JP2016204820A - Regenerated cellulose fiber containing functional material, method for producing the same, and fiber structure containing the same - Google Patents
Regenerated cellulose fiber containing functional material, method for producing the same, and fiber structure containing the same Download PDFInfo
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- JP2016204820A JP2016204820A JP2016089660A JP2016089660A JP2016204820A JP 2016204820 A JP2016204820 A JP 2016204820A JP 2016089660 A JP2016089660 A JP 2016089660A JP 2016089660 A JP2016089660 A JP 2016089660A JP 2016204820 A JP2016204820 A JP 2016204820A
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- functional material
- regenerated cellulose
- functional
- mass
- cellulose fiber
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- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Landscapes
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Abstract
Description
本発明は、特定の基材中に機能剤を包含した機能材を練り込んだ機能材含有再生セルロース繊維、その製造方法及びそれを含む繊維構造物に関する。 TECHNICAL FIELD The present invention relates to a functional material-containing regenerated cellulose fiber obtained by kneading a functional material containing a functional agent in a specific base material, a method for producing the same, and a fiber structure including the same.
再生セルロースを用いた再生セルロース繊維は、ビスコース法、銅アンモニア法、溶剤紡糸法等様々な方法で製造されることが知られている。再生セルロース繊維は基質がセルロースであるため、それ自体肌に優しい性質を有する。最近、再生セルロース繊維に様々な機能剤を練り込んで様々な性能を付与することが提案されている。 It is known that a regenerated cellulose fiber using regenerated cellulose is produced by various methods such as a viscose method, a copper ammonia method, and a solvent spinning method. Regenerated cellulose fiber has a nature that is gentle to the skin itself because the substrate is cellulose. Recently, it has been proposed to knead various functional agents into regenerated cellulose fibers to impart various performances.
例えば、特許文献1には、セルロース系繊維に、融点が100℃未満の炭化水素、オイル、脂肪酸、脂肪酸エステル、蜜蝋等の非極性有機化合物で忌避剤等の活性成分を包含した非極性有機化合物の包含物を含ませることが提案されている。また、特許文献2には、レーヨン繊維に脂肪酸及び/又はその塩と水溶性抗酸化剤や揮発性の芳香剤等の機能剤を含ませることが提案されている。また、特許文献3には、レーヨン繊維に20℃で固体であるシアバター等の油脂を含ませることが提案されている。また、特許文献4には、パラフィン系炭化水素、脂肪族アルコール等の非水溶性溶剤と水不溶性香料を混合した混合物を練り込んだビスコースレーヨン繊維が提案されている。 For example, Patent Document 1 discloses a nonpolar organic compound in which an active component such as a repellent is included in a cellulosic fiber and a nonpolar organic compound such as hydrocarbon, oil, fatty acid, fatty acid ester, or beeswax having a melting point of less than 100 ° C. It is proposed to include the inclusions. Patent Document 2 proposes that a rayon fiber contains a fatty acid and / or a salt thereof and a functional agent such as a water-soluble antioxidant or a volatile fragrance. Patent Document 3 proposes that oils such as shea butter that are solid at 20 ° C. are contained in rayon fibers. Patent Document 4 proposes a viscose rayon fiber kneaded with a mixture of a water-insoluble fragrance and a water-insoluble solvent such as paraffinic hydrocarbon and aliphatic alcohol.
特許文献1では、非極性有機化合物の包含物を繊維中に練り込むためにナノスケールヒューム等の粘度増加剤を用いており、工程中に異常が発生するおそれや、生産コストが上昇する問題と、非極性有機化合物及び所望により活性成分は、曲がりくねった経路を経由してのみ、セルロースマトリックスの中に入ることができるため、繊維断面から包含物や非極性有機化合物が流出し易いという問題がある。また、特許文献2では、脂肪酸を用いるため、ビスコース法によるレーヨン繊維化後の工程において強いアルカリ系の薬剤を使用すると、レーヨン繊維中の脂肪酸とアルカリ系の薬剤が反応し、中和し石鹸化してしまう問題がある。また、特許文献3では、油脂を用いるため、ビスコース法によるレーヨン繊維化後の工程において強いアルカリ系の薬剤を使用すると、レーヨン繊維中の油脂の脂肪酸成分とアルカリ系の薬剤が反応し、鹸化してしまう問題がある。また、特許文献4では、パラフィン系炭化水素、脂肪族アルコール等の非水溶性溶剤を用いているが、水不溶性香料が揮発性物質である場合、芳香成分の徐放性をさらに改善することが求められている。 In Patent Document 1, a viscosity increasing agent such as nanoscale fume is used to knead inclusions of nonpolar organic compounds into fibers, and there is a risk that abnormality may occur during the process and production costs increase. Since non-polar organic compounds and, if desired, active ingredients can only enter the cellulose matrix via a tortuous path, inclusions and non-polar organic compounds tend to flow out of the fiber cross section. . Further, in Patent Document 2, since fatty acid is used, if a strong alkaline chemical is used in the step after the formation of rayon fiber by the viscose method, the fatty acid in the rayon fiber reacts with the alkaline chemical to neutralize the soap. There is a problem that becomes. Further, in Patent Document 3, since fats and oils are used, if a strong alkaline chemical is used in the process after the formation of rayon fiber by the viscose method, the fatty acid component of the fats and oils in the rayon fiber reacts with the alkaline chemicals to saponify. There is a problem. In Patent Document 4, a water-insoluble solvent such as paraffinic hydrocarbon and aliphatic alcohol is used. However, when the water-insoluble fragrance is a volatile substance, the sustained release of the fragrance component can be further improved. It has been demanded.
本発明は、上記従来の問題を解決するため、特定の基材中に機能剤を包含した機能材を再生セルロース繊維中に練り込むことで、機能剤による効果を発揮することができる機能材含有再生セルロース繊維、その製造方法及びそれを含む繊維構造物を提供する。 In order to solve the above-mentioned conventional problems, the present invention contains a functional material that can exhibit the effect of the functional agent by kneading the functional material containing the functional agent in a specific base material into the regenerated cellulose fiber. A regenerated cellulose fiber, a method for producing the same, and a fiber structure including the same are provided.
本発明は、再生セルロース繊維内に機能材が含有された機能材含有再生セルロース繊維であり、上記再生セルロース繊維内のセルロースと上記機能材は非相溶であり、上記機能材は、基材と、上記基材に混合されている機能剤を含み、上記基材は、基材の全体質量に対して脂肪酸エステルを25質量%以上含むことを特徴とする機能材含有再生セルロース繊維に関する。 The present invention is a functional material-containing regenerated cellulose fiber in which a functional material is contained in the regenerated cellulose fiber, the cellulose in the regenerated cellulose fiber and the functional material are incompatible, and the functional material comprises a substrate and The functional material is contained in the base material, and the base material relates to a functional material-containing regenerated cellulose fiber containing 25 mass% or more of a fatty acid ester with respect to the total mass of the base material.
上記基材は、動物蝋及び植物蝋からなる群から選ばれる一種以上であることが好ましい。 The base material is preferably at least one selected from the group consisting of animal waxes and vegetable waxes.
上記脂肪酸エステルは、脂肪酸と1価アルコールのエステル、及び脂肪酸と2価アルコールのエステルからなる群から選ばれる一種以上であることが好ましい。 The fatty acid ester is preferably one or more selected from the group consisting of fatty acid and monohydric alcohol esters, and fatty acid and dihydric alcohol esters.
上記基材は、融点が40℃以上であることが好ましい。また、上記基材は、疎水性であることが好ましい。また、上記基材は、さらに脂肪酸及び炭化水素を含むことが好ましく、蜜蝋、カルナバ蝋及び木蝋からなる群から選ばれる一種以上であることがより好ましい。 The base material preferably has a melting point of 40 ° C. or higher. Moreover, it is preferable that the said base material is hydrophobic. Moreover, it is preferable that the said base material contains a fatty acid and a hydrocarbon further, and it is more preferable that it is 1 or more types chosen from the group which consists of beeswax, carnauba wax, and wood wax.
上記機能材含有再生セルロース繊維において、上記機能材は、セルロース100質量部に対して0.5〜20質量部の範囲で含まれていることが好ましい。上記機能材において、上記機能剤は、上記基材100質量部に対して3〜30質量部の範囲で含まれていることが好ましい。 In the above-described functional material-containing regenerated cellulose fiber, the functional material is preferably contained in the range of 0.5 to 20 parts by mass with respect to 100 parts by mass of cellulose. In the functional material, the functional agent is preferably contained in a range of 3 to 30 parts by mass with respect to 100 parts by mass of the base material.
本発明は、また、再生セルロース繊維内に機能材が含有された機能材含有再生セルロース繊維の製造方法であって、基材に機能剤を混合した混合物である機能材を乳化分散して得られた機能材の分散液を、セルロースを含むビスコースに混合して紡糸用ビスコースを調製し、上記紡糸用ビスコースをノズルより押し出して紡糸し、凝固再生することで、機能材含有再生セルロース繊維を得ており、上記機能材含有再生セルロース繊維において、上記機能材とセルロースは非相溶であり、上記基材は、基材の全体質量に対して脂肪酸エステルを25質量%以上含むことを特徴とする機能材含有再生セルロース繊維の製造方法に関する。 The present invention is also a method for producing a functional material-containing regenerated cellulose fiber in which a functional material is contained in a regenerated cellulose fiber, which is obtained by emulsifying and dispersing a functional material that is a mixture in which a functional agent is mixed with a base material. A functional material-containing regenerated cellulose fiber is prepared by mixing a dispersion of the functional material with viscose containing cellulose to prepare a viscose for spinning, extruding the spinning viscose from a nozzle, spinning, and coagulating and regenerating. In the above-mentioned functional material-containing regenerated cellulose fiber, the functional material and cellulose are incompatible, and the base material contains 25% by mass or more of a fatty acid ester with respect to the total mass of the base material. The present invention relates to a method for producing a functional material-containing regenerated cellulose fiber.
上記機能材の分散液において、上記機能材の平均粒子径は0.10〜0.90μmであることが好ましい。 In the functional material dispersion, the functional material preferably has an average particle size of 0.10 to 0.90 μm.
本発明は、また、上記の機能材含有再生セルロース繊維を含むことを特徴とする繊維構造物に関する。 The present invention also relates to a fiber structure comprising the above-described functional material-containing regenerated cellulose fiber.
上記繊維構造物は、上記機能材含有再生セルロース繊維を10〜90質量%含み、他の繊維として、機能材含有再生セルロース繊維以外の再生セルロース繊維、コットン、麻、ウール、アクリル繊維、ポリエステル繊維、ポリアミド繊維、ポリオレフィン繊維及びポリウレタン繊維からなる群から選ばれる少なくとも一つの繊維を10〜90質量%含むことが好ましい。 The fiber structure contains 10 to 90% by mass of the functional material-containing regenerated cellulose fiber, and as other fibers, regenerated cellulose fibers other than the functional material-containing regenerated cellulose fiber, cotton, hemp, wool, acrylic fiber, polyester fiber, It is preferable that 10-90 mass% of at least 1 fiber chosen from the group which consists of a polyamide fiber, a polyolefin fiber, and a polyurethane fiber is included.
本発明は、特定の基材中に機能剤を包含した機能材を再生セルロース繊維中に練り込むことで、機能剤による効果を発揮することができる機能材含有再生セルロース繊維及びそれを含む繊維構造物を提供する。 The present invention relates to a functional material-containing regenerated cellulose fiber capable of exhibiting the effect of the functional agent by kneading a functional material containing the functional agent in a specific base material into the regenerated cellulose fiber, and a fiber structure including the same Offer things.
本発明の製造方法によると、特定の基材に機能剤を混合した混合物である機能材を乳化分散して得られた機能材の分散液を、セルロースを含むビスコースに混合して調製した紡糸用ビスコースを用いることにより、特定の基材中に機能剤を包含した機能材を再生セルロース繊維中に練り込んだ機能材含有再生セルロース繊維を製造することができる。 According to the production method of the present invention, a spinning material prepared by mixing a functional material dispersion obtained by emulsifying and dispersing a functional material, which is a mixture of a functional material and a specific base material, mixed with viscose containing cellulose. By using viscose for use, a functional material-containing regenerated cellulose fiber in which a functional material including a functional agent in a specific base material is kneaded into the regenerated cellulose fiber can be produced.
本発明の発明者は機能剤を再生セルロース繊維に練り込むことについて鋭意検討した結果、脂肪酸エステルを25質量%以上含む基材を用い、機能剤を上記基材に混合した混合物である機能材を乳化分散して得られた機能材の分散液、好ましくは機能材の平均粒子径が0.10〜0.90μmの機能材の分散液をセルロースを含む紡糸液に添加し、該紡糸液を紡糸することで、機能剤を包含する機能材を再生セルロース繊維中に容易に練り込むことができ、機能剤による効果を持続的に発揮することができることを見出し、本発明に至った。上記機能材含有再生セルロース繊維において、上記機能材とセルロースは非相溶である。また、上記機能材含有再生セルロース繊維において、上記機能材はセルロース中に分散されていることが好ましい。繊維中の機能材粒子は、分散液に分散された粒子径のままか、それに近い粒子径で繊維内に存在することが予想される。そのため、分散液における機能材の平均粒子径と、上記機能材含有再生セルロース繊維における機能材の平均粒子径はほぼ同等であると考えられる。本発明において、分散液における機能材の平均粒子径は、レーザー回折光散乱法によって測定したメジアン径(D50)をいう。上記機能材含有再生セルロース繊維における機能材の存在は、例えば、繊維断面又は繊維側面を光学顕微鏡やデジタルマイクロスコープで観察することで確認することができる。 As a result of intensive studies on kneading the functional agent into the regenerated cellulose fiber, the inventor of the present invention uses a base material containing 25% by mass or more of a fatty acid ester, and a functional material that is a mixture in which the functional agent is mixed with the base material. A functional material dispersion obtained by emulsification and dispersion, preferably a functional material dispersion having an average particle diameter of 0.10 to 0.90 μm, is added to a spinning solution containing cellulose, and the spinning solution is spun. Thus, the present inventors have found that a functional material including a functional agent can be easily kneaded into the regenerated cellulose fiber, and that the effect of the functional agent can be continuously exhibited, and the present invention has been achieved. In the functional material-containing regenerated cellulose fiber, the functional material and cellulose are incompatible. In the functional material-containing regenerated cellulose fiber, the functional material is preferably dispersed in cellulose. The functional material particles in the fiber are expected to be present in the fiber with the particle diameter dispersed in the dispersion or close to that. Therefore, it is considered that the average particle diameter of the functional material in the dispersion and the average particle diameter of the functional material in the functional material-containing regenerated cellulose fiber are substantially the same. In the present invention, the average particle diameter of the functional material in the dispersion refers to the median diameter (D50) measured by a laser diffraction light scattering method. The presence of the functional material in the functional material-containing regenerated cellulose fiber can be confirmed by, for example, observing the fiber cross section or the fiber side surface with an optical microscope or a digital microscope.
上記基材は、基材の全体質量に対して脂肪酸エステルを25質量%以上含み、より好ましくは28質量%以上含み、さらに好ましくは30質量%以上含み、さらにより好ましくは35質量%以上含む。このような基材に機能剤を混合して基材中に機能剤を包含した機能材にすることで、該機能材を再生セルロース繊維中に練り込みやすく、機能剤による効果を持続的に発揮することができる機能材含有再生セルロース繊維が得られる。また、上記基材に機能剤を混合して得られた基材中に機能剤を包含した機能材を再生セルロース繊維中に練り込むことで、繊維の白度を従来の脂肪酸や油脂を含有させた繊維よりも高くすることができる。脂肪酸エステルは、例えば、脂肪酸トリグリセリドであってもよく、脂肪酸アルコールエステルであってもよい。 The base material contains 25% by mass or more, more preferably 28% by mass or more, further preferably 30% by mass or more, and still more preferably 35% by mass or more, based on the total mass of the base material. By mixing a functional agent with such a base material to make a functional material that includes the functional agent in the base material, the functional material can be easily kneaded into the regenerated cellulose fiber, and the effect of the functional agent can be demonstrated continuously. A functional material-containing regenerated cellulose fiber that can be obtained is obtained. In addition, the functional material containing the functional agent in the base material obtained by mixing the functional agent with the base material is kneaded into the regenerated cellulose fiber, so that the whiteness of the fiber is made to contain conventional fatty acids and fats and oils. It can be higher than the fiber. The fatty acid ester may be, for example, a fatty acid triglyceride or a fatty acid alcohol ester.
上記基材は、水に不溶性の機能剤を保持する母体としての機能を発揮しやすい観点から、脂肪酸と1価アルコールのエステル、及び脂肪酸と2価アルコールのエステルからなる群から選ばれる一種以上の脂肪酸エステルを25質量%以上含むことが好ましく、より好ましくは28質量%以上含み、さらに好ましくは30質量%以上含み、さらにより好ましくは35質量%以上含む。また、上記基材は、機能剤を基材に混ぜ合わせやすくするという観点から、脂肪酸と1価アルコールのエステル、及び脂肪酸と2価アルコールのエステルからなる群から選ばれる一種以上の脂肪酸エステルを85質量%以下含むことが好ましく、より好ましくは80質量%以下含む。また、高融点及び乳化性の観点から、上記基材において、上記脂肪酸エステルは、炭素数が20以上の高級アルコールと、炭素数が10以上の高級脂肪酸からなる炭素数が30以上の脂肪酸エステルであることが好ましい。炭素数が10以上の高級脂肪酸としては、例えば、セロチン酸、パルミチン酸、エイコセン酸、ドコセン酸、オレイン酸等が挙げられる。炭素数が20以上の高級アルコールとしては、例えば、ミリシルアルコール、セリルアルコール、エイコセノール、ドコセノール等が挙げられる。上記基材は、機能剤を基材に混ぜ合わせやすくするという観点から、さらに脂肪酸と炭化水素を含むことが好ましい。上記基材は、機能材を再生セルロース繊維内のセルロース中に分散させやすい観点から、疎水性であることが好ましい。 The base material is one or more selected from the group consisting of esters of fatty acids and monohydric alcohols, and esters of fatty acids and dihydric alcohols, from the viewpoint of easily exhibiting a function as a matrix that retains a water-insoluble functional agent. The fatty acid ester is preferably contained in an amount of 25% by mass or more, more preferably 28% by mass or more, further preferably 30% by mass or more, and still more preferably 35% by mass or more. In addition, from the viewpoint of facilitating mixing of the functional agent with the base material, the base material contains 85 or more types of fatty acid esters selected from the group consisting of fatty acid and monohydric alcohol esters and fatty acid and dihydric alcohol esters. It is preferably contained in an amount of not more than mass%, more preferably not more than 80 mass%. From the viewpoint of high melting point and emulsifiability, the fatty acid ester in the substrate is a fatty acid ester having 30 or more carbon atoms composed of a higher alcohol having 20 or more carbon atoms and a higher fatty acid having 10 or more carbon atoms. Preferably there is. Examples of higher fatty acids having 10 or more carbon atoms include serotic acid, palmitic acid, eicosenoic acid, docosenoic acid, and oleic acid. Examples of the higher alcohol having 20 or more carbon atoms include myricyl alcohol, seryl alcohol, eicosenol, docosenol and the like. It is preferable that the base material further contains a fatty acid and a hydrocarbon from the viewpoint of easily mixing the functional agent with the base material. The base material is preferably hydrophobic from the viewpoint of easily dispersing the functional material in the cellulose in the regenerated cellulose fiber.
上記基材は、融点が40℃以上であることが好ましく、より好ましくは45℃以上であり、さらに好ましくは50℃以上であり、さらに好ましくは60℃以上である。基材の融点が高いと、常温では固体で存在するため、基材中の機能剤が流出しにくく、また、機能剤が周囲環境の影響により変異しにくく、機能剤による効果が発揮されやすい。また、基材は、基材に機能剤を混合して得られた基材中に機能剤を包含した機能材を乳化分散して機能材の平均粒子径が0.10〜0.90μm程度の分散液を調整しやすい観点から、融点が100℃以下であることが好ましい。 The base material preferably has a melting point of 40 ° C or higher, more preferably 45 ° C or higher, still more preferably 50 ° C or higher, and further preferably 60 ° C or higher. When the base material has a high melting point, it exists in a solid state at normal temperature, so that the functional agent in the base material is less likely to flow out, and the functional agent is less likely to be mutated due to the influence of the surrounding environment, so that the effect of the functional agent is easily exhibited. The base material is obtained by emulsifying and dispersing a functional material including the functional agent in the base material obtained by mixing the functional agent with the base material, and the average particle size of the functional material is about 0.10 to 0.90 μm. From the viewpoint of easy adjustment of the dispersion, the melting point is preferably 100 ° C. or lower.
上記基材は、動物蝋及び植物蝋からなる群から選ばれる一種以上であることが好ましい。植物蝋としては、例えば、カルナバ蝋、木蝋、サトウキビ蝋、パーム蝋、カンデリラ蝋、オーリクリ蝋、大豆蝋、米ぬか蝋、ホホバオイル等が挙げられる。動物系の蝋としては、例えば、蜜蝋(ビーズワックス)、支那蝋(昆虫蝋)、クジラ蝋、セラック蝋、イボタ蝋、羊毛蝋(ラノリン)等が挙げられる。上記基材として、脂肪酸エステルを25質量%以上含む鉱物蝋を用いてもよい。脂肪酸エステルを25質量%以上含む鉱物蝋としては、モンタン蝋等が挙げられる。 The base material is preferably at least one selected from the group consisting of animal waxes and vegetable waxes. Examples of the vegetable wax include carnauba wax, wood wax, sugarcane wax, palm wax, candelilla wax, aurikuri wax, soybean wax, rice bran wax, jojoba oil and the like. Examples of animal waxes include beeswax (bead wax), Chinese wax (insect wax), whale wax, shellac wax, ibota wax, and wool wax (lanolin). As the base material, a mineral wax containing 25% by mass or more of a fatty acid ester may be used. Examples of the mineral wax containing 25% by mass or more of a fatty acid ester include montan wax.
上記基材は、脂肪酸と1価アルコールのエステル、及び脂肪酸と2価アルコールのエステルからなる群から選ばれる一種以上の脂肪酸エステルを25質量%以上含むことが好ましい。このような基材としては、例えば、蜜蝋(ビーズワックス)、支那蝋(昆虫蝋)、クジラ蝋、セラック蝋、イボタ蝋、羊毛蝋(ラノリン)等の動物蝋、カルナバ蝋、サトウキビ蝋、パーム蝋、カンデリラ蝋、オーリクリ蝋、大豆蝋、米ぬか蝋、ホホバオイル等の植物蝋、モンタン蝋等の鉱物系蝋等が挙げられる。上記基材は、脂肪酸と1価アルコールのエステル、及び脂肪酸と2価アルコールのエステルからなる群から選ばれる一種以上の脂肪酸エステルを30質量%以上含むことがより好ましい。このような基材としては、蜜蝋(ビーズワックス)、支那蝋(昆虫蝋)、クジラ蝋、セラック蝋、イボタ蝋、羊毛蝋(ラノリン)等の動物蝋、カルナバ蝋、サトウキビ蝋、パーム蝋、カンデリラ蝋、オーリクリ蝋、大豆蝋、米ぬか蝋、ホホバオイル等の植物蝋、モンタン蝋等の鉱物系蝋等が挙げられる。上記基材は、脂肪酸エステルに加えて、脂肪酸と炭化水素を含むことがより好ましい。中でも、高融点、保湿性及び分散性の観点から、蜜蝋及び/又はカルナバ蝋が好ましく、保湿性及び分散性の観点から、木蝋が好ましい。また、蜜蝋は、セイヨウミツバチ由来の高酸価の蜜蝋であることが好ましい。 The base material preferably contains 25% by mass or more of one or more fatty acid esters selected from the group consisting of esters of fatty acids and monohydric alcohols and esters of fatty acids and dihydric alcohols. Examples of such a base material include animal waxes such as beeswax, beeswax (insect wax), whale wax, shellac wax, ibota wax, wool wax (lanolin), carnauba wax, sugar cane wax, palm wax. , Plant waxes such as candelilla wax, aurikuri wax, soybean wax, rice bran wax, jojoba oil, and mineral waxes such as montan wax. More preferably, the substrate contains at least 30% by mass of one or more fatty acid esters selected from the group consisting of esters of fatty acids and monohydric alcohols, and esters of fatty acids and dihydric alcohols. Examples of such base materials include beeswax, beeswax (insect wax), whale wax, shellac wax, ibota wax, wool wax (lanolin) and other animal waxes, carnauba wax, sugar cane wax, palm wax, candelilla Examples thereof include waxes, aurikuri wax, soybean wax, rice bran wax, vegetable waxes such as jojoba oil, and mineral waxes such as montan wax. More preferably, the base material contains a fatty acid and a hydrocarbon in addition to the fatty acid ester. Among these, beeswax and / or carnauba wax are preferable from the viewpoint of high melting point, moisture retention and dispersibility, and wood wax is preferable from the viewpoint of moisture retention and dispersibility. The beeswax is preferably a high acid value beeswax derived from honey bees.
上述した基材は、一種で用いてもよく、二種以上を組み合わせて用いてもよい。基材が保湿性に優れ、且つ基材に機能剤を混合して得られた基材中に機能剤を包含した機能材を乳化分散して機能材の平均粒子径が0.10〜0.90μm程度の分散液を調整しやすい観点から、上記基材は、蜜蝋、カルナバ蝋及び木蝋からなる群から選ばれる一種以上であることが好ましい。 The base material mentioned above may be used by 1 type, and may be used in combination of 2 or more type. The base material is excellent in moisture retention, and the functional material containing the functional agent is emulsified and dispersed in the base material obtained by mixing the functional agent with the base material, so that the average particle size of the functional material is 0.10 to 0.00. From the viewpoint of easily adjusting a dispersion of about 90 μm, the substrate is preferably at least one selected from the group consisting of beeswax, carnauba wax and wood wax.
蜜蝋は、通常、下記表1に示すような組成を有する(佐々木正己、「養蜂の科学」、第1版、2003年4月22日、株式会社サイエンスハウス発行、122〜124頁を参照)。また、蜜蝋は、通常、62〜67℃の融点を有する。 Beeswax usually has a composition as shown in Table 1 below (see Masami Sasaki, “Beekeeping Science”, first edition, April 22, 2003, published by Science House, Inc., pages 122-124). Also, beeswax usually has a melting point of 62-67 ° C.
カルナバ蝋は、例えば、下記表2に示すような組成を有する(Totten, George E.; Westbrook, Steven R.; Shah, Rajesh J., "Fuels and Lubricants Handbook", 2003年, ASTM International発行, 526頁を参照)。また、カルナバ蝋は、通常、80〜86℃の融点を有する。 Carnauba wax has, for example, the composition shown in Table 2 below (Totten, George E .; Westbrook, Steven R .; Shah, Rajesh J., “Fuels and Lubricants Handbook”, 2003, published by ASTM International, 526. Page). Carnauba wax usually has a melting point of 80 to 86 ° C.
木蝋は、通常、下記表3に示すような組成を有する(Totten, George E.; Westbrook, Steven R.; Shah, Rajesh J., "Fuels and Lubricants Handbook", 2003年, ASTM International発行, 624頁を参照)。また、木蝋は、通常、45〜53℃の融点を有する。 Wood wax usually has the composition shown in Table 3 below (Totten, George E .; Westbrook, Steven R .; Shah, Rajesh J., "Fuels and Lubricants Handbook", 2003, published by ASTM International, page 624). See). In addition, wood wax usually has a melting point of 45 to 53 ° C.
上記機能剤としては、再生セルロース繊維に所定の性能、例えば、芳香性、保湿性、保温性、発熱性、消臭性、防虫性、抗菌性、防カビ性、防汚性、難燃性、温度調節性、導電性、制電性、帯電性、撥水性、親水性、光遮蔽性、熱遮蔽性、抗酸化性等の様々な性能を付与することができるものであればよく、特に限定されない。機能剤を基材と混合して機能剤を基材中に含有させた状態で再生セルロース繊維に練り込みやすい観点から、上記機能剤は、上記基材と相溶性を有することが好ましい。例えば、芳香剤、抗酸化剤、顔料、保湿剤、抗菌剤、防カビ剤、難燃剤、消臭剤、可塑剤、忌避剤、防蚊剤等の防虫剤、紫外線、可視光線及び赤外線から群から選ばれる一種以上の光線を吸収及び/又は反射する光遮蔽剤、紫外線、可視光線及び赤外線から群から選ばれる一種以上の熱線を吸収及び/又は反射する熱遮蔽剤等が挙げられる。芳香剤は、精油や樹脂等の天然香料、合成香料、調合香料等を含む。上記機能剤は、揮発性物質であってもよい。揮発性物質としては、揮発性の香料や忌避剤等が挙げられる。 As the functional agent, the regenerated cellulose fiber has a predetermined performance, for example, fragrance, moisture retention, heat retention, heat generation, deodorization, insect repellent, antibacterial property, antifungal property, antifouling property, flame retardancy, It is not particularly limited as long as it can provide various performances such as temperature controllability, conductivity, antistatic property, chargeability, water repellency, hydrophilicity, light shielding property, heat shielding property, and antioxidant property. Not. From the viewpoint of easy kneading into the regenerated cellulose fiber in a state where the functional agent is mixed with the base material and the functional agent is contained in the base material, the functional agent is preferably compatible with the base material. For example, fragrances, antioxidants, pigments, moisturizers, antibacterial agents, fungicides, flame retardants, deodorants, plasticizers, repellents, mosquito repellents, ultraviolet rays, visible light and infrared rays And a light shielding agent that absorbs and / or reflects one or more light rays selected from the group, a heat shielding agent that absorbs and / or reflects one or more heat rays selected from the group consisting of ultraviolet rays, visible rays, and infrared rays. The fragrance includes natural fragrances such as essential oils and resins, synthetic fragrances, blended fragrances and the like. The functional agent may be a volatile substance. Volatile substances include volatile fragrances and repellents.
芳香剤としては、特に限定されないが、例えば、ローズ、ジャスミン、キンモクセイ、ライラック、カシス、ペパーミント、スペアミント、シソ、ローズマリー、ローズヒップ、カモミール、ミント、レモングラス、ラベンダー、ベルガモット、セージ、ローレル、ウインターグリーン、ユーカリ、シナモン、キハダ、ハッカ、ジンジャー、ターメリック、オレンジ、ネーブルオレンジ、バレンシアオレンジ、マンダリン、レモン、ライム、柚子、温州みかん、伊予柑、夏ミカン、文旦、グレープフルーツ、シトラス、バニラ、ナツメグ、ビターアーモンド、マスタード、アップル、グレープ、ピーチ、ストロベリー、メロン、バナナ、パイナップル、マンゴー、アセロラ、ラズベリー、ブルーベリー、ミルク、キャラメル、チョコレート、桜、リモネン系、フローラルブーケ系、ホワイトフローラル系、ウッディ系、ムスク、アンバーグリス、シベット、カストリウム、スギ、ヒノキ等の樹木抽出物が挙げられる。 The fragrance is not particularly limited, but for example, rose, jasmine, beetle, lilac, cassis, peppermint, spearmint, perilla, rosemary, rose hip, chamomile, mint, lemongrass, lavender, bergamot, sage, laurel, winter Green, eucalyptus, cinnamon, yellowfin, peppermint, ginger, turmeric, orange, navel orange, valencia orange, mandarin, lemon, lime, coconut, mandarin orange, Iyokan, summer mandarin, summer mandarin, grapefruit, citrus, vanilla, nutmeg, bitter Almond, mustard, apple, grape, peach, strawberry, melon, banana, pineapple, mango, acerola, raspberry, blueberry, milk, caramel, chocolate, , Limonene-based, floral bouquet based, white floral, woody type, musk, ambergris, civet, castoreum, cedar, and trees extract cypress like.
抗酸化剤としては、特に限定されないが、例えば、トコフェロール(α型、β型、γ型、δ型);アスコルビン酸;イソアスコルビン酸;ユビキノール(コエンザイムQ10);リコピン;カテキン;アントシアニン;タンニン;クエルセチン;ミリシトリン;ミリセチン;グルタチオン;リポ酸;BHA(ブチルヒドロキシアニソール);BHT(ジブチルヒドロキシルトルエン);β−カロチン;イソフラボン等のフラボノイド;クロロゲン酸、エラグ酸、クルクミン等のフェノール酸;リンゴポリフェノール、カカオマスポリフェノール等のポリフェノール;アスタキサンチン、ルテイン等のカルテノイド、没食子酸誘導体;レスベラトロール等が挙げられる。 Although it does not specifically limit as an antioxidant, For example, tocopherol (alpha type, beta type, gamma type, delta type); Ascorbic acid; Isoascorbic acid; Ubiquinol (Coenzyme Q10); Lycopene; Catechin; Anthocyanin; Tannin; Quercetin Mycitolin; myricetin; glutathione; lipoic acid; BHA (butylhydroxyanisole); BHT (dibutylhydroxyltoluene); β-carotene; flavonoids such as isoflavone; phenolic acids such as chlorogenic acid, ellagic acid and curcumin; apple polyphenol, cacao mass Polyphenols such as polyphenols; carotenoids such as astaxanthin and lutein; gallic acid derivatives; resveratrol and the like.
保湿剤としては、特に限定されないが、例えば、ATP(アデノシン三リン酸、トリリン酸アデノシン)、コラーゲン、アミノ酸、γ−アミノ酪酸(ピぺリジン酸)、アルファヒドロキシ酸(AHA)、アルブミン、1、3−プチレングリコール(1、3BG)、HSオイル(HSリピッド)、NMF(白然保湿因子)、エラスチン、アスパラギン酸、アスパラキン酸ナトリウム、アルギニン、イソロイシン、グルタミン、グルタミン酸、グルタミン酸ナトリウム、スレオニン、チロシン、トリプトファン、バリン、ヒスチジン塩酸塩、ヒドロキシプロリン、プロリン、ロイシン、メチオニン、塩化マグネシウム、塩酸リジン、核酸、加水分解エラスチン、加水分解ケラチン、加水分解コンキオリン液、加水分解シルク、ゼラチン、カゼイン、酵母、マリンクレイ、キシリトール、キチン、キトサン、ムチン、グアノシン、グアニン、グリコール酸、グリシン、グリセリン、グルクロン酸、グルコサミン、ケラチン、酵素、コンドロイチン、シスチン、システイン、ジプロピレングリコール(DPG)、リパーゼ、シルク抽出液、エラスチン、セラミド、セリシン、セリン、ソルビトール、大豆タンパク質、大豆リン脂質、脱脂粉乳、タンパク質分解酵素、アラニン、ビロリドンカルポン酸、デオキシリポ核酸、動物胎盤エキス、トサカ抽出液、トレハロース、納豆エキス、ニガリパウダー、乳酸、乳酸菌培養液、ラクトース、尿酸、尿素、ハチミツ、ヒアルロン酸、ヒアルロン酸ナトリウム、ビプィズス菌エキス、フェニルアラニン、グルコース、プラセンターエキス、プルラン、プロデュウ、プロピレングリコール、ホエ一(乳清、乳酸菌発酵液)、ポリエチレングリコール、ポリグリセリン、マリンコラーゲン、ラクトフェリン、卵黄レシチン、リポ核酸、リンゴ酸、リン酸、リン酸リボフラビンナトリウム、リン脂質、レシチン、ローヤルゼリー等が挙げられる。 Although it does not specifically limit as a moisturizer, For example, ATP (adenosine triphosphate, adenosine triphosphate), collagen, an amino acid, (gamma) -aminobutyric acid (piperidine acid), alpha hydroxy acid (AHA), albumin, 1, 3-Putylene glycol (1, 3BG), HS oil (HS lipid), NMF (white moisturizing factor), elastin, aspartic acid, sodium aspartate, arginine, isoleucine, glutamine, glutamic acid, sodium glutamate, threonine, tyrosine , Tryptophan, valine, histidine hydrochloride, hydroxyproline, proline, leucine, methionine, magnesium chloride, lysine hydrochloride, nucleic acid, hydrolyzed elastin, hydrolyzed keratin, hydrolyzed conchiolin solution, hydrolyzed silk, gelatin, casein Yeast, marine clay, xylitol, chitin, chitosan, mucin, guanosine, guanine, glycolic acid, glycine, glycerin, glucuronic acid, glucosamine, keratin, enzyme, chondroitin, cystine, cysteine, dipropylene glycol (DPG), lipase, silk extraction Liquid, elastin, ceramide, sericin, serine, sorbitol, soy protein, soy phospholipid, skim milk powder, proteolytic enzyme, alanine, bilolidon carponic acid, deoxyliponucleic acid, animal placenta extract, Tosaka extract, trehalose, natto extract , Bittern powder, lactic acid, lactic acid bacteria culture solution, lactose, uric acid, urea, honey, hyaluronic acid, sodium hyaluronate, bipyzu bacteria extract, phenylalanine, glucose, placenta extract, pullulan, Produw, propylene glycol, whey (whey, lactic acid bacteria fermentation liquid), polyethylene glycol, polyglycerin, marine collagen, lactoferrin, egg yolk lecithin, liponucleic acid, malic acid, phosphoric acid, sodium riboflavin phosphate, phospholipid, lecithin, royal jelly Etc.
抗菌剤としては、特に限定されないが、例えば、アミノグリコシド系抗生物質、カルバペネム系抗生物質、セフェム系抗生物質、ペニシリン系抗生物質、ペネム系抗生物質、モノバクタム系抗生物質、ホスホマイシン系抗生物質、ケトライド系抗生物質、クロラムフェニコール系抗生物質、テトラサイクリン系抗生物質、リンコマイシン系抗生物質、マクロライド系抗生物質、塩酸バンコマイシン、キヌプリチン・ダルホプリスチン、コリスチンメタンスルホン酸ナトリウム、テイコプラニン、硫酸ポリミキシンB、リモネン、銀及びその化合物、亜鉛及びその化合物、アルミニウム及びその化合物等が挙げられる。 The antibacterial agent is not particularly limited. For example, aminoglycoside antibiotics, carbapenem antibiotics, cephem antibiotics, penicillin antibiotics, penem antibiotics, monobactam antibiotics, fosfomycin antibiotics, ketolide antibiotics Substances, chloramphenicol antibiotics, tetracycline antibiotics, lincomycin antibiotics, macrolide antibiotics, vancomycin hydrochloride, quinupritin / dalfopristin, sodium colistin methanesulfonate, teicoplanin, polymyxin B sulfate, limonene, silver and The compound, zinc and its compound, aluminum, its compound, etc. are mentioned.
防カビ剤としては、特に限定されないが、例えば、イマザリル、ジフェニル、チアベンダゾール、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、フルジオキソニル、アゾキシストロビン、ピリメタニル等が挙げられる。 The antifungal agent is not particularly limited, and examples thereof include imazalyl, diphenyl, thiabendazole, orthophenylphenol, sodium orthophenylphenol, fludioxonil, azoxystrobin, pyrimethanil and the like.
難燃剤としては、特に限定されないが、例えば、無機系難燃剤、有機系難燃剤、シリコン系難燃剤等が挙げられる。無機系難燃剤としては、特に限定されないが、例えば、水酸化アルミニウム、水酸化マグネシウム等の水和金属系;赤リン、リン酸アンモニウム、炭酸アンモニウム等のリン系・窒素系;ホウ酸亜鉛;錫酸亜鉛;モリブテン化合物等が挙げられる。有機系難燃剤としては、反応型や添加型等が挙げられる。反応型有機系難燃剤としては、特に限定されないが、例えば、臭素化モノマー、臭素化エポキシ等のハロゲン系難燃剤、リン酸エステル等のリン系難燃剤等が挙げられる。添加型有機系難燃剤としては、特に限定されないが、例えば、臭素系エーテル、臭素系オリゴマー/ポリマー、臭素化ポリスチレン、塩素系等のハロゲン系難燃剤;ハロゲン-リン系難燃剤;リン酸エステル、含リンポリオール、含リンアミン等のリン系難燃剤;メラミンシアヌレート、トリアジン化合物、グアニジン化合物等の窒素系難燃剤等が挙げられる。シリコン系難燃剤としては、特に限定されないが、例えば、シリコンポリマー、ケイ酸、ケイ酸塩等が挙げられる。 The flame retardant is not particularly limited, and examples thereof include inorganic flame retardants, organic flame retardants, and silicon flame retardants. The inorganic flame retardant is not particularly limited. For example, hydrated metal systems such as aluminum hydroxide and magnesium hydroxide; phosphorus and nitrogen systems such as red phosphorus, ammonium phosphate and ammonium carbonate; zinc borate; tin Zinc acid; a molybdate compound and the like. Examples of the organic flame retardant include a reaction type and an addition type. The reactive organic flame retardant is not particularly limited, and examples thereof include halogen flame retardants such as brominated monomers and brominated epoxies, and phosphorus flame retardants such as phosphate esters. The additive-type organic flame retardant is not particularly limited, and examples thereof include halogen flame retardants such as bromine ether, bromine oligomer / polymer, brominated polystyrene, and chlorine; halogen-phosphorous flame retardants; phosphate esters, Examples thereof include phosphorus-based flame retardants such as phosphorus-containing polyols and phosphorus-containing amines; nitrogen-based flame retardants such as melamine cyanurate, triazine compounds, and guanidine compounds. Although it does not specifically limit as a silicon-type flame retardant, For example, a silicon polymer, a silicic acid, a silicate etc. are mentioned.
消臭剤としては、特に限定されないが、例えば、酸化アルミニウム、二酸化ケイ素、酸化銅、酸化鉄、酸化コバルト、酸化ニッケル、シリカゲル、シリカゾル、ゼオライト、モンモリロナイト、アロフェン、セピオライト等の無機系消臭剤;カルボキシル基、スルホン基、アミノ基等の官能基を有する吸着剤、カルボキシル基、スルホン基、アミノ基等の官能基を有するポリマー等の有機系消臭剤が挙げられる。 Although it does not specifically limit as a deodorizer, For example, inorganic type deodorizers, such as aluminum oxide, silicon dioxide, copper oxide, iron oxide, cobalt oxide, nickel oxide, silica gel, silica sol, zeolite, montmorillonite, allophane, sepiolite; Examples thereof include an adsorbent having a functional group such as a carboxyl group, a sulfone group, and an amino group, and an organic deodorant such as a polymer having a functional group such as a carboxyl group, a sulfone group, and an amino group.
忌避剤としては、特に限定されないが、例えば、ケイ皮酸エチル、ケイ皮酸メチル、シンナミルアセテート、ケイ皮酸誘導体、除虫菊、パラジクロロベンゼン、ナフタリン、樟脳、ピレスロイド、ワサビ、唐辛子、シソ、茶エキス、ハッカ油、スギ、ヒノキ等の樹木からの抽出物等が挙げられる。 The repellent is not particularly limited. For example, ethyl cinnamate, methyl cinnamate, cinnamyl acetate, cinnamic acid derivatives, pesticide chrysanthemum, paradichlorobenzene, naphthalene, camphor, pyrethroid, wasabi, chili, perilla, tea extract , Extracts from trees such as mint oil, cedar and cypress.
光遮蔽剤としては、特に限定されないが、例えば、二酸化チタン、硫酸バリウム、アルミナ、シリカ、酸化亜鉛、酸化マグネシウム、硫酸マグネシウム等が挙げられる。 The light shielding agent is not particularly limited, and examples thereof include titanium dioxide, barium sulfate, alumina, silica, zinc oxide, magnesium oxide, and magnesium sulfate.
熱遮蔽剤としては、特に限定されないが、例えば、フタロシアニン類、ナフタロシアニン類、アントラキノン類、酸化チタン、酸化マグネシウム、酸化アルミニウム、酸化亜鉛、金、銀、銅等の金属微粒子等が挙げられる。 Although it does not specifically limit as a heat shielding agent, For example, metal particles, such as phthalocyanines, naphthalocyanines, anthraquinones, titanium oxide, magnesium oxide, aluminum oxide, zinc oxide, gold, silver, copper, etc. are mentioned.
上記機能剤は、水不溶性であることが好ましい。上記機能剤が基材中に包含されていることにより、機能剤による性能付与が向上するとともに、耐久性が向上する。特に、機能剤が揮発性物質である場合、繊維の製造工程中の機能剤の喪失を防ぎ、機能剤による性能付与が容易になるとともに、耐久性が向上し、芳香性等の性能を長く維持でき、機能剤を長期間持続的に放出する(徐放性)ことが可能となる。上記機能剤は、一種を単独で用いてもよく、二種以上を組み合わせて用いてもよい。 The functional agent is preferably water-insoluble. When the functional agent is included in the base material, performance imparting by the functional agent is improved and durability is improved. In particular, when the functional agent is a volatile substance, loss of the functional agent during the fiber manufacturing process can be prevented, performance can be easily imparted by the functional agent, durability can be improved, and performance such as fragrance can be maintained for a long time. It is possible to release the functional agent continuously for a long period of time (sustained release). The said functional agent may be used individually by 1 type, and may be used in combination of 2 or more type.
上記機能材含有再生セルロース繊維において、上記機能剤を基材中に包含している機能材は、セルロース100質量部に対して0.5〜20質量部の範囲で存在しているのが好ましく、より好ましくは0.7〜15質量部の範囲であり、さらに好ましくは1.0〜10質量部の範囲であり、さらにより好ましくは1.5〜6質量部の範囲である。この範囲であると、機能剤による性能付与と繊維強度の両立が可能となる。 In the functional material-containing regenerated cellulose fiber, the functional material containing the functional agent in the base material is preferably present in a range of 0.5 to 20 parts by mass with respect to 100 parts by mass of cellulose. More preferably, it is the range of 0.7-15 mass parts, More preferably, it is the range of 1.0-10 mass parts, More preferably, it is the range of 1.5-6 mass parts. Within this range, it is possible to achieve both performance imparting by the functional agent and fiber strength.
上記機能材において、上記機能剤は、基材100質量部に対して3〜30質量部の範囲で含まれていることが好ましく、より好ましくは4〜30質量部の範囲で含まれており、さらに好ましくは5〜28質量部含まれている。この範囲であると、機能剤を基材中に包含されることが容易であるとともに、機能剤による性能を発揮しやすい。 In the said functional material, it is preferable that the said functional agent is contained in the range of 3-30 mass parts with respect to 100 mass parts of base materials, More preferably, it is contained in the range of 4-30 mass parts, More preferably, 5-28 mass parts is contained. Within this range, it is easy for the functional agent to be included in the base material, and performance by the functional agent is easily exhibited.
繊維中に均一に微分散されることで機能材の特性が発揮できるという観点から、上記機能材含有再生セルロース繊維において、上記機能材の平均粒子径は、0.05〜1.00μmであることが好ましく、より好ましくは0.07〜0.95μmであり、さらに好ましくは0.10〜0.90μmであり、さらにより好ましくは0.15〜0.80μmである。 From the viewpoint that the properties of the functional material can be exhibited by being uniformly finely dispersed in the fiber, in the functional material-containing regenerated cellulose fiber, the average particle size of the functional material is 0.05 to 1.00 μm. Is more preferably 0.07 to 0.95 μm, still more preferably 0.10 to 0.90 μm, and even more preferably 0.15 to 0.80 μm.
上記機能材含有再生セルロース繊維において、機能材の平均粒子径は、脱油処理後の上記機能材含有再生セルロース繊維を用いて測定することができる。具体的には、脱油処理後の上記機能材含有再生セルロース繊維における空隙部の平均孔径を測定することで、上記機能材含有再生セルロース繊維内の機能材の平均粒子径を確認することができる。脱油処理後の上記機能材含有再生セルロース繊維における空隙部は、脱油処理により微分散していた機能材が抜けることにより形成されるものであるため、脱油処理後の上記機能材含有再生セルロース繊維における空隙部の平均孔径を測定することで、上記機能材含有再生セルロース繊維内の機能材の平均粒子径を確認することができる。上記機能材含有再生セルロース繊維の脱油処理後の空隙部の平均孔径は、脱油処理後の繊維の断面写真(走査型電子顕微鏡写真、倍率3000倍)を用いて測定する。具体的には、脱油処理後の繊維の断面写真(走査型電子顕微鏡写真、倍率3000倍)を画像処理により倍率9010倍に拡大し、印刷した紙面上から任意の繊維の断面をサンプリングし、その繊維断面における繊維の外周から3μm内部までの間に存在する空隙部の直径を計測し、計測した100個の空隙部の直径を平均して空隙部の平均孔径とする。なお、楕円状の空隙部は長径及び短径を計測して算出した面積から真円直径に換算し、空隙部の直径とする。上記において、脱油処理は、下記のように行う。
(I)試料約2.3gを精秤し、底部に小さい穴の空いた試料管に詰める。
(II)底部の穴を塞ぎ、抽出溶媒としてメタノール10mlを試料管に注加し、一定時間静置し浸透させてからプレス装置によりメタノール処理液を抽出する。
(III)同じ試料を使用して上記の操作(II)による抽出を20回繰り返した後、試料管から取り出した試料を水洗し、105℃、2時間で乾燥して脱油処理後の繊維を得る。
In the functional material-containing regenerated cellulose fiber, the average particle diameter of the functional material can be measured using the functional material-containing regenerated cellulose fiber after deoiling treatment. Specifically, the average particle diameter of the functional material in the functional material-containing regenerated cellulose fiber can be confirmed by measuring the average pore size of the voids in the functional material-containing regenerated cellulose fiber after the deoiling treatment. . The voids in the functional material-containing regenerated cellulose fiber after the deoiling treatment are formed by the removal of the functional material that was finely dispersed by the deoiling treatment, so the functional material-containing regeneration after the deoiling treatment. By measuring the average pore diameter of the voids in the cellulose fiber, the average particle diameter of the functional material in the functional material-containing regenerated cellulose fiber can be confirmed. The average pore diameter of the voids after the deoiling treatment of the functional material-containing regenerated cellulose fiber is measured using a cross-sectional photograph (scanning electron micrograph, magnification 3000 times) of the fiber after the deoiling treatment. Specifically, the cross-sectional photograph of the fiber after deoiling treatment (scanning electron micrograph, magnification 3000 times) is magnified to a magnification of 9010 by image processing, and the cross-section of any fiber is sampled from the printed paper, The diameter of the void existing between the outer periphery of the fiber and the inside of 3 μm in the fiber cross section is measured, and the average diameter of the 100 measured voids is taken as the average pore diameter of the void. In addition, an elliptical space | gap part is converted into a perfect circle diameter from the area calculated by measuring a long diameter and a short diameter, and is set as the diameter of a space | gap part. In the above, the deoiling process is performed as follows.
(I) About 2.3 g of a sample is precisely weighed and packed in a sample tube having a small hole at the bottom.
(II) The bottom hole is closed, and 10 ml of methanol as an extraction solvent is poured into the sample tube, allowed to stand for a certain period of time and allowed to permeate, and then the methanol treatment liquid is extracted by a press device.
(III) Using the same sample, the extraction by the above operation (II) was repeated 20 times, and then the sample taken out from the sample tube was washed with water, dried at 105 ° C. for 2 hours, and the fiber after the deoiling treatment was performed. obtain.
上記機能材含有再生セルロース繊維は、本発明の目的を阻害しない範囲内において、上記機能材に加えて、他の化合物粒子を含んでもよい。他の化合物粒子としては、有機及び/又は無機の材料が挙げられる。有機の材料としては、例えば、スチレン系樹脂、アクリル系樹脂等の粒子が挙げられる。無機の材料としては、例えば、亜鉛、銅、マグネシウム、カルシウム、アルミニウム、銀等の金属又はその塩;酸化チタン、酸化スズ、酸化ジルコニウム、ケイ酸ジルコニウム等の金属酸化物;二酸化ケイ素、リン酸系化合物等の非金属化合物等が挙げられる。 The functional material-containing regenerated cellulose fiber may contain other compound particles in addition to the functional material as long as the object of the present invention is not impaired. Other compound particles include organic and / or inorganic materials. Examples of the organic material include particles such as a styrene resin and an acrylic resin. Inorganic materials include, for example, metals such as zinc, copper, magnesium, calcium, aluminum and silver or salts thereof; metal oxides such as titanium oxide, tin oxide, zirconium oxide and zirconium silicate; silicon dioxide and phosphate Non-metallic compounds such as compounds are exemplified.
上記機能材含有再生セルロース繊維が、ビスコース法によるビスコースレーヨン繊維の場合、他の化合物粒子は、耐酸及び/又は耐アルカリの粒子であることが好ましい。例えば、pH1以下の強酸及び/又はpH13以上の強アルカリ雰囲気に耐性を有する粒子であることが好ましい。或いは、他の化合物粒子は、ビスコースに溶解するか、又はビスコース中で異物形成しない粒子であることが好ましい。具体的には、他の化合物粒子の耐酸性は、10%硫酸水溶液に約1〜3質量%の粒子を添加し、溶液中の粒子の状態を観察することで確認できる。同様に、他の粒子の耐アルカリ性は、6%水酸化ナトリウム溶液に、約1〜3質量%の粒子を添加し、耐酸性と同様にして確認できる。 When the functional material-containing regenerated cellulose fiber is a viscose rayon fiber by a viscose method, the other compound particles are preferably acid-resistant and / or alkali-resistant particles. For example, particles having resistance to a strong acid having a pH of 1 or less and / or a strong alkali atmosphere having a pH of 13 or more are preferable. Alternatively, the other compound particles are preferably particles that dissolve in viscose or do not form foreign matters in the viscose. Specifically, the acid resistance of other compound particles can be confirmed by adding about 1 to 3% by mass of particles to a 10% sulfuric acid aqueous solution and observing the state of the particles in the solution. Similarly, the alkali resistance of other particles can be confirmed in the same manner as acid resistance by adding about 1 to 3% by mass of particles to a 6% sodium hydroxide solution.
風合いと繊維強度の両立の観点から、上記機能材含有再生セルロース繊維内における他の化合物粒子の含有量は、セルロース100質量部に対して0.1〜15質量部であることが好ましく、より好ましくは0.15〜10質量部であり、さらに好ましくは0.2〜5質量部である。 From the viewpoint of the balance between texture and fiber strength, the content of the other compound particles in the functional material-containing regenerated cellulose fiber is preferably 0.1 to 15 parts by mass, more preferably 100 parts by mass of cellulose. Is 0.15 to 10 parts by mass, and more preferably 0.2 to 5 parts by mass.
上記機能材含有再生セルロース繊維は、ビスコース法により得られるビスコースレーヨン繊維以外にも、銅アンモニアレーヨン(キュプラ)、溶剤紡糸セルロース繊維(リヨセル)、アセテート繊維等が挙げられる。 In addition to the viscose rayon fiber obtained by the viscose method, the functional material-containing regenerated cellulose fiber includes copper ammonia rayon (cupra), solvent-spun cellulose fiber (lyocell), acetate fiber, and the like.
上記機能材含有再生セルロース繊維は、上記機能材を紡糸液に添加する以外は、公知の再生セルロース繊維の製造方法にて製造することができる。紡糸液としては、ビスコースレーヨン繊維の場合は、セルロースを含むビスコースを用いることができ、銅アンモニアレーヨン(キュプラ)の場合は、セルロースを溶解させた銅アンモニウム溶液を用いることができ、溶剤紡糸セルロース繊維(リヨセル)の場合は、セルロースを溶剤に溶解させた溶液を用いることができ、アセテート繊維の場合は、アセチルセルロースをアセトンに溶解した溶液を用いることができる。これらの紡糸液に機能材の分散液、好ましくは機能材の平均粒子径が0.10〜0.90μmの機能材の分散液を添加し、機能材を添加した紡糸液を一般的な湿式紡糸法で紡糸することで、基材中に機能剤を包含した機能材がセルロース中に存在する機能材含有再生セルロース繊維を得ることができる。 The functional material-containing regenerated cellulose fiber can be produced by a known method for producing regenerated cellulose fiber, except that the functional material is added to the spinning solution. As the spinning solution, in the case of viscose rayon fiber, viscose containing cellulose can be used, and in the case of copper ammonia rayon (cupra), a copper ammonium solution in which cellulose is dissolved can be used. In the case of cellulose fiber (lyocell), a solution in which cellulose is dissolved in a solvent can be used, and in the case of acetate fiber, a solution in which acetyl cellulose is dissolved in acetone can be used. A functional material dispersion liquid, preferably a functional material dispersion liquid having an average particle diameter of the functional material of 0.10 to 0.90 μm, is added to these spinning liquids, and the spinning liquid to which the functional material is added is used for general wet spinning. By spinning by the method, a functional material-containing regenerated cellulose fiber in which a functional material including a functional agent in the substrate is present in cellulose can be obtained.
上記機能材の分散液において、乳化分散された機能材の平均粒子径(D50)が0.10〜0.90μmの範囲内であることにより、生産工程が良好になり、繊維の繊度を細くしやすくなる。上記機能材の分散液において、機能材の平均粒子径は、好ましくは0.15〜0.80μmであり、より好ましくは0.20〜0.70μmであり、さらに好ましくは0.30〜0.70μmの範囲内であり、さらにより好ましくは0.40〜0.60μmの範囲内である。 In the dispersion of the functional material, when the average particle diameter (D50) of the emulsified and dispersed functional material is within the range of 0.10 to 0.90 μm, the production process is improved and the fineness of the fiber is reduced. It becomes easy. In the functional material dispersion, the average particle size of the functional material is preferably 0.15 to 0.80 μm, more preferably 0.20 to 0.70 μm, and still more preferably 0.30 to 0.00. It is in the range of 70 μm, and more preferably in the range of 0.40 to 0.60 μm.
基材中に機能剤を包含しやすい観点から、上記基材を融点以上の温度で溶融した後に溶融状態の基材に機能剤を混合して機能材を調製することが好ましい。次いで、得られた基材と機能剤の混合物である機能材を、乳化分散して機能材の分散液を調製する。乳化分散時に、必要に応じて、界面活性剤、具体的にはアニオン系界面活性剤及び/又はノニオン系界面活性剤を乳化剤として用いることができる。 From the viewpoint of easily including the functional agent in the base material, it is preferable to prepare the functional material by melting the base material at a temperature equal to or higher than the melting point and then mixing the functional agent with the molten base material. Subsequently, the functional material which is a mixture of the obtained base material and functional agent is emulsified and dispersed to prepare a functional material dispersion. At the time of emulsification and dispersion, a surfactant, specifically, an anionic surfactant and / or a nonionic surfactant can be used as an emulsifier as needed.
ビスコースレーヨンの場合、具体的には、上記基材に上記機能剤を混合して得られた機能材を水に乳化分散して機能材の水分散液、好ましくは機能材の平均粒子径が0.10〜0.90μmの機能材の水分散液を調製し、得られた水分散液をセルロースを含むビスコースに混合して紡糸用ビスコースを調製し、得られた紡糸用ビスコースをノズルより押し出して紡糸し、凝固再生することで作製することができる。これにより、基材中に機能剤を包含した機能材を再生セルロース繊維内に存在させることができる。 In the case of viscose rayon, specifically, the functional material obtained by mixing the functional agent with the base material is emulsified and dispersed in water to obtain an aqueous dispersion of the functional material, preferably the average particle diameter of the functional material. An aqueous dispersion of a functional material of 0.10 to 0.90 μm is prepared, and the obtained aqueous dispersion is mixed with viscose containing cellulose to prepare a viscose for spinning, and the obtained viscose for spinning is obtained. It can be produced by extruding from a nozzle, spinning, and coagulating and regenerating. Thereby, the functional material which included the functional agent in the base material can be made to exist in the regenerated cellulose fiber.
セルロースを含むビスコースとしては、例えば、セルロースを7〜10質量%、水酸化ナトリウムを5〜8質量%、二硫化炭素を2〜3.5質量%を含むビスコースを用いることができる。また、セルロースを含むビスコースは、必要に応じて、エチレンジアミン4酢酸(EDTA)、二酸化チタン等の添加剤を含んでもよい。上記セルロースを含むビスコースに、上記機能材の水分散液を混合して紡糸用ビスコースを調製する。また、必要に応じて、上述した他の化合物粒子を混合する。紡糸用ビスコースの温度は19〜23℃に保持するのが好ましい。上記紡糸用ビスコースにおいて、上記機能材の添加量はセルロース100質量部に対して0.5〜20質量部であることが好ましく、0.7〜15質量部であることがより好ましく、1.0〜10質量部であることがさらに好ましく、1.5〜6質量部であることがさらにより好ましい。 As viscose containing cellulose, for example, viscose containing 7 to 10% by mass of cellulose, 5 to 8% by mass of sodium hydroxide, and 2 to 3.5% by mass of carbon disulfide can be used. Moreover, the viscose containing a cellulose may also contain additives, such as ethylenediaminetetraacetic acid (EDTA) and titanium dioxide, as needed. A viscose for spinning is prepared by mixing an aqueous dispersion of the functional material with the viscose containing cellulose. Moreover, the other compound particle | grains mentioned above are mixed as needed. The temperature of the spinning viscose is preferably maintained at 19 to 23 ° C. In the spinning viscose, the amount of the functional material added is preferably 0.5 to 20 parts by mass, more preferably 0.7 to 15 parts by mass with respect to 100 parts by mass of cellulose. It is more preferable that it is 0-10 mass parts, and it is still more preferable that it is 1.5-6 mass parts.
紡糸浴(ミューラー浴)としては、硫酸を95〜130g/リットル、硫酸亜鉛を10〜17g/リットル、硫酸ナトリウムを290〜370g/リットルを含む紡糸浴を用いることが好ましい。より好ましい硫酸濃度は、100〜120g/リットルである。また、紡糸浴は、温度を45〜60℃とすることが好ましい。 As the spinning bath (Mueller bath), it is preferable to use a spinning bath containing 95 to 130 g / liter of sulfuric acid, 10 to 17 g / liter of zinc sulfate, and 290 to 370 g / liter of sodium sulfate. A more preferable sulfuric acid concentration is 100 to 120 g / liter. The spinning bath preferably has a temperature of 45 to 60 ° C.
紡糸ノズルとしては、特に限定されず、円形ノズルを用いてもよく、異形ノズルを用いてもよい。また、紡糸ノズルの選定は、目的とする生産量にもよるが、直径0.05〜0.12mmのホールを1000〜20000ホール有するものが好ましい。 The spinning nozzle is not particularly limited, and a circular nozzle or a deformed nozzle may be used. In addition, the selection of the spinning nozzle depends on the target production amount, but preferably has a hole having a diameter of 0.05 to 0.12 mm and 1000 to 20000 holes.
上記紡糸ノズルを用いて、上記で得られた紡糸用ビスコースを紡糸浴中に押し出して紡糸し、凝固再生させる。紡糸速度は35〜75m/分の範囲が好ましい。また、延伸率は30〜50%が好ましい。本発明において、「延伸率」とは、延伸前の糸条の長さを100%としたとき、延伸後の糸条の長さを何%伸ばすかを示すものである。倍率で示すと、延伸前が1、延伸後は1.30〜1.50倍となる。 Using the spinning nozzle, the spinning viscose obtained above is extruded into a spinning bath, spun, and coagulated and regenerated. The spinning speed is preferably in the range of 35 to 75 m / min. The stretching ratio is preferably 30 to 50%. In the present invention, the “stretch rate” indicates how many percent the length of the yarn after stretching is to be extended when the length of the yarn before stretching is 100%. In terms of magnification, the ratio is 1 before stretching and 1.30 to 1.50 times after stretching.
上記のようにして得られた再生セルロース繊維糸条を所定の長さにカットし、精練処理を行う。精練処理は、通常の方法で、熱水処理、水硫化処理、漂白、酸洗い、及び油剤付与の順で行うとよい。水硫化処理は、例えば、水硫化ソーダ等で行うことができる。漂白は、例えば、次亜塩素酸ソーダ等で行うことができる。なお、水硫化処理、漂白及び酸洗いは、適宜省いてもよい。 The regenerated cellulose fiber yarn obtained as described above is cut into a predetermined length and subjected to a scouring treatment. The scouring treatment is preferably carried out in the order of hot water treatment, hydrosulfurization treatment, bleaching, pickling, and oil application. The hydrosulfurization treatment can be performed using, for example, sodium hydrosulfide. Bleaching can be performed, for example, with sodium hypochlorite. The hydrosulfurization treatment, bleaching and pickling may be omitted as appropriate.
その後、必要に応じて圧縮ローラーや真空吸引等の方法で余分な油剤、水分を繊維から除去した後、乾燥処理を施す。 Then, after removing excess oil agent and water | moisture content from a fiber by methods, such as a compression roller and vacuum suction, as needed, a drying process is performed.
上記機能材含有再生セルロース繊維は、繊度が0.3〜6.0dtexであることが好ましい。より好ましくは0.6〜4.0dtexであり、さらに好ましくは0.9〜3.3dtexである。繊度が0.3dtex未満であると、延伸時に単繊維切れが発生しやすい傾向にある。繊度が6.0dtexを越えると、衣料用途には向かなくなる恐れがある。しかし、カーペット等のインテリア製品用であれば6.0dtexを越える太繊度の繊維でも使用できる。 The functional material-containing regenerated cellulose fiber preferably has a fineness of 0.3 to 6.0 dtex. More preferably, it is 0.6-4.0 dtex, More preferably, it is 0.9-3.3 dtex. When the fineness is less than 0.3 dtex, the single fiber tends to be broken during stretching. If the fineness exceeds 6.0 dtex, there is a risk that it will not be suitable for clothing use. However, for interior products such as carpets, fibers having a fineness exceeding 6.0 dtex can be used.
上記機能材含有再生セルロース繊維は、通常の再生セルロース繊維とほぼ同等の強度を有する観点から、乾強度は1.5cN/dtex以上であることが好ましく、より好ましくは2.0cN/dtex以上であり、湿強度は0.8cN/dtex以上であることが好ましく、より好ましくは1.0cN/dtex以上である。また、通常の再生セルロース繊維とほぼ同等の伸度を有する観点から、乾伸度は15%以上であることが好ましく、より好ましくは17%以上であり、湿伸度は17%以上であることが好ましく、より好ましくは19%以上である。本発明において、繊度、乾強度、湿強度、乾伸度及び湿伸度は、後述するとおりに測定する。 The functional material-containing regenerated cellulose fiber preferably has a dry strength of 1.5 cN / dtex or more, more preferably 2.0 cN / dtex or more, from the viewpoint of having almost the same strength as normal regenerated cellulose fiber. The wet strength is preferably 0.8 cN / dtex or more, more preferably 1.0 cN / dtex or more. Further, from the viewpoint of having an elongation almost equal to that of ordinary regenerated cellulose fiber, the dry elongation is preferably 15% or more, more preferably 17% or more, and the wet elongation is 17% or more. Is more preferable, and more preferably 19% or more. In the present invention, the fineness, dry strength, wet strength, dry elongation, and wet elongation are measured as described later.
上記機能材含有再生セルロース繊維は、水硫化処理や漂白処理を行っても変質しにくい基材を使うため、白度が高い繊維を得ることができる。上記機能材含有再生セルロース繊維は、白度が向上する観点から、後述するように測定算出したハンター白色度が80以上であることが好ましく、より好ましくは85以上であり、さらに好ましくは90以上である。 Since the functional material-containing regenerated cellulose fiber uses a base material that does not easily deteriorate even when subjected to hydrosulfurization treatment or bleaching treatment, a fiber with high whiteness can be obtained. From the viewpoint of improving whiteness, the functional material-containing regenerated cellulose fiber preferably has a Hunter whiteness measured and calculated as described later of 80 or more, more preferably 85 or more, and still more preferably 90 or more. is there.
上記機能材含有再生セルロース繊維は、長繊維状及び短繊維状のいずれの形態であってもよい。長繊維状としては、トウ、フィラメント、不織布等が挙げられる。短繊維状としては、湿式抄紙用原綿、エアレイド不織布用原綿、カード用原綿等が挙げられる。 The functional material-containing regenerated cellulose fibers may be in the form of long fibers or short fibers. Examples of the long fiber include tow, filament, and non-woven fabric. Examples of the short fiber include wet papermaking raw cotton, airlaid non-woven raw cotton, and card raw cotton.
本発明の繊維構造物は、上記機能材含有再生セルロース繊維を含む。上記繊維構造物としては、例えば、トウ、フィラメント、紡績糸、中綿(詰め綿)、紙、不織布及び織編物等が好ましい。上記繊維構造物は、機能材含有再生セルロース繊維を含むことにより、機能材に包含されている機能剤による性能を発現することができる。上記繊維構造物は、上記機能材含有再生セルロース繊維単独で構成されていてもよい。他の繊維と併用する場合は、上記機能材含有再生セルロース繊維を繊維構造物全体質量に対して10質量%以上含有させることが好ましく、20質量%以上で含有させることがより好ましく、30質量%以上で含有させることがさらに好ましい。上記繊維構造物における機能材含有再生セルロース繊維の含有量の上限は、特に限定されないが、90質量%以下であってもよく、80質量%以下であってもよく、70質量%以下であってもよい。また、上記繊維構造物は、繊維構造物全体質量に対して他の繊維を10〜90質量%含んでもよい。 The fiber structure of this invention contains the said functional material containing reproduction | regeneration cellulose fiber. As the fiber structure, for example, tow, filament, spun yarn, batting (padded cotton), paper, non-woven fabric, and woven / knitted fabric are preferable. The said fiber structure can express the performance by the functional agent included in the functional material by including the functional material containing regenerated cellulose fiber. The fiber structure may be composed of the functional material-containing regenerated cellulose fiber alone. When used in combination with other fibers, the functional material-containing regenerated cellulose fiber is preferably contained in an amount of 10% by mass or more, more preferably 20% by mass or more, and more preferably 30% by mass with respect to the total mass of the fiber structure. More preferably, it is contained above. The upper limit of the content of the functional material-containing regenerated cellulose fiber in the fiber structure is not particularly limited, but may be 90% by mass or less, 80% by mass or less, and 70% by mass or less. Also good. Moreover, the said fiber structure may contain 10-90 mass% of other fibers with respect to the fiber structure whole mass.
上記繊維構造物が紡績糸である場合、上記機能材含有再生セルロース繊維単独で構成してもよく、或いは、上記機能材含有再生セルロース繊維とその他の再生セルロース繊維、コットン、麻、ウール、アクリル繊維、ポリエステル繊維、ポリアミド繊維、ポリオレフィン繊維、ポリウレタン繊維等の他の繊維と混紡してもよい。このような紡績糸は、例えば織物や編物に加工されて衣料等に用いることができる。 When the fiber structure is a spun yarn, the functional material-containing regenerated cellulose fiber may be used alone, or the functional material-containing regenerated cellulose fiber and other regenerated cellulose fibers, cotton, hemp, wool, acrylic fiber , Polyester fibers, polyamide fibers, polyolefin fibers, polyurethane fibers, and other fibers may be blended. Such spun yarn can be processed into a woven fabric or a knitted fabric and used for clothing or the like.
上記繊維構造物が不織布である場合、上記機能材含有再生セルロース繊維単独で構成してもよく、或いは、上記機能材含有再生セルロース繊維とその他の再生セルロース繊維、コットン、麻、ウール、アクリル繊維、ポリエステル繊維、ポリアミド繊維、ポリオレフィン繊維、ポリウレタン繊維等の他の繊維と混綿して不織布にしてもよい。不織布の形態としては、例えば、湿式不織布(湿式抄紙)、エアレイド不織布、水流交絡不織布、ニードルパンチ不織布等が挙げられる。このような不織布は、例えば、ウェットティッシュ、対人・対物用ワイパー等のウェットシート、水解シート等に用いることができる。また、化粧パフ、吸収体等の衛生シートに用いることができる。 When the fiber structure is a non-woven fabric, the functional material-containing regenerated cellulose fiber may be constituted alone, or the functional material-containing regenerated cellulose fiber and other regenerated cellulose fibers, cotton, hemp, wool, acrylic fiber, A non-woven fabric may be blended with other fibers such as polyester fiber, polyamide fiber, polyolefin fiber and polyurethane fiber. Examples of the form of the nonwoven fabric include a wet nonwoven fabric (wet papermaking), an airlaid nonwoven fabric, a hydroentangled nonwoven fabric, and a needle punched nonwoven fabric. Such a nonwoven fabric can be used, for example, for wet tissues, wet sheets such as interpersonal / objective wipers, hydrolytic sheets, and the like. Moreover, it can be used for sanitary sheets such as cosmetic puffs and absorbent bodies.
以下、図面を用いて説明する。図1は本発明の一実施例における機能材含有再生セルロース繊維の断面を示すデジタルマイクロスコープ写真(倍率:1000倍)であり、図2は同機能材含有再生セルロース繊維の側面を示す光学顕微鏡写真(倍率:320倍)である。図1において、繊維断面における島部分は機能剤を基材中に包含した機能材である。図2において、黒い点が機能剤を基材中に包含した機能材である。図1及び図2から、機能材含有再生セルロース繊維において、機能剤を基材中に包含した機能材と、セルロースは非相溶状態であり、機能材がセルロース中に粒子状で微分散されていることがわかる。機能材含有再生セルロース繊維において、上記機能材はセルロース中に微分散していることが好ましい。機能材がセルロース中に微分散することで、機能剤が繊維内でより全体的に存在することができ、機能剤の効果を発揮しやすく、また、良好な繊維強度の繊維を得やすくなる。 Hereinafter, it demonstrates using drawing. FIG. 1 is a digital microscope photograph (magnification: 1000 times) showing a cross section of a functional material-containing regenerated cellulose fiber in one example of the present invention, and FIG. 2 is an optical micrograph showing a side surface of the functional material-containing regenerated cellulose fiber. (Magnification: 320 times). In FIG. 1, the island portion in the fiber cross section is a functional material including a functional agent in the base material. In FIG. 2, a black dot is a functional material in which the functional agent is included in the base material. From FIG. 1 and FIG. 2, in the functional material-containing regenerated cellulose fiber, the functional material containing the functional agent in the base material and the cellulose are in an incompatible state, and the functional material is finely dispersed in the form of particles in the cellulose. I understand that. In the functional material-containing regenerated cellulose fiber, the functional material is preferably finely dispersed in cellulose. When the functional material is finely dispersed in cellulose, the functional agent can be present in the fiber as a whole, so that the effect of the functional agent can be easily exerted, and fibers having good fiber strength can be easily obtained.
以下、実施例により本発明をさらに具体的に説明する。本発明は、下記の実施例に限定されるものではない。なお、下記の実施例で添加量を単に%と表記した場合は、質量%を意味する。 Hereinafter, the present invention will be described more specifically with reference to examples. The present invention is not limited to the following examples. In addition, when the addition amount is simply expressed as% in the following examples, it means mass%.
(実施例1)
[紡糸用ビスコースの調製]
下記表4に示す配合割合で溶融状態の蜜蝋(融点62℃)に木の精油成分からなる香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.45μmになるように調製した水分散液を、セルロース100質量部に対して機能材が15質量部となるように、原料ビスコースへ添加し、混合機にて攪拌混合を行い、紡糸用ビスコースを調製した。原料ビスコースとしては、セルロース8.5量%、水酸化ナトリウム5.7質量%、二硫化炭素2.8質量%を含むビスコースを用いた。
Example 1
[Preparation of viscose for spinning]
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, a mixture (functional material) prepared by mixing a beef wax (melting point 62 ° C.) in a molten state with a fragrance made of an essential oil component of wood at a blending ratio shown in Table 4 below. Then, the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.45 μm is added to the raw material viscose so that the functional material is 15 parts by mass with respect to 100 parts by mass of cellulose, and is added to the mixer. The mixture was stirred and mixed to prepare a viscose for spinning. As the raw material viscose, viscose containing 8.5% by mass of cellulose, 5.7% by mass of sodium hydroxide, and 2.8% by mass of carbon disulfide was used.
[紡糸条件]
得られた紡糸用ビスコースを、2浴緊張紡糸法により、紡糸速度50m/分、延伸率50%で紡糸した。第一浴(紡糸浴)は、硫酸115g/L、硫酸亜鉛15g/L、硫酸ナトリウム350g/L含むミューラー浴(50℃)を用いた。また、ビスコースを吐出する紡糸口金には、孔径0.06mmのホールを4000個有する円形ノズルを用いた。紡糸中、単糸切れ等の不都合は生じず、機能材の水分散液を混合した紡糸用ビスコースの紡糸性は良好であった。
[Spinning conditions]
The obtained viscose for spinning was spun at a spinning speed of 50 m / min and a draw ratio of 50% by a two-bath tension spinning method. As the first bath (spinning bath), a Mueller bath (50 ° C.) containing 115 g / L of sulfuric acid, 15 g / L of zinc sulfate, and 350 g / L of sodium sulfate was used. In addition, a circular nozzle having 4000 holes having a hole diameter of 0.06 mm was used as a spinneret for discharging viscose. During spinning, there was no inconvenience such as single yarn breakage, and the spinnability of the spinning viscose mixed with the aqueous dispersion of the functional material was good.
[精練条件]
上記で得られたレーヨン繊維を、繊維長38mmにカットし、精練処理を行った。精錬処理は、具体的には、下記のように行った。カットしたレーヨン繊維を熱水処理後に水洗を行い、その後圧縮ローラーで余分な水分を繊維から落とした後、水硫化ソーダにて処理し、水洗後、圧縮ローラーで水分を落とした。次いで、次亜塩素酸ソーダ、硫酸にて処理し、水洗、圧縮ローラーにて水分を落とし、油剤処理後、圧縮ローラーにて水分を落とした。その後、乾燥処理(60℃、7時間)を施して、表4に示す繊度の繊維Aを得た。
[Scouring conditions]
The rayon fiber obtained above was cut into a fiber length of 38 mm and scoured. Specifically, the refining process was performed as follows. The cut rayon fiber was washed with water after hot water treatment, and after removing excess moisture from the fiber with a compression roller, it was treated with sodium hydrosulfide, washed with water, and then dried with a compression roller. Subsequently, it processed with sodium hypochlorite and a sulfuric acid, water | moisture content was dropped with the water washing and the compression roller, and the water | moisture content was dropped with the compression roller after oil agent processing. Then, the drying process (60 degreeC, 7 hours) was performed, and the fiber A of the fineness shown in Table 4 was obtained.
(実施例2)
下記表4に示す配合割合で溶融状態の蜜蝋にジャスミン系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.30μmになるように調製した水分散液を、セルロース100質量部に対して機能材が2質量部となるように、原料ビスコースへ添加した以外は、実施例1と同様にして、表4に示す繊度の繊維Bを得た。
(Example 2)
A mixture (functional material) obtained by mixing a beeswax in a melted state with jasmine fragrance at a blending ratio shown in Table 4 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier, and the average particle diameter of the functional material is 0. Table 4 was prepared in the same manner as in Example 1 except that the aqueous dispersion prepared to be 30 μm was added to the raw material viscose so that the functional material was 2 parts by mass with respect to 100 parts by mass of cellulose. A fiber B having the fineness shown in FIG.
(実施例3)
下記表4に示す配合割合で溶融状態の蜜蝋にフローラルブーケ系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.49μmになるように調製した水分散液を用いた以外は、実施例2と同様にして、表4に示す繊度の繊維Cを得た。
Example 3
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, the mixture (functional material) in which a floral bouquet-based fragrance is mixed with molten beeswax in the blending ratio shown in Table 4 below, the average particle diameter of the functional material is A fiber C having the fineness shown in Table 4 was obtained in the same manner as in Example 2 except that the aqueous dispersion prepared to 0.49 μm was used.
(実施例4)
下記表4に示す配合割合で溶融状態の蜜蝋にフローラルブーケ系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.49μmになるように調製した水分散液を、セルロース100質量部に対して機能材が4質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表4に示す繊度の繊維Dを得た。
Example 4
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, the mixture (functional material) in which a floral bouquet-based fragrance is mixed with molten beeswax in the blending ratio shown in Table 4 below, the average particle diameter of the functional material is Table 1 was prepared in the same manner as in Example 2 except that the aqueous dispersion prepared to 0.49 μm was added to the raw material viscose so that the functional material was 4 parts by mass with respect to 100 parts by mass of cellulose. A fiber D having the fineness shown in 4 was obtained.
(実施例5)
下記表4に示す配合割合で溶融状態の蜜蝋にホワイトフローラル系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.59μmになるように調製した水分散液を用いた以外は、実施例2と同様にして、表4に示す繊度の繊維Eを得た。
(Example 5)
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, a mixture (functional material) in which white floral fragrance is mixed with beeswax in a molten state at a blending ratio shown in Table 4 below, the average particle size of the functional material is A fiber E having the fineness shown in Table 4 was obtained in the same manner as in Example 2 except that the aqueous dispersion prepared to be 0.59 μm was used.
(実施例6)
下記表4に示す配合割合で溶融状態の蜜蝋にフローラルブーケ系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.48μmになるように調製した水分散液を用いた以外は、実施例2と同様にして、表4に示す繊度の繊維Fを得た。
(Example 6)
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, the mixture (functional material) in which a floral bouquet-based fragrance is mixed with molten beeswax in the blending ratio shown in Table 4 below, the average particle diameter of the functional material is A fiber F having the fineness shown in Table 4 was obtained in the same manner as in Example 2 except that the aqueous dispersion prepared to 0.48 μm was used.
(実施例7)
下記表4に示す配合割合で溶融状態の蜜蝋にジャスミン系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.11μmになるように調製した水分散液を用いた以外は、実施例2と同様にして、表4に示す繊度の繊維Gを得た。
(Example 7)
A mixture (functional material) obtained by mixing a beeswax in a melted state with jasmine fragrance at a blending ratio shown in Table 4 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier, and the average particle diameter of the functional material is 0. A fiber G having the fineness shown in Table 4 was obtained in the same manner as in Example 2 except that the aqueous dispersion prepared to be 11 μm was used.
(実施例8)
下記表4に示す配合割合で溶融状態の蜜蝋にジャスミン系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.56μmになるように調製した水分散液を用いた以外は、実施例2と同様にして、表4に示す繊度の繊維Hを得た。
(Example 8)
A mixture (functional material) obtained by mixing a beeswax in a melted state with jasmine fragrance at a blending ratio shown in Table 4 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier, and the average particle diameter of the functional material is 0. A fiber H having the fineness shown in Table 4 was obtained in the same manner as in Example 2 except that the aqueous dispersion prepared to be .56 μm was used.
(実施例9)
下記表4に示す配合割合で溶融状態のカルナバ蝋(融点83℃)にフローラルブーケ系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.43μmになるように調製した水分散液を、セルロース100質量部に対して機能材が1.2質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表4に示す繊度の繊維Xを得た。
Example 9
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, a mixture (functional material) obtained by mixing a floral bouquet-based fragrance with a melted carnauba wax (melting point 83 ° C.) at a blending ratio shown in Table 4 below. Implementation was performed except that the aqueous dispersion prepared so that the average particle size of the material was 0.43 μm was added to the raw material viscose so that the functional material was 1.2 parts by mass with respect to 100 parts by mass of the cellulose. In the same manner as in Example 2, fibers X having the fineness shown in Table 4 were obtained.
(実施例10)
下記表4に示す配合割合で溶融状態の木蝋(融点49℃)にフローラルブーケ系香料を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.19μmになるように調製した水分散液を、セルロース100質量部に対して機能材が1.2質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表4に示す繊度の繊維Yを得た。
(Example 10)
A functional material obtained by emulsifying and dispersing in water using a nonionic surfactant as a emulsifier a mixture (functional material) obtained by mixing a floral bouquet-based fragrance with molten wax (melting point: 49 ° C.) in the blending ratio shown in Table 4 below. The aqueous dispersion prepared to have an average particle size of 0.19 μm was added to the raw material viscose so that the functional material was 1.2 parts by mass with respect to 100 parts by mass of cellulose. In the same manner as in No. 2, fibers Y having the fineness shown in Table 4 were obtained.
(実施例11)
下記表4に示す配合割合で溶融状態の密蝋にリモネン(抗菌剤として用いた)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.32μmになるように調製した水分散液を、セルロース100質量部に対して機能材が0.8質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表4に示す繊度の繊維Vを得た。
(Example 11)
A functional material obtained by emulsifying and dispersing in water using a nonionic surfactant as an emulsifier, a mixture (functional material) obtained by mixing limonene (used as an antibacterial agent) with molten wax at the blending ratio shown in Table 4 below. Example 1 except that the aqueous dispersion prepared so that the average particle diameter of the material was 0.32 μm was added to the raw material viscose so that the functional material was 0.8 parts by mass with respect to 100 parts by mass of cellulose. In the same manner as in No. 2, fibers V having the fineness shown in Table 4 were obtained.
(実施例12)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸エチル)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.39μmになるように調製した水分散液を、セルロース100質量部に対して機能材が12.9質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表6に示す繊度の繊維Pを得た。
(Example 12)
The mixture (functional material) obtained by mixing a repellent (active ingredient: ethyl cinnamate) with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. Except for adding the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.39 μm to the raw material viscose so that the functional material is 12.9 parts by mass with respect to 100 parts by mass of cellulose, In the same manner as in Example 2, fibers P having the fineness shown in Table 6 were obtained.
(実施例13)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸メチル)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.45μmになるように調製した水分散液を用いた以外は、実施例12と同様にして、表6に示す繊度の繊維Qを得た。
(Example 13)
Emulsified and dispersed in water using a nonionic surfactant as an emulsifier, a mixture (functional material) obtained by mixing a repellent (active ingredient: methyl cinnamate) with beeswax in a molten state at a blending ratio shown in Table 6 below, A fiber Q having the fineness shown in Table 6 was obtained in the same manner as in Example 12 except that the aqueous dispersion prepared so that the average particle size of the functional material was 0.45 μm was used.
(実施例14)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:シンナミルアセテート)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.11μmになるように調製した水分散液を、セルロース100質量部に対して機能材が12.5質量部となるように、原料ビスコースへ添加した以外は、実施例12と同様にして、表6に示す繊度の繊維Rを得た。
(Example 14)
The mixture (functional material) obtained by mixing a repellent (active ingredient: cinnamyl acetate) with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier, and functions. Implementation was performed except that the aqueous dispersion prepared so that the average particle size of the material was 0.11 μm was added to the raw material viscose so that the functional material was 12.5 parts by mass with respect to 100 parts by mass of cellulose. In the same manner as in Example 12, fibers R having the fineness shown in Table 6 were obtained.
(実施例15)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸誘導体)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.84μmになるように調製した水分散液を、セルロース100質量部に対して機能材が6.5質量部となるように、原料ビスコースへ添加した以外は、実施例12と同様にして、表6に示す繊度の繊維Sを得た。
(Example 15)
A mixture (functional material) in which a repellent (active ingredient: cinnamic acid derivative) is mixed with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. Except for adding the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.84 μm to the raw material viscose so that the functional material is 6.5 parts by mass with respect to 100 parts by mass of cellulose, In the same manner as in Example 12, fibers S having the fineness shown in Table 6 were obtained.
(実施例16)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸誘導体)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.28μmになるように調製した水分散液を、セルロース100質量部に対して機能材が6.5質量部となるように、原料ビスコースへ添加した以外は、実施例12と同様にして、表6に示す繊度の繊維Tを得た。
(Example 16)
A mixture (functional material) in which a repellent (active ingredient: cinnamic acid derivative) is mixed with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. Except for adding the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.28 μm to the raw material viscose so that the functional material is 6.5 parts by mass with respect to 100 parts by mass of cellulose, In the same manner as in Example 12, fibers T having the fineness shown in Table 6 were obtained.
(実施例17)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸誘導体)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.28μmになるように調製した水分散液を、セルロース100質量部に対して機能材が3.5質量部となるように、原料ビスコースへ添加した以外は、実施例12と同様にして、表6に示す繊度の繊維Uを得た。
(Example 17)
A mixture (functional material) in which a repellent (active ingredient: cinnamic acid derivative) is mixed with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. Except for adding the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.28 μm to the raw material viscose so that the functional material is 3.5 parts by mass with respect to 100 parts by mass of cellulose, In the same manner as in Example 12, fibers U having the fineness shown in Table 6 were obtained.
(実施例18)
下記表6に示す配合割合で溶融状態の蜜蝋に忌避剤(有効成分:ケイ皮酸誘導体)を混合した混合物(機能材)を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、機能材の平均粒子径が0.28μmになるように調製した水分散液を、セルロース100質量部に対して機能材が5.0質量部となるように、原料ビスコースへ添加した以外は、実施例12と同様にして、表6に示す繊度の繊維Wを得た。
(Example 18)
A mixture (functional material) in which a repellent (active ingredient: cinnamic acid derivative) is mixed with beeswax in a molten state at a blending ratio shown in Table 6 below is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. Except for adding the aqueous dispersion prepared so that the average particle diameter of the functional material is 0.28 μm to the raw material viscose so that the functional material is 5.0 parts by mass with respect to 100 parts by mass of cellulose, In the same manner as in Example 12, fibers W having the fineness shown in Table 6 were obtained.
(比較例1)
蜜蝋を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、蜜蝋の平均粒子径が0.40μmになるように調製した水分散液を、セルロース100質量部に対して蜜蝋が2質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表5に示す繊度の繊維Iを得た。
(Comparative Example 1)
An aqueous dispersion prepared by emulsifying and dispersing beeswax in water using a nonionic surfactant as an emulsifier to have an average particle size of beeswax of 0.40 μm was obtained by adding 2 parts of beeswax to 100 parts by weight of cellulose. A fiber I having the fineness shown in Table 5 was obtained in the same manner as in Example 2 except that it was added to the raw material viscose.
(比較例2)
下記表5に示す配合割合で溶融状態のオレフィン系炭化水素(融点35℃)にジャスミン系香料を混合した混合物を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、混合物の平均粒子径が0.50μmになるように調製した水分散液を、セルロース100質量部に対して混合物が2質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表5に示す繊度の繊維Jを得た。
(Comparative Example 2)
The average particle size of the mixture is emulsified and dispersed in water using a nonionic surfactant as an emulsifier with a mixture obtained by mixing a jasmine fragrance with a molten olefinic hydrocarbon (melting point 35 ° C.) at a blending ratio shown in Table 5 below. Except that the aqueous dispersion prepared to have a diameter of 0.50 μm was added to the raw material viscose so that the mixture was 2 parts by mass with respect to 100 parts by mass of cellulose, the same as in Example 2, Fiber J having the fineness shown in Table 5 was obtained.
(比較例3)
下記表5に示す配合割合で溶融状態のノルマルパラフィン(融点30℃)にジャスミン系香料を混合した混合物を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、混合物の平均粒子径が0.59μmになるように調製した水分散液を、セルロース100質量部に対して混合物が2質量部となるように、原料ビスコースへ添加した以外は、実施例2と同様にして、表5に示す繊度の繊維Kを得た。
(Comparative Example 3)
An average particle size of the mixture is obtained by emulsifying and dispersing in water using a nonionic surfactant as an emulsifier, a mixture obtained by mixing jasmine fragrance with molten normal paraffin (melting point: 30 ° C.) at a blending ratio shown in Table 5 below. Table 5 shows the same procedure as in Example 2 except that the aqueous dispersion prepared to 0.59 μm was added to the raw material viscose so that the mixture was 2 parts by mass with respect to 100 parts by mass of cellulose. A fiber K having the fineness shown in FIG.
(比較例4)
下記表5に示す配合割合でヒマワリ油と桜系香料を混合し、得られた混合物を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、混合物の平均粒子径が0.35μmになるように調製した水分散液を、セルロース100質量部に対して混合物が2質量部となるように、原料ビスコースへ添加し、水流化ソーダによる処理及び次亜塩素酸ソーダによる処理を行わなかった以外は、実施例2と同様にして、表5に示す繊度の繊維Lを得た。
(Comparative Example 4)
Sunflower oil and cherry perfume are mixed at the blending ratio shown in Table 5 below, and the resulting mixture is emulsified and dispersed in water using a nonionic surfactant as an emulsifier, so that the average particle size of the mixture is 0.35 μm. The aqueous dispersion prepared as described above is added to the raw material viscose so that the mixture becomes 2 parts by mass with respect to 100 parts by mass of cellulose, and the treatment with hydrous soda and the treatment with sodium hypochlorite are not performed. Except for the above, a fiber L having the fineness shown in Table 5 was obtained in the same manner as in Example 2.
(比較例5)
下記表5に示す配合割合でヒマワリ油と木の精油成分からなる香料を混合し、得られた混合物を乳化剤としてノニオン系界面活性剤を用いて水に乳化分散して、混合物の平均粒子径が0.48μmになるように調製した水分散液を、セルロース100質量部に対して混合物が2質量部となるように、原料ビスコースへ添加し、水流化ソーダによる処理及び次亜塩素酸ソーダによる処理を行わなかった以外は、実施例1と同様にして、表5に示す繊度の繊維Mを得た。
(Comparative Example 5)
The blending ratio shown in Table 5 below is used to mix a fragrance comprising sunflower oil and a wood essential oil component, and the resulting mixture is emulsified and dispersed in water using a nonionic surfactant as an emulsifier. The aqueous dispersion prepared to 0.48 μm is added to the raw material viscose so that the mixture becomes 2 parts by mass with respect to 100 parts by mass of the cellulose, treatment with hydrous soda and sodium hypochlorite A fiber M having the fineness shown in Table 5 was obtained in the same manner as in Example 1 except that the treatment was not performed.
(参考例1)
原料ビスコースをそのまま紡糸用ビスコースとして用いた以外は、実施例2と同様にして、表5に示す繊度の繊維Zを得た。
(Reference Example 1)
A fiber Z having the fineness shown in Table 5 was obtained in the same manner as in Example 2 except that the raw material viscose was used as it was as the viscose for spinning.
実施例及び比較例において、水分散液における機能剤と基材の混合物の平均粒子径は、下記のように測定した。 In Examples and Comparative Examples, the average particle size of the mixture of the functional agent and the substrate in the aqueous dispersion was measured as follows.
<平均粒子径>
島津製作所製「島津ナノ粒子径分布測定装置 SALD−7500nano」を使用し、レーザー回折光散乱法により、50%粒子径(D50)を測定し、平均粒子径とした。
<Average particle size>
A 50% particle diameter (D50) was measured by a laser diffraction light scattering method using a Shimadzu “Shimadzu nanoparticle size distribution analyzer SALD-7500 nano”, and the average particle diameter was determined.
実施例1〜18、比較例1〜5及び参考例1のレーヨン繊維の物性を下記のように測定し、その結果を下記表4〜6に示した。また、実施例1及び比較例5のレーヨン繊維の白度を下記のように測定評価し、その結果を下記表4及び5に示した。表4〜6には、基材と機能剤の混合物の水分散液における基材及び機能剤の含有率、及び基材100質量部に対する機能剤の配合量も示した。また、表4〜6には、紡糸用ビスコース液において、セルロース100質量部に対する機能材及び機能剤の添加量をそれぞれ示した。なお、上記実施例及び比較例で用いた香料及び忌避剤は、全て水不溶性で揮発性物質であった。 The physical properties of the rayon fibers of Examples 1 to 18, Comparative Examples 1 to 5 and Reference Example 1 were measured as follows, and the results are shown in Tables 4 to 6 below. The whiteness of the rayon fibers of Example 1 and Comparative Example 5 was measured and evaluated as follows, and the results are shown in Tables 4 and 5 below. Tables 4 to 6 also show the content ratio of the base material and the functional agent in the aqueous dispersion of the mixture of the base material and the functional agent, and the blending amount of the functional agent with respect to 100 parts by mass of the base material. Tables 4 to 6 show the amounts of the functional material and the functional agent added to 100 parts by mass of cellulose in the spinning viscose liquid, respectively. In addition, the fragrance | flavor and repellent used in the said Example and comparative example were all water-insoluble and volatile substances.
<繊維物性>
繊度及び乾湿強伸度の測定はJIS L 1015に準じた試験で行った。
<Fiber physical properties>
The fineness and the wet and dry strength were measured by a test according to JIS L 1015.
<繊維の色>
繊維の色は、JIS Z 8722にて定義されている拡散照明垂直受光方式に準拠した日本電色製「SPECTROPHOTOMETER NF333」を用いて、JIS Z 8729に規定されている「L*a*b*表色系」に従って測定した。また、ハンター白色度は、L*、a*及びb*値に基づいて、下記式を用いて算出した。
ハンター白色度=100−√〔(100−L*)+(a*2+b*2)〕
<Fiber color>
The color of the fiber is “L * a * b * table” defined in JIS Z 8729 using “SPECTROTOPOMETER NF333” manufactured by Nippon Denshoku, which conforms to the diffuse illumination vertical light receiving method defined in JIS Z 8722. Measured according to “color system”. Hunter whiteness was calculated using the following formula based on L * , a * and b * values.
Hunter whiteness = 100-√ [(100-L * ) + (a * 2 + b * 2 )]
<繊維中の機能材の平均粒子径>
(1)繊維を下記のように脱油処理した。
(I)試料約2.3gを精秤し、底部に小さい穴の空いた試料管に詰めた。
(II)底部の穴を塞ぎ、抽出溶媒としてメタノール10mlを試料管に注加し、一定時間静置し浸透させてからプレス装置によりメタノール処理液を抽出した。
(III)同じ試料を使用して上記の操作(II)による抽出を20回繰り返した後、試料管から取り出した試料を水洗し、定温乾燥機(アズワン製、型番「DO−450FA」)を用いて105℃、2時間で乾燥して脱油処理後の繊維を得た。
(2)脱油処理後の繊維を用いて機能材の平均粒子径を測定した。
脱油処理後の繊維の断面写真(走査型電子顕微鏡写真、倍率3000倍)を画像処理により倍率9010倍に拡大し、印刷した紙面上から任意の繊維の断面をサンプリングし、その繊維断面における繊維の外周から3μm内部までの間に存在する空隙部の直径を計測し、計測した100個の空隙部の直径を平均して空隙部の平均孔径を算出し、機能材の平均粒子径とした。なお、楕円状の空隙部は長径及び短径を計測して算出した面積から真円直径に換算し、空隙部の直径とした。なお、走査型電子顕微鏡としては、日立製作所製「S−2500N」を用いた。
<Average particle diameter of functional material in fiber>
(1) The fiber was deoiled as follows.
(I) About 2.3 g of a sample was precisely weighed and packed in a sample tube having a small hole at the bottom.
(II) The bottom hole was closed, 10 ml of methanol was poured into the sample tube as an extraction solvent, allowed to stand for a certain period of time and permeated, and then the methanol treatment liquid was extracted with a press device.
(III) Using the same sample, the extraction by the above operation (II) was repeated 20 times, and then the sample taken out from the sample tube was washed with water and using a constant temperature dryer (manufactured by ASONE, model number “DO-450FA”). And dried at 105 ° C. for 2 hours to obtain a fiber after deoiling treatment.
(2) The average particle diameter of the functional material was measured using the fiber after the deoiling treatment.
The cross-sectional photograph of the fiber after deoiling treatment (scanning electron micrograph, magnification 3000 times) is enlarged to 9010 times by image processing, and the cross section of an arbitrary fiber is sampled from the printed paper, and the fiber in the fiber cross section The diameters of the voids existing between the outer periphery of the particles and the inside of 3 μm were measured, and the average diameters of the 100 voids measured were averaged to calculate the average pore diameter of the voids. In addition, the elliptical void portion was converted into a perfect circle diameter from the area calculated by measuring the major axis and the minor axis, and was defined as the diameter of the void portion. Note that “S-2500N” manufactured by Hitachi, Ltd. was used as the scanning electron microscope.
実施例1〜10及び比較例2〜5のレーヨン繊維の残香性を下記のように評価し、その結果を下記表4及び5に示した。また、実施例1〜6、比較例4及び5のレーヨン繊維を下記のようにアルカリ処理し、アルカリ処理後の残香性を下記のように評価し、その結果を下記表4及び5に示した。また、実施例4のレーヨン繊維を下記のように経時促進処理し、経時促進処理後の残香性を下記のように評価し、その結果を下記表4に示した。なお、下記表4及び5において、「−」は、測定を行っていないことを意味する。 The afterglow properties of the rayon fibers of Examples 1 to 10 and Comparative Examples 2 to 5 were evaluated as follows, and the results are shown in Tables 4 and 5 below. Moreover, the rayon fibers of Examples 1 to 6 and Comparative Examples 4 and 5 were subjected to alkali treatment as described below, and the residual fragrance after the alkali treatment was evaluated as follows. The results are shown in Tables 4 and 5 below. . Further, the rayon fiber of Example 4 was subjected to aging promotion treatment as described below, and the residual fragrance after the aging promotion treatment was evaluated as follows. The results are shown in Table 4 below. In Tables 4 and 5 below, “−” means that no measurement was performed.
<残香性>
モニター4名にまず対象のレーヨン繊維に使用した機能材の水分散液の香りを嗅いでもらい香料の臭いを確認し、次に参考例1のレーヨン繊維(繊維Z)の香りを嗅いでもらいレーヨン臭を確認させた後、対象のレーヨン繊維にレーヨン臭とは明らかに異なる残香性があれば、その程度を、下記の5段階で評価した。なお、体温と似たような条件での残香性を確認するため、ぬるま湯(36℃)で濡らしたレーヨン繊維を測定サンプルとした。下記表4及び5には、4名のモニターの評価の平均値を示した。
5:明らかに香りがわかる
4:香りがわかる
3:やや香りがする
2:ごくわずかに香りがわかる
1:香りがわからない
<Rescent>
Firstly, four monitors were allowed to smell the scent of the water dispersion of the functional material used in the target rayon fiber, and then the smell of the fragrance was checked, and then the rayon fiber (fiber Z) of Reference Example 1 was smelled. After confirming the odor, if the target rayon fiber had a residual fragrance that was clearly different from the rayon odor, the degree was evaluated in the following five stages. In addition, in order to confirm the residual fragrance property on the conditions similar to body temperature, the rayon fiber wetted with lukewarm water (36 degreeC) was made into the measurement sample. Tables 4 and 5 below show the average values of the evaluation of four monitors.
5: Clearly scented 4: Scented scented 3: Slightly scented 2: Slightly scented 1: Scented not understood
<アルカリ処理後の残香性>
レーヨン繊維を炭酸ソーダ3質量%の水浴(60℃)で120分間処理後、pH3〜5の酢酸浴で処理し、その後水洗し、乾燥させた。次いで、アルカリ後の処理後のレーヨン繊維の残香性を上述したとおりに評価した。
<Afterglow after alkali treatment>
The rayon fiber was treated with a 3% by weight sodium carbonate water bath (60 ° C.) for 120 minutes, then with a pH 3 to 5 acetic acid bath, then washed with water and dried. Subsequently, the residual fragrance property of the rayon fiber after the alkali treatment was evaluated as described above.
<経時促進処理後の残香性>
レーヨン繊維を、定温乾燥機(アズワン製、型番「DO−450FA」)を用いて温度が70℃の環境に20日間放置した。次いで、経時促進処理後のレーヨン繊維の残香性を上述したとおりに評価した。
<Remaining fragrance after aging acceleration treatment>
The rayon fiber was allowed to stand in an environment having a temperature of 70 ° C. for 20 days using a constant temperature dryer (manufactured by ASONE, model number “DO-450FA”). Subsequently, the residual fragrance property of the rayon fiber after an aging promotion process was evaluated as mentioned above.
また、実施例4の繊維Dを用いて下記のように作製した水流交絡不織布の残香性を上記のように測定し、その結果を下記表4に示した。また、実施例4の繊維Dを用いて下記のように作製した水流交絡不織布の残香性を上記のように測定し、その結果を下記表4に示した。 Moreover, the residual fragrance property of the hydroentangled nonwoven fabric produced as described below using the fiber D of Example 4 was measured as described above, and the results are shown in Table 4 below. Moreover, the residual fragrance property of the hydroentangled nonwoven fabric produced as described below using the fiber D of Example 4 was measured as described above, and the results are shown in Table 4 below.
<水流交絡不織布の製造例1>
アクリル繊維(東レ製「シルウォーム」、繊度1.1dtex、繊維長38mm)65質量%と、上記で得られた実施例4(繊維D)を35質量%混綿し、カードウェブを作製した。次に、カードウェブの片面に対して、孔径0.13mmφ、孔ピッチ1mm間隔で配列されたノズルから3MPaの水圧で柱状水流を噴射し、再度同じ面に対して5MPaの水圧で柱状水流を噴射し、裏返して5MPaの水圧で柱状水流を噴射して、目付が130g/m2の水流交絡不織布(レーヨン繊維35質量%の混綿不織布)を作製した。
<Production example 1 of hydroentangled nonwoven fabric>
A card web was prepared by mixing 65% by mass of acrylic fiber (“Sylwarm” manufactured by Toray, fineness 1.1 dtex, fiber length 38 mm) and 35% by mass of Example 4 (fiber D) obtained above. Next, a columnar water flow is injected at a water pressure of 3 MPa from a nozzle arranged at a hole diameter of 0.13 mmφ and a hole pitch of 1 mm on one side of the card web, and a columnar water flow is injected again at a water pressure of 5 MPa on the same surface. Then, it was turned over and a columnar water stream was jetted at a water pressure of 5 MPa to produce a hydroentangled nonwoven fabric (mixed cotton nonwoven fabric with 35% by weight of rayon fibers) having a basis weight of 130 g / m 2 .
<水流交絡不織布の製造例2>
実施例4で得られた繊維Dについて、上述したようにアルカリ処理を実施し、得られたアルカリ処理後の繊維D35質量%とアクリル繊維(東レ製「シルウォーム」、繊度1.1dtex、繊維長38mm)65質量%を混綿した以外は、上述した水流交絡不織布の製造例1と同様にして混綿不織布(目付:130g/m2)を作製した。
<Production example 2 of hydroentangled nonwoven fabric>
The fiber D obtained in Example 4 was subjected to alkali treatment as described above, and 35% by mass of the obtained fiber D after alkali treatment and acrylic fiber (“Sylworm” manufactured by Toray, fineness 1.1 dtex, fiber length 38 mm) A mixed cotton nonwoven fabric (weight per unit: 130 g / m 2 ) was prepared in the same manner as in Production Example 1 of the hydroentangled nonwoven fabric described above except that 65% by mass was mixed.
実施例12〜18のレーヨン繊維を用いて上述した水流交絡不織布の製造例1と同様にしてレーヨン繊維100質量%の水流交絡不織布(目付:45g/m2)を作製し、下記のように蚊に対する防蚊試験で防蚊性能を評価し、その結果を下記表6に示した。また、実施例15〜17のレーヨン繊維を用いて上述した水流交絡不織布の製造例1と同様にして作製したレーヨン繊維100質量%の水流交絡不織布を下記のようにアルカリ処理し、アルカリ処理後の防蚊性能を下記のように評価し、その結果を下記表6に示した。また、実施例18のレーヨン繊維を、上述したとおりに経時促進処理した後、上述した水流交絡不織布の製造例1と同様にして作製したレーヨン繊維100質量%の水流交絡不織布を用い、経時促進処理後の防蚊性能を下記のように評価し、その結果を下記表6に示した。nは2とし、下記表6には平均値を示した。なお、下記表6において、「−」は、測定を行っていないことを意味する。 A hydroentangled non-woven fabric (weight per unit area: 45 g / m 2 ) of rayon fiber 100% by mass was produced using the rayon fibers of Examples 12 to 18 in the same manner as in Production Example 1 of hydroentangled non-woven fabric described above. The anti-mosquito performance was evaluated in a mosquito-proof test against the above, and the results are shown in Table 6 below. Moreover, the hydroentangled nonwoven fabric of 100 mass% rayon fiber produced using the rayon fibers of Examples 15 to 17 in the same manner as in Production Example 1 of the hydroentangled nonwoven fabric described above was alkali-treated as described below, and subjected to alkali treatment. The anti-mosquito performance was evaluated as follows, and the results are shown in Table 6 below. In addition, the rayon fiber of Example 18 was subjected to a aging promotion treatment as described above, and then a 100% by mass hydroentangled nonwoven fabric produced in the same manner as in Production Example 1 of the hydroentangled nonwoven fabric described above was used to accelerate the aging treatment. The later mosquito performance was evaluated as follows, and the results are shown in Table 6 below. n is 2, and the average value is shown in Table 6 below. In Table 6 below, “−” means that no measurement was performed.
<防蚊試験>
密閉した空間に成虫した雌蚊(交尾後のもの)を放ち、その空間に、比較対象の試験サンプルの水流交絡不織布を巻いた腕を入れて蚊が何匹止まったか(静止数)を数え、その数をN1とした。また、上記蚊を放った空間に、対象の試験サンプルの水流交絡不織布を巻いた腕を入れて蚊が何匹止まったか(静止数)を数え、その数をN2とし、下記式により忌避率を算出した。比較対象として、参考例1のレーヨン繊維を用いた。
忌避率(%)=(N1−N2)/N1×100
<Mosquito protection test>
Release adult female mosquitoes (after mating) in a sealed space, put arms wrapped with hydroentangled nonwoven fabric of the test sample to be compared in that space, and count how many mosquitoes stopped (number of stationary), The number was N1. Also, put the arm wrapped with the hydroentangled nonwoven fabric of the target test sample in the space where the mosquito was released, count how many mosquitoes stopped (the number of stationary), and let N2 be the repelling rate by the following formula Calculated. For comparison, the rayon fiber of Reference Example 1 was used.
Repelling rate (%) = (N1-N2) / N1 × 100
<アルカリ処理>
レーヨン繊維100質量%の水流交絡不織布を炭酸ソーダ3質量%の水浴(60℃)で120分間処理後、pH3〜5の酢酸浴で処理し、その後水洗・乾燥させた。アルカリ後の処理後の水流交絡不織布の防蚊性を上述したとおりに評価した。
<Alkali treatment>
The hydroentangled nonwoven fabric of 100% by weight of rayon fiber was treated with a 3% by weight sodium carbonate water bath (60 ° C.) for 120 minutes, then with a pH 3-5 acetic acid bath, and then washed and dried. The anti-mosquito properties of the hydroentangled nonwoven fabric after the alkali treatment were evaluated as described above.
(参考例2〜4)
下記表7に示す基材10.0gを瓶に入れ、80℃に設定した定温乾燥機(アズワン社製、型番「DO−450FA」)にて溶融させ、溶融後、すぐさまフローラルブーケ系香料0.10gと混合した後、蓋を閉めて室温(15℃)に静置して固化させた。固化直後の混合物、及び固化した後蓋を解放し20日経過後の混合物の香気強度を下記のように評価した。その結果を下記表7に示した。
(Reference Examples 2 to 4)
10.0 g of the base material shown in Table 7 below is put in a bottle and melted in a constant temperature dryer set to 80 ° C. (manufactured by ASONE, model number “DO-450FA”). After mixing with 10 g, the lid was closed and allowed to stand at room temperature (15 ° C.) to solidify. The fragrance intensity of the mixture immediately after solidification and the mixture after solidification was released and 20 days passed were evaluated as follows. The results are shown in Table 7 below.
<混合物の残香性>
モニター4名に混合物の香りを嗅いでもらい、その強さを5段階で評価した。
5:強く香る
4:やや強く香る
3:香りがわかる
2:わずかに香りがわかる
1:香りがわからない
<Rescent of mixture>
Four monitors were allowed to smell the mixture, and the strength was evaluated in five levels.
5: Strongly scented 4: Slightly scented 3: Scented 2: Slightly scented 1: Unrecognizable scented
機能材含有再生セルロース繊維における機能剤の保持率を下記のようなモデル試験で確認した。 The retention rate of the functional agent in the functional material-containing regenerated cellulose fiber was confirmed by the following model test.
実験1:各種基材を用いた場合のフローラル系香料の保持率の経時変化
基材8.0gとホワイトフローラル系香料2gを試料瓶に入れ密栓し、80℃に設定した定温乾燥機(アズワン社製、型番「DO−300FA」)にて溶融(カルナバ蝋のみ90℃で溶融)させ、室温(20℃)に戻した後、開栓状態で40℃下(定温乾燥機アズワン社製、型番「DO−300FA」)に放置し、所定時間経過後ごとの試料瓶の質量を測定して、機能剤(ホワイトフローラル系香料)の質量を算出した。その後、機能剤の初期質量及び所定時間経過後の機能剤の質量に基づいて、下記式によって機能剤の保持率(質量%)を算出した。その結果を下記表8及び図3に示した。
機能剤の保持率(質量%)=(所定時間経過後の機能剤の質量/機能剤の初期質量)×100
Experiment 1: Temporal change in retention rate of floral fragrance when using various base materials 8.0 g of base material and 2 g of white floral fragrance were placed in a sample bottle, sealed tightly, and a constant temperature dryer set at 80 ° C. (As One Corporation) Made by model No. “DO-300FA”) (only carnauba wax melted at 90 ° C.), returned to room temperature (20 ° C.), and then opened at 40 ° C. (manufactured by constant temperature dryer ASONE, model no. “ The mass of the functional agent (white floral fragrance) was calculated by measuring the mass of the sample bottle after a predetermined period of time. Thereafter, based on the initial mass of the functional agent and the mass of the functional agent after a predetermined time, the retention rate (mass%) of the functional agent was calculated by the following formula. The results are shown in Table 8 below and FIG.
Retention rate of functional agent (mass%) = (mass of functional agent after elapse of predetermined time / initial mass of functional agent) × 100
実験2:各種基材を用いた場合のリモネンの保持率の経時変化
基材8.0gとリモネン2gを試料瓶に入れ密栓し、80℃に設定した定温乾燥機(アズワン社製、型番「DO−300FA」)にて溶融させ、室温(20℃)に戻した後、開栓状態で40℃下(定温乾燥機アズワン社製、型番「DO−300FA」)に放置し、所定時間経過後ごとの試料瓶の質量を測定して、機能剤(リモネン)の質量を算出した。その後、機能剤の初期質量及び所定時間経過後の機能剤の質量に基づいて、下記式によって機能剤の保持率(質量%)を算出した。その結果を下記表9及び図4に示した。
機能剤の保持率(質量%)=(所定時間経過後の機能剤の質量/機能剤の初期質量)×100
Experiment 2: Temporal change in retention rate of limonene when using various base materials 8.0 g of base material and 2 g of limonene were put in a sample bottle and sealed tightly, and a constant temperature dryer set at 80 ° C. (manufactured by ASONE, model number “DO” -300FA "), returned to room temperature (20 ° C), left in an open state at 40 ° C (manufactured by Constant Temperature Dryer ASONE, model number" DO-300FA "), and after a predetermined time The mass of the sample bottle was measured, and the mass of the functional agent (limonene) was calculated. Thereafter, based on the initial mass of the functional agent and the mass of the functional agent after a predetermined time, the retention rate (mass%) of the functional agent was calculated by the following formula. The results are shown in Table 9 below and FIG.
Retention rate of functional agent (mass%) = (mass of functional agent after elapse of predetermined time / initial mass of functional agent) × 100
試験3:蜜蝋を用いた場合のホワイトフローラル系香料の保持率の経時変化
下記表10に示す質量の基材とホワイトフローラル系香料を試料瓶に入れ密栓し、80℃に設定した定温乾燥機(アズワン社製、型番「DO−300FA」)にて溶融させ、室温(20℃)に戻した後、開栓状態で40℃下(アズワン社製定温乾燥機、型番「DO−300FA」)に放置し、所定時間経過後ごとの試料瓶の質量を測定して、機能剤(ホワイトフローラル系香料)の質量を算出した。その後、機能剤の初期質量及び所定時間経過後の機能剤の質量に基づいて、下記式によって機能剤の保持率(質量%)を算出した。その結果を下記表10及び図5に示した。
機能剤の保持率(質量%)=(所定時間経過後の機能剤の質量/機能剤の初期質量)×100
Test 3: Temporal change in retention ratio of white floral fragrance when beeswax was used A constant temperature dryer (80 ° C.) with a base material and white floral fragrance having the mass shown in Table 10 below put in a sample bottle and sealed. After melting with ASONE, model number “DO-300FA” and returning to room temperature (20 ° C.), the product is left open at 40 ° C. (Azwan constant temperature dryer, model number “DO-300FA”) in the open state. And the mass of the sample bottle after every predetermined time passed was measured, and the mass of the functional agent (white floral fragrance) was calculated. Thereafter, based on the initial mass of the functional agent and the mass of the functional agent after a predetermined time, the retention rate (mass%) of the functional agent was calculated by the following formula. The results are shown in Table 10 below and FIG.
Retention rate of functional agent (mass%) = (mass of functional agent after elapse of predetermined time / initial mass of functional agent) × 100
上記表4〜表6の結果から分かるように、実施例のレーヨン繊維は、強度及び伸度といった繊維物性は通常のレーヨン繊維とほぼ変わらず、機能剤による効果を発現していた。また、実施例1と比較例5の対比から明らかなように、実施例のレーヨン繊維は、水硫化処理や漂白処理を行っても基材が変質しにくく、白度が高かった。また、実施例1〜6のレーヨン繊維は、アルカリ処理前後において、残香性の変化幅が小さく、耐久性に優れていた。また、実施例4のレーヨン繊維は、経時促進処理前後における残香性の変化幅が小さく、機能剤の徐放性に優れていた。また、実施例4のレーヨン繊維をアクリル繊維と混綿して得られた不織布の場合も、アルカリ処理前後及び経時促進処理前後の残香性の変化幅が小さく、耐久性及び徐放性に優れていた。また、実施例4と実施例6とを対比すると、繊維中の香料の量が同じであっても、繊維中の機能材の量が多い実施例4の方が残香性が高かった。これは、繊維中の機能材の量が多い、すなわちセルロース中に含まれている機能材の粒子の数が多いことで、香料が繊維外に出て行きやすくなるためと考えられる。 As can be seen from the results in Tables 4 to 6, the rayon fibers of the examples had almost the same fiber properties such as strength and elongation as ordinary rayon fibers, and exhibited the effect of the functional agent. Further, as is clear from the comparison between Example 1 and Comparative Example 5, the rayon fiber of the Example hardly deteriorated the base material even when the hydrosulfurization treatment or the bleaching treatment was performed, and the whiteness was high. In addition, the rayon fibers of Examples 1 to 6 had a small change in residual fragrance before and after the alkali treatment, and were excellent in durability. In addition, the rayon fiber of Example 4 had a small change in the remaining fragrance before and after the aging acceleration treatment, and was excellent in the sustained release of the functional agent. In addition, in the case of the nonwoven fabric obtained by blending the rayon fiber of Example 4 with acrylic fiber, the change in the remaining fragrance was small before and after the alkali treatment and before and after the aging promotion treatment, and was excellent in durability and sustained release. . Moreover, when Example 4 and Example 6 were contrasted, even if the quantity of the fragrance | flavor in a fiber was the same, the direction of Example 4 with much quantity of the functional material in a fiber was higher. This is probably because the amount of the functional material in the fiber is large, that is, the number of the functional material particles contained in the cellulose is large, so that the fragrance easily goes out of the fiber.
実施例2、7及び8と、比較例2及び3の対比から、蜜蝋と機能剤を混合して得られた蜜蝋中に機能剤を包含した機能材をレーヨン繊維に練り込んだ方が、炭化水素やパラフィンと機能剤を混合した混合物をレーヨン繊維に練り込んだ場合より、機能剤による性能付与効果が高いことが分かった。 From the comparison between Examples 2, 7, and 8 and Comparative Examples 2 and 3, it was more carbonized when kneading a functional material containing a functional agent in beeswax obtained by mixing beeswax and a functional agent into rayon fiber. It was found that the performance-imparting effect of the functional agent was higher than when a mixture of hydrogen or paraffin and the functional agent was kneaded into the rayon fiber.
実施例の機能材含有レーヨン繊維において、繊維の断面をデジタルマイクロスコープ(倍率:1000倍、株式会社キーエンス社製、型番「VHX−500F」)で観察したところ、機能剤を基材中に包含する機能材と、セルロースは非相溶状態であり、機能材がセルロース中に分散されていることが確認された。また、実施例の機能材含有レーヨン繊維において、繊維の側面を光学顕微鏡(倍率:320倍、株式会社ニコン社製、型番「ECLIPSE E600」)で観察したところ、機能剤を基材中に包含する機能材と、セルロースは非相溶状態であり、機能材がセルロース中に分散されていることが確認された。機能材の粒子径は一定ではなく分布を持つため、粒子径が小さいものは上述したデジタルマイクロスコープによる観察では確認されなかったが、機能材はセルロース中に微分散されていると予想される。 In the functional material-containing rayon fiber of the example, the cross section of the fiber was observed with a digital microscope (magnification: 1000 times, manufactured by Keyence Corporation, model number “VHX-500F”), and the functional agent was included in the base material. The functional material and cellulose were in an incompatible state, and it was confirmed that the functional material was dispersed in cellulose. Further, in the functional material-containing rayon fiber of the example, the side surface of the fiber was observed with an optical microscope (magnification: 320 times, manufactured by Nikon Corporation, model number “ECLIPSE E600”), and the functional agent was included in the base material. The functional material and cellulose were in an incompatible state, and it was confirmed that the functional material was dispersed in cellulose. Since the particle diameter of the functional material is not constant but has a distribution, those having a small particle diameter were not confirmed by observation with the digital microscope described above, but the functional material is expected to be finely dispersed in cellulose.
図1には、デジタルマイクロスコープ(株式会社キーエンス社製、型番「VHX−500F」)で観察した実施例4のレーヨン繊維の断面の写真(倍率:1000倍)を示した。図2には同機能材含有再生セルロース繊維を光学顕微鏡(株式会社ニコン社製、型番「ECLIPSE E600」)で観察した側面写真(倍率:320倍)を示した。図1において、繊維断面における島部分は機能剤を基材中に包含した機能材である。図2において、黒い点が機能剤を基材中に包含した機能材である。図1及び図2から、機能材含有再生セルロース繊維において、機能剤を基材中に包含した機能材と、セルロースは非相溶状態であり、機能材がセルロース中に粒子状で微分散されていることが確認された。 FIG. 1 shows a photograph (magnification: 1000 times) of the cross section of the rayon fiber of Example 4 observed with a digital microscope (manufactured by Keyence Corporation, model number “VHX-500F”). FIG. 2 shows a side view photograph (magnification: 320 times) of the same functional material-containing regenerated cellulose fiber observed with an optical microscope (manufactured by Nikon Corporation, model number “ECLIPSE E600”). In FIG. 1, the island portion in the fiber cross section is a functional material including a functional agent in the base material. In FIG. 2, a black dot is a functional material in which the functional agent is included in the base material. From FIG. 1 and FIG. 2, in the functional material-containing regenerated cellulose fiber, the functional material containing the functional agent in the base material and the cellulose are in an incompatible state, and the functional material is finely dispersed in the form of particles in the cellulose. It was confirmed that
また、上記表7の結果から分かるように、基材として蜜蝋を用いた場合、基材として1−エイコサノール(直鎖脂肪族アルコール)やオクタコサン(炭化水素)を用いた場合と比較して、固化直後の香気強度は低いが、20日経過後は高くなっていた。これは、蜜蝋は程よく香料を保持し徐々に放出するため香気強度が抑えられていることを示している。強く香るということはそれだけ放出が早く繊維化後の加工後に香気が弱くなることが考えられる。実際に一定期間経過後、1−エイコサノール及びオクタコサンを用いた場合は、香気強度は格段に下がったが、蜜蝋を用いた場合は、香気強度の変化が小さかった。 In addition, as can be seen from the results in Table 7 above, when beeswax is used as the base material, solidification is performed as compared with the case where 1-eicosanol (linear aliphatic alcohol) or octacosane (hydrocarbon) is used as the base material. Immediately after the fragrance intensity was low, it was high after 20 days. This indicates that beeswax moderately holds the fragrance and gradually releases it, thus reducing the fragrance intensity. A strong fragrance is considered to be that the release is so fast that the fragrance becomes weak after processing after fiberization. In fact, when 1-eicosanol and octacosane were used after a certain period of time, the fragrance intensity decreased markedly, but when beeswax was used, the change in fragrance intensity was small.
上記表8及び図3の結果から分かるように、基材として蜜蝋又はカルナバ蝋を用いた場合、基材として1−エイコサノールやオクタコサンを用いた場合と比較して、160時間経過後の機能剤(ホワイトフローラル系香料)の保持率が高かった。これは、基材として蜜蝋又はカルナバ蝋を用いた場合、機能剤の徐放性に優れることを意味する。なお、蜜蝋のみを試料瓶に入れ、40℃以下で静置させ、所定時間ごとの試料瓶(蜜蝋が導入された状態)の質量を測定したところ、160時間経過まで、蜜蝋の質量がほぼ変化しないことが確認された。 As can be seen from the results in Table 8 and FIG. 3, when beeswax or carnauba wax is used as the base material, a functional agent after 160 hours has elapsed compared to the case where 1-eicosanol or octacosane is used as the base material ( The retention rate of white floral fragrance was high. This means that when beeswax or carnauba wax is used as the substrate, the sustained release of the functional agent is excellent. In addition, only beeswax was put in a sample bottle, allowed to stand at 40 ° C. or less, and the mass of the sample bottle (in which beeswax was introduced) was measured every predetermined time. The mass of beeswax almost changed until 160 hours passed. It was confirmed not to.
また、上記表9及び図4の結果から分かるように、機能剤としてリモネンを使用しても、蜜蝋を用いた方が、1−エイコサノールやオクタコサンを用いた場合と比較して、160時間経過後の機能剤の保持率が高かった。 In addition, as can be seen from the results in Table 9 and FIG. 4 above, even when limonene is used as a functional agent, the use of beeswax is after 160 hours as compared with the case of using 1-eicosanol or octacosane. The retention rate of functional agents was high.
上記表10及び図5の結果から分かるように、基材が蜜蝋であり、機能剤がホワイトフローラル系香料の場合、時間経過に伴う機能剤保持率の変化幅が小さく、機能剤の徐放性に優れていた。 As can be seen from the results of Table 10 and FIG. 5, when the base material is beeswax and the functional agent is a white floral fragrance, the change in the functional agent retention rate with time is small, and the sustained release of the functional agent It was excellent.
本発明の機能材含有再生セルロース繊維は、例えば、トウ、フィラメント、紡績糸、中綿(詰め綿)、紙、不織布、織編物等の繊維構造物に用いることができる。また、本発明の繊維構造物は、下着、中着、外着、マフラー、ストール、帽子、耳掛け、手袋等の衣類製品、壁紙、障子紙、カーペット、カーテン等のインテリア製品、毛布、布団カバー、シーツ、枕カバー等の寝具等に有用である。 The functional material-containing regenerated cellulose fiber of the present invention can be used for fiber structures such as tow, filament, spun yarn, batting (padded cotton), paper, nonwoven fabric, woven and knitted fabric. The fiber structure of the present invention includes underwear, innerwear, outerwear, mufflers, stalls, hats, ear hooks, gloves and other clothing products, wallpaper, shoji paper, carpets, curtains and other interior products, blankets, and duvet covers. Useful for bedding such as sheets, pillowcases, etc.
Claims (13)
前記再生セルロース繊維内のセルロースと前記機能材とは非相溶であり、
前記機能材は、基材と、前記基材に混合されている機能剤を含み、
前記基材は、基材の全体質量に対して脂肪酸エステルを25質量%以上含むことを特徴とする機能材含有再生セルロース繊維。 A functional material-containing regenerated cellulose fiber in which a functional material is contained in the regenerated cellulose fiber,
The cellulose in the regenerated cellulose fiber and the functional material are incompatible,
The functional material includes a base material and a functional agent mixed in the base material,
The base material contains 25% by mass or more of a fatty acid ester with respect to the total mass of the base material.
セルロースを含むビスコースに、基材に機能剤を混合した混合物である機能材を乳化分散して得られた機能材の分散液を混合して紡糸用ビスコースを調製し、
前記紡糸用ビスコースをノズルより押し出して紡糸し、凝固再生することで、機能材含有再生セルロース繊維を得ており、
前記機能材含有再生セルロース繊維において、前記機能材とセルロースは非相溶であり、
前記基材は、基材の全体質量に対して脂肪酸エステルを25質量%以上含むことを特徴とする機能材含有再生セルロース繊維の製造方法。 A functional material-containing regenerated cellulose fiber containing a functional material in the regenerated cellulose fiber,
A viscose for spinning is prepared by mixing a dispersion of a functional material obtained by emulsifying and dispersing a functional material which is a mixture of a functional agent and a base material mixed with viscose containing cellulose,
The viscose for spinning is extruded from a nozzle, spun, and coagulated and regenerated to obtain a functional material-containing regenerated cellulose fiber.
In the functional material-containing regenerated cellulose fiber, the functional material and cellulose are incompatible,
The said base material contains 25 mass% or more of fatty acid ester with respect to the whole mass of a base material, The manufacturing method of the functional material containing regenerated cellulose fiber characterized by the above-mentioned.
他の繊維として、機能材含有再生セルロース繊維以外の再生セルロース繊維、コットン、麻、ウール、アクリル繊維、ポリエステル繊維、ポリアミド繊維、ポリオレフィン繊維及びポリウレタン繊維からなる群から選ばれる少なくとも一つの繊維を10〜90質量%含む請求項12に記載の繊維構造物。 Containing 10 to 90% by mass of the functional material-containing regenerated cellulose fiber,
As other fibers, at least one fiber selected from the group consisting of regenerated cellulose fibers other than the functional material-containing regenerated cellulose fibers, cotton, hemp, wool, acrylic fibers, polyester fibers, polyamide fibers, polyolefin fibers, and polyurethane fibers is 10 to 10. The fiber structure according to claim 12, comprising 90% by mass.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019126786A (en) * | 2018-01-25 | 2019-08-01 | ダイワボウホールディングス株式会社 | Molded body of arsenic adsorption regenerated cellulose, production method of the same, arsenic adsorption material, and water treatment material |
JP2019173207A (en) * | 2018-03-28 | 2019-10-10 | 俊夫 小室 | Health-promoting composition generating photon and ion |
WO2021130966A1 (en) * | 2019-12-26 | 2021-07-01 | 株式会社フィル | Wall paper and pasting method therefor |
JP2021123818A (en) * | 2020-02-04 | 2021-08-30 | オーミケンシ株式会社 | Modified fiber, yarn, fabric and textile product |
CN115094524A (en) * | 2022-07-26 | 2022-09-23 | 天津大学浙江研究院 | Method for preparing nano cellulose-based microfiber by adopting microfluid spinning process |
US11938687B2 (en) | 2020-10-28 | 2024-03-26 | Panasonic Intellectual Property Management Co., Ltd. | Plant fiber-containing composite resin molded article with sustained release of aroma |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011503382A (en) * | 2007-11-14 | 2011-01-27 | テューリンギッシェス・インスティトゥート・フューア・テクスティル−ウント・クンストストッフ−フォルシュング・エー・ファウ | Method for producing cellulosic molded product, cellulosic molded product and use thereof |
JP2012097399A (en) * | 2010-10-06 | 2012-05-24 | Daiwabo Holdings Co Ltd | Fat-containing rayon fiber, its manufacturing method and fiber structure |
JP2013144855A (en) * | 2012-01-13 | 2013-07-25 | Daiwabo Holdings Co Ltd | Rayon fiber including fat and oil, method for producing the same, and fiber structure |
JP2014141765A (en) * | 2013-01-25 | 2014-08-07 | Daiwabo Holdings Co Ltd | Fat-containing rayon fiber, production method thereof and fiber structure |
-
2016
- 2016-04-27 JP JP2016089660A patent/JP6727022B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011503382A (en) * | 2007-11-14 | 2011-01-27 | テューリンギッシェス・インスティトゥート・フューア・テクスティル−ウント・クンストストッフ−フォルシュング・エー・ファウ | Method for producing cellulosic molded product, cellulosic molded product and use thereof |
JP2012097399A (en) * | 2010-10-06 | 2012-05-24 | Daiwabo Holdings Co Ltd | Fat-containing rayon fiber, its manufacturing method and fiber structure |
JP2013144855A (en) * | 2012-01-13 | 2013-07-25 | Daiwabo Holdings Co Ltd | Rayon fiber including fat and oil, method for producing the same, and fiber structure |
JP2014141765A (en) * | 2013-01-25 | 2014-08-07 | Daiwabo Holdings Co Ltd | Fat-containing rayon fiber, production method thereof and fiber structure |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019126786A (en) * | 2018-01-25 | 2019-08-01 | ダイワボウホールディングス株式会社 | Molded body of arsenic adsorption regenerated cellulose, production method of the same, arsenic adsorption material, and water treatment material |
JP7130192B2 (en) | 2018-01-25 | 2022-09-05 | ダイワボウレーヨン株式会社 | Arsenic-adsorbing regenerated cellulose molded article, method for producing same, arsenic-adsorbing material, and water treatment material |
JP2019173207A (en) * | 2018-03-28 | 2019-10-10 | 俊夫 小室 | Health-promoting composition generating photon and ion |
WO2021130966A1 (en) * | 2019-12-26 | 2021-07-01 | 株式会社フィル | Wall paper and pasting method therefor |
JPWO2021130966A1 (en) * | 2019-12-26 | 2021-07-01 | ||
JP6993632B2 (en) | 2019-12-26 | 2022-01-13 | 株式会社フィル | How to paste wallpaper |
JP2021123818A (en) * | 2020-02-04 | 2021-08-30 | オーミケンシ株式会社 | Modified fiber, yarn, fabric and textile product |
JP7343743B2 (en) | 2020-02-04 | 2023-09-13 | オーミケンシ株式会社 | Modified fibers, yarns, fabrics and textile products |
US11938687B2 (en) | 2020-10-28 | 2024-03-26 | Panasonic Intellectual Property Management Co., Ltd. | Plant fiber-containing composite resin molded article with sustained release of aroma |
CN115094524A (en) * | 2022-07-26 | 2022-09-23 | 天津大学浙江研究院 | Method for preparing nano cellulose-based microfiber by adopting microfluid spinning process |
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