JP2016073940A - Concentration system - Google Patents

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JP2016073940A
JP2016073940A JP2014206753A JP2014206753A JP2016073940A JP 2016073940 A JP2016073940 A JP 2016073940A JP 2014206753 A JP2014206753 A JP 2014206753A JP 2014206753 A JP2014206753 A JP 2014206753A JP 2016073940 A JP2016073940 A JP 2016073940A
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membrane distillation
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distillation unit
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JP6476715B2 (en
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聡志 三輪
Satoshi Miwa
聡志 三輪
岩崎 守
Mamoru Iwasaki
守 岩崎
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Kurita Water Industries Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

PROBLEM TO BE SOLVED: To provide a concentration system for concentration treatment of a large amount of treatment target liquid with a simple system of a vacuum type membrane distillation unit and at a low cost.SOLUTION: A concentration system 1 for a treatment target liquid W has four branch lines 2A of a raw water line 2, which are provided respectively with vacuum type membrane distillation units 3 in parallel. These vacuum type membrane distillation units 3 have raw water chambers that introduce the treatment target liquid W and condensation chambers and makes a vacuum pump 4 as decompression degree measurement means communicate with the condensation chamber side and are provided with vacuum gauges 5 as decompression degree measurement means. Valves 6 for adjusting vacuum degrees are provided between the vacuum pump 4 and the vacuum type membrane distillation units 3 to be capable of controlling inflow amounts of the treatment target liquid W.SELECTED DRAWING: Figure 1

Description

本発明は、真空式膜蒸留ユニットを用いて大量の被処理液を濃縮処理するための濃縮システムに関する。   The present invention relates to a concentration system for concentrating a large amount of liquid to be processed using a vacuum membrane distillation unit.

膜蒸留技術は、海水淡水化、溶媒や油からの脱水などの他、食品プロセス、例えば、果汁や糖液や蜂蜜などの濃縮を想定した用途で、省エネルギー、省スペースの技術として期待されている。特に、真空式膜蒸留ユニットへの関心が、近年、高まっている。   Membrane distillation technology is expected to save energy and save space in applications that assume desalination from seawater, dehydration from solvents and oils, and other food processes such as fruit juice, sugar solution, and honey. . In particular, interest in vacuum membrane distillation units has increased in recent years.

この真空式膜蒸留ユニットは、水を弾く疎水性多孔質膜(水蒸気のみを透過する)を介して、片側に60℃から80℃程度の被処理液を通液する流路(原水室)と、疎水性膜を透過した水蒸気を被処理液と反対側にある凝縮部へ導き凝縮させて蒸留水を得る凝縮室とを単位構造体とし、この単位構造体を複数段、直列に配置してなる。単位構造体の1段目で濃縮された被濃縮液は、直列配置された2段目で更に濃縮され、2段目で濃縮された被処理液は、さらに3段目で濃縮され、というように次々と濃縮され、最終段で濃縮された後回収される。一方、凝縮室は疎水性膜を透過した水蒸気を凝縮させて蒸留水を得るため、被処理液側よりも数度以上低温である。この凝縮室で水蒸気は凝縮して蒸留水となり、濃縮液とは別に回収される。疎水性多孔質膜には、撥水性の高いテフロン(登録商標)樹脂膜が汎用されている。この真空式膜蒸留ユニットとしては、特許文献1、2に示すような技術が公知である。   This vacuum membrane distillation unit has a flow path (raw water chamber) for passing a liquid to be treated at about 60 ° C. to 80 ° C. on one side through a hydrophobic porous membrane that repels water (permeates only water vapor). The water vapor that has passed through the hydrophobic membrane is led to the condensing part on the opposite side of the liquid to be treated and condensed to obtain distilled water as a unit structure, and this unit structure is arranged in multiple stages in series. Become. The concentrated liquid concentrated in the first stage of the unit structure is further concentrated in the second stage arranged in series, the processed liquid concentrated in the second stage is further concentrated in the third stage, and so on. It is concentrated one after another and collected after being concentrated in the final stage. On the other hand, the condensing chamber condenses the water vapor that has passed through the hydrophobic membrane to obtain distilled water, and is therefore at a temperature that is several degrees lower than the liquid to be treated. In this condensing chamber, the water vapor is condensed into distilled water, which is collected separately from the concentrated liquid. As the hydrophobic porous film, a Teflon (registered trademark) resin film having high water repellency is widely used. As this vacuum membrane distillation unit, techniques as disclosed in Patent Documents 1 and 2 are known.

特開2011−173097号公報JP 2011-173097 A 特開2013−212464号公報JP 2013-212464 A

上述したような真空式膜蒸留ユニットは、数十℃から100℃未満の低温の液体を減圧条件下で蒸気化して蒸留濃縮するものであるので、液体温度の他、ユニット内の真空度が蒸留速度に影響するため、ユニットは密閉性の高い材料を用いて密閉性の高い構造及び加工がなされている。真空式膜蒸留ユニットは、逆浸透膜のように、浸透圧の影響はない。また、ユニットの材料を選定する事によって、逆浸透膜に比べて、高温や酸やアルカリにも強くすることができ、さらに金属製蒸留缶に比べて酸やアルカリで錆びず、軽いユニットにできるなどのメリットがある。例えば、疎水性多孔質膜をテフロン(登録商標)樹脂製とし、その他のユニット部分をポリプロピレン樹脂やテフロン(登録商標)樹脂あるいはフッ化ビニリデン樹脂製のものを用いるとともに、各部材を溶着して密閉性を高めて真空式膜蒸留ユニットを構成すればよい。   Since the vacuum membrane distillation unit as described above is for evaporating and condensing a low-temperature liquid of several tens of degrees C. to less than 100.degree. C. under reduced pressure conditions, the degree of vacuum in the unit is distilled in addition to the liquid temperature. In order to influence the speed, the unit has a highly sealed structure and processing using a highly sealed material. A vacuum membrane distillation unit is not affected by osmotic pressure unlike a reverse osmosis membrane. In addition, by selecting the material of the unit, it can withstand high temperatures, acids and alkalis compared to reverse osmosis membranes, and it can be made lighter and less rusted by acids and alkalis than metal distillation cans. There are merits such as. For example, a hydrophobic porous membrane is made of Teflon (registered trademark) resin, and other units are made of polypropylene resin, Teflon (registered trademark) resin or vinylidene fluoride resin, and each member is welded and sealed. What is necessary is just to comprise a vacuum type film | membrane distillation unit by improving property.

上述したようなメリットがあるため、汎用される真空式膜蒸留ユニットは合成樹脂から製作されている。しかしながら、合成樹脂材料は金属材料よりも強度が弱いため、この合成樹脂材料を、しっかりと確実に溶着加工するため、一単位のユニットを大型化するのは容易でなく、一つのユニットで大量の液を濃縮するのは容易でないという問題点があった。このため複数のユニットを安価で、簡便に組み合わせて処理液量を増加させる技術が求められていた。   Because of the advantages as described above, a widely used vacuum membrane distillation unit is made of synthetic resin. However, since the strength of synthetic resin materials is weaker than that of metal materials, it is not easy to increase the size of a single unit in order to securely and reliably weld this synthetic resin material. There was a problem that it was not easy to concentrate the liquid. For this reason, a technique for increasing the amount of processing liquid by combining a plurality of units inexpensively and simply has been demanded.

そこで、図4に示すように真空式膜蒸留ユニットを並列に設けることが行われている。図4において、被処理液Wの濃縮システム31は、原水ライン32が複数(ここでは4本)に分岐した分岐ライン32Aを有していて、それぞれに濃縮手段としての真空式膜蒸留ユニット33が並列に設けられており、原水ライン32の上流側には図示しない加熱手段としての熱交換器が配置されている。そして、これら真空式膜蒸留ユニット33は、被処理液Wを導入する原水室と凝縮室とを有しており、それぞれの真空式膜蒸留ユニット33の凝縮室側には減圧度測定手段としての真空ポンプ34が個別に連通しているとともに、減圧度測定手段としての真空計35が設けられている。そして、分岐ライン32Aには、被処理液Wの流入量の制御手段としてのバルブ36と、真空式膜蒸留ユニット33への被処理液Wの流入量を計測する流量計37とがそれぞれ設けられている。   Therefore, as shown in FIG. 4, vacuum membrane distillation units are provided in parallel. In FIG. 4, the concentration system 31 of the liquid W to be treated has a branch line 32A in which the raw water line 32 is branched into a plurality (here, four), each of which has a vacuum membrane distillation unit 33 as a concentration means. A heat exchanger as a heating means (not shown) is arranged on the upstream side of the raw water line 32. These vacuum membrane distillation units 33 have a raw water chamber into which the liquid W to be treated and a condensation chamber are introduced, and the vacuum membrane distillation unit 33 has a decompression degree measuring means on the condensation chamber side. The vacuum pumps 34 are individually communicated with each other, and a vacuum gauge 35 is provided as a decompression degree measuring unit. The branch line 32A is provided with a valve 36 as a means for controlling the amount of inflow of the liquid W to be processed and a flow meter 37 for measuring the amount of inflow of the liquid W to be processed into the vacuum membrane distillation unit 33. ing.

このように真空式膜蒸留ユニット33を並列に備えた従来の濃縮システムにおいて、被処理液Wは、図示しない熱交換器により所定の温度に加熱され、例えば100℃未満、好ましくは40〜90℃、特に50℃〜80℃程度になるように温度調整され、分岐ライン32Aを経て後段の真空式膜蒸留ユニット33に供給される。   Thus, in the conventional concentration system provided with the vacuum membrane distillation unit 33 in parallel, the liquid W to be processed is heated to a predetermined temperature by a heat exchanger (not shown), and is, for example, less than 100 ° C., preferably 40 to 90 ° C. In particular, the temperature is adjusted to about 50 ° C. to 80 ° C., and then supplied to the vacuum membrane distillation unit 33 at the subsequent stage via the branch line 32A.

このとき、真空式膜蒸留ユニット33の凝縮室を真空ポンプ34により減圧し、その真空状態を真空計35により監視して減圧下に維持しておくことで、被処理液Wの蒸気が凝縮室に引き込まれる。この結果、原水室で濃縮液W1が得られるので、これを排出して回収する。この際、各真空式膜蒸留ユニット33で均質な濃縮液W1を得るために、真空式膜蒸留ユニット33の真空状態を真空計35で監視し、各真空式膜蒸留ユニット33への被処理液Wの流入量を流量計37で確認して、バルブ36の開度を調整して濃縮条件を調整している。   At this time, the condensation chamber of the vacuum membrane distillation unit 33 is depressurized by the vacuum pump 34, and the vacuum state is monitored by the vacuum gauge 35 and maintained under reduced pressure, whereby the vapor of the liquid W to be treated is condensed into the condensation chamber. Be drawn into. As a result, the concentrate W1 is obtained in the raw water chamber, and is discharged and collected. At this time, in order to obtain a homogeneous concentrated solution W1 in each vacuum membrane distillation unit 33, the vacuum state of the vacuum membrane distillation unit 33 is monitored by a vacuum gauge 35, and the liquid to be treated to each vacuum membrane distillation unit 33 is monitored. The inflow amount of W is confirmed with the flow meter 37, and the opening condition of the valve 36 is adjusted to adjust the concentration condition.

このように従来は、各真空式膜蒸留ユニット33から得られる濃縮液W1をほぼ均質なものとするために、流量計37とバルブ36とを組み合わせて、被処理液Wの真空式膜蒸留ユニット33への供給量を調整している。しかしながら、例えば食品プロセスでは、被処理液Wの導電率が極端に低い、被処理液Wの粘度が極端に高い、あるいは微細な縣濁質が多く含まれるなどの状況が日常的であり、比較的安価で汚染の少ない電磁流量計や面積式流量計が適用できないことが多く、各真空式膜蒸留ユニット33への被処理液Wの供給量を簡便に測定でない、という問題点があった。このため、人手で濃縮液量と蒸留水量とデミスタの量を計量するか、あるいは高価で少流量用の流量計、例えばコリオリ式流量計などを適用せざるを得ず、流量測定が煩雑で、大量測定は容易でないという問題点があった。   Thus, conventionally, in order to make the concentrate W1 obtained from each vacuum membrane distillation unit 33 substantially homogeneous, the flow meter 37 and the valve 36 are combined to provide a vacuum membrane distillation unit for the liquid W to be processed. The supply amount to 33 is adjusted. However, in the food process, for example, the conductivity of the liquid W to be processed is extremely low, the viscosity of the liquid W to be processed is extremely high, or a lot of fine suspensions are included. In many cases, an electromagnetic flow meter and an area type flow meter that are inexpensive and less contaminated cannot be applied, and the supply amount of the liquid W to be processed to each vacuum membrane distillation unit 33 cannot be measured easily. For this reason, it is necessary to manually measure the amount of concentrated liquid, the amount of distilled water, and the amount of demister, or to apply an expensive and low flow meter such as a Coriolis flow meter, and the flow measurement is complicated. There was a problem that mass measurement was not easy.

さらに、上述した従来のシステムでは、真空式膜蒸留ユニット33を並列化すると、ユニット33と同数の高価な流量計が必要になり、大幅なコストの増加を伴うため、大量処理への適用は不向きであった。   Furthermore, in the conventional system described above, when the vacuum membrane distillation units 33 are arranged in parallel, the same number of expensive flow meters as the units 33 are required, which is accompanied by a significant increase in cost, and is not suitable for mass processing. Met.

本発明は、上記課題に鑑みてなされたものであり、真空式膜蒸留ユニットを用いて、簡便なシステム及び低コストで大量の被処理液を濃縮処理するための濃縮システムを提供すること目的とする。   The present invention has been made in view of the above problems, and provides a simple system and a concentration system for concentrating a large amount of liquid to be processed at a low cost using a vacuum membrane distillation unit. To do.

上記課題を解決するために、本発明は、被処理液を濃縮する真空式膜蒸留ユニットを2段以上並列に備える濃縮システムであって、前記真空式膜蒸留ユニットが、疎水性多孔質膜により区画された原水部及び凝縮部と、前記凝縮部を減圧状態に維持する減圧手段と、前記凝縮部の減圧状態を計測する減圧度測定手段と、前記真空式膜蒸留ユニットへの被処理液の流入量を制御する制御手段とを有し、前記減圧手段が前記並列の真空式膜蒸留ユニットに共有して設けられており、前記制御手段が前記減圧度測定手段の計測値に基づいて、前記減圧手段による減圧度又は前記原水部への被処理液の流入量を調整可能となっていることを特徴とする濃縮システムを提供する(発明1)。   In order to solve the above problems, the present invention is a concentration system comprising two or more stages of vacuum membrane distillation units for concentrating a liquid to be treated, wherein the vacuum membrane distillation unit comprises a hydrophobic porous membrane. Partitioned raw water section and condensing section, depressurizing means for maintaining the condensing section in a depressurized state, depressurization degree measuring means for measuring the depressurizing state of the condensing section, and the liquid to be processed to the vacuum membrane distillation unit Control means for controlling the inflow amount, the decompression means is provided in common to the parallel vacuum membrane distillation unit, the control means based on the measurement value of the decompression degree measurement means, Provided is a concentration system characterized in that the degree of decompression by the decompression means or the inflow amount of the liquid to be treated into the raw water part can be adjusted (Invention 1).

かかる発明(発明1)によれば、減圧度測定手段により測定した各真空式膜蒸留ユニットの真空度に基づいて、減圧手段による減圧度又は原水部への被処理液の流入量を調整することで、各真空式膜蒸留ユニットから均質な濃縮液を得ることができる。これは、真空式膜蒸留ユニットでは、真空式膜蒸留ユニット内が減圧され、真空度が上がっていることに起因して被処理液が真空式膜蒸留ユニットに吸い込まれるため、真空式膜蒸留ユニットへの被処理液の供給量は、ユニット内の真空度に比例している。この性質を利用することにより、高価な流量計を用いることなく、被処理液の供給量を調整することができる。これにより、真空式膜蒸留ユニットを大量の被処理液を処理するのに好適に適用することができる。   According to this invention (Invention 1), the degree of vacuum of the vacuum membrane distillation unit measured by the degree of vacuum measuring means is adjusted, or the degree of pressure reduction by the pressure reducing means or the amount of inflow of the liquid to be treated into the raw water section is adjusted. Thus, a homogeneous concentrate can be obtained from each vacuum membrane distillation unit. This is because in a vacuum membrane distillation unit, the vacuum membrane distillation unit is depressurized and the liquid to be treated is sucked into the vacuum membrane distillation unit due to the increased vacuum, so the vacuum membrane distillation unit The supply amount of the liquid to be processed is proportional to the degree of vacuum in the unit. By utilizing this property, the supply amount of the liquid to be processed can be adjusted without using an expensive flow meter. Thus, the vacuum membrane distillation unit can be suitably applied to process a large amount of liquid to be processed.

上記発明(発明1)においては、前記制御手段が前記減圧手段と連通しており、前記減圧手段による減圧度を調整可能となっているのが好ましい(発明2)。   In the said invention (invention 1), it is preferable that the said control means is connected with the said pressure reduction means, and the pressure reduction degree by the said pressure reduction means can be adjusted (invention 2).

かかる発明(発明2)によれば、減圧度測定手段により測定した各真空式膜蒸留ユニットの真空度に基づいて、減圧手段に連通した制御手段により減圧手段による減圧度を調整して、各真空式膜蒸留ユニットの真空度を均一化し、被処理液の供給量を均一に制御して各真空式膜蒸留ユニットから均質な濃縮液を得ることができる。この結果、高価な流量計を用いることなく、被処理液の供給量を調整することができる。これにより、真空式膜蒸留ユニットを大量の被処理液を処理するのに好適に適用することができる。   According to this invention (Invention 2), based on the vacuum degree of each vacuum membrane distillation unit measured by the vacuum degree measuring means, the vacuum degree by the vacuum means is adjusted by the control means communicating with the vacuum means, and each vacuum It is possible to obtain a uniform concentrated solution from each vacuum membrane distillation unit by making the degree of vacuum of the membrane distillation unit uniform and uniformly controlling the supply amount of the liquid to be treated. As a result, the supply amount of the liquid to be processed can be adjusted without using an expensive flow meter. Thus, the vacuum membrane distillation unit can be suitably applied to process a large amount of liquid to be processed.

また、上記発明(発明1)においては、前記制御手段が前記真空式膜蒸留ユニットの原水部の導入側に設けられており、前記原水部への被処理液の流入量を調整可能となっているのが好ましい(発明3)。   Moreover, in the said invention (invention 1), the said control means is provided in the introduction side of the raw | natural water part of the said vacuum-type membrane distillation unit, and it becomes possible to adjust the inflow amount of the to-be-processed liquid to the said raw | natural water part. (Invention 3)

かかる発明(発明3)によれば、減圧度測定手段により測定した各真空式膜蒸留ユニットの真空度に基づいて、原水部の導入側に設けられた制御手段により原水部への被処理液の流入量を調整することで、各真空式膜蒸留ユニットの真空度に応じて被処理液の供給量を制御して、各真空式膜蒸留ユニットから均質な濃縮液を得ることができる。この結果、高価な流量計を用いることなく、被処理液の供給量を調整することができる。これにより、真空式膜蒸留ユニットを大量の被処理液を処理するのに好適に適用することができる。   According to this invention (invention 3), based on the degree of vacuum of each vacuum membrane distillation unit measured by the degree of reduced pressure measurement means, the control means provided on the introduction side of the raw water section allows the liquid to be treated to the raw water section. By adjusting the inflow amount, the supply amount of the liquid to be treated can be controlled according to the degree of vacuum of each vacuum membrane distillation unit, and a homogeneous concentrated liquid can be obtained from each vacuum membrane distillation unit. As a result, the supply amount of the liquid to be processed can be adjusted without using an expensive flow meter. Thus, the vacuum membrane distillation unit can be suitably applied to process a large amount of liquid to be processed.

さらに、上記発明(発明1〜3)においては、前記真空式膜蒸留ユニットの前記原水部に導入する前記被処理液を廃熱を利用して加熱する加熱手段を備えるのが好ましい(発明4)。   Furthermore, in the said invention (invention 1-3), it is preferable to provide the heating means which heats the said to-be-processed liquid introduce | transduced into the said raw | natural water part of the said vacuum membrane distillation unit using waste heat (invention 4). .

かかる発明(発明4)によれば、加熱手段の熱源として廃熱を活用することで熱エネルギーの有効利用を図ることができ、一層の省エネルギー化や省コスト化を図ることができるので、環境保全や産業活性化にも有効である。   According to this invention (invention 4), it is possible to effectively use heat energy by utilizing waste heat as a heat source of the heating means, and further energy saving and cost saving can be achieved. It is also effective for industrial revitalization.

本発明の濃縮システムは、減圧度測定手段により測定した各真空式膜蒸留ユニットの真空度に基づいて減圧手段による減圧度又は原水部への流入量を調整することで、真空式膜蒸留ユニットの真空度に応じて被処理液の供給量を制御して、各真空式膜蒸留ユニットから均質な濃縮液を得ることができる。この結果、高価な流量計を用いることなく、被処理液の供給量を調整することができる。これにより、海水淡水化、溶媒や油からの脱水などの他、食品プロセス、例えば、果汁や糖液や蜂蜜などの濃縮など大規模な処理を必要とする工業的な用途において、真空式膜蒸留ユニットを好適に適用することができる。   The concentration system of the present invention adjusts the degree of decompression by the decompression means or the amount of inflow into the raw water section based on the degree of vacuum of each vacuum membrane distillation unit measured by the degree of decompression measurement means, thereby By controlling the supply amount of the liquid to be treated according to the degree of vacuum, a homogeneous concentrated liquid can be obtained from each vacuum membrane distillation unit. As a result, the supply amount of the liquid to be processed can be adjusted without using an expensive flow meter. This enables vacuum membrane distillation in industrial applications that require large-scale processing such as seawater desalination, dehydration from solvents and oils, and food processes such as concentration of fruit juice, sugar solution, and honey. The unit can be suitably applied.

本発明の第一の実施形態に係る濃縮システムを示す概略図である。It is the schematic which shows the concentration system which concerns on 1st embodiment of this invention. 真空式膜蒸留ユニットの一例を示す概略図である。It is the schematic which shows an example of a vacuum type film | membrane distillation unit. 本発明の第二の実施形態に係る濃縮システムを示す概略図である。It is the schematic which shows the concentration system which concerns on 2nd embodiment of this invention. 従来の濃縮システムを示す概略図である。It is the schematic which shows the conventional concentration system.

以下、本発明の一実施形態について添付図面を参照して詳細に説明する。   Hereinafter, an embodiment of the present invention will be described in detail with reference to the accompanying drawings.

図1は、本発明の第一の実施形態に係る濃縮システムを示す概略図である。図1において、被処理液Wの濃縮システム1は、原水ライン2が複数(本実施形態においては4本)に分岐した分岐ライン2Aを有しており、それぞれに濃縮手段としての真空式膜蒸留ユニット3が並列に設けられていて、原水ライン2の上流側には図示しない加熱手段としての熱交換器が配置されている。これら真空式膜蒸留ユニット3は、被処理液Wを導入する原水室と凝縮室とを有しており、凝縮室側には減圧手段としての真空ポンプ4が連通しているとともにと、減圧度測定手段としての真空計5が設けられている。そして、真空ポンプ4と真空式膜蒸留ユニット3との間には、真空ポンプ4による真空度を調整するための制御手段としてのバルブ6が設けられていて、被処理液Wの流入量を制御可能となっている。   FIG. 1 is a schematic diagram showing a concentration system according to a first embodiment of the present invention. In FIG. 1, the concentration system 1 of the liquid W to be processed has branch lines 2A in which the raw water line 2 branches into a plurality (four in the present embodiment), each of which is a vacuum membrane distillation as a concentration means. The units 3 are provided in parallel, and a heat exchanger as heating means (not shown) is arranged on the upstream side of the raw water line 2. These vacuum membrane distillation units 3 have a raw water chamber for introducing the liquid W to be treated and a condensing chamber. A vacuum pump 4 as a depressurizing means communicates with the condensing chamber side. A vacuum gauge 5 is provided as a measuring means. A valve 6 is provided between the vacuum pump 4 and the vacuum membrane distillation unit 3 as a control means for adjusting the degree of vacuum by the vacuum pump 4 to control the inflow amount of the liquid W to be processed. It is possible.

図2は、真空式膜蒸留ユニット3の一例を示している。この真空式膜蒸留ユニット3としては、低温廃熱を利用して図示しない熱交換器により加熱した被処理液Wを疎水性多孔質膜に通過させて、その蒸気を減圧および低温条件下で蒸留または濃縮する膜蒸留技術を用いる。   FIG. 2 shows an example of the vacuum membrane distillation unit 3. The vacuum membrane distillation unit 3 uses a low temperature waste heat to pass a liquid W to be treated heated by a heat exchanger (not shown) through a hydrophobic porous membrane, and distills the vapor under reduced pressure and low temperature conditions. Or use a membrane distillation technique to concentrate.

この真空式膜蒸留ユニット3には、疎水性多孔質膜11が備えられており、この疎水性多孔質膜11により区画されることで原水室12と凝縮室13とが形成されている。原水室12は被処理液Wを導入する原水部の一例であり、凝縮室13は疎水性多孔質膜11を通過した蒸気Sを凝縮する凝縮部の一例である。   The vacuum membrane distillation unit 3 includes a hydrophobic porous membrane 11, and a raw water chamber 12 and a condensing chamber 13 are formed by being partitioned by the hydrophobic porous membrane 11. The raw water chamber 12 is an example of a raw water unit that introduces the liquid W to be treated, and the condensing chamber 13 is an example of a condensing unit that condenses the vapor S that has passed through the hydrophobic porous membrane 11.

疎水性多孔質膜11は、原水室12に導入された被処理液Wの蒸気のみを選択的に通過させる手段の一例である。この疎水性多孔質膜11としては、耐熱性に優れていることからフッ素樹脂製多孔質膜を好適に用いることができる。この疎水性多孔質膜11においては、被処理液Wの蒸気Sのみを透過させ、膜透過蒸気量に対する被処理液Wの浸透圧や粘度の影響を受けにくく、蒸気透過性が高く、被処理液Wの懸濁成分などの濃縮を効率的に行うことができる。   The hydrophobic porous membrane 11 is an example of means for selectively allowing only the vapor of the liquid W to be treated introduced into the raw water chamber 12 to pass through. As the hydrophobic porous membrane 11, a fluororesin porous membrane can be suitably used because of its excellent heat resistance. In this hydrophobic porous membrane 11, only the vapor S of the liquid to be treated W is permeated, hardly affected by the osmotic pressure and viscosity of the liquid W to be treated with respect to the amount of vapor passing through the membrane, has high vapor permeability, and is treated. Concentration of the suspended component of the liquid W can be performed efficiently.

凝縮室13には真空ポンプ14(図1における真空ポンプ4)が接続され、凝縮室13の壁面には冷却部15が備えられている。凝縮室13とともに原水室12が真空ポンプ14により減圧されて減圧状態に維持され、冷却部15は接触する蒸気Sを凝縮する程度の温度に冷却手段(図示せず)により冷却されている。   A vacuum pump 14 (the vacuum pump 4 in FIG. 1) is connected to the condensation chamber 13, and a cooling unit 15 is provided on the wall surface of the condensation chamber 13. The raw water chamber 12 is decompressed by the vacuum pump 14 together with the condensing chamber 13 and maintained in a depressurized state, and the cooling unit 15 is cooled by a cooling means (not shown) to a temperature at which the steam S in contact therewith is condensed.

なお、上記濃縮対象となる被処理液Wとしては、果汁、液糖、蜂蜜などの糖分を含む食品関連溶液が好適である。ここで、被処理液Wは、糖分などの目的とする濃縮成分の初期濃度が10%以下、特に2〜7%程度である。また、海水淡水化、溶媒や油からの脱水などの工業プロセスでのプロセス排出にも好適に適用することができる。   In addition, as the to-be-processed liquid W used as the said concentration object, the food related solution containing sugars, such as fruit juice, liquid sugar, and honey, is suitable. Here, in the liquid W to be treated, the initial concentration of the target concentrated component such as sugar is 10% or less, particularly about 2 to 7%. It can also be suitably applied to process discharge in industrial processes such as seawater desalination and dehydration from solvents and oils.

次に上述したような4台の真空式膜蒸留ユニット3を並列に備えた本実施形態の濃縮システム1の作用について説明する。   Next, the operation of the concentration system 1 of the present embodiment including the four vacuum membrane distillation units 3 as described above in parallel will be described.

まず、被処理液Wは、図示しない熱交換器により所定の温度、例えば100℃未満、好ましくは40〜90℃、特に50℃〜80℃程度になるように温度調整され、分岐ライン2Aを経て後段の真空式膜蒸留ユニット3に供給される。ここで、各真空式膜蒸留ユニット3内は一台の真空ポンプ4により減圧されている。このため被処理液Wは、バルブ6が開成していれば、真空式膜蒸留ユニット3の原水室12内へと吸いこまれる。   First, the temperature of the liquid W to be treated is adjusted to a predetermined temperature, for example, less than 100 ° C., preferably 40 to 90 ° C., particularly about 50 ° C. to 80 ° C. by a heat exchanger (not shown), and then passes through the branch line 2A. It is supplied to the vacuum membrane distillation unit 3 at the subsequent stage. Here, each vacuum membrane distillation unit 3 is decompressed by a single vacuum pump 4. Therefore, the liquid W to be treated is sucked into the raw water chamber 12 of the vacuum membrane distillation unit 3 if the valve 6 is open.

この場合、凝縮室13が減圧状態に維持されるので、蒸気Sを引き込む機能だけでなく、被処理液Wの沸点をより降下させる機能を有する。これにより、被処理液Wから生じる蒸気Sが顕著となり、疎水性多孔質膜11を透過する蒸気量が増大する。この結果、原水室12で濃縮液W1が得られる。つまり、被処理液Wから多くの蒸気Sが凝縮除去されて濃縮液W1に変換されるので、原水室12の被処理液Wが効率的に濃縮される。したがって、原水室12から多くの濃縮液W1が生成され、濃縮液回収ライン16から回収される。一方、蒸気Sは凝縮室13の冷却部15に触れ凝縮して水滴Lが生じる。これにより、冷却部15では蒸気Sが結露して蒸留水W2が蒸留水排出ライン17から排出される。   In this case, since the condensing chamber 13 is maintained in a reduced pressure state, it has not only a function of drawing the steam S but also a function of lowering the boiling point of the liquid W to be processed. Thereby, the vapor | steam S which arises from the to-be-processed liquid W becomes remarkable, and the vapor | steam amount which permeate | transmits the hydrophobic porous membrane 11 increases. As a result, the concentrate W1 is obtained in the raw water chamber 12. That is, since much steam S is condensed and removed from the liquid W to be processed and converted into the concentrated liquid W1, the liquid W to be processed in the raw water chamber 12 is efficiently concentrated. Accordingly, a large amount of concentrated liquid W1 is generated from the raw water chamber 12 and recovered from the concentrated liquid recovery line 16. On the other hand, the vapor S touches the cooling unit 15 of the condensation chamber 13 and condenses, and water droplets L are generated. Thereby, the steam S is condensed in the cooling unit 15, and the distilled water W <b> 2 is discharged from the distilled water discharge line 17.

このような膜蒸留において、被処理液Wを濃縮して濃縮液W1を得る上で、被処理液Wの流路幅および膜面線流速は重要である。流路幅は、被処理液Wを通過させるに有効な流路径などの大きさである。これに対し、膜面線流速は、被処理液Wの流量を装置内の有効断面積で割った値で与えられる線速度であり、見かけ上、被処理液Wの速度である。具体的には、疎水性多孔質膜11の膜面に平行な被処理液Wの平均流速である。   In such membrane distillation, when the liquid W to be processed is concentrated to obtain the concentrated liquid W1, the channel width and the membrane surface line flow rate of the liquid W to be processed are important. The channel width is a size such as a channel diameter effective for passing the liquid W to be processed. On the other hand, the film surface linear velocity is a linear velocity given by a value obtained by dividing the flow rate of the liquid W to be processed by the effective cross-sectional area in the apparatus, and is apparently the velocity of the liquid W to be processed. Specifically, the average flow velocity of the liquid W to be processed is parallel to the membrane surface of the hydrophobic porous membrane 11.

そして、この真空式膜蒸留ユニット3では、被処理液Wの流路幅wが例えば、1[mm]以上、30[mm]以下であればよく、より好ましくは3[mm]以上、20[mm]以下とする。また、被処理液Wの膜面線流速Vは例えば、0.01[m/s]以上、5[m/s]以下とし、より好ましくは0.05[m/s]以上、2[m/s]以下とすればよい。   In the vacuum membrane distillation unit 3, the flow path width w of the liquid W to be processed may be, for example, 1 [mm] or more and 30 [mm] or less, and more preferably 3 [mm] or more and 20 [ mm] or less. Further, the membrane surface flow velocity V of the liquid W to be treated is, for example, 0.01 [m / s] or more and 5 [m / s] or less, more preferably 0.05 [m / s] or more and 2 [m]. / S] or less.

ここで、4台の真空式膜蒸留ユニット3は同一の条件であるのが好ましい。したがって、各真空式膜蒸留ユニット3の高さ位置及び被処理液Wの吸い込み口高さは同一とするのが好ましい。   Here, it is preferable that the four vacuum membrane distillation units 3 have the same conditions. Therefore, the height position of each vacuum membrane distillation unit 3 and the suction port height of the liquid W to be processed are preferably the same.

被処理液Wの原水室12への流入量は、通常は真空式膜蒸留ユニット3の真空度によって決定される。この被処理液Wの原水室12への流入量は、真空式膜蒸留ユニット3の真空度を調節、すなわちバルブ6の開度を調節することによって増減することができる。真空ポンプ4の排気容量は、真空式膜蒸留ユニット3の容積と台数に応じて決定すればよい。   The inflow amount of the liquid W to be treated into the raw water chamber 12 is usually determined by the degree of vacuum of the vacuum membrane distillation unit 3. The amount of the liquid W to be treated flowing into the raw water chamber 12 can be increased or decreased by adjusting the degree of vacuum of the vacuum membrane distillation unit 3, that is, by adjusting the opening of the valve 6. The exhaust capacity of the vacuum pump 4 may be determined according to the volume and the number of vacuum membrane distillation units 3.

具体的には、本実施形態においては、各真空式膜蒸留ユニット3内は共有している一台の真空ポンプ4により減圧されているので、各真空式膜蒸留ユニット3の真空度と被処理液Wの流路長さが同一で真空式膜蒸留ユニット3が同一の条件であれば、各真空式膜蒸留ユニット3間の被処理液Wの吸いこみ力は原則として同一となるので、各真空式膜蒸留ユニット3には同一量の被処理液Wが流入して蒸留濃縮され、同濃度の濃縮液W1と蒸留水W2とを得ることができる。   Specifically, in this embodiment, each vacuum membrane distillation unit 3 is depressurized by a common vacuum pump 4, so the vacuum degree of each vacuum membrane distillation unit 3 and the object to be treated are reduced. If the flow path length of the liquid W is the same and the vacuum membrane distillation unit 3 has the same conditions, the suction force of the liquid W to be treated between the vacuum membrane distillation units 3 is basically the same. The same amount of the liquid W to be treated flows into the vacuum membrane distillation unit 3 and is concentrated by distillation, whereby a concentrated liquid W1 and distilled water W2 having the same concentration can be obtained.

一方、被処理液Wの分岐ライン2Aの長さが各真空式膜蒸留ユニット3毎に異なる場合、被処理液Wの流路2Aの長さによって生じる流路抵抗の差分を考慮して真空計5の測定値が異なるように各真空式膜蒸留ユニット3のバルブ6の開度を調節する。なお、各真空式膜蒸留ユニット3の分岐ライン2Aの配管径が異なることによって生じる差圧分を各真空式膜蒸留ユニット3の真空度差に考慮することはいうまでもない。   On the other hand, when the length of the branch line 2A of the liquid W to be processed is different for each vacuum membrane distillation unit 3, the vacuum gauge is considered in consideration of the difference in flow path resistance caused by the length of the flow path 2A of the liquid W to be processed. The opening degree of the valve 6 of each vacuum membrane distillation unit 3 is adjusted so that the measured value of 5 is different. Needless to say, the difference in the pressure difference caused by the difference in the pipe diameter of the branch line 2 </ b> A of each vacuum membrane distillation unit 3 is considered in the difference in the degree of vacuum of each vacuum membrane distillation unit 3.

上述したようにして制御する複数台(4台)の真空式膜蒸留ユニット3への被処理液Wの流入量とユニット3の真空度との関係は、処理対象である被処理液Wの性状、特に温度と粘度に依存するため、あらかじめ実験により確認しておく。このように並列に接続した真空式膜蒸留ユニット3の真空度が一定になるようにバルブ6を調整することで、各ユニット3に同一量の被処理液Wが流入して蒸留濃縮されることで、それぞれの真空式膜蒸留ユニット3から同濃度の濃縮液W1を得ることができる。そして、この濃縮液W1の濃度もある程度制御することができる。   The relationship between the amount of inflow of the liquid W to be processed and the degree of vacuum of the unit 3 into the plurality of (four) vacuum membrane distillation units 3 controlled as described above is the property of the liquid W to be processed. In particular, since it depends on temperature and viscosity, it is confirmed beforehand by experiment. By adjusting the valve 6 so that the degree of vacuum of the vacuum membrane distillation units 3 connected in parallel in this way is constant, the same amount of liquid W to be treated flows into each unit 3 and is concentrated by distillation. Thus, the concentrated solution W1 having the same concentration can be obtained from each vacuum membrane distillation unit 3. And the density | concentration of this concentrate W1 can also be controlled to some extent.

この真空式膜蒸留ユニット3において、被処理液Wの濃縮は、処理対象である被処理液Wの性状、温度に依存するが、70〜80%程度(容積減少率、以下同じ)の高濃度から40〜70%程度にまで濃縮することができる。したがって、目的とする濃縮率に応じて、真空式膜蒸留ユニット3は必要に応じてさらに直列に多段、例えば、2段〜12段、望ましくは3段〜10段として濃縮することができる。   In this vacuum membrane distillation unit 3, the concentration of the liquid W to be processed depends on the property and temperature of the liquid W to be processed, but it is a high concentration of about 70 to 80% (volume reduction rate, the same applies hereinafter). To about 40-70%. Therefore, depending on the target concentration rate, the vacuum membrane distillation unit 3 can be further concentrated in series as necessary in multiple stages, for example, 2 to 12 stages, preferably 3 to 10 stages.

次に本発明の第二の実施形態に係る濃縮システムについて説明する。図3は第二実施形態に係る濃縮システムを示す概略図である。図3において、被処理液Wの濃縮システム21は、原水ライン22が複数(本実施形態においては4本)に分岐した分岐ライン22Aを有しており、それぞれに濃縮手段としての真空式膜蒸留ユニット23が並列に設けられており、原水ライン22の上流側には図示しない加熱手段としての熱交換器が配置されている。これら真空式膜蒸留ユニット23は、被処理液Wを導入する原水室と凝縮室とを有しており、凝縮室側には減圧手段としての真空ポンプ24が連通しているとともに、減圧度測定手段としての真空計25が設けられている。そして、各分岐ライン22Aの真空式膜蒸留ユニット23の原水室12の導入側には、被処理液Wの流入量の制御手段としてのバルブ26がそれぞれ設けられている。なお、真空式膜蒸留ユニット23としては、前述した第一実施形態と同様に図2に示したものを用いることができる。   Next, a concentration system according to a second embodiment of the present invention will be described. FIG. 3 is a schematic view showing a concentration system according to the second embodiment. In FIG. 3, the concentration system 21 of the liquid W to be treated has branch lines 22A in which the raw water lines 22 are branched into a plurality (four in this embodiment), each of which is a vacuum membrane distillation as a concentration means. Units 23 are provided in parallel, and a heat exchanger as a heating means (not shown) is arranged upstream of the raw water line 22. These vacuum membrane distillation units 23 have a raw water chamber for introducing the liquid W to be treated and a condensing chamber. A vacuum pump 24 as a depressurizing means communicates with the condensing chamber side, and the degree of decompression is measured. A vacuum gauge 25 is provided as a means. And the valve | bulb 26 as a control means of the inflow amount of the to-be-processed liquid W is each provided in the introduction side of the raw | natural water chamber 12 of the vacuum membrane distillation unit 23 of each branch line 22A. As the vacuum membrane distillation unit 23, the one shown in FIG. 2 can be used as in the first embodiment described above.

次に上述したような4台の真空式膜蒸留ユニット23を並列に備えた第二実施形態の濃縮システム1の作用について説明する。   Next, the operation of the concentration system 1 of the second embodiment including the four vacuum membrane distillation units 23 as described above in parallel will be described.

まず、被処理液Wは、図示しない熱交換器により所定の温度、例えば100℃未満、好ましくは40〜90℃、特に50℃〜80℃程度になるように温度調整され、分岐ライン22Aを経て後段の真空式膜蒸留ユニット23に供給される。ここで、真空式膜蒸留ユニット23内は一台の真空ポンプ24により減圧されている。このため被処理液Wは、バルブ26が開成していれば、真空式膜蒸留ユニット23の原水室12内へと吸いこまれる。原水室12の被処理液Wが効率的に濃縮され濃縮液W1が生成され、濃縮液回収ライン16から回収される。一方、蒸気Sは凝縮室13の冷却部15に触れ凝縮して水滴Lが生じる。この結果、冷却部15では蒸気Sが結露して蒸留水W2が蒸留水排出ライン17から排出される。   First, the temperature of the liquid W to be treated is adjusted to a predetermined temperature, for example, less than 100 ° C., preferably about 40 to 90 ° C., particularly about 50 ° C. to 80 ° C. by a heat exchanger (not shown), and then passes through the branch line 22A. It is supplied to the vacuum membrane distillation unit 23 in the subsequent stage. Here, the vacuum membrane distillation unit 23 is depressurized by a single vacuum pump 24. Therefore, the liquid W to be treated is sucked into the raw water chamber 12 of the vacuum membrane distillation unit 23 if the valve 26 is opened. The liquid W to be treated in the raw water chamber 12 is efficiently concentrated to produce a concentrated liquid W1, which is recovered from the concentrated liquid recovery line 16. On the other hand, the vapor S touches the cooling unit 15 of the condensation chamber 13 and condenses, and water droplets L are generated. As a result, the steam S is condensed in the cooling unit 15, and distilled water W <b> 2 is discharged from the distilled water discharge line 17.

ここで、4台の真空式膜蒸留ユニット23は同一の条件であるのが好ましい。したがって、各真空式膜蒸留ユニット23の高さ位置及び被処理液Wの吸い込み口高さは同一とするのが好ましい。   Here, it is preferable that the four vacuum membrane distillation units 23 have the same conditions. Therefore, it is preferable that the height position of each vacuum membrane distillation unit 23 and the suction port height of the liquid W to be processed are the same.

被処理液Wの原水室12への流入量は、通常は真空式膜蒸留ユニット23の真空度によって決定される。そこで、この被処理液Wの原水室12への流入量は、真空式膜蒸留ユニット23の真空度に応じてバルブ26の開度を調節することによって増減させる。なお、真空ポンプ24の排気容量は、真空式膜蒸留ユニット23の容積と台数に応じて決定すればよい。   The inflow amount of the liquid W to be treated into the raw water chamber 12 is usually determined by the degree of vacuum of the vacuum membrane distillation unit 23. Therefore, the amount of the liquid W to be treated flowing into the raw water chamber 12 is increased or decreased by adjusting the opening of the valve 26 in accordance with the degree of vacuum of the vacuum membrane distillation unit 23. The exhaust capacity of the vacuum pump 24 may be determined according to the volume and number of vacuum membrane distillation units 23.

具体的には、本実施形態においては、各真空式膜蒸留ユニット3内は共有している一台の真空ポンプ4により減圧されているので、各真空式膜蒸留ユニット23の真空度と被処理液Wの流路長さが同一で真空式膜蒸留ユニット23は同一の条件であれば、各真空式膜蒸留ユニット23間の被処理液Wの吸いこみ力は原則として同一となるので、各真空式膜蒸留ユニット23には同一量の被処理液Wが流入して蒸留濃縮され、同濃度の濃縮液W1と蒸留水W2とを得ることができる。   Specifically, in this embodiment, each vacuum membrane distillation unit 3 is depressurized by a common vacuum pump 4, so the vacuum degree of each vacuum membrane distillation unit 23 and the processing target are reduced. If the flow path length of the liquid W is the same and the vacuum membrane distillation unit 23 has the same conditions, the suction force of the liquid W to be treated between the vacuum membrane distillation units 23 is basically the same. The same amount of the liquid W to be treated flows into the vacuum membrane distillation unit 23 and is concentrated by distillation, whereby a concentrated liquid W1 and distilled water W2 having the same concentration can be obtained.

一方、被処理液Wの分岐ライン22Aの長さが各真空式膜蒸留ユニット23毎に異なる場合、被処理液Wの分岐ライン22Aの長さによって生じる流路抵抗の差分を考慮して真空計25の測定値が異なるように分岐ライン22Aのバルブ26の開度を調節する。すなわち、真空度が高ければ被処理液Wの流入量が増加するようにバルブ26の開度を高め、低ければ被処理液Wの流入量が減少するように開度を下げる。なお、各真空式膜蒸留ユニット23の分岐ライン22Aの径が異なることによって生じる差圧分を各真空式膜蒸留ユニット23の真空度差に考慮することはいうまでもない。   On the other hand, when the length of the branch line 22A of the liquid W to be processed is different for each vacuum membrane distillation unit 23, the vacuum gauge is considered in consideration of the difference in flow path resistance caused by the length of the branch line 22A of the liquid W to be processed. The opening degree of the valve 26 of the branch line 22A is adjusted so that the 25 measured values are different. That is, when the degree of vacuum is high, the opening degree of the valve 26 is increased so that the inflow amount of the liquid W to be processed increases, and when the degree of vacuum is low, the opening degree is decreased so that the inflow amount of the liquid W to be processed decreases. Needless to say, the difference in the pressure difference caused by the difference in the diameter of the branch line 22 </ b> A of each vacuum membrane distillation unit 23 is taken into account in the difference in the degree of vacuum of each vacuum membrane distillation unit 23.

上述したようにして制御する複数台(4台)の真空式膜蒸留ユニット23への被処理液Wの流入量とユニット23の真空度との関係は、処理対象である被処理液Wの性状、特に温度と粘度に依存するため、あらかじめ実験により確認しておく。このように並列に接続した真空式膜蒸留ユニット23の真空度に応じて被処理液Wの流入量をバルブ26の開度で調整することで、各ユニット23で真空度に応じた被処理液Wが流入して蒸留濃縮されることで、それぞれの真空式膜蒸留ユニット3から同濃度の濃縮液W1を得ることができる。そして、この濃縮液W1の濃度もある程度制御することができる。   The relationship between the amount of inflow of the liquid W to be processed and the degree of vacuum of the units 23 into a plurality of (four) vacuum membrane distillation units 23 controlled as described above is the property of the liquid W to be processed. In particular, since it depends on temperature and viscosity, it is confirmed beforehand by experiment. By adjusting the inflow amount of the liquid W to be processed in accordance with the degree of vacuum of the vacuum membrane distillation units 23 connected in parallel in this way, the liquid to be processed corresponding to the degree of vacuum in each unit 23 is adjusted. As W flows in and is concentrated by distillation, concentrated liquid W1 having the same concentration can be obtained from each vacuum membrane distillation unit 3. And the density | concentration of this concentrate W1 can also be controlled to some extent.

本実施形態のように、バルブ26を被処理液Wの流入側(原水室12の導入側)に設けて、真空度に応じて流入量を調整することで調整してもよい。   Like this embodiment, you may adjust by providing the valve | bulb 26 in the inflow side (introduction side of the raw | natural water chamber 12) of the to-be-processed liquid W, and adjusting the inflow amount according to a vacuum degree.

以上、本発明について説明してきたが、本発明は前記実施形態に限らず種々の変形実施が可能である。第一の実施形態及び第二の実施形態における制御手段としてのバルブ6、26の開閉度は、自動バルブを用いて真空式膜蒸留ユニット23の真空度に対応して自動調節するようにしてもよい。   Although the present invention has been described above, the present invention is not limited to the above-described embodiment, and various modifications can be made. The degree of opening and closing of the valves 6 and 26 as the control means in the first embodiment and the second embodiment may be automatically adjusted according to the degree of vacuum of the vacuum membrane distillation unit 23 using an automatic valve. Good.

なお、蒸留水W2は、必要に応じて、用水、例えば逆浸透膜や膜蒸留ユニットの洗浄水、あるいは希釈水などに用いて、資源の有効利用を図ることができる。   In addition, the distilled water W2 can be used for water, for example, a reverse osmosis membrane, the washing water of a membrane distillation unit, or dilution water as needed, and can use resources effectively.

本発明の濃縮システムによれば、複数の真空式膜蒸留ユニットの真空度に応じて被処理液の供給量を制御して、各真空式膜蒸留ユニットから均質な濃縮液を得ることができる。これにより、海水淡水化、溶媒や油からの脱水などの他、食品プロセス、例えば、果汁や糖液や蜂蜜などの濃縮など大規模な被処理水を処理する必要がある工業的な用途における真空式膜蒸留ユニットの適用性を高めることができる。   According to the concentration system of the present invention, it is possible to obtain a homogeneous concentrate from each vacuum membrane distillation unit by controlling the supply amount of the liquid to be treated according to the degree of vacuum of the plurality of vacuum membrane distillation units. As a result, in addition to seawater desalination, dehydration from solvents and oils, etc., food processing, such as vacuum for industrial applications where large-scale treated water needs to be processed, such as concentration of fruit juice, sugar solution, honey, etc. The applicability of the formula membrane distillation unit can be enhanced.

1,21…濃縮システム
2,22…原水ライン
2A,22A…分岐ライン
3,23…真空式膜蒸留ユニット
4,24…真空ポンプ(減圧手段)
5,25…真空計(減圧度測定手段)
6,26…バルブ(制御手段)
11…疎水性多孔質膜
12…原水室
13…凝縮室
14…真空ポンプ
15…冷却部
W…被処理液
W1…濃縮液
W2…蒸留水
S…蒸気
1, 21 ... Concentration system 2, 22 ... Raw water line 2A, 22A ... Branch line 3, 23 ... Vacuum membrane distillation unit 4, 24 ... Vacuum pump (pressure reduction means)
5, 25 ... Vacuum gauge (pressure reduction measuring means)
6, 26 ... Valve (control means)
DESCRIPTION OF SYMBOLS 11 ... Hydrophobic porous membrane 12 ... Raw water chamber 13 ... Condensing chamber 14 ... Vacuum pump 15 ... Cooling part W ... Liquid W1 ... Concentrated liquid W2 ... Distilled water S ... Steam

Claims (4)

被処理液を濃縮する真空式膜蒸留ユニットを2段以上並列に備える濃縮システムであって、
前記真空式膜蒸留ユニットが、
疎水性多孔質膜により区画された原水部及び凝縮部と、
前記凝縮部を減圧状態に維持する減圧手段と、
前記凝縮部の減圧状態を計測する減圧度測定手段と、
前記真空式膜蒸留ユニットへの被処理液の流入量を制御する制御手段と
を有し、
前記減圧手段が前記並列の真空式膜蒸留ユニットに共有して設けられており、
前記制御手段が前記減圧度測定手段の計測値に基づいて、前記減圧手段による減圧度又は前記原水部への被処理液の流入量を調整可能となっていることを特徴とする濃縮システム。
A concentration system comprising two or more stages of vacuum membrane distillation units for concentrating a liquid to be treated,
The vacuum membrane distillation unit is
Raw water section and condensation section partitioned by a hydrophobic porous membrane;
Pressure reducing means for maintaining the condensing part in a reduced pressure state;
Decompression degree measuring means for measuring the depressurized state of the condensing part,
Control means for controlling the flow rate of the liquid to be treated into the vacuum membrane distillation unit,
The decompression means is shared by the parallel vacuum membrane distillation units,
The concentration system characterized in that the control means can adjust the degree of pressure reduction by the pressure reduction means or the inflow amount of the liquid to be treated into the raw water part based on the measurement value of the pressure reduction degree measurement means.
前記制御手段が前記減圧手段と連通しており、前記減圧手段による減圧度を調整可能となっていることを特徴とする請求項1に記載の濃縮システム。   The concentration system according to claim 1, wherein the control unit communicates with the decompression unit, and the degree of decompression by the decompression unit can be adjusted. 前記制御手段が前記真空式膜蒸留ユニットの原水部の導入側に設けられており、前記原水部への被処理液の流入量を調整可能となっていることを特徴とする請求項1に記載の濃縮システム。   The said control means is provided in the introduction side of the raw | natural water part of the said vacuum-type membrane distillation unit, The inflow amount of the to-be-processed liquid to the said raw | natural water part can be adjusted. Concentration system. 前記真空式膜蒸留ユニットの前記原水部に導入する前記被処理液を廃熱を利用して加熱する加熱手段を備えることを特徴とする請求項1〜3のいずれかに記載の濃縮システム。   The concentration system according to any one of claims 1 to 3, further comprising heating means for heating the liquid to be treated introduced into the raw water portion of the vacuum membrane distillation unit using waste heat.
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