JP2016081594A - Water content measuring device for fuel battery - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a water content measuring device for a fuel battery that can surely measure impedance with a simple construction and also can accurately and easily measure the water content of any portion of an electrolytic film/electrode structure.SOLUTION: An impedance measuring device 10 is provided with a first cut-out portion 50a on one surface of an electrolyte film/electrode structure 24, and a first electrode portion 52a is disposed at the first cut-out portion 50a. A second cut-out portion 50b is provided on the other surface of the electrolyte/electrode structure 24, and a second electrode portion 52b is disposed at the second cut-out portion 50b. The first electrode portion 52a is provided with a first sheet member 54, and the second electrode portion 52b is provided with a second sheet member 56.SELECTED DRAWING: Figure 2

Description

  The present invention relates to a water content measuring device for a fuel cell that is incorporated in a fuel cell in which an electrolyte membrane / electrode structure having electrodes provided on both sides of an electrolyte membrane and a separator are stacked, and measures the water content of the electrolyte membrane. .

  For example, a polymer electrolyte fuel cell employs an electrolyte membrane made of a polymer ion exchange membrane. This fuel cell is constructed by sandwiching an electrolyte membrane / electrode structure (MEA) having an anode electrode on one side of the electrolyte membrane and a cathode electrode on the other side of the electrolyte membrane with a separator. ing.

  In a fuel cell, it is necessary to accurately grasp the power generation status in order to reliably perform desired power generation. For example, the electrolyte membrane must be moistened to a desired wet state in order to maintain the power generation performance. When the electrolyte membrane is in a dry state, the power generation performance is degraded.

  On the other hand, when the amount of water generated by power generation is large and the water becomes excessive, flooding is likely to occur. For this reason, the channel | path etc. which distribute | circulate reaction gas may be clogged, and there exists a possibility that electric power generation performance may fall. In addition, performance degradation may occur due to a shortage of fuel gas.

  Here, the internal moisture content of the fuel cell can be measured by measuring the impedance of the fuel cell. For example, an AC impedance method is employed in which impedance is measured at a number of points while changing the frequency of the applied sine wave.

  As this type of technology, for example, a fuel cell impedance distribution measuring device disclosed in Patent Document 1 is known. In this impedance distribution measuring apparatus, the fuel cell is divided into a plurality of regions from one port of the anode-side and cathode-side gas flow paths toward the other port, and a separator is formed between the divided regions. Are separated from each other.

  The impedance distribution measuring device supplies fuel gas from one port of the anode-side gas flow channel to the other port and oxidizes from one port of the cathode-side gas flow channel to the other port. Gas supply means for supplying gas is provided. Further, the impedance distribution measuring device includes measuring means for independently measuring the impedance between the divided separators facing each other with the electrolyte membrane sandwiched between the fuel gas and the oxidizing gas supplied by the gas supply means. I have.

Japanese Patent No. 5103813

  In the impedance distribution measuring apparatus, the fuel cell is divided into a plurality of regions, and the separators are divided between the divided regions in a state of being insulated from each other. For this reason, there exists a problem that a structure becomes complicated and manufacturing cost rises.

  The present invention solves this type of problem, and with a simple configuration, the impedance can be reliably measured, and the water content of any part of the electrolyte membrane / electrode structure can be accurately and easily measured. An object of the present invention is to provide a water content measuring device for a fuel cell.

  The present invention relates to a water content measuring device for a fuel cell that is incorporated in a fuel cell in which an electrolyte membrane / electrode structure having electrodes provided on both sides of an electrolyte membrane and a separator are stacked, and measures the water content of the electrolyte membrane. Is. The fuel cell moisture content measuring device includes a first cutout portion provided by cutting out a part of the electrode on one surface of the electrolyte membrane / electrode structure. The fuel cell moisture content measuring apparatus includes a second cutout portion provided by cutting out a part of the electrode on the other surface of the electrolyte membrane / electrode structure.

  The fuel cell moisture content measuring device further includes a first electrode portion disposed in the first notch portion, a second electrode portion disposed in the second notch portion, a first sheet member, and a second sheet member. Yes. One end portion of the first sheet member is electrically connected to the first electrode portion, and the other end portion extends outward from the electrolyte membrane / electrode structure. One end portion of the second sheet member is electrically connected to the second electrode portion, and the other end portion extends outward from the electrolyte membrane / electrode structure. And the alternating current application part is connected to the other end part of the 1st sheet member, and the other end part of the 2nd sheet member.

  Further, in this fuel cell moisture content measuring device, the first electrode portion and the second electrode portion are each provided in a single or a plurality of locations, and are disposed within the electrolyte membrane range of the electrolyte membrane / electrode structure. Is preferred.

  The fuel cell moisture content measuring device according to the present invention is disposed on the first electrode portion disposed on one electrode surface of the electrolyte membrane / electrode structure and on the other electrode surface of the electrolyte membrane / electrode structure. A second electrode part, a first sheet member and a second sheet member are provided.

  One end portion of the first sheet member is electrically connected to the first electrode portion, and the other end portion extends outward from the electrolyte membrane / electrode structure. One end portion of the second sheet member is electrically connected to the second electrode portion, and the other end portion extends outward from the electrolyte membrane / electrode structure. And the alternating current application part is connected to the other end part of the 1st sheet member, and the other end part of the 2nd sheet member.

  Furthermore, in this fuel cell moisture content measuring apparatus, it is preferable that the first sheet member and the second sheet member are provided with AC application wiring and measurement wiring, respectively.

  According to the present invention, on both surfaces of the electrolyte membrane / electrode structure, a first cutout portion and a second cutout portion are provided by cutting out a part of the electrode, and the first electrode is provided in the first cutout portion. The second electrode portion is disposed in the second notch portion while the portion is disposed. For this reason, it is possible to measure impedance at a necessary portion of the electrolyte membrane / electrode structure only by setting the positions of the first notch and the second notch.

  Moreover, according to this invention, the 1st electrode part and the 2nd electrode part are arrange | positioned on both surfaces of electrolyte membrane and an electrode structure. Therefore, it is possible to measure impedance at a necessary portion of the electrolyte membrane / electrode structure.

  Thereby, the impedance can be reliably measured with a simple configuration, and the water content of an arbitrary part of the electrolyte membrane / electrode structure can be accurately and easily measured.

1 is a schematic side view of a fuel cell stack in which an impedance measuring device according to a first embodiment of the present invention is incorporated. It is a principal part disassembled perspective view of the fuel cell for a measurement which comprises the said fuel cell stack. FIG. 3 is a cross-sectional view of the fuel cell taken along line III-III in FIG. 2. It is front explanatory drawing of one surface of the electrolyte membrane and electrode structure which comprises the said fuel cell. It is front explanatory drawing of the other surface of the said electrolyte membrane and electrode structure. It is a partial perspective explanatory view of the impedance measuring device. It is a relationship explanatory drawing of the direct current | flow resistance component of alternating current impedance, and moisture content. It is principal part cross-sectional explanatory drawing of the electrolyte membrane and electrode structure in which the impedance measuring device which concerns on the 2nd Embodiment of this invention was integrated. It is front explanatory drawing of the electrolyte membrane and electrode structure in which the impedance measuring device which concerns on the 3rd Embodiment of this invention was integrated. It is a schematic perspective view of the impedance measuring device. It is front explanatory drawing of the electrolyte membrane and electrode structure in which the impedance measuring device which concerns on the 4th Embodiment of this invention was integrated. It is a schematic perspective explanatory drawing of the impedance measuring device which concerns on the 5th Embodiment of this invention.

  As shown in FIG. 1, an impedance measuring device 10 that is a water content measuring device for a fuel cell according to a first embodiment of the present invention is incorporated in a fuel cell stack 12.

  The fuel cell stack 12 includes at least one measurement fuel cell 14S and a plurality of fuel cells 14, and is configured as, for example, an in-vehicle fuel cell stack. In the fuel cell stack 12, a terminal plate 16a, an insulating plate 18a, and an end plate 20a are disposed at one end of the fuel cell 14 in the stacking direction (arrow A direction). In the fuel cell stack 12, a terminal plate 16b, an insulating plate 18b, and an end plate 20b are disposed at the other end in the stacking direction.

  The terminal plate 16a is accommodated in the insulating plate 18a, and the terminal portion 16at projects to one end side in the stacking direction. The terminal plate 16b is accommodated in the insulating plate 18b, and the terminal portion 16bt protrudes to the other end side in the stacking direction. An external load 22 is connected to the terminal portions 16at and 16bt.

  As shown in FIG. 2, the fuel cell 14 </ b> S includes an electrolyte membrane / electrode structure 24, and a first separator 26 and a second separator 28 that sandwich the electrolyte membrane / electrode structure 24. The first separator 26 and the second separator 28 are constituted by, for example, a metal separator or a carbon separator.

  One end edge of the fuel cell 14S in the arrow B direction (horizontal direction intersecting the arrow A direction) communicates with each other in the direction of arrow A, which is the stacking direction, and the oxidant gas supply communication hole 30a and the cooling medium supply communication hole. 32a and a fuel gas discharge communication hole 34b are provided. The oxidant gas supply communication hole 30a supplies an oxidant gas, for example, an oxygen-containing gas, the cooling medium supply communication hole 32a supplies a cooling medium, and the fuel gas discharge communication hole 34b has a fuel gas, for example, hydrogen. The contained gas is discharged. The oxidant gas supply communication hole 30a, the cooling medium supply communication hole 32a, and the fuel gas discharge communication hole 34b are arranged in the arrow C direction (vertical direction).

  The other end edge of the fuel cell 14S in the direction of arrow B communicates with each other in the direction of arrow A, and a fuel gas supply communication hole 34a, a cooling medium discharge communication hole 32b, and an oxidant gas discharge communication hole 30b extend in the direction of arrow C. Arranged and provided. The fuel gas supply communication hole 34a supplies fuel gas, the cooling medium discharge communication hole 32b discharges the cooling medium, and the oxidant gas discharge communication hole 30b discharges the oxidant gas.

  The electrolyte membrane / electrode structure 24 includes, for example, a solid polymer electrolyte membrane 36 in which a perfluorosulfonic acid thin film is impregnated with water, and a cathode electrode 38 and an anode electrode 40 sandwiching the solid polymer electrolyte membrane 36. Prepare.

  As shown in FIG. 3, the cathode electrode 38 is a porous and made of an electrode catalyst layer 38a joined to one surface of the solid polymer electrolyte membrane 36, a carbon paper or the like disposed on the electrode catalyst layer 38a. A conductive gas diffusion layer 38b is provided. The anode electrode 40 includes an electrode catalyst layer 40a joined to the other surface of the solid polymer electrolyte membrane 36, and a porous and conductive gas diffusion layer made of carbon paper or the like disposed on the electrode catalyst layer 40a. 40b. The electrode catalyst layers 38 a and 40 a are formed, for example, by uniformly applying porous carbon particles having a platinum alloy supported on the surface thereof to both surfaces of the solid polymer electrolyte membrane 36. The electrode catalyst layers 38a and 40a may be formed of multiple layers.

  As shown in FIG. 2, an oxidant gas flow path 42 is provided on the surface 26 a of the first separator 26 facing the electrolyte membrane / electrode structure 24. The oxidant gas flow channel 42 has a plurality of flow channel grooves extending in the arrow B direction, and communicates with the oxidant gas supply communication hole 30a and the oxidant gas discharge communication hole 30b. A cooling medium flow path 44 is provided between the surface 26 b of the first separator 26 and the surface 28 b of the second separator 28.

  A fuel gas channel 46 is provided on a surface 28 a of the second separator 28 facing the electrolyte membrane / electrode structure 24. Similar to the oxidant gas flow path 42, the fuel gas flow path 46 has a plurality of flow path grooves extending in the direction of arrow B, and communicates with the fuel gas supply communication hole 34a and the fuel gas discharge communication hole 34b. . The first separator 26 is provided with a first seal member 48a, while the second separator 28 is provided with a second seal member 48b.

  As shown in FIGS. 3 and 4, the impedance measuring device 10 is formed by cutting out a part of the anode electrode 40 on one surface of the electrolyte membrane / electrode structure 24, that is, on the surface on the anode electrode 40 side. A first cutout 50a is provided. The first cutout portion 50a is provided by single or plural cutouts of a part of the electrode catalyst layer 40a and the gas diffusion layer 40b, and is disposed within the solid polymer electrolyte membrane 36.

  The first cutout 50a is provided, for example, in the vicinity of the fuel gas supply communication hole 34a and in the vicinity of the fuel gas discharge communication hole 34b, and is preferably disposed at a position close to the outer peripheral end of the anode electrode 40. . This is because it does not affect the flow of fuel gas.

  The first cutout portion 50a has a rectangular shape that is closed or open on one side, but is not limited thereto, and can be set in various shapes such as a polygon, a circle, and an ellipse. . The number and installation positions of the first notches 50a can be variously changed. For example, the first notches 50a may be provided in the vicinity of the oxidant gas supply communication hole 30a and in the vicinity of the oxidant gas discharge communication hole 30b.

  The first electrode portion 52 a is disposed integrally with the solid polymer electrolyte membrane 36 with a gap in the first cutout portion 50 a without being in contact with the anode electrode 40. That is, the first electrode portion 52 a is configured in an island shape independently of the anode electrode 40. This is because the first electrode parts 52a are insulated from each other. For example, the first electrode portion 52a uses porous carbon particles having platinum or platinum alloy constituting the catalyst layer supported on the surface thereof.

  As shown in FIGS. 3 and 5, the impedance measuring apparatus 10 is formed by cutting out a part of the cathode electrode 38 on the other surface of the electrolyte membrane / electrode structure 24, that is, on the surface on the cathode electrode 38 side. Single or plural second notches 50b are provided. A plurality of the second cutout portions 50b are provided by cutting out part of the electrode catalyst layer 38a and the gas diffusion layer 38b, and are within the range of the solid polymer electrolyte membrane 36, preferably the first cutout portion 50b. It arrange | positions in the position which overlaps seeing from the lamination direction with the part 50a. Note that the first cutout portion 50a and the second cutout portion 50b do not have to be disposed at the same position with the solid polymer electrolyte membrane 36 interposed therebetween, and it is sufficient that at least a part thereof overlaps.

  The second cutout portion 50b is configured in the same manner as the first cutout portion 50a and has a rectangular shape. However, the second cutout portion 50b is not limited to this, and has various shapes such as a polygon, a circle, and an ellipse. Can be set. The number and installation position of the second cutout portions 50b can be variously changed.

  In the second notch 50b, the second electrode 52b is disposed integrally with the solid polymer electrolyte membrane 36 with a gap in a state where it is not in contact with the cathode electrode 38. That is, the second electrode portion 52 b is configured in an island shape independently of the cathode electrode 38. This is to insulate the second electrode parts 52b from each other. The second electrode portion 52b uses, for example, porous carbon particles having platinum or platinum alloy constituting the catalyst layer supported on the surface.

  The impedance measuring apparatus 10 includes a first sheet member 54 having one end electrically connected to the first electrode portion 52 a and the other end extending outward from the electrolyte membrane / electrode structure 24. The impedance measuring apparatus 10 further includes a second sheet member 56 having one end portion electrically connected to the second electrode portion 52 b and the other end portion extending outward from the electrolyte membrane / electrode structure 24. .

  As shown in FIGS. 3 and 6, the first sheet member 54 has an AC application wiring 58 a and a measurement wiring 58 b disposed between the strip-shaped insulating films 54 a and 54 b. The insulating films 54a and 54b are preferably electrically insulating and pass gas or water vapor but not liquid water. The insulating films 54a and 54b are, for example, polyimide (PI), polyethylene naphthalate, polytetrafluoroethylene (PTFE), liquid crystal polymer (LCP), polyphenylene sulfide (PPS), polyethylene terephthalate (PET), fluorine-based electrolyte membrane or carbonized. It is formed of a hydrogen-based electrolyte membrane or the like.

  As shown in FIG. 3, the insulating film 54a is configured to be shorter than the insulating film 54b, the AC application wiring 58a and the measurement wiring 58b extend forward from the front end of the insulating film 54a, and the first electrode portion. 52a is connected (contacted). A filler 59a that is a liquid electrolyte or a liquid resin is provided between the tip of the insulating film 54a and the tip of the solid polymer electrolyte membrane 36. The insulating film 54b preferably protrudes outward from the AC application wiring 58a and the measurement wiring 58b. In order to improve the measurement accuracy, it is preferable to separate the AC applying wiring 58a and the measuring wiring 58b.

  As shown in FIGS. 3 and 6, the second sheet member 56 has an AC application wiring 60 a and a measurement wiring 60 b disposed between the strip-shaped insulating films 56 a and 56 b. The insulating films 56a and 56b are preferably electrically insulative and pass gas or water vapor, but not liquid water. The insulating films 56a and 56b are, for example, polyimide (PI), polyethylene naphthalate, polytetrafluoroethylene (PTFE), liquid crystal polymer (LCP), polyphenylene sulfide (PPS), polyethylene terephthalate (PET), fluorine-based electrolyte membrane, or carbonized. It is formed of a hydrogen-based electrolyte membrane or the like.

  As shown in FIG. 3, the insulating film 56a is configured to be shorter than the insulating film 56b, the AC application wiring 60a and the measurement wiring 60b extend forward from the tip of the insulating film 56a, and the second electrode portion. 52b is connected (contacted). A filler 59b that is a liquid electrolyte or a liquid resin is provided between the tip of the insulating film 56a and the tip of the solid polymer electrolyte membrane 36. It is preferable that the insulating film 56b protrudes outward from the AC application wiring 60a and the measurement wiring 60b. In order to improve the measurement accuracy, it is preferable to separate the AC application wiring 60a and the measurement wiring 60b.

  As shown in FIG. 6, the first electrode portion 52 a and the second electrode portion 52 b can sandwich the solid polymer electrolyte membrane 36 on one end portion side of the first sheet member 54 and one end portion side of the second sheet member 56. In this way, the other end portions are separated from each other and exposed to the outside, and the other end portions are integrated (welded) by thermocompression bonding or the like.

  The other end portions of the first sheet member 54 and the second sheet member 56 are integrated (welded) to each other by thermocompression bonding or the like, and are connected to the connector 62. The connector 62 is connected to the controller 66 via the cable 64. The controller 66 includes an AC voltage / current application unit 68, a voltage measurement unit 70, and a current measurement unit 72. As shown in FIG. 1, the AC application wires 58 a and 60 a are connected to the AC voltage / current application unit 68, while the measurement wires 58 b and 60 b are connected to the voltage measurement unit 70 and the current measurement unit 72. . In the controller 66, the method of applying an alternating current is not limited to voltage or current, and the selection of whether to control the current or the voltage by the measurement method is performed.

  As shown in FIG. 1, the fuel cell 14 includes an electrolyte membrane / electrode structure 24, and a first separator 26 and a second separator 28 that sandwich the electrolyte membrane / electrode structure 24. In the fuel cell 14, the same components as those in the fuel cell 14S are denoted by the same reference numerals, and detailed description thereof is omitted. Substantially, the fuel cell 14 has the same configuration as the fuel cell 14S except that the impedance measuring device 10 is not incorporated.

  The operation of the fuel cell stack 12 configured as described above will be described below.

  As shown in FIG. 2, an oxidant gas such as an oxygen-containing gas is supplied to the oxidant gas supply communication hole 30a, and a fuel gas such as a hydrogen-containing gas is supplied to the fuel gas supply communication hole 34a. Further, a coolant such as pure water or ethylene glycol is supplied to the coolant supply passage 32a.

  The oxidant gas is introduced into the oxidant gas flow path 42 provided in the first separator 26 and moves along the cathode electrode 38 constituting the electrolyte membrane / electrode structure 24. On the other hand, the fuel gas supplied to the fuel gas supply communication hole 34 a is introduced into the fuel gas flow path 46 of the second separator 28 and moves along the anode electrode 40 constituting the electrolyte membrane / electrode structure 24.

  Therefore, in each electrolyte membrane / electrode structure 24, the oxidant gas supplied to the cathode electrode 38 and the fuel gas supplied to the anode electrode 40 are consumed by an electrochemical reaction in the electrode catalyst layers 38a and 40a. Power generation is performed.

  Next, the oxidant gas supplied to and consumed by the cathode electrode 38 is discharged to the oxidant gas discharge communication hole 30b. Similarly, the fuel gas consumed by being supplied to the anode electrode 40 is discharged to the fuel gas discharge communication hole 34b.

  Further, the cooling medium supplied to the cooling medium supply communication hole 32 a is introduced into the cooling medium flow path 44 between the first separator 26 and the second separator 28. The cooling medium cools the electrolyte membrane / electrode structure 24 and then is discharged into the cooling medium discharge communication hole 32b.

  At the time of the above power generation, as shown in FIG. 1, the controller 66 causes the external load 22 to output a direct current (may be an alternating current or a voltage in impedance measurement) from the fuel cell stack 12. An alternating current or voltage is superimposed on the first electrode portion 52a and the second electrode portion 52b by a load (not shown) different from the external load 22 from the controller 66.

  For this reason, the voltage measuring unit 70 measures the alternating current response voltage with respect to the alternating current, while the current measuring unit 72 measures the alternating current. Accordingly, the AC impedance between the first electrode portion 52a and the second electrode portion 52b is calculated from the measured AC voltage and AC current. Thereby, it becomes possible to detect the alternating current impedance of the local site in the electrode surface of the fuel cell 14S.

  Based on the detected AC impedance, a DC resistance component of the AC impedance is calculated. Here, the AC impedance depends on the moisture content of the solid polymer electrolyte membrane 36. As shown in FIG. 7, the resistance value decreases as the humidity (high RH) (high water content) decreases, and the resistance value increases as the humidity (low RH) (small water content) decreases. For this reason, it is possible to grasp the water content of the solid polymer electrolyte membrane 36 from the DC resistance component.

  In this case, in the first embodiment, a part of the anode electrode 40 is cut out on one surface of the electrolyte membrane / electrode structure 24 to provide a first cutout portion 50a. On the other surface of the electrolyte membrane / electrode structure 24, a part of the cathode electrode 38 is notched and a second notch 50b is provided. The first electrode portion 52a is disposed in the first cutout portion 50a, while the second electrode portion 52b is disposed in the second cutout portion 50b.

  For this reason, it becomes possible to measure the alternating current impedance in the necessary part of the electrolyte membrane / electrode structure 24 only by setting the positions of the first notch 50a and the second notch 50b.

  Therefore, the AC impedance can be reliably measured with a simple configuration, and the water content of any part of the electrolyte membrane / electrode structure 24 can be accurately and easily measured.

  FIG. 8 is a cross-sectional explanatory view of a main part of an electrolyte membrane / electrode structure 82 in which an impedance measuring device 80 which is a fuel cell moisture content measuring device according to the second embodiment of the present invention is incorporated. In addition, the same referential mark is attached | subjected to the component same as the electrolyte membrane and electrode structure 24 which comprises the impedance measuring device 10 which concerns on 1st Embodiment, and the detailed description is abbreviate | omitted.

  The impedance measuring device 80 includes a first sheet member 84 disposed on one surface side (anode electrode 40 side) of the solid polymer electrolyte membrane 36, and the other surface side (cathode electrode 38) of the solid polymer electrolyte membrane 36. And a second sheet member 86 disposed on the side).

  The first sheet member 84 has an AC applying wire 58a and a measuring wire 58b disposed between the insulating films 84a and 84b, and the AC applying wire 58a and the measuring wire 58b are provided with a first electrode portion 52a. It is done. The second sheet member 86 has an AC application wiring 60a and a measurement wiring 60b disposed between the insulating films 86a and 86b, and a second electrode portion 52b is provided on the AC application wiring 60a and the measurement wiring 60b. It is done.

  The insulating film 84a is formed to be shorter than the insulating film 84b, and the tip portion of the insulating film 84a overlaps the tip portion of the solid polymer electrolyte membrane 36 and is adjacent to the first electrode portion 52a. preferable. The tip of the insulating film 84a is preferably bonded to the solid polymer electrolyte membrane 36, and the insulating film 84a is preferably thinner than the first electrode portion 52a.

  The insulating film 86a is formed to be shorter than the insulating film 86b, and the distal end portion of the insulating film 86a overlaps the distal end portion of the solid polymer electrolyte membrane 36 and is adjacent to the second electrode portion 52b. preferable. The tip of the insulating film 86a is preferably bonded to the solid polymer electrolyte membrane 36, and the insulating film 86a is preferably thinner than the second electrode portion 52b. The first electrode portion 52a is in contact with one surface of the solid polymer electrolyte membrane 36, and the second electrode portion 52b is in contact with the other surface of the solid polymer electrolyte membrane 36. It is preferable that the extended portions of the insulating film 84a and the insulating film 86a are bonded.

  In the second embodiment configured as described above, the AC impedance can be reliably measured with a simple configuration, and the water content of an arbitrary portion of the electrolyte membrane / electrode structure 82 is accurately and easily measured. For example, the same effects as those of the first embodiment can be obtained.

  In the second embodiment, the tip portions of the insulating films 86a and 86b overlap the tip portion of the solid polymer electrolyte membrane 36. However, the present invention is not limited to this. For example, as in the first embodiment, a gap may be provided between the respective leading end portions of the insulating films 86a and 86b and the leading end portion of the solid polymer electrolyte membrane 36, and a filler may be provided in the gap. On the other hand, you may employ | adopt the structure of said 2nd Embodiment for 1st Embodiment.

  FIG. 9 is an explanatory front view of an electrolyte membrane / electrode structure 92 in which an impedance measuring device 90 that is a water content measuring device for a fuel cell according to a third embodiment of the present invention is incorporated. In addition, the same referential mark is attached | subjected to the component same as the electrolyte membrane and electrode structure 24 which comprises the impedance measuring device 10 which concerns on 1st Embodiment, and the detailed description is abbreviate | omitted.

  As shown in FIG. 10, the impedance measuring device 90 includes a first sheet member 94 disposed on one surface side (the anode electrode 40 side) of the solid polymer electrolyte membrane 36 and the other of the solid polymer electrolyte membrane 36. And a second sheet member 96 disposed on the surface side (cathode electrode 38 side).

  The first sheet member 94 has an AC applying wiring 58a disposed between the insulating films 94a and 94b, and a first electrode portion 98a is fixed to the insulating film 94a at the tip of the AC applying wiring 58a. It is done. The second sheet member 96 has an AC applying wiring 60a disposed between the insulating films 96a and 96b, and a second electrode portion 98b is fixed to the insulating film 96b at the tip of the AC applying wiring 60a. It is done.

  The 1st electrode part 98a and the 2nd electrode part 98b are comprised by the electrode etc. which used carbon with which platinum (Pt), platinum, or a platinum alloy is carry | supported. The first sheet member 94 and the second sheet member 96 are integrated at the ends, but may be configured separately.

  As shown in FIG. 9, the electrolyte membrane / electrode structure 92 is not provided with a notch, and for example, the first electrode portion 98a and the second electrode portion 98b constituting the impedance measuring device 90 are: The polymer electrolyte membrane 36 is directly disposed at any position (outside the power generation region) on both surfaces of the solid polymer electrolyte membrane 36. In FIG. 9, two impedance measuring devices 90 are arranged, but may be one or three or more.

  Therefore, in the third embodiment, it is not necessary to provide a notch in the electrolyte membrane / electrode structure 92, and the impedance measuring device 90 can be easily arranged at an arbitrary position. Thereby, impedance measurement can be performed more easily.

  FIG. 11 is an explanatory front view of an electrolyte membrane / electrode structure 100 in which an impedance measuring device 90 that is a water content measuring device for a fuel cell according to a fourth embodiment of the present invention is incorporated. The same components as those of the impedance measuring device 90 and the electrolyte membrane / electrode structure 92 according to the third embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the electrolyte membrane / electrode structure 100, the first electrode portion 98a and the second electrode portion 98b constituting the impedance measuring device 90 are directly arranged at arbitrary positions (within the power generation region) of the anode electrode 40 and the cathode electrode 38. The In FIG. 11, two impedance measuring devices 90 are arranged, but may be one or three or more.

  Therefore, in the fourth embodiment, it is not necessary to provide a notch in the electrolyte membrane / electrode structure 100, and the impedance measuring device 90 can be easily arranged at an arbitrary position. As a result, the same effects as those of the third embodiment can be obtained, for example, impedance measurement can be performed more easily.

  FIG. 12 is a schematic perspective explanatory view of an impedance measuring device 110 which is a water content measuring device for a fuel cell according to a fifth embodiment of the present invention. Note that the same components as those of the impedance measuring apparatus 10 according to the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

  The impedance measuring device 110 includes a first sheet member 112 and a second sheet member 114. In the first sheet member 112, an AC applying wiring 58a and a measuring wiring 58b are disposed between the insulating films 112a and 112b. A first electrode portion 116a is fixed to the insulating film 112a at the tips of the AC application wiring 58a and the measurement wiring 58b. In the second sheet member 114, the AC application wiring 60a and the measurement wiring 60b are disposed between the insulating films 114a and 114b. A second electrode portion 116b is fixed to the insulating film 114b at the tips of the AC application wiring 60a and the measurement wiring 60b.

  The impedance measuring device 110 configured as described above can be used in place of the impedance measuring device 90 described above, and in particular, the AC applying wires 58a and 60a and the measuring wires 58b and 60b are provided separately. Yes. Therefore, a more accurate impedance measurement process is performed.

DESCRIPTION OF SYMBOLS 10, 80, 90, 110 ... Impedance measuring device 12 ... Fuel cell stack 14, 14S ... Fuel cell 24, 82, 92, 100 ... Electrolyte membrane and electrode structure 26, 28 ... Separator 30a ... Oxidant gas supply communication hole 30b ... Oxidant gas discharge communication hole 32a ... Cooling medium supply communication hole 32b ... Cooling medium discharge communication hole 34a ... Fuel gas supply communication hole 34b ... Fuel gas discharge communication hole 36 ... Solid polymer electrolyte membrane 38 ... Cathode electrodes 38a, 40a ... Electrode catalyst layer 38b, 40b ... Gas diffusion layer 40 ... Anode electrode 42 ... Oxidant gas channel 44 ... Coolant medium channel 46 ... Fuel gas channel 48a, 48b ... Seal members 50a, 50b ... Notches 52a, 52b, 98a, 98b, 116a, 116b ... electrode portions 54, 56, 84, 86, 94, 96, 112, 114 ... sheet members 4a, 54b, 56a, 56b, 84a, 84b, 86a, 86b, 94a, 94b, 96a, 96b, 112a, 112b, 114a, 114b ... Insulating films 58a, 60a ... AC application wiring 58b, 60b ... Measurement wiring 59a 59b ... filler 66 ... controller

Claims (4)

A water content measuring device for a fuel cell, which is incorporated in a fuel cell in which an electrolyte membrane / electrode structure provided with electrodes on both sides of the electrolyte membrane and a separator are stacked, and measures the water content of the electrolyte membrane,
A first cutout portion provided on one surface of the electrolyte membrane / electrode structure by cutting out a part of the electrode;
A second cutout portion provided by cutting out a part of the electrode on the other surface of the electrolyte membrane / electrode structure;
A first electrode portion disposed in the first cutout portion;
A second electrode portion disposed in the second notch,
A first sheet member having one end portion electrically connected to the first electrode portion and the other end portion extending outward of the electrolyte membrane / electrode structure;
A second sheet member having one end portion electrically connected to the second electrode portion and the other end portion extending outward of the electrolyte membrane / electrode structure;
An alternating-current applying unit connected to the other end of the first sheet member and the other end of the second sheet member;
A water content measuring device for a fuel cell, comprising: The water content measuring device for a fuel cell according to claim 1, wherein the first electrode portion and the second electrode portion are provided at a single location or at a plurality of locations, respectively.
A water content measuring device for a fuel cell, which is disposed within an electrolyte membrane range of the electrolyte membrane / electrode structure. A water content measuring device for a fuel cell, which is incorporated in a fuel cell in which an electrolyte membrane / electrode structure provided with electrodes on both sides of the electrolyte membrane and a separator are stacked, and measures the water content of the electrolyte membrane,
A first electrode portion disposed on one electrode surface of the electrolyte membrane / electrode structure;
A second electrode portion disposed on the other electrode surface of the electrolyte membrane / electrode structure;
A first sheet member having one end portion electrically connected to the first electrode portion and the other end portion extending outward of the electrolyte membrane / electrode structure;
A second sheet member having one end portion electrically connected to the second electrode portion and the other end portion extending outward of the electrolyte membrane / electrode structure;
An alternating-current applying unit connected to the other end of the first sheet member and the other end of the second sheet member;
A water content measuring device for a fuel cell, comprising:   The fuel cell moisture content measuring device according to any one of claims 1 to 3, wherein the first sheet member and the second sheet member are provided with an AC application wiring and a measurement wiring, respectively. A water content measuring device for a fuel cell.

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