JP2016040380A5 - - Google Patents
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- JP2016040380A5 JP2016040380A5 JP2015224679A JP2015224679A JP2016040380A5 JP 2016040380 A5 JP2016040380 A5 JP 2016040380A5 JP 2015224679 A JP2015224679 A JP 2015224679A JP 2015224679 A JP2015224679 A JP 2015224679A JP 2016040380 A5 JP2016040380 A5 JP 2016040380A5
- Authority
- JP
- Japan
- Prior art keywords
- surface treatment
- treatment agent
- agent according
- group
- nonionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003795 chemical substances by application Substances 0.000 claims 11
- 238000004381 surface treatment Methods 0.000 claims 7
- -1 acrylate ester Chemical class 0.000 claims 6
- 239000003093 cationic surfactant Substances 0.000 claims 5
- 239000002736 nonionic surfactant Substances 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 239000004753 textile Substances 0.000 claims 4
- 150000001412 amines Chemical class 0.000 claims 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- 239000000194 fatty acid Substances 0.000 claims 3
- 150000001298 alcohols Chemical class 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-O 4,5-dihydro-1H-imidazol-1-ium Chemical class C1CN=C[NH2+]1 MTNDZQHUAFNZQY-UHFFFAOYSA-O 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000002519 antifouling agent Substances 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 229920002313 fluoropolymer Polymers 0.000 claims 1
- 239000004811 fluoropolymer Substances 0.000 claims 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 1
- 150000002462 imidazolines Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- 230000002940 repellent Effects 0.000 claims 1
- 239000005871 repellent Substances 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Claims (9)
CH2=CA11−C(=O)−O−A12
[式中、A11は、水素原子またはメチル基であり、
A12は、炭素数18〜30の直鎖または分岐の脂肪族炭化水素基である。]
で示される長鎖(メタ)アクリレートエステル単量体から誘導された繰り返し単位
を有する非フッ素重合体、
(2)ノニオン性界面活性剤およびカチオン性界面活性剤の両方を含み、ノニオン性界面活性剤およびカチオン性界面活性剤の合計量に対し、カチオン性界面活性剤の量が22重量%以上である界面活性剤、ならびに
(3)水を含む液状媒体
を含む水系エマルションである表面処理剤であって、
表面処理剤が含フッ素重合体を含有しない表面処理剤。 (1) (a) Formula:
CH 2 = CA 11 -C (= O) -O-A 12
[In the formula, A 11 represents a hydrogen atom or a methyl group;
A 12 is a linear or branched aliphatic hydrocarbon group having 18 to 30 carbon atoms. ]
A non-fluorine polymer having a repeating unit derived from a long-chain (meth) acrylate ester monomer represented by:
(2) Including both nonionic surfactant and cationic surfactant, the amount of the cationic surfactant is 22% by weight or more based on the total amount of the nonionic surfactant and the cationic surfactant. A surface treatment agent that is an aqueous emulsion containing a surfactant and (3) a liquid medium containing water,
A surface treatment agent in which the surface treatment agent does not contain a fluoropolymer.
カチオン性界面活性剤が、アミン、アミン塩、4級アンモニウム塩、イミダゾリンおよびイミダゾリニウム塩からなる群から選択された少なくとも1種である請求項1または2に記載の表面処理剤。 The nonionic surfactant comprises at least one selected from the group consisting of ethers, esters, ester ethers, alkanolamides, polyhydric alcohols and amine oxides;
The surface treatment agent according to claim 1 or 2, wherein the cationic surfactant is at least one selected from the group consisting of amines, amine salts, quaternary ammonium salts, imidazolines and imidazolinium salts.
i)アルコールと脂肪酸のエステル、
ii)アルコールと脂肪酸のエステルに、アルキレンオキシド(特にエチレンオキシド)を付加した化合物であるエステルエーテル
iii)アルカノールアミド
iv)多価アルコール、および
v)アミンオキシド
からなる群から選択された少なくとも1種の化合物を含有する請求項1〜3のいずれかに記載の表面処理剤。 In addition to ether, which is a nonionic surfactant, a compound having an oxyalkylene group,
i) alcohol and fatty acid esters,
ii) Ester ethers, which are compounds in which alkylene oxide (especially ethylene oxide) is added to esters of alcohol and fatty acid.
iii) Alkanolamide
iv) polyhydric alcohols, and
v) The surface treatment agent according to any one of claims 1 to 3, comprising at least one compound selected from the group consisting of amine oxides.
i)アルコールと脂肪酸のエステル
を含有する請求項1〜4のいずれかに記載の表面処理剤。 In addition to ether, which is a nonionic surfactant, a compound having a polyoxyethylene group,
i) The surface treating agent according to any one of claims 1 to 4, comprising an ester of alcohol and fatty acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015224679A JP6107921B2 (en) | 2013-11-22 | 2015-11-17 | Surface treatment agent |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013241991 | 2013-11-22 | ||
JP2013241991 | 2013-11-22 | ||
JP2015224679A JP6107921B2 (en) | 2013-11-22 | 2015-11-17 | Surface treatment agent |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014235506A Division JP5880668B2 (en) | 2013-11-22 | 2014-11-20 | Water-based surface treatment agent |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2016040380A JP2016040380A (en) | 2016-03-24 |
JP2016040380A5 true JP2016040380A5 (en) | 2016-05-12 |
JP6107921B2 JP6107921B2 (en) | 2017-04-05 |
Family
ID=53179608
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014235506A Active JP5880668B2 (en) | 2013-11-22 | 2014-11-20 | Water-based surface treatment agent |
JP2015224679A Active JP6107921B2 (en) | 2013-11-22 | 2015-11-17 | Surface treatment agent |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014235506A Active JP5880668B2 (en) | 2013-11-22 | 2014-11-20 | Water-based surface treatment agent |
Country Status (5)
Country | Link |
---|---|
JP (2) | JP5880668B2 (en) |
KR (1) | KR101872133B1 (en) |
CN (1) | CN105765025B (en) |
TW (1) | TWI591114B (en) |
WO (1) | WO2015076348A1 (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013224140A1 (en) * | 2013-11-26 | 2015-05-28 | Rudolf Gmbh | Finishing agents with blocked polyisocyanates |
EP3356476B1 (en) | 2015-10-02 | 2021-09-22 | The Chemours Company FC, LLC | Hydrophobic extenders in non-fluorinated surface effect coatings |
JP6839336B2 (en) * | 2016-02-29 | 2021-03-10 | 大原パラヂウム化学株式会社 | Textile processing agents and processing formulations and textile fabrics and textile products treated with them. |
JP6680017B2 (en) * | 2016-03-16 | 2020-04-15 | ダイキン工業株式会社 | Surface treatment agent |
JP6727865B2 (en) * | 2016-03-16 | 2020-07-22 | ダイキン工業株式会社 | Copolymer and surface treatment agent |
JP6949354B2 (en) * | 2016-06-08 | 2021-10-13 | 明成化学工業株式会社 | Fluorine-free water repellent and water repellent processing method, water repellent textile products |
JP6688171B2 (en) * | 2016-06-17 | 2020-04-28 | 日華化学株式会社 | Water repellent composition, water repellent fiber product and method for producing water repellent fiber product |
US10844151B2 (en) * | 2016-09-23 | 2020-11-24 | Huntsman Textile Effects (Germany) Gmbh | Fluorine-free aqueous dispersions for the finishing of textile fabrics |
CN106884327A (en) * | 2017-03-09 | 2017-06-23 | 浙江康德新材料有限公司 | Fabric waterproof composition for treating dispersion liquid |
JP6840385B2 (en) * | 2017-04-21 | 2021-03-10 | 明成化学工業株式会社 | Fluorine-free water repellent and water repellent processing method, water repellent textile products |
JP6870093B2 (en) * | 2017-07-31 | 2021-05-12 | ダイキン工業株式会社 | Water repellent composition |
CN111742031B (en) | 2018-02-20 | 2023-06-30 | 大金工业株式会社 | Surface treating agent |
JP7157307B2 (en) * | 2018-05-11 | 2022-10-20 | ダイキン工業株式会社 | Water and oil repellents and textile products |
CN110820337A (en) * | 2018-08-14 | 2020-02-21 | 苏州黄永源化工有限公司 | Ecological fluorine-free waterproof agent and preparation method thereof |
CN108893892B (en) * | 2018-08-22 | 2020-05-12 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Embroidery cloth and manufacturing method thereof |
WO2020045407A1 (en) * | 2018-08-28 | 2020-03-05 | 国立大学法人 奈良先端科学技術大学院大学 | Water repellent oil repellent agent for fibers and fiber product |
JP7157349B2 (en) * | 2018-09-14 | 2022-10-20 | ダイキン工業株式会社 | Oil resistant agent for paper |
EP3904588A4 (en) * | 2018-12-28 | 2022-10-05 | Daikin Industries, Ltd. | Water repellent composition |
EP4083078A4 (en) * | 2019-12-24 | 2024-01-10 | Mitsui Chemicals Inc | Water repellent composition, method for producing water repellent composition, and textile product |
WO2021187442A1 (en) * | 2020-03-18 | 2021-09-23 | ダイキン工業株式会社 | Non-fluorinated copolymer composition and oil-resistant agent for paper |
JP7039661B2 (en) * | 2020-07-27 | 2022-03-22 | 日華化学株式会社 | Method for manufacturing non-fluorine-based water repellent composition and water-repellent fiber product |
CN114318943A (en) * | 2020-09-30 | 2022-04-12 | 四川赛华睿科技有限责任公司 | Surface treatment method and object obtained by using same |
JP7157270B1 (en) * | 2022-04-04 | 2022-10-19 | 北越コーポレーション株式会社 | AIR FILTER MEDIUM AND MANUFACTURING METHOD THEREOF |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3744035B2 (en) * | 1995-10-27 | 2006-02-08 | 旭硝子株式会社 | Water-dispersed water / oil repellent composition with excellent stability |
JP2002129031A (en) * | 2000-10-30 | 2002-05-09 | Nitto Denko Corp | Aqueous dispersion of polymer and method for producing the same |
RU2354664C2 (en) * | 2003-09-11 | 2009-05-10 | Циба Спешиалти Кемикэлз Холдинг Инк. | Concentrated forms of water-based light-stabilisers made by heterophase polymerisation technique |
JP4996875B2 (en) | 2005-04-28 | 2012-08-08 | 日華化学株式会社 | Water repellent, water repellent processing method and water repellent fiber product |
JP4927760B2 (en) * | 2005-05-09 | 2012-05-09 | ダイキン工業株式会社 | Fluorosilicone and fluorine-containing silicon-containing surface treatment agent |
EP2233633A1 (en) * | 2009-03-28 | 2010-09-29 | Huntsman Textile Effects (Germany) GmbH | Fluorine-free aqueous dispersion for the treatment of textile area-measured material |
CN101838370B (en) * | 2010-02-12 | 2012-03-28 | 长兴化学工业(中国)有限公司 | Aqueous concoction, aqueous polymer emulsion prepared from same and application thereof |
CN104204079B (en) * | 2012-03-23 | 2016-03-23 | 大金工业株式会社 | Water soluble emulsion composite |
-
2014
- 2014-11-20 WO PCT/JP2014/080816 patent/WO2015076348A1/en active Application Filing
- 2014-11-20 JP JP2014235506A patent/JP5880668B2/en active Active
- 2014-11-20 CN CN201480063525.8A patent/CN105765025B/en active Active
- 2014-11-20 KR KR1020167013367A patent/KR101872133B1/en active IP Right Grant
- 2014-11-21 TW TW103140412A patent/TWI591114B/en active
-
2015
- 2015-11-17 JP JP2015224679A patent/JP6107921B2/en active Active
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