JP2016507855A - Phosphonium ionic liquid, salt, composition, production method and apparatus formed therefrom - Google Patents

Abstract

The present invention generally encompasses phosphonium ionic liquids, salts, compositions and their use in many applications, among other applications such as memory devices including static memory, fixed memory and dynamic random access memory. As an electrolyte for electronic devices, as an electrolyte for batteries, electrochemical double layer capacitors (EDLC) or energy storage devices such as supercapacitors or ultracapacitors, electrolytic capacitors, as an electrolyte for dye-sensitized solar cells (DSSC), fuel cells Examples of the electrolyte include, but are not limited to, use as a heat transfer medium. In particular, the present invention generally relates to phosphonium ionic liquids, salts, compositions, which have thermodynamic stability, low volatility, wide liquid phase range, ionic conductivity, and electrochemical stability. Excellent combination. The present invention further encompasses methods of making such phosphonium ionic liquids, salts, and compositions, and operating devices and systems comprising the same.

Description

  The present invention generally encompasses phosphonium ionic liquids, salts, compositions and their use in many applications, and among other applications, memory devices including static memory, fixed memory and dynamic random access memory. As an electrolyte of an electronic device such as a battery, an electrochemical double layer capacitor (EDLC) or as an electrolyte of an energy storage device such as a supercapacitor or ultracapacitor, an electrolytic capacitor, as an electrolyte of a dye-sensitized solar cell (DSSC), Examples of fuel cell electrolytes include, but are not limited to, heat transfer media, high temperature reactions and / or extraction media. In particular, the present invention relates to phosphonium ionic liquids, salts, compositions and molecules that have structural features, the composition of thermodynamic stability, low volatility, wide liquid phase range, and ionic conductivity. At least two or more desired combinations are shown. The invention further encompasses methods for making such phosphonium ionic liquids, salts, compositions and molecules, and operating devices and systems comprising the same.

  Ionic liquids have received considerable attention in part because of their wide use and versatility. The term “ionic liquid” is commonly used for salts with a relatively low melting point (100 ° C. or less). Salts that are liquid at room temperature are commonly referred to as room temperature ionic liquids. Early researchers utilized dialkylimidazolium salt-based ionic liquids. For example, Wilkes et al. Developed a dialkylimidazolium salt-based ionic liquid for use with an aluminum metal anode and a chlorine cathode with the goal of creating a battery. J. Wilkes, J. Levisky, R. Wilson, C. Hussey, Inorg. Chem, 21, 1263 (1982).

  Some of the most widely studied and commonly used ionic liquids are based on pyridinium salts and have found important uses for N-alkylpyridinium and N, N′-dialkylimidazoliums. Pyridinium-based ionic liquids, including N-alkyl-pyridinium and N, N-dialkylimidazolium, and nitrogen-based ionic liquids generally have thermodynamic stability limited to 300 ° C or less and are easy It tends to have a measurable vapor pressure at temperatures well below 200 ° C. Such properties limit their usefulness as well as their use. For example, such an ionic liquid is liable to be decomposed during heat treatment in a post process (BEOL). Furthermore, such ionic liquids also break down during other heat transfer steps that subject the ionic liquids to continuous thermal cycling to temperatures often above 300 ° C.

  The various properties of ionic liquids are continuously investigated and further uses of ionic liquids are considered. For example, electrochemical methods and applications require electrolytes that increase conductivity in various devices and applications. Recent work has been done in the area of room temperature ionic liquids as a possible alternative to conventional solvent-based electrolytes.

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J. Wilkes, J. Levisky, R. Wilson, C. Hussey, Inorg. Chem, 21, 1263 (1982) Yang et al. (1999) J. Porphyrins Phthalocyanines, 3: 117-147 Seth et al. (1994) J. Am. Chem. Soc., 116: 10578-10592 Seth et al. (1996) J. Am. Chem. Soc., 118: 11194-11207 Strachan et al. (1997) J. Am. Chem. Soc., 119: 11191-11201 Li et al. (1997) J. Mater. Chem., 7: 1245-1262. Strachan et al. (1998) Inorg. Chem., 37: 1191-1201 Yang et al. (1999) J. Am. Chem. Soc., 121: 4008-4018 Handbook of Electrochemistry of the Elements Roth et al. (2000) Vac. Sci. Technol. B 18: 2359-2364 Roth et al. (2003) J. Am. Chem. Soc. 125: 505-517 Advanced Inorganic Chemistry, 5th edition, Cotton & Wilkinson, John Wiley & Sons, 1988, Chapter 26 Organometallics, A Concise Introduction, Elschenbroich et al., 2nd edition, 1992, VCH Comprehensive Organometallic Chemistry II, A Review of the Literature 1982-1994, edited by Abel et al., 7, 7, 8, 10 and 11, Pergamon Press Robins et al., J. Am. Chem. Soc. 104: 1882-1893 (1982) Gassman et al., J. Am. Chem. Soc. 108: 4228-4229 (1986) Connelly et al., Chem. Rev. 96: 877-910 (1996) Geiger et al., Advances in Organometallic Chemistry 23: 1-93 Geiger et al., Advances in Organometallic Chemistry 24:87 Ng and Jiang (1997) Chemical Society Reviews 26: 433-442 Jiang et al. (1999) J. Porphyrins Phthalocyanines 3: 322-328 Arnold et al. (1999) Chemistry Letters 483-484 Cotton and Wilkenson, Advanced Organic Chemistry, 5th edition, John Wiley & Sons, 1988 Rai-Choudhury (1997) The Handbook of Microlithography, Micromachining, and Microfabrication, SPIE Optical Engineering Press Bard & Faulkner (1997) Fundamentals of Microfabrication

  While development has been underway, the need for new developments in ionic liquids, salts, and electrolyte compositions, and electrolytes are electrochemical double layer capacitors, lithium metal and lithium ion batteries, fuel cells, dye sensitized Clearly, there is a continuing need for materials and uses that are available for use in solar cells and molecular memory devices.

  The present invention broadly encompasses phosphonium ionic liquids, salts, compositions and their use in many applications, among other applications, memory devices including static memory, fixed memory and dynamic random access memory, etc. As an electrolyte for electronic devices, as an electrolyte for energy storage devices such as batteries, electrochemical double layer capacitors (EDLC) or supercapacitors or ultracapacitors, electrolytic capacitors, as an electrolyte for dye-sensitized solar cells (DSSC) Examples of battery electrolytes include, but are not limited to, heat transfer media, high temperature reactions and / or applications as extraction media. In particular, the present invention relates to phosphonium ionic liquids, salts, compositions and molecules that have structural features, the composition of thermodynamic stability, low volatility, wide liquid phase range, and ionic conductivity. At least two or more desired combinations are shown.

In one aspect, an ionic liquid composition is provided, the ionic liquid composition having the general formula:
R ¹ R ² R ³ R ⁴ P
One or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are any and each independently a substituent. Including. In some embodiments, R ¹ , R ² , R ^3, and R ⁴ are each independently a different alkyl group composed of 2-14 carbon atoms. In some embodiments, at least one of R ¹ , R ² , R ³ and R ⁴ is an aliphatic, heterocyclic moiety. Instead, at least one of R ¹ , R ² , R ³ and R ⁴ is an aromatic, heterocyclic moiety. In other embodiments, R ¹ and R ² are the same and are composed of tetramethylene phosphorane, pentamethylene phosphorinane, tetramethynyl phosphor, phospholane, or phosphorinane. In another embodiment, R ² , R ³ and R ⁴ are the same and are composed of phospholane, phosphorinane or phosphole.

  In another embodiment, an ionic liquid composition comprising one or more phosphonium-based cations and one or more anions is provided, the ionic liquid composition having a thermodynamic stability above 375 ° C. And an ionic conductivity of 10 mS / cm or less at room temperature and a liquidus range exceeding 400 ° C.

  In another aspect, the invention includes an electrolyte composition comprised of a phosphonium-based cation with a suitable anion. In some embodiments, the term “electrolyte” or “electrolyte solution” or “electrolyte composition” or “ion electrolyte” or “ion conductive electrolyte” or “ion conductive composition” or “ionic composition” As used herein, this term is defined as any one or more of the following: (a) an ionic liquid, (b) a room temperature ionic liquid, (c) in at least one solvent. One or more salts dissolved in (d) and (d) one or more salts forming a gel electrolyte by dissolving with at least one polymer in at least one solvent. Further, the one or more salts are defined to include: (a) one or more salts that are solid at a temperature of 100 ° C. or lower; and (b) at a temperature of 100 ° C. or lower. One or more salts that are liquids.

In another embodiment, an electrolyte composition is provided, the electrolyte composition being composed of one or more salts dissolved in a solvent, the one or more salts having the general formula:
R ¹ R ² R ³ R ⁴ P (1)
One or more of the formulas wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent such as, but not limited to, an alkyl group as described below A phosphonium-based cation and one or more anions. In some embodiments, R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group composed of 1 to 6 carbon atoms, more usually 1 to 4 carbon atoms. It is. Any one or more of the salts may be liquid or solid at a temperature of 100 ° C. or lower. In some embodiments, the salt is composed of one cation and one anion pair. In other embodiments, the salt is composed of one cation and multiple anions. In other embodiments, the salt is composed of one anion and multiple cations. In a further embodiment, the salt is composed of multiple cations and multiple anions.

In another embodiment, the electrolyte composition further comprises one or more conventional, non-phosphonium salts. In some embodiments, the electrolyte composition may be composed of conventional salts, in which case the phosphonium-based ionic liquids or salts disclosed herein are additives. In some embodiments, the electrolyte composition is comprised of a phosphonium-based ionic liquid or salt and one or more conventional salts, which are phosphonium-based ionic liquids or salts: moles of conventional salts (or Molar concentration) ratio exists in the range of 1: 100 to 1: 1. Examples of conventional salts include, but are not limited to, tetraalkylammonium, such as (CH ₃ CH ₂ ) ₄ N ⁺ , (CH ₃ CH ₂ ) ₃ (CH ₃ ) N ⁺ , (CH ₃ CH ₂ ) ₂ (CH ₃ ) ₂ N ⁺ , (CH ₃ CH ₂ ) (CH ₃ ) ₃ N ⁺ , (CH ₃ ) ₄ N ⁺ etc., from the group consisting of imidazolium, pyrazolium, pyridinium, pyrazinium, pyrimidinium, pyridazinium, pyrrolidinium One or more selected cations and ClO ₄ ⁻ , BF ₄ ⁻ , CF ₃ SO ₃ ⁻ , PF ₆ ⁻ , AsF ₆ ⁻ , SbF ₆ ⁻ , (CF ₃ SO ₂ ) ₂ N ⁻ , (CF ₃ And a salt composed of one or more anions selected from the group consisting of CF ₂ SO ₂ ) ₂ N ⁻ and (CF ₃ SO ₂ ) ₃ C ⁻ . In some embodiments, one or more conventional salts include, but are not limited to, tetraethylammonium tetrafluoroborate (TEABF ₄ ), triethylmethylammonium tetrafluoroborate (TEMABF ₄ ), tetrafluoroboric acid 1-ethyl-3-methylimidazolium (EMIBF ₄ ), 1-ethyl-1-methylpyrrolidinium tetrafluoroborate (EMPBF ₄ ), 1-ethyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide ( EMIIm) and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIPF ₆ ). In some embodiments, one or more conventional salts include, but are not limited to, lithium hexafluorophosphate (LiPF ₆ ), lithium tetrafluoroborate (LiBF ₄ ), lithium perchlorate (LiClO ₄ ), Lithium hexafluoroarsenate (LiAsF ₆ ), lithium trifluoromethanesulfonate or lithium triflate (LiCF ₃ SO ₃ ), lithium bis (trifluoromethanesulfonyl) imido (Li (CF ₃ SO ₂ ) ₂ N or LiIm), And bis (pentafluoromethanesulfonyl) imide lithium (Li (CF ₃ CF ₂ SO ₂ ) ₂ N or LiBETI).

A further aspect of the present invention provides a battery comprising an anode, a cathode, a separator between the anode and cathode, and an electrolyte. The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more salts dissolved in a liquid composition or solvent. In another embodiment, the electrolyte is characterized as having one or more phosphonium-based cations and one or more anions, the ionic liquid composition having a thermodynamic up to above 375 ° C. Stability, a liquidus range wider than 400 ° C., and an ionic conductivity of at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm at room temperature. In another embodiment, the electrolyte is comprised of one or more salts dissolved in a solvent having one or more phosphonium-based cations and one or more anions, the electrolyte composition comprising: At room temperature, at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm The ionic conductivity of is shown. In a further aspect, the phosphonium electrolyte exhibits lower flammability compared to conventional electrolytes, thus improving battery operation safety. In a further aspect, phosphonium ionic liquids or salts can be used as additives to facilitate the formation of a solid electrolyte interphase (SEI) layer or electrode protection layer. The SEI layer can widen the electrochemical stability window, suppress battery degradation or decomposition reactions, and thus improve battery cycle life.

A further aspect of the invention provides an electrochemical double layer capacitor (EDLC) comprising an anode, a cathode, a separator between the anode and cathode, and an electrolyte. . The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more salts dissolved in a liquid composition or solvent. In another embodiment, the electrolyte is characterized as having one or more phosphonium-based cations and one or more anions, wherein the ionic liquid composition or salt is up to above 375 ° C. Thermodynamic stability, liquid phase range greater than 400 ° C., and ionic conductivity at room temperature of at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm. In another embodiment, the electrolyte is comprised of one or more salts dissolved in a solvent having one or more phosphonium-based cations and one or more anions, the electrolyte composition comprising: At room temperature, at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm The ionic conductivity of is shown. In a further embodiment, the phosphonium electrolyte exhibits lower flammability compared to conventional electrolytes, thus improving the safety of EDLC operation. In a further aspect, phosphonium ionic liquids or salts can be used as additives to facilitate the formation of a solid electrolyte interphase (SEI) layer or electrode protection layer. The protective layer acts to widen the electrochemical stability window, suppress EDLC degradation or decomposition reactions and thus improve the cycle life of the EDLC.

  Embodiments of the present invention provide a heat transfer medium comprising one or more salts dissolved in an ionic liquid composition or solvent comprising one or more phosphonium-based cations and one or more anions. Further provided, this heat transfer medium exhibits thermodynamic stability at temperatures above 375 ° C., a liquidus range greater than 400 ° C.

Phosphonium ionic liquid compositions and salts are useful in forming a variety of hybrid electrical devices. For example, in one embodiment, the first electrode, the second electrode, and the general formula:
R ¹ R ² R ³ R ⁴ P
An ionic liquid composition comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent And an electrolyte composed of one or more salts dissolved in a solvent or solvent, wherein the electrolyte is electrically coupled to at least one of the first and second electrodes. It's ringing. In some embodiments, the first electrode is composed of a redox active molecule (ReAM).

  In another embodiment, a molecular storage device comprising a working electrode and a counter electrode configured to provide electrical capacitance, and an ion conductive composition comprising one or more phosphonium-based cations of the above general formula Provided, the ionically conductive composition is electrically coupled to at least the working electrode and the counter electrode.

  In another embodiment, the present invention encompasses a molecular memory element comprising a switching device, bit lines and word lines coupled to the switching device, and a molecular storage device accessible via the switching device. The molecular storage device can be placed in more than one discontinuity, in which case the molecular storage device is placed in one of the discontinuities by a signal applied to the bit and word lines. The molecular storage device includes a first electrode, a second electrode, and a phosphonium-based cation and a suitable anion electrolyte between the first and second electrodes.

  Another embodiment includes a molecular memory array that includes a plurality of molecular storage elements that can place each molecular storage element in two or more distinct states. The plurality of bit lines and word lines are coupled to the plurality of molecular storage elements such that each molecular storage element is coupled to and addressable by at least one bit line and at least one word line. .

  Other aspects, embodiments and advantages of the present invention will become apparent upon reading the detailed description of the invention and the appended claims provided below, and upon reference to the following drawings.

FIG. 3 illustrates one reaction scheme for forming a phosphonium ionic liquid according to some embodiments of the present invention. FIG. 6 depicts another reaction scheme for forming another embodiment of the phosphonium ionic liquid of the present invention. FIG. 5 shows another reaction scheme for forming a phosphonium ionic liquid according to another embodiment of the present invention. FIG. 5 shows another reaction scheme for forming a phosphonium ionic liquid according to a further embodiment of the invention. 2 is a thermogravimetric analysis (TGA) graph performed on an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 1. FIG. FIG. 2 shows a reaction scheme for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 2. 2 is a graph illustrating thermogravimetric analysis (TGA) for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 2. FIG. 2 is a graph illustrating evolved gas analysis (EGA) for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 2. 4 is a graph illustrating thermogravimetric analysis (TGA) for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 3. FIG. 4 is a graph illustrating evolved gas analysis (EGA) for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 3. FIG. FIG. 5 shows a reaction scheme for an exemplary embodiment of a phosphonium ionic liquid prepared as described in FIG. 2 and Example 4. FIG. 5 shows a ¹ H NMR spectrum for an exemplary embodiment of a phosphonium ionic liquid prepared as described in FIG. 2 and Example 4. FIG. 6 shows a reaction scheme for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 5. 6 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 5. FIG. 6 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 6. 6 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 7. FIG. FIG. 9 shows a reaction scheme for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 8. 6 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 8. FIG. 10 shows a ¹ H NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 9. FIG. 10 shows a ³¹ P NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 9. 6 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium salt prepared according to Example 9. FIG. 5 shows a ¹ H NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 10. FIG. 10 shows a ³¹ P NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 10. 2 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium salt prepared according to Example 10. FIG. FIG. 6 shows a ¹ H NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 11. FIG. 10 shows a ³¹ P NMR spectrum for an exemplary embodiment of a phosphonium salt prepared as described in Example 11. 2 is a graph showing thermogravimetric analysis (TGA) results for an exemplary embodiment of a phosphonium salt prepared according to Example 11. FIG. FIG. 6 is a graph showing differential scanning calorimetry (DSC) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 12. FIG. FIG. 6 is a graph showing differential scanning calorimetry (DSC) results for an exemplary embodiment of a phosphonium ionic liquid prepared according to Example 12. FIG. Of the volume ratio of ACN / salt to phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ in acetonitrile (ACN) as described in Example 14. 3 is a graph showing ionic conductivity as a function. Volume ratio of PC / salt to phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) _{3 in} propylene carbonate (PC) as described in Example 15. Is a graph showing ionic conductivity as a function of FIG. 4 is a graph showing ionic conductivity as a function of molar concentration of phosphonium salt compared to ammonium salt in propylene carbonate as described in Examples 42-45. FIG. 4 is a graph showing vapor pressure as a function of temperature for acetonitrile, acetonitrile with 1M ammonium salt and acetonitrile with 1M phosphonium salt as described in Example 46. FIG. Phosphonium salt (CH ₃ CH ₂ CH ₂ ) for ionic conductivity of 1.0M LiPF _{6 in} EC: DEC 1: 1 at different temperatures from -30 to 60 ° C. as described in Example 51 ₃ is a graph showing the influence of CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ . Phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH for ionic conductivity of 1.0M LiPF _{6 in} EC: DEC 1: 1 at different temperatures of 20-90 ° C. as described in Example 52 ₃ CH ₂ ) (CH ₃ ) ₂ is a graph showing the influence of PCF ₃ BF ₃ .

Overview The present invention is generally directed to phosphonium ionic liquids, salts, and compositions and their use in many applications.

General Description The present invention encompasses novel phosphonium ionic liquids, salts, compositions and their use in many applications, including electronic devices such as memory devices including static memory, fixed memory and dynamic random access memory. Examples of the electrolyte include, but are not limited to, batteries, electrochemical double layer capacitors, electrolytic capacitors, fuel cells, dye-sensitized solar cells, and electrochromic device applications. Further applications include the use as heat transfer media, high temperature reactions and / or extraction media, among other applications. In particular, the present invention relates to phosphonium ionic liquids, salts, compositions and molecules possessing structural characteristics, which compositions have thermodynamic stability, low volatility, wide liquid phase range, ionic conductivity, and electrical properties. A desirable combination of at least two of the chemical stability is indicated. The present invention further encompasses methods for making such phosphonium ionic liquids, compositions and molecules, and operating devices and systems comprising the same.

  In another aspect, embodiments of the present invention provide a device having an electrolyte comprised of a phosphonium ionic liquid composition or one or more salts dissolved in a solvent. In another aspect, embodiments of the present invention provide a battery comprising an electrolyte comprised of a phosphonium ionic liquid composition or one or more salts dissolved in a solvent. In a further aspect, embodiments of the present invention provide an electrochemical double layer capacitor (EDLC) comprising an electrolyte composed of a phosphonium ionic liquid composition or one or more salts dissolved in a solvent.

  Phosphonium ionic liquid compositions, due to their advantageous properties, make them particularly suitable for use as electrolytes in electronic devices, batteries, EDLCs, fuel cells, dye-sensitized solar cells (DSSCs), and electrochromic devices. Become.

  In a further aspect of the present invention there is provided a heat transfer medium composed of one or more salts dissolved in a phosphonium ionic liquid composition or solvent. The advantageous properties of the compositions of the present invention are well suited for heat transfer media, making the heat transfer media useful in processes and systems utilized, for example, in heat extraction processes and high temperature reactions.

Definitions As used herein and unless otherwise indicated, “electrolyte” or “electrolyte solution” or “electrolyte composition” or “ionic electrolyte” or “ionic conductive electrolyte” or “ionic conductive composition” Or “ionic composition”, which is defined herein as any one or more of the following: (a) an ionic liquid, (b) room temperature ions A liquid, (c) one or more salts dissolved in at least one solvent, and (d) one or more that forms a gel electrolyte by dissolving with at least one polymer in at least one solvent. Multiple salts. Further, the one or more salts are defined to include: (a) one or more salts that are solid at a temperature of 100 ° C. or lower; and (b) at a temperature of 100 ° C. or lower. One or more salts that are liquids.

  As used herein and unless otherwise indicated, the term “acyl” refers to the OH of the carboxyl group as a number of other substituents (RCO—), such as “R” substituents. It refers to organic acid groups that can be replaced with those described in the specification. Examples include but are not limited to halo, acetyl, and benzoyl.

  As used herein and unless otherwise indicated, the term “alkoxy group” means an —O-alkyl group, where alkyl is as defined herein. An alkoxy group can be unsubstituted or substituted with one, two or three suitable substituents. Preferably, the alkyl chain of an alkoxy group is 1 to 6 carbon atoms in length, referred to herein as, for example, “(C1-C6) alkoxy”.

  As used herein and unless otherwise indicated, an “alkyl” by itself or as part of another substituent is a single carbon atom from the single carbon atom of the parent alkane, alkene, or alkyne. A saturated or unsaturated, branched, linear or cyclic monovalent hydrocarbon group obtained by removing a hydrogen atom. Also included within the definition of alkyl groups are cycloalkyl groups such as C5, C6 or other rings, and heterocyclic rings having nitrogen, oxygen, sulfur or phosphorus (heterocycloalkyl). Alkyl also includes heteroalkyl having the heteroatoms sulfur, oxygen, nitrogen, phosphorus, and silicon, which have found particular use in certain embodiments. The alkyl group can be optionally substituted with R groups independently selected at each position, as described below.

  Examples of alkyl groups include, but are not limited to, (C1-C6) alkyl groups such as methyl, ethyl, propyl, isopropyl, 2-methyl-1-propyl, 2-methyl-2-propyl, 2-methyl- 1-butyl, 3-methyl-1-butyl, 2-methyl-3-butyl, 2,2-dimethyl-1-propyl, 2-methyl-1-pentyl, 3-methyl-1-pentyl, 4-methyl- 1-pentyl, 2-methyl-2-pentyl, 3-methyl-2-pentyl, 4-methyl-2-pentyl, 2,2-dimethyl-1-butyl, 3,3-dimethyl-1-butyl, 2- Examples include ethyl-1-butyl, butyl, isobutyl, t-butyl, pentyl, isopentyl, neopentyl, and hexyl, and longer alkyl groups such as heptyl and octyl.

  The term “alkyl” refers to groups having any degree or level of saturation, ie, groups having exclusively carbon-carbon single bonds, groups having one or more carbon-carbon double bonds, one or more It is specifically intended to include groups having a carbon-carbon triple bond as well as groups having a mixture of carbon-carbon single, double and triple bonds. Where a specific level of saturation is intended, the expressions “alkanyl”, “alkenyl” and “alkynyl” are used.

  “Alkanyl” by itself or as part of another substituent is a saturated branched, linear or cyclic, obtained by removing one hydrogen atom from one carbon atom of a parent alkane. An alkyl group of “Heteroalkanyl” is included as described above.

  “Alkenyl” by itself or as part of another substituent has an at least one carbon-carbon double bond obtained by removing one hydrogen atom from one carbon atom of the parent alkene. Saturated branched, straight-chain or cyclic alkyl group. This group may be in either cis or trans configuration relative to the double bond. Suitable alkenyl groups include, but are not limited to, (C2-C6) alkenyl groups such as vinyl, allyl, butenyl, pentenyl, hexenyl, butadienyl, pentadienyl, hexadienyl, 2-ethylhexenyl, 2-propyl-2-butenyl. 4- (2-methyl-3-butene) -pentenyl and the like. An alkenyl group can be unsubstituted or substituted with one or more independently selected R groups.

  An `` alkynyl '' is a non-alkyl having itself at least one carbon-carbon triple bond obtained by removing one hydrogen atom from a single carbon atom of the parent alkyne, as part of another substituent. Saturated branched, straight-chain or cyclic alkyl group.

  Also included within the definition of “alkyl” are “substituted alkyl”. “Substituted” is commonly designated herein as “R” and refers to a group in which one or more hydrogen atoms are independently replaced with the same or different substituents. R substituents include, but are not limited to, hydrogen, halogen, alkyl (including substituted alkyl (alkylthio, alkylamino, alkoxy, etc.), cycloalkyl, substituted cycloalkyl, cycloheteroalkyl, and substituted cycloheteroalkyl), aryl (Including substituted aryl, heteroaryl or substituted heteroaryl), carbonyl, alcohol, amino, amide, nitro, ether, ester, aldehyde, sulfonyl, sulfoxyl, carbamoyl, acyl, cyano, thiocyanato, silicon moiety, halogen, sulfur-containing moiety , And can be selected independently from the phosphorus-containing portion and the like. In some embodiments, the R substituent comprises a redox active moiety (ReAM) as described herein. In some embodiments, optionally R and R ′, together with the atoms to which they are attached, include cycloalkyl (including cycloheteroalkyl) and / or cycloaryl (including cycloheteroaryl). These can be further substituted if desired. In the structures depicted herein, R is hydrogen when the position is unsubstituted. Note that some positions may allow 2 or 3 substituents, R, R ′, and R ″, in which case the R, R ′, and R ″ groups may be the same or different. Should.

  In some embodiments, the R group (subunit) is used to modulate the redox potential of the subject compound. Thus, as described more fully below and in the references cited herein, an R group, such as a redox active subunit, can be used to change its redox potential, particularly macrocyclic molecules, particularly porphyrins. Can be added to macrocycles. Certain preferred substituents include, but are not limited to, 4-chlorophenyl, 3-acetamidophenyl, 2,4-dichloro-4-trifluoromethyl, and ferrocene (including ferrocene derivatives). When substituents are used to change the redox potential, preferred substituents provide a redox potential range of less than about 5 volts, preferably less than about 2 volts, more preferably less than about 1 volt.

  In certain embodiments, the R group is as defined and depicted in the figures and text of US Provisional Patent Application No. 60 / 687,464, incorporated herein by reference. Some suitable proligands and complexes, and suitable substituents are described in U.S. Patent No. 6,212,093; U.S. Patent No. 6,728,129; U.S. Patent No. 6,451,942; U.S. Patent No. 6,777,516; U.S. Patent No. 6,381,169; U.S. Patent No. 6,657,884; U.S. Patent No. 6,272,038; U.S. Patent No. 6,484,394; and U.S. Patent Application No. 10 / 040,059; U.S. Patent Application No. 10 / 682,868; U.S. Patent Application No. 10 / 445,977; U.S. Patent Application No. 10 / 834,630; U.S. Patent Application No. 10 / 135,220; U.S. Patent Application No. 10 / 723,315; U.S. Patent Application No. 10 / 456,321; U.S. Patent Application No. 10 / 376,865. All of these, especially those structures and descriptions depicted therein, are expressly incorporated by reference, thereby allowing certain macrocycles with substituents depicted therein, and further For both substituted derivatives, It is explicitly incorporated as an embodiment.

  “Aryl” or grammatical equivalents herein refer to aromatic monocyclic or polycyclic hydrocarbon moieties generally having from 5 to 14 carbon atoms (but larger polycyclic ring structures And any carbocyclic ketone, imine, or thioketone derivative thereof, a carbon atom having a free valence is a member of an aromatic ring. Aromatic groups include arylene groups and aromatic groups from which more than two atoms have been removed. For the purposes of this application, aryl includes heteroaryl. “Heteroaryl” means an aromatic group in which 1 to 5 of the carbon atoms indicated above are replaced with heteroatoms selected from nitrogen, oxygen, sulfur, phosphorus, boron, and silicon; An atom having a free valence is a member of an aromatic ring and any of its heterocyclic ketone and thioketone derivatives. Thus, heterocycles include both monocyclic and polycyclic systems such as thienyl, furyl, pyrrolyl, pyrimidinyl, indolyl, purinyl, quinolyl, isoquinolyl, thiazolyl, imidazolyl, naphthalene, phenanthroline, and the like. Also included within the definition of aryl are substituted aryls having one or more substituents “R” as defined herein and outlined above and herein. For example, “perfluoroaryl” is included, which refers to an aryl group in which all hydrogen atoms are replaced with fluorine atoms. Also included is oxalyl.

  As used herein, the term “halogen” refers to one of the electronegative elements of Group VIIA (fluorine, chlorine, bromine, iodine, and astatine) of the periodic table.

The term “nitro” refers to the —NO ₂ group.

“Amino group” or grammatical equivalents herein means a —NH ₂ , —NHR and NRR ′ group, where R and R ′ are independently as defined herein. is there.

  As used herein, the term “pyridyl” refers to an aryl group in which one CH unit is replaced with a nitrogen atom.

  As used herein, the term “cyano” refers to a —CN group.

  As used herein, the term “thiocyanato” refers to a —SCN group.

  The term `` sulfoxyl '' includes alkyl (cycloalkyl, perfluoroalkyl, etc.) or aryl (e.g., a perfluoroaryl group) composition RS (O)-, where R is defined herein. Which is a substituent as defined). Examples include, but are not limited to, methylsulfoxyl, phenylsulfoxyl, and the like.

The term “sulfonyl” is a composition RSO ₂ — (wherein R is defined herein) having an alkyl, aryl, (including cycloalkyl, perfluoroalkyl, or perfluoroaryl group). Which is a normal substituent). Examples include, but are not limited to, methylsulfonyl, phenylsulfonyl, p-toluenesulfonyl, and the like.

  The term “carbamoyl” refers to a group of the composition R (R ′) NC (O) —, where R and R ′ are as defined herein. Examples include, but are not limited to, N-ethylcarbamoyl, N, N-dimethylcarbamoyl, and the like.

The term “amido” refers to a group of the composition R ₁ CONR ₂ —, where R ₁ and R ₂ are substituents as defined herein. Examples include, but are not limited to, acetamide, N-ethylbenzamide, and the like.

  The term “imine” refers to ═NR.

In certain embodiments, if a metal is designated, for example, as “M” or “M _n ” (where n is an integer), it is recognized that the metal can be accompanied by a counter ion. .

  As used herein and unless otherwise indicated, the term “current measuring device” measures the current generated in an electrochemical cell as a result of applying a specific electric field potential (“voltage”). It is a device that can do.

  As used herein and unless otherwise indicated, the term “aryloxy group” means an —O-aryl group, where aryl is as defined herein. To do. An aryloxy group can be unsubstituted or substituted with one or two suitable substituents. Preferably, the aryl ring of the aryloxy group is a monocyclic ring, which contains 6 carbon atoms and is referred to herein as “(C6) aryloxy”.

As used herein and unless otherwise indicated, the term “benzyl” means —CH ₂ -phenyl.

  As used herein and unless otherwise indicated, the term “carbonyl” group is a divalent group of formula —C (O) —.

  As used herein and unless otherwise indicated, the term “coulometric device” measures the net charge generated while applying a potential field to an electrochemical cell (“voltage”). It is a device that can do.

  As used herein and unless otherwise indicated, the term “cyano” refers to a —CN group.

  As used herein and unless otherwise indicated, the term “different and distinguishable” refers to an entity (atom, molecule, aggregate, subunit, when referring to two or more oxidation states. Etc.) means that the effective charge above can exist in two different states. If the difference between these states exceeds the thermal energy at room temperature, these states are said to be “distinguishable”.

As used herein and unless otherwise indicated, the term “E _1/2 ” means E = E ₀ + (RT / nF) 1 n (D _ox / D _red ) where R is the gas constant, T is temperature in K (Kelvin), n is the number of electrons involved in the process, F is the Faraday constant (96,485 coulombs / mol), D _ox is the diffusion of the oxidizing species a rate, D _red refers to the practical definition of the apparent potential of the redox process as defined by the spreading ratio of the reduced species) (E _0).

  As used herein and unless otherwise indicated, the term “electrically coupled” means that when used with respect to storage molecules and / or storage media and electrodes, electrons are Refers to a bond between a storage medium or molecule and an electrode that travels to or from the electrode to the storage medium / molecule, thereby changing the oxidation state of the storage medium / molecule. As electrical coupling, direct covalent coupling between storage medium / molecule and electrode, indirect covalent coupling (e.g. via a linker), direct or between storage medium / molecule and electrode Mention may be made of indirect ionic bonds or other bonds (eg hydrophobic bonds). Furthermore, the actual binding may not be necessary and the storage medium / molecule may simply be in contact with the electrode surface. Similarly, if the electrode is sufficiently close to the storage medium / molecule so that electron tunneling between the medium / molecule and the electrode is possible, the contact between the electrode and the storage medium / molecule is It is not always necessary.

  As used herein and unless otherwise indicated, the term “electrochemical cell” includes, at a minimum, a reference electrode, a working electrode, a redox active medium (eg, a storage medium), as appropriate. Consisting of any means (eg, a dielectric) for providing electrical conductivity between the electrodes and / or between the electrode and the medium. In some embodiments, the dielectric is a component of the storage medium.

  As used herein and unless otherwise indicated, the term `` electrode '' refers to any medium capable of transporting charge (e.g., electrons) to and / or from a storage molecule. Point to. Preferred electrodes are metals or conductive organic molecules. The electrodes can be fabricated into almost any two-dimensional or three-dimensional shape (eg, discontinuous lines, pads, planes, spheres, cylinders).

  As used herein and unless otherwise indicated, the term “fixed electrode” reflects the fact that the electrode is inherently stable and cannot be moved relative to the storage medium. I intend to. That is, the electrode and the storage medium are arranged in a geometric relationship that is essentially fixed to each other. It is naturally recognized that this relationship changes somewhat due to expansion and contraction of the medium due to thermal changes or due to changes in the configuration of the molecules that make up the electrodes and / or storage medium. Nevertheless, the overall spatial arrangement remains essentially unchanged.

  As used herein and unless otherwise indicated, the term “linker” is used to couple two different molecules, two subunits of a molecule, or a molecule to a substrate. Is a molecule.

  Many of the compounds described herein utilize a substituent that is generally designated herein as “R”. Suitable R groups include, but are not limited to, hydrogen, alkyl, alcohol, aryl, amino, amide, nitro, ether, ester, aldehyde, sulfonyl, silicon moiety, halogen, cyano, acyl, sulfur-containing moiety, phosphorus-containing moiety , Sb, imide, carbamoyl, linker, addition moiety, ReAM and other subunits. Some positions may allow two substituents, R and R ′, in which case the R and R ′ groups may be the same or different, and one of the substituents may be hydrogen. It should be noted that it is generally preferred. In some embodiments, the R group is as defined and shown in US figures and text. Some suitable proligands and complexes, and suitable substituents are described in U.S. Patent No. 6,212,093; U.S. Patent No. 6,728,129; U.S. Patent No. 6,451,942; U.S. Patent No. 6,777,516; U.S. Patent No. 6,381,169; U.S. Patent No. 6,657,884; U.S. Patent No. 6,272,038; U.S. Patent No. 6,484,394; and U.S. Patent Application No. 10 / 040,059; U.S. Patent Application No. 10 / 682,868; U.S. Patent Application No. 10 / 445,977; U.S. Patent Application No. 10 / 834,630; U.S. Patent Application No. 10 / 135,220; U.S. Patent Application No. 10 / 723,315; U.S. Patent Application No. 10 / 456,321; U.S. Patent Application No. 10 / 376,865. All of these, especially those structures and descriptions depicted therein, are expressly incorporated by reference, thereby allowing certain macrocycles with substituents depicted therein, and further For both substituted derivatives, It is explicitly incorporated as an embodiment.

  As used herein and unless otherwise indicated, the term “subunit” refers to the redox active portion of a molecule.

Phosphonium Ionic Liquids, Salts, and Compositions of the Invention As described in detail herein, the novel phosphonium ionic liquids, salts, and composition embodiments of the present invention have desirable properties and particularly high heat. Shows a combination of at least two or more of mechanical stability, low volatility, wide liquid phase range, high ionic conductivity, and wide electrochemical stability window. Combinations up to the desired level within one composition, and in some embodiments, all combinations of these properties at the desired level are unexpected, unexpected, known ions It provides significant advantages over the composition. Embodiments of the phosphonium compositions of the present invention that exhibit such properties enable applications and devices that were not previously available.

  In some embodiments, the phosphonium ionic liquids of the present invention comprise a phosphonium cation having a selected molecular weight and substitution pattern coupled with a selected anion, thereby providing thermodynamic stability, ionic conductivity, An ionic liquid is formed having an adjustable combination of liquid phase range and low volatility properties.

  In some embodiments, “ionic liquid” herein means a salt that is liquid at 100 ° C. or lower. A “room temperature” ionic liquid is further defined herein as being liquid at or below room temperature.

  In other embodiments, the term “electrolyte” or “electrolyte solution” or “electrolyte composition” or “ion electrolyte” or “ion conductive electrolyte” or “ion conductive composition” or “ionic composition” is used. And the term is defined herein as any one or more of the following: (a) an ionic liquid, (b) a room temperature ionic liquid, (c) in at least one solvent One or more salts dissolved, and (d) one or more salts forming a gel electrolyte by dissolving with at least one polymer in at least one solvent. Further, the one or more salts are defined to include: (a) one or more salts that are solid at a temperature of 100 ° C. or lower; and (b) at a temperature of 100 ° C. or lower. One or more salts that are liquids.

  In some embodiments, the present invention includes phosphonium ionic liquids and phosphonium electrolytes that exhibit thermodynamic stability up to a temperature of about 400 ° C., more usually up to a temperature of about 375 ° C. Showing thermal stability to such high temperatures is an important development and allows the use of the phosphonium ionic liquids of the present invention in a wide range of applications. Embodiments of the phosphonium ionic liquids and phosphonium electrolytes of the present invention are at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / at room temperature. It further exhibits an ionic conductivity of cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm. Embodiments of the phosphonium ionic liquids and phosphonium electrolytes of the present invention exhibit volatility that is about 20% lower compared to these nitrogen-based analogs. This combination of high thermal stability, high ionic conductivity, wide liquid phase range, and low volatility was highly desirable and unexpected. In the prior art, it has generally been found that the thermal stability and ionic conductivity of ionic liquids exhibit an inverse correlation.

  In some embodiments, the phosphonium ionic liquid and phosphonium electrolyte are composed of cations having a molecular weight of 500 Daltons or less. In other embodiments, the phosphonium ionic liquid and phosphonium electrolyte are composed of cations having a molecular weight in the range of 200-500 Daltons relative to the ionic liquid in the lower thermal stability region.

The phosphonium ion composition of the present invention has the general formula:
R ¹ R ² R ³ R ⁴ P (1)
(Wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent). In some embodiments, the cation is composed of open chains.

In some embodiments, R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group. In one embodiment, at least one of the alkyl groups is different from the other two. In one embodiment, none of the alkyl groups are methyl. In some embodiments, the alkyl group consists of 2 to 7 carbon atoms, more usually 1 to 6 carbon atoms. In some embodiments, R ¹ , R ² , R ^3, and R ⁴ are each independently a different alkyl group composed of 2-14 carbon atoms. In some embodiments, the alkyl group has no branches. In one embodiment, R ¹ = R ² in the aliphatic, heterocyclic moiety. Alternatively, R ¹ = R ² in the aromatic or heterocyclic moiety.

In some embodiments, R ¹ or R ² is composed of phenyl or substituted alkylphenyl. In some embodiments, R ¹ and R ² are the same and are composed of tetramethylene (phosphorane) or pentamethylene (phosphorinane). Alternatively, R ¹ and R ² are the same and are composed of tetramethynyl (phosphole). In a further embodiment, R ¹ and R ² are the same and are composed of phospholane or phosphorinane. In yet another embodiment, R ² , R ³ and R ⁴ are the same and are composed of phospholane, phosphorinane or phosphole.

In some embodiments, at least one, more than, or all of R ¹ , R ² , R ³ and R ⁴ have a functional group that reacts with a redox active molecule (ReAM) as described below. Each is chosen not to have. In some embodiments, at least one, more or all of R ¹ , R ² , R ³ and R ⁴ do not contain halide, metal or O, N, P, or Sb.

  In some embodiments, the alkyl group contains 1-7 carbon atoms. In another embodiment, the total number of carbon atoms in all alkyl groups is 12 or less. In still other embodiments, each alkyl group is independently composed of 1-6 carbon atoms, more usually 1-5 carbon atoms.

In another embodiment, a phosphonium ion composition is provided, the phosphonium ion composition being composed of one or more salts dissolved in a solvent, the one or more salts having the general formula:
R ¹ R ² R ³ R ⁴ P (1)
One or more of the formulas wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent such as, but not limited to, an alkyl group as described below A phosphonium-based cation and one or more anions. In some embodiments, R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group composed of 1 to 6 carbon atoms, more usually 1 to 4 carbon atoms. It is. In some embodiments, one or more of the hydrogen atoms in one or more of the R groups are substituted with fluorine. Any one or more of the salts may be liquid or solid at a temperature of 100 ° C. or lower. In some embodiments, the salt is composed of one cation and one anion. In other embodiments, the salt is composed of one cation and multiple anions. In other embodiments, the salt is composed of one anion and multiple cations. In a further embodiment, the salt is composed of multiple cations and multiple anions. Exemplary embodiments of suitable solvents include, but are not limited to, one or more of the following: acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC) or methyl ethyl carbonate (MEC), methyl propionate (MP), fluoroethylene carbonate (FEC), fluorobenzene (FB), vinylene carbonate (VC), Vinyl ethylene carbonate (VEC), phenyl ethylene carbonate (PhEC), propyl methyl carbonate (PMC), diethoxyethane (DEE), dimethoxyethane (DME), tetrahydrofuran (THF), γ-butyrolactone (GBL), and γ-valero Lactone (GVL).

  In an exemplary embodiment, the phosphonium cation is composed of the following formula:

  In another exemplary embodiment, the phosphonium cation is composed of the following formula:

  In yet another exemplary embodiment, the phosphonium cation is composed of the following formula:

  In a further exemplary embodiment, the phosphonium cation is composed of the following formula:

  In a further exemplary embodiment, the phosphonium cation is composed of the following formula:

  In a further exemplary embodiment, the phosphonium cation is composed of the following formula:

  In a further exemplary embodiment, the phosphonium cation is composed of the following formula:

  In another exemplary embodiment, the phosphonium cation is composed of the following formula:

  In a further exemplary embodiment, the phosphonium cation is composed of the following formula:

  In yet another exemplary embodiment, the phosphonium cation is composed of the following formula:

  In yet another exemplary embodiment, the phosphonium cation is composed of the following formula:

  Another exemplary embodiment provides a phosphonium cation composed of the following formula:

  Further provided are phosphonium cations composed of the following formula:

  In some embodiments, examples of suitable phosphonium cations include, but are not limited to, di-n-propylethylphosphonium; n-butyl n-propylethylphosphonium; n-hexyl n-butylethylphosphonium, and the like. .

  In other embodiments, examples of suitable phosphonium cations include, but are not limited to, ethylphosphorane; n-propylphosphorane; n-butylphosphorane; n-hexylphosphorane; and phenylphosphorane.

  In further embodiments, examples of suitable phosphonium cations include, but are not limited to, ethyl phosphole; n-propyl phosphole; n-butyl phosphole; n-hexyl phosphole; and phenyl phosphole.

  In yet another embodiment, examples of suitable phosphonium cations include, but are not limited to, 1-ethyl phosphacyclohexane; n-propyl phosphacyclohexane; n-butyl phosphacyclohexane; n-hexyl phosphacyclohexane; and And phenylphosphacyclohexane.

The phosphonium ionic liquid or salt of the present invention is composed of a cation and an anion. There will be a wide variety of possible cation and anion combinations, as will be appreciated by those skilled in the art. The phosphonium ionic liquid or salt of the present invention comprises a cation as described above having the general formula:
C ⁺ A ^-
(Where C ⁺ is a cation and A ⁺ is an anion) with an anion generally selected from compounds that are readily ion exchanged with reagents or solvents. In the case of organic solvents, C ⁺ is preferably Li ⁺ , K ⁺ , Na ⁺ , NH ₄ ⁺ or Ag ⁺ . In the case of an aqueous solvent, C ⁺ is preferably Ag ⁺ .

Many anions can be selected. In one preferred embodiment, the anion is bis-perfluoromethylsulfonylimide. Exemplary embodiments of suitable anions include, but are not limited to, any one or more of the following: NO ₃ ⁻ , O ₃ SCF ₃ ⁻ , N (SO ₂ CF ₃ ) ₂ ⁻ , ^{_{PF 6 -, O 3 SC 6}} H 4 CH 3 -, O 3 SCF 2 CF 2 CF 3 -, O 3 SCH 3 -, I -, C (CN) 3 -, - O 3 SCF 3, - N (SO _{2) 2 CF 3, CF 3} BF 3 -, - O 3 SCF 2 CF 2 CF 3, SO 4 2-, - O 2 CCF 3, - O 2 CCF 2 CF 2 CF 3, or ^- N (CN) ₂ .

  In some embodiments, the phosphonium ionic liquids or salts of the invention are composed of a single cation-anion pair. Alternatively, two or more phosphonium ionic liquids or salts can be used to form a common binary system, a mixed binary system, a common ternary system, a mixed ternary system, and the like. Composition ranges for binary, ternary, etc. include from 1 ppm to 999,999 ppm for each component cation and each component anion. In another embodiment, the phosphonium electrolyte is composed of one or more salts dissolved in a solvent, and the salts may be liquid or solid at a temperature of 100 ° C. In some embodiments, the salt is composed of a single cation-anion pair. In other embodiments, the salt is composed of one cation and multiple anions. In other embodiments, the salt is composed of one anion and multiple cations. In still other embodiments, the salt is composed of multiple cations and multiple anions.

  In a preferred embodiment, the phosphonium ionic liquid composition is composed of a combination of cations and anions as shown in Tables 1A and 1B below. In another preferred embodiment, the phosphonium electrolyte is composed of combinations of cations and anions as shown in Table 1C, Table 1D, Table 1E and Table 1F below. For clarity, the sign of the charge is omitted in the formula.

  Table 1A illustrates an example of an anionic binary system having a common cation:

  Table 1B illustrates examples of combinations of cations and anions:

  In another embodiment, the phosphonium electrolyte composition is composed of salts with cations as shown in Tables 1C-1 to 1C-3 below:

  In another embodiment, the phosphonium electrolyte is comprised of a salt having an anion as shown in Tables 1D-1 to 1D-4 below:

  In a further embodiment, the phosphonium electrolyte composition is comprised of a salt having a combination of cations and anions as shown in Tables 1E-1 to 1E-4 below:

In some embodiments, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising one or more cations of the following formula:
P (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _4-xy (x, y = 0 to 4 and x + y ≦ 4)
P (CF ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _4-xy (x, y = 0 to 4 and x + y ≦ 4)
P (-CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (x, y = 0-2, x + y (≦ 2)
P (-CH ₂ CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (x, y = 0-2, x + y ≦ 2),
And one or more anions of the following formula:
(CF ₃ ) _x BR _4-x (x = 0 ~ 4)
(CF ₃ (CF ₂ ) _n ) _x PF _6-x (n = 0-2, x = 0-4)
(-OCO (CH ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (n = 0-2, x = 0-2)
(-OCO (CF ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (n = 0-2, x = 0-2)
(-OCO (CH ₂ ) _n COO-) ₂ B (n = 0 to 2)
(-OCO (CF ₂ ) _n COO-) ₂ B (n = 0-2)
(-OOR) _x (CF ₃ ) BF _3-x (where x = 0 to 3)
(-OCOCOCOO-) (CF ₃ ) _x BF _2-x (x = 0 ~ 2)
(-OCOCOCOO-) ₂ B
(-OSOCH ₂ SOO-) (CF ₃ ) _x BF _2-x (x = 0 ~ ₂ )
(-OSOCF ₂ SOO-) (CF ₃ ) _x BF _2-x (where x = 0 to 2)
(-OCOCOO-) _x (CF ₃ ) _y PF _6-2x-y (x = 1-3, y = 0-4, 2x + y ≦ 6)
Consists of.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt having the formula:
P (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _4-xy (where x, y = 0 to 4 and x + y ≦ 4)
One or more cations of
And the formula:
(CF ₃ ) _x BF _4-x (where x = 0 to 4)
(CF ₃ (CF ₂ ) _n ) _x PF _6-x (where n = 0 to 2 and x = 0 to 4)
(-OCO (CH ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (where n = 0 to 2 and x = 0 to 2)
(-OCO (CH ₂ ) _n COO-) ₂ B (where n = 0 to 2)
(-OSOCH ₂ SOO-) (CF ₃ ) _x BF _2-x (where x = 0 to 2)
(-OCOCOO-) _x (CF ₃ ) _y PF _6-2x-y (x = 1-3, y = 0-4, 2x + y ≦ 6)
Of one or more anions.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt having the formula:
P (-CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (where x, y = 0 to 2, x + y ≦ 2)
P (-CH ₂ CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (where x, y = 0 to 2 Yes, x + y ≦ 2)
One or more cations and formula:
(CF ₃ ) _x BF _4-x (where x = 0 to 4)
(CF ₃ (CF ₂ ) _n ) _x PF _6-x (where n = 0 to 2 and x = 0 to 4)
(-OCO (CH ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (where n = 0 to 2 and x = 0 to 2)
(-OCO (CH ₂ ) _n COO-) ₂ B (where n = 0 to 2)
(-OSOCH ₂ SOO-) (CF ₃ ) _x BF _2-x (where x = 0 to 2)
(-OCOCOO-) _x (CF ₃ ) _y PF _6-2x-y (x = 1-3, y = 0-4, 2x + y ≦ 6)
Of one or more anions.

In one embodiment, the phosphonium electrolyte is composed of a salt dissolved in a solvent, which is PF ₆ , (CF ₃ ) ₃ PF ₃ , (CF ₃ ) ₄ PF ₂ , (CF ₃ CF ₂ ) ₄ PF ₂ , (CF ₃ CF ₂ CF ₂ ) ₄ PF ₂ , (-OCOCOO-) PF ₄ , (-OCOCOO-) (CF ₃ ) ₃ PF, (-OCOCOO-) ₃ P, BF ₄ , CF ₃ BF ₃ , (CF ₃ ) ₂ BF ₂ , (CF ₃ ) ₃ BF, (CF ₃ ) ₄ B, (-OCOCOO-) BF ₂ , (-OCOCOO-) BF (CF ₃ ), (-OCOCOO-) (CF ₃ ) ₂ B, (-OSOCH ₂ SOO-) BF ₂ , (-OSOCF ₂ SOO-) BF ₂ , (-OSOCH ₂ SOO-) BF (CF ₃ ), (-OSOCF ₂ SOO-) BF (CF ₃ ), ( -OSOCH ₂ SOO-) B (CF ₃ ) ₂ , (-OSOCF ₂ SOO-) B (CF ₃ ) ₂ , CF ₃ SO ₃ , (CF ₃ SO ₂ ) ₂ N, (-OCOCOO-) ₂ PF ₂ , (CF ₃ CF ₂ ) ₃ PF ₃ , (CF ₃ CF ₂ CF ₂ ) ₃ PF ₃ , (-OCOCOO-) ₂ B, (-OCO (CH ₂ ) _n COO-) BF (CF ₃ ), (-OCOCR ₂ COO-) BF (CF ₃ ), (-OCOCR ₂ COO-) B (CF ₃ ) ₂ , (-OCOCR ₂ COO-) ₂ B, CF ₃ BF (-OOR) ₂ , CF ₃ B (-OOR) ₃ , CF ₃ B (-OOR) F ₂ , (-OCOCOCOO-) BF (CF ₃ ), (-OCOCOCOO-) B (CF ₃ ) ₂ , (-OCOCOCOO-) ₂ B, (-OCOCR ¹ R ² CR ¹ R ² COO-) BF (CF ₃ ), and (-OCOCR ¹ R ² CR ¹ R ² COO-) B (CF ₃ ) _{2 wherein} R, R ¹ , and R ² are each independently one or more anions selected from the group consisting of H or F.

In one embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of the formula: (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P ⁺ and the formula ^{_{: BF 4 -, PF 6 -}} , CF 3 BF 3 -, (- OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 ^{_{-, C (CN) 3 -}} , (CF 3 SO 2) 2 N - consists of or any one or more anions of these combinations.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ ) (CH ₃ CH ₂ ) ₃ P ⁺ and a formula BF ₄ ⁻ , PF ₆ ⁻ , ^{_{CF 3 BF 3 -, (-}} OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, It is composed of (CF ₃ SO ₂ ) ₂ N ^- or any one or more anions of these combinations.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) ₃ P ⁺ and formula BF ₄ ⁻ , ^{_{PF 6 -, CF 3 BF 3}} -, (- OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN ) ₃ ⁻ , (CF ₃ SO ₂ ) ₂ N ⁻ or a combination of any one or more anions thereof.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ CH ₂ CH ₂ ) ₃ (CH ₃ ) P ⁺ and a formula BF ₄ ⁻ , PF _{6. ^{-, CF 3 BF 3 -,}} (- OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 ^- , (CF ₃ SO ₂ ) ₂ N ^- or a combination of any one or more anions thereof.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ CH ₂ CH ₂ ) ₃ (CH ₃ CH ₂ ) P ⁺ and a formula BF ₄ ⁻ , ^{_{PF 6 -, CF 3 BF 3}} -, (- OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN ) ₃ ⁻ , (CF ₃ SO ₂ ) ₂ N ⁻ or a combination of any one or more anions thereof.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ CH ₂ CH ₂ ) ₂ (CH ₃ CH ₂ ) (CH ₃ ) P ⁺ and a formula ^{_{BF 4 -, PF 6 -,}} CF 3 BF 3 -, (- OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 - , C (CN) ₃ ⁻ , (CF ₃ SO ₂ ) ₂ N ^−, or a combination thereof, and any one or more anions.

In another embodiment, the phosphonium electrolyte is comprised of a salt dissolved in a solvent, the salt comprising a cation of formula (CH ₃ CH ₂ ) ₄ P ⁺ and a formula BF ₄ ⁻ , PF ₆ ⁻ , CF ₃ BF _{3. ^{-, (- OCOCOO-) BF 2}} -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO ₂ ) It is composed of one or more anions of ₂ N ^- or combinations thereof.

In a further embodiment, the phosphonium electrolyte is composed of a salt dissolved in a solvent, which salt has the formula (CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ P / (CH in a 1: 3: 1 molar ratio. _{3 CH 2 CH 2) (CH} 3 CH 2) (CH 3) 2 P / (CH 3 CH 2 CH 2) (CH 3 CH 2) 2 (CH 3) P cations and formula BF ₄ ^-, PF ₆ ^{- _{, CF 3 BF 3 -, (}} - OCOCOO-) BF 2 -, (- OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 - , (CF ₃ SO ₂ ) ₂ N ^- or a combination of any one or more anions thereof. In some embodiments, the anion is a mixture of BF ₄ ⁻ and CF ₃ BF ₃ ⁻ at a concentration ratio of [BF ₄ ⁻ ]: [CF ₃ BF ₃ ⁻ ] ranging from 100/1 to 1/1. Composed. In another embodiment, the anion is composed of a mixture of PF ₆ ⁻ and CF ₃ BF ₃ ⁻ at a concentration ratio of [PF ₆ ⁻ ]: [CF ₃ BF ₃ ⁻ ] ranging from 100/1 to 1/1. Is done. In yet a further embodiment, the anion is comprised of a mixture of PF ₆ ⁻ and BF ₄ ⁻ at a concentration ratio of [PF ₆ ⁻ ]: [BF ₄ ⁻ ] in the range of 100/1 to 1/1.

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 2 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 3 below:

  In a further preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 4 below:

  In yet a further preferred embodiment, the phosphonium ionic liquid composition is composed of a combination of cations and anions as shown in Table 5 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 6 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 7 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 8 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 9 below:

  In another preferred embodiment, the phosphonium ionic liquid composition is composed of combinations of cations and anions as shown in Table 10 below:

  Further preferred embodiments include phosphonium ionic liquid compositions composed of combinations of cations and anions as shown in Table 11 below:

  Further preferred embodiments of phosphonium ionic liquid compositions composed of combinations of cations and anions as shown in Table 12 below are provided:

  Another preferred exemplary embodiment includes a phosphonium ionic liquid composition composed of a combination of cations and anions as shown in Table 13 below:

  In some embodiments, additional examples of suitable phosphonium ionic liquid compositions include, but are not limited to, di-n-propylethylmethylphosphonium bis- (trifluoromethylsulfonyl) imide; n-butyl n-propyl And ethylmethylphosphonium bis- (trifluoromethylsulfonyl) imide; n-hexyl n-butylethylmethylphosphonium bis- (trifluoromethylsulfonyl) imide and the like.

  Examples of suitable phosphonium ionic liquid compositions include, but are not limited to, 1-ethyl-1-methylphosphoranium bis- (trifluoromethylsulfonyl) imide; n-propylmethylphosphoranium bis- (trifluoromethyl N-butylmethylphosphoranium bis- (trifluoromethylsulfonyl) imide; n-hexylmethylphosphoranium bis- (trifluoromethylsulfonyl) imide; and phenylmethylphosphoranium bis- (trifluoromethyl) Further included are sulfonyl) imides.

  In another embodiment, examples of suitable phosphonium ionic liquid compositions include, but are not limited to, 1-ethyl-1-methylphosphoranium bis- (trifluoromethylsulfonyl) imide; n-propylmethylphosphoranium Bis- (trifluoromethylsulfonyl) imide; n-butylmethylphosphoranium bis- (trifluoromethylsulfonyl) imide; n-hexylmethylphosphoranium bis- (trifluoromethylsulfonyl) imide; and phenylmethylphosphoranium Bis- (trifluoromethylsulfonyl) imide is mentioned.

  Further exemplary embodiments of suitable phosphonium ionic liquid compositions include, but are not limited to, 1-ethyl-1-methylphosphacyclohexanebis- (trifluoromethylsulfonyl) imide; n-propylmethylphosphacyclohexanebis -(Trifluoromethylsulfonyl) imide; n-butylmethylphosphacyclohexanebis- (trifluoromethylsulfonyl) imide; n-hexylmethylphosphacyclohexanebis- (trifluoromethylsulfonyl) imide; and phenylmethylphosphacyclohexanebis -(Trifluoromethylsulfonyl) imide is mentioned.

  The phosphonium ionic liquids of the present invention may also form eutectics from one or more solids, or solids and liquids, according to some embodiments. In this case, the term “ionic liquid” is further defined to include ionic liquids that are ionic solids or eutectics originating from ionic liquids and ionic solids, such as binary, ternary, etc.

Redox Active Molecules The phosphonium ionic liquids of the present invention described herein can be utilized to synthesize a wide range of hybrid components and / or devices, such as memory devices and elements. In exemplary embodiments, the phosphonium ionic liquids herein are used to form molecular memory devices in which information is stored in redox active information storage molecules.

  As used herein, the term “redox active molecule (ReAM)” is intended to refer to a molecule or component of a molecule that can be oxidized or reduced, eg, by applying an appropriate voltage. As described below, ReAM can include macrocycles, including but not limited to porphyrins and porphyrin derivatives, and non-macrocyclic compounds, including sandwich compounds such as those described herein. And the like. In certain embodiments, the ReAM can include multiple subunits, such as in the case of a dyad or triad. Examples of ReAM include ferrocene, Bipy, PAH, and viologen. In general, as described below, there are several types of ReAM useful in the present invention, all based on multidentate proligands, including macrocyclic and non-macrocyclic moieties. Some suitable proligands and complexes, and suitable substituents are described in U.S. Patent No. 6,212,093; U.S. Patent No. 6,728,129; U.S. Patent No. 6,451,942; U.S. Patent No. 6,777,516; U.S. Patent No. 6,381,169; U.S. Patent No. 6,657,884; U.S. Patent No. 6,272,038; U.S. Patent No. 6,484,394; and U.S. Patent Application No. 10 / 040,059; U.S. Patent Application No. 10 / 682,868; U.S. Patent Application No. 10 / 445,977; U.S. Patent Application No. 10 / 834,630; U.S. Patent Application No. 10 / 135,220; U.S. Patent Application No. 10 / 723,315; U.S. Patent Application No. 10 / 456,321; U.S. Patent Application No. 10 / 376,865. All of these, and in particular their structure and description shown therein, are expressly incorporated by reference.

  Suitable proligands fall into two categories: ligands that use nitrogen, oxygen, sulfur, carbon or phosphorus atoms (depending on the metal ion) as coordination atoms (in the literature sigma (σ) donors and generally And organometallic ligands, such as metallocene ligands (commonly referred to in the literature as pi (π) donors and represented herein as Lm).

  In addition, a single ReAM can have more than one redox activity. For example, FIG. 13A of US Patent Application Publication No. 2007/0108438 shows two redox active subunits, porphyrin (shown in the absence of metal), and ferrocene. Similarly, a sandwich coordination compound is considered a single ReAM. This is distinguished from the case where these ReAMs are polymerized as monomers. Furthermore, the metal ions / complexes of the present invention may be accompanied by counter ions not generally shown herein.

Macrocyclic Ligand In one embodiment, ReAM is a macrocyclic ligand, which includes both macrocyclic proligands and macrocyclic complexes. As used herein, “macrocyclic proligands” contain donor atoms (sometimes referred to herein as “coordinating atoms”) that are oriented so that they can bind to metal ions, and surround metal atoms. Means a cyclic compound having a sufficient size. Generally, the donor atom is a heteroatom including, but not limited to, nitrogen, oxygen and sulfur, with nitrogen being particularly preferred. However, as will be appreciated by those skilled in the art, different metal ions preferentially bind to different heteroatoms, and thus the heteroatoms used can vary depending on the desired metal ion. Further, in some embodiments, a single macrocycle can contain different types of heteroatoms.

  A “macrocyclic complex” is a macrocyclic proligand having at least one metal ion, and in some embodiments, the macrocyclic complex comprises a single metal ion, but is described below. As such, multinuclear complexes including polynuclear macrocyclic complexes are also envisioned.

  A wide variety of macrocyclic ligands have found use in the present invention, including those that are electronically conjugated and those that may not, but the macrocyclic ligands of the present invention are preferably Has at least one, preferably two or more oxidation states, with 4, 6 and 8 oxidation states being particularly significant.

A rough schematic of a suitable macrocyclic ligand is shown and described in FIGS. 11 and 14 of US Patent Application Publication No. 2007/0108438, all in addition to FIGS. It is incorporated in the description. In this embodiment, which is largely based on porphyrins, a 16-membered ring (either carbon or heteroatom if the -X- moiety contains one atom), a 17-membered ring (two of the -X- moieties are two 18-membered ring (when two of the -X- moieties contain two skeleton atoms), 19-membered ring (three of the -X- moieties contain two skeletal atoms) ) Or 20-membered rings (when all four of the -X- moieties contain two skeletal atoms) are envisioned. Each -X- group is independently selected. The -Q- moiety, together with the backbone -C-heteroatom-C (having either a single bond or a double bond to independently bond the carbon and heteroatom), is one or two (In the case of a 5-membered ring) or 1, 2 or 3 (in the case of a 6-membered ring) form a 5- or 6-membered ring optionally substituted with independently selected R ² groups. In some embodiments, the rings, bonds, and substituents are chosen such that the compound is electronically conjugated as a result and has at least two oxidation states.

  In some embodiments, the macrocyclic ligand of the present invention is selected from the group consisting of porphyrins (particularly porphyrin derivatives as defined below) and cyclen derivatives.

Porphyrins A particularly preferred subset of macrocycles suitable in the present invention are porphyrins including porphyrin derivatives. Such derivatives include porphyrins having an additional ring ortho- or ortho-perfused to the porphyrin nucleus, or porphyrins in which one or more carbon atoms of the porphyrin ring are replaced by atoms of another element (skeletal substitution) Derivatives in which the nitrogen atom of the porphyrin ring is replaced by an atom of another element (nitrogen skeleton substitution), a substituent other than hydrogen is a peripheral atom of the porphyrin (meso-, (3- or a derivative located in a nuclear atom, Derivatives with saturation of one or more bonds of porphyrins (including hydroporphyrins such as chlorin, bacteriochlorin, isobacteriochlorin, decahydroporphyrin, colfin, pyrocorphine, etc.), pyrrole units and pyromethenyl units, 1 One or more atoms inserted into the porphyrin ring Conductors (extended porphyrins), derivatives in which one or more groups have been removed from the porphyrin ring (reduced porphyrins, eg choline, corrole) and combinations of the aforementioned derivatives (eg phthalocyanines, subphthalocyanines, and porphyrin isomers) Further suitable porphyrin derivatives include, but are not limited to, etiophyllin, pyroporphyrin, rhodoporphyrin, philoporphyrin, phyloerythrin, chlorophyll groups including chlorophyll a and b, and deuteroporphyrin, Hemoglobin groups including telohemin, hemin, hematin, protoporphyrin, mesohemin, hematoporphyrin, mesoporphyrin, coproporphyrin, uruporphyrin and turacin, and Series Tiger aryl aza di pyro methine and the like.

  As is the case for the compounds outlined herein, and as will be appreciated by those skilled in the art, each unsaturation position is defined herein as either a carbon or a heteroatom. One or more such substituents may be included depending on the desired valence of the system.

  In a preferred embodiment, the redox active molecule can be a metallocene, which can be substituted at any suitable position using the R group independently selected herein. Metallocenes that find particular use in the present invention include ferrocene and its derivatives. In this embodiment, preferred substituents include, but are not limited to, 4-chlorophenyl, 3-acetamidophenyl, 2,4-dichloro-4-trifluoromethyl. Preferred substituents provide a redox potential range of less than about 2 volts.

  It is understood that the oxidation potential of these series members can be varied as usual by changing the metal (M) or substituent.

  Another example of a redox active molecule composed of porphyrins is shown in FIG. 12H of US Patent Application Publication No. 2007/018438 (where F is a redox active subunit (eg, ferrocene, substituted ferrocene, metalloporphyrin, or metallochlorin). J1 is a linker, M is a metal (for example, Zn, Mg, Cd, Hg, Cu, Ag, Au, Ni, Pd, Pt, Co, Rh, Ir, Mn, B, Al, Ga, Pb and Sn etc.), and S1 and S2 are independently aryl, phenyl, cycloalkyl, alkyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, Selected from the group of alkylamino, acyl, sulfoxyl, sulfonyl, imide, amide, and carbamoyl, wherein the substituent has a redox potential range of less than about 2 volts K1, K2, K3 and K4 are independently selected from the group of N, O, S, Se, Te and CH, L is a linker, and X is a substrate, coupling to the substrate And selected from the group of reaction sites that can be ion coupled to the substrate). In preferred embodiments, X or L-X may be an alcohol or thiol. In some embodiments, L-X can be eliminated and replaced with a substituent independently selected from the same group as S1 or S2.

  The control over the hole accumulation and hole hopping characteristics of the redox active unit of the redox active molecule used in the memory device of the present invention allows fine control over the architecture of the memory device.

  Such control is executed by synthetic design. The hole accumulation characteristics depend on the oxidation potential of the redox active unit or subunit that is itself the storage medium used in the device of the present invention or that is used to assemble this storage medium. Hole accumulation properties and redox potentials can be precisely adjusted by selection of the base molecule, the metal to which it is attached, and peripheral substituents (Yang et al. (1999) J. Porphyrins Phthalocyanines, 3: 117-147), this disclosure. Are hereby incorporated by reference.

  For example, in the case of porphyrins, Mg porphyrins are more easily oxidized than Zn porphyrins, and electron-withdrawing or electron-emitting aryl groups can adjust their oxidation properties as expected. Hole hopping occurs between isoenergetic porphyrins in the nanostructure and is mediated through covalent linkers linking the porphyrins (Seth et al. (1994) J. Am. Chem. Soc., 116: 10578-10592 , Seth et al. (1996) J. Am. Chem. Soc., 118: 11194-11207, Strachan et al. (1997) J. Am. Chem. Soc., 119: 11191-11201, Li et al. (1997) J. Am. Mater. Chem., 7: 1245-1262, Strachan et al. (1998) Inorg. Chem., 37: 1191-1201, Yang et al. (1999) J. Am. Chem. Soc., 121: 4008-4018) These disclosures are specifically incorporated herein by reference in their entirety.

  The design of compounds with predicted redox potentials is well known to those skilled in the art. In general, the oxidation potential of a redox active unit or subunit is well known to those skilled in the art and can be examined (see, eg, Handbook of Electrochemistry of the Elements). Furthermore, in general, the effect of various substituents on the redox potential of a molecule is generally additive. Thus, the theoretical oxidation potential can be easily predicted for any potential data storage molecule. The actual oxidation potential, in particular the oxidation potential of the information storage molecule or information storage medium, can be measured according to standard methods. Usually, the oxidation potential is predicted by comparing the experimentally determined oxidation potential of a basic molecule with the oxidation potential of a basic molecule with one substituent and determining the potential shift due to that particular substituent. Is done. The predicted oxidation potential is then obtained from the sum of such substituent-dependent potential shifts for each substituent.

  The suitability of a particular redox active molecule for use in the methods of the present invention can be readily determined. In accordance with the method of the present invention, the molecule of interest is simply polymerized and coupled to a surface (eg, a hydrogen passivated surface). (Eg, in the specification or in US Pat. No. 6,272,038; US Pat. No. 6,212,093; and US Pat. No. 6,208,553, WO 01/03126, or (Roth et al. (2000) Vac. Sci. Technol. B 18: 2359-2364; Roth et al. (2003) J. Am. Chem. Soc. 125: 505-517)) to evaluate the following by performing sinusoidal voltammetry): Can: 1) whether the molecule is coupled to the surface, 2) the extent of the coating, 3) whether the molecule degrades during the coupling procedure, and 4) multiple read / write operations Stability of the molecule against.

  Also included in the definition of “porphyrin” is a porphyrin complex comprising a porphyrin proligand and at least one metal ion. Suitable metals for porphyrin compounds will vary with the heteroatoms used as coordination atoms, but are generally selected from transition metal ions. The term “transition metal” as used herein generally refers to 38 elements in groups 3-12 of the periodic table. Usually, transition metals say that these valence electrons, or the electrons they use to combine with other elements, are present in multiple shells, often resulting in some common oxidation state. Characterized by facts. In certain embodiments, transition metals of the present invention include, but are not limited to, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, zirconium, niobium, molybdenum, technetium, Ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, ruzafodium, and / or their oxides and / or nitrides, and / or alloys, and One or more of the mixtures may be mentioned.

Other macrocycles There are several macrocycles based on cyclene derivatives. FIGS. 17 and 13C of U.S. Patent Application Publication No. 2007/0108438 show several examples based on cyclene / cyclam derivatives that can include skeletal expansion by inclusion of independently selected carbon or heteroatoms. The macrocyclic proligand is shown. In some embodiments, at least one R group is a redox active subunit, preferably electronically conjugated to a metal. In some embodiments, two or more adjacent R ² groups form a ring or an aryl group, including when at least one R group is a redox active subunit.

  Further, in some embodiments, macrocyclic complexes that rely on organometallic ligands are used. In addition to pure organic compounds for use as redox moieties, and various transition metal coordination complexes with δ-bonded organic ligands having donor atoms as heterocyclic or exocyclic substituents, π-bonded organic ligands A wide variety of transition metal organometallic compounds are available (Advanced Inorganic Chemistry, 5th edition, Cotton & Wilkinson, John Wiley & Sons, 1988, Chapter 6; Organometallics, A Concise Introduction, Elschenbroich et al., 2nd edition , 1992, VCH; and Comprehensive Organometallic Chemistry II, A Review of the Literature 1982-1994, edited by Abel et al., 7, 7, 8, 10 and 11, Pergamon Press, which are hereby incorporated by reference. Explicitly incorporated by). Such organometallic ligands include cyclic aromatic compounds such as cyclopentadienide ion [C5H5 (-1)], as well as indenides (classes of metallocenes) that form a class of bis (cyclopentadienyl) metal compounds (ie, metallocenes). Robins et al., J. Am. Chem. Soc. 104: 1882-1893 (1982), and Gassman, including various ring-substituted and ring-fused derivatives such as indenylide) (-1) ions, incorporated by reference. Et al., J. Am. Chem. Soc. 108: 4228-4229 (1986). Of these, ferrocene [(C5H5) 2Fe] and its derivatives are a wide variety of chemicals (Connelly et al., Chem. Rev. 96: 877-910 (1996) incorporated by reference) and electrochemical ( Geiger et al., Advances in Organometallic Chemistry 23: 1-93 and Geiger et al., Advances in Organometallic Chemistry 24: 87, incorporated by reference, are typical examples that have been used for electron transfer or "redox" reactions. . A variety of first, second and third period transition metal metallocene derivatives are useful as redox moieties (and redox subunits). Other potentially suitable organometallic ligands include cyclic arenes, such as benzene, and their ring substituted and fused derivatives to produce bis (arene) metal compounds, among which bis (benzene) chromium Is a typical example. Other acyclic π-bonded ligands, such as allyl (-1) ions, or butadiene, produce potentially suitable organometallic compounds, and all such ligands can be combined with other π-bonded and δ-bonded ligands. Together, it constitutes a general class of organometallic compounds in which a metal carbon bond is present. Electrochemical studies of various dimers and oligomers of such compounds with crosslinked organic ligands and additional non-crosslinked ligands and with and without metal-metal bonds are all useful.

  When the one or more co-ligands are organometallic ligands, the ligand is generally attached via one of the carbon atoms of the organometallic ligand, provided that The addition may be through other atoms to the heterocyclic ligand. Preferred organometallic ligands include metallocene ligands including substituted derivatives and metallocene neophanes (see Cotton and Wilkenson, supra, page 1174). For example, a derivative of a metallocene ligand, such as methylcyclopentadienyl, preferably has a plurality of methyl groups such as pentamethylcyclopentadienyl. By using this, the stability of metallocene is increased. be able to. In some embodiments, the metallocene is derivatized with one or more substituents as outlined herein, particularly to alter the redox potential of the subunit or portion thereof.

  Any combination of ligands can be used as described herein. Preferred combinations include: a) all ligands are nitrogen donor ligands; b) all ligands are organometallic ligands.

Sandwich coordination complex In some embodiments, ReAM is a sandwich coordination complex. The term “sandwich coordination compound” or “sandwich coordination complex” refers to a compound of formula L-Mn-L, where each L is a heterocyclic ligand (as described below) and each M Is a metal, n is 2 or more, most preferably 2 or 3, and each metal is located between a pair of ligands and (depending on the oxidation state of the metal) one or each in each ligand Multiple heteroatoms (usually bonded to multiple heteroatoms, eg 2, 3, 4, 5 etc.). Therefore, a sandwich coordination compound is not an organometallic compound such as ferrocene in which a metal is bonded to a carbon atom. The ligands in the sandwich coordination compound are generally arranged in a stacking direction (i.e. are generally coplanarly oriented and axially aligned with each other, provided that they are relative to each other, It may or may not be rotating about its axis) (see, eg, Ng and Jiang (1997) Chemical Society Reviews 26: 433-442, incorporated by reference). Sandwich coordination complexes include, but are not limited to, “double-decker sandwich coordination compounds” and “triple-decker sandwich coordination compounds”. The synthesis and use of sandwich coordination compounds is described in detail in U.S. Patent No. 6,212,093; U.S. Patent No. 6,451,942; U.S. Patent No. 6,777,516, and the polymerization of these molecules is described in U.S. Patent Application Publication No. 2007/0123618. All of these, especially the individual substituents found to be used in both sandwich complexes and “single macrocycle” complexes, are included herein.

  The term “double-decker sandwich coordination compound” refers to a sandwich coordination compound in which n is 2 as described above, and thus the formula L′-M′-LZ, wherein each of L1 and LZ is the same (Eg, Jiang et al. (1999) J. Porphyrins Phthalocyanines 3: 322-328 and US Pat. No. 6,212,093; US Pat. No. 6,451,942; US Pat. No. 6,777,516) The polymerization of these molecules is described in US Patent Application Publication No. 2007/0123618, which is incorporated herein by reference in its entirety.

  The term “triple-decker sandwich coordination compound” refers to a sandwich coordination compound in which n is 3, as described above, and thus the formula L′-M′LZ-MZ-L3 (where L1, LZ and L3 Each of which may be the same or different, and M1 and MZ may be the same or different) (see, for example, Arnold et al. (1999) Chemistry Letters 483-484 and US Pat. No. 6,212,093). U.S. Patent No. 6,451,942; see U.S. Patent No. 6,777,516), the polymerization of these molecules is described in U.S. Patent Application Publication No. 2007/0123618, which is incorporated herein by reference in its entirety. Have been described.

  In addition, polymers of these sandwich compounds are also useful, including “dyads” and “triads” as described in US Pat. No. 6,212,093; US Pat. No. 6,451,942; US Pat. No. 6,777,516. The polymerization of these molecules, which are included, is described in US Patent Publication No. 2007/0123618, which is incorporated by reference.

Non-macrocyclic proligands and complexes As a general rule, ReAM containing a non-macrocyclic chelator forms a non-macrocyclic chelate by binding to a metal ion, because of the presence of the metal, This is because a plurality of oxidation states can be obtained by binding a plurality of proligands together.

In some embodiments, a nitrogen donating proligand is used. Suitable nitrogen donating proligands are well known in the art and include, but are not limited to, NH ₂ ; NHR; NRR ';pyridine;pyrazine;isonicotinamide;imidazole; substituted derivatives of bipyridine and bipyridine; terpyridine and substituted derivatives Phenanthroline, especially 1,10-phenanthroline (short for phen) and substituted derivatives of phenanthroline such as 4,7-dimethylphenanthroline and dipyridol [3,2-a: 2 ', 3'-c] phenazine ( Dipyridophenazine; 1,4,5,8,9,12-hexaazatriphenylene (short hat); 9,10-phenanthrenequinone diimine (short phi); 1 1,4,5,8-tetraazaphenanthrene (abbreviated tap); 1,4,8,11-tetra-azacyclotetradecane (abbreviated cyclam) and isocyanide. Substituted derivatives including fused derivatives can also be used. It should be noted that macrocyclic ligands that do not coordinately saturate metal ions and require the addition of another proligand are considered non-macrocyclic for this purpose. As those skilled in the art will appreciate, it is possible to form a coordinately saturated compound by covalently adding several “non-macrocyclic” ligands, but Lack of formula skeleton.

  Suitable sigma donating ligands using carbon, oxygen, sulfur and phosphorus are known in the art. For example, suitable sigma carbon donors can be found in Cotton and Wilkenson, Advanced Organic Chemistry, 5th edition, John Wiley & Sons, 1988 (see, e.g., page 38), incorporated herein by reference. Found. Similarly, suitable oxygen ligands include crown ethers, water and others known in the art. Phosphine and substituted phosphines are also suitable, see Cotton and Wilkenson, page 38.

  Oxygen, sulfur, phosphorus and nitrogen donor ligands are added in such a way as to allow the heteroatom to function as a coordination atom.

Multinucleated proligands and complexes Further, some embodiments utilize multidentate ligands that are multinucleated ligands, eg, these multidentate ligands can bind multiple metal ions. These multidentate ligands may be macrocyclic or non-macrocyclic.

  Some suitable proligands and complexes, and suitable substituents are described in U.S. Patent No. 6,212,093; U.S. Patent No. 6,728,129; U.S. Patent No. 6,451,942; U.S. Patent No. 6,777,516; U.S. Patent No. 6,381,169; U.S. Patent No. 6,657,884; U.S. Patent No. 6,272,038; U.S. Patent No. 6,484,394; and U.S. Patent Application No. 10 / 040,059; U.S. Patent Application No. 10 / 682,868; U.S. Patent Application No. 10 / 445,977; U.S. Patent Application No. 10 / 834,630; U.S. Patent Application No. 10 / 135,220; U.S. Patent Application No. 10 / 723,315; U.S. Patent Application No. 10 / 456,321; U.S. Patent Application No. 10 / 376,865. All of these, and in particular their structure and description shown therein, are expressly incorporated by reference.

Applications and Uses of Phosphonium Ionic Liquids or Salts As used herein and unless otherwise indicated, the terms “memory element”, “memory cell” or “memory cell” are used to store information. Refers to an electrochemical cell that can. A preferred “storage cell” is a discontinuous region of the storage medium addressed by at least one, preferably two electrodes (eg, working electrode and reference electrode). A memory cell can be individually addressed (eg, a unique electrode is associated with each memory element), or multiple memory elements can be a single electrode, especially if the oxidation states of different memory elements can be distinguished. Can be addressed. The memory element can optionally include a dielectric (eg, a dielectric impregnated with counter ions).

  As used herein, the term “electrode” refers to any medium capable of transporting charge (eg, electrons) to and / or from a storage molecule. Preferred electrodes include, but are not limited to, Group III elements (including doped and oxidized Group III elements), Group IV elements (including doped and oxidized Group IV elements), Group V elements (doped And oxidized organic group V elements) and transition metals (including transition metal oxides and transition metal nitrides) and metals and conductive organic molecules. The electrodes can be fabricated into almost any two-dimensional or three-dimensional shape (eg, discontinuous lines, pads, planes, spheres, cylinders).

  As used herein and unless otherwise indicated, the term “plural oxidation states” means more than one oxidation state. In a preferred embodiment, the oxidation state may reflect an increase in electrons (reduction) or a loss of electrons (oxidation).

  As used herein and unless otherwise indicated, the term “multiporphyrin array” refers to a macrocycle of porphyrins linked by a discrete number of two or more covalent bonds. The multiporphyrin array may be linear, cyclic, or branched.

  As used herein and unless otherwise indicated, the term “output of an integrated circuit” is generated by one or more integrated circuits and / or one or more integrated circuit components. Refers to voltage or signal.

  As used herein and unless otherwise indicated, the term “present on a single plane” when used in connection with the memory device of the present invention is the subject component (eg, Storage medium, electrodes, etc.) refers to the fact that they reside on the same physical plane of the device (eg, on a single sheet). Components that lie on the same plane can usually be fabricated simultaneously, eg, in a single operation. Thus, for example, all electrodes on a single plane can usually be applied in a single (eg, sputtering) step (assuming they are all made of the same material).

  As used herein and unless otherwise indicated, a potentiometric device is a device capable of measuring the potential across an interface resulting from a difference in the equilibrium concentration of redox molecules in an electrochemical cell.

As used herein and unless otherwise stated, the term “oxidation” refers to the loss of one or more electrons in an element, compound, or chemical substituent / subunit. In the oxidation reaction, electrons are lost by the atoms of the elements involved in the reaction. The charge on these atoms should then be more positive. The electrons are lost from the species undergoing oxidation, and thus the electrons appear as products in the oxidation reaction. Oxidation occurs in the reaction Fe ²⁺ (aqueous) → Fe ³⁺ (aqueous) + e ⁻ because it is an oxidized species, although electrons are clearly generated as “free” entities in the oxidation reaction. This is because electrons are lost from some Fe ²⁺ (aqueous). Conversely, the term reduction refers to the increase of one or more electrons by an element, compound, or chemical substituent / subunit.

  As used herein and unless otherwise stated, the term “oxidation state” refers to an electrically neutral state or an increase in electrons to an element, compound, or chemical substituent / subunit or This refers to the state generated by loss. In a preferred embodiment, the term “oxidation state” refers to a state including a neutral state and any state other than a neutral state caused by an increase or loss (reduction or oxidation) of electrons.

  As used herein and unless otherwise stated, the term “read” or “interrogation” refers to the oxidation state of one or more molecules (eg, molecules comprising a storage medium). Refers to judging.

  As used herein and unless otherwise stated, the term “redox active unit” or “redox active subunit” refers to a molecule or molecule that can be oxidized or reduced by applying an appropriate voltage. Refers to the ingredients.

  As used herein and unless otherwise stated, the term “refresh”, when used in connection with a storage molecule or storage medium, applies the voltage to the storage molecule or storage medium by applying a voltage to the storage molecule or storage medium. Alternatively, it refers to resetting the oxidation state of the storage medium to a predetermined state (for example, the oxidation state in which the storage molecule or storage medium was placed immediately before reading).

  As used herein and unless otherwise stated, the term “reference electrode” refers to one or more electrodes that provide a measurement reference (eg, a specific reference voltage) recorded from the working electrode. Used to point. In a preferred embodiment, the reference electrodes of the memory device of the present invention are at the same potential, although this is not necessarily the case in some embodiments.

  As used herein and unless otherwise noted, a “sinusoidal voltammeter” is a voltammetric device capable of determining the frequency domain characteristics of an electrochemical cell.

  As used herein and unless otherwise stated, the term “memory density” refers to the number of bits per unit volume and / or the number of bits per molecule that can be stored. If the storage medium is said to have a storage density of more than 1 bit per molecule, this preferably means that the storage medium contains molecules that allow a single molecule to store at least 1 bit of information. Refers to the fact that

  As used herein and unless otherwise noted, the term “storage location” refers to a discrete area or area in which a storage medium is located. When addressed with one or more electrodes, the storage location may form a storage cell. However, if two storage locations include essentially the same storage medium and have essentially the same oxidation state, and both storage locations are commonly addressed, they can form a functional storage cell.

  As used herein and unless otherwise stated, the term “storage medium” refers to a composition comprising a memory molecule of the invention, preferably a memory molecule of the invention bound to a substrate.

  The substrate is preferably a solid material suitable for the addition of one or more molecules. The substrate can be formed of materials including but not limited to glass, plastic, silicon, inorganic materials (eg, quartz), semiconductor materials, ceramics, metals, and the like.

  As used herein and unless otherwise stated, the term “voltammetric device” is capable of measuring the current generated in an electrochemical cell as a result of applying a voltage or changing a voltage. It is a device.

  As used herein and unless otherwise noted, a voltage source is any source (eg, molecule, device, circuit, etc.) that can apply a voltage to a target (eg, an electrode).

  As used herein and unless otherwise noted, the term “working electrode” refers to one or more electrodes used to set or read the state of a storage medium and / or storage molecule. Used for.

Devices Some embodiments of the phosphonium ionic liquid compositions of the present invention are useful in forming a variety of hybrid electrical devices. For example, in one embodiment, a device is provided that includes a first electrode, a second electrode, and an electrolyte comprised of an ionic liquid composition, the ionic liquid composition having the general formula:
R ¹ R ² R ³ R ⁴ P
(Wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent), comprising one or more phosphonium-based cations and one or more anions, An electrolyte is electrically coupled to at least one of the first and second electrodes. In some embodiments, the first electrode is composed of a redox active molecule (ReAM) as described in detail above.

  In another embodiment, a molecular storage device comprising a working electrode and a counter electrode configured to provide electrical capacitance, and an ion conductive composition comprising one or more phosphonium-based cations of the above general formula Provided, the ionically conductive composition is electrically coupled to at least the working electrode and the counter electrode.

  In another embodiment, the present invention encompasses a molecular memory element comprising a switching device, bit lines and word lines coupled to the switching device, and a molecular storage device accessible via the switching device. The molecular storage device can be placed in more than one discontinuity, in which case the molecular storage device is placed in one of the discontinuities by a signal applied to the bit and word lines. The molecular storage device includes a first electrode, a second electrode, and a phosphonium-based cation and a suitable anion electrolyte between the first and second electrodes. Another embodiment includes a molecular memory array that includes a plurality of molecular memory elements capable of placing each molecular memory element in two or more discontinuities. The plurality of bit lines and word lines are coupled to the plurality of molecular storage elements such that each molecular storage element is coupled to and addressable by at least one bit line and at least one word line. .

  A molecular memory device may include an addressable array of molecular storage elements. The address decoder receives the coded address and creates a word line signal corresponding to the coded address. The word line driver is coupled with the address decoder and generates an amplified word line signal. The amplified word line signal controls a switch that selectively couples a member of the array of molecular storage elements to the bit line. Read / write logic coupled to the bit line determines whether the molecular memory device is in read or write mode. In the read mode, the sense amplifier coupled to each bit line detects the electronic state of the selectively coupled molecular memory element and outputs a data signal indicating the electronic state of the selectively coupled molecular memory element on the bit line. To generate. In write mode, the read / write logic carries data signals on the bit lines and selectively coupled molecular storage elements.

  Another embodiment includes devices that include logic integrated with an embedded molecular memory device, such as application specific integrated circuit (ASIC) and system on chip (SOC) devices. Such an implementation includes one or more functional components formed monolithically with a molecular memory device and interconnected to the molecular memory device. Functional components may include solid state electronic devices and / or molecular electronic devices.

  In certain embodiments, the molecular storage device is implemented as a stacked structure formed subsequent to and on a semiconductor substrate having an active device formed therein. In other embodiments, the molecular storage device is implemented as a micron or nanometer sized hole in a semiconductor substrate having an active device formed therein. Molecular storage devices are fabricated using processing techniques that are compatible with semiconductor substrates and active devices previously formed in the semiconductor substrates. A molecular storage device includes, for example, an electrochemical cell having two or more electrode surfaces separated by an electrolyte (eg, a ceramic or solid electrolyte). A memory molecule (eg, a molecule having one or more oxidation states that can be used for information to be stored) is coupled to an electrode surface within the electrochemical cell.

  Other embodiments of the invention include transistor switching devices including field effect transistors; row decoders coupled to word lines; column decoders coupled to bit lines; current preamplifiers connected to bit lines; connected to bit lines Sense amplifier, an address decoder that receives a coded address and generates a word line signal corresponding to the coded address, a line driver coupled to the address decoder (the line driver generates an amplified word line signal ( In some cases, the amplified word line signal controls a switch that selectively couples a member of the array of molecular storage elements to the bit line)), and the read / write logic coupled to the bit line (the read / write logic is , Molecular memory A sense amplifier coupled to each bit line (if the device is in read mode, the sense amplifier coupled to each bit line is a selectively coupled numerator). Detects the electronic state of the storage element and generates a data signal on the bit line indicating the electronic state of the selectively coupled molecular storage element (if the device is in write mode, the read / write logic will bit the data signal Including the use of components selected independently from the lines and selectively coupled molecular memory elements))); electrolyte layers; and combinations thereof.

  Further embodiments include a second electrode coupled to the ground and bit and word lines that are either vertical or parallel.

  Further embodiments have the memory array of the present invention including volatile memory such as DRAM or SRAM, or non-volatile memory such as flash or ferroelectric memory.

  In a further embodiment, the molecular storage device includes an additional layer formed on the first electrode, the additional layer includes an opening, the molecular material is in the opening, and the first layer is formed on the additional layer. An array is provided that is electronically coupled to the two electrode layers and the electrolyte layer.

  Another embodiment includes a monolithically integrated device that includes a logic device configured to perform a particular function and an implantable molecular memory device of the present invention coupled to the logic device. The device may optionally include an application specific integrated circuit (ASIC), system on chip (SOC), solid state electronic device or molecular electronic device.

  The memory device of the present invention can be fabricated using standard methods well known to those skilled in the art. In a preferred embodiment, following standard well-known methods (see, e.g., Rai-Choudhury (1997) The Handbook of Microlithography, Micromachining, and Microfabrication, SPIE Optical Engineering Press; Bard & Faulkner (1997) Fundamentals of Microfabrication). Apply the electrode layer to a suitable substrate (eg, silica, glass, plastic, ceramic, etc.) Various methods include: US Patent No. 6,212,093; US Patent No. 6,728,129; US Patent No. 6,451,942; US Patent No. 6,777,516; US Patent No. 6,381,169; US Patent No. 6,208,553; US Patent No. 6,657,884; No. 6,272,038; U.S. Patent No. 6,484,394; and U.S. Patent Application No. 10 / 040,059; U.S. Patent Application No. 10 / 682,868; U.S. Patent Application No. 10 / 445,977; U.S. Patent Application No. 10 / 834,630; U.S. Patent Application U.S. Patent Application No. 10 / 723,315; U.S. Patent Application No. 10 / 456,321; U.S. Patent Application No. 10 / 376,865; and U.S. Patent Application Publication No. 2007/0123618, All of these, especially the fabrication methods outlined there, are expressly incorporated herein by reference.

  There are a wide variety of device and system architectures that benefit from the use of molecular memory.

  The memory device operates by receiving an N-bit row address in the row address decoder and an M-bit column address in the column address decoder. The row address decoder generates a signal on one word line. The word line may include a word line driver circuit that carries a high current signal on the word line. Because wordlines tend to be long and thin conductors that extend over most of the chip surface, a significant amount of current and a large power switch are required to carry the wordline signal. As a result, line driver circuits often include a power supply in addition to a power supply circuit (not shown) that provides operating power to other logic. Thus, word line drivers tend to include large components, and high-speed switching of large currents tends to create noise, press the limits of power supplies and power regulators, and press isolated structures.

  A conventional storage array has more columns (bit lines) than rows (word lines) because each word line becomes active during a refresh operation and is coupled to that word line. This is because all of the storage elements that have been refreshed are refreshed. Thus, the smaller the number of rows, the less time is required to refresh all of the rows. One feature of the present invention is that molecular memory devices have data retention on the order of 10 seconds, 100 seconds, 1000 seconds, or effectively an unlimited number of seconds, much longer than normal capacitors. It can be configured to show. Thus, the refresh cycle can be carried out with a frequency that is several orders of magnitude lower or can be omitted altogether. Thus, the refresh considerations that actually affect the physical layout of the memory array can be relaxed and various shaped arrays can be implemented. For example, a memory array can be easily manufactured with a larger number of word lines, which makes each word line shorter. As a result, less current is required to carry each word line at high speed, and the word line driver circuit can be reduced or eliminated. Alternatively or additionally, read / write access time can be improved by driving shorter word lines faster. As yet another alternative, a mechanism for storing multiple states of information in each memory location can be obtained by providing each row of memory locations with multiple word lines.

  The sense amplifier is coupled to each bit line and operates to detect a signal on the bit line 109 that indicates the state of the memory element coupled to that bit line and amplifies the state to a signal of an appropriate logic level. To do. In one embodiment, the sense amplifier may be implemented with a substantially conventional design because such a conventional design operates to detect and amplify signals from molecular memory devices. Because it becomes. Instead, unlike conventional capacitors, some molecular storage elements provide highly characteristic signals that indicate these states. These characteristic signals can be more easily and reliably latched by the read / write logic buffer than the state signal from the molecular storage device is stored in the conventional capacitor, so that conventional sense amplifier logic The need for can be reduced. That is, the present invention can provide a device that is large enough to eliminate the need for a sense amplifier.

  The read / write logic includes circuitry for placing the memory device in a read or write state. In the read state, data from the molecular array is placed on the bit line (with or without the activation of the sense amplifier) and captured by the read / write logic buffer / latch. The column address decoder will select which bit line is active in a particular read operation. In a write operation, the read / write logic causes the data signal on the selected bit line to overwrite any data already stored in the memory element that the data addressed when the word line becomes active. carry.

  The refresh operation is substantially similar to the read operation, but the word line is driven by a refresh circuit (not shown) rather than an externally applied address. In a refresh operation, if a sense amplifier is used, it drives the bit line to a signal level that indicates the current state of the memory element, and its value is automatically rewritten to the memory element. Unlike the read operation, the bit line state is not coupled to the read / write logic during the refresh. This operation is required only when the charge retention time of the molecules used is shorter than the operating life of the device used (eg, about 10 years for flash memory).

  In an exemplary embedded system that includes a central processing unit and molecular memory, the memory bus exchanges address, data, and control signals by coupling with the CPU and molecular memory devices. In some cases, the embedded system may also include a conventional memory coupled to a memory bus. Conventional memory may include random access memory (eg, DRAM, SRAM, SDRAM, etc.) or read only memory (eg, ROM, EPROM, EEPROM, etc.). These other types of memory can be useful for caching data molecular memory devices, storing operating system or BIOS files, and so on. The embedded system may include one or more input / output (I / O) interfaces that allow the CPU to communicate with external devices and systems. The I / O interface may be implemented by a serial port, a parallel port, a radio frequency port, an optical port, an infrared port, or the like. Further, the interface may be configured to communicate using any available protocol, including packet-based protocols.

Batteries The phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are very suitable as electrolytes in battery applications. In one embodiment, a battery is provided that includes an anode (cathode), a cathode (anode), a separator between the anode and cathode, and an electrolyte. The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more ionic liquids or salts dissolved in a liquid composition or solvent. In some embodiments, R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group composed of 1 to 6 carbon atoms, more usually 1 to 4 carbon atoms. It is. Any one or more of the salts may be liquid or solid at a temperature of 100 ° C. or lower. In some embodiments, the salt is composed of one cation and one anion pair. In other embodiments, the salt is composed of one cation and multiple anions. In other embodiments, the salt is composed of one anion and multiple cations. In a further embodiment, the salt is composed of multiple cations and multiple anions. In one embodiment, the electrolyte is composed of an ionic liquid having one or more phosphonium-based cations and one or more anions, the ionic liquid composition having a thermodynamic stability below 375 ° C. , Liquid phase range above 400 ° C. and ionic conductivity at room temperature of at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm. In another embodiment, the electrolyte is comprised of one or more salts dissolved in a solvent having one or more phosphonium-based cations and one or more anions, the electrolyte composition comprising: At room temperature, at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm The ionic conductivity of is shown.

  A battery comprising an electrolyte composition according to embodiments of the present invention is disclosed in co-pending US patent application ______________________________________________ This is further described in reference number 057472-060).

In some embodiments, the electrolyte composition is comprised of one or more of the following, but not limited to: acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC ), Dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC) or methyl ethyl carbonate (MEC), methyl propionate (MP), fluoroethylene carbonate (FEC), fluorobenzene (FB), vinylene carbonate (VC), vinyl ethylene carbonate (VEC), phenyl ethylene carbonate (PhEC), propyl methyl carbonate (PMC), diethoxyethane (DEE), dimethoxyethane (DME), tetrahydrofuran (THF), γ-butyrolactone (GBL), And γ-valerolactone (GVL).

In some embodiments, the electrolyte composition comprises PF ₆ , (CF ₃ ) ₃ PF ₃ , (CF ₃ ) ₄ PF ₂ , (CF ₃ CF ₂ ) ₄ PF ₂ , (CF ₃ CF ₂ CF ₂ ) ₄ PF ₂ , (-OCOCOO-) PF ₄ , (-OCOCOO-) (CF ₃ ) ₃ PF, (-OCOCOO-) ₃ P, BF ₄ , CF ₃ BF ₃ , (CF ₃ ) ₂ BF ₂ , (CF ₃ ) ₃ BF, (CF ₃ ) ₄ B, (-OCOCOO-) BF ₂ , (-OCOCOO-) BF (CF ₃ ), (-OCOCOO-) (CF ₃ ) ₂ B, (-OSOCH ₂ SOO-) BF ₂ , (-OSOCF ₂ SOO-) BF ₂ , (-OSOCH ₂ SOO-) BF (CF ₃ ), (-OSOCF ₂ SOO-) BF (CF ₃ ), (-OSOCH ₂ SOO-) B (CF ₃ ) ₂ , (-OSOCF ₂ SOO-) B (CF ₃ ) ₂ , CF ₃ SO ₃ , (CF ₃ SO ₂ ) ₂ N, (-OCOCOO-) ₂ PF ₂ , (CF ₃ CF ₂ ) ₃ PF ₃ , ( CF ₃ CF ₂ CF ₂ ) ₃ PF ₃ , (-OCOCOO-) ₂ B, (-OCO (CH ₂ ) _n COO-) BF (CF ₃ ), (-OCOCR ₂ COO-) BF (CF ₃ ), ( -OCOCR ₂ COO-) B (CF ₃ ) ₂ , (-OCOCR ₂ COO-) ₂ B, CF ₃ BF (-OOR) ₂ , CF ₃ B (-OOR) ₃ , CF ₃ B (-OOR) F ₂ , (-OCOCOCOO-) BF (CF ₃ ), (-OCOCOCOO-) B (CF ₃ ) ₂ , (-OCOCOCOO-) ₂ B, (-OCOCR ¹ R ² CR ¹ R ² COO-) BF (CF ₃ ) and ^{(-OCOCR 1 R 2 CR 1 R} 2 COO-) B (CF 3) 2 ( wherein, R, R ^1, and R ² are each independently Composed of one or more lithium salt having one or more anions selected from the group consisting of H or F).

In further embodiments, the electrolyte composition is comprised of, but not limited to, one or more of the following lithium salts: lithium hexafluorophosphate (LiPF ₆ ), lithium tetrafluoroborate (LiBF ₄ ), Lithium perchlorate (LiClO ₄ ), lithium hexafluoroarsenate (LiAsF ₆ ), lithium trifluoromethanesulfonate or lithium triflate (LiCF ₃ SO ₃ ), lithium bis (trifluoromethanesulfonyl) imide (Li (CF ₃ SO _{2) 2} N or LiIm), and bis (pentafluorophenyl) imide lithium _{(Li (CF 3 CF 2 SO} 2) 2 N or LiBETI).

  An important requirement for enhanced energy cycle efficiency and maximum power delivery is a low equivalent series resistance (ESR) of the cell. Therefore, it is useful for the battery electrolyte to have a high conductivity for ion movement. Surprisingly, when the phosphonium electrolyte composition disclosed herein replaces a conventional electrolyte, as described above, or when a phosphonium salt is used as an additive with a conventional electrolyte, The ionic conductivity is significantly increased and the performance stability of the battery device is greatly improved, as can be seen in the examples below.

In one exemplary embodiment, an undiluted phosphonium ionic liquid without solvent (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is an ion of 15.2 mS / cm The conductivity is shown.

In another exemplary embodiment, the phosphonium ionic liquid (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is 1.5% when mixed in a solvent of acetonitrile (ACN). It exhibits an ionic conductivity of 75 mS / cm at an ACN / ionic liquid volume ratio between ˜2.0.

In another exemplary embodiment, the phosphonium ionic liquid (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is mixed in a propylene carbonate (PC) solvent, It exhibits an ionic conductivity of 22 mS / cm at a PC / ionic liquid volume ratio between 0.75 and 1.25.

  In other exemplary embodiments, various phosphonium salts were dissolved in acetonitrile (ACN) solvent at a concentration of 1.0M. The resulting electrolyte exhibits an ionic conductivity of greater than about 28 mS / cm, greater than about 34 mS / cm, greater than about 41 mS / cm, greater than about 55 mS / cm, or greater than about 61 mS / cm at room temperature. It was.

In another exemplary embodiment, a conventional electrolyte solution of 1.0 M LiPF ₆ in a mixed solvent of EC (ethylene carbonate) and DEC (diethyl carbonate) in a mass ratio of 1: 1 (denoted as EC: DEC = 1: 1) 10% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is added. With the addition of the phosphonium additive, the ionic conductivity of the electrolyte increases by 109% at -30 ° C and by about 25% at + 20 ° C and + 60 ° C. In general, the ionic conductivity of conventional electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

In a further exemplary embodiment, a mixed solvent of EC (ethylene carbonate), DEC (diethyl carbonate) and EMC (ethyl methyl carbonate) in a mass ratio of 1: 1: 1 (EC: DEC: EMC 1: 1 represents 1: 1). ) 10% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ is added to 1.0 M LiPF ₆ conventional electrolyte solution. With the addition of the phosphonium additive, the ionic conductivity of the electrolyte increases by 36% at 20 ° C, 26% at 60 ° C, and 38% at 90 ° C. In general, the ionic conductivity of conventional electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

  Another important advantage of using the novel phosphonium electrolyte compositions disclosed herein as replacements for conventional electrolytes or using phosphonium salts as additives in conventional electrolytes is that they are conventional electrolytes. A broader electrochemical voltage stability window.

  In some exemplary embodiments, the electrolyte solution is formed at a concentration of 1.0 M by dissolving various phosphonium salts in acetonitrile (ACN) solvent. The electrochemical voltage window is determined in a cell having a Pt working electrode and a Pt counter electrode and an Ag / Ag + reference electrode. In one arrangement, the stable voltage window is between about -3.0V to + 2.4V. In another arrangement, the voltage window is between about -3.2V to + 2.4V. In another arrangement, the voltage window is between about -2.4V to + 2.5V. In another arrangement, the voltage window is between about -1.9V and + 3.0V.

  Another important advantage of using the phosphonium electrolyte compositions disclosed herein as a replacement for conventional electrolytes, or using phosphonium salts as additives in conventional electrolytes is that they are compared to conventional electrolytes. Thus exhibiting a lower vapor pressure and thus lower flammability, thus improving the safety of battery operation. In one aspect of the present invention, when a phosphonium salt is used as an additive with a conventional electrolyte (containing a conventional non-phosphonium salt), the phosphonium salt and the conventional salt are in the phosphonium salt / conventional salt molar ratio in the electrolyte. It exists in the range of 1/100 to 1/1.

In one exemplary embodiment, the electrolyte is a phosphonium salt- (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ at a concentration of 1.0 M in a solvent of acetonitrile (ACN). Formed by dissolving. The vapor pressure of ACN drops by about 39% at 25 ° C and 38% at 105 ° C. Significant suppression of vapor pressure by phosphonium salts is an advantage in reducing the flammability of the electrolyte solution and thus improving the safety of device operation.

In another exemplary embodiment, a conventional electrolyte solution of 1.0 M LiPF _{6 in} a 1: 1 solvent mixture of EC (ethylene carbonate) and DEC (diethyl carbonate) was added with 20 w% phosphonium additive (CH ₃ CH Add ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ . Addition of phosphonium additives to conventional electrolytes reduces self-extinguishing time by 53%. This indicates that the safety and reliability of a lithium ion battery can be substantially improved by using a phosphonium salt as an additive in a conventional lithium ion electrolyte.

  In a further aspect, the phosphonium ionic liquid or salt can be used as an additive to promote the formation of a solid electrolyte interphase (SEI) layer or electrode protection layer. The SEI layer expands the electrochemical stability window and helps to suppress battery degradation or decomposition reactions and thus improve battery cycle life.

The phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for electrolytes such as lithium primary batteries and lithium secondary batteries, including lithium ion batteries and rechargeable lithium metal batteries. Yes. Examples of lithium primary batteries include, but are not limited to: lithium / manganese dioxide (Li / MnO ₂ ), lithium / carbon monofluoride (Li / CFx), lithium / silver vanadium oxide (Li / _{Ag 2 V 4 O 11),} Li- (CF) x, lithium / iron disulfide (Li / FeS _2), and lithium / copper oxide (Li / CuO). Examples of lithium ion batteries (LIB) include, but are not limited to: carbon, graphite, graphene, silicon (Si), tin (Sn), Si / Co doped carbon, metal oxides such as lithium Anode such as titanium oxide (LTO), lithium cobalt oxide (LCO) (LiCoO ₂ ), lithium manganese oxide (LMO) (LiMn ₂ O ₄ ), lithium iron phosphate (LFP) (LiFePO ₄ ), lithium Nickel manganese cobalt oxide (NMC) (Li (NiMnCo) O ₂ ), lithium nickel cobalt aluminum oxide (NCA) (Li (NiCoAl) O ₂ ), lithium nickel manganese oxide (LNMO) (Li ₂ NiMn ₃ O ₈ ), And lithium vanadium oxide (LVO) cathode. Examples of rechargeable lithium metal batteries include, but are not limited to: lithium cobalt oxide (LCO) (LiCoO ₂ ), lithium manganese oxide (LMO) (Li / Mn ₂ O ₄ ), phosphoric acid Iron lithium (LFP) (LiFePO ₄ ), lithium nickel manganese cobalt oxide (NMC) (Li (NiMnCo) O ₂ ), lithium nickel cobalt aluminum (NCA) (Li (NiCoAl) O ₂ ), lithium nickel manganese oxide ( LNMO) (Li ₂ NiMn ₃ O ₈ ) cathode and lithium metal anode, lithium / sulfur battery, and lithium / air battery.

  In further embodiments, the above approach to energy storage can be combined with an electrochemical double layer capacitor (EDLC) to form a hybrid energy storage system that includes an array of batteries and EDLC.

Electrochemical Double Layer Capacitors The phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for electrochemical double layer capacitor (EDLC) electrolytes. In one embodiment, an EDLC is provided that includes an anode, a cathode, a separator between the anode and cathode, and an electrolyte. The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more ionic liquids or salts dissolved in a liquid composition or solvent. In some embodiments, R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group composed of 1 to 6 carbon atoms, more usually 1 to 4 carbon atoms. It is. Any one or more of the salts may be liquid or solid at a temperature of 100 ° C. or lower. In some embodiments, the salt is composed of one cation and one anion pair. In other embodiments, the salt is composed of one cation and multiple anions. In other embodiments, the salt is composed of one anion and multiple cations. In a further embodiment, the salt is composed of multiple cations and multiple anions. In one embodiment, the electrolyte is composed of an ionic liquid having one or more phosphonium-based cations and one or more anions, the ionic liquid composition having a thermodynamic stability below 375 ° C. , Liquid phase range above 400 ° C. and ionic conductivity at room temperature of at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm. In another embodiment, the electrolyte is comprised of one or more salts dissolved in a solvent having one or more phosphonium-based cations and one or more anions, the electrolyte composition comprising: At room temperature, at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm The ionic conductivity of is shown.

In another embodiment, the electrolyte composition further comprises one or more conventional, non-phosphonium salts. In some embodiments, the electrolyte composition may be composed of conventional salts, in which case the phosphonium-based ionic liquids or salts disclosed herein are additives. In some embodiments, the electrolyte composition is comprised of a phosphonium-based ionic liquid or salt and one or more conventional salts, which are phosphonium-based ionic liquids or salts: moles of conventional salts (or Molar concentration) ratio exists in the range of 1: 100 to 1: 1. Examples of conventional salts include, but are not limited to, tetraalkylammonium, such as (CH ₃ CH ₂ ) ₄ N ⁺ , (CH ₃ CH ₂ ) ₃ (CH ₃ ) N ⁺ , (CH ₃ CH ₂ ) ₂ (CH ₃ ) ₂ N ⁺ , (CH ₃ CH ₂ ) (CH ₃ ) ₃ N ⁺ , (CH ₃ ) ₄ N ⁺ etc., selected from the group consisting of imidazolium, pyrazolium, pyridinium, pyrazinium, pyrimidinium, pyridazinium, pyrrolidinium And one or more cations formed, ClO ₄ ⁻ , BF ₄ ⁻ , CF ₃ SO ₃ ⁻ , PF ₆ ⁻ , AsF ₆ ⁻ , SbF ₆ ⁻ , (CF ₃ SO ₂ ) ₂ N ⁻ , (CF ₃ CF ₂ SO ₂ ) ₂ N ⁻ , (CF ₃ SO ₂ ) ₃ C ^— and a salt composed of one or more anions selected from the group consisting of. In some embodiments, one or more conventional salts include, but are not limited to, tetraethylammonium tetrafluoroborate (TEABF ₄ ), triethylmethylammonium tetrafluoroborate (TEMABF ₄ ), tetrafluoroboric acid 1-ethyl-3-methylimidazolium (EMIBF ₄ ), 1-ethyl-1-methylpyrrolidinium tetrafluoroborate (EMPBF ₄ ), 1-ethyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide ( EMIIm) and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIPF ₆ ). In some embodiments, one or more conventional salts include, but are not limited to, lithium hexafluorophosphate (LiPF ₆ ), lithium tetrafluoroborate (LiBF ₄ ), lithium perchlorate (LiClO ₄ ), Lithium hexafluoroarsenate (LiAsF ₆ ), lithium trifluoromethanesulfonate or lithium triflate (LiCF ₃ SO ₃ ), lithium bis (trifluoromethanesulfonyl) imide (Li (CF ₃ SO ₂ ) ₂ N or LiIm), and Lithium-based salts including bis (pentafluoromethanesulfonyl) imidolithium (Li (CF ₃ CF ₂ SO ₂ ) ₂ N or LiBETI).

An EDLC device comprising an electrolyte composition according to some embodiments of the present invention is filed concurrently with this specification and is hereby incorporated by reference in its entirety. (Attorney Docket No. 057472-059).

  In some embodiments, the electrolyte composition is composed of, but not limited to, one or more of the following solvents: acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate ( BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC) or methyl ethyl carbonate (MEC), methyl propionate (MP), fluoroethylene carbonate (FEC), fluorobenzene (FB), vinylene Carbonate (VC), vinyl ethylene carbonate (VEC), phenyl ethylene carbonate (PhEC), propyl methyl carbonate (PMC), diethoxyethane (DEE), dimethoxyethane (DME), tetrahydrofuran (THF), γ-butyrolactone (GBL) , And γ-valerolactone (GVL).

  An important requirement for increased energy cycle efficiency and maximum power delivery is a low equivalent series resistance (ESR) of the cell. Therefore, it is useful for the battery electrolyte to have a high conductivity for ion movement. Surprisingly, when the phosphonium electrolyte composition disclosed herein replaces a conventional electrolyte, as described above, or when a phosphonium salt is used as an additive with a conventional electrolyte, The ionic conductivity is significantly increased and the performance stability of the battery device is greatly improved, as can be seen in the examples below.

In one exemplary embodiment, undiluted phosphonium ionic liquid without solvent (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is an ion of 15.2 mS / cm The conductivity is shown.

In another exemplary embodiment, the phosphonium ionic liquid (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is 1.5% when mixed in a solvent of acetonitrile (ACN). It exhibits an ionic conductivity of 75 mS / cm at an ACN / ionic liquid volume ratio between ˜2.0.

In another exemplary embodiment, the phosphonium ionic liquid (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is mixed in a propylene carbonate (PC) solvent, It exhibits an ionic conductivity of 22 mS / cm at a PC / ionic liquid volume ratio between 0.75 and 1.25.

  In other exemplary embodiments, various phosphonium salts were dissolved in acetonitrile (ACN) solvent at a concentration of 1.0M. The resulting electrolyte exhibits an ionic conductivity of greater than about 28 mS / cm, greater than about 34 mS / cm, greater than about 41 mS / cm, greater than about 55 mS / cm, or greater than about 61 mS / cm at room temperature. It was.

In another exemplary embodiment, a conventional electrolyte solution of 1.0 M LiPF ₆ in a mixed solvent of EC (ethylene carbonate) and DEC (diethyl carbonate) in a mass ratio of 1: 1 (denoted as EC: DEC = 1: 1) 10 w% of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ is added. With the addition of the phosphonium additive, the ionic conductivity of the electrolyte increases by 109% at -30 ° C and by about 25% at + 20 ° C and + 60 ° C. In general, the ionic conductivity of conventional electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

In a further exemplary embodiment, a 1: 1 mixed solvent ratio of EC (ethylene carbonate), DEC (diethyl carbonate) and EMC (ethyl methyl carbonate) is described as EC (DEC: EMC 1: 1: 1). 10 w% of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ is added to 1.0 M LiPF ₆ conventional electrolyte solution. With the addition of the phosphonium additive, the ionic conductivity of the electrolyte increases by 36% at 20 ° C, 26% at 60 ° C, and 38% at 90 ° C. In general, the ionic conductivity of conventional electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

  Another important advantage of using the novel phosphonium electrolyte compositions disclosed herein as replacements for conventional electrolytes or using phosphonium salts as additives in conventional electrolytes is that they are conventional electrolytes. A broader electrochemical voltage stability window.

  In some exemplary embodiments, the electrolyte solution is formed at a concentration of 1.0 M by dissolving various phosphonium salts in acetonitrile (ACN) solvent. The electrochemical voltage window is determined in a cell having a Pt working electrode and a Pt counter electrode and an Ag / Ag + reference electrode. In one arrangement, the stable voltage window is between about -3.0V to + 2.4V. In another arrangement, the voltage window is between about -3.2V to + 2.4V. In another arrangement, the voltage window is between about -2.4V to + 2.5V. In another arrangement, the voltage window is between about -1.9V and + 3.0V.

  Another important advantage of using the phosphonium electrolyte compositions disclosed herein as a replacement for conventional electrolytes, or using phosphonium salts as additives in conventional electrolytes is that they are compared to conventional electrolytes. Thus exhibiting a lower vapor pressure and thus lower flammability, thus improving the safety of battery operation. In one aspect of the present invention, when a phosphonium salt is used as an additive with a conventional electrolyte (containing a conventional non-phosphonium salt), the phosphonium salt and the conventional salt are in the phosphonium salt / conventional salt molar ratio in the electrolyte. It exists in the range of 1/100 to 1/1.

In one exemplary embodiment, the electrolyte is a phosphonium salt- (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ at a concentration of 1.0 M in a solvent of acetonitrile (ACN). Formed by dissolving. The vapor pressure of ACN drops by about 39% at 25 ° C and 38% at 105 ° C. Significant suppression of vapor pressure by phosphonium salts is an advantage in reducing the flammability of the electrolyte solution and thus improving the safety of device operation.

In another exemplary embodiment, a conventional electrolyte solution of 1.0 M LiPF _{6 in} a 1: 1 solvent mixture of EC (ethylene carbonate) and DEC (diethyl carbonate) was added with 20 w% phosphonium additive (CH ₃ CH Add ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ . Addition of phosphonium additives to conventional electrolytes reduces self-extinguishing time by 53%. This indicates that the safety and reliability of a lithium ion battery can be substantially improved by using a phosphonium salt as an additive in a conventional lithium ion electrolyte.

  In a further aspect, the phosphonium ionic liquid or salt can be used as an additive to facilitate the formation of a solid electrolyte interphase (SEI) layer or electrode protection layer. The protective layer broadens the electrochemical stability window and helps to suppress EDLC degradation or degradation reactions, thus improving the EDLC cycle life.

  The phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for various EDLC electrolytes, such as carbon black, graphite, graphene; carbon-metal composites; polyaniline, polypyrrole , Polythiophene; oxides, chlorides, bromides, sulfates, nitrates, sulfides, hydrides, nitrides of lithium, ruthenium, tantalum, rhodium, iridium, cobalt, nickel, molybdenum, tungsten, or vanadium, and combinations thereof , Phosphide, or selenide is selected from any one or more of the group consisting of:

  In a further embodiment, an EDLC device was made of a phosphonium electrolyte composition disclosed herein, a cathode (anode) made of high surface area activated carbon and graphite intercalated with lithium ions. It can be constructed using an anode (cathode). The formed EDLC is an asymmetric hybrid capacitor called a lithium ion capacitor (LIC).

  In further embodiments, an EDLC can be combined with a battery to form a capacitor battery hybrid energy storage system that includes battery cells and an array of EDLCs.

Electrolytic Capacitors Phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for electrolytes of electrolytic capacitors. In one embodiment, an electrolytic capacitor is provided that includes an anode, a cathode, a separator between the positive and negative electrodes, and an electrolyte. The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more ionic liquids or salts dissolved in a liquid composition or solvent. In one embodiment, the electrolyte is composed of an ionic liquid having one or more phosphonium-based cations and one or more anions, the ionic liquid composition having a thermodynamic stability below 375 ° C. , Liquid phase range above 400 ° C. and ionic conductivity at room temperature of at least 1 mS / cm, or at least 5 mS / cm, or at least 10 mS / cm. In another embodiment, the electrolyte is comprised of one or more salts dissolved in a solvent having one or more phosphonium-based cations and one or more anions, the electrolyte composition comprising: At room temperature, at least 5 mS / cm, or at least 10 mS / cm, or at least 15 mS / cm, or at least 20 mS / cm, or at least 30 mS / cm, or at least 40 mS / cm, or at least 50 mS / cm, or at least 60 mS / cm The ionic conductivity of is shown. In some embodiments, the electrolyte composition is composed of, but not limited to, one or more of the following solvents: acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate ( BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC) or methyl ethyl carbonate (MEC), methyl propionate (MP), fluoroethylene carbonate (FEC), fluorobenzene (FB), vinylene Carbonate (VC), vinyl ethylene carbonate (VEC), phenyl ethylene carbonate (PhEC), propyl methyl carbonate (PMC), diethoxyethane (DEE), dimethoxyethane (DME), tetrahydrofuran (THF), γ-butyrolactone (GBL) , And γ-valerolactone (GVL). In one embodiment, the anode, or anode, is typically an aluminum foil with a thin oxide film formed by electrolytic oxidation or anodization. Aluminum is the preferred metal for the anode, but other metals such as tantalum, magnesium, titanium, niobium, zirconium and zinc may be used. The cathode, or cathode, is usually an etched aluminum foil. In a further aspect, the phosphonium electrolyte exhibits lower flammability compared to conventional electrolytes, thus improving the safety of electrolytic capacitor operation.

Dye-sensitized solar cell The phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for dye-sensitized solar cell (DSSC) electrolytes. In one embodiment, a DSSC is provided that includes an anode to which dye molecules are attached, an electrolyte containing a redox system, and a cathode. The electrolyte has the general formula:
R ¹ R ² R ³ R ⁴ P
An ion comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently a substituent Consists of one or more ionic liquids or salts dissolved in a liquid composition or solvent. In another embodiment, the electrolyte is characterized as having one or more phosphonium-based cations and one or more anions, and the electrolyte composition comprises at least two or more of the following: Shows: thermodynamic stability, low volatility, wide liquid phase range, ionic conductivity, chemical stability, and electrochemical stability. In another embodiment, the electrolyte is characterized as having one or more phosphonium-based cations and one or more anions, and the electrolyte composition has a temperature of about 375 ° C. or higher. Thermodynamic stability up to and ionic conductivity up to 10mS / cm.

Electrolytic Films Phosphonium ionic liquids, salts, and compositions according to embodiments of the present invention are well suited for electrolytic films or electrolyte films. In one embodiment, an electrolytic film is provided that includes a phosphonium ionic liquid composition applied to a substrate. In another embodiment, an electrolytic film is provided that includes a salt dissolved in one or more phosphonium ionic liquids or solvents applied to a substrate. In one example, a coating solution is formed by dissolving one or more phosphonium ionic liquids or salts in a solvent. The solution is applied to the substrate by any suitable means, such as spraying, spin coating, and the like. The substrate is then heated to partially or completely remove the solvent and form an electrolyte or ion conductive film. In other embodiments, a solution of ionic liquid, salt and polymer dissolved in a suitable solvent is coated onto the substrate, such as by spraying or spin coating, and then the solvent is partially or fully evaporated. This results in the formation of an ion conducting polymer gel / film. Such films are particularly suitable for electrolytes for batteries, EDLC and DSSC and fuel cell membranes.

Heat Transfer Medium The desirable properties of the phosphonium ionic liquid of the present invention, high thermodynamic stability, low volatility and wide liquid phase range, are well suited for heat transfer media. Some embodiments of the present invention comprise an ionic liquid composition or one or more salts dissolved in a solvent comprising one or more phosphonium-based cations and one or more anions. A heat transfer medium is provided, the heat transfer medium exhibiting thermodynamic stability at temperatures below about 375 ° C., a liquidus range in excess of 400 ° C. In some embodiments, the heat transfer medium of the present invention is a high temperature reaction medium. In another embodiment, the heat transfer medium of the present invention is a heat extraction medium.

Other Applications The phosphonium ionic liquids of the present invention find use in further applications. In one exemplary embodiment, an embedded capacitor has been demonstrated. In one embodiment, the embedded capacitor is comprised of a dielectric disposed between two electrodes, the dielectric comprising an electrolytic film of a phosphonium ion composition as described above. The embedded capacitor of the present invention can be embedded in an integrated circuit package. Further embodiments include the placement of “on-board” capacitors.

  Embodiments of the invention will now be described in more detail with reference to specific examples. The examples provided below are intended for illustrative purposes only and are in no way intended to limit the scope and / or teachings of the present invention.

  In general, phosphonium ionic liquids are metathesis reactions of appropriately substituted phosphonium salts with appropriately substituted metal salts, or reactions of appropriately substituted phosphine precursors with appropriately substituted anion precursors. It is prepared by either. 1-4 illustrate a reaction scheme for making four exemplary embodiments of the phosphonium ionic liquid of the present invention.

Example 1
A phosphonium ionic liquid was prepared. AgSO ₃ CF ₃ was charged into a 50 ml round bottom (Rb) flask and attached to a 3 cm swivel frit. The flask was evacuated and brought into the glove box. In the glove box, di-n-propylethylmethylphosphonium iodide was added, the flask was reassembled, brought to the vacuum line, degassed, and anhydrous THF was vacuum transferred. The flask was allowed to warm to room temperature and then heated to 40 ° C. for 2 hours. This resulted in the formation of a light green bead-like solid. This solid was removed by filtration. This resulted in a pearly, milky white solution. Volatiles were removed under high vacuum while heating using a 30 ° C. water bath. This produced a white crystalline material with a yield of 0.470 g. A thermogravimetric analysis (TGA) was performed on this material and the results are shown in FIG.

(Example 2)
Additional phosphonium ionic liquids were prepared. Di-n-propylethylmethylphosphonium iodide was charged into a 100 ml Rb flask in the glove box, then removed and dissolved in 50 ml DI H ₂ O. When AgO ₂ CCF ₃ was added to this solution, a yellow bead-like precipitate immediately formed. After stirring for 2 hours, AgI was removed by filtration and the cake was washed 3 times with 5 ml of DI H ₂ O each time. Most of the water was removed on a rotary evaporator. This resulted in a clear, low viscosity liquid which was then dried under high vacuum with heating and stirring. This caused solidification of the material. Mild warming to the white solid in a warm water bath produces a liquid that appears to melt immediately above room temperature. This experiment yielded 0.410 g of material. The reaction scheme is shown in FIG. 6A. This material was subjected to thermogravimetric analysis (TGA) and evolved gas analysis (EGA) tests, the results of which are shown in FIGS. 6B and 6C, respectively.

(Example 3)
In this example, di-n-propylethylmethylphosphonium iodide was charged into a 100 ml Rb flask in a glove box and then removed from the draft chamber and dissolved in 70 ml MeOH. Next, when AgO ₂ CCF ₂ CF ₂ CF ₃ was added, a yellow colored slurry was immediately obtained. After stirring for 3 hours, the solid was removed by filtration, most of the MeOH was removed by evaporation on a rotary evaporator, and the remaining residue was dried under high vacuum. This gave a yellow, mushy gel-like substance. “Liquid” type crystals were observed to form on the sides of the Rb flask and then “melted” out by rubbing the flask. This experiment yielded 0.618 g of material. A thermogravimetric analysis (TGA) was performed on this material and the results are shown in FIG. 7A. Evolved gas analysis (EGA) was also performed and the results are shown in FIG. 7B.

Example 4
The pressure flask was brought into the glove box and charged with 0.100 g of P (CH ₂ OH) ₃ followed by 5 mL of THF-d8. When the solid dissolved, Me ₂ SO ₄ was added. The flask was then sealed and removed from the glove box. This was heated in a 110 ° C. oil bath for 10 minutes, then cooled and returned to the glove box and a ¹ mL aliquot was removed for ¹ H NMR. The reaction scheme is illustrated in FIG. 8A. ¹ H NMR spectrum is shown in FIG. 8B.

(Example 5)
In this test, 1-ethyl-1-methylphosphoranium nitrate was charged into a 100 ml 14/20 Rb flask in a glove box. To this was added KC (CN) ₃ and then this Rb was attached to a 3 cm swivel frit. This frit was brought into the line and CHCl ₃ was vacuum transferred. The flask was allowed to stir for 12 hours. A sticky brown material was observed at the bottom of the flask. Filtration of the solution gave a pearly, milky filtrate from which the brown oil was separated. The brown material was washed twice with recycled CHCl ₃ to become whiter and more granular. All volatile components were removed under high vacuum to give a low viscosity brown oil. This test yielded 1.52 g of material. The reaction scheme is shown in FIG. 9A. This material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG. 9B.

(Example 6)
In this test, 1-ethyl-1-methylphosphorinanium iodide was charged into a 100 ml Rb flask in a glove box and then brought into a draft chamber where it was dissolved in 70 ml MeOH. Then, when AgO ₂ CCF ₂ CF ₂ CF ₃ was added, a yellow precipitate was immediately obtained. The flask was stirred for 18 hours and then the solid was removed by filtration. Most of the MeOH was removed by evaporation on a rotary evaporator and the residue was dried under high vacuum. This procedure gave an off-white, pale yellow colored solid. This test yielded 0.620 g of material. The material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG.

(Example 7)
In another test, 1-butyl-1-ethylphosphoranium iodide was charged into an Rb flask in a draft chamber and then dissolved in water and stirred. When AgO ₃ SCF ₃ was added, a yellow precipitate immediately formed. The flask was stirred for 2 hours and then vacuum filtered. A solution formed during filtration and milky material was observed after filtration. This material was evaporated on a rotary evaporator and the residue was dried under vacuum on an oil bath, which melted the solid. This test yielded 0.490 g of material. The material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG.

(Example 8)
In a further test, 1-butyl-1-ethylphosphorinanium iodide was charged to a flask in a draft chamber. MeOH was added and the flask was then stirred for 15 minutes. Silver p-toluenesulfonate was added. The flask was stirred for 4 hours. A yellow precipitate was formed. This material was gravity filtered and then evaporated on a rotary evaporator. This material was dried under vacuum to yield a liquid. This test yielded 0.253 g of material. The reaction scheme is shown in FIG. 12A. The material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG. 12B.

Example 9
In another test, 250 mg (0.96 mmol) of triethylmethylphosphonium iodide is added to 15 mL of deionized water followed by 163 mg (0.96 mmol) of silver nitrate predissolved in 5.0 mL of deionized water. The reaction is stirred for 10 minutes, at which point the white to yellow precipitate is filtered off. The solid is then washed with 5.0 mL deionized water and the aqueous fractions are combined. Removal of water on a rotary evaporator under vacuum leaves a white solid residue which is recrystallized from a 3: 1 mixture of ethyl acetate and acetonitrile to give triethylmethylphosphonium nitrate. Yield: 176 mg, 94%. Phosphonium nitrate (176 mg, 0.90 mmol) is dissolved in 5 mL anhydrous acetonitrile. 113 mg (0.90 mmol) potassium tetrafluoroborate dissolved in 5 mL anhydrous acetonitrile is added to the phosphonium salt and after stirring for 5 minutes, the solid is removed by filtration. The solvent is removed on a rotary evaporator and the resulting off-white solid is recrystallized from hot 2-propanol to give pure triethylmethylphosphonium tetrafluoroborate for analysis. Yield: 161 mg, 81%. This composition is confirmed by the ¹ H NMR spectrum shown in FIG. 13A and by the ³¹ P NMR spectrum shown in FIG. 13B. The material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG.

(Example 10)
In another test, 250 mg (1.04 mmol) triethylpropylphosphonium bromide and 135 mg (1.06 mmol) potassium tetrafluoroborate were mixed in 10 mL acetonitrile. A fine white precipitate of KBr began to form immediately. The mixture was stirred for 1 hour, filtered, and the solvent was removed on a rotary evaporator to produce a white solid. Yield: 218 mg, 85%. By recrystallizing this crude product from 2-propanol, pure material can be produced in the analysis. This composition is confirmed by the ¹ H NMR spectrum shown in FIG. 15A and by the ³¹ P NMR spectrum shown in FIG. 15B. The material was subjected to thermogravimetric analysis (TGA) and the results are shown in FIG.

(Example 11)
In further tests, the reaction was carried out in a glove box under a nitrogen atmosphere. Triethylpropylphosphonium iodide (1.00 g, 3.47 mmol) was dissolved in 20 mL of anhydrous acetonitrile. To this solution, 877 mg (3.47 mmol) of silver hexafluorophosphate was added with constant stirring. A silver iodide white precipitate formed immediately and the reaction was stirred for 5 min. The precipitate was filtered and washed several times with anhydrous CH ₃ CN. The filtrate was removed from the glove box and evaporated to give a white solid. The crude material was dissolved in hot isopropanol and passed through a 0.2 μm PTFE membrane. Cooling the filtrate gave white crystals that were collected by filtration. Yield: 744 mg, 70%. This composition is confirmed by the ¹ H NMR spectrum shown in FIG. 17A and by the ³¹ P NMR spectrum shown in FIG. 17B. A thermogravimetric analysis (TGA) was performed on this material and the results are shown in FIG.

(Example 12)
In this example, (CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ PCF ₃ BF ₃ / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) _{2 in} a molar ratio of 1: 3: 1 PCF ₃ BF ₃ / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) ₂ (CH ₃ ) A ternary phosphonium ionic liquid composition containing PCF ₃ BF ₃ is converted into (CH ₃ CH ₂ CH ₂ ) (CH ₃ Compared to a one-component composition comprising CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ . Differential scanning calorimetry (DSC) was performed on these materials and the results are shown in FIG. 21A for the one-component composition and FIG. 21B for the three-component composition. As shown in FIGS. 19A and 19B, the ternary composition exhibits the advantage of a lower freezing temperature and thus a larger liquid phase range compared to the one-component composition.

(Example 13)
In another test, the phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ was prepared. This salt has a low viscosity of 19.5 cP at 25 ° C, a melting point of -10.0 ° C, an onset decomposition temperature of 396.1 ° C, a liquid range of 407 ° C, an ionic conductivity of 15.2 mS / cm, and a Pt working electrode and a Pt counter electrode and An electrochemical voltage window of -1.5V to + 1.5V is shown when measured in an electrochemical cell with an Ag / Ag ⁺ reference electrode. The results are summarized in Table 14 below.

(Example 14)
In another test, the phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ was prepared. Salts were dissolved in acetonitrile (ACN) solvent at ACN / salt volume ratios ranging from 0-4. The ionic conductivity of the produced electrolyte solution was measured at room temperature, and the result is shown in FIG. As FIG. 20 shows, the ACN / salt ratio increases from 13.9 mS / cm at zero ratio (undiluted ionic liquid) to a peak value of 75 mS / cm at a ratio between 1.5 and 2.0. Along with this, the ionic conductivity increases.

(Example 15)
In another test, the phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ was prepared. The salt was dissolved in propylene carbonate (PC) solvent with PC / salt volume ratio ranging from 0 to 2.3. The ionic conductivity of the produced electrolyte solution was measured at room temperature, and the result is shown in FIG. As FIG. 21 shows, as the PC / salt ratio increases from 13.9 mS / cm at zero ratio (undiluted ionic liquid) to a peak value of 22 mS / cm at a ratio between 0.75 and 1.25 The ionic conductivity is increasing.

(Examples 16 to 35)
In further testing, various phosphonium salts were prepared. An electrolyte solution was formed at a concentration of 1.0 M by dissolving the salt in a solvent of acetonitrile (ACN). The ionic conductivity of the produced electrolyte solution was measured at room temperature. The electrochemical window (Echem Window) was determined on an electrochemical cell with a Pt working electrode and a Pt counter electrode and an Ag / Ag + reference electrode. The results are summarized in Table 15. The electrolyte exhibited an ionic conductivity at room temperature of greater than about 28 mS / cm, or greater than about 34 mS / cm, or greater than about 41 mS / cm, or greater than about 55 mS / cm, or greater than about 61 mS / cm. In one arrangement, the Echem Window was between about -3.2V and + 3.2V. In another arrangement, the Echem Window was between about -2.0V and + 2.4V. In another arrangement, the electrochemical window was between about -1.5V and + 1.5V. In yet another arrangement, the electrochemical window was between about -1.0V and + 1.0V.

(Examples 36 to 41)
In further tests, various phosphonium salts were prepared and compared to the ammonium salt as a control. An electrolyte solution was formed at a concentration of 1.0 M by dissolving the salt in a solvent of propylene carbonate (PC). The ionic conductivity of the produced electrolyte solution was measured at room temperature. The electrochemical window was determined with an electrochemical cell having a Pt working electrode and a Pt counter electrode and an Ag / Ag + reference electrode. The results are summarized in Table 16, which demonstrates that the phosphonium salt exhibits higher conductivity and a broader electrochemical voltage stability window compared to the control ammonium analog.

(Examples 42 to 45)
In further tests, various phosphonium salts were prepared and compared to the ammonium salt as a control. Electrolyte solutions were formed at concentrations ranging from 0.6 M to 5.4 M by dissolving the salt in propylene carbonate (PC) solvent. The ionic conductivity of the produced electrolyte solution was measured at room temperature, and the result is shown in FIG. The conductivity values at a concentration of 2.0M are shown in Table 17, which explains that the phosphonium salt exhibits higher conductivity compared to the control ammonium analog.

(Example 46)
In another test, the phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ was prepared and the ammonium salt (CH ₃ CH ₂ ) ₃ (CH ₃ ) as a control. Compared to NBF ₄ . An electrolyte solution was formed at a concentration of 1.0 M by dissolving these salts in a solvent of acetonitrile (ACN). The vapor pressure of the solution was measured by pressurized differential scanning calorimetry (DSC) at a temperature of 25-105 ° C. As shown in Figure 25, the vapor pressure of ACN is 39% lower for phosphonium salts compared to 27% for ammonium salts at 25 ° C and 13% for ammonium salts at 105 ° C. The phosphonium salt is 38% lower. Significant suppression of vapor pressure by phosphonium salts is an advantage in reducing the flammability of the electrolyte solution and thus improving the safety of devices utilizing electrolyte compositions such as batteries, EDLC devices and the like.

(Examples 47 to 50)
In another test, phosphonium salts were used as additives in standard electrolyte solutions for lithium batteries. In one embodiment of the present invention, a standard electrolyte solution of 1.0M LiPF ₆ in a mixed solvent of EC (ethylene carbonate) and DEC (diethyl carbonate) in a mass ratio of 1: 1 (denoted as EC: DEC 1: 1) is , Provided by Novolyte Technologies (part of BASF Group). 20% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ was added to the standard electrolyte solution. In another embodiment of the present invention, a mixed solvent of EC (ethylene carbonate), DEC (diethyl carbonate) and EMC (ethyl methyl carbonate) in a mass ratio of 1: 1: 1 (EC: DEC: EMC 1: 1: 1) Description) A standard electrolyte solution of 1.0M LiPF ₆ was provided by Novolyte Technologies (part of BASF group). 10% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ was added to the standard electrolyte solution. A self-extinguishing test was performed by placing a 1 g sample of the electrolyte solution in a glass petri dish, igniting the sample, and recording the time required for the flame to extinguish. The results are summarized in Table 18 below. Phosphonium additives at a concentration between 10-20% by weight reduced the self-extinguishing time (seconds / gram) by 33-53%. This indicates that the safety and reliability of a lithium ion battery can be substantially improved by using a phosphonium salt as an additive in a conventional lithium ion electrolyte.

(Example 51)
In another test, phosphonium salts were used as additives in standard electrolyte solutions for lithium batteries. In one embodiment of the present invention, a standard electrolyte solution of 1.0M LiPF ₆ in a mixed solvent of EC (ethylene carbonate) and DEC (diethyl carbonate) in a mass ratio of 1: 1 (denoted as EC: DEC 1: 1) is , Provided by Novolyte Technologies (part of BASF Group). 10% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PC (CN) ₃ was added to the standard electrolyte solution. The ionic conductivity of both the standard electrolyte solution and the phosphonium additive-containing solution was measured at different temperatures from -30 to + 60 ° C. As shown in FIG. 24, the phosphonium additive improves the ionic conductivity of the electrolyte solution over a wide temperature range. At −30 ° C., the ionic conductivity is increased by 109% as a result of the phosphonium additive. At + 20 ° C., the ionic conductivity is increased by 23% as a result of the phosphonium additive. At + 60 ° C., the ionic conductivity is increased by about 25% as a result of the phosphonium additive. In general, the ionic conductivity of standard electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

(Example 52)
In another test, phosphonium salts were used as additives in standard electrolyte solutions for lithium batteries. In one embodiment of the present invention, a mixed solvent of EC (ethylene carbonate), DEC (diethyl carbonate), and EMC (ethyl methyl carbonate) in a mass ratio of 1: 1: 1 (EC: DEC: EMC 1: 1: 1) is described. A standard electrolyte solution of 1.0M LiPF ₆ was provided by Novolyte Technologies (part of BASF group). 10% by weight of phosphonium salt (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ PCF ₃ BF ₃ was added to the standard electrolyte solution. The ionic conductivity of both the standard electrolyte solution and the phosphonium additive-containing solution was measured at different temperatures of 20-90 ° C. As shown in FIG. 25, the phosphonium additive improves the ionic conductivity of the electrolyte solution over a wide temperature range, particularly at high temperatures. At 20 ° C., the ionic conductivity is increased by about 36% as a result of the phosphonium additive. At 60 ° C., the ionic conductivity is increased by about 26% as a result of the phosphonium additive. At 90 ° C., the ionic conductivity is increased by about 38% as a result of the phosphonium additive. In general, the ionic conductivity of standard electrolyte solutions is increased by at least 25% as a result of the phosphonium additive.

  The present invention should not be limited in scope by the specific embodiments disclosed in the examples, which are intended as illustrations of several aspects of the invention, and Any equivalent embodiment is within the scope of the present invention. Indeed, various modifications of the invention in addition to those shown and described herein will be apparent to those skilled in the art and are intended to be within the scope of the claims appended hereto.

  Several references are cited, the entire disclosures of which are incorporated herein by reference.

Claims (44)

One or more phosphonium ionic liquids or one or more phosphonium salts dissolved in a solvent, wherein the one or more phosphonium ionic liquids or phosphonium salts are of the formula:
R ¹ R ² R ³ R ⁴ P

An electrolyte comprising one or more phosphonium-based cations and one or more anions, wherein R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group Composition. The electrolyte composition according to claim ¹ , wherein R ¹ , R ² , R ^3, and R ⁴ are each independently an alkyl group composed of 1 to 4 carbon atoms. R ¹ , R ² , R ³ and R ⁴ are each independently an alkyl group composed of 1 to 4 carbon atoms, at least two of the R groups are the same, and any of the R groups The electrolyte composition of claim 1, wherein the electrolyte has no oxygen.   The electrolyte composition of claim 1, wherein one or more of the hydrogen atoms in one or more of the R groups are substituted with fluorine.   The electrolyte composition according to claim 1, wherein any one or more of the phosphonium salts may be liquid or solid at a temperature of 100 ° C. or lower.   The electrolyte composition according to claim 1, wherein at least one of the phosphonium ionic liquid or salt is composed of one cation and one anion pair.   The electrolyte composition according to claim 1, wherein at least one of the phosphonium ionic liquid or the phosphonium salt is composed of one anion and a plurality of cations.   The electrolyte composition according to claim 1, wherein at least one of the phosphonium ionic liquid or the phosphonium salt is composed of one cation and a plurality of anions.   The electrolyte composition according to claim 1, wherein at least one of the phosphonium ionic liquid or the phosphonium salt is composed of a plurality of cations and a plurality of anions. The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ CH ₂ ) ₂ (CH ₃ CH ₂ ) (CH ₃ ) P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ ) ₃ (CH ₃ ) P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) ₃ P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ ) ₄ P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ CH ₂ ) ₃ (CH ₃ ) P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CH ₃ CH ₂ CH ₂ ) ₃ (CH ₃ CH ₂ ) P ⁺ . Phosphonium based cation is comprised of the _{formula: (CF 3 CH 2 CH 2} ) (CH 3 CH 2) 3 composed of P ^+, electrolyte composition of claim 1. The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CF ₃ CH ₂ CH ₂ ) ₃ (CH ₃ CH ₂ ) P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CF ₃ CH ₂ CH ₂ ) ₃ (CH ₃ ) P ⁺ . The electrolyte composition of claim 1, wherein the phosphonium-based cation is composed of the formula: (CF ₃ CH ₂ CH ₂ ) ₄ P ⁺ . The phosphonium ionic liquid or phosphonium salt is PF ₆ , (CF ₃ ) ₃ PF ₃ , (CF ₃ ) ₄ PF ₂ , (CF ₃ CF ₂ ) ₄ PF ₂ , (CF ₃ CF ₂ CF ₂ ) ₄ PF ₂ , ( -OCOCOO-) PF ₄ , (-OCOCOO-) (CF ₃ ) ₃ PF, (-OCOCOO-) ₃ P, BF ₄ , CF ₃ BF ₃ , (CF ₃ ) ₂ BF ₂ , (CF ₃ ) ₃ BF, (CF ₃ ) ₄ B, (-OCOCOO-) BF ₂ , (-OCOCOO-) BF (CF ₃ ), (-OCOCOO-) (CF ₃ ) ₂ B, (-OSOCH ₂ SOO-) BF ₂ , (- OSOCF ₂ SOO-) BF ₂ , (-OSOCH ₂ SOO-) BF (CF ₃ ), (-OSOCF ₂ SOO-) BF (CF ₃ ), (-OSOCH ₂ SOO-) B (CF ₃ ) ₂ , (- OSOCF ₂ SOO-) B (CF ₃ ) ₂ , CF ₃ SO ₃ , (CF ₃ SO ₂ ) ₂ N, (-OCOCOO-) ₂ PF ₂ , (CF ₃ CF ₂ ) ₃ PF ₃ , (CF ₃ CF _{2 CF 2) 3 PF 3, (} - OCOCOO-) 2 B, (- OCO (CH 2) n COO-) BF (CF 3), (- OCOCR 2 COO-) BF (CF 3), (- OCOCR 2 COO -) B (CF ₃ ) ₂ , (-OCOCR ₂ COO-) ₂ B, CF ₃ BF (-OOR) ₂ , CF ₃ B (-OOR) ₃ , CF ₃ B (-OOR) F ₂ , (-OCOCOCOO -) BF (CF ₃ ), (-OCOCOCOO-) B (CF ₃ ) ₂ , (-OCOCOCOO-) ₂ B, (-OCOCR ¹ R ² CR ¹ R ² COO-) BF (CF ₃ ), and (- ^{OCOCR 1 R 2 CR 1 R 2} COO-) B (CF 3) 2 ( wherein, R, R ^1, and R ^2, it Independently comprised of one or more anions selected from the group consisting of is H or F), electrolyte composition of claim 1. One or more _{^{anions, - O 3 SCF 3, -}} O 2 CCF 3, - O 2 CCF 2 CF 2 CF 3, CF 3 BF 3 -, C (CN) 3 -, PF 6 -, NO 3 - _{^{, - O 3 SCH 3, BF}} 4 -, - O 3 SCF 2 CF 2 CF 3, - O 2 CCF 2 CF 3, - O 2 CH, - O 2 CC 6 H 5, - OCN, CO 3 2-, ^{_{(-OCOCOO-) BF 2 -, (}} - OCOCOO -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, (CF 3 SO 2) 2 N -, (CF 3) 2 BF 2 -, _2. The electrolyte composition according to claim 1, comprising one or more of (CF ₃ ) ₃ BF ⁻ , CF ₃ CF ₂ BF ₃ ⁻ , ^and —N (CN) ₂ .   The solvent is acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), or methyl ethyl carbonate (MEC), Methyl propionate (MP), fluoroethylene carbonate (FEC), fluorobenzene (FB), vinylene carbonate (VC), vinyl ethylene carbonate (VEC), phenyl ethylene carbonate (PhEC), propyl methyl carbonate (PMC), diethoxyethane (DEE), dimethoxyethane (DME), tetrahydrofuran (THF), γ-butyrolactone (GBL), γ-valerolactone (GVL), or a mixture thereof. The electrolyte composition described. The phosphonium salt is a cation of the formula: (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P ⁺ and the formulas BF ₄ ⁻ , PF ₆ ⁻ , CF ₃ BF ₃ ⁻ , (—OCOCOO— ^{_{) BF 2 -, (- OCOCOO}} -) (CF 3) 2 B -, (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO 2) 2 N -, Or the electrolyte composition of Claim 1 comprised by any one or more anions of these combinations. The phosphonium salt is a cation of the formula (CH ₃ ) (CH ₃ CH ₂ ) ₃ P, and the formulas: BF ₄ ⁻ , PF ₆ ⁻ , CF ₃ BF ₃ ⁻ , (—OCOCOO-) BF ₂ ⁻ , (—OCOCOO— ^{_{) (CF 3) 2 B -}} , (- OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO 2) 2 N -, or any of these combinations The electrolyte composition according to claim 1, comprising one or more anions. The phosphonium salt is a cation of the formula (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) ₃ P ⁺ and the formulas: BF ₄ ⁻ , PF ₆ ⁻ , CF ₃ BF ₃ ⁻ , (—OCOCOO−) BF ₂ ^{− _{, (- OCOCOO-) 2 B -}} , (- OCOCOO -) (CF 3) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO 2) 2 N -, or a combination thereof The electrolyte composition according to claim 1, comprising any one or more anions. The phosphonium salt is a cation of the formula (CH ₃ CH ₂ ) ₄ P ⁺ and the formulas: BF ₄ ⁻ , PF ₆ ⁻ , CF ₃ BF ₃ ⁻ , (—OCOCOO-) BF ₂ ⁻ , (—OCOCOO —) (CF ^{_{3) 2 B -, (-}} OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO 2) 2 N -, or any one of these combinations or The electrolyte composition according to claim 1, comprising an anion.   The electrolyte composition of claim 1 further comprising one or more conventional, non-phosphonium salts.   29. The electrolyte composition according to claim 28, wherein the phosphonium ionic liquid or phosphonium salt is an additive.   29. The electrolyte composition of claim 28, wherein the phosphonium ionic liquid or phosphonium salt and the conventional salt are present in the electrolyte composition in a molar ratio of phosphonium ionic liquid or salt: conventional salt ranging from 1: 100 to 1: 1. object. One or more conventional salts are tetraethylammonium tetrafluoroborate (TEABF ₄ ), triethylmethylammonium tetrafluoroborate (TEMABF ₄ ), 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF ₄ ) 1-ethyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide (EMIIm), or 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIPF ₆ ) and mixtures thereof, The electrolyte composition according to claim 28.   30. The electrolyte composition of claim 28, wherein the one or more conventional salts are lithium-based salts. One or more conventional salts are lithium hexafluorophosphate (LiPF ₆ ), lithium tetrafluoroborate (LiBF ₄ ), lithium perchlorate (LiClO ₄ ), lithium hexafluoroarsenate (LiAsF ₆ ), trifluoro Lithium methanesulfonate (LiCF ₃ SO ₃ ), bis (trifluoromethanesulfonyl) imide lithium (Li (CF ₃ SO ₂ ) ₂ N), and bis (pentafluoromethanesulfonyl) imide lithium (Li (CF ₃ CF ₂ SO ₂₎ ) ₂ N), and is selected from the group of mixtures thereof, the electrolyte composition according to claim 28. One or more phosphonium ionic liquids, or one or more phosphonium salts dissolved in a solvent, wherein the one or more ionic liquids or salts are of the formula:
P (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _4-xy (where x, y = 0 to 4 and x + y ≦ 4)
One or more cations of
formula:
(CF ₃ ) _x BF _4-x (where x = 0 to 4)
(CF ₃ (CF ₂ ) _n ) _x PF _6-x (where n = 0 to 2 and x = 0 to 4)
(-OCO (CH ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (where n = 0 to 2 and x = 0 to 2)
(-OCO (CH ₂ ) _n COO-) ₂ B (where n = 0 to 2)
(-OSOCH ₂ SOO-) (CF ₃ ) _x BF _2-x (where x = 0 to 2)
(-OCOCOO-) _x (CF ₃ ) _y PF _6-2x-y (x = 1-3, y = 0-4, 2x + y ≦ 6)
An electrolyte composition comprising one or more anions of: One or more phosphonium ionic liquids, or one or more phosphonium salts dissolved in a solvent, wherein the one or more ionic liquids or salts are of the formula:
P (-CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (where x, y = 0 to 2, x + y ≦ 2)
P (-CH ₂ CH ₂ CH ₂ CH ₂ CH _2- ) (CH ₃ CH ₂ CH ₂ ) _y (CH ₃ CH ₂ ) _x (CH ₃ ) _2-xy (where x, y = 0 to 2 Yes, x + y ≦ 2)
One or more cations of
formula:
(CF ₃ ) _x BF _4-x (where x = 0 to 4)
(CF ₃ (CF ₂ ) _n ) _x PF _6-x (where n = 0 to 2 and x = 0 to 4)
(-OCO (CH ₂ ) _n COO-) (CF ₃ ) _x BF _2-x (where n = 0 to 2 and x = 0 to 2)
(-OCO (CH ₂ ) _n COO-) ₂ B (where n = 0 to 2)
(-OSOCH ₂ SOO-) (CF ₃ ) _x BF _2-x (where x = 0 to 2)
(-OCOCOO-) _x (CF ₃ ) _y PF _6-2x-y (x = 1-3, y = 0-4, 2x + y ≦ 6)
An electrolyte composition comprising one or more anions of:   35. The electrolyte composition of claim 34, wherein one or more of the hydrogen atoms in one or more cations or anions are replaced with fluorine.   36. The electrolyte composition of claim 35, wherein one or more of the hydrogen atoms in one or more cations or anions are substituted with fluorine. A phosphonium salt dissolved in a solvent, wherein the phosphonium salt is
(CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ P / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P / (CH ₃ CH ₂ CH in a molar ratio of 1: 3: 1 _{2) (CH 3 CH 2)} 2 (CH 3) formed of a P-cation and formula _{^{BF 4 -, PF 6 -,}} CF 3 BF 3 -, (- OCOCOO-) BF 2 -, (- OCOCOO -) ( ^{_{CF 3) 2 B -, (}} - OCOCOO-) 2 B -, CF 3 SO 3 -, C (CN) 3 -, (CF 3 SO 2) 2 N - or one or more anions of these combinations An electrolyte composition comprising: 39. The anion is composed of a mixture of BF ₄ ⁻ and CF ₃ BF ₃ ⁻ at a concentration ratio of [BF ₄ ⁻ ]: [CF ₃ BF ₃ ⁻ ] in a molar ratio range of 100/1 to 1/1. The electrolyte according to 1. 39. The anion is composed of a mixture of PF ₆ ⁻ and CF ₃ BF ₃ ⁻ at a concentration ratio of [PF ₆ ⁻ ]: [CF ₃ BF ₃ ⁻ ] in a molar ratio range of 100/1 to 1/1. The electrolyte according to 1. Anion, [PF ₆ ^-]: [BF ₄ ^-] molar ratio of 100 / 1-1 / 1 in the range of concentration of PF ₆ of ^- and BF ₄ ^- consists of a mixture of electrolyte of claim 38 . A phosphonium salt dissolved in a solvent, wherein the phosphonium salt is
(CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ P / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P / (CH ₃ CH ₂ CH in a molar ratio of 1: 3: 1 ₂ ) a cation composed of (CH ₃ CH ₂ ) ₂ (CH ₃ ) P and
CF ₃ BF ₃ ^- composed of the constituted anions, the electrolyte composition. A phosphonium salt dissolved in a solvent,
(CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ P / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P / (CH ₃ CH ₂ CH in a molar ratio of 1: 3: 1 ₂ ) a cation composed of (CH ₃ CH ₂ ) ₂ (CH ₃ ) P and
BF ₄ ^- composed of the constituted anions, the electrolyte composition. A phosphonium salt dissolved in a solvent, wherein the phosphonium salt is
(CH ₃ CH ₂ CH ₂ ) (CH ₃ ) ₃ P / (CH ₃ CH ₂ CH ₂ ) (CH ₃ CH ₂ ) (CH ₃ ) ₂ P / (CH ₃ CH ₂ CH in a molar ratio of 1: 3: 1 ₂ ) a cation composed of (CH ₃ CH ₂ ) ₂ (CH ₃ ) P and
PF ₆ ^- constituted by the formed anion with electrolyte composition.

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