) * 2022-10-17 2022-12-20 闽都创新实验室 Ce-excess-doped magneto-optical transparent ceramic and preparation method and application thereof

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