JP2015229669A - Hair dye composition - Google Patents
Hair dye composition Download PDFInfo
- Publication number
- JP2015229669A JP2015229669A JP2014117909A JP2014117909A JP2015229669A JP 2015229669 A JP2015229669 A JP 2015229669A JP 2014117909 A JP2014117909 A JP 2014117909A JP 2014117909 A JP2014117909 A JP 2014117909A JP 2015229669 A JP2015229669 A JP 2015229669A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- hair
- hair dye
- less
- dye composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 147
- 239000000118 hair dye Substances 0.000 title claims abstract description 106
- -1 alkali metal salt Chemical class 0.000 claims abstract description 39
- 238000004043 dyeing Methods 0.000 claims abstract description 27
- 239000000987 azo dye Substances 0.000 claims abstract description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 17
- 239000003093 cationic surfactant Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 3
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 3
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- 125000002091 cationic group Chemical group 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 description 78
- 238000002156 mixing Methods 0.000 description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 20
- 235000002639 sodium chloride Nutrition 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000007800 oxidant agent Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000982 direct dye Substances 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 229960003237 betaine Drugs 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000000980 acid dye Substances 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000000981 basic dye Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 235000010493 xanthan gum Nutrition 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 229940082509 xanthan gum Drugs 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920000591 gum Polymers 0.000 description 3
- 230000003700 hair damage Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000011736 potassium bicarbonate Substances 0.000 description 3
- 235000015497 potassium bicarbonate Nutrition 0.000 description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 235000011181 potassium carbonates Nutrition 0.000 description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 3
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical class C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 2
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 description 2
- 235000011151 potassium sulphates Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 229940117986 sulfobetaine Drugs 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- OQWWMUWGSBRNMA-UHFFFAOYSA-N 1-(2,4-diaminophenoxy)ethanol Chemical compound CC(O)OC1=CC=C(N)C=C1N OQWWMUWGSBRNMA-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- 229940113489 2,4-diaminophenoxyethanol Drugs 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
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- LMKFATMCEGPAPC-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-2-nitroanilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C([N+]([O-])=O)=C1 LMKFATMCEGPAPC-UHFFFAOYSA-N 0.000 description 1
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- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
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- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
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- HSDSBIUUVWRHTM-UHFFFAOYSA-N 4-(2-nitroanilino)phenol Chemical compound C1=CC(O)=CC=C1NC1=CC=CC=C1[N+]([O-])=O HSDSBIUUVWRHTM-UHFFFAOYSA-N 0.000 description 1
- VTXBLQLZQLHDIL-UHFFFAOYSA-N 4-(3-hydroxypropylamino)-3-nitrophenol Chemical compound OCCCNC1=CC=C(O)C=C1[N+]([O-])=O VTXBLQLZQLHDIL-UHFFFAOYSA-N 0.000 description 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 1
- IQXUIDYRTHQTET-UHFFFAOYSA-N 4-amino-3-nitrophenol Chemical compound NC1=CC=C(O)C=C1[N+]([O-])=O IQXUIDYRTHQTET-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- YGRFRBUGAPOJDU-UHFFFAOYSA-N 5-(2-hydroxyethylamino)-2-methylphenol Chemical compound CC1=CC=C(NCCO)C=C1O YGRFRBUGAPOJDU-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- TWLMSPNQBKSXOP-UHFFFAOYSA-N 6358-09-4 Chemical compound NC1=CC([N+]([O-])=O)=CC(Cl)=C1O TWLMSPNQBKSXOP-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、染毛剤組成物及びそれを用いた染毛方法に関する。 The present invention relates to a hair dye composition and a hair dyeing method using the same.
染毛剤には、酸性染料、塩基性染料、ニトロ染料等の種々の直接染料が用いられているが、いずれの場合においても、洗浄や光によって比較的容易に毛髪上の直接染料が失われてしまうため、褪色しやすく、これは損傷を受けた毛髪において著しいとされている。 Various direct dyes such as acid dyes, basic dyes, and nitro dyes are used as hair dyes, but in any case, the direct dye on the hair is lost relatively easily by washing and light. Therefore, it is easy to fade and this is considered to be remarkable in damaged hair.
そこで、この問題に対処すべく種々の技術提案が行われおり、例えば、この問題を解決した、鮮明な染毛が可能で安定な染毛剤組成物として、解離性プロトンを有する解離性アゾ染料を直接染料として用いる染毛剤が提案されている（特許文献１）。 Therefore, various technical proposals have been made to deal with this problem. For example, a dissociable azo dye having a dissociable proton as a stable hair dye composition capable of clear hair dyeing and solving this problem. A hair dye using a direct dye as a dye has been proposed (Patent Document 1).
解離性アゾ染料は、アルカリ性下、解離性プロトンが解離した状態で染毛性を発揮するとされているが、一方で毛髪はアルカリ性条件におくと、毛髪そのものが膨潤して内部からタンパク質や脂質が溶出する結果、毛髪ダメージをもたらし、染毛剤使用後の毛髪の感触を著しく低下させる。ところが、染毛剤使用後の毛髪の感触を向上させるカチオン界面活性剤を上記解離性アゾ染料と併用しようとすると、プロトンを解離してアニオン性となった解離性アゾ染料がカチオン界面活性剤との間で難溶性の塩を形成してしまうため、配合時に染毛剤組成物系内で沈殿を生じ、配合時の操作性が悪くなると共に外観が悪くなるという問題に加え、使用時に良好な感触を付与することができないだけでなく、すすぎ時に簡単に洗い流されて染毛性が低下してしまうという問題があった。 Dissociable azo dyes are said to exhibit hair dyeability in the state where dissociable protons are dissociated under alkalinity. On the other hand, when hair is placed under alkaline conditions, the hair itself swells and proteins and lipids are absorbed from the inside. As a result of elution, hair damage is caused and the feel of the hair after using the hair dye is remarkably lowered. However, when a cationic surfactant that improves the feel of hair after using a hair dye is used in combination with the dissociable azo dye, the dissociable azo dye that has become anionic by dissociating protons is combined with the cationic surfactant. In addition to the problem that precipitation occurs in the hair dye composition system at the time of blending, and the operability at the time of blending is deteriorated and the appearance is deteriorated. In addition to not being able to impart a touch, there was a problem that the hair was easily washed out during rinsing and the hair dyeability was reduced.
従って、本発明は、カチオン界面活性剤と解離性アゾ染料が難溶性の塩を形成することなく安定に配合され、良好な染毛性を有し、かつ、染毛後の毛髪に対して優れた感触を付与することができる染毛剤組成物に関する。 Therefore, in the present invention, the cationic surfactant and the dissociable azo dye are stably blended without forming a hardly soluble salt, have good hair dyeing properties, and are excellent for hair after hair dyeing. It is related with the hair dye composition which can provide the touch.
本発明者らは、特定構造の解離性アゾ染料にあっては、アルカリ性下、アルカリ金属塩を解離性アゾ染料と共存させれば、カチオン界面活性剤を含むアルカリ性溶液とした場合でも、難溶性の塩を形成することなく安定に配合でき、鮮やかな染毛効果とともに、染毛後の毛髪に対して優れた感触（特に、すすぎ時の優れた感触）を付与する効果があることを見出した。 In the dissociable azo dye having a specific structure, the alkali metal salt coexisting with the dissociable azo dye under alkalinity is hardly soluble even in the case of an alkaline solution containing a cationic surfactant. It has been found that it can be blended stably without forming a salt, has a vivid hair dyeing effect, and has an effect of imparting an excellent feel (especially an excellent feel during rinsing) to the hair after dyeing. .
本発明は、次の成分(A)、(B)及び(C)を含有し、使用時のpH（25℃）が7.5以上12以下である染毛剤組成物を提供するものである。
(A)：下記(A-1)、(A-2)及び(A-3)からなる群より選択される１種又は２種以上のアゾ染料
The present invention provides a hair dye composition containing the following components (A), (B) and (C) and having a pH (25 ° C.) of 7.5 or more and 12 or less when used.
(A): One or more azo dyes selected from the group consisting of (A-1), (A-2) and (A-3) below
(B)：カチオン界面活性剤
(C)：塩酸、炭酸及び硫酸からなる群より選択される酸のアルカリ金属塩の少なくとも１種 0.1質量％以上８質量％以下
(B): Cationic surfactant
(C): at least one alkali metal salt of an acid selected from the group consisting of hydrochloric acid, carbonic acid and sulfuric acid 0.1% by mass to 8% by mass
更に、本発明は、上記の染毛剤組成物を毛髪に適用し、１〜60分間放置した後、洗い流す染毛方法を提供するものである。 Furthermore, the present invention provides a hair dyeing method in which the above hair dye composition is applied to hair, left for 1 to 60 minutes, and then washed away.
本発明の染毛剤組成物は、特定構造のアゾ染料とカチオン界面活性剤が難溶性の塩を形成することなく安定に配合され、鮮やかな染毛効果とともに、染毛後の毛髪に対して優れた感触（特に、剤すすぎ時の優れた感触）を付与することができる。 In the hair dye composition of the present invention, an azo dye having a specific structure and a cationic surfactant are stably blended without forming a sparingly soluble salt. An excellent feel (particularly, an excellent feel when the agent is rinsed) can be imparted.
〔成分(A)：アゾ染料〕
本発明の染毛剤組成物は、成分(A)として、下記(A-1)、(A-2)及び(A-3)からなる群より選択される１種又は２種以上のアゾ染料を含有する。
[Component (A): Azo dye]
The hair dye composition of the present invention comprises, as component (A), one or more azo dyes selected from the group consisting of the following (A-1), (A-2) and (A-3) Containing.
なお、アゾ染料(A-1)、(A-2)及び(A-3)のpKaは、それぞれ6.0、6.0及び7.5である。よって、pH（25℃）が7.5〜12である本発明の染毛剤組成物中では、これらアゾ染料のほぼ８割以上は、プロトンを解離したアニオン性の状態で存在する。プロトンが解離したとき、(A-1)は赤色、(A-2)は青色、(A-3)は黄色を呈する。 The pKa of the azo dyes (A-1), (A-2), and (A-3) are 6.0, 6.0, and 7.5, respectively. Therefore, in the hair dye composition of the present invention having a pH (25 ° C.) of 7.5 to 12, almost 80% or more of these azo dyes exist in an anionic state in which protons are dissociated. When protons are dissociated, (A-1) is red, (A-2) is blue, and (A-3) is yellow.
全組成中における上記アゾ染料の総含有量は、処方配合の安定性の観点から、好ましくは0.005質量％以上、より好ましくは0.01質量％以上、更に好ましくは0.05質量％以上、更に好ましくは0.1質量％以上であり、また、好ましくは５質量％以下、より好ましくは３質量％以下、更に好ましくは2.5質量％以下、更に好ましくは1.5質量％以下、更に好ましくは１質量％以下である。なお、本発明の染毛剤組成物には、アゾ染料(A-1)、(A-2)及び(A-3)以外の染料を併用することもできる。ただし、成分(A)による染色性に影響を与えない観点より、アゾ染料(A-1)、(A-2)及び(A-3)の総含有量が、全染料中の１質量％以上100質量％以下、更には５質量％以上100質量％以下、更には10質量％以上100質量％以下、更には20質量％以上100質量％以下であることが好ましい。 The total content of the azo dye in the total composition is preferably 0.005% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.05% by mass or more, and further preferably 0.1% by mass, from the viewpoint of the stability of the formulation. % Or more, preferably 5% by mass or less, more preferably 3% by mass or less, further preferably 2.5% by mass or less, still more preferably 1.5% by mass or less, and further preferably 1% by mass or less. The hair dye composition of the present invention may be used in combination with a dye other than the azo dyes (A-1), (A-2) and (A-3). However, the total content of the azo dyes (A-1), (A-2) and (A-3) is 1% by mass or more in the total dyes from the viewpoint of not affecting the dyeability of the component (A). It is preferably 100% by mass or less, more preferably 5% by mass or more and 100% by mass or less, further 10% by mass or more and 100% by mass or less, and further preferably 20% by mass or more and 100% by mass or less.
〔酸化染料〕
本発明の染毛剤組成物が二剤式又は三剤式である場合、第１剤中には前記アゾ染料に加え、酸化染料を配合することもできる。本発明の染毛剤組成物に好適な酸化染料としては、通常染毛剤に使用されている公知のプレカーサー及びカップラーを用いることができる。
[Oxidative dye]
When the hair dye composition of the present invention is a two-part or three-part type, in addition to the azo dye, an oxidation dye can be blended in the first agent. As an oxidation dye suitable for the hair dye composition of the present invention, known precursors and couplers that are usually used in hair dyes can be used.
プレカーサーとしては、例えばパラフェニレンジアミン、トルエン-2,5-ジアミン、2-クロロパラフェニレンジアミン、パラアミノフェノール、パラメチルアミノフェノール、オルトアミノフェノール、2,4-ジアミノフェノール、N-フェニルパラフェニレンジアミンとこれらの塩等が挙げられる。 Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloroparaphenylenediamine, paraaminophenol, paramethylaminophenol, orthoaminophenol, 2,4-diaminophenol, and N-phenylparaphenylenediamine. These salts are mentioned.
また、カップラーとしては、例えばメタフェニレンジアミン、2,4-ジアミノフェノキシエタノール、メタアミノフェノール、2-メチル-5-アミノフェノール、2-メチル-5-（2-ヒドロキシエチルアミノ）フェノール、レゾルシン、1-ナフトール、1,5-ジヒドロキシナフタレン、ヒロドキノンとこれらの塩等が挙げられる。 Examples of couplers include metaphenylenediamine, 2,4-diaminophenoxyethanol, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, resorcin, 1- Examples thereof include naphthol, 1,5-dihydroxynaphthalene, hydroquinone and their salts.
プレカーサーとカップラーは、それぞれ単独で又は２種以上を組み合わせて用いてもよく、その全組成物中の総含有量は、上記アゾ染料の染色性に影響を与えない程度の含有量であることが好ましく、好ましくは0.01質量％以上、より好ましくは0.1質量％以上、また好ましくは５質量％以下、より好ましくは３質量％、更に好ましくは２質量％以下、更に好ましくは１質量％以下、更に好ましくは0.5質量％以下である。 The precursor and the coupler may be used alone or in combination of two or more, and the total content in the total composition may be a content that does not affect the dyeability of the azo dye. Preferably, it is 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, more preferably 3% by mass, still more preferably 2% by mass or less, still more preferably 1% by mass or less, still more preferably. Is 0.5 mass% or less.
〔成分(A)以外の直接染料〕
本発明の染毛剤組成物には、上記アゾ染料(A-1)、(A-2)、及び(A-3)以外の直接染料を更に配合することができる。本発明の染毛剤組成物が二剤式染毛剤である場合は、第１剤中に上記アゾ染料(A-1)、(A-2)、及び(A-3)以外の直接染料を更に配合することができる。この直接染料としては、染毛剤に利用可能である公知の酸性染料、塩基性染料、分散染料等を用いることができる。
[Direct dyes other than component (A)]
The hair dye composition of the present invention may further contain a direct dye other than the azo dyes (A-1), (A-2), and (A-3). When the hair dye composition of the present invention is a two-component hair dye, a direct dye other than the azo dyes (A-1), (A-2), and (A-3) in the first agent Can be further blended. As this direct dye, known acid dyes, basic dyes, disperse dyes and the like that can be used in hair dyes can be used.
酸性染料としては、例えば青色１号、紫色401号、黒色401号、だいだい色205号、赤色227号、赤色106号、黄色203号、酸性橙３等が挙げられる。塩基性染料としては、例えば塩基性青99、塩基性茶16、塩基性茶17、塩基性赤76、塩基性黄57等が挙げられる。 Examples of the acid dye include Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No. 203, and Acid Orange 3. Examples of the basic dye include basic blue 99, basic brown 16, basic brown 17, basic red 76, basic yellow 57, and the like.
酸性染料及び塩基性染料以外の直接染料としては、例えば2-ニトロ-p-フェニレンジアミン、2-アミノ-6-クロロ-4-ニトロフェノール、3-ニトロ-p-ヒドロキシエチルアミノフェノール、4-ニトロ-o-フェニレンジアミン、4-アミノ-3-ニトロフェノール、4-ヒドロキシプロピルアミノ-3-ニトロフェノール、N,N-ビス（2-ヒドロキシエチル）-2-ニトロ-p-フェニレンジアミン、分散紫１、分散青１、分散黒９、HC青２、HC橙１、HC赤１、HC赤３、HC黄２、HC黄４、HC黄５等が挙げられる。 Examples of direct dyes other than acid dyes and basic dyes include 2-nitro-p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, and 4-nitro. -o-phenylenediamine, 4-amino-3-nitrophenol, 4-hydroxypropylamino-3-nitrophenol, N, N-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, dispersed purple 1 , Dispersion blue 1, dispersion black 9, HC blue 2, HC orange 1, HC red 1, HC red 3, HC yellow 2, HC yellow 4, HC yellow 5, and the like.
これらアゾ染料(A-1)、(A-2)、及び(A-3)以外の直接染料は、単独で又は２種以上を組み合わせて用いることができ、その全組成物中の含有量は、好ましくは0.001質量％以上、より好ましくは0.01質量％以上であり、また好ましくは５質量％以下、より好ましくは３質量％以下、更に好ましくは２質量％以下、更に好ましくは１質量％以下、更に好ましくは0.5質量％以下である。 Direct dyes other than these azo dyes (A-1), (A-2), and (A-3) can be used alone or in combination of two or more, and the content in the total composition is , Preferably 0.001% by mass or more, more preferably 0.01% by mass or more, and preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 2% by mass or less, still more preferably 1% by mass or less, More preferably, it is 0.5 mass% or less.
〔成分(B)：カチオン界面活性剤〕
本発明の染毛剤組成物は、成分(B)として、カチオン界面活性剤を含有する。カチオン界面活性剤としては、次の一般式(1)で表されるものを用いることができる。
[Component (B): Cationic surfactant]
The hair dye composition of the present invention contains a cationic surfactant as component (B). As the cationic surfactant, one represented by the following general formula (1) can be used.
〔式中、Ｒ1、Ｒ2、Ｒ3及びＲ4は、独立に水素原子又は炭化水素基を示し、Ｒ1、Ｒ2、Ｒ3及びＲ4のうち１つ又は２つは炭素数８〜36の炭化水素基であって、かつ残余が水素原子又は炭素数１〜７の炭化水素基である。Ｘ-はアニオンを示す。〕 [Wherein R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom or a hydrocarbon group, and one or two of R 1 , R 2 , R 3 and R 4 have 8 carbon atoms. -36 hydrocarbon group, and the remainder is a hydrogen atom or a hydrocarbon group having 1 to 7 carbon atoms. X − represents an anion. ]
ここで炭化水素基としては、直鎖又は分岐鎖のアルキル基、直鎖又は分岐鎖のアルケニル基、アリール基、アラルキル基が挙げられる。 Here, examples of the hydrocarbon group include a linear or branched alkyl group, a linear or branched alkenyl group, an aryl group, and an aralkyl group.
Ｒ1、Ｒ2、Ｒ3及びＲ4のうち１つ又は２つ（好ましくは１つ）が、直鎖若しくは分岐鎖の炭素数８〜30、更には炭素数10〜24、更には炭素数12〜18のアルキル基であることが好ましく、残余が水素原子又は炭素数１〜３のアルキル基、更には炭素数１もしくは２のアルキル基、更には炭素数１のアルキル基であることが好ましい。 One or two (preferably one) of R 1 , R 2 , R 3 and R 4 is a linear or branched carbon group having 8 to 30 carbon atoms, more preferably 10 to 24 carbon atoms, and even more carbon atoms. It is preferably a 12-18 alkyl group, and the remainder is preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, further an alkyl group having 1 or 2 carbon atoms, and further an alkyl group having 1 carbon atom. .
アニオンとしては、塩化物イオン、臭化物イオン、ヨウ化物イオン、メチル硫酸イオン、エチル硫酸イオン、酢酸イオン、リン酸イオン、硫酸イオン、乳酸イオン、サッカリンイオンが挙げられ、なかでも入手の容易性の観点から塩化物イオン及び臭化物イオンが好ましい。 Examples of the anion include chloride ion, bromide ion, iodide ion, methyl sulfate ion, ethyl sulfate ion, acetate ion, phosphate ion, sulfate ion, lactate ion, and saccharin ion. To chloride and bromide ions are preferred.
成分(B)としては、染毛後の毛髪に対して優れた感触を付与させる観点から、塩化モノアルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、臭化モノアルキルトリメチルアンモニウムが好ましく、なかでも塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウムがより好ましく、これらの混合物もまた好ましい。 Component (B) is preferably monoalkyltrimethylammonium chloride, dialkyldimethylammonium chloride, monoalkyltrimethylammonium bromide, and lauryltrimethylammonium chloride from the viewpoint of imparting an excellent feel to the hair after dyeing. More preferred are cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride, and mixtures thereof are also preferred.
カチオン界面活性剤は、二種以上を併用することもできる。全組成中におけるカチオン界面活性剤の含有量は、染毛後の毛髪に対して優れた感触を付与させる観点から、好ましくは0.05質量％以上、より好ましくは0.1質量％以上、更に好ましくは0.3質量％以上であり、また、好ましくは20質量％以下、より好ましくは18質量％以下、更に好ましくは15質量％以下、更に好ましくは10質量％以下、更に好ましくは５質量％以下、更に好ましくは３質量％以下、更に好ましくは1.5質量％以下、更に好ましくは１質量％以下である。 Two or more cationic surfactants can be used in combination. The content of the cationic surfactant in the total composition is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.3% by mass, from the viewpoint of imparting an excellent feel to the hair after dyeing. % Or more, preferably 20% by mass or less, more preferably 18% by mass or less, still more preferably 15% by mass or less, still more preferably 10% by mass or less, still more preferably 5% by mass or less, and further preferably 3%. It is not more than mass%, more preferably not more than 1.5 mass%, still more preferably not more than 1 mass%.
〔成分(B)以外の界面活性剤〕
本発明の染毛剤組成物は、成分(B)以外の界面活性剤として、非イオン界面活性剤、両性界面活性剤、アニオン界面活性剤を含有させることができる。
[Surfactants other than component (B)]
The hair dye composition of the present invention can contain a nonionic surfactant, an amphoteric surfactant, and an anionic surfactant as a surfactant other than the component (B).
非イオン界面活性剤としては、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルケニルエーテル、高級脂肪酸ショ糖エステル、ポリグリセリン脂肪酸エステル、高級脂肪酸モノ又はジエタノールアミド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステル、アルキルサッカライド、アルキルアミンオキサイド、アルキルアミドアミンオキサイド等が挙げられる。これらのうち、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油、アルキルサッカライドが好ましく、ポリオキシエチレンアルキル(12〜14)エーテル、アルキルポリグルコシドがより好ましい。 Nonionic surfactants include polyoxyalkylene alkyl ether, polyoxyalkylene alkenyl ether, higher fatty acid sucrose ester, polyglycerin fatty acid ester, higher fatty acid mono- or diethanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid Examples thereof include esters, polyoxyethylene sorbite fatty acid esters, alkyl saccharides, alkylamine oxides, and alkylamidoamine oxides. Of these, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, and alkyl saccharide are preferred, and polyoxyethylene alkyl (12-14) ether and alkyl polyglucoside are more preferred.
両性界面活性剤としてはイミダゾリン、カルボベタイン、アミドベタイン、スルホベタイン、ヒドロキシスルホベタイン、アミドスルホベタイン等が挙げられ、アルキルジメチルアミノ酢酸ベタイン、脂肪酸アミドプロピルベタイン等のベタイン界面活性剤がより好ましく、脂肪酸アミドプロピルベタインが更に好ましい。 Examples of amphoteric surfactants include imidazoline, carbobetaine, amide betaine, sulfobetaine, hydroxysulfobetaine, amide sulfobetaine, and the like, and betaine surfactants such as alkyldimethylaminoacetic acid betaine and fatty acid amidopropyl betaine are more preferable. More preferred is amidopropyl betaine.
アニオン界面活性剤としては、アルキルベンゼンスルホン酸塩、アルキル又はアルケニルエーテル硫酸塩、アルキル又はアルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α-スルホ脂肪酸塩、Ｎ-アシルアミノ酸、リン酸モノ又はジエステル、スルホコハク酸エステル等が挙げられる。アルキルエーテル硫酸塩としては、ポリオキシエチレンアルキルエーテル硫酸塩が挙げられる。これらアニオン界面活性剤のアニオン性基の対イオンとしては、ナトリウムイオン、カリウムイオン等のアルカリ金属イオン；カルシウムイオン、マグネシウムイオン等のアルカリ土類金属イオン；アンモニウムイオン；炭素数２又は３のアルカノール基を１〜３個有するアルカノールアミン（例えばモノエタノールアミン、ジエタノールアミン、トリエタノールアミン、トリイソプロパノールアミン等）が挙げられる。 Anionic surfactants include alkyl benzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates, Examples include α-sulfo fatty acid salts, N-acyl amino acids, phosphoric acid mono- or diesters, and sulfosuccinic acid esters. Examples of the alkyl ether sulfate include polyoxyethylene alkyl ether sulfate. Counter ions of the anionic group of these anionic surfactants include alkali metal ions such as sodium ion and potassium ion; alkaline earth metal ions such as calcium ion and magnesium ion; ammonium ion; alkanol group having 2 or 3 carbon atoms Alkanolamines having 1 to 3 (for example, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.).
これら成分(B)以外の界面活性剤は、二種以上を併用することもでき、全組成中の含有量は、良好な感触、乳化性能の観点から、好ましくは0.1質量％以上、より好ましくは0.2質量％以上、更に好ましくは0.5質量％以上であり、また好ましくは30質量％以下、より好ましくは25質量％以下、更に好ましくは20質量％以下、更に好ましくは10質量％以下、更に好ましくは５質量％以下、更に好ましくは３質量％以下、更に好ましくは1.5質量％以下である。 Surfactants other than these components (B) can be used in combination of two or more, and the content in the total composition is preferably 0.1% by mass or more, more preferably from the viewpoint of good feel and emulsification performance. 0.2% by mass or more, more preferably 0.5% by mass or more, and preferably 30% by mass or less, more preferably 25% by mass or less, still more preferably 20% by mass or less, still more preferably 10% by mass or less, still more preferably. It is 5 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 1.5 mass% or less.
〔成分(C)：塩酸、炭酸又は硫酸のアルカリ金属塩〕
本発明の染毛剤組成物は、成分(C)として、使用時に良好な感触を付与する観点から、塩酸、炭酸及び硫酸からなる群より選択される酸のアルカリ金属塩の少なくとも１種を0.1質量％以上５質量％以下含有する。
[Component (C): Alkali metal salt of hydrochloric acid, carbonic acid or sulfuric acid]
The hair dye composition of the present invention contains, as component (C), at least one alkali metal salt of an acid selected from the group consisting of hydrochloric acid, carbonic acid and sulfuric acid from the viewpoint of imparting a good feel during use. It is contained in an amount of 5% to 5% by mass.
成分(C)の塩酸、炭酸又は硫酸のアルカリ金属塩とは、塩酸、炭酸又は硫酸の水素原子の一部又は全部を、アルカリ金属で置換した化合物である。染毛処理後に毛髪を乾燥したときの感触の点からカリウム塩、ナトリウム塩が好ましい。具体的には、塩化ナトリウム、塩化カリウム、炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム、炭酸水素カリウム、硫酸ナトリウム、硫酸カリウム、が挙げられる。 The alkali metal salt of hydrochloric acid, carbonic acid or sulfuric acid of component (C) is a compound in which part or all of the hydrogen atoms of hydrochloric acid, carbonic acid or sulfuric acid are substituted with an alkali metal. A potassium salt and a sodium salt are preferable from the viewpoint of touch when the hair is dried after the hair dyeing treatment. Specific examples include sodium chloride, potassium chloride, sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, sodium sulfate, and potassium sulfate.
これら成分(C)は、二種以上を併用することもでき、全組成物中における含有量は、成分(A)と成分(B)を難溶性の塩を形成することなく安定に配合させる観点から、0.1質量％以上であり、好ましくは0.2質量％以上、より好ましくは0.3質量％以上、更に好ましくは0.6質量％以上であり、また、乾燥した状態での毛髪の感触の観点から、８質量％以下であり、好ましくは６質量％以下、より好ましくは５質量％以下、更に好ましくは４質量％以下、更に好ましくは３質量％以下である。 These components (C) can also be used in combination of two or more, the content in the total composition is a viewpoint of stably blending the components (A) and (B) without forming a hardly soluble salt From 0.1% by mass, preferably 0.2% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.6% by mass or more, and 8% by mass from the viewpoint of the feel of the hair in a dry state. % Or less, preferably 6% by mass or less, more preferably 5% by mass or less, still more preferably 4% by mass or less, and further preferably 3% by mass or less.
全組成中における成分(A)と成分(C)との合計に対する成分(B)の質量比(B)／[(A)＋(C)]は、染色性及び剤安定性を向上させる観点から、好ましくは0.01以上、より好ましくは0.05以上、好ましくは0.08以上、より好ましくは0.15以上であり、また好ましくは６以下、より好ましくは４以下、更に好ましくは３以下、更に好ましくは１以下、更に好ましくは0.9以下である。 The mass ratio (B) / [(A) + (C)] of the component (B) to the sum of the components (A) and (C) in the total composition is from the viewpoint of improving dyeability and agent stability. , Preferably 0.01 or more, more preferably 0.05 or more, preferably 0.08 or more, more preferably 0.15 or more, preferably 6 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 1 or less, Preferably it is 0.9 or less.
〔アルカリ剤〕
本発明の染毛剤組成物には、更にアルカリ剤を含有させることができる。本発明の染毛剤組成物が二剤式又は三剤式の場合は、アルカリ剤は第１剤に含有させる。アルカリ剤としては、アンモニア及びその塩、水酸化ナトリウム、水酸化カリウム、モノエタノールアミン、イソプロパノールアミン、2-アミノ-2-メチルプロパノール、2-アミノブタノール等のアルカノールアミン及びその塩、1,3-プロパンジアミン等のアルカンジアミン及びその塩、炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、炭酸水素カリウム、炭酸グアニジン等の炭酸塩等が挙げられる。
[Alkaline agent]
The hair dye composition of the present invention may further contain an alkali agent. When the hair dye composition of the present invention is a two-part or three-part type, the alkaline agent is contained in the first agent. Alkaline agents include ammonia and salts thereof, sodium hydroxide, potassium hydroxide, monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, 2-aminobutanol and other alkanolamines and salts thereof, 1,3- Examples include alkanediamines such as propanediamine and salts thereof, and carbonates such as sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, and guanidine carbonate.
アルカリ剤は、２種以上を併用してもよく、全組成物中の含有量は、十分な染毛効果の点から、0.01質量％以上、更には0.05質量％以上、更には0.1質量％以上、更には0.2質量％以上が好ましく、また、毛髪損傷や頭皮刺激の低減の点から、20質量％以下、更には10質量％以下、更には５質量％以下、更には４質量％以下が好ましい。 Two or more alkali agents may be used in combination, and the content in the total composition is 0.01% by mass or more, further 0.05% by mass or more, and further 0.1% by mass or more from the viewpoint of sufficient hair dyeing effect. Furthermore, 0.2% by mass or more is preferable, and from the viewpoint of reducing hair damage and scalp irritation, 20% by mass or less, further 10% by mass or less, further 5% by mass or less, and further 4% by mass or less are preferable. .
〔pH調整剤〕
本発明の染毛剤組成物は、所望のpHとするために、pH調整剤として、前記のアルカリ剤のほか、塩酸、リン酸等の無機酸、クエン酸、グリコール酸、乳酸等の有機酸等を使用することができる。
(PH adjuster)
In order to obtain a desired pH, the hair dye composition of the present invention includes an inorganic acid such as hydrochloric acid and phosphoric acid, an organic acid such as citric acid, glycolic acid, and lactic acid in addition to the alkaline agent as a pH adjuster. Etc. can be used.
〔酸化剤〕
本発明の染毛剤組成物が二剤式又は三剤式の場合には、第２剤は酸化剤を含有する。この場合、染色と脱色が同時に行われ、より鮮やかな染色が得られる。本発明で用いるアゾ染料は、酸化剤に対して極めて安定である。
〔Oxidant〕
When the hair dye composition of the present invention is a two-part or three-part type, the second agent contains an oxidizing agent. In this case, dyeing and decoloring are performed simultaneously, and a more vivid dyeing is obtained. The azo dye used in the present invention is extremely stable against an oxidizing agent.
酸化剤としては、例えば、過酸化水素；過硫酸アンモニウム、過硫酸カリウム、過硫酸ナトリウム等の過硫酸塩；過ホウ酸ナトリウム等の過ホウ酸塩；過炭酸ナトリウム等の過炭酸塩；臭素酸ナトリウム、臭素酸カリウム等の臭素酸塩などが挙げられる。なかでも、毛髪に対する脱色性及び酸化剤自体の安定性及び有効性の点から、過酸化水素が好ましい。また、過酸化水素と共に、酸化助剤として他の酸化剤を組み合わせて用いることもできる。このうち、過酸化水素と過硫酸塩とを組み合わせて用いるのが好ましい。 Examples of the oxidizing agent include hydrogen peroxide; persulfates such as ammonium persulfate, potassium persulfate, and sodium persulfate; perborates such as sodium perborate; percarbonates such as sodium percarbonate; sodium bromate; And bromates such as potassium bromate. Among these, hydrogen peroxide is preferable from the viewpoint of decolorization to hair and the stability and effectiveness of the oxidizing agent itself. In addition to hydrogen peroxide, other oxidizing agents can be used in combination as an oxidizing aid. Of these, it is preferable to use a combination of hydrogen peroxide and persulfate.
酸化剤を用いる場合、酸化剤は単独で又は２種以上を組み合わせて用いることができ、全組成中の含有量は、十分な染毛効果の点から0.1質量％以上、更には0.5質量％以上、更には1.0質量％以上が好ましく、また、毛髪損傷や頭皮刺激の低減の点から、12.0質量％以下、更には9.0質量％以下、更には6.0質量％以下が好ましい。 When the oxidizing agent is used, the oxidizing agent can be used alone or in combination of two or more, and the content in the whole composition is 0.1% by mass or more, further 0.5% by mass or more from the viewpoint of sufficient hair dyeing effect. Further, it is preferably 1.0% by mass or more, and from the viewpoint of reducing hair damage and scalp irritation, it is preferably 12.0% by mass or less, more preferably 9.0% by mass or less, and further preferably 6.0% by mass or less.
過酸化水素と過硫酸塩とを組み合わせて用いる場合には、過酸化水素の含有量が、全組成中の0.5質量％以上10質量％以下であり、過硫酸塩の含有量が全組成中の0.5質量％以上25質量％以下であり、両者の合計含有量が１質量％以上30質量％以下であるのが好ましい。 When hydrogen peroxide and persulfate are used in combination, the hydrogen peroxide content is 0.5% by mass or more and 10% by mass or less in the total composition, and the persulfate content is in the total composition. It is preferably 0.5% by mass or more and 25% by mass or less, and the total content of both is preferably 1% by mass or more and 30% by mass or less.
〔水溶性高分子〕
本発明の染毛剤組成物には、使用時のたれ落ち防止、頭皮などへの汚着防止の目的で、水溶性高分子を含有させることができる。水溶性高分子としては、例えばアラビアガム、カラギーナン、カラヤガム、トラガカントガム、キャロブガム、クインスシード（マルメロ）、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アルギン酸ナトリウム、メチルセルロース、エチルセルロース、カルボキシメチルセルロース（CMC）、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ポリビニルアルコール（PVA）、ポリビニルメチルエーテル（PVM）、ポリビニルピロリドン（PVP）、ポリアクリル酸ナトリウム、ローカストビーンガム、グアーガム、タマリントガム、ジアルキルジメチルアンモニウム硫酸セルロース、キサンタンガム、変性キサンタンガム、ウェランガム、ラボールガム、ジェランガム、カルボキシビニルポリマー、アクリル酸／メタクリル酸エステル共重合体、メチルビニルエーテル／無水マレイン酸共重合体の1,9-デカジエンによる部分架橋物、ポリエチレングリコール、ケイ酸アルミニウムマグネシウム、ベントナイト等が挙げられる。これらのうち、ヒドロキシエチルセルロース、キサンタンガム、変性キサンタンガムが好ましい。
(Water-soluble polymer)
The hair dye composition of the present invention may contain a water-soluble polymer for the purpose of preventing sagging during use and preventing staining on the scalp. Examples of water-soluble polymers include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, carboxymethylcellulose (CMC), hydroxyethylcellulose , Hydroxypropyl cellulose, polyvinyl alcohol (PVA), polyvinyl methyl ether (PVM), polyvinyl pyrrolidone (PVP), sodium polyacrylate, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, modified xanthan gum, welan gum, Labor gum, gellan gum, carboxyvinyl polymer, acrylic acid / metac Le ester copolymers, partially crosslinked products by 1,9 decadiene methyl vinyl ether / maleic anhydride copolymer, polyethylene glycol, magnesium aluminum silicate, bentonite and the like. Of these, hydroxyethyl cellulose, xanthan gum, and modified xanthan gum are preferred.
これらの水溶性高分子は、単独で又は２種以上を組み合わせて使用することができ、全組成中における含有量は、好ましくは0.1質量％以上、より好ましくは0.5質量％以上であり、また、好ましくは10質量％以下、より好ましくは５質量％以下である。 These water-soluble polymers can be used alone or in combination of two or more, and the content in the whole composition is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less.
〔コンディショニング成分〕
本発明の染毛剤組成物は、毛髪への適用に好適なコンディショニング成分を含むことができる。コンディショニング成分は、染毛剤組成物に溶解又は分散可能なポリマー又はオイル類であり、染毛剤組成物を洗い流す際、又は水やシャンプーで希釈された際に毛髪へ付着する。
[Conditioning ingredients]
The hair dye composition of the present invention can contain a conditioning component suitable for application to hair. The conditioning component is a polymer or oil that can be dissolved or dispersed in the hair dye composition, and adheres to the hair when the hair dye composition is washed away or diluted with water or shampoo.
本発明の染毛剤組成物に使用される好適なコンディショニング成分としては、カチオン性ポリマー、シリコーン（例えばシリコーンオイル、カチオン性シリコーン、シリコーンガム、シリコーン樹脂）、有機コンディショニングオイル（例えば、炭化水素オイル、ポリオレフィン、脂肪酸エステル）、脂肪族アミド、ポリアルキレングリコール等が挙げられる。 Suitable conditioning components for use in the hair dye composition of the present invention include cationic polymers, silicones (eg, silicone oils, cationic silicones, silicone gums, silicone resins), organic conditioning oils (eg, hydrocarbon oils, Polyolefin, fatty acid ester), aliphatic amide, polyalkylene glycol and the like.
これらコンディショニング成分は、単独で又は２種類以上を組み合わせて使用することができ、またその全組成物中の含有量は、好ましくは0.01質量％以上、より好ましくは0.05質量％以上、更に好ましくは0.5質量％以上であり、また、好ましくは20質量％以下、より好ましくは15質量％以下、更に好ましくは５質量％以下である。 These conditioning components can be used alone or in combination of two or more, and the content in the total composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.5%. It is at least 20% by mass, preferably at most 20% by mass, more preferably at most 15% by mass, still more preferably at most 5% by mass.
〔有機溶剤〕
本発明の染毛剤組成物は、有機溶剤を含有してもよい。有機溶剤としては、エタノール、1-プロパノール、2-プロパノール等の低級アルカノール、ベンジルアルコール、2-ベンジルオキシエタノール、フェノキシエタノール等の芳香族アルコール、プロピレングリコール、1,3-ブタンジオール、ジエチレングリコール、グリセリン等のポリオール、エトキシエタノール、エトキシジグリコール、メトキシエタノール等のエーテルアルコール、N-メチルピロリドン、N-エチルピロリドン等のN-アルキルピロリドン；炭酸プロピレン等の炭酸アルキレン；γ-バレロラクトン、γ-カプロラクトン等のラクトンが挙げられる。
〔Organic solvent〕
The hair dye composition of the present invention may contain an organic solvent. Examples of organic solvents include lower alkanols such as ethanol, 1-propanol and 2-propanol, aromatic alcohols such as benzyl alcohol, 2-benzyloxyethanol and phenoxyethanol, propylene glycol, 1,3-butanediol, diethylene glycol and glycerin. Polyols, ether alcohols such as ethoxyethanol, ethoxydiglycol and methoxyethanol, N-alkylpyrrolidones such as N-methylpyrrolidone and N-ethylpyrrolidone; alkylene carbonates such as propylene carbonate; lactones such as γ-valerolactone and γ-caprolactone Is mentioned.
これら有機溶剤は、単独で又は２種類以上を組み合わせて使用することができ、またその全組成物中の含有量は、好ましくは0.1質量％以上、より好ましくは１質量％以上、更に好ましくは２質量％以上であり、また好ましくは35質量％以下、より好ましくは30質量％以下、更に好ましくは25質量％以下である。 These organic solvents can be used alone or in combination of two or more, and the content in the total composition is preferably 0.1% by mass or more, more preferably 1% by mass or more, and further preferably 2%. It is at least 35% by mass, preferably at most 35% by mass, more preferably at most 30% by mass, still more preferably at most 25% by mass.
〔媒体〕
本発明の染毛剤組成物には、媒体として水が使用される。染毛剤組成物中の水の含有量は、10質量％以上、更には20質量％以上、更に30質量％以上、更には40質量％以上、更には50質量％以上が好ましく、また、95質量％以下、更には90質量％以下、更には85質量％以下が好ましい。
[Medium]
In the hair dye composition of the present invention, water is used as a medium. The content of water in the hair dye composition is preferably 10% by mass or more, more preferably 20% by mass or more, further 30% by mass or more, further 40% by mass or more, and further preferably 50% by mass or more. It is preferably not more than mass%, more preferably not more than 90 mass%, and further preferably not more than 85 mass%.
〔その他の任意成分〕
本発明の染毛剤組成物には、上記成分のほかに、通常化粧品原料として用いられる他の成分を加えることができる。
[Other optional ingredients]
In addition to the above components, other components that are usually used as cosmetic raw materials can be added to the hair dye composition of the present invention.
このような任意成分の配合目的としては、パール化、防腐、金属封鎖、安定化、酸化防止、紫外線吸収、保湿、製品着色、付香等を挙げることができ、具体的な任意成分としては、動植物油脂、高級脂肪酸、タンパク質加水分解物、タンパク質誘導体、アミノ酸、植物抽出物、ビタミン、色素、香料等が挙げられる。 Examples of the purpose of blending such optional components include pearling, antiseptic, metal sequestering, stabilization, antioxidant, ultraviolet absorption, moisture retention, product coloring, fragrance, etc. As specific optional components, Examples include animal and vegetable oils and fats, higher fatty acids, protein hydrolysates, protein derivatives, amino acids, plant extracts, vitamins, pigments, and fragrances.
〔剤型〕
本発明の染毛剤組成物は、一剤式、二剤式、又は三剤式の各種染毛剤として使用できる。一剤式染毛剤組成物は、成分(A)を含有する単一の剤からなる。二剤式染毛剤組成物は、成分(A)及びアルカリ剤を含有する第１剤と、過酸化水素を含有する第２剤からなることが好ましい。三剤式染毛剤組成物は、アルカリ剤を含有する第１剤と、過酸化水素を含有する第２剤と、成分(A)を含有する第３剤からなるか、又は成分(A)及びアルカリ剤を含有する第１剤と、過酸化水素を含有する第２剤と、その他の成分を含有する第３剤からなることが好ましい。上記のその他の成分を含有する第３剤としては脱色力向上のために過硫酸塩（過硫酸アンモニウム、過硫酸カリウム、過硫酸ナトリウム等）等の造粒物からなる粉末状酸化剤を用いることが好ましい。
なお、本発明において「全組成物」とは、染毛処理の使用時の組成物全体をいい、上述の二剤式染毛剤にあっては、第１剤と第２剤を混合した後の混合物を意味し、三剤式染毛剤にあっては、第１剤と第２剤と第３剤を混合した後の混合物を意味する。
[Drug type]
The hair dye composition of the present invention can be used as various one-part, two-part, or three-part hair dyes. The one-pack hair dye composition comprises a single agent containing component (A). The two-component hair dye composition preferably comprises a first agent containing component (A) and an alkaline agent, and a second agent containing hydrogen peroxide. The three-component hair dye composition comprises a first agent containing an alkaline agent, a second agent containing hydrogen peroxide, and a third agent containing component (A), or component (A) And a first agent containing an alkali agent, a second agent containing hydrogen peroxide, and a third agent containing other components. As the third agent containing the above-mentioned other components, a powdery oxidizer made of a granulated material such as persulfate (ammonium persulfate, potassium persulfate, sodium persulfate, etc.) may be used to improve decolorization power. preferable.
In the present invention, the “total composition” refers to the entire composition at the time of use of the hair dyeing treatment. In the above-mentioned two-component hair dye, after mixing the first agent and the second agent In the case of a three-part hair dye, it means a mixture after mixing the first agent, the second agent and the third agent.
本発明の染毛剤組成物は、例えば、液状、乳液状、クリーム状、ゲル状、ペースト状、ムース状等の形態で用いられるものとすることができ、エアゾール形態とすることもできる。これらの場合における全組成物の粘度は、毛髪に塗布したときに液だれしにくいように調整することが望ましい。この全組成物の粘度（25℃）は、ヘリカルスタンド付きＢ型回転粘度計（モデル；デジタル粘度計TVB-10、東機産業株式会社）により、ローターT-Cを用いて10rpmで１分間回転させた後の測定値として、好ましくは2,000〜100,000mPa・s、より好ましくは2,000〜200,000mPa・s、更に好ましくは4,000〜150,000mPa・s、更に好ましくは6,000〜100,000mPa・s、更に好ましくは8,000〜80,000mPa・sである。なお、二剤式又は三剤式の場合には、各剤の混合後３分経過後に測定するものとする。 The hair dye composition of the present invention can be used, for example, in the form of liquid, emulsion, cream, gel, paste, mousse, etc., and can also be in the form of an aerosol. It is desirable to adjust the viscosity of the entire composition in these cases so that it does not easily drip when applied to the hair. The viscosity (25 ° C.) of this whole composition was rotated at 10 rpm for 1 minute using a rotor TC by a B-type rotational viscometer with a helical stand (model; digital viscometer TVB-10, Toki Sangyo Co., Ltd.). The measured value is preferably 2,000 to 100,000 mPa · s, more preferably 2,000 to 200,000 mPa · s, more preferably 4,000 to 150,000 mPa · s, still more preferably 6,000 to 100,000 mPa · s, and still more preferably 8,000 to 80,000mPa · s. In addition, in the case of a two-part type or a three-part type, the measurement shall be made after 3 minutes have elapsed since the mixing of each agent.
また、本発明の染毛剤組成物は、毛髪に塗布するときにノンエアゾールのフォーマー容器から吐出させたり、カップ内でシェークして発泡させたりして泡状として使用することもできる。この場合における発泡前の全組成物の粘度も、泡状として毛髪に塗布したときに液だれしにくいように調整することが望ましい。この全組成物の粘度（25℃）は、Ｂ型回転粘度計（モデル；デジタル粘度計TV-10、東機産業株式会社）により、ローターNo.1を用いて30rpmで１分間回転させた後の測定値（但し、粘度が160mPa・sを超える場合は、12rpmで１分間回転させた後の測定値）として、好ましくは１〜800mPa・s、より好ましくは１〜600mPa・s、更に好ましくは１〜500mPa・s、更に好ましくは１〜300mPa・sである。なお、二剤式又は三剤式の場合には、各剤の混合後３分経過後に測定するものとする。 The hair dye composition of the present invention can also be used in the form of foam by being discharged from a non-aerosol foamer container when applied to hair, or by shaking in a cup and foaming. In this case, the viscosity of the entire composition before foaming is also preferably adjusted so that it does not easily drip when applied to the hair as a foam. The viscosity (25 ° C.) of this entire composition was rotated for 1 minute at 30 rpm using a rotor No. 1 with a B-type rotational viscometer (model; Digital Viscometer TV-10, Toki Sangyo Co., Ltd.). The measured value (however, when the viscosity exceeds 160 mPa · s, the measured value after rotating for 1 minute at 12 rpm) is preferably 1 to 800 mPa · s, more preferably 1 to 600 mPa · s, still more preferably 1 to 500 mPa · s, more preferably 1 to 300 mPa · s. In addition, in the case of a two-part type or a three-part type, the measurement shall be made after 3 minutes have elapsed since the mixing of each agent.
〔pH〕
本発明の染毛剤組成物のpH（25℃）は、良好な染毛効果と皮膚刺激抑制の点から、使用時（二剤式又は三剤式の場合は混合時）において、7.5以上、好ましくは８以上、より好ましくは8.5以上、更に好ましくは９以上であり、また、12以下、好ましくは11.5以下、より好ましくは11以下である。また、本発明の染毛剤組成物が二剤式染毛剤である場合、第１剤のpH（25℃）は８以上12以下、第２剤のpH（25℃）は２以上５以下が好ましい。なお、本明細書において、染毛剤組成物のpHは、HORIBA社製pHメーターF-22とHORIBA社製pH電極6367-10Dを用いて室温（25℃）で測定した値である。
[PH]
The pH (25 ° C.) of the hair dye composition of the present invention is 7.5 or more at the time of use (during mixing in the case of two-part or three-part type) from the viewpoint of good hair dyeing effect and suppression of skin irritation. Preferably it is 8 or more, more preferably 8.5 or more, still more preferably 9 or more, and 12 or less, preferably 11.5 or less, more preferably 11 or less. When the hair dye composition of the present invention is a two-component hair dye, the pH of the first agent (25 ° C.) is 8 or more and 12 or less, and the pH of the second agent (25 ° C.) is 2 or more and 5 or less. Is preferred. In the present specification, the pH of the hair dye composition is a value measured at room temperature (25 ° C.) using a HORIBA pH meter F-22 and a HORIBA pH electrode 6367-10D.
〔染毛剤組成物の製造方法〕
本発明の染毛剤組成物が一剤式の場合、染毛剤組成物の安定性の観点から、成分(B)と成分(C)を混合した後、得られた混合物と成分(A)を混合するか、又は、成分(A)と成分(C)を混合した後、得られた混合物と成分(B)を混合して調製することが好ましい。また、本発明の染毛剤組成物が二剤式又は三剤式であって第１剤中に成分(A)〜(C)の全てを含有する場合も、当該第１剤は、染毛剤組成物の安定性の観点から、成分(B)と成分(C)を混合した後、得られた混合物と成分(A)を混合するか、又は、成分(A)と成分(C)を混合した後、得られた混合物と成分(B)を混合して調製することが好ましい。
〔染毛方法〕
本発明の染毛剤組成物を用いて染毛処理するには、例えば本発明の染毛剤組成物（二剤式の場合は第１剤と第２剤、三剤式の場合は第１剤と第２剤と第３剤を使用直前に混合した後）を毛髪に適用し、所定時間放置後、洗い流し、乾燥すればよい。本発明の染毛剤組成物は、毛髪質量に対して0.1倍〜10倍量を適用し、毛髪への適用温度は15〜45℃、適用時間は１〜60分間、更には３〜45分間、更には５〜30分間が好ましい。
[Method for producing hair dye composition]
When the hair dye composition of the present invention is a one-pack type, from the viewpoint of the stability of the hair dye composition, after mixing component (B) and component (C), the resulting mixture and component (A) It is preferable to prepare by mixing the components (A) and (C), and then mixing the resulting mixture and the component (B). Further, when the hair dye composition of the present invention is a two-part or three-part type and contains all of the components (A) to (C) in the first agent, the first agent is also a hair dye. From the viewpoint of the stability of the agent composition, after mixing component (B) and component (C), the resulting mixture and component (A) are mixed, or component (A) and component (C) are mixed. After mixing, it is preferable to prepare by mixing the resulting mixture and component (B).
[Hair dyeing method]
For hair dyeing treatment using the hair dye composition of the present invention, for example, the hair dye composition of the present invention (first agent and second agent in the case of two agents, first in the case of three agents). After mixing the agent, the second agent, and the third agent immediately before use), the mixture is applied to the hair, left standing for a predetermined time, rinsed and dried. The hair dye composition of the present invention is applied in an amount of 0.1 to 10 times the hair mass, the application temperature to the hair is 15 to 45 ° C., the application time is 1 to 60 minutes, and further 3 to 45 minutes. Furthermore, 5 to 30 minutes are preferable.
以上述べた実施形態に関し、以下に本発明の好ましい態様を更に開示する。 With respect to the embodiments described above, preferred aspects of the present invention will be further disclosed below.
＜１＞ 次の成分(A)、(B)及び(C)を含有し、使用時のpH（25℃）が7.5以上12以下である染毛剤組成物。
(A)：下記(A-1)、(A-2)及び(A-3)からなる群より選択される１種又は２種以上のアゾ染料
<1> A hair dye composition comprising the following components (A), (B) and (C), and having a pH (25 ° C.) of 7.5 or more and 12 or less when used.
(A): One or more azo dyes selected from the group consisting of (A-1), (A-2) and (A-3) below
(B)：カチオン界面活性剤
(C)：塩酸、炭酸及び硫酸からなる群より選択される酸のアルカリ金属塩の少なくとも１種 0.1質量％以上５質量％以下
(B): Cationic surfactant
(C): At least one alkali metal salt of an acid selected from the group consisting of hydrochloric acid, carbonic acid and sulfuric acid 0.1% by mass to 5% by mass
＜２＞ 全組成中における成分(A)の総含有量が、好ましくは0.005質量％以上、より好ましくは0.01質量％以、更に好ましくは0.05質量％以上、更に好ましくは0.1質量％以上であり、また、好ましくは５質量％以下、より好ましくは３質量％以下、更に好ましくは2.5質量％以下、更に好ましくは1.5質量％以下、更に好ましくは１質量％以下である、＜１＞に記載の染毛剤組成物。 <2> The total content of component (A) in the total composition is preferably 0.005% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.05% by mass or more, and further preferably 0.1% by mass or more. The dye according to <1>, preferably 5% by mass or less, more preferably 3% by mass or less, further preferably 2.5% by mass or less, further preferably 1.5% by mass or less, and further preferably 1% by mass or less. Hair composition.
＜３＞ 成分(B)が、好ましくは下記一般式(1)で表されるカチオン界面活性剤である、＜１＞又は＜２＞に記載の染毛剤組成物。 <3> The hair dye composition according to <1> or <2>, wherein the component (B) is preferably a cationic surfactant represented by the following general formula (1).
〔式中、Ｒ1、Ｒ2、Ｒ3及びＲ4は、独立に水素原子又は炭化水素基を示し、Ｒ1、Ｒ2、Ｒ3及びＲ4のうち１つ又は２つは炭素数８〜36の炭化水素基であって、かつ残余が水素原子又は炭素数１〜７の炭化水素基である。Ｘ-はアニオンを示す。〕 [Wherein R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom or a hydrocarbon group, and one or two of R 1 , R 2 , R 3 and R 4 have 8 carbon atoms. -36 hydrocarbon group, and the remainder is a hydrogen atom or a hydrocarbon group having 1 to 7 carbon atoms. X − represents an anion. ]
＜４＞ 成分(B)が、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、及び塩化ベヘニルトリメチルアンモニウムからなる群より選択される１種又は２種以上である、＜３＞に記載の染毛剤組成物。 <4> The component (B) is one or more selected from the group consisting of lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride, according to <3>. Hair dye composition.
＜５＞ 全組成中における成分(B)の含有量が、好ましくは0.05質量％以上、より好ましくは0.1質量％以上、更に好ましくは0.3質量％以上であり、また、好ましくは20質量％以下、より好ましくは18質量％以下、更に好ましくは15質量％以下、更に好ましくは10質量％以下、更に好ましくは５質量％以下、更に好ましくは３質量％以下、更に好ましくは1.5質量％以下、更に好ましくは１質量％以下である、＜１＞〜＜４＞のいずれか一項に記載の染毛剤組成物。 <5> The content of the component (B) in the total composition is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more, and preferably 20% by mass or less. More preferably, it is 18 mass% or less, More preferably, it is 15 mass% or less, More preferably, it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 1.5 mass% or less, More preferably Is 1 mass% or less, The hair dye composition as described in any one of <1>-<4>.
＜６＞ 成分(C)が、好ましくは塩化ナトリウム、塩化カリウム、炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム、炭酸水素カリウム、硫酸ナトリウム、及び硫酸カリウムからなる群より選択される１種又は２種以上である、＜１＞〜＜５＞のいずれか一項に記載の染毛剤組成物。 <6> Component (C) is preferably one or more selected from the group consisting of sodium chloride, potassium chloride, sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, sodium sulfate, and potassium sulfate The hair dye composition according to any one of <1> to <5>.
＜７＞ 全組成中における成分(C)の含有量が、好ましくは0.2質量％以上、より好ましくは0.3質量％以上、更に好ましくは0.6質量％以上であり、また、好ましくは６質量％以下、より好ましくは５質量％以下、更に好ましくは４質量％以下、更に好ましくは３質量％以下である、＜１＞〜＜６＞のいずれか一項に記載の染毛剤組成物。 <7> The content of the component (C) in the total composition is preferably 0.2% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.6% by mass or more, and preferably 6% by mass or less. More preferably, it is 5 mass% or less, More preferably, it is 4 mass% or less, More preferably, it is 3 mass% or less, The hair dye composition as described in any one of <1>-<6>.
＜８＞ 全組成中における成分(A)と成分(C)との合計に対する成分(B)の質量比(B)／[(A)＋(C)]が、好ましくは0.01以上、より好ましくは0.05以上、好ましくは0.08以上、より好ましくは0.15以上であり、また好ましくは６以下、より好ましくは４以下、更に好ましくは３以下、更に好ましくは１以下、更に好ましくは0.9以下である、＜１＞〜＜７＞のいずれか一項に記載の染毛剤組成物。 <8> The mass ratio (B) / [(A) + (C)] of component (B) to the sum of component (A) and component (C) in the total composition is preferably 0.01 or more, more preferably 0.05 or more, preferably 0.08 or more, more preferably 0.15 or more, preferably 6 or less, more preferably 4 or less, further preferably 3 or less, still more preferably 1 or less, still more preferably 0.9 or less, <1 The hair dye composition according to any one of> to <7>.
＜９＞ 好ましくは、更にアルカリ剤を含有する＜１＞〜＜８＞のいずれか一項に記載の染毛剤組成物。 <9> The hair dye composition according to any one of <1> to <8>, preferably further containing an alkali agent.
＜10＞ 全組成中におけるアルカリ剤の含有量が、好ましくは0.01質量％以上、より好ましくは0.05質量％以上、更に好ましくは0.1質量％以上、更に好ましくは0.2質量％以上であり、また、好ましくは20質量％以下、より好ましくは10質量％以下、更に好ましくは５質量％以下、更に好ましくは４質量％以下である、＜９＞に記載の染毛剤組成物。 <10> The content of the alkali agent in the total composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, further preferably 0.2% by mass or more, and preferably The hair dye composition according to <9>, wherein is 20% by mass or less, more preferably 10% by mass or less, further preferably 5% by mass or less, and further preferably 4% by mass or less.
＜11＞ 二剤式又は三剤式染毛剤であり、好ましくは第２剤に酸化剤を含有する、＜１＞〜＜10＞のいずれか一項に記載の染毛剤組成物。 <11> The hair dye composition according to any one of <1> to <10>, which is a two-component or three-component hair dye, and preferably contains an oxidizing agent in the second agent.
＜12＞ 全組成中における酸化剤の含有量が、好ましくは0.1質量％以上、より好ましくは0.5質量％以上、更に好ましくは1.0質量％以上であり、また、好ましくは12.0質量％以下、より好ましくは9.0質量％以下、更に好ましくは6.0質量％以下である、＜11＞に記載の染毛剤組成物。 <12> The content of the oxidizing agent in the total composition is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1.0% by mass or more, and preferably 12.0% by mass or less, more preferably Is 9.0 mass% or less, More preferably, it is 6.0 mass% or less, The hair dye composition as described in <11>.
＜13＞ 25℃におけるpHが、使用時において、好ましくは８以上、より好ましくは8.5以上、更に好ましくは９以上であり、また、好ましくは11.5以下、より好ましくは11以下である、＜１＞〜＜12＞のいずれか一項に記載の染毛剤組成物。 <13> The pH at 25 ° C. is preferably 8 or more, more preferably 8.5 or more, still more preferably 9 or more, and preferably 11.5 or less, more preferably 11 or less in use. <1> Hair dye composition as described in any one of-<12>.
＜14＞ ＜１＞〜＜13＞のいずれか一項に記載の染毛剤組成物を毛髪に適用し、１〜60分間放置した後、洗い流す染毛方法。 <14> A hair dyeing method in which the hair dye composition according to any one of <1> to <13> is applied to hair, left standing for 1 to 60 minutes, and then washed away.
実施例１〜５及び比較例１〜２
表１に示す組成からなる染毛剤組成物（一剤式染毛剤）を下記方法により調製した。得られた染毛剤組成物について、以下の方法によって、配合時の沈殿の有無、染色性、剤すすぎ時の感触の評価を行った。これらの結果を表１に併せて示す。
〔染毛剤組成物の調製方法〕
水に成分(C)を配合し、溶解したのを確認後、成分(B)を添加し、一定時間撹拌を行い、混合液１を調製する。また、別途、水にモノエタノールアミンと成分(A-2)を溶解させた混合液２を調製した。そして混合液１に混合液２を配合し、一定時間撹拌を行うことで染毛剤組成物を得た。
Examples 1-5 and Comparative Examples 1-2
A hair dye composition (one-component hair dye) having the composition shown in Table 1 was prepared by the following method. About the obtained hair dye composition, the presence or absence of the precipitation at the time of a mixing | blending, dyeing | staining property, and the touch at the time of agent rinsing were evaluated by the following methods. These results are also shown in Table 1.
[Method for preparing hair dye composition]
After confirming that the component (C) is blended and dissolved in water, the component (B) is added, and the mixture is stirred for a predetermined time to prepare a mixed solution 1. Separately, a mixed solution 2 in which monoethanolamine and component (A-2) were dissolved in water was prepared. And the liquid mixture 2 was mix | blended with the liquid mixture 1, and the hair dye composition was obtained by stirring for a fixed time.
〔剤安定性〕
染毛剤組成物の安定性の評価は、第１剤及び第２剤の混合直後に次に示す基準に従って目視により確認した。
３：沈殿物がなく透明である
２：沈殿物はないが白濁している
１：沈殿物が存在する
[Agent stability]
Evaluation of the stability of the hair dye composition was confirmed by visual observation according to the following criteria immediately after mixing the first agent and the second agent.
3: There is no precipitate and it is transparent 2: There is no precipitate but it is cloudy 1: There is a precipitate
〔染色性〕
染毛剤組成物を中国人白髪１ｇの毛束に浴比（剤：毛髪）＝１：１で塗布し、30℃で20分放置した後、約40℃の水ですすぎ、市販のシャンプーで洗浄、水洗した。次いで、市販のヘアリンスを塗布した後、約40℃の水ですすぎ、タオルで拭き、ドライヤーで乾燥させた。
得られた染毛直後の毛束の色合いを、色差計（コニカミノルタセンシング社製、色彩色差計CR-400）を用いてCIE表色系（Ｌ*,ａ*,ｂ*）で計測し、染色前の色合いとの差を下記式により求めて染色性ΔＥ*とした。ΔＥ*が大きいほど染色性が優れていることを示す。
[Dyeability]
Apply the hair dye composition to 1g of Chinese white hair at a bath ratio (agent: hair) = 1: 1, leave it at 30 ° C for 20 minutes, rinse with water at about 40 ° C, and use a commercial shampoo. Washed and washed with water. Next, after applying a commercial hair rinse, it was rinsed with water at about 40 ° C., wiped with a towel, and dried with a dryer.
The color of the resulting hair bundle immediately after dyeing is measured with a CIE color system (L * , a * , b * ) using a color difference meter (manufactured by Konica Minolta Sensing Co., Ltd., color difference meter CR-400), The difference from the color before dyeing was determined by the following formula and was defined as dyeability ΔE * . The larger ΔE *, the better the dyeability.
〔式中、Ｌ* 0、ａ* 0及びｂ* 0は、それぞれ染色前の毛束のＬ*、ａ*及びｂ*の値を示し、Ｌ* 1、ａ* 1及びｂ* 1は、それぞれ染色直後のＬ*、ａ*及びｂ*の値を示す。〕 [In the formula, L * 0 , a * 0 and b * 0 represent the values of L * , a * and b * of the hair bundle before dyeing, respectively, L * 1 , a * 1 and b * 1 are The values of L * , a * and b * immediately after staining are shown, respectively. ]
〔剤すすぎ時の感触〕
欧米人毛髪を用いて幅５cm、長さ23cm、重さ８ｇの毛束を作製した。染毛剤組成物を毛束に浴比（剤：毛髪）＝１：１で塗布し、30℃で20分放置した後、約40℃の水中で、すすぐ際の指通り性を、コミングフォース測定機によって測定した。コミングフォース測定機は、毛束をロードセルに繋がるフックに吊し、デンマンブラシ（デンマン社製のデンマンブラシD-3（全長204mm、行数７））を２本用いて挟みこんだ状態で毛束をコミングした
時にロードセルで検出される力を、読み取るもので、指通り性を定量的に評価する手法である（J. Soc. Cosmet. Chem., 37, 111-124 (May/June 1986) 参照）。毛束を10回分コミングした時にロードセルで検出される力の平均値をコミングフォース測定値とした。コミングフォース（ｇ）が小さいほど、剤すすぎ時の感触に優れることを示す。
[Feel when rinsing]
A hair bundle having a width of 5 cm, a length of 23 cm, and a weight of 8 g was prepared using Western hair. Apply the hair dye composition to the hair bundle at a bath ratio (agent: hair) = 1: 1, leave it at 30 ° C. for 20 minutes, and then comb the fingering property when rinsing in water at about 40 ° C. It was measured with a force measuring machine. The Coming Force measuring machine hangs the hair bundle on the hook connected to the load cell, and uses two Denman brushes (Denman brush D-3 (total length: 204mm, number of rows: 7)) to sandwich the hair. This is a method to read the force detected by the load cell when the bundle is combed, and is a technique for quantitatively evaluating fingering (J. Soc. Cosmet. Chem., 37, 111-124 (May / June 1986) reference). The average value of the force detected by the load cell when the hair bundle was combed 10 times was defined as the coming force measurement value. It shows that it is excellent in the feel at the time of agent rinsing, so that a coming force (g) is small.
表１に示すとおり、実施例１〜５の染毛剤組成物は、剤安定性、染色性、剤すすぎ時の感触の全てに優れているのに対して、比較例１は、実施例１〜５に比べて剤すすぎ時の感触の点で劣っており、比較例２は、実施例１〜５に比べて剤安定性、染色性、剤すすぎ時の感触の全ての点で劣っていた。 As shown in Table 1, the hair dye compositions of Examples 1 to 5 are excellent in all of the agent stability, dyeability, and feel during agent rinsing, while Comparative Example 1 is in Example 1. Compared to Examples 5-5, the feel at the time of agent rinsing was inferior, and Comparative Example 2 was inferior to Examples 1-5 in all aspects of the agent stability, dyeability, and feel at the time of agent rinsing. .
実施例６〜10及び比較例３〜４
表２に示す組成からなる染毛剤組成物（二剤式染毛剤）の第１剤と第２剤とを下記方法により調製した。第１剤は、表１に示す一剤式染毛剤と同じものである。表２に示す第１剤と第２剤とを１：１で混合した染毛剤組成物を用いて、上記と同様に、染色性、剤すすぎ時の感触の評価を行った。評価結果を表２に併せて示す。
〔第１剤の調製方法〕
水に成分(C)を配合し、溶解したのを確認後、成分(B)を添加し、一定時間撹拌を行い、混合液１を調製した。また、別途、水にモノエタノールアミンと成分(A-2)を溶解させた混合液２を調製した。そして、混合液１に混合液２を配合し、一定時間撹拌を行うことで第１剤を得た。
〔第２剤の調製方法〕
水に過酸化水素及びエチドロン酸を配合し、一定時間撹拌を行うことで第２剤を得た。
Examples 6 to 10 and Comparative Examples 3 to 4
A first agent and a second agent of a hair dye composition (two-component hair dye) having the composition shown in Table 2 were prepared by the following method. The first agent is the same as the one-component hair dye shown in Table 1. Using the hair dye composition in which the first agent and the second agent shown in Table 2 were mixed at a ratio of 1: 1, the dyeability and the feel when rinsing the agent were evaluated in the same manner as described above. The evaluation results are also shown in Table 2.
[Method for preparing first agent]
After confirming that the component (C) was blended and dissolved in water, the component (B) was added, and the mixture was stirred for a certain time to prepare a mixed solution 1. Separately, a mixed solution 2 in which monoethanolamine and component (A-2) were dissolved in water was prepared. And the liquid mixture 2 was mix | blended with the liquid mixture 1, and the 1st agent was obtained by stirring for a fixed time.
[Method for preparing second agent]
Hydrogen peroxide and etidronic acid were mixed in water, and the second agent was obtained by stirring for a certain time.
表１の第１剤としての安定性の評価結果、及び表２の評価結果より、実施例６〜10の染毛剤組成物は、染色性、剤すすぎ時の感触の全てに優れているのに対して、比較例３は、実施例６〜10に比べて剤すすぎ時の感触の点で劣っており、比較例４は、実施例６〜10に比べて染色性の点で劣っていた。 From the evaluation results of the stability as the first agent in Table 1 and the evaluation results in Table 2, the hair dye compositions of Examples 6 to 10 are excellent in all of the dyeability and the feel when rinsing the agent. On the other hand, the comparative example 3 was inferior in the point of the feel at the time of agent rinsing compared with Examples 6-10, and the comparative example 4 was inferior in the point of dyeability compared with Examples 6-10. .
実施例11及び比較例５
表３に示す組成からなる染毛剤組成物（一剤式染毛剤）を下記方法により調製した。得られた染毛剤組成物について、上記と同様に、剤安定性、染色性、剤すすぎ時の感触の評価を行った。評価結果を表３に併せて示す。
〔染毛剤組成物の調製方法〕
水に塩化アンモニウムと成分(C)を配合し、溶解したのを確認後、成分(B)を添加し、一定時間撹拌を行い、混合液１を調製した。また、別途、水にアンモニアと成分(A-1)〜(A-3)を溶解させた混合液２を調製した。そして、混合液１に混合液２を配合し、一定時間撹拌を行うことで、染毛剤組成物を得た。
Example 11 and Comparative Example 5
A hair dye composition (one-component hair dye) having the composition shown in Table 3 was prepared by the following method. The resulting hair dye composition was evaluated for agent stability, dyeability, and feel during agent rinsing in the same manner as described above. The evaluation results are also shown in Table 3.
[Method for preparing hair dye composition]
After confirming that ammonium chloride and component (C) were mixed and dissolved in water, component (B) was added, and the mixture was stirred for a certain period of time to prepare mixture 1. Separately, a mixed solution 2 in which ammonia and components (A-1) to (A-3) were dissolved in water was prepared. And the liquid mixture 2 was mix | blended with the liquid mixture 1, and the hair dye composition was obtained by stirring for a fixed time.
表３に示すとおり、実施例11の染毛剤組成物は、剤安定性、染色性、剤すすぎ時の感触全てに優れているのに対して、比較例５は、実施例11に比べて剤安定性、染色性、剤すすぎ時の感触の全ての点で劣っていた。 As shown in Table 3, the hair dye composition of Example 11 is superior in all of agent stability, dyeability, and feel during agent rinsing, while Comparative Example 5 is more in comparison with Example 11. It was inferior in all aspects of agent stability, dyeability, and feel during agent rinsing.
実施例12〜17
表４に示す組成からなる染毛剤組成物（一剤式染毛剤）を下記方法より調製した。得られた染毛剤組成物について、染色性と配合時の沈殿の有無の評価を行った。評価結果を表４に併せて示す。
〔染毛剤組成物の調製方法〕
水に塩化アンモニウム、アルキルグルコシド及び成分(C)を配合し、溶解したのを確認後、成分(B)を添加し、一定時間撹拌を行い、混合液１を調製した。また、別途、水にアンモニアと成分(A-2)を溶解させた混合液２を調製した。そして、混合液１に混合液２を配合し、一定時間撹拌を行うことで染毛剤組成物を得た。
Examples 12-17
A hair dye composition (one-component hair dye) having the composition shown in Table 4 was prepared by the following method. About the obtained hair dye composition, dyeing property and the presence or absence of the precipitation at the time of a mixing | blending were evaluated. The evaluation results are also shown in Table 4.
[Method for preparing hair dye composition]
After mixing ammonium chloride, alkyl glucoside and component (C) in water and confirming that they were dissolved, component (B) was added and stirred for a certain period of time to prepare mixture 1. Separately, a mixed solution 2 in which ammonia and the component (A-2) were dissolved in water was prepared. And the liquid mixture 2 was mix | blended with the liquid mixture 1, and the hair dye composition was obtained by stirring for a fixed time.
*１：花王社製 コータミン60W
*２：花王社製 コータミン24P
*３：花王社製 マイドール10
* 1: Cotamin 60W manufactured by Kao Corporation
* 2: Cotamin 24P manufactured by Kao Corporation
* 3 Myodoll 10 manufactured by Kao
Claims (6)
(A)：下記(A-1)、(A-2)及び(A-3)からなる群より選択される１種又は２種以上のアゾ染料
(C)：塩酸、炭酸及び硫酸からなる群より選択される酸のアルカリ金属塩の少なくとも１種 0.1質量％以上８質量％以下 A hair dye composition comprising the following components (A), (B) and (C), and having a pH (25 ° C.) of 7.5 or more and 12 or less at the time of use.
(A): One or more azo dyes selected from the group consisting of (A-1), (A-2) and (A-3) below
(C): at least one alkali metal salt of an acid selected from the group consisting of hydrochloric acid, carbonic acid and sulfuric acid 0.1% by mass to 8% by mass
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| JP2014117909A JP6403442B2 (en) | 2014-06-06 | 2014-06-06 | Hair dye composition |
| TW109144397A TWI744138B (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| TW104118384A TWI716352B (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| PCT/JP2015/066279 WO2015186815A1 (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| BR112016028639-1A BR112016028639B1 (en) | 2014-06-06 | 2015-06-05 | composition of hair dye and method for dyeing hair |
| CN201580029830.XA CN106456493B (en) | 2014-06-06 | 2015-06-05 | Hair coloring preparation composition |
| US15/316,291 US10470990B2 (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| SG10201806680XA SG10201806680XA (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| SG11201610204TA SG11201610204TA (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| EP15802537.9A EP3153152B1 (en) | 2014-06-06 | 2015-06-05 | Hair dye composition |
| US16/591,170 US10772815B2 (en) | 2014-06-06 | 2019-10-02 | Hair dye composition |
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| JPH03170413A (en) * | 1989-11-30 | 1991-07-24 | Sunstar Inc | Two-pack type hair dyeing agent |
| JP2003342139A (en) * | 2002-05-28 | 2003-12-03 | Kao Corp | Hair dye composition |
| JP2010006804A (en) * | 2008-05-30 | 2010-01-14 | Kao Corp | Two agent type foamy hair dyestuff |
| JP2010024158A (en) * | 2008-07-16 | 2010-02-04 | Kao Corp | Hair dye composition |
| EP2883531A1 (en) * | 2013-12-13 | 2015-06-17 | Kao Corporation | Bleaching and coloring composition for hair |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03170413A (en) * | 1989-11-30 | 1991-07-24 | Sunstar Inc | Two-pack type hair dyeing agent |
| JP2003342139A (en) * | 2002-05-28 | 2003-12-03 | Kao Corp | Hair dye composition |
| JP2010006804A (en) * | 2008-05-30 | 2010-01-14 | Kao Corp | Two agent type foamy hair dyestuff |
| JP2010024158A (en) * | 2008-07-16 | 2010-02-04 | Kao Corp | Hair dye composition |
| EP2883531A1 (en) * | 2013-12-13 | 2015-06-17 | Kao Corporation | Bleaching and coloring composition for hair |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015229667A (en) * | 2014-06-06 | 2015-12-21 | 花王株式会社 | Hair dye composition |
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