JP2016223029A - Hydrolysis sheet - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hydrolysis sheet having enhanced hardness to break when strongly scratched while maintaining hydrolysis.SOLUTION: A toilet cleaner 100 has an aqueous agent impregnated into a base paper sheet of a plurality of water-dispersible plies practically containing a pulp and a water soluble binder, basis weight of the plurality of plies of 30 to 150 gsm and status where the content of the water-soluble binder is increased toward a surface and/or a back surface.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a water-decomposable sheet.

Conventionally, woven cloth cloths that are used repeatedly have been used for cleaning toilets. Instead, disposable wet sheets made of paper have been used in recent years. And this type of wet sheet is preferably provided in a state of being impregnated with a cleaning agent, and can be processed by flowing into a toilet after use.
In such wet sheets, it is required to ensure paper strength that does not break in a wet state impregnated with a cleaning agent at the time of wiping work, and water disintegrability that does not clog piping etc. when flowing into a toilet or the like. However, as one technique for effectively achieving these, it is known to use a hydrolytic paper to which a water-soluble binder containing carboxymethylcellulose (CMC) is added as the base paper (for example, Patent Document 1). reference).

Japanese Patent No. 3865506

  By the way, for example, when a wet sheet is used for cleaning a toilet, the conventional wet sheet may be broken if the edge of the toilet is rubbed strongly. Therefore, it has been a problem to improve the resistance to tearing when rubbed strongly while ensuring water disintegration.

  The present invention has been made in view of the above problems, and an object of the present invention is to provide a water-decomposable sheet having improved water-disintegrability and improved resistance to tearing when strongly rubbed.

In order to solve the above-described problem, the water-decomposable sheet according to claim 1 is
A substantially water-dispersible multi-ply base paper sheet containing pulp and a water-soluble binder is impregnated with an aqueous agent;
The basis weight of the plurality of plies is 30 to 150 gsm,
This is a state in which the content of the water-soluble binder is increased toward the front surface and / or the back surface.

The invention according to claim 2 is the invention according to claim 1,
An emboss is formed on the water-decomposable sheet.

The invention according to claim 3 is the invention according to claim 2,
The water-decomposable sheet has a first emboss and a second emboss disposed around the first emboss and having a different bulge shape from the first emboss.

The invention according to claim 4 is the invention according to claim 3,
The first embosses are arranged in a rhombus lattice.

The invention according to claim 5 is the invention according to claim 3 or 4,
The second emboss is arranged between the two first embosses.

The invention according to claim 6 is the invention according to any one of claims 3 to 5,
The first emboss and the second emboss are in contact with each other.

The invention according to claim 7 is the invention according to claim 2,
The water-decomposable sheet has a plurality of rows in which convex portions and concave portions having a shape obtained by inverting the convex portions are arranged in a single row, and the convex portions and the concave portions in adjacent rows are arranged so as to be shifted from each other by a half pitch. A grid-like embossed pattern is formed.

The invention according to claim 8 is the invention according to any one of claims 1 to 7,
The water-decomposable sheet has a blending ratio of softwood pulp to hardwood pulp of less than 1/1.

  According to the present invention, it is possible to provide a water-decomposable sheet that has improved water-disintegrability and improved resistance to tearing when rubbed strongly.

It is a top view which shows an example of the toilet cleaner which concerns on this embodiment. (A) is a figure which shows the fiber orientation of the conventional paper, (b) is a figure which shows the fiber orientation of this invention. It is the enlarged view and sectional drawing of the embossed part of a toilet cleaner. It is explanatory drawing which shows an example of the contact area of embossing. It is a flowchart which shows the manufacturing method of the toilet cleaner which concerns on this embodiment. It is a schematic diagram which shows an example of the manufacturing equipment (solution provision equipment) of the toilet cleaner which concerns on this embodiment. It is a schematic diagram which shows an example of the manufacturing equipment (processing equipment) of the toilet cleaner which concerns on this embodiment. It is a top view which shows another example of the toilet cleaner which concerns on this embodiment. It is a top view which shows another example of the toilet cleaner which concerns on this embodiment. FIG. 10 is an AA partial enlarged view of FIG. 9. (A) is a BB cutting part end elevation of Drawing 10, and (b) is a CC cutting part end elevation of Drawing 10.

  Hereinafter, a water-decomposable sheet which is an embodiment of the present invention will be described in detail with reference to the drawings. However, the scope of the invention is not limited to the illustrated examples.

  In the water-decomposable sheet according to the present invention, the water-decomposable sheet will be described by taking the toilet cleaner 100 as an example. Is also included. Further, the paper conveyance direction at the time of manufacturing the toilet cleaner 100 will be described as the Y direction (vertical direction), and the direction orthogonal to the conveyance direction will be described as the X direction (lateral direction).

[Composition of toilet cleaner 100]
First, the configuration of the toilet cleaner 100 will be described.
The toilet cleaner 100 is obtained by plying (stacking) a plurality of (for example, two) base paper sheets, and is impregnated with a predetermined chemical solution. Moreover, as shown in FIG. 1, two types of embossing EM11 and EM12 are given to the whole sheet | seat surface of the toilet cleaner 100 by embossing. The contact area between the two embossing EM11 and such cleaning object caused by EM12 is, 100 mm ² per ^is preferably 15 mm 2 ～30Mm ² about.

  For example, by arranging the embossed EM11 to be a rhombus lattice, it is possible to reduce wiping unevenness compared to the case where the embossed EM11 is disposed in a square lattice or a rectangular lattice. Further, the embossing EM12 is disposed between the embossing EM11.

  Further, the toilet cleaner 100 is folded into two at the center in the Y direction by being folded. Then, it is stored in a folded plastic case, packaging film, etc. in a folded state, and is expanded and used as needed during use. Note that the method of folding the toilet cleaner 100 is not limited to two, and may be, for example, four or eight.

  In addition, the base paper sheet of the toilet cleaner 100 of the present embodiment is composed of a water-decomposable fiber assembly so that the toilet paper can be discarded as it is in a toilet pool after cleaning the toilet.

  As the fiber assembly, fibers obtained by mixing hardwood bleached kraft pulp (LBKP) and softwood bleached kraft pulp (NBKP) are used. As a suitable raw material fiber, the component ratio of the hardwood bleached kraft pulp exceeds 50% by weight, that is, the blending ratio of the softwood bleached kraft pulp to the hardwood bleached kraft pulp is less than 1/1. Can be given. By increasing the compounding ratio of hardwood bleached kraft pulp to softwood bleached kraft pulp, gaps between fibers are reduced and moisture transpiration is suppressed, so that the difficulty of drying can be improved. Further, in order to improve the surface strength of the base paper sheet that is the base material of the toilet cleaner 100, a solution containing carboxymethyl cellulose (CMC) is applied to the base paper sheet from the front and back as a binder solution for enhancing paper strength. The toilet cleaner 100 is in a state in which the content of CMC increases from the center in the thickness direction toward the front and back surfaces. As a result, the toilet cleaner 100 is less likely to be broken even if the edge of the toilet bowl is rubbed more strongly than a conventional product that is uniformly impregnated with a water-soluble binder.

Further, the toilet cleaner 100 preferably has a ratio of vertical and horizontal fiber orientation (vertical / horizontal) of 0.8 to 2.0, and more preferably 1.0.
In the paper making process, which is a paper manufacturing process, fibers are spread on the wire of the paper machine and flow in the transport direction. Therefore, in general, the paper is lined with many fibers in the machine direction of the paper machine. (For example, vertical: horizontal = 2.3: 1, etc., see FIG. 2A). Therefore, the fiber density in the lateral direction is thin and the fiber is easy to tear. That is, it is easily broken depending on the direction of wiping. Therefore, in this embodiment, as shown in FIG. 2 (b), the vertical and horizontal fiber orientation ratio of the toilet cleaner 100 is set to 0.8 to 2.0, preferably 1.0. It is possible to provide a toilet cleaner 100 that is hard to tear even if wiped. The ratio of the vertical and horizontal fiber orientations can be determined by the ratio of the wet strength in the MD and CD directions.

  In addition, the toilet cleaner 100 of the present embodiment is impregnated with a predetermined chemical solution (aqueous drug). Specifically, in addition to an aqueous cleaning agent, a fragrance, an antiseptic, a disinfectant, a paper strength enhancer, A predetermined chemical solution containing an auxiliary agent such as an organic solvent is impregnated. The chemical solution is preferably impregnated in an amount of 150 to 300% by weight with respect to the weight of the base paper sheet that is the base material of the toilet cleaner 100.

  As the chemical solution, an appropriate one can be used. For example, as the aqueous cleaning agent, a surfactant or a lower or higher (aliphatic) alcohol can be used. As a fragrance | flavor, 1 type or several types can be suitably selected and used out of oil-based fragrance | flavors, such as orange oil other than an aqueous | water-based fragrance | flavor. As the preservative, for example, parabens such as methyl paraben, ethyl paraben, propyl paraben and the like can be used. As a disinfectant, for example, benzalkonium chloride, chlorhexidine gluconate, popidone iodine, ethanol, benzilium cetyl oxide, triclosan, chlorxylenol, isopropylmethylphenol and the like can be used. As the paper strength enhancer (crosslinking agent), boric acid, various metal ions, and the like can be used. As the organic solvent, polyhydric alcohols such as glycol (divalent), glycerin (trivalent), and sorbitol (tetravalent) can be used.

  In addition, the above-mentioned auxiliary agent for the component of the chemical solution can be appropriately selected, and a component that performs other functions may be included in the chemical solution as necessary.

  As shown in FIG. 3A, the embossed EM11 has a bulged portion PR21 having a curved shape.

  Moreover, as shown in FIG.3 (b), the embossing EM12 has the planar shape in the bulging part PR22.

And since the embossing EM12 is arrange | positioned between embossing EM11, when the bulging part PR21 of embossing EM11 and the bulging part PR22 of EM12 adjoin and adjoin, they are connected as shown in FIG.3 (c). The embossed EM21 is formed.
Moreover, the case where the bulging part PR21 of the embossing EM11 and the bulging part PR22 of the embossing EM12 are only close to each other and may not be continuous may be used.

  Since the two types of embosses EM11 and EM12 formed in this way can increase the contact area with the object to be cleaned and the like, the hardness of the toilet cleaner 100 is reduced and the wiping performance is improved.

  That is, by forming the embossed EM11 whose bulged portion PR21 is a curved surface and the embossed EM12 whose bulged portion PR22 is a flat surface on the entire sheet surface of the toilet cleaner 100, the toilet cleaner 100 is powered during wiping work. When each emboss is deformed, the contact area is increased for the first time. Therefore, the contact area is increased, and the flexibility is improved due to the deformation of each emboss.

  For example, as shown in FIG. 4A, in the case of a single embossed EM11, the contact area CN31 generated by the deformation of the embossed EM11 due to the force applied to the toilet cleaner 100 during the wiping operation is discrete in the vicinity of the embossed EM11. Will occur. On the other hand, when two types of embossing EM11 and EM12 are combined, as shown in FIG.4 (b), the embossing EM11 and EM12 which deform | transform and generate | occur | produce by the force added to the toilet cleaner 100 at the time of wiping work It can be seen that the area CN32 increases as compared with the contact area CN31 of FIG.

  Moreover, the two types of embossing EM11 and EM12 can similarly obtain the effect of normal embossing, and can improve the texture, absorbability, bulkiness, and the like of the toilet cleaner. Furthermore, the continuous embossing EM21 can also obtain the effect of the appearance by giving embossing similarly to normal embossing.

[Manufacturing method of toilet cleaner 100]
Next, a method for manufacturing the toilet cleaner 100 will be described.
FIG. 5 is a flowchart showing a method for manufacturing the toilet cleaner 100. FIG. 6 is a schematic diagram of a solution application facility for applying a binder solution to the base paper sheet of the toilet cleaner 100. FIG. 7 is a schematic diagram of processing equipment for processing a base paper sheet to which a binder solution has been applied by the solution application equipment shown in FIG.

  In the manufacturing method of the toilet cleaner 100, as shown in FIG. 5, first, a paper making process (S1) for making a paper as a base paper with a paper machine (not shown) is performed.

  Next, as shown in FIG. 5 and FIG. 6, in the solution application facility, continuous dry base paper 1 </ b> A fed out from a plurality of (for example, two) primary raw rolls 1, 1 each wound up the base paper that has been made. A ply processing step (S2) for plying 1A to form a ply continuous sheet 1B, a solution application step (S3) for applying a binder solution to the ply continuous sheet 1B to form a continuous sheet 1C, and drying the continuous sheet 1C A drying process (S4) and a slit / winding process (S5) for slitting and winding the dried continuous water-decomposable sheet 1D are performed. The number of primary rolls can be changed as long as there are two or more. However, in the following description, an example of using two primary rolls will be described.

  Next, as shown in FIGS. 5 and 7, in the processing facility, the continuous water-decomposable sheet 1 </ b> D fed from the secondary raw roll 11 wound in the slit / winding step (S <b> 5) is embossed. An embossing process (S6) and a finishing process (S7) for finishing the embossed sheet 1E that has been embossed are performed. Details of each process will be described later.

[Paper making process]
First, the paper making process (S1) according to the present embodiment will be described. In the papermaking step (S1) of the present invention, for example, a papermaking raw material is made by a known wet papermaking technique to form a base paper sheet. That is, after making the papermaking raw material into a wet paper state, it is dried by a dryer or the like to form a base paper sheet such as thin paper or crepe paper.
As a raw material of the base paper sheet, for example, known virgin pulp, waste paper pulp and the like can be used, and at least pulp fibers are included. As the pulp used as the raw material, a blend of LBKP and NBKP in an appropriate ratio is particularly suitable. In addition, rayon fiber, synthetic fiber, etc. may contain as fibers other than a pulp fiber.
The base paper sheet of the present invention contains an anionic acrylamide polymer (hereinafter referred to as “anionic PAM”) as a flocculant. An anionic PAM is a polymer obtained by copolymerizing an acrylamide monomer and an anionic monomer.
Examples of the acrylamide monomer include acrylamide alone or a mixture of acrylamide and the following nonionic monomer copolymerizable with acrylamide. Nonionic monomers copolymerizable with acrylamide include methacrylamide, N, N-dimethylacrylamide, N, N-diethylacrylamide, N-isopropylacrylamide, N-isopropylacrylamide, N-hydroxyethylacrylamide, diacetone. Examples include acrylamide, acryloylmorpholine, N-acryloylpyrrolidine, N-acryloylpiperidine, N-vinylrolidone, N-vinylformamide, and N-vinylacetamide. These may be used alone or in combination of two or more.
Examples of the anionic monomer include acrylic acid, methacrylic acid, acrylamide-2-methylpropanesulfonic acid, itaconic acid, maleic acid, fumaric acid, and neutralized salts thereof.
A monomer such as styrene, acrylonitrile, (meth) acrylic acid ester, or the like may be blended as long as the water solubility of the anionic PAM is not impaired.
The addition amount of the anionic PAM is preferably about 10 to 1000 ppm. By making paper using such an anionic flocculant having the same charge as pulp, the aggregation of the base paper sheet can be reduced, and the water disintegrability can be improved by capillary action.
In addition to the above-described pulp and flocculant, papermaking chemicals such as a wet paper strength agent, an adhesive, and a release agent may be appropriately used for the base paper sheet.

  In the present embodiment, in the paper making process, adjustment is performed so that the ratio of vertical and horizontal fiber orientations (vertical / horizontal) of the base paper sheet is 0.8 to 2.0, preferably 1.0. The fiber orientation can be adjusted, for example, by adjusting the angle at which the papermaking raw material is supplied to the wire part in a paper machine. The angle at which the papermaking raw material is supplied can be determined, for example, by adjusting the slice opening degree of the head box. Or it is good also as adjusting fiber orientation by giving a vibration in the direction orthogonal to the conveyance direction (running direction) of a paper machine.

[Continuous dry base paper]
As physical properties of the continuous dry base paper 1A, the basis weight is preferably about 15 to 75 gsm. Moreover, the basis weight of the ply-processed sheet containing the water-soluble binder (continuous water-decomposable sheet 1D) is about 30 to 150 gsm. The basis weight is based on JIS P 8124.
The continuous dry base paper 1A becomes a ply-processed hydrolyzed paper through a ply processing step (S2), a solution application step (S3), a drying step (S4), and a slit / winding step (S5), which will be described later. The toilet cleaner 100 is processed through an embossing process (S6) and a finishing process (S7).

[Ply processing process]
Next, the ply processing step (S2) of this embodiment will be described. In the ply processing step (S2), as shown in FIG. 6, the continuous dry base papers 1A and 1A continuously fed from the raw roll 1 are ply processed along the continuous direction to form a ply continuous sheet 1B. It is supplied to the mating unit 2. The overlapping portion 2 is composed of a pair of rolls, and plies each continuous base paper 1A, 1A to form a ply continuous sheet 1B subjected to ply processing. In addition, when the continuous dry base papers 1A and 1A are overlapped, the continuous dry base papers 1A and 1A may be lightly fastened with pin embossing (contact embossing) so that they are not easily displaced.

[Binder solution]
Next, the binder solution will be described. The binder solution contains carboxymethyl cellulose (CMC) as a water-soluble binder. The concentration of carboxymethylcellulose in the binder solution is 1 to 30% by weight, preferably 1% by weight or more and less than 4% by weight.

  On the other hand, the degree of etherification of CMC is desirably 0.6 to 2.0, particularly 0.9 to 1.8, and more preferably 1.0 to 1.5. The expression of water disintegration and wet paper strength is very good.

  Moreover, CMC can use a water-swellable thing. This demonstrates the function of tying together the fibers constituting the sheet while remaining unswelled by crosslinking of specific metal ions in the chemical solution, and can exhibit strength as a wiping sheet that can withstand cleaning and wiping operations.

  Ingredients other than carboxymethylcellulose in the binder solution include polyvinyl alcohol, starch or derivatives thereof, hydroxypropylcellulose, sodium alginate, tolton gum, guar gum, xanthan gum, gum arabic, carrageenan, galactomannan, gelatin, casein, albumin, pull plan, poly Examples thereof include binder components such as ethylene oxide, viscose, polyvinyl ethyl ether, polyacrylic acid soda, polymethacrylic acid soda, polyacrylamide, hydroxylated derivatives of polyacrylic acid, and polyvinylpyrrolidone / vinylpyrrolidone vinyl acetate copolymer.

It is preferable to use a water-soluble binder having a carboxyl group from the viewpoint of good water decomposability and a point at which wet strength can be expressed by a crosslinking reaction.
The water-soluble binder having a carboxyl group is an anionic water-soluble binder that easily forms a carboxylate in water. Examples thereof include polysaccharide derivatives, synthetic polymers, and natural products. Examples of the polysaccharide derivative include a salt of carboxymethyl cellulose, carboxyethyl cellulose or a salt thereof, carboxymethylated denven or a salt thereof, and an alkali metal salt of carboxymethyl cellulose is particularly preferable.

  Examples of the synthetic polymer include an unsaturated carboxylic acid polymer or copolymer salt, and a copolymer salt of an unsaturated carboxylic acid and a monomer copolymerizable with the unsaturated carboxylic acid. Examples of the unsaturated carboxylic acid include acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic anhydride, maleic acid, and fumaric acid. Examples of monomers that can be copolymerized with these include esters of these unsaturated carboxylic acids, vinyl acetate, ethylene, acrylamide, and vinyl ether. Particularly preferred synthetic polymers are those using acrylic acid or methacrylic acid as the unsaturated carboxylic acid. Specifically, polyacrylic acid, polymethacrylic acid, acrylic acid-methacrylic acid copolymer salt, acrylic acid or methacrylic acid. Examples thereof include a salt of a copolymer of an acid and an alkyl acrylate or an alkyl methacrylate. Examples of natural products include sodium alginate, xanthan gum, gellan gum, tarragant gum, pectin and the like.

[Solution application process]
Next, the solution application step (S3) of this embodiment will be described. In the solution application step (S3), as shown in FIG. 6, two fluids are formed on both outer surfaces of the ply continuous sheet 1B (the surfaces on which the continuous dry base papers 1A and 1A do not face each other when the continuous dry base papers 1A and 1A are plyed). The above-mentioned binder solution is sprayed by each type of spray nozzles 3 and 3 to produce a continuous sheet 1C. In addition, as a spraying method of a binder solution, you may make it spray the above-mentioned binder solution on the one outer surface of the ply continuous sheet 1B.

The two-fluid spray nozzle 3 is a spray nozzle that mixes and sprays compressed air and liquid divided into two systems, compared to a one-fluid spray nozzle that sprays compressed liquid alone, The liquid can be sprayed finely and uniformly.
When a two-fluid spray nozzle is used in the present embodiment, a binder solution (viscosity 400 to 1200 MPa.s) is applied to each outer surface of the ply-processed ply continuous sheet 1B with a high pressure (injection pressure of 1.5 MPa or more). Since it is applied, it is easy to impregnate the binder solution in the thickness direction of the sheet.
On the other hand, when a one-fluid spray nozzle is used in the present embodiment, a binder solution (viscosity 40) is applied to the outer surface of each ply-processed ply continuous sheet 1B at an injection pressure of 1.5 MPa or less.
0 to 1200 MPa. By applying s), the binder solution is easily impregnated in the thickness direction of the sheet, and the binder solution is easily applied uniformly to the sheet surface.
In this way, by spraying the binder solution onto the outer surface of the ply continuous sheet 1B, the toilet cleaner 100 is centered in the thickness direction (when applied on both sides) or non-coated with the binder solution (when applied on one side). Since the content of the water-soluble binder increases as it goes from the surface to the application surface of the binder solution, the surface strength can be improved while ensuring water disintegration, and the toilet cleaner 100 is less likely to be damaged even when rubbed strongly. Can be manufactured.

[Drying process]
Next, the drying step (S4) of this embodiment will be described. In the drying step (S4), as shown in FIG. 6, in the drying equipment 4, the insoluble liquid in the binder solution of the continuous sheet 1C is evaporated to fix the active ingredient, particularly CMC, to the fibers. .
Here, since the amount of the binder solution that permeates decreases from the outer surface of the continuous sheet 1C toward the inside in the thickness direction, the fixing amount of CMC decreases toward the inside in the thickness direction. Therefore, when the chemical solution is impregnated in the finishing step (S7) described later, the cross-linking reaction hardly occurs as it goes inward in the thickness direction, and since there are many voids, the chemical solution is confined inside the sheet. be able to. Thereby, the toilet cleaner 100 obtained can be made hard to dry.
As the drying equipment 4, a hooded dryer equipment that blows hot air on the continuous sheet 1C to dry it can be used. In order to make the sheets more closely contact each other, a press roll or a turn roll may be installed, and the continuous sheet 1C may be passed through the press roll or the turn roll before the drying step (S4).

  Moreover, you may use the installation by infrared irradiation as said drying installation. In this case, a plurality of infrared irradiation units are arranged in parallel in the conveying direction of the continuous sheet 1C, and drying is performed by irradiating the continuous sheet 1C to be conveyed with infrared rays. Since moisture is generated by infrared rays and dried, uniform drying is possible as compared with a dryer using hot air, and wrinkles can be prevented from occurring in the subsequent slit / winding process.

[Slit and winding process]
Next, the slit / winding step (S5) of this embodiment will be described. In the slit / winding step (S5), in order to use the ply-processed continuous water-decomposable sheet 1D with an off-line processing machine, it is dried in the drying step (S4) and the CMC is fixed. The illustrated continuous water-decomposable sheet 1D is slit to a predetermined width by the slitter 5 while adjusting the tension, and wound by the winder facility 6. The winding speed is appropriately determined in consideration of the ply processing step (S2), the solution application step (S3), and the drying step (S4). Note that if it is too early, the sheet will break, and if it is too late, wrinkles will occur.
In the slit / winding step (S5), the continuous water-decomposable sheet 1D subjected to the ply process is pressure-bonded, whereby the continuous water-decomposable sheet 1D is more integrated and becomes a sheet corresponding to one sheet.

[Embossing process]
Next, the embossing process (S6) of this embodiment will be described. In the embossing step (S6), as shown in FIG. 7, the embossing roll 12 has an embossing process that forms a predetermined shape on the entire surface of the continuous water-decomposable sheet 1D fed from the secondary raw roll 11 by the embossing roll 12. Applied. This embossing is performed for the purpose of improving the strength, bulkiness, wiping property and the like of the sheet, as well as the design.

[Finishing process]
Next, the finishing process (S7) of this embodiment will be described. In the finishing process (S7), as shown in FIG. 7, in the finishing equipment 13, the embossed sheet 1E is cut, the cut sheets are folded, and the chemicals are applied to the folded sheets. Impregnation and packaging of each sheet impregnated with the chemical solution are performed in a series of flows. Here, when CMC is used as the water-soluble binder, the cross-linking agent contained in the chemical solution is preferably a polyvalent metal ion. In particular, the use of one or more polyvalent metal ions selected from the group consisting of alkaline earth metals, manganese, zinc, cobalt, and nickel allows the fibers to be sufficiently bonded to withstand use. It is preferable from the standpoint that strength is developed and water disintegration is sufficient. Of these metal ions, it is particularly preferable to use ions of calcium, strontium, barium, zinc, cobalt, and nickel.
The toilet cleaner 100 is manufactured through the above steps.

  Next, Table 1 shows the results of evaluating the damage when rubbed strongly for the toilet cleaner (Example) in which the CMC of the present embodiment was applied from the outer surface and the toilet cleaner (Comparative Example) uniformly impregnated with the conventional CMC. Will be described.

<Conditions for implementation>
Example Material of base paper: 100% pulp
Weighing: 45 g / m ²
Number of plies: 2 plies Water-soluble binder and its content: CMC 1.2 g / m ² (spray coating)
Chemical ingredient: Surfactant, glycol ether, disinfectant, fragrance, etc. Embossing: No comparison Example Base paper material: 100% pulp
Weighing: 45 g / m ²
Number of plies: 2 plies Water-soluble binder and its content: CMC 1.2 g / m ² (uniformly impregnated)
Chemical component: Surfactant, glycol ether, disinfectant, fragrance, etc. Embossing: Yes

<Test method>
The toilet cleaner was folded in three, the measurement part was rubbed with a Gakushin type friction fastness tester, and the number of times when damage such as fluffing and tearing was visually confirmed on the paper surface was measured. The test conditions with the Gakushin type friction fastness tester are as follows.
・ Gaku pendulum: PP band (Sekisui Jushi Corporation product number 15.5K)
・ Overweight 200gf
・ The speed is 30 cpm (30 reciprocations per minute) and the stroke is 120 mm.

  As shown in Table 1, it was found that the surface coated with CMC in the example had a stronger surface strength than the comparative example, and damage such as fluffing and tearing was hardly generated when rubbed strongly. . That is, as in this embodiment, by applying a solution containing a water-soluble binder to the outer surface (both sides or one side) of the base paper sheet, the content of the water-soluble binder increases toward the front surface and / or the back surface. It was found that the water-decomposable sheet was not easily torn even when rubbed strongly while ensuring water-decomposability.

As mentioned above, although this invention was concretely demonstrated based on embodiment, this invention is not limited to the said embodiment, It can change in the range which does not deviate from the summary.
In describing the embodiment of the present invention, the embossed EM11 in which the bulging part PR21 has a curved shape and the embossing EM12 in which the bulging part PR22 has a flat shape are illustrated. It is not necessarily limited to this shape, for example, the bulging part of embossing EM11 and embossing EM12 may be a planar shape from which height differs. Further, for example, the bulging portion of the emboss EM 11 may be a flat shape, and the bulging portion of the emboss EM 12 may be a curved shape.

  In other words, there are two types of embossing (first embossing and second embossing) in which the shape of the bulging part is not the same shape, and the second embossing is arranged around the first embossing. If it exists, the shape of the bulging portion of each emboss may be any shape.

  In the description of the embodiment of the present invention, the embossed EM12 having a flat bulge is disposed between the embossed EM11 having a curved bulge, but the embossed EM11 intersects each other. Also good.

  In the description of the embodiment of the present invention, all the embosses EM11 and EM12 are convex in the front direction of the drawing in FIG. 1, but the embossments EM11 and EM12 that are convex in the front direction of the drawing and the front direction of the drawing. Alternatively, the concave embosses EM11 and EM12 may be alternately arranged.

  For example, as shown in FIG. 8, embosses EM11 and EM12 (solid line portions) convex in the front direction of FIG. 8 and embossments EM11 and EM12 (broken line portions) concave in the front direction of FIG. Thus, it is possible to increase the surface strength of the water-decomposable sheet by embossing and to provide a water-decomposable sheet having high wiping performance on both surfaces of the toilet cleaner 100.

  In the description of the embodiment of the present invention, the bulging portion PR21 of the emboss EM11 and the bulging portion PR22 of the EM12 are formed as a continuous embossing EM21 by closely adhering to each other. The bulging portion PR21 and the bulging portion PR22 of the EM 12 may be close to each other but not closely attached.

  In the description of the embodiment of the present invention, the shape of the emboss EM 11 is exemplified as a circular shape or an elliptical shape, but the emboss shape may be any shape such as a square or a polygon.

  Moreover, it is preferable that height HT21 and HT22 of the bulging part of embossing EM11 and EM12 in FIG. 3 are 0.40 mm-0.75 mm, for example. The height of the bulging portion of the emboss can be measured by measuring the surface in 3D with a Keyence digital microscope.

  For example, if the height is less than 0.40 mm, the friction at the time of wiping becomes strong and difficult to wipe, and if the height exceeds 0.75 mm, the shapes of the embosses EM11 and EM12 are liable to break during packaging. It looks bad.

  Moreover, the embossing pattern of the toilet cleaner is not limited to the above-described pattern. 9 is a plan view of the toilet cleaner 101 in which only the embossing pattern of the toilet cleaner 100 is changed, FIG. 10 is an enlarged view of a portion AA in FIG. 9, and FIG. 11A is a BB cut portion in FIG. FIG. 11B is an end view of the CC cut part in FIG.

  9-11, the recessed part e2 is the shape which reversed the convex part e1. The convex portions e1 and the concave portions e2 are alternately arranged as an example, and this row forms an emboss pattern in which the rows are arranged in multiple rows and the convex portions e1 and the concave portions e2 in adjacent rows are shifted from each other by a half pitch. . As described above, the convex portions e1 and the concave portions e2 are alternately formed both in the vertical direction and in the horizontal direction, so that the wiping property of dirt is improved compared to the embossed pattern in which the convex portions and the concave portions are arranged in a line. Can be made. In addition, the shape of the convex part e1 and the recessed part e2 is not specifically limited, Circular, an ellipse, a polygon etc. are used. It is good also as what combined each shape.

  In addition, the detailed configuration of the toilet cleaner 1 can be changed as appropriate without departing from the spirit of the present invention.

100, 101 Toilet cleaner 1 Primary raw roll 1A Continuous dry base paper 1B Ply continuous sheet 1C Continuous sheet 1D Continuous water-decomposable sheet 1E Embossed sheet 2 Superposition part 3 Spray nozzle 4 First drying equipment 5 Slitter 6 Winder equipment 11 2 Next material roll 12 Embossing roll 13 Finishing equipment EM11 Embossing EM12 Embossing EM13 Embossing PR21 Bulging part PR22 Bulging part

In order to solve the above-described problem, the water-decomposable sheet according to claim 1 is
A substantially water-dispersible multi-ply base paper sheet containing pulp and a water-soluble binder is impregnated with an aqueous agent;
The basis weight of the plurality of plies is 30 to 150 gsm,
The content of the water-soluble binder is gradually increased toward the front surface and / or back surface.

The invention according to claim 2 is the invention according to claim 1,
A convex portion is formed on the water-decomposable sheet.

The invention according to claim 3 is the invention according to claim 2,
To the water disintegratable sheet has a first convex portion, the first arranged around the projecting portion and the first projecting portion is different from the second convex shape of the bulging portion, but formed on the entire surface Has been.

The invention according to claim 4 is the invention according to claim 3,
The first convex portions are arranged in a rhombus lattice.

The invention according to claim 5 is the invention according to claim 3 or 4,
The second convex portion is arranged between the two first convex portions .

The invention according to claim 6 is the invention according to any one of claims 3 to 5,
The first convex portion and the second convex portion are in contact with each other to form a convex portion .

The invention according to claim 7 is the invention according to claim 2,
The water-decomposable sheet has a plurality of rows in which the convex portions and concave portions having a shape obtained by inverting the convex portions are arranged in a single row, and the convex portions and the concave portions in adjacent rows are shifted from each other by a half pitch. ordered lattice pattern is formed.

Claims (8)

A substantially water-dispersible multi-ply base paper sheet containing pulp and a water-soluble binder is impregnated with an aqueous agent;
The basis weight of the plurality of plies is 30 to 150 gsm,
A water-decomposable sheet in which the content of the water-soluble binder is increased toward the front surface and / or back surface.   The water-decomposable sheet according to claim 1, wherein an emboss is formed on the water-decomposable sheet.   The water-decomposable sheet has a first emboss and a second emboss disposed around the first emboss and having a different bulge shape from the first emboss. Item 3. The water-decomposable sheet according to Item 2.   The water-decomposable sheet according to claim 3, wherein the first emboss is arranged in a rhombus lattice.   The water-decomposable sheet according to claim 3 or 4, wherein the second emboss is arranged between two of the first embosses.   The water-decomposable sheet according to any one of claims 3 to 5, wherein the first emboss and the second emboss are in contact with each other to form an emboss.   The water-decomposable sheet has a plurality of rows in which convex portions and concave portions having a shape obtained by inverting the convex portions are arranged in a single row, and the convex portions and the concave portions in adjacent rows are arranged so as to be shifted from each other by a half pitch. The water-decomposable sheet according to claim 2, wherein a latticed embossed pattern is formed.   The water-decomposable sheet according to any one of claims 1 to 7, wherein the water-decomposable sheet has a blending ratio of softwood pulp to hardwood pulp of less than 1/1.

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