JP2016017895A - Sensor and manufacturing method of sensor - Google Patents

Sensor and manufacturing method of sensor Download PDF

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JP2016017895A
JP2016017895A JP2014142014A JP2014142014A JP2016017895A JP 2016017895 A JP2016017895 A JP 2016017895A JP 2014142014 A JP2014142014 A JP 2014142014A JP 2014142014 A JP2014142014 A JP 2014142014A JP 2016017895 A JP2016017895 A JP 2016017895A
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terminal
sensor element
end side
rear end
sensor
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雄次 島崎
Yuji Shimazaki
雄次 島崎
藤田 康弘
Yasuhiro Fujita
康弘 藤田
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Niterra Co Ltd
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NGK Spark Plug Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a sensor and a manufacturing method of the sensor capable of appropriately maintaining a fitting depth of a sensor element into a connection terminal thereby preventing an electrode extraction part of the sensor element from wearing and capable of excellently maintaining an electrical contact between the connection terminal and the electrode extraction part.SOLUTION: In a sensor including: a sensor element 3 formed with an electrode extraction part 3CP on a rear end side; and a connection terminal 91 having a terminal part 93 and a main body part 94 of the rear end side of a terminal part, while the terminal part being fitted into the sensor element, the sensor element is provided with a housing part 3R which is recessed from the inner peripheral surface. The terminal part is provided with a terminal side protrusion 93P accommodated into the housing part and a contact part 93C formed on the tip end side nearer than the terminal side protrusion and brought into contact with the electrode extraction part. One or more places are arranged for a folding part 96a which is folded at a curved line in the direction orthogonal to the direction of the axis O between the terminal part of the connection terminal and the main body part, and a spring part 96 elastically bent in an axial direction is provided.SELECTED DRAWING: Figure 2

Description

本発明は、被検出体の検出を行うセンサ素子の出力を取り出すための接続端子がセンサ素子の後端側に嵌め込まれたセンサ及びセンサの製造方法に関する。   The present invention relates to a sensor in which a connection terminal for taking out an output of a sensor element for detecting a detected object is fitted on the rear end side of the sensor element, and a method for manufacturing the sensor.

従来、被検出体の検出を行うセンサ素子を備えたセンサの一例として、自動車の排気ガスに含まれる酸素の濃度を検出する酸素センサが知られている。図8に示すように、この酸素センサのセンサ素子300としては、有底筒状に形成した固体電解質体の先端側に、固体電解質体を内側と外側から一対の電極で挟むようにして形成した検出部300CSを有するものが知られている(特許文献1)。このようなセンサ素子300の後端側の外周面300Sの表面には、検出部300CSからの検出信号を取り出すための電極取出し部300CPがリード部300CLを介して形成されている。そして、検出部300CSからの検出信号を外部回路に出力するためのリード線に、コネクタ部950を介して接続端子910が接続される。接続端子910はセンサ素子300の後端側に装着され、接続端子910と電極取出し部300CLとが接触により電気的に接続されている。   2. Description of the Related Art Conventionally, an oxygen sensor that detects the concentration of oxygen contained in automobile exhaust gas is known as an example of a sensor that includes a sensor element that detects an object to be detected. As shown in FIG. 8, as the sensor element 300 of this oxygen sensor, a detection unit formed by sandwiching a solid electrolyte body from the inside and the outside from a pair of electrodes on the tip side of the solid electrolyte body formed in a bottomed cylindrical shape. What has 300CS is known (patent document 1). On the surface of the outer peripheral surface 300S on the rear end side of such a sensor element 300, an electrode extraction portion 300CP for extracting a detection signal from the detection portion 300CS is formed via a lead portion 300CL. Then, the connection terminal 910 is connected to the lead wire for outputting the detection signal from the detection unit 300CS to the external circuit via the connector unit 950. The connection terminal 910 is attached to the rear end side of the sensor element 300, and the connection terminal 910 and the electrode extraction part 300CL are electrically connected by contact.

ここで、特許文献1記載のセンサにおいて、センサ素子(酸素センサ素子)300は筒状であり、その後端側に設けた電極取出し部300CPと接続端子910との接触を確実に行えるようにするため、接続端子910に筒状の端子部(把持部)930を設けている。又、端子部930の後端側には頸部960を介して板状の本体部940が接続され、本体部940の後端側に上記コネクタ部950が接続されて接続端子910が構成されている。さらに、接続端子910の後端側にセパレータ1210が配置され、本体部940をセパレータ1210の図示しない挿通孔内に保持すると共に、セパレータの先端向き面1210fが端子部930の後端縁930eに当接している。
そして、センサの組付け時には、セパレータ1210を介して接続端子910の端子部930を軸線O方向の先端側に押圧することで、端子部930を、センサ素子300によって径方向外側へ押し広げながら、センサ素子300の後端側に嵌め込む。嵌め込み後には、端子部930の弾性力によってセンサ素子300が端子部930の内周面に包まれるように把持される形態となるので、接続端子910と電極取出し部300CPとの接触を良好に維持することができる。
Here, in the sensor described in Patent Document 1, the sensor element (oxygen sensor element) 300 has a cylindrical shape, so that the contact between the electrode extraction portion 300CP provided on the rear end side and the connection terminal 910 can be reliably performed. The connection terminal 910 is provided with a cylindrical terminal portion (gripping portion) 930. In addition, a plate-like main body 940 is connected to the rear end side of the terminal portion 930 via a neck portion 960, and the connector portion 950 is connected to the rear end side of the main body portion 940 to form a connection terminal 910. Yes. Further, a separator 1210 is disposed on the rear end side of the connection terminal 910, holds the main body portion 940 in an insertion hole (not shown) of the separator 1210, and the front end surface 1210f of the separator contacts the rear end edge 930e of the terminal portion 930. It touches.
And, when assembling the sensor, by pressing the terminal portion 930 of the connection terminal 910 to the tip end side in the axis O direction via the separator 1210, the sensor element 300 pushes the terminal portion 930 outward in the radial direction, The sensor element 300 is fitted on the rear end side. After the fitting, the sensor element 300 is held by the elastic force of the terminal portion 930 so as to be wrapped by the inner peripheral surface of the terminal portion 930, so that the contact between the connection terminal 910 and the electrode extraction portion 300CP is maintained well. can do.

又、センサ素子300の電極取出し部300CPより後端側に、外周面から凹んだ収容部300Rを設け、且つ端子部930には収容部300R内に収容される突出部930Pを設けている。このため、センサ素子300の後端側へ端子部930を嵌め込む際、突出部930Pが端子部930を押し広げてセンサ素子300の外周面300Sから遠ざけた状態としたまま、端子部930の嵌め込んだ後、所定の嵌め込み深さになったときに収容部300R内に突出部930Pが収容され、接続端子910と電極取出し部300CPとを接触させることができる。これにより端子部930の嵌め込みの際、センサ素子300の外周面300Sの表面に設けられた電極取出し部300CPが端子部930の先端で削られたり、突出部930Pよりも先端側の端子部930に設けた接触部930Cと電極取出し部300CPとが摺擦し摩耗することを防止できる。   Further, a receiving portion 300R that is recessed from the outer peripheral surface is provided on the rear end side of the electrode extraction portion 300CP of the sensor element 300, and a protruding portion 930P that is received in the receiving portion 300R is provided in the terminal portion 930. For this reason, when the terminal portion 930 is fitted to the rear end side of the sensor element 300, the protruding portion 930P pushes the terminal portion 930 away from the outer peripheral surface 300S of the sensor element 300, and the terminal portion 930 is fitted. After the insertion, the protrusion 930P is accommodated in the accommodating portion 300R when the predetermined insertion depth is reached, and the connection terminal 910 and the electrode extraction portion 300CP can be brought into contact with each other. Thus, when the terminal portion 930 is fitted, the electrode extraction portion 300CP provided on the outer peripheral surface 300S of the sensor element 300 is scraped at the tip of the terminal portion 930, or the terminal portion 930 on the tip side of the protrusion portion 930P. It is possible to prevent the provided contact portion 930C and the electrode extraction portion 300CP from rubbing and wearing.

特開2008−298535号公報JP 2008-298535 A

しかしながら、セパレータ1210による接続端子910の押圧力が大きくなり過ぎると、端子部930が所定の位置を超えて先端側へ深く嵌め込まれ、センサ素子300の収容部300Rの先端側に設けた電極取出し部300CPを削ったり摩耗させるおそれがある。また、端子部930の突出部930Pが収容部300Rを乗り越えるほど端子部930が深く押し込まれた場合、端子部930が再び拡径されてしまい、端子部930に設けた接触部930Cと電極取出し部300CPとが離間して電気的接続が不安定になるという問題がある。
従って、本発明は、センサ素子への接続端子の嵌め込み深さを適切に保ち、接続端子がセンサ素子から抜けにくくなり、さらに接続端子の嵌め込みによるセンサ素子の電極取出し部の摩耗を防止すると共に、接続端子と電極取出し部との電気的接触を良好に維持することができるセンサ及びセンサの製造方法の提供を目的とする。
However, if the pressing force of the connection terminal 910 by the separator 1210 becomes too large, the terminal portion 930 is deeply fitted to the distal end side beyond a predetermined position, and the electrode extraction portion provided on the distal end side of the housing portion 300R of the sensor element 300 There is a risk of scraping or wearing 300 CP. In addition, when the terminal portion 930 is pushed deep enough so that the protruding portion 930P of the terminal portion 930 gets over the housing portion 300R, the terminal portion 930 is expanded again, and the contact portion 930C provided in the terminal portion 930 and the electrode extraction portion There is a problem that the electrical connection becomes unstable due to separation from 300 CP.
Therefore, the present invention appropriately maintains the fitting depth of the connection terminal to the sensor element, makes it difficult for the connection terminal to come out of the sensor element, and further prevents wear of the electrode extraction portion of the sensor element due to the fitting of the connection terminal, It is an object of the present invention to provide a sensor and a method for manufacturing the sensor that can satisfactorily maintain electrical contact between a connection terminal and an electrode lead-out portion.

上記課題を解決するため、本発明のセンサは、軸線方向に延び、先端側が閉じられた有底筒状をなすセンサ素子であって、先端側に、被検出体の検出を行うための検出部を有すると共に、後端側の外周面上に、前記検出部の出力を取り出すための電極取出し部が形成されたセンサ素子と、当該センサ素子の後端側の周方向を覆い前記電極取出し部と電気的に接続される端子部と、前記端子部の後端側に接続される板状の本体部とを有し、前記検出部からの検出信号を外部回路に出力する接続端子とを備え、前記端子部が前記センサ素子に嵌め込まれ、前記端子部と前記電極取出し部とが接触するセンサにおいて、前記センサ素子には、前記電極取出し部よりも前記軸線方向の後端側に、外周面から凹んだ収容部が設けられると共に、前記接続端子の前記端子部には、内周面から内向きに突出されつつ前記収容部内に収容される端子側突出部と、前記端子側突出部よりも先端側に形成され、前記電極取出し部と接触する接触部と、が設けられるか、又は、前記センサ素子の前記電極取出し部よりも後端側に、前記電極取出し部の外表面より前記軸線方向と直交する方向の外側に突出する素子側凸部が周方向の少なくとも一部に設けられ、前記端子部の後端縁が前記素子側凸部の先端縁よりも先端側に位置してなり、前記接続端子の前記端子部と前記本体部との間には、前記軸線方向と直交する方向に曲線で折り返す折り返し部を一カ所以上有し、前記軸線方向に弾性的に撓むバネ部が設けられている。   In order to solve the above-described problem, the sensor of the present invention is a sensor element having a bottomed cylindrical shape extending in the axial direction and closed at the tip side, and a detection unit for detecting a detection target at the tip side A sensor element having an electrode extraction part for extracting the output of the detection unit on the outer peripheral surface on the rear end side, and covering the circumferential direction on the rear end side of the sensor element, and the electrode extraction part A terminal part that is electrically connected; and a plate-like main body part connected to a rear end side of the terminal part, and a connection terminal that outputs a detection signal from the detection part to an external circuit, In the sensor in which the terminal portion is fitted into the sensor element and the terminal portion and the electrode extraction portion are in contact with each other, the sensor element has a rear end side in the axial direction with respect to the electrode extraction portion, from an outer peripheral surface. A recessed housing is provided and the connection The terminal portion of the child is formed in a terminal side protruding portion that is protruded inward from an inner peripheral surface and is accommodated in the accommodating portion, and is formed on a tip side of the terminal side protruding portion, and is in contact with the electrode extraction portion An element-side protrusion that protrudes outward from the outer surface of the electrode extraction portion in a direction perpendicular to the axial direction, on the rear end side of the electrode extraction portion of the sensor element. Part is provided in at least a part of the circumferential direction, and the rear end edge of the terminal part is located on the front end side with respect to the front end edge of the element-side convex part, Between them, there is provided a spring portion that has one or more folded portions that are folded back in a direction perpendicular to the axial direction and elastically bends in the axial direction.

このセンサによれば、センサ素子の後端側へ端子部を嵌め込んで電極取出し部と接触させる際、接続端子のバネ部より後端側の本体部への押圧力が大きくなり過ぎても、バネ部の弾性力により押圧力を吸収し、バネ部より先端側の端子部へ過大な押圧力が掛かるのを抑制するので、センサ素子への接続端子の嵌め込み深さを適切に保ち、端子部がそれ以上先端側へ押し込まれて電極取出し部を削ったり摩耗させることを抑制することができる。又、接続端子に端子側突出部を設けた場合に、端子部への押圧力が過大になって端子部が深く嵌め込まれることで、端子部が拡径して接触部と電極取出し部とが離間し、電気的接続が不安定になることをも抑制することができる。
また、端子部に端子側突出部を設け、又はセンサ素子に素子側凸部を設けているので、端子側突出部又は素子側凸部が端子部を押し広げてセンサ素子の外周面から遠ざける、その結果、端子部を外周面に設けられた電極取出し部に接触させないようにして端子部を嵌め込むことができる。さらには、端子側突出部又は素子側凸部は、接続端子がセンサ素子から抜けるのを防止する抜け止め部としても作用する。
According to this sensor, when the terminal portion is fitted to the rear end side of the sensor element and brought into contact with the electrode extraction portion, even if the pressing force to the main body portion on the rear end side from the spring portion of the connection terminal becomes too large, Since the pressing force is absorbed by the elastic force of the spring part and the excessive pressing force is applied to the terminal part on the tip side from the spring part, the fitting depth of the connection terminal to the sensor element is kept appropriately, and the terminal part Can be prevented from being pushed further into the tip side and scraping or wearing the electrode lead-out portion. In addition, when a terminal-side protruding part is provided on the connection terminal, the terminal part is expanded due to excessive pressing force on the terminal part and the terminal part is deeply fitted, so that the contact part and the electrode take-out part are separated. It is possible to suppress separation and electrical connection from becoming unstable.
Moreover, since the terminal side protrusion is provided in the terminal part or the element side convex part is provided in the sensor element, the terminal side protruding part or the element side convex part spreads the terminal part and away from the outer peripheral surface of the sensor element. As a result, the terminal portion can be fitted in such a manner that the terminal portion is not brought into contact with the electrode extraction portion provided on the outer peripheral surface. Furthermore, the terminal-side protruding portion or the element-side convex portion also acts as a retaining portion that prevents the connection terminal from coming off the sensor element.

本発明のセンサは、前記接続端子の前記本体部の少なくとも一部を保持し、前記端子部の後端側に該端子部と離間して配置されるセパレータを備え、前記セパレータを介して前記接続端子を前記軸線方向の先端側に押圧することで、前記端子部が前記センサ素子に嵌め込まれてもよい。
このセンサによれば、センサが備えるセパレータにより接続端子を押圧するので、接続端子を押圧する他部材が不要となり、生産性が向上する。
The sensor of the present invention includes a separator that holds at least a part of the main body portion of the connection terminal and is disposed on the rear end side of the terminal portion so as to be separated from the terminal portion, and the connection via the separator. The terminal portion may be fitted into the sensor element by pressing the terminal toward the distal end side in the axial direction.
According to this sensor, since the connection terminal is pressed by the separator included in the sensor, other members that press the connection terminal are not required, and productivity is improved.

本発明のセンサにおいて、前記本体部には、該本体部から前記軸線方向と直交する方向に突出して前記セパレータの挿通孔に係止される係止部が設けられ、前記バネ部は前記係止部よりも先端側に位置してもよい。
このセンサによれば、端子部の後端側にセパレータを確実に離間させることができ、バネ部の弾性力によりセパレータの押圧力を確実に吸収し、端子部がそれ以上先端側へ押し込まれることをより一層抑制することができる。
In the sensor of the present invention, the main body portion is provided with a locking portion that protrudes from the main body portion in a direction orthogonal to the axial direction and is locked to the insertion hole of the separator, and the spring portion is the locking portion. You may be located in the front end side rather than a part.
According to this sensor, the separator can be reliably separated to the rear end side of the terminal portion, the pressing force of the separator is reliably absorbed by the elastic force of the spring portion, and the terminal portion is pushed further to the front end side. Can be further suppressed.

本発明のセンサの製造方法は、軸線方向に延び、先端側が閉じられた有底筒状をなすセンサ素子であって、先端側に、被検出体の検出を行うための検出部を有すると共に、後端側の外周面上に、前記検出部の出力を取り出すための電極取出し部が形成されたセンサ素子と、当該センサ素子の後端側の周方向を覆い前記電極と電気的に接続される端子部と、前記端子部の後端側に接続される板状の本体部とを有し、前記検出部からの検出信号を外部回路に出力する接続端子と、前記接続端子の前記本体部の少なくとも一部を保持し、前記端子部の後端側に該端子部と離間して配置されるセパレータと、を備えたセンサの製造方法において、前記センサ素子には、前記電極取出し部よりも前記軸線方向の後端側に、外周面から凹んだ収容部が設けられると共に、前記接続端子の前記端子部には、内周面から内向きに突出されつつ前記収容部内に収容される端子側突出部と、前記端子側突出部よりも先端側に形成され、前記電極取出し部と接触する接触部と、が設けられるか、又は、前記センサ素子の前記電極取出し部よりも後端側に、前記電極取出し部の外表面より前記軸線方向と直交する方向の外側に突出する素子側凸部が周方向の少なくとも一部に設けられ、前記接続端子の前記端子部と前記本体部との間には、前記軸線方向と直交する方向に曲線で折り返す折り返し部を一カ所以上有し、前記軸線方向に弾性的に撓むバネ部が設けられており、前記接続端子を保持したセパレータを前記軸線方向の先端側に押圧し、前記端子側突出部が前記収容部内に収容されるよう、又は前記端子部の後端縁が前記素子側凸部の先端縁よりも先端側に位置するように前記端子部を前記センサ素子の後端側に嵌め込み、前記接触部を前記電極と電気的に接続する。   The sensor manufacturing method of the present invention is a sensor element having a bottomed cylindrical shape extending in the axial direction and closed at the distal end side, and has a detection unit for detecting the detected object at the distal end side, A sensor element having an electrode take-out portion for taking out the output of the detection portion on the outer peripheral surface on the rear end side, covers the circumferential direction on the rear end side of the sensor element, and is electrically connected to the electrode. A terminal part and a plate-like main body part connected to the rear end side of the terminal part; a connection terminal for outputting a detection signal from the detection part to an external circuit; and a main body part of the connection terminal. In a method for manufacturing a sensor, comprising: a separator that holds at least a part and is disposed on the rear end side of the terminal portion and spaced apart from the terminal portion. A receiving part that is recessed from the outer peripheral surface is provided on the rear end side in the axial direction. In addition, the terminal portion of the connection terminal is formed on the tip side of the terminal-side protruding portion, the terminal-side protruding portion that is accommodated in the accommodating portion while protruding inward from the inner peripheral surface, A contact portion that comes into contact with the electrode extraction portion, or on the rear end side of the electrode extraction portion of the sensor element, on the outer side in the direction orthogonal to the axial direction from the outer surface of the electrode extraction portion. A protruding element-side convex portion is provided in at least a part of the circumferential direction, and a folding portion that is folded back in a direction perpendicular to the axial direction is provided between the terminal portion of the connection terminal and the main body portion. The spring part which has the above and is elastically bent in the axial direction is provided, the separator holding the connection terminal is pressed to the distal end side in the axial direction, and the terminal side protruding part is accommodated in the accommodating part. Or the end The terminal portion as a rear end edge of the part is positioned at the front end side from the distal end edge of the element-side convex portion fitted into the rear end side of the sensor element, for connecting said contact portion electrically with the electrode.

この発明によれば、センサ素子への接続端子の嵌め込み深さを適切に保ち、接続端子がセンサ素子から抜けにくくなり、さらに接続端子の嵌め込みによるセンサ素子の電極取出し部の摩耗を防止すると共に、接続端子と電極取出し部との電気的接触を良好に維持することができる。   According to the present invention, the fitting depth of the connection terminal to the sensor element is appropriately maintained, the connection terminal is difficult to be removed from the sensor element, and further, the wear of the electrode extraction portion of the sensor element due to the fitting of the connection terminal is prevented. The electrical contact between the connection terminal and the electrode lead-out portion can be maintained well.

本発明の第1の実施形態に係るセンサを軸線方向に沿う面で切断した断面図である。It is sectional drawing which cut | disconnected the sensor which concerns on the 1st Embodiment of this invention in the surface which follows an axial direction. センサ素子及び接続端子の構造を示す斜視図である。It is a perspective view which shows the structure of a sensor element and a connection terminal. 接続端子のセパレータへの保持状態を示す斜視図である。It is a perspective view which shows the holding state to the separator of a connection terminal. バネ部の弾性力により隙間Gを減少させながらセパレータの押圧力を吸収する機構を示す図である。It is a figure which shows the mechanism which absorbs the pressing force of a separator, reducing the clearance gap G by the elastic force of a spring part. センサを製造する態様を示す図である。It is a figure which shows the aspect which manufactures a sensor. 端子部をセンサ素子に嵌め込む過程を示す工程図である。It is process drawing which shows the process of inserting a terminal part in a sensor element. 本発明の第2の実施形態に係るセンサのセンサ素子及び接続端子の構造を示す斜視図である。It is a perspective view which shows the structure of the sensor element and connection terminal of a sensor which concern on the 2nd Embodiment of this invention. 従来のセンサ素子及び接続端子の構造を示す斜視図である。It is a perspective view which shows the structure of the conventional sensor element and a connecting terminal.

以下、本発明の実施形態について説明する。
図1は、本発明の第1の実施形態に係るセンサ100を軸線方向(先端から基端に向かう方向)に沿う面で切断した断面構造を示す。図2はセンサ素子及び接続端子の構造を示す斜視図である。
この実施形態において、センサ100は自動車の排気管内に挿入されて先端(図1の矢印F側)が排気ガス中に曝され、排気ガス中の酸素濃度を検出する酸素センサになっている。センサ素子3は、酸素イオン伝導性の固体電解質体に一対の電極を積層した酸素濃淡電池を構成し、酸素量に応じた検出値を出力する公知の酸素センサ素子である。図3は接続端子91のセパレータ121への保持状態を示す斜視図である。図4はバネ部96の弾性力により隙間Gを減少させながらセパレータ121の押圧力を吸収する機構を示す図である。
なお、図1の下側(矢印F側)をセンサ100の先端側とし、図1の上側をセンサ100の基端側とする。
Hereinafter, embodiments of the present invention will be described.
FIG. 1 shows a cross-sectional structure of the sensor 100 according to the first embodiment of the present invention cut along a plane along the axial direction (direction from the distal end toward the proximal end). FIG. 2 is a perspective view showing the structure of the sensor element and the connection terminal.
In this embodiment, the sensor 100 is an oxygen sensor that is inserted into the exhaust pipe of an automobile and the tip (arrow F side in FIG. 1) is exposed to the exhaust gas to detect the oxygen concentration in the exhaust gas. The sensor element 3 is a known oxygen sensor element that constitutes an oxygen concentration cell in which a pair of electrodes are laminated on an oxygen ion conductive solid electrolyte body and outputs a detection value corresponding to the amount of oxygen. FIG. 3 is a perspective view showing a state in which the connection terminal 91 is held on the separator 121. FIG. 4 is a view showing a mechanism for absorbing the pressing force of the separator 121 while reducing the gap G by the elastic force of the spring portion 96.
Note that the lower side (arrow F side) in FIG. 1 is the distal end side of the sensor 100, and the upper side in FIG. 1 is the proximal end side of the sensor 100.

センサ100は、先端が閉じた略円筒状(中空軸状)のセンサ素子(この例では酸素センサ素子)3を、筒状の金具本体(主体金具)20の内側に挿通して保持するよう組み付けられている。センサ素子3は、先端に向かってテーパ状に縮径する筒状の固体電解質体と、固体電解質体の内周面と外周面にそれぞれ形成された内側電極3B及び外側電極3Cとからなる。そして、センサ素子3の内部空間を基準ガス雰囲気とし、センサ素子3の外面に被検出ガスを接触させてガスの検知を行うようになっている。又、センサ素子3の中空部には丸棒状のヒータ15が挿入され、固体電解質体を活性化温度に昇温するようになっている。さらに、詳しくは後述するが、センサ素子3の後端側に収容部3Rが形成され、外側端子91には収容部3Rに収容される端子側突出部93Pが形成されている。
金具本体20の基端部には、センサ素子3の基端側に設けられたリード線や端子(後述)を保持し、センサ素子3の基端部を覆う筒状の外筒40が接合されている。さらに、センサ素子3の基端側の外筒40内側には、絶縁性で円柱状のセパレータ121が加締め固定されている。一方、センサ素子3先端の検出部はプロテクタ7で覆われている。そして、このようにして製造されたセンサ100の金具本体20の雄ねじ部20dを排気管等のネジ孔に取付けることで、センサ素子3先端の検出部を排気管内に露出させて被検出ガス(排気ガス)を検知している。なお、金具本体20の中央付近には、六角レンチ等を係合するための多角形の鍔部20cが設けられ、鍔部20cと雄ねじ部20dとの間の段部には、排気管に取付けた際のガス抜けを防止するガスケット14が嵌挿されている。
The sensor 100 is assembled so that a substantially cylindrical (hollow shaft-shaped) sensor element 3 (in this example, an oxygen sensor element) 3 having a closed end is inserted and held inside a cylindrical metal fitting body (main metal fitting) 20. It has been. The sensor element 3 includes a cylindrical solid electrolyte body that is tapered toward the tip, and an inner electrode 3B and an outer electrode 3C that are respectively formed on the inner and outer peripheral surfaces of the solid electrolyte body. The internal space of the sensor element 3 is set as a reference gas atmosphere, and the gas to be detected is brought into contact with the outer surface of the sensor element 3 to detect the gas. A round bar heater 15 is inserted into the hollow portion of the sensor element 3 so as to raise the temperature of the solid electrolyte body to the activation temperature. Furthermore, although mentioned later in detail, the accommodating part 3R is formed in the rear end side of the sensor element 3, and the terminal side protrusion part 93P accommodated in the accommodating part 3R is formed in the outer side terminal 91. FIG.
A cylindrical outer tube 40 that holds lead wires and terminals (described later) provided on the proximal end side of the sensor element 3 and covers the proximal end portion of the sensor element 3 is joined to the proximal end portion of the metal fitting body 20. ing. Further, an insulating and cylindrical separator 121 is caulked and fixed inside the outer cylinder 40 on the proximal end side of the sensor element 3. On the other hand, the detection part at the tip of the sensor element 3 is covered with a protector 7. Then, by attaching the male screw portion 20d of the metal fitting body 20 of the sensor 100 manufactured in this way to a screw hole such as an exhaust pipe, the detection part at the tip of the sensor element 3 is exposed in the exhaust pipe, and the detected gas (exhaust gas) Gas). A polygonal flange 20c for engaging a hexagon wrench or the like is provided near the center of the metal fitting body 20, and the step between the flange 20c and the male thread 20d is attached to the exhaust pipe. A gasket 14 is inserted to prevent the gas from leaking when it is blown.

センサ素子3の中央側に鍔部3aが設けられ、金具本体20の先端寄りの内周面には内側に縮径する段部が設けられている。又、段部の基端向き面にワッシャ12を介して筒状のセラミックホルダ5が配置されている。そして、センサ素子3が金具本体20及びセラミックホルダ5の内側に挿通され、セラミックホルダ5に基端側からセンサ素子3の鍔部3aが当接している。
さらに、鍔部3aの基端側におけるセンサ素子3と金具本体20との径方向(軸線方向と直交する方向)の隙間に、筒状の滑石粉末6、及び筒状のセラミックスリーブ10が配置されている。そして、セラミックスリーブ10の基端側に金属リング30を配し、金具本体20基端部を内側に屈曲して加締め部20aを形成することにより、セラミックスリーブ10が先端側に押し付けられる。これにより滑石リング6を押し潰し、セラミックスリーブ10及び滑石粉末6が加締め固定されるとともに、センサ素子3と金具本体20の隙間がシールされている。
A flange portion 3 a is provided on the center side of the sensor element 3, and a step portion that is reduced in diameter is provided on the inner peripheral surface near the tip of the metal fitting body 20. In addition, a cylindrical ceramic holder 5 is disposed on a surface facing the base end of the step portion via a washer 12. The sensor element 3 is inserted inside the metal fitting body 20 and the ceramic holder 5, and the flange 3 a of the sensor element 3 is in contact with the ceramic holder 5 from the base end side.
Further, the cylindrical talc powder 6 and the cylindrical ceramic sleeve 10 are arranged in a gap in the radial direction (direction orthogonal to the axial direction) between the sensor element 3 and the metal fitting body 20 on the proximal end side of the flange portion 3a. ing. Then, the metal ring 30 is disposed on the proximal end side of the ceramic sleeve 10, and the base end portion of the metal fitting body 20 is bent inward to form the crimped portion 20a, whereby the ceramic sleeve 10 is pressed against the distal end side. As a result, the talc ring 6 is crushed and the ceramic sleeve 10 and the talc powder 6 are fixed by caulking, and the gap between the sensor element 3 and the metal fitting body 20 is sealed.

ガスセンサ素子3の後端側にセパレータ121が配置され、セパレータ121と外筒40との間隙には保持金具80が配置されている。そして、保持金具80の内部にセパレータ121が保持されている。
セパレータ121には、挿通孔(この例では4個)が設けられ、そのうち2個の挿通孔にそれぞれ内側端子71、外側端子91の板状基部74、94が挿入されて固定されている。各板状基部74、94の後端にはそれぞれコネクタ部75、95が形成され、コネクタ部75、95にそれぞれリード線41、41が加締め接続されている。又、セパレータ121の図示しない2個の挿通孔(ヒータリード孔)に、ヒータ15から引き出されたヒータリード線43(図1では1個のみ図示)が挿通されている。
セパレータ121の後端側の外筒40内側には筒状のグロメット131が加締め固定され、グロメット131の4個の挿通孔からそれぞれ2個のリード線41、及び2個のヒータリード線43が外部に引き出されている。
なお、グロメット131の中心には貫通孔131aが形成され、ガスセンサ素子3の内部空間に連通している。そして、グロメット131の貫通孔131aに撥水性の通気フィルタ140が介装され、外部の水を通さずにガスセンサ素子3の内部空間に基準ガス(大気)を導入するようになっている。
又、外側端子91が特許請求の範囲の「接続端子」に相当し、板状基部94が特許請求の範囲の「本体部」に相当する。
A separator 121 is disposed on the rear end side of the gas sensor element 3, and a holding metal fitting 80 is disposed in the gap between the separator 121 and the outer cylinder 40. The separator 121 is held inside the holding metal fitting 80.
The separator 121 is provided with insertion holes (four in this example), and the plate-like base portions 74 and 94 of the inner terminal 71 and the outer terminal 91 are inserted and fixed to two of the insertion holes, respectively. Connector portions 75 and 95 are formed at the rear ends of the plate-like base portions 74 and 94, respectively, and lead wires 41 and 41 are crimped to the connector portions 75 and 95, respectively. Further, a heater lead wire 43 (only one is shown in FIG. 1) drawn from the heater 15 is inserted into two insertion holes (heater lead holes) (not shown) of the separator 121.
A cylindrical grommet 131 is caulked and fixed inside the outer cylinder 40 on the rear end side of the separator 121, and two lead wires 41 and two heater lead wires 43 are respectively inserted from the four insertion holes of the grommet 131. Has been pulled out.
A through hole 131 a is formed at the center of the grommet 131 and communicates with the internal space of the gas sensor element 3. A water-repellent ventilation filter 140 is interposed in the through-hole 131a of the grommet 131 so that the reference gas (atmosphere) is introduced into the internal space of the gas sensor element 3 without passing outside water.
The outer terminal 91 corresponds to a “connection terminal” in the claims, and the plate-like base portion 94 corresponds to a “main body” in the claims.

一方、金具本体20の先端側には筒状のプロテクタ7が外嵌され、金具本体20から突出するセンサ素子3の先端側がプロテクタ7で覆われている。プロテクタ7は、複数の孔部(図示せず)を有する有底筒状で金属製(例えば、ステンレスなど)二重の外側プロテクタ7bおよび内側プロテクタ7aを、溶接等によって取り付けて構成されている。   On the other hand, a cylindrical protector 7 is fitted on the front end side of the metal fitting body 20, and the front end side of the sensor element 3 protruding from the metal fitting body 20 is covered with the protector 7. The protector 7 is configured by attaching a bottomed cylindrical metal (for example, stainless steel, etc.) double outer protector 7b and an inner protector 7a having a plurality of holes (not shown) by welding or the like.

図2に示すように、外側電極(検知電極)3Cはガスセンサ素子3の外周面3Sの先端側に形成され、さらに外側電極3Cは、外周面3Sの先端側の全周に亘って設けられる検出部3CSと、検出部3CSから後端に延びる線状のリード部3CLと、外周面3Sの後端側に周方向の一部に延びるように設けられてリード部3CL(検出部3CS)と接続する電極取出し部3CPとを有している。なお、電極取出し部3CPは周方向にリード部3CLより広幅で形成され、電極取出し部3CPとリード部3CLとがT字状をなしている。又、内側電極3B(図1参照)は、外周面3Sの先端部から後端部3eの内孔3dの表面に設けられている。なお、後端部3eは面取りされた角部となっている。
さらに、センサ素子3の電極取出し部3CPよりも後端側で後端部3eよりも先端側に、外周面3Sより径方向内側に凹んだ収容部3Rが設けられている。収容部3Rは、例えば収容部3Rの概形を有するセンサ素子3を、固体電解質体を含む粉末からプレス成形して焼成した後、切削加工によって仕上げて形成することができる。
As shown in FIG. 2, the outer electrode (detection electrode) 3C is formed on the distal end side of the outer circumferential surface 3S of the gas sensor element 3, and the outer electrode 3C is provided over the entire circumference on the distal end side of the outer circumferential surface 3S. Portion 3CS, a linear lead portion 3CL extending from the detection portion 3CS to the rear end, and a portion extending in the circumferential direction on the rear end side of the outer peripheral surface 3S and connected to the lead portion 3CL (detection portion 3CS) Electrode extraction portion 3CP. The electrode extraction portion 3CP is formed to be wider than the lead portion 3CL in the circumferential direction, and the electrode extraction portion 3CP and the lead portion 3CL have a T shape. Further, the inner electrode 3B (see FIG. 1) is provided on the surface of the inner hole 3d in the rear end portion 3e from the front end portion of the outer peripheral surface 3S. The rear end 3e is a chamfered corner.
Further, a receiving portion 3R that is recessed radially inward from the outer peripheral surface 3S is provided on the rear end side with respect to the electrode extraction portion 3CP of the sensor element 3 and on the front end side with respect to the rear end portion 3e. The accommodating portion 3R can be formed by, for example, press-molding and firing the sensor element 3 having the general shape of the accommodating portion 3R from a powder containing a solid electrolyte body, and then finishing by cutting.

一方、外側端子(接続端子)91は、先端から後端に細長く延び、所定の形状に打ち抜かれた金属薄板(耐食耐熱超合金板)を曲げ加工して一体に形成されている。外側端子91の後端側には板状基部94が形成され、板状基部94の後端側にはリード線41の芯線に加締め接続される接続端部95が配置されている。板状基部94の先端側には、板状基部94より狭幅のバネ部96を介して筒状の端子部93が接続されている。
バネ部96は、端子部93の外面に面一に後端側に延びた後、径方向外側に屈曲し、さらに後端側で径方向内側に曲線で折り返される折り返し部96aを一カ所有し、折り返し部の後端側で軸線方向に屈曲して板状基部94に繋がっている。そして、バネ部96は、折り返し部96aで軸線方向に弾性的に撓むようになっている。
さらに板状基部94の軸線方向中央側には、他の部位より広幅の広幅部94wが形成され、広幅部94wの中央部は後端側が固定されたコ字状に打ち抜かれ、広幅部94wの背面側(前面と反対側の面)に切起こされた切り起こし部94Yが設けられている。
On the other hand, the outer terminal (connection terminal) 91 is elongated from the front end to the rear end, and is integrally formed by bending a thin metal plate (corrosion resistant heat resistant superalloy plate) punched into a predetermined shape. A plate-like base portion 94 is formed on the rear end side of the outer terminal 91, and a connection end portion 95 that is caulked and connected to the core wire of the lead wire 41 is disposed on the rear end side of the plate-like base portion 94. A cylindrical terminal portion 93 is connected to the distal end side of the plate-like base portion 94 via a spring portion 96 that is narrower than the plate-like base portion 94.
The spring portion 96 extends to the rear end side flush with the outer surface of the terminal portion 93, then bends radially outward, and further has a folded portion 96 a that is folded back in a radial direction on the rear end side. The bent portion is bent in the axial direction on the rear end side and connected to the plate-like base portion 94. The spring portion 96 is elastically bent in the axial direction at the folded portion 96a.
Further, a wide portion 94w that is wider than other portions is formed on the center side in the axial direction of the plate-like base portion 94, and the central portion of the wide portion 94w is punched into a U-shape with the rear end side fixed, and the wide portion 94w A cut-and-raised portion 94Y cut and raised on the back side (the surface opposite to the front side) is provided.

そして、図3に示すように、接続端子91をセパレータ121の挿通孔121hの先端側から挿入すると、広幅部94wの後端側の肩部94sが挿通孔121内の先端側に向くテーパ部121tに当接し、接続端子91がセパレータ121内に位置決めされる。又、上記した切起こし部94Yが挿通孔121hの外端壁に当接し、そのバネ力によって板状基部94を挿通孔121h内に保持している。又、端子部93の後端側にセパレータ121が隙間Gを設けて離間するようにして、接続端子91がセパレータ121に保持されている。
従って、図4に示すように、セパレータ121を過度の押圧力で先端側に押し込んだ場合でも、バネ部96の弾性力により隙間Gを減少させながらセパレータ121の押圧力を吸収し、端子部93がそれ以上先端側へ押し込まれることを抑制するようになっている。
なお、本実施形態では、バネ部96はセパレータ121の挿通孔121h内に収容されている。又、肩部94sが特許請求の範囲の「係止部」に相当する。
As shown in FIG. 3, when the connection terminal 91 is inserted from the front end side of the insertion hole 121 h of the separator 121, the shoulder portion 94 s on the rear end side of the wide portion 94 w is a tapered portion 121 t that faces the front end side in the insertion hole 121. The connection terminal 91 is positioned in the separator 121. The cut and raised portion 94Y is in contact with the outer end wall of the insertion hole 121h, and the plate-like base portion 94 is held in the insertion hole 121h by the spring force. In addition, the connection terminal 91 is held by the separator 121 such that the separator 121 is separated from the rear end side of the terminal portion 93 by providing a gap G.
Therefore, as shown in FIG. 4, even when the separator 121 is pushed to the tip side with an excessive pressing force, the pressing force of the separator 121 is absorbed while the gap G is reduced by the elastic force of the spring portion 96, and the terminal portion 93. Is prevented from being pushed further toward the tip side.
In the present embodiment, the spring portion 96 is accommodated in the insertion hole 121 h of the separator 121. The shoulder portion 94s corresponds to a “locking portion” in the claims.

また、端子部93は軸線Oを中心とする筒状をなし、かつ板状基部94と反対側に母線に沿ったスリットMを有する断面C字形状をなしている。そして、端子部93の内径は、ガスセンサ素子3(外周面3S)の後端部の外径より小さく、端子部93をガスセンサ素子3に外嵌して拡開した際にバネ力によって端子部93が縮まり、ガスセンサ素子3の外側電極3C(電極取出し部3CP)に押圧されるようになっている。
又、端子部93には、内周面から内向きに突出されつつ収容部300R内に収容される半球状の端子側突出部93Pが合計4個(図2では3つのみ図示)設けられ、端子側突出部93Pよりも先端側の端子部93の内面は電極取出し部3CPと接触する接触部93Cを構成している。
さらに、端子部93における先端側には、先端縁93fで端子部93を径方向外側に向かって折り返した片状のガイド片98が周方向に断続的に、かつ放射状に合計8個(図2では3つのみ図示)形成されている。ガイド片98は径方向外側に広がりつつ、先端縁93fから先端に向かって延び、端子部93をセンサ素子3に外嵌する際のガイドとなっている。
Further, the terminal portion 93 has a cylindrical shape centered on the axis O, and has a C-shaped cross section having a slit M along the generatrix on the opposite side to the plate-like base portion 94. The inner diameter of the terminal portion 93 is smaller than the outer diameter of the rear end portion of the gas sensor element 3 (outer peripheral surface 3S), and when the terminal portion 93 is externally fitted to the gas sensor element 3 and expanded, the terminal portion 93 is caused by a spring force. Is shrunk and pressed by the outer electrode 3C (electrode extraction part 3CP) of the gas sensor element 3.
In addition, the terminal portion 93 is provided with a total of four hemispherical terminal side protruding portions 93P (only three are shown in FIG. 2) that are accommodated in the accommodating portion 300R while protruding inward from the inner peripheral surface. The inner surface of the terminal portion 93 on the tip side of the terminal side protruding portion 93P constitutes a contact portion 93C that comes into contact with the electrode extraction portion 3CP.
Further, on the distal end side of the terminal portion 93, there are a total of eight piece-like guide pieces 98 in which the terminal portion 93 is folded back radially outward at the distal edge 93f intermittently and radially in the circumferential direction (FIG. 2). (Only three are shown). The guide piece 98 extends radially outward while extending from the tip edge 93f toward the tip, and serves as a guide when the terminal portion 93 is externally fitted to the sensor element 3.

このセンサ100は、図5に示すようにして製造される。まず、センサ素子3を主体金具20の内側に保持してセンサ素子アセンブリBを組み付ける。具体的には、センサ素子3を主体金具20内に配置されたセラミックホルダ5上に配置する。その後、主体金具20とセンサ素子3との間隙に滑石(タルク)6を充填し、セラミックスリーブ10、金属パッキン30を順に滑石6上に配置し、主体金具20の後端側を加締めてセンサ素子アセンブリBを組み付ける。
一方で、外筒40内に、内側の内側端子71及び外側の外側端子91を組み付けたセパレータ121をグロメット131と共に外筒40を配置し、セパレータアセンブリAを組み付ける。具体的には、リード線41に接続された内側端子71及び外側端子91をセパレータ121内に挿入し、その後、セパレータ121を外筒40の段部40dに当接する。
その後、セパレータ121と外筒40との間隙に保持金具80を挿入すると共に、グロメット131を外筒40の後端側に配置し、セパレータアセンブリAを組み付ける。なお、内側端子71にはヒータ15が既に取付けられている。
This sensor 100 is manufactured as shown in FIG. First, the sensor element assembly B is assembled while holding the sensor element 3 inside the metal shell 20. Specifically, the sensor element 3 is disposed on the ceramic holder 5 disposed in the metal shell 20. Thereafter, the talc 6 is filled in the gap between the metal shell 20 and the sensor element 3, the ceramic sleeve 10 and the metal packing 30 are sequentially disposed on the talc 6, and the rear end side of the metal shell 20 is swaged. The element assembly B is assembled.
On the other hand, the outer cylinder 40 is disposed together with the grommet 131 on the separator 121 assembled with the inner terminal 71 and the outer terminal 91 on the outer cylinder 40, and the separator assembly A is assembled. Specifically, the inner terminal 71 and the outer terminal 91 connected to the lead wire 41 are inserted into the separator 121, and then the separator 121 is brought into contact with the stepped portion 40 d of the outer cylinder 40.
Thereafter, the holding metal fitting 80 is inserted into the gap between the separator 121 and the outer cylinder 40, the grommet 131 is disposed on the rear end side of the outer cylinder 40, and the separator assembly A is assembled. The heater 15 is already attached to the inner terminal 71.

そして、セパレータアセンブリAと素子アセンブリBとの軸線を合わせ、セパレータアセンブリAをセンサ素子アセンブリBの後端に被せると、センサ素子3内にヒータ15が挿入されると共に、センサ素子3の内側電極3B及び外側電極3Cがそれぞれ内側端子71及び外側端子91と電気的に接続される。その後、外筒40のうち、保持金具80の外周部、グロメット131の外周部、主体金具20との重なり部をそれぞれ加締めると共に、外筒40と主体金具20との重なり部をレーザ溶接等によって主体金具20の後端に外筒40を接続させ、センサ100を製造する。
セパレータアセンブリAをセンサ素子アセンブリBに押し込む際には、加圧装置(図示せず)を用い、セパレータ121を所定ストロークで押し込む。このとき、セパレータ121と端子部93とは離間しており、図4で説明したように、バネ部96の弾性力によりセパレータ121の押圧力を吸収しながら、一定の力で端子部93が先端側へ押し込まれる。これにより、端子部93の先端側が、センサ素子3の収容部3Rを乗り越えて自身の弾性力で拡径することを利用して、センサ素子3の後端部寄り(外側電極3Cの電極取出し部3CPの形成部分)に外嵌する。
このようにして、センサ素子3の後端側の外周面に、外側端子91の端子部93を外嵌し、電極取出し部3CPと端子部93とを電気的に接続する。これにより、外側電極3C(検出部3CS)の検出信号を外側端子91からリード線41を介して外部に取り出すようになっている。
Then, when the axis lines of the separator assembly A and the element assembly B are aligned and the separator assembly A is put on the rear end of the sensor element assembly B, the heater 15 is inserted into the sensor element 3 and the inner electrode 3B of the sensor element 3 is inserted. The outer electrode 3C is electrically connected to the inner terminal 71 and the outer terminal 91, respectively. After that, among the outer cylinder 40, the outer peripheral part of the holding metal fitting 80, the outer peripheral part of the grommet 131, and the overlapping part with the metal shell 20 are respectively crimped, and the overlapping part between the outer cylinder 40 and the metal shell 20 is laser welded or the like. The outer cylinder 40 is connected to the rear end of the metal shell 20 to manufacture the sensor 100.
When pushing the separator assembly A into the sensor element assembly B, a pressurizing device (not shown) is used to push the separator 121 with a predetermined stroke. At this time, the separator 121 and the terminal portion 93 are separated from each other. As described with reference to FIG. 4, the terminal portion 93 has a constant force while absorbing the pressing force of the separator 121 by the elastic force of the spring portion 96. It is pushed to the side. Thereby, the tip end side of the terminal portion 93 gets over the housing portion 3R of the sensor element 3 and expands the diameter by its own elastic force, and thus close to the rear end portion of the sensor element 3 (the electrode extraction portion of the outer electrode 3C). 3CP forming part).
In this manner, the terminal portion 93 of the outer terminal 91 is externally fitted to the outer peripheral surface on the rear end side of the sensor element 3, and the electrode extraction portion 3CP and the terminal portion 93 are electrically connected. Thereby, the detection signal of the outer electrode 3C (detector 3CS) is taken out from the outer terminal 91 via the lead wire 41.

次に、図6を参照し、製造時に端子部93をセンサ素子3に嵌め込む過程について説明する。
まず、図6(a)に示すように、端子部93を先端側からセンサ素子3の後端側に外嵌すると、ガイド片98の内面がセンサ素子3の後端部3eに接し、ガイド片98をガイドとして端子部93が拡径しつつ、センサ素子3の先端側に嵌め込まれてゆく。
端子部93をさらにセンサ素子3の先端側に外嵌すると(図6(b))、端子部93の内面が後端部3eを乗り越え、端子部93をハの字に押し広げる。ここで、さらに端子部93をセンサ素子3の先端側に外嵌すると(図6(c))、端子部93の先端縁93fが、センサ素子3の外周面3Sに設けられた電極取出し部3CPに近接する。
さらに端子部93をセンサ素子3の先端側に外嵌すると(図6(d))、端子部93の端子側突出部93Pが後端部3eを乗り越える。このとき、端子側突出部93Pが端子部93をさらにハの字に押し広げ、端子部93をセンサ素子3の外周面3Sから遠ざけるので、端子部93の先端縁93fが電極取出し部3CPに接触させないようにしつつ、端子部93をさらに深く嵌め込むことができる。
端子部93をさらにセンサ素子3の先端側に外嵌すると(図6(e))、端子部93の端子側突出部93Pが後端部3eを乗り越えて小径の収容部3Rに収容され、これに伴って端子部93全体が自身の弾性力により縮径し、端子部93と電極取出し部3CPとが電気的に接触する。
Next, a process of fitting the terminal portion 93 into the sensor element 3 during manufacturing will be described with reference to FIG.
First, as shown in FIG. 6A, when the terminal portion 93 is externally fitted from the front end side to the rear end side of the sensor element 3, the inner surface of the guide piece 98 comes into contact with the rear end portion 3e of the sensor element 3, and the guide piece The terminal portion 93 is fitted into the distal end side of the sensor element 3 while expanding the diameter with 98 as a guide.
When the terminal portion 93 is further externally fitted to the front end side of the sensor element 3 (FIG. 6B), the inner surface of the terminal portion 93 gets over the rear end portion 3e and pushes the terminal portion 93 into a letter C shape. Here, when the terminal portion 93 is further fitted on the distal end side of the sensor element 3 (FIG. 6C), the distal end edge 93f of the terminal portion 93 is the electrode extraction portion 3CP provided on the outer peripheral surface 3S of the sensor element 3. Proximity to.
Further, when the terminal portion 93 is externally fitted to the front end side of the sensor element 3 (FIG. 6D), the terminal side protruding portion 93P of the terminal portion 93 gets over the rear end portion 3e. At this time, the terminal-side protruding portion 93P further pushes the terminal portion 93 into a cross-section and moves the terminal portion 93 away from the outer peripheral surface 3S of the sensor element 3, so that the tip edge 93f of the terminal portion 93 contacts the electrode extraction portion 3CP. The terminal portion 93 can be fitted more deeply while preventing this.
When the terminal portion 93 is further externally fitted to the front end side of the sensor element 3 (FIG. 6 (e)), the terminal side protruding portion 93P of the terminal portion 93 gets over the rear end portion 3e and is accommodated in the small diameter accommodating portion 3R. Accordingly, the diameter of the entire terminal portion 93 is reduced by its own elastic force, and the terminal portion 93 and the electrode extraction portion 3CP are in electrical contact.

ここで、図5で説明したように、セパレータアセンブリAをセンサ素子アセンブリBに押し込む際には、加圧装置(図示せず)を用い、セパレータ121を所定ストロークで押し込む。
このとき、図6(e)のように、既に端子部93が所定の深さまで嵌め込まれ、端子部93と電極取出し部3CPとが電気的に接触しているにも関わらず、セパレータ121が端子部93をさらに先端側へ押圧することがある。
このような場合であっても、図4で説明したように、バネ部96の弾性力によりセパレータ121の押圧力が一定の力(バネ部96の弾性力に等しい力)を超えないように押圧力を吸収するので、端子部93がそれ以上先端側へ押し込まれることを抑制することができる。その結果、図6(f)に示すように、センサ素子3への接続端子91の嵌め込み深さを一定に保ち、端子部93が所定の位置を超えて先端側へ深く嵌め込まれて電極取出し部3CPを削ったり摩耗させることを抑制することができる。又、端子部93の端子側突出部93Pが収容部3Rを乗り越えて深く嵌め込まれることで、端子部93が拡径して接触部93Cと電極取出し部3CPとが離間し、電気的接続が不安定になることをも抑制することができる。
Here, as described with reference to FIG. 5, when the separator assembly A is pushed into the sensor element assembly B, the separator 121 is pushed in by a predetermined stroke using a pressurizing device (not shown).
At this time, as shown in FIG. 6E, the terminal portion 93 is already fitted to a predetermined depth, and the separator 121 is connected to the terminal even though the terminal portion 93 and the electrode extraction portion 3CP are in electrical contact. The part 93 may be further pressed toward the tip side.
Even in such a case, as described with reference to FIG. 4, the pressing force of the separator 121 is pushed so as not to exceed a certain force (a force equal to the elastic force of the spring portion 96) by the elastic force of the spring portion 96. Since pressure is absorbed, it can suppress that the terminal part 93 is pushed into the front end side any more. As a result, as shown in FIG. 6 (f), the fitting depth of the connection terminal 91 to the sensor element 3 is kept constant, and the terminal portion 93 is deeply fitted to the distal end side beyond a predetermined position, so that the electrode extraction portion It is possible to suppress the 3CP from being scraped or worn. Further, since the terminal side protruding portion 93P of the terminal portion 93 gets over and deeply fits over the housing portion 3R, the terminal portion 93 is expanded in diameter, and the contact portion 93C and the electrode extraction portion 3CP are separated from each other, and electrical connection is not achieved. It can also be suppressed that it becomes stable.

また、端子部93に端子側突出部93Pを設けているので、端子側突出部93Pが端子部93を押し広げてセンサ素子3の外周面3Sから遠ざける、その結果、端子部93をセンサ素子3の外周面3Sに設けられた電極取出し部3CPに接触させないようにして端子部93を嵌め込むことができる。
さらには、端子側突出部93Pは、外側端子91(端子部93)がセンサ素子3から抜けるのを防止する抜け止め部としても作用する。
なお、外側端子91をセンサ素子3に嵌め込む際には、バネ部96に軸線O方向に荷重(押圧力)が加わるが、外側端子91がセンサ素子3に嵌め込まれた完成品のセンサ100においては、バネ部96に軸線O方向に荷重(押圧力)が加わっていてもよく、加わっていなくてもよい。
Moreover, since the terminal side protrusion part 93P is provided in the terminal part 93, the terminal side protrusion part 93P spreads the terminal part 93, and keeps it away from the outer peripheral surface 3S of the sensor element 3, As a result, the terminal part 93 is made into the sensor element 3. The terminal portion 93 can be fitted so as not to contact the electrode extraction portion 3CP provided on the outer peripheral surface 3S.
Furthermore, the terminal side protruding portion 93P also functions as a retaining portion that prevents the outer terminal 91 (terminal portion 93) from coming off the sensor element 3.
When the outer terminal 91 is fitted into the sensor element 3, a load (pressing force) is applied to the spring portion 96 in the direction of the axis O, but in the completed sensor 100 in which the outer terminal 91 is fitted into the sensor element 3. The load (pressing force) may be applied to the spring portion 96 in the direction of the axis O or may not be applied.

なお、図8に示したように、従来の接続端子910においては、端子部930と本体部940とを繋ぐ頸部960は、端子部930から軸線方向後端側へまっすぐ伸びた後、径方向内側へ屈曲して本体部940へ繋がっており、径方向に曲線で折り返す折り返し部を有していない。このため、セパレータ1210が接続端子910を先端側へ過度に押圧した際に、必ずしも頸部860の位置で撓むとは限らないので、頸部960はセパレータ121の押圧力を十分に吸収することが困難である。又、そもそもセパレータ1210と端子部930とが離間していないので、セパレータ1210の押圧力は端子部930に直接加わり、セパレータ121の押圧力が途中で吸収されることはない。   As shown in FIG. 8, in the conventional connection terminal 910, the neck portion 960 that connects the terminal portion 930 and the main body portion 940 extends straight from the terminal portion 930 toward the rear end side in the axial direction, and then in the radial direction. It is bent inward and connected to the main body 940, and does not have a folded portion that folds in a radial direction. For this reason, when the separator 1210 excessively presses the connection terminal 910 toward the distal end, the neck 960 does not necessarily bend at the position of the neck 860, so that the neck 960 cannot sufficiently absorb the pressing force of the separator 121. It is. In addition, since the separator 1210 and the terminal portion 930 are not separated from each other, the pressing force of the separator 1210 is directly applied to the terminal portion 930, and the pressing force of the separator 121 is not absorbed halfway.

また、本実施形態では、広幅部94wの後端側の肩部94sを介して、接続端子91がセパレータ121内に保持される。このため、端子部93の後端側にセパレータ121を確実に離間させることができ、バネ部96の弾性力によりセパレータ121の押圧力を確実に吸収し、端子部93がそれ以上先端側へ押し込まれることをより一層抑制することができる。   In the present embodiment, the connection terminal 91 is held in the separator 121 via the shoulder portion 94s on the rear end side of the wide width portion 94w. For this reason, the separator 121 can be reliably separated to the rear end side of the terminal portion 93, the pressing force of the separator 121 is reliably absorbed by the elastic force of the spring portion 96, and the terminal portion 93 is pushed further to the front end side. Can be further suppressed.

次に、図7を参照して本発明の第2の実施形態に係るセンサについて説明する。図7は、本発明の第2の実施形態に係るセンサ100Zのセンサ素子3Z及び接続端子91Zの構造を示す斜視図である。なお、第2の実施形態に係るセンサ100Zは、センサ素子3Z及び外側端子91Z以外の構成は第1の実施形態と同一であるので、第1の実施形態に係るセンサ1と同一の構成部分については、図示を省略したり同一符号を付して説明を省略する。
接続端子91Zは、素子側凸部を有しておらず、一般的な形状の接続端子をそのまま使用することができる。
一方、センサ素子3Zは、電極取出し部3CPよりも後端側に、外周面3S及び電極取出し部3CPの外表面より径方向外側に突出する素子側凸部3Pを有する。図7の例では、素子側凸部3Pは、センサ素子3の後端縁から先端側に向かってテーパ状に拡径する拡径部3P1と、拡径部3P1から先端側に延びるストレート部3P2とを有している。又、凸部3P(ストレート部3P2)の先端縁3Pfは段部を形成して外周面3Sと繋がっている。
Next, a sensor according to a second embodiment of the present invention will be described with reference to FIG. FIG. 7 is a perspective view showing structures of the sensor element 3Z and the connection terminal 91Z of the sensor 100Z according to the second embodiment of the present invention. The sensor 100Z according to the second embodiment has the same configuration as the first embodiment except for the sensor element 3Z and the outer terminal 91Z. Therefore, the same components as the sensor 1 according to the first embodiment are used. These are omitted from the illustration or are given the same reference numerals, and the description thereof is omitted.
The connection terminal 91Z does not have an element-side convex portion, and a connection terminal having a general shape can be used as it is.
On the other hand, the sensor element 3Z has an element-side convex portion 3P that protrudes radially outward from the outer peripheral surface 3S and the outer surface of the electrode extraction portion 3CP on the rear end side of the electrode extraction portion 3CP. In the example of FIG. 7, the element-side convex portion 3 </ b> P includes a diameter-enlarged portion 3 </ b> P <b> 1 that increases in a taper shape from the rear end edge of the sensor element 3 toward the front end side, and a straight portion 3 </ b> P <b> 2 that extends from the enlarged diameter portion 3 </ b> P < And have. Further, the tip edge 3Pf of the convex portion 3P (straight portion 3P2) forms a step portion and is connected to the outer peripheral surface 3S.

第2の実施形態においても、外側端子91Zをセンサ素子3に嵌め込む際、バネ部96の弾性力により押圧力を吸収するので、端子部93がそれ以上先端側へ押し込まれることを抑制することができる。その結果、センサ素子3Zへの外側端子91Zの嵌め込み深さを一定に保ち、端子部93が所定の位置を超えて先端側へ深く嵌め込まれて電極取出し部3CPを削ったり摩耗させることを抑制することができる。   Also in the second embodiment, when the outer terminal 91Z is fitted into the sensor element 3, the pressing force is absorbed by the elastic force of the spring portion 96, so that the terminal portion 93 is prevented from being pushed further toward the distal end side. Can do. As a result, the fitting depth of the outer terminal 91Z into the sensor element 3Z is kept constant, and the terminal portion 93 is prevented from being deeply fitted to the distal end side beyond a predetermined position to scrape or wear the electrode extraction portion 3CP. be able to.

また、センサ素子3Zに素子側凸部3Pを設けているので、素子側凸部3Pが端子部93を押し広げてセンサ素子3Zの外周面3Sから遠ざける、その結果、端子部93をセンサ素子3Zの外周面3Sに設けられた電極取出し部3CPに接触させないようにして端子部93を嵌め込むことができる。
さらには、素子側凸部3Pは、外側端子91Z(端子部93)がセンサ素子3Zから抜けるのを防止する抜け止め部としても作用する。
Further, since the element-side convex portion 3P is provided in the sensor element 3Z, the element-side convex portion 3P spreads the terminal portion 93 and moves away from the outer peripheral surface 3S of the sensor element 3Z. As a result, the terminal portion 93 is moved to the sensor element 3Z. The terminal portion 93 can be fitted so as not to contact the electrode extraction portion 3CP provided on the outer peripheral surface 3S.
Furthermore, the element-side convex portion 3P also functions as a retaining portion that prevents the outer terminal 91Z (terminal portion 93) from coming out of the sensor element 3Z.

本発明は上記実施形態に限定されず、本発明の思想と範囲に含まれる様々な変形及び均等物に及ぶことはいうまでもない。
例えば、上記実施形態では、外側端子91を予めセパレータ121に保持し、セパレータを介して外側端子91をセンサ素子3に嵌め込むようにしたが、外側端子91の本体部94をセパレータ121と異なる別部材で保持し、センサ素子3に嵌め込んでもよい。
また、上記実施形態では、バネ部96が折り返し部96aを一カ所有したが、複数箇所の折り返し部を有してもよい。なお、複数箇所の折り返し部を有する場合、各折り返し部はそれぞれ軸線方向に並ぶことになる。折り返し部及びバネ部の形状も上記実施形態に限定されない。
端子部93に設けられた端子側突出部93Pの形状、位置及び個数も上記実施形態に限定されない。又、センサ素子3の収容部3Rの形状も上記実施形態に限定されない。なお、上記実施形態では、端子側突出部93Pの軸線方向の長さよりも収容部3Rの軸線方向の長さを長くしている。これは、センサ素子3の製造における収容部3Rの寸法バラツキ(公差)を考慮し、端子側突出部93Pを収容部3Rに確実に収容させるためである。
It goes without saying that the present invention is not limited to the above-described embodiment, but extends to various modifications and equivalents included in the spirit and scope of the present invention.
For example, in the above embodiment, the outer terminal 91 is held in the separator 121 in advance, and the outer terminal 91 is fitted into the sensor element 3 via the separator, but the main body 94 of the outer terminal 91 is different from the separator 121. It may be held by a member and fitted into the sensor element 3.
Moreover, in the said embodiment, although the spring part 96 owned one folding | returning part 96a, you may have several folding | turning part. In addition, when it has a several folding | turning part, each folding | returning part will respectively be located in a line with an axial direction. The shapes of the folded portion and the spring portion are not limited to the above embodiment.
The shape, position, and number of terminal side protrusions 93P provided in the terminal portion 93 are not limited to the above embodiment. Further, the shape of the accommodating portion 3R of the sensor element 3 is not limited to the above embodiment. In the above-described embodiment, the length in the axial direction of the accommodating portion 3R is made longer than the length in the axial direction of the terminal side protruding portion 93P. This is because the terminal side protruding portion 93P is reliably accommodated in the accommodating portion 3R in consideration of the dimensional variation (tolerance) of the accommodating portion 3R in the manufacture of the sensor element 3.

又、センサ素子3Zの素子側凸部3Pの形状も上記実施形態に限定されない。なお、上記実施形態では、素子側凸部3Pの周方向の一部が切欠かれて切欠き部3Xを形成し、切欠き部3Xの外表面は外周面3Sと軸線方向に面一になっている。そして、切欠き部3Xの周方向の内側に頸部96が位置するように、端子部93をセンサ素子3Zに嵌め込むことにより、外周面3S及び電極取出し部3CPの外表面より突出した凸部3Pに頸部96が干渉することを防止している。但し、これに限らず、素子側凸部3Pが全周にわたって形成されていてもよい。
さらに、端子部93は、センサ素子3の後端側を覆う筒状の形状であって、径方向外側に押し広げられる形状があればよく、上記した端子部93の軸線方向にスリットが1つ入り軸線方向に垂直な断面がC字形状をなすものの他、軸線方向にスリットが複数入った形状をなすものでもよい。
Further, the shape of the element-side convex portion 3P of the sensor element 3Z is not limited to the above embodiment. In the above-described embodiment, a part of the element side convex portion 3P in the circumferential direction is notched to form the notched portion 3X, and the outer surface of the notched portion 3X is flush with the outer circumferential surface 3S in the axial direction. Yes. And the convex part which protruded from the outer surface 3S and the outer surface of electrode extraction part 3CP by fitting the terminal part 93 in the sensor element 3Z so that the neck part 96 is located inside the notch part 3X in the circumferential direction This prevents the neck 96 from interfering with 3P. However, the invention is not limited thereto, and the element-side convex portion 3P may be formed over the entire circumference.
Furthermore, the terminal portion 93 has a cylindrical shape that covers the rear end side of the sensor element 3, and may have a shape that can be spread outward in the radial direction. One slit is provided in the axial direction of the terminal portion 93 described above. The cross section perpendicular to the entering axial direction may be a C-shaped cross section, or a shape having a plurality of slits in the axial direction.

3、3Z センサ素子
3CS 検出部
3CP 電極取出し部
3R 収容部
3S センサ素子の外周面
3P 素子側凸部
91、91Z 接続端子
93 端子部
93C 接触部
93P 端子側突出部
94 本体部
94s 係止部
96 バネ部
96a 折り返し部
100、100Z センサ
121 セパレータ
O 軸線
G 端子部とセパレータの隙間
3, 3Z sensor element 3CS detection part 3CP electrode extraction part 3R accommodating part 3S outer peripheral surface of sensor element 3P element side convex part 91, 91Z connection terminal 93 terminal part 93C contact part 93P terminal side protrusion 94 body part 94s locking part 96 Spring part 96a Folded part 100, 100Z Sensor 121 Separator O Axis G Gap between terminal part and separator

Claims (4)

軸線方向に延び、先端側が閉じられた有底筒状をなすセンサ素子であって、先端側に、被検出体の検出を行うための検出部を有すると共に、後端側の外周面上に、前記検出部の出力を取り出すための電極取出し部が形成されたセンサ素子と、
当該センサ素子の後端側の周方向を覆い前記電極取出し部と電気的に接続される端子部と、前記端子部の後端側に接続される板状の本体部とを有し、前記検出部からの検出信号を外部回路に出力する接続端子と
を備え、前記端子部が前記センサ素子に嵌め込まれ、前記端子部と前記電極取出し部とが接触するセンサにおいて、
前記センサ素子には、前記電極取出し部よりも前記軸線方向の後端側に、外周面から凹んだ収容部が設けられると共に、
前記接続端子の前記端子部には、
内周面から内向きに突出されつつ前記収容部内に収容される端子側突出部と、
前記端子側突出部よりも先端側に形成され、前記電極取出し部と接触する接触部と、が設けられるか、
又は、前記センサ素子の前記電極取出し部よりも後端側に、前記電極取出し部の外表面より前記軸線方向と直交する方向の外側に突出する素子側凸部が周方向の少なくとも一部に設けられ、前記端子部の後端縁が前記素子側凸部の先端縁よりも先端側に位置してなり、
前記接続端子の前記端子部と前記本体部との間には、前記軸線方向と直交する方向に曲線で折り返す折り返し部を一カ所以上有し、前記軸線方向に弾性的に撓むバネ部が設けられているセンサ。
A sensor element that extends in the axial direction and has a bottomed cylindrical shape with the tip side closed, and has a detection unit for detecting the detected object on the tip side, and on the outer peripheral surface on the rear end side, A sensor element in which an electrode extraction part for extracting the output of the detection part is formed;
A terminal portion that covers a circumferential direction on the rear end side of the sensor element and is electrically connected to the electrode take-out portion; and a plate-shaped main body portion connected to the rear end side of the terminal portion; A connection terminal that outputs a detection signal from a part to an external circuit, wherein the terminal part is fitted into the sensor element, and the terminal part and the electrode extraction part are in contact with each other,
The sensor element is provided with a housing portion recessed from the outer peripheral surface on the rear end side in the axial direction from the electrode extraction portion,
In the terminal portion of the connection terminal,
A terminal-side protruding portion that is accommodated in the accommodating portion while protruding inward from the inner peripheral surface;
A contact portion that is formed on the tip side of the terminal-side protruding portion and is in contact with the electrode extraction portion; or
Alternatively, an element-side convex portion that protrudes outward from the outer surface of the electrode extraction portion in a direction orthogonal to the axial direction is provided on at least a part of the circumferential direction on the rear end side of the electrode extraction portion of the sensor element. The rear end edge of the terminal portion is located on the front end side of the front end edge of the element side convex portion,
Between the terminal portion of the connection terminal and the main body portion, there is provided a spring portion that has one or more folded portions that are folded back in a direction perpendicular to the axial direction and elastically bends in the axial direction. Sensor.
前記接続端子の前記本体部の少なくとも一部を保持し、前記端子部の後端側に該端子部と離間して配置されるセパレータを備え、
前記セパレータを介して前記接続端子を前記軸線方向の先端側に押圧することで、前記端子部が前記センサ素子に嵌め込まれる請求項1に記載のセンサ。
A separator that holds at least a part of the main body portion of the connection terminal and is disposed on the rear end side of the terminal portion apart from the terminal portion;
The sensor according to claim 1, wherein the terminal portion is fitted into the sensor element by pressing the connection terminal toward the distal end side in the axial direction via the separator.
前記本体部には、該本体部から前記軸線方向と直交する方向に突出して前記セパレータの挿通孔に係止される係止部が設けられ、
前記バネ部は前記係止部よりも先端側に位置する請求項2に記載のセンサ。
The main body portion is provided with a locking portion that protrudes from the main body portion in a direction orthogonal to the axial direction and is locked to the insertion hole of the separator.
The sensor according to claim 2, wherein the spring portion is located on a distal end side with respect to the locking portion.
軸線方向に延び、先端側が閉じられた有底筒状をなすセンサ素子であって、先端側に、被検出体の検出を行うための検出部を有すると共に、後端側の外周面上に、前記検出部の出力を取り出すための電極取出し部が形成されたセンサ素子と、
当該センサ素子の後端側の周方向を覆い前記電極と電気的に接続される端子部と、前記端子部の後端側に接続される板状の本体部とを有し、前記検出部からの検出信号を外部回路に出力する接続端子と、
前記接続端子の前記本体部の少なくとも一部を保持し、前記端子部の後端側に該端子部と離間して配置されるセパレータと、
を備えたセンサの製造方法において、
前記センサ素子には、前記電極取出し部よりも前記軸線方向の後端側に、外周面から凹んだ収容部が設けられると共に、
前記接続端子の前記端子部には、
内周面から内向きに突出されつつ前記収容部内に収容される端子側突出部と、
前記端子側突出部よりも先端側に形成され、前記電極取出し部と接触する接触部と、が設けられるか、
又は、前記センサ素子の前記電極取出し部よりも後端側に、前記電極取出し部の外表面より前記軸線方向と直交する方向の外側に突出する素子側凸部が周方向の少なくとも一部に設けられ、前記端子部の後端縁が前記素子側凸部の先端縁よりも先端側に位置してなり、
前記接続端子の前記端子部と前記本体部との間には、前記軸線方向と直交する方向に曲線で折り返す折り返し部を一カ所以上有し、前記軸線方向に弾性的に撓むバネ部が設けられており、
前記接続端子を保持したセパレータを前記軸線方向の先端側に押圧し、前記突出部が前記収容部内に収容されるように前記端子部を前記センサ素子の後端側に嵌め込み、前記接触部を前記電極と電気的に接続するセンサの製造方法。
A sensor element that extends in the axial direction and has a bottomed cylindrical shape with the tip side closed, and has a detection unit for detecting the detected object on the tip side, and on the outer peripheral surface on the rear end side, A sensor element in which an electrode extraction part for extracting the output of the detection part is formed;
A terminal portion that covers the circumferential direction on the rear end side of the sensor element and is electrically connected to the electrode; and a plate-shaped main body portion connected to the rear end side of the terminal portion; A connection terminal that outputs a detection signal of
A separator that holds at least a part of the main body portion of the connection terminal and is disposed on the rear end side of the terminal portion so as to be separated from the terminal portion;
In a method for manufacturing a sensor comprising:
The sensor element is provided with a housing portion recessed from the outer peripheral surface on the rear end side in the axial direction from the electrode extraction portion,
In the terminal portion of the connection terminal,
A terminal-side protruding portion that is accommodated in the accommodating portion while protruding inward from the inner peripheral surface;
A contact portion that is formed on the tip side of the terminal-side protruding portion and is in contact with the electrode extraction portion; or
Alternatively, an element-side convex portion that protrudes outward from the outer surface of the electrode extraction portion in a direction orthogonal to the axial direction is provided on at least a part of the circumferential direction on the rear end side of the electrode extraction portion of the sensor element. The rear end edge of the terminal portion is located on the front end side of the front end edge of the element side convex portion,
Between the terminal portion of the connection terminal and the main body portion, there is provided a spring portion that has one or more folded portions that are folded back in a direction perpendicular to the axial direction and elastically bends in the axial direction. And
The separator holding the connection terminal is pressed toward the distal end side in the axial direction, the terminal portion is fitted into the rear end side of the sensor element so that the protruding portion is accommodated in the accommodating portion, and the contact portion is A method for manufacturing a sensor electrically connected to an electrode.
JP2014142014A 2014-07-10 2014-07-10 Sensor and manufacturing method of sensor Pending JP2016017895A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020051769A (en) * 2018-09-25 2020-04-02 日本特殊陶業株式会社 Gas sensor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020051769A (en) * 2018-09-25 2020-04-02 日本特殊陶業株式会社 Gas sensor
JP7149791B2 (en) 2018-09-25 2022-10-07 日本特殊陶業株式会社 gas sensor

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