JP2016113172A - Food packaging sheet, food packaging bag, and food package - Google Patents
Food packaging sheet, food packaging bag, and food package Download PDFInfo
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- JP2016113172A JP2016113172A JP2014252651A JP2014252651A JP2016113172A JP 2016113172 A JP2016113172 A JP 2016113172A JP 2014252651 A JP2014252651 A JP 2014252651A JP 2014252651 A JP2014252651 A JP 2014252651A JP 2016113172 A JP2016113172 A JP 2016113172A
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Landscapes
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Abstract
Description
本発明は、食品包装用シート、食品包装袋、および食品包装体に関するものである。 The present invention relates to a food packaging sheet, a food packaging bag, and a food packaging body.
食品は、例えば、生産や出荷した後、市場に流通する前に、ポリプロピレンフィルムや
ポリエチレンフィルムのようなフィルムによって包装される場合がある。この場合、袋内の酸素で、食品が酸化し、変色してしまうことがある。
For example, food products may be packaged by a film such as a polypropylene film or a polyethylene film after production or shipment and before distribution to the market. In this case, the food may be oxidized and discolored by oxygen in the bag.
食品鮮度保持方法としては、特許文献1に記載のように、ミョウバンおよびpH調整剤を含みそしてpHが2.75〜3.75である水溶液で食品を処理する方法がある。しかしながら特許文献1に記載の方法では、薬品を使用することが問題であった。 As a method for maintaining food freshness, there is a method of treating food with an aqueous solution containing alum and a pH adjuster and having a pH of 2.75 to 3.75, as described in Patent Document 1. However, in the method described in Patent Document 1, the use of chemicals has been a problem.
本発明は、食品の変色防止が可能な食品包装用シート、および食品包装袋を提供することにある。 An object of the present invention is to provide a food packaging sheet capable of preventing discoloration of food and a food packaging bag.
このような目的は、下記(1)〜(10)の本発明により達成される。 Such an object is achieved by the present inventions (1) to (10) below.
(1)食品を包装するのに用いられる食品包装用シートであって、第1の層と、第2の層を有し、前記第2の層の厚みが、3μm以上、30μm以下であり、前記食品包装用シートの酸素透過度が20cc/m2・日・atm以上、250cc/m2・日・atm(23℃、90%RH)以下であることを特徴とする食品包装用シート。 (1) A food packaging sheet used for packaging food, comprising a first layer and a second layer, wherein the thickness of the second layer is 3 μm or more and 30 μm or less, The food packaging sheet, wherein the food packaging sheet has an oxygen permeability of 20 cc / m 2 · day · atm or more and 250 cc / m 2 · day · atm (23 ° C., 90% RH) or less.
(2)前記第1の層が、ポリエステル系樹脂或いはポリアミド系樹脂を含むことを特徴とする(1)記載の食品包装用シート。 (2) The food packaging sheet according to (1), wherein the first layer contains a polyester resin or a polyamide resin.
(3)前記第1の層の厚みが、5μm以上、30μm以下であることを特徴とする(1)または(2)に記載の食品包装用シート。 (3) The food packaging sheet according to (1) or (2), wherein the thickness of the first layer is 5 μm or more and 30 μm or less.
(4)前記第2の層が、ポリオレフィン系樹脂を含むことを特徴とする(1)ないし(3)のいずれか1項に記載の食品包装用シート。 (4) The food packaging sheet according to any one of (1) to (3), wherein the second layer includes a polyolefin resin.
(5)前記食品包装のシートの厚みが、20μm以上、40μm以下である(1)ないし(4)のいずれか1項に記載の食品包装用シート。 (5) The food packaging sheet according to any one of (1) to (4), wherein a thickness of the food packaging sheet is 20 μm or more and 40 μm or less.
(6)(1)ないし(5)のいずれか1項に記載の食品包装用シートを、袋状に成形したことを特徴とする食品包装袋。 (6) A food packaging bag, wherein the food packaging sheet according to any one of (1) to (5) is formed into a bag shape.
(7)幅および長さが250mm以下であることを特徴とする、(6)記載の食品包装袋。 (7) The food packaging bag according to (6), wherein the width and length are 250 mm or less.
(8)包装される食品100gあたりの袋の表面積が、0.05m2以上0.13m2以下であることを特徴とする、(6)または(7)に記載の食品包装袋。 (8) surface area of the bag per food 100g to be packaged, characterized in that at 0.05 m 2 or more 0.13 m 2 or less, food packaging bag according to (6) or (7).
(9)レタスを包装するのに用いられることを特徴とする、(6)ないし(8)のいずれか1項に記載の食品包装袋。 (9) The food packaging bag according to any one of (6) to (8), which is used for packaging lettuce.
(10)カットレタスを包装するのに用いられる、(6)ないし(9)のいずれか1項に記載の食品包装袋。 (10) The food packaging bag according to any one of (6) to (9), which is used for packaging cut lettuce.
(11)(6)ないし(10)のいずれか1項に記載の食品包装袋に、食品を密封し、脱気し、包装したのちの厚みが0.5cm以上、3cm以下であることを特徴とする食品包装体。 (11) The thickness of the food packaging bag according to any one of (6) to (10) is 0.5 cm or more and 3 cm or less after the food is sealed, degassed and packaged. Food packaging body.
本発明によれば、食品の変色防止が可能な食品包装用シートを得ることができる。また、かかる食品包装用シートで構成された食品包装袋を得ることができる。 According to the present invention, a food packaging sheet capable of preventing discoloration of food can be obtained. Moreover, the food packaging bag comprised with this food packaging sheet can be obtained.
以下、本発明の食品包装用シート、食品包装袋を添付図面に示す好適な実施形態に基づいて詳細に説明する。
<食品包装体>
図1は、本発明の食品包装体の第1実施形態を模式的に示す図((a)は平面図、(b)は図1(a)中のA−A線断面図)、図2は、図1に示す食品包装用シートの断面図である。
Hereinafter, the food packaging sheet and food packaging bag of the present invention will be described in detail based on preferred embodiments shown in the accompanying drawings.
<Food packaging>
FIG. 1 is a diagram schematically showing a first embodiment of a food packaging body according to the present invention ((a) is a plan view, (b) is a cross-sectional view taken along line AA in FIG. 1 (a)), FIG. These are sectional drawings of the sheet | seat for food packaging shown in FIG.
なお、以下の説明では、図1中の上側を「上」、下側を「下」と言い、左側を「左」、右側を「右」という。また、本明細書で参照する図面は、構成の一部を誇張して示したものであり、実際の寸法等を正確に反映したものではない。 In the following description, the upper side in FIG. 1 is referred to as “upper”, the lower side is referred to as “lower”, the left side is referred to as “left”, and the right side is referred to as “right”. In addition, the drawings referred to in this specification show part of the configuration in an exaggerated manner, and do not accurately reflect actual dimensions and the like.
図1に示す食品包装体100は、食品包装袋50と、この食品包装袋50で密閉された状態で包装された食品1とを有している。 A food packaging body 100 shown in FIG. 1 has a food packaging bag 50 and a food 1 packaged in a state of being sealed with the food packaging bag 50.
食品1としては、特に限定されず、例えば、バナナ、マンゴー、ウメ、リンゴ、イチゴ、ミカン、ブドウ、和梨、西洋梨のような果実類、ダイコン、ニンジン、ナガイモ、ゴボウのような根菜類、トマト、キュウリ、ナス、ピーマン、エダマメ、オクラのような果菜類、緑豆モヤシ、大豆モヤシ、トウミョウのような芽物類、シイタケ、シメジ、エリンギ、マイタケ、マツタケのような菌茸類(キノコ類)、ブロッコリー、ホウレンソウ、コマツナ、チンゲンサイ、レタス、アスパラガスのような葉茎菜類、キク、ユリ、カーネーション等の花卉または苗等の青果物やこれらの加工品・調理品等(例えば、漬物、ジャム、果実ソース等)、鶏肉、豚肉、牛肉、魚肉等の肉類やこれらの加工品・調理品等(例えば、蒲鉾、ちくわ、ソーセージ、ハム等)、饅頭、チョコレート、ガム、ゼリー、寒天、クッキー等の菓子、牛乳、ヨーグルト、チーズ等の乳製品、醤油、味噌等の調味料、酒、清涼飲料水等の液体飲料またはゼリー状の飲料、サプリメント(栄養補助食品)、健康機能食品等の健康食品、うどん、そば等の麺類、パン類、米類、餅類等、あるいはこれらを組み合わせたものが挙げられ、これらの何れであっても、食品包装袋50で包装することができる。なお、飲料としては、緑茶、ほうじ茶等のお茶や紅茶等の茶葉や、各種ティーパック、ココア、粉ジュース等の、いわゆる粉末飲料等であってもよい。 The food 1 is not particularly limited. For example, fruits such as banana, mango, ume, apple, strawberry, mandarin orange, grape, Japanese pear, and pear, radish, carrot, yam, root vegetables such as burdock, Fruit vegetables such as tomato, cucumber, eggplant, bell pepper, green beans, okra, mung bean sprout, soybean sprout, sprout such as cypress, fungi (mushrooms) such as shiitake, shimeji, eringi, maitake, matsutake , Broccoli, Spinach, Komatsuna, Chingensai, Lettuce, Leaf and stem vegetables such as asparagus, chrysanthemum, lily, carnations and other fruits and vegetables, and processed and cooked products thereof (for example, pickles, jams, Fruit sauce, etc.), chicken, pork, beef, fish and other meats and their processed and cooked products (eg, salmon, chikuwa, sausage, Etc.), buns, chocolate, gum, jelly, agar, cookies and other confectionery, milk, yogurt, cheese and other dairy products, soy sauce, miso and other seasonings, liquor, soft drinks and other liquid beverages or jelly-like Examples include beverages, supplements (dietary supplements), health foods such as functional health foods, noodles such as udon and soba, breads, rice, potatoes, etc., or combinations thereof. Can also be packaged in the food packaging bag 50. In addition, as a drink, what is called powder drinks, such as tea leaves, such as teas, such as green tea and hojicha, and tea, various tea packs, cocoa, powdered juice, etc. may be sufficient.
このような食品1は、食品包装袋50に収納されて食品包装体100とされ、例えば市場や小売店で陳列して販売される。 Such a food 1 is stored in a food packaging bag 50 to form a food packaging body 100, and is displayed and sold in, for example, a market or a retail store.
以下、本発明の食品包装体が備える食品用包装袋について説明する。
<食品包装袋>
図1に示す食品包装袋50は、食品を収納するために用いられる食品包装容器である。
Hereinafter, the packaging bag for food with which the food packaging body of this invention is provided is demonstrated.
<Food packaging bag>
A food packaging bag 50 shown in FIG. 1 is a food packaging container used for storing food.
食品包装袋50は、食品包装用シート10として、四角形状の第1のシート10aおよび第2のシート10bを、互いの各辺同士が重なるように重ね合わせた後、3辺を接着、溶融、縫製等により接合することで、袋状に形成されたものである。図1では、接合された部分をシール部52として、網掛けを付して示す。 The food packaging bag 50 is composed of the first sheet 10a and the second sheet 10b having a rectangular shape as the food packaging sheet 10, and the three sides are bonded and melted after overlapping each other. It is formed into a bag shape by joining by sewing or the like. In FIG. 1, the joined portion is shown as a seal portion 52 with shading.
また、食品包装袋50は、図1に示すように、その内部に形成された空間53と、食品包装袋50の図1(a)中右辺部に設けられた封止部54とを有している。この封止部54は、食品包装袋50の図1(a)中右側に開口した口部を封止することで得られる。なお、封止部54を封止する方法としては、例えば、口部を金属または樹脂製かしめ、輪ゴム、テープおよびジッパー等で縛る方法、または、口部を接着、溶融(ヒートシール)、縫製する方法等が挙げられ、いかなる方法であってもよい。 Further, as shown in FIG. 1, the food packaging bag 50 has a space 53 formed therein, and a sealing portion 54 provided on the right side of the food packaging bag 50 in FIG. ing. This sealing part 54 is obtained by sealing the mouth part opened to the right side in Fig.1 (a) of the food packaging bag 50. FIG. In addition, as a method of sealing the sealing part 54, for example, the mouth part is made of metal or resin, and the mouth part is tied with a rubber band, a tape, a zipper, or the like, or the mouth part is bonded, melted (heat sealed), and sewn. Any method may be used.
図1に示すような食品包装体100は、このような構成の食品包装袋50の空間53内に、口部を介して食品1を入れた後、口部を前記のような方法により封止することにより得られる。このとき、食品包装袋50の3辺がシール部52によって接合されているため、食品1は食品包装袋50から脱落することが防止されている。 The food packaging body 100 as shown in FIG. 1 puts the food 1 into the space 53 of the food packaging bag 50 having such a configuration through the mouth portion, and then seals the mouth portion by the method as described above. Can be obtained. At this time, since the three sides of the food packaging bag 50 are joined by the seal portion 52, the food 1 is prevented from falling off the food packaging bag 50.
食品包装体100の厚みは、食品包装袋50の空間53内に、口部を介して食品1を入れた後、脱気し、包装したとき、3cm以下であることが好ましい。これにより食品の変色防止効果が得られる。また、食品包装体100の厚みは、食品包装袋50の空間53内に、口部を介して食品1を入れた後、脱気し、包装したとき、0.5cm以上であることが好ましい。これにより内容物の食品がつぶれることがなく、好ましい。1cm以上がより好ましい。 The thickness of the food packaging body 100 is preferably 3 cm or less when the food 1 is put into the space 53 of the food packaging bag 50 through the mouth and then deaerated and packaged. Thereby, the discoloration prevention effect of food is acquired. In addition, the thickness of the food package 100 is preferably 0.5 cm or more when the food 1 is put in the space 53 of the food packaging bag 50 through the mouth and then deaerated and packaged. This is preferable because the food of the contents is not crushed. 1 cm or more is more preferable.
食品包装袋50の幅および長さは250mm以下であることが好ましい。これにより、食品包装袋50を脱気し、包装する際の作業性が向上する。 The width and length of the food packaging bag 50 are preferably 250 mm or less. Thereby, the workability | operativity at the time of deaeration and packaging the food packaging bag 50 improves.
食品包装袋50の表面積は、食品1の100gあたり、0.05m2以上0.13m2以下であることが好ましい。これにより食品の変色防止効果を有しつつ、食品を食品包装袋50に入れるのが容易となる。 The surface area of the food packaging bag 50, per 100g of the food 1 is preferably 0.05 m 2 or more 0.13 m 2 or less. Thereby, it becomes easy to put food into the food packaging bag 50 while having the effect of preventing discoloration of the food.
以下に、このような構成の食品包装袋50を形成する食品包装用シート10について説明する。
<食品包装用シート>
図2に示すように、食品包装用シート10は、それぞれ、第1の層11と、第2の層12とを有するものである。
Below, the sheet | seat 10 for food packaging which forms the food packaging bag 50 of such a structure is demonstrated.
<Food packaging sheet>
As shown in FIG. 2, the food packaging sheet 10 includes a first layer 11 and a second layer 12.
以下、第1の層11と第2の層12とについて順次説明する。 Hereinafter, the first layer 11 and the second layer 12 will be sequentially described.
(第1の層11)
第1の層11は、適度な酸素透過性を有し、袋外の酸素が袋内に透過するのを防止する機能を有する。
(First layer 11)
The first layer 11 has an appropriate oxygen permeability and has a function of preventing oxygen outside the bag from permeating into the bag.
第1の層11は、内容物を確認できる観点から、透明な樹脂フィルム層であることが好ましい。 The first layer 11 is preferably a transparent resin film layer from the viewpoint of confirming the contents.
第1の層11は、樹脂を含有する。樹脂としては特に限定されないが、ポリエステル系樹脂、ポリアミド系樹脂、ポリオレフィン系樹脂があげられる。 The first layer 11 contains a resin. The resin is not particularly limited, and examples thereof include polyester resins, polyamide resins, and polyolefin resins.
第1の層11は、ポリエステル系樹脂又はポリアミド系樹脂を含有していることが好ましい。これにより食品包装用シート10が適度な酸素透過効果を有する。ポリエステル系樹脂としては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート、ポリ乳酸、等の単独又は二種以上組み合わせが好ましく、ポリエチレンテレフタレート単独がより好ましい。ポリアミド系樹脂としては、ナイロンが好ましい。ナイロンは、ナイロン6、ナイロン11、ナイロン12、ナイロン66、ナイロン6・10、ナイロン6・12、ナイロン6・T、ナイロン6・I、ナイロン9T、ナイロンM5T、ポリメタキシリレンアジパミド(MXDナイロン)、等の単独又は二種以上組み合わせが好ましく、ナイロン6、ナイロン11、ナイロン12、及びナイロン66の単独又は二種以上組み合わせがより好ましく、ナイロン6及びナイロン66の単独又は二種の組み合わせがさらに好ましい。 The first layer 11 preferably contains a polyester resin or a polyamide resin. Thereby, the sheet | seat 10 for food packaging has a moderate oxygen permeation effect. As the polyester-based resin, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polylactic acid or the like is preferably used alone or in combination of two or more, and polyethylene terephthalate alone is more preferable. Nylon is preferable as the polyamide resin. Nylon 6, Nylon 11, Nylon 12, Nylon 66, Nylon 6 · 10, Nylon 6 · 12, Nylon 6 · T, Nylon 6 · I, Nylon 9T, Nylon M5T, Polymetaxylylene adipamide (MXD Nylon) ), Etc., or a combination of two or more, such as nylon 6, nylon 11, nylon 12, and nylon 66 is more preferable, or a combination of two or more is more preferable, and a combination of nylon 6 and nylon 66 is also a combination of two or more. preferable.
第1の層11は、必要に応じて、無機系フィラーを含有することが出来る。無機系フィラーとしては、特に限定されない。例えば、ゼオライト、セピオライト、珪藻土、シリカ、シリカゲル、アロブェン、イモゴライト、モンモリロナイト、アタパルジャイト、或いはゾノトライトのような鉱物(無機質結晶体)等を用いてもよい。 The first layer 11 can contain an inorganic filler as necessary. The inorganic filler is not particularly limited. For example, a mineral (inorganic crystal) such as zeolite, sepiolite, diatomaceous earth, silica, silica gel, arobene, imogolite, montmorillonite, attapulgite, or zonotlite may be used.
第1の層11は、必要に応じて、熱安定剤、滑剤、防曇剤、耐衝撃改良剤、加工助剤、静電防止剤、紫外線吸収剤、酸化防止剤、耐侯劣化防止剤、充填剤、顔料、等の添加剤を樹脂フィルムの性能を損なわない範囲で含有することができる。 If necessary, the first layer 11 may be a heat stabilizer, a lubricant, an antifogging agent, an impact resistance improving agent, a processing aid, an antistatic agent, an ultraviolet absorber, an antioxidant, an anti-wrinkle-proofing agent, or a filling. Additives such as agents, pigments, and the like can be contained within a range that does not impair the performance of the resin film.
また、第1の層11としては、前述したような樹脂材料を含む単層フィルムや、樹脂材料で構成された単層フィルムを2層以上積層した多層フィルムのものを用いることができる。なお、多層フィルムの場合には、同一の材料で構成されていてもよいし、異なる材料で構成されていてもよい。また、第1の層11は、樹脂材料を含むフィルム(単層フィルムのおよび多層フィルム)に金属箔、紙や不織布等を積層したものであってもよい。 Moreover, as the 1st layer 11, the thing of the multilayer film which laminated | stacked two or more layers of the single layer film containing the resin material as mentioned above, or the single layer film comprised with the resin material can be used. In addition, in the case of a multilayer film, it may be comprised with the same material and may be comprised with a different material. Moreover, the 1st layer 11 may laminate | stack metal foil, paper, a nonwoven fabric, etc. on the film (a single layer film and a multilayer film) containing a resin material.
第1の層11の厚みは、5μm以上が好ましく、10μm以上がより好ましく、一方、30μm以下が好ましく、20μm以下がより好ましい。第1の層11の厚みを5μm以上、30μm以下とすることで、食品包装袋50の見栄えを良好にし、適度な酸素透過性及び強度が得られる。また、適度な柔軟性が得られる。 The thickness of the first layer 11 is preferably 5 μm or more, more preferably 10 μm or more, on the other hand, preferably 30 μm or less, more preferably 20 μm or less. By making the thickness of the 1st layer 11 into 5 micrometers or more and 30 micrometers or less, the appearance of the food packaging bag 50 is made favorable, and moderate oxygen permeability and intensity | strength are obtained. Moreover, moderate flexibility can be obtained.
(第2の層12)
第2の層12は、第1の層11を支持し、食品包装用シート10全体としての、強度等を好適なものとする機能を有している。
(Second layer 12)
The second layer 12 has a function of supporting the first layer 11 and making the strength and the like of the food packaging sheet 10 as a whole suitable.
第2の層12は、樹脂を含有する。樹脂としては特に限定されないが、ポリエチレン、ポリプロピレン、エチレン−ビニルアルコール共重合体、エチレン−酢酸ビニル共重合体、エチレン−アクリル酸共重合体、エチレン−メチルメタアクリレート共重合体、アイオノマー等があげられる。第2の層12が含有する樹脂は、食品包装用シート10から自動包装機で青果物を包装する際に、安定して充分なシール強度を得つつ、密封しやすくするために、ポリオレフィン系樹脂が好ましく、これらのポリオレフィン系樹脂は、単独で又は二種以上組み合わせて使用できる。ポリオレフィン系樹脂の内、ポリエチレン、ポリプロピレン或いはエチレン酢酸ビニル共重合体がより好ましい。 The second layer 12 contains a resin. The resin is not particularly limited, and examples thereof include polyethylene, polypropylene, ethylene-vinyl alcohol copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-methyl methacrylate copolymer, and ionomer. . The resin contained in the second layer 12 is a polyolefin resin in order to make it easy to seal while obtaining sufficient sealing strength stably when packaging fruits and vegetables from the food packaging sheet 10 with an automatic packaging machine. Preferably, these polyolefin resins can be used alone or in combination of two or more. Of the polyolefin-based resins, polyethylene, polypropylene, or ethylene vinyl acetate copolymer is more preferable.
第2の層12は、フィルムのブロッキング防止、或いはその水蒸気透過度及び水の接触角を調整するために、ゼオライト、セピオライト、珪藻土、シリカ、シリカゲル、アロブェン、イモゴライト、モンモリロナイト、アタパルジャイト、或いはゾノトライトのような鉱物等を含有してもよい。 The second layer 12 is made of zeolite, sepiolite, diatomaceous earth, silica, silica gel, arobene, imogolite, montmorillonite, attapulgite, or zonotlite to prevent blocking of the film or adjust its water vapor permeability and water contact angle. May contain various minerals.
第2の層12は、必要に応じて、防曇剤、熱安定剤、滑剤、上記以外の防曇剤、耐衝撃改良剤、加工助剤、静電防止剤、紫外線吸収剤、酸化防止剤、耐侯劣化防止剤、無機粒子、充填剤及び顔料等の添加剤を含有してもよい。 If necessary, the second layer 12 is made of an antifogging agent, a heat stabilizer, a lubricant, an antifogging agent other than the above, an impact resistance improving agent, a processing aid, an antistatic agent, an ultraviolet absorber, or an antioxidant. Further, additives such as anti-wrinkle resistance inhibitor, inorganic particles, fillers and pigments may be contained.
第2の層12の厚みは、3μm以上であり、8μm以上が好ましく、14μm以上がより好ましく、一方、30μm以下であり、25μm以下が好ましく、20μm以下がより好ましい。最内層3の厚みを3μm以上とすることにより、食品包装用シート10で製造した食品包装袋50の強度を保持できるとともに袋の高密封性を得ることができ、30μm以下とすることにより、積層体の柔軟性や透明性を得ることができる。 The thickness of the second layer 12 is 3 μm or more, preferably 8 μm or more, more preferably 14 μm or more, and on the other hand, 30 μm or less, preferably 25 μm or less, and more preferably 20 μm or less. By setting the thickness of the innermost layer 3 to 3 μm or more, it is possible to maintain the strength of the food packaging bag 50 manufactured by the food packaging sheet 10 and to obtain high sealing performance of the bag. Body flexibility and transparency can be obtained.
(その他の層)
第3の層13は、必要に応じて、第1の層11と第2の層12との間に設けることができる。これにより、第1の層11と第2の層12との密着性をより向上できる。
(Other layers)
The third layer 13 can be provided between the first layer 11 and the second layer 12 as necessary. Thereby, the adhesiveness of the 1st layer 11 and the 2nd layer 12 can be improved more.
第3の層13は、変性ポリエチレン、変性ポリプロピレン、変性エチレン・酢酸ビニル共重合体、変性ポリエステル等のいわゆる接着性樹脂、或いはウレタン系、チタネート系、イミン系、ブタジエン系、オレフィン系等のいわゆるアンカーコート剤、ポリエステル系やポリエーテル系等の接着剤を含む樹脂を含むことができる。 The third layer 13 is a so-called adhesive resin such as modified polyethylene, modified polypropylene, modified ethylene / vinyl acetate copolymer, modified polyester, or so-called anchor such as urethane, titanate, imine, butadiene, or olefin. A resin containing an adhesive such as a coating agent, polyester or polyether may be included.
食品包装用シート10の酸素透過度は、20cc/m2・日・atm以上、250cc/m2・日・atm(23℃、90%RH)以下であることが好ましい。さらに好ましくは、20cc/m2・日・atm以上、200cc/m2・日・atm(23℃、90%RH)以下、より好ましくは、20cc/m2・日・atm以上、150cc/m2・日・atm(23℃、90%RH)以下である。これにより、食品の保存性を向上することができる。 The oxygen permeability of the food packaging sheet 10 is preferably 20 cc / m 2 · day · atm or more and 250 cc / m 2 · day · atm (23 ° C., 90% RH) or less. More preferably, it is 20 cc / m 2 · day · atm or more, 200 cc / m 2 · day · atm (23 ° C., 90% RH) or less, more preferably 20 cc / m 2 · day · atm or more, 150 cc / m 2. -Day-atm (23 ° C., 90% RH) or less. Thereby, the preservability of foodstuffs can be improved.
食品包装用シート10の水蒸気透過度は、20g/m2・日以下が好ましく、10g/m2・日以上100g/m2・日以下がより好ましい。20g/m2・日以下とすることで、食品包装袋50の外部の環境の影響を低減し、食品自身からの水分の蒸散を抑制しつつ、食品包装袋50の内部に外部から水分が入り込むのを抑制できる。これにより、食品包装袋50内の食品の乾燥を防ぐことができる。なお、水蒸気透過度は、JIS Z 0208(40℃、90%RH)に準拠して測定する。 The water vapor permeability of the food packaging sheet 10 is preferably 20 g / m 2 · day or less, and more preferably 10 g / m 2 · day to 100 g / m 2 · day. By setting the amount to 20 g / m 2 · day or less, moisture from the outside enters the inside of the food packaging bag 50 while reducing the influence of the environment outside the food packaging bag 50 and suppressing the evaporation of moisture from the food itself. Can be suppressed. Thereby, drying of the foodstuff in the food packaging bag 50 can be prevented. The water vapor permeability is measured according to JIS Z 0208 (40 ° C., 90% RH).
食品包装用シート10の厚さは、20μm以上が好ましく、25μm以上がより好ましく、一方、40μm以下が好ましく、35μm以下がより好ましい。食品包装シート10の厚さを20μm以上とすることにより、食品包装袋50において良好な強度が得られ、50μm以下とすることにより、適度な柔軟性が得られる。 The thickness of the food packaging sheet 10 is preferably 20 μm or more, more preferably 25 μm or more, on the other hand, preferably 40 μm or less, more preferably 35 μm or less. By setting the thickness of the food packaging sheet 10 to 20 μm or more, good strength can be obtained in the food packaging bag 50, and by setting the thickness to 50 μm or less, appropriate flexibility can be obtained.
食品包装用シート10の透明度は、2%以上10%以下のヘイズであることが好ましく、3%以上8%以下のヘイズであることがより好ましい。ヘイズを2%以上10%以下の範囲とすることにより、食品包装袋50とした際に透明性が得られ、包装袋の中身(青果物など)を充分に見分けることができ、良好な外観が得られる。 The transparency of the food packaging sheet 10 is preferably 2% or more and 10% or less, and more preferably 3% or more and 8% or less. By setting the haze in the range of 2% or more and 10% or less, transparency can be obtained when the food packaging bag 50 is made, the contents (such as fruits and vegetables) of the packaging bag can be distinguished sufficiently, and a good appearance can be obtained. It is done.
なお、ヘイズとは、拡散光透過率を全光線透過率で除した値であり、JIS K7105に準拠して測定する。 The haze is a value obtained by dividing the diffuse light transmittance by the total light transmittance, and is measured according to JIS K7105.
食品包装用シート10は、上記のような材料、厚み等の特性を有する第1の層11第2の層12を押出ラミネート法、ドライラミネート法、共押出しラミネート法、コート法等により積層させることによって得られる。積層方法は、どのような方法で行っても差し支えない。 The food packaging sheet 10 is formed by laminating the first layer 11 and the second layer 12 having the above-described characteristics such as material and thickness by an extrusion lamination method, a dry lamination method, a co-extrusion lamination method, a coating method, and the like. Obtained by. Any lamination method may be used.
なお、第1のシート10aおよび第2のシート10bは、同一の構成のものであってもよいし、異なる構成のものであってもよい。例えば、第1のシート10aおよび第2のシート10bの膜厚や構成材料が、それぞれ異なるものであってもよい。 Note that the first sheet 10a and the second sheet 10b may have the same configuration or different configurations. For example, the film thicknesses and constituent materials of the first sheet 10a and the second sheet 10b may be different from each other.
食品包装袋50は、青果物を保存して結露を防止することができる。すなわち、食品包装袋50は、内部に入れた青果物自身の呼吸による水蒸気によって生じる食品包装袋50の内面の曇りを抑制するとともに、長期間保存しても、結露の発生を抑制できるものである。この理由としては、食品包装袋50の内面に付着した水分が、青果物包装袋用多層フィルム10の第2の層12により膜状に広がるため、結露を抑制できると考えられる。 The food packaging bag 50 can store fruits and vegetables to prevent condensation. That is, the food packaging bag 50 can suppress fogging of the inner surface of the food packaging bag 50 caused by water vapor due to respiration of the fruits and vegetables contained therein, and can suppress the occurrence of condensation even if stored for a long time. The reason for this is considered that moisture adhering to the inner surface of the food packaging bag 50 spreads in a film shape by the second layer 12 of the multilayer film 10 for fruit and vegetable packaging bags, and therefore it is considered that dew condensation can be suppressed.
本実施形態の食品包装袋50の内容物である食品1は、酸化によって変色するものが好適であり、レタスや、キャベツ、白菜、カットレタス、カットリンゴがあげられるが、レタスが適しており、特にカットレタスが適している。 The food 1 that is the contents of the food packaging bag 50 of the present embodiment is preferably one that changes color by oxidation, and includes lettuce, cabbage, Chinese cabbage, cut lettuce, and cut apple, but lettuce is suitable. Cut lettuce is particularly suitable.
本発明においては、食品包装用シート10の酸素透過度を、20cc/m2・日・atm以上、250cc/m2・日・atm(23℃、90%RH)以下とし、さらに第2の層12の厚みを3μm以上と30μm以下とすることで、食品包装用シート10が適度な高密封性と柔軟性、透明性を得るため、食品包装袋50に食品を入れ、脱気する際に、圧力をかけた際に食品包装袋50が破損することがなく、さらに、適度な酸素透過度を有するために、食品包装袋50を窒素置換しなくとも、内容物である食品の鮮度が十分に保持されるというものである。 In the present invention, the oxygen permeability of the food packaging sheet 10 is 20 cc / m 2 · day · atm or more and 250 cc / m 2 · day · atm (23 ° C., 90% RH) or less, and the second layer. When the thickness of 12 is 3 μm or more and 30 μm or less, the food packaging sheet 10 obtains appropriate high sealing performance, flexibility, and transparency, so when food is put into the food packaging bag 50 and deaerated, The food packaging bag 50 is not damaged when pressure is applied, and furthermore, since it has an appropriate oxygen permeability, the freshness of the food that is the content is sufficient even if the food packaging bag 50 is not replaced with nitrogen. It is to be retained.
以上、本発明の食品包装用シート、食品包装容器および食品包装体の実施形態について説明したが、本発明は、これらに限定されるものではない。 As mentioned above, although embodiment of the sheet | seat for food packaging of this invention, a food packaging container, and a food packaging body was demonstrated, this invention is not limited to these.
例えば、本発明の食品包装用シート、食品包装容器および食品包装体を構成する各部は、同様の機能を発揮し得る任意の構成のものと置換することができる。また、任意の構成物が付加されていてもよい。 For example, each part which comprises the sheet | seat for food packaging of this invention, a food packaging container, and a food packaging body can be substituted with the thing of the arbitrary structures which can exhibit the same function. Moreover, arbitrary components may be added.
また、前記実施形態では、食品用包装袋は、2枚の食品包装用シートを重ね合わせて袋状に形成したものとして説明したが、これに限定されず、例えば、1枚の食品包装用シートを2つに折り重ね、対向する2辺を接合することにより袋状にしたものであってもよい。なお、1枚の食品包装用シートを2つに折り重ねて食品包装袋を形成した場合には、折り曲げた部分を境にして、一方の面を第1のシートとし、他方の面を第2のシートとして用いることとする。また、縦ピロー機等、自動包装機で製袋したものでも良い。 Moreover, in the said embodiment, although the food packaging bag demonstrated as what formed two sheets for food packaging on the bag shape, it is not limited to this, For example, one sheet for food packaging May be formed into a bag shape by folding the two into two and joining two opposing sides. When a food packaging bag is formed by folding a single food packaging sheet into two, one side is the first sheet and the other side is the second, with the folded portion as a boundary. It will be used as a sheet. Further, a bag made by an automatic packaging machine such as a vertical pillow machine may be used.
また、食品用包装袋としては、例えば、ガゼット袋や台形袋等の形態の袋であってもよく、さらには、トレー、カップ等に食品を充填し、これを食品用包装袋で包装する形態のものであってもよい。 In addition, the food packaging bag may be, for example, a bag in the form of a gusset bag or a trapezoidal bag, and further, a form in which food is filled in trays, cups, etc., and this is packed in a food packaging bag. It may be.
また、前記実施形態では、食品包装袋は、全体が食品包装用シートで構成されているものであったが、食品包装袋は、その全体が食品包装用シートで構成されていなくてもよい。例えば、食品包装袋は、第2の層を有する食品包装用シートと、第2の層を有さない第1の層のみで構成されたシートとを組み合わせたものであってもよい。 Moreover, in the said embodiment, although the food packaging bag was entirely comprised with the sheet | seat for food packaging, the whole food packaging bag does not need to be comprised with the sheet | seat for food packaging. For example, the food packaging bag may be a combination of a food packaging sheet having a second layer and a sheet composed of only the first layer not having the second layer.
また、上記実施形態では、第1の層11の片側に第2の層12が積層された例について説明したが、第2の層12は、第1の層11の両側に積層してもよい。 In the above embodiment, the example in which the second layer 12 is stacked on one side of the first layer 11 has been described. However, the second layer 12 may be stacked on both sides of the first layer 11. .
以下に実施例により本発明をさらに詳細に説明する。但し、本発明は以下の実施例により何ら制限されるものではない。なお、以下の実施例、比較例に記載されている%及び部は、質量%及び質量部を表わす。 Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited by the following examples. In addition,% and part described in the following examples and comparative examples represent mass% and mass part.
<食品包装袋用シートの作成>
以下の実施例、比較例で示される原料を用いて、押出ラミネーションで多層フィルムを製造した。
<Creation of food packaging bag sheet>
Using the raw materials shown in the following examples and comparative examples, multilayer films were produced by extrusion lamination.
得られた食品包装用シートは、いずれも透明(ヘイズ10%以下:JIS K7105準拠)であった。 The obtained food packaging sheets were all transparent (haze 10% or less: JIS K7105 compliant).
(実施例1)
第1の層の原料として、厚み16μmのポリエチレンテレフタレートフィルム(フタムラ化学株式会社、FE2001)を用いた。
Example 1
As a raw material of the first layer, a polyethylene terephthalate film (Futamura Chemical Co., Ltd., FE2001) having a thickness of 16 μm was used.
第2の層の原料として、低密度ポリエチレン(宇部丸善ポリエチレン株式会社、UBEポリエチレンL719)に防曇剤マスターバッチ(理研ビタミン株式会社、リケマスターEAR−5)を7対1の比率で配合したものを用いた。 As a raw material for the second layer, a low-density polyethylene (Ube Maruzen Polyethylene Co., Ltd., UBE Polyethylene L719) blended with an antifogging agent masterbatch (RIKEN Vitamin Co., Ltd., Riquete Master EAR-5) in a ratio of 7: 1. Was used.
上記原料を用いて総厚み31μm、第2の層の厚み15μmの食品包装用シートを製造した。 A food packaging sheet having a total thickness of 31 μm and a second layer thickness of 15 μm was produced using the above raw materials.
<食品包装袋の作製>
上記で得られた食品包装用シートの一部を切りとり、互いに寸法が等しい2枚の四角形状のシート(第1のシートおよび第2のシート)を用意した。その後、第1のシートおよび第2のシートを、それぞれの第2の層が内側になるように、互いの各辺同士を重ね合わせ、3辺をヒートシールにより融着した。これにより、内寸170×180mmの食品包装袋を作製した。
<Production of food packaging bags>
A part of the food packaging sheet obtained above was cut out to prepare two rectangular sheets (first sheet and second sheet) having the same dimensions. Thereafter, the first sheet and the second sheet were overlapped with each other so that the respective second layers were inside, and the three sides were fused by heat sealing. As a result, a food packaging bag having an inner size of 170 × 180 mm was produced.
この食品包装用シートの厚み、第2の層の厚み、酸素透過量、およびこの食品包装用シートより得られた食品包装袋の食品保存性を測定した。 The thickness of the food packaging sheet, the thickness of the second layer, the oxygen permeation amount, and the food preservability of the food packaging bag obtained from the food packaging sheet were measured.
(実施例2)
第2の層として、厚み5μmの低密度ポリエチレン層を設けた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Example 2)
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a low-density polyethylene layer having a thickness of 5 μm was provided as the second layer, and physical properties were measured.
(実施例3)
第2の層の原料として、厚み20μmの低密度ポリエチレン層を設けた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Example 3)
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a low-density polyethylene layer having a thickness of 20 μm was provided as a raw material for the second layer, and physical properties were measured.
(実施例4)
第1の層の原料として、厚み12μmのポリエチレンテレフタレートフィルムを用いた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
Example 4
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a polyethylene terephthalate film having a thickness of 12 μm was used as a raw material for the first layer, and physical properties were measured.
(実施例5)
第2の層の原料として、厚み30μmの低密度ポリエチレン層を設けた以外は実施例4と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Example 5)
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 4 except that a low-density polyethylene layer having a thickness of 30 μm was provided as a raw material for the second layer, and physical properties were measured.
(実施例6)
第2の層の原料として、防曇剤マスターバッチ(理研ビタミン株式会社、リケマスターPAR−380)をポリプロピレン(住友化学株式会社、住友ノーブレンFS2011DG2)に対して5:1の比率で配合した厚み30μmのポリプロピレン層を設けた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Example 6)
As a raw material for the second layer, an antifogging agent master batch (RIKEN VITAMIN Co., Ltd., Riquete Master PAR-380) was blended at a ratio of 5: 1 with respect to polypropylene (Sumitomo Chemical Co., Ltd., Sumitomo Nobrene FS2011DG2). A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that the polypropylene layer was provided, and the physical properties were measured.
(実施例7)
第1の層の原料として、厚み15μmの二軸延伸ナイロンフィルム(ユニチカ株式会社、エンブレムONBC)を用いた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Example 7)
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a biaxially stretched nylon film (Unitika Ltd., Emblem ONBC) having a thickness of 15 μm was used as the raw material for the first layer. Was measured.
(比較例1)
第1の層の原料として、厚み20μmの二軸延伸ポリプロピレンフィルム(東洋紡株式会社、パイレンフィルム−OTP2102)を用いた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Comparative Example 1)
As a raw material for the first layer, a food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a biaxially stretched polypropylene film (Toyobo Co., Ltd., Pyrene Film-OTP2102) having a thickness of 20 μm was used. Physical property values were measured.
(比較例2)
第2の層の原料として、厚み50μmのポリプロピレン層を設けた以外は実施例1と同様にして食品包装用シートおよび食品包装袋を作成し、物性値を測定した。
(Comparative Example 2)
A food packaging sheet and a food packaging bag were prepared in the same manner as in Example 1 except that a polypropylene layer having a thickness of 50 μm was provided as a raw material for the second layer, and physical properties were measured.
<測定方法>
(食品包装用シートの厚み)
食品包装用シートの厚みは、連続厚み測定機フィルムテスターS−2270(株式会社フジワーク社製)で測定した。試験片の幅は、50mm、測定時のフィルムの送り速度は、1.5m/分とした。
<Measurement method>
(Thickness of food packaging sheet)
The thickness of the sheet for food packaging was measured with a continuous thickness measuring device film tester S-2270 (manufactured by Fuji Work Corporation). The width of the test piece was 50 mm, and the film feed rate during measurement was 1.5 m / min.
(食品包装用シートの第2の層の厚み)
食品包装用シートの第2の層の厚みは、食品包装用シートの断面を観察して、第2の層の厚みを測定した。または、食品包装用シートの断面を観察して、食品包装用シート全体に対する第2の層の比率から、第2の層の厚みを算出した。
(The thickness of the second layer of the food packaging sheet)
The thickness of the 2nd layer of the sheet | seat for food packaging observed the cross section of the sheet | seat for food packaging, and measured the thickness of the 2nd layer. Or the cross section of the sheet | seat for food packaging was observed, and the thickness of the 2nd layer was computed from the ratio of the 2nd layer with respect to the whole sheet | seat for food packaging.
(酸素透過量)
樹脂フィルムの酸素透過量(酸素透過度)は、JIS7126Bに規格化されているモコン法(23℃、90%RH)より測定した。
(Oxygen transmission rate)
The oxygen permeation amount (oxygen permeability) of the resin film was measured by the Mokon method (23 ° C., 90% RH) standardized in JIS 7126B.
(カットレタスの保管試験)
上記で得られた内寸170×180mmの食品包装袋内に、カットレタス95gを注入し、上面より、圧力をかけて脱気したのちに、食品包装袋の開口している部分(口部)をヒートシールで密封し、包装体(食品包装体)を得た。
(Cut lettuce storage test)
Inject the cut lettuce 95g into the above-obtained food packaging bag with an internal size of 170 x 180mm, degass it by applying pressure from the top, and then open the mouth of the food packaging bag (mouth) Was sealed with a heat seal to obtain a package (food package).
この包装体を10℃で4日間保管し、カットレタスの変色の有無を確認した。 This package was stored at 10 ° C. for 4 days, and the presence or absence of discoloration of cut lettuce was confirmed.
(食品包装体の厚み測定)
面が平行になるように配置した平板2面に、上記で得られた食品包装体をはさみ、袋が破裂しない程度(300〜500gf)に圧縮して平板の面と面との間の距離を測定した。
(Measurement of food packaging thickness)
Place the food packaging body obtained above on two flat plates placed so that the planes are parallel, and compress the bag so that the bag does not rupture (300-500 gf). It was measured.
各結果を表1に示す。 The results are shown in Table 1.
1 :食品
10 :食品包装用シート
10a :第1のシート
10b :第2のシート
11 :第1の層
12 :第2の層
50 :食品包装袋
52 :シール部
53 :空間
54 :封止部
100 :食品包装体
1: Food 10: Food packaging sheet 10a: First sheet 10b: Second sheet 11: First layer 12: Second layer 50: Food packaging bag 52: Seal part 53: Space 54: Sealing part 100: Food packaging body
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JP2018070248A (en) * | 2016-11-01 | 2018-05-10 | 住友ベークライト株式会社 | Package containing fungus and method of keeping freshness of fungus |
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JP2019006426A (en) * | 2017-06-21 | 2019-01-17 | 旭化成株式会社 | Package of garden stuff, storage device and storage method |
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