JP2015218981A - Method and device for removing deposit in water tube boiler - Google Patents
Method and device for removing deposit in water tube boiler Download PDFInfo
- Publication number
- JP2015218981A JP2015218981A JP2014104370A JP2014104370A JP2015218981A JP 2015218981 A JP2015218981 A JP 2015218981A JP 2014104370 A JP2014104370 A JP 2014104370A JP 2014104370 A JP2014104370 A JP 2014104370A JP 2015218981 A JP2015218981 A JP 2015218981A
- Authority
- JP
- Japan
- Prior art keywords
- water tube
- pipe
- cleaning
- water
- dry ice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 129
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000004140 cleaning Methods 0.000 claims abstract description 93
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 40
- 235000011089 carbon dioxide Nutrition 0.000 claims abstract description 40
- 238000002347 injection Methods 0.000 claims abstract description 18
- 239000007924 injection Substances 0.000 claims abstract description 18
- 238000005507 spraying Methods 0.000 claims abstract description 9
- 239000008188 pellet Substances 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 7
- 239000013049 sediment Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 208000031872 Body Remains Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Incineration Of Waste (AREA)
Abstract
Description
本発明は、水管ボイラ内の水管外表面に付着する堆積物の除去技術に関する。詳細には、水管ボイラ内の水管外表面に付着する堆積物にドライアイス噴射し、堆積物を剥離除去する技術に関する。 The present invention relates to a technique for removing deposits adhering to an outer surface of a water pipe in a water pipe boiler. More specifically, the present invention relates to a technique of spraying dry ice on deposits adhering to the outer surface of a water tube in a water tube boiler, and separating and removing the deposits.
一般に、水管ボイラ内の水管外表面に付着する堆積物(硫黄分を含んだ燃焼灰など)の除去には、水管を内蔵するボイラ筒などの容器に水・薬品等を投入しプール状にして堆積物を溶出する「プール工法」(特許文献1)、水管の外表面に水・薬品・ドライアイスなどで構成する圧力液体あるいはマイクロバブルを噴射し堆積物を剥離除去する「液体吹付工法」(特許文献2、特許文献3)が行われている。 Generally, in order to remove deposits (such as combustion ash containing sulfur) attached to the outer surface of the water tube in the water tube boiler, water, chemicals, etc. are poured into a container such as a boiler tube with a built-in water tube to form a pool. “Pool construction method” for eluting deposits (Patent Document 1), “Liquid spraying method” for peeling and removing deposits by spraying pressure liquid or microbubbles composed of water, chemicals, dry ice, etc. on the outer surface of water pipe ( Patent Documents 2 and 3) have been performed.
また、水管ではない一般の構造物等に付着した堆積物の除去には、ドライアイスを噴射し、堆積物を除去する「ドライアイス工法」(非特許文献1)が行われている。 Further, for the removal of deposits attached to general structures or the like that are not water pipes, a “dry ice method” (Non-patent Document 1) in which dry ice is sprayed to remove deposits is performed.
「プール工法」による特許文献1は、スラッジを除去しようとする対象を洗浄液にて浸
漬させるステップ1と、洗浄液の温度と圧力を変化させ、洗浄液に気泡を発生させるステップ2と、温度を上昇させ、スラッジの除去を促進するステップ3からなる沈積スラッジの物理化学的洗浄方法が開示されている。この場合、ステップ2は、洗浄液に気体窒素、液体窒素、及びドライアイスからなる群より選択される少なくとも一種を注入して温度と圧力を変化させ、気泡を発生させるものである。
Patent Document 1 based on the “Pool Method” includes a step 1 in which an object to remove sludge is immersed in a cleaning liquid, a step 2 in which the temperature and pressure of the cleaning liquid are changed to generate bubbles in the cleaning liquid, and a temperature increase. A method of physicochemical cleaning of deposited sludge comprising step 3 of promoting sludge removal is disclosed. In this case, in Step 2, at least one selected from the group consisting of gaseous nitrogen, liquid nitrogen, and dry ice is injected into the cleaning liquid to change the temperature and pressure to generate bubbles.
この方法は、スラッジを除去しようとする対象を洗浄液にて浸漬させる前提であるため、非常に大規模な洗浄となり、かつ、洗浄液の廃液処理に対する設備の対応が必要となり、非常に大がかりな洗浄となることで設備費が高いものとなる。さらには、洗浄液に浸漬させるための水密構造であることが要求されるため、予め洗浄を考慮した設備構成とすることが必要であった。 Since this method is based on the premise that the object to be removed of sludge is immersed in the cleaning liquid, it becomes a very large-scale cleaning, and it is necessary to cope with the waste liquid treatment of the cleaning liquid. As a result, the equipment cost becomes high. Furthermore, since it is required to have a watertight structure for immersing in the cleaning liquid, it is necessary to have an equipment configuration that considers cleaning in advance.
「液体吹付工法」による特許文献2は、ボイラ燃焼室内に設けられた伝熱管群の中に複数のガイドパイプを設け、このガイドパイプに洗浄パイプを挿入し、その洗浄パイプから洗浄水を噴射させることで伝熱管群の外表面を洗浄するものである。 In Patent Document 2 based on the “liquid spraying method”, a plurality of guide pipes are provided in a heat transfer tube group provided in a boiler combustion chamber, a cleaning pipe is inserted into the guide pipe, and cleaning water is injected from the cleaning pipe. This cleans the outer surface of the heat transfer tube group.
この方法は、ボイラの新規の設置段階から、装置に組み込んだ洗浄機構とすることが必要であり、設備が複雑で高価なものとなる。また、洗浄パイプから洗浄水を噴射させる位置が固定化されているため、洗浄できる位置が限定される。水管ボイラの堆積物は、水ドラムに接続される水管の接続部周辺に多く発生するため、堆積物の除去が理想的にはいかない状況が発生する。 This method requires a cleaning mechanism incorporated in the apparatus from the new installation stage of the boiler, and the equipment becomes complicated and expensive. Moreover, since the position where the cleaning water is jetted from the cleaning pipe is fixed, the position where cleaning can be performed is limited. A lot of deposits in the water pipe boiler are generated around the connection portion of the water pipe connected to the water drum, so that a situation where the removal of the deposits is not ideal occurs.
さらに、ボイラ燃焼室内に洗浄機構を組み込む構造であるため、水管のみを内蔵するボイラ燃焼室と比較すると付着する堆積物がより多くなり、複雑となる。 Furthermore, since the cleaning mechanism is built into the boiler combustion chamber, the amount of deposits to be attached becomes more complex than that of the boiler combustion chamber having only a water pipe.
特許文献3は、ボイラ燃焼室内の伝熱管群に相対して水管洗浄装置を設け、該水管洗浄装置から洗浄水を噴射させ、伝熱管群の外表面堆積物を除去するものであり、伝熱管群と水管洗浄装置とが相対して、かつ、複数設けられている。 Patent Document 3 is provided with a water pipe cleaning device relative to a heat transfer tube group in a boiler combustion chamber, injecting cleaning water from the water pipe cleaning device, and removing deposits on the outer surface of the heat transfer tube group. A plurality of groups and water pipe cleaning devices are provided opposite to each other.
この方法は、ボイラの新規の設置段階から、装置に組み込んだ水管洗浄装置とすることが必要であり、設備が複雑で高価なものとなる。また、水管洗浄装置から洗浄水を噴射さ
せる位置が固定化されているため、洗浄できる範囲が限定される。水管ボイラの堆積物は、水ドラムに接続される水管の接続部周辺に多く発生するため、堆積物の除去が理想的にはいかない状況が発生する。
This method requires a water pipe cleaning device incorporated in the apparatus from the new installation stage of the boiler, and the equipment becomes complicated and expensive. Moreover, since the position where the cleaning water is jetted from the water pipe cleaning device is fixed, the cleaning range is limited. A lot of deposits in the water pipe boiler are generated around the connection portion of the water pipe connected to the water drum.
一方、非特許文献1には、一般の構造物等に付着した堆積物の除去方法として、ドライアイスペレットを圧縮空気と混合させ、噴射ノズルから噴射させることで熱収縮と体積膨張を利用し、洗浄対象物に付着した堆積物を剥離させる方法が開示されている。 On the other hand, Non-Patent Document 1 uses heat shrinkage and volume expansion by mixing dry ice pellets with compressed air and spraying from a spray nozzle as a method for removing deposits adhering to general structures, A method for peeling off deposits adhering to an object to be cleaned is disclosed.
ただ、この技術は、オープンスペースでの洗浄対象物に付着した堆積物を剥離するのには非常に効果を発揮するが、水管ボイラにおいては、水管の配置が複雑で狭隘であるため、中に入っての洗浄対象物に付着した堆積物の剥離ができず、表面的な洗浄となり、効果的な洗浄を実現することができなかった。 However, this technology is very effective in peeling off deposits attached to objects to be cleaned in an open space, but in a water tube boiler, the arrangement of water tubes is complicated and narrow. The deposit adhering to the object to be cleaned could not be peeled off, resulting in a superficial cleaning, and an effective cleaning could not be realized.
図5は、定格能力25t/h、伝熱面積353m2、最高使用圧力1.96MPa、常
用圧力1.47MPa、燃料にA重油(JIS1種1号)の水管ボイラの外壁を取り除いた状態をa)に、その外観をb)に、平面図をc)に、側面図をd)に示す。図5b)の白□で示す部分は、水管と水ドラムとの接続部であり、付着物が堆積しやすい個所である。このように、水管ボイラの水管部と水ドラム部は非常に狭隘部が多く、複雑な状況を呈している。
FIG. 5 shows a state in which the outer wall of the water tube boiler of A heavy oil (JIS type 1 No. 1) is removed as a fuel with a rated capacity of 25 t / h, a heat transfer area of 353 m 2 , a maximum working pressure of 1.96 MPa, a normal pressure of 1.47 MPa, and a The appearance is shown in b), the plan view in c), and the side view in d). The portion indicated by white square in FIG. 5b) is a connecting portion between the water pipe and the water drum, and is a portion where deposits are easily deposited. Thus, the water pipe part and water drum part of a water pipe boiler have many very narrow parts, and are presenting a complicated situation.
本例では、水ドラムに接続される水管は30mm間隔で1,400本程度に及び、一方向に直立しているため、複雑かつ狭隘であり、洗浄作業者の出入りができない構造であるため、付着した堆積物の剥離除去の作業性が悪く、効率の良い堆積物の剥離除去が困難となっていた。 In this example, the water pipe connected to the water drum is about 1,400 at intervals of 30 mm, and stands upright in one direction, so it is complicated and narrow, and the structure is incapable of entering and leaving the cleaning operator. The workability of peeling and removing the deposited deposit is poor, and it is difficult to peel and remove the deposit efficiently.
上記を勘案し、複雑かつ狭隘であっても、安価で、かつ簡略な構造で、洗浄対象物である水管に付着した堆積物の剥離を効率よく実現できる水管ボイラ内の堆積物除去方法及び装置が望まれていた。 In consideration of the above, even if it is complicated and narrow, it is cheap and has a simple structure, and a deposit removal method and apparatus in a water tube boiler that can efficiently achieve the separation of deposits attached to the water tube that is the object to be cleaned. Was desired.
本発明は、従来技術で記載した問題点に鑑み、水管ボイラ内が複雑かつ狭隘であっても、安価で、かつ簡略な構造で、洗浄対象物である水管に付着した堆積物の剥離を効率よく実現できる水管ボイラ内の堆積物除去方法及び装置を提供することを課題とする。 In view of the problems described in the prior art, the present invention efficiently removes deposits attached to a water pipe that is an object to be cleaned with an inexpensive and simple structure even if the inside of the water pipe boiler is complicated and narrow. It is an object of the present invention to provide a deposit removal method and apparatus in a water tube boiler that can be well realized.
本発明の第1の発明は、水管ボイラ内に圧力を印加したペレット状もしくはパウダー状のドライアイスを噴射させ、水管部外表面を洗浄する水管ボイラ内の堆積物除去方法であって、ドライアイスと圧縮空気とを混合する洗浄機本体と、前記洗浄機本体で製造したドライアイスと圧縮空気との混合気体である洗浄体をノズル部によって水管部外表面に吹き
付ける構成とし、水管部外表面に付着した堆積物を剥離する水管ボイラ内の堆積物除去方法である。
A first invention of the present invention is a method for removing deposits in a water tube boiler, in which a dry ice in the form of pellets or powder that has been pressurized is injected into the water tube boiler to clean the outer surface of the water tube part. And a cleaning body that mixes dry air and compressed air, and a cleaning body, which is a mixed gas of dry ice and compressed air manufactured by the cleaning body, is sprayed to the outer surface of the water pipe portion by the nozzle portion, It is the deposit removal method in the water pipe boiler which peels the deposited deposit.
本発明の第2の発明は、第1の発明に付加して、前記ノズル部は、複数の延長管を接続した延長管部と、延長管部の軸線方向に対してドライアイスと高圧の圧縮空気との混合気体の吹き出す方向を30〜60度とした噴射ノズル部とで構成する水管ボイラ内の堆積物除去方法である。 According to a second aspect of the present invention, in addition to the first aspect, the nozzle section includes an extension pipe section connecting a plurality of extension pipes, and compression of dry ice and high pressure in the axial direction of the extension pipe sections. It is the deposit removal method in the water tube boiler comprised with the injection nozzle part which made the direction which the mixed gas with air blows off 30-60 degrees.
本発明の第3の発明は、第1乃至第2の発明に付加して、前記延長管は、円筒状のパイプと、該パイプの一端に留め具によって袋ナットを自在に保持し、他端に、他の延長管の袋ナットと接続するための接続ネジとを備えた構成であり、前記水管部外表面に付着した堆積物を剥離する位置に合わせて、前記延長管を1個乃至複数個を組合わせて接続し延長管部とした水管ボイラ内の堆積物除去方法である。 According to a third aspect of the present invention, in addition to the first or second aspect, the extension pipe is configured to freely hold a cap nut with a cylindrical pipe and a fastener at one end of the pipe, and the other end. And a connection screw for connecting to a cap nut of another extension pipe, and one or a plurality of extension pipes are arranged in accordance with the position where the deposit adhered to the outer surface of the water pipe portion is peeled off. This is a method for removing deposits in a water pipe boiler that is connected in combination to form an extension pipe part.
本発明の第4の発明は、第1乃至第3の発明に付加して、前記ドライアイスは、ペレット状および/あるいはパウダー状である水管ボイラ内の堆積物除去方法である。 According to a fourth aspect of the present invention, in addition to the first to third aspects, the dry ice is a method for removing deposits in a water tube boiler in the form of pellets and / or powder.
本発明の第5の発明は、水管ボイラ内に圧力を印加したペレット状もしくはパウダー状のドライアイスを噴射させ、水管部外表面を洗浄する水管ボイラ内の堆積物除去方法であって、ドライアイスと圧縮空気とを混合する洗浄機本体と、前記洗浄機本体で製造したドライアイスと圧縮空気との混合気体である洗浄体をノズル部によって水管部外表面に吹き付ける構成とし、水管部外表面に付着した堆積物を剥離する水管ボイラ内の堆積物除去装置である。 According to a fifth aspect of the present invention, there is provided a method for removing deposits in a water tube boiler by spraying pellet-shaped or powder-shaped dry ice to which pressure is applied into the water tube boiler, and cleaning the outer surface of the water tube portion. And a cleaning body that mixes dry air and compressed air, and a cleaning body, which is a mixed gas of dry ice and compressed air manufactured by the cleaning body, is sprayed to the outer surface of the water pipe portion by the nozzle portion, It is the deposit removal apparatus in the water pipe boiler which peels off the deposited deposit.
本発明の第6の発明は、第5の発明に付加して、前記ノズル部は、複数の延長管を接続した延長管部と、延長管部の軸線方向に対してドライアイスと高圧の圧縮空気との混合気体の吹き出す方向を30〜60度とした噴射ノズル部とで構成する水管ボイラ内の堆積物除去装置である。 According to a sixth aspect of the present invention, in addition to the fifth aspect, the nozzle section includes an extension pipe section connected to a plurality of extension pipes, and compression of dry ice and high pressure with respect to the axial direction of the extension pipe sections. It is the deposit removal apparatus in the water tube boiler comprised with the injection nozzle part which made the direction which the mixed gas with air blows off 30-60 degrees.
本発明の第7の発明は、第5乃至6の発明に付加して、前記延長管は、円筒状のパイプと、該パイプの一端に留め具によって袋ナットを自在に保持し、他端に、他の延長管の袋ナットと接続するための留め具とを備えた構成であり、前記水管部外表面に付着した堆積物を剥離する位置に合わせて、前記延長管を1個乃至複数個を組合わせて接続し延長管部とした水管ボイラ内の堆積物除去装置である。 According to a seventh aspect of the present invention, in addition to the fifth to sixth aspects of the present invention, the extension pipe has a cylindrical pipe and a cap nut freely held by one end of the pipe and a second end at the other end. And a fastener for connecting with a cap nut of another extension pipe, and one or a plurality of the extension pipes according to the position where the deposit attached to the outer surface of the water pipe portion is peeled off. It is the deposit removal apparatus in the water pipe boiler which connected and combined as the extension pipe part.
本発明の第8の発明は、第5乃至7の発明に付加して、前記ドライアイスは、ペレット状および/あるいはパウダー状である水管ボイラ内の堆積物除去装置である。 According to an eighth aspect of the present invention, in addition to the fifth to seventh aspects of the present invention, the dry ice is a deposit removing device in a water tube boiler in the form of pellets and / or powder.
ここで、洗浄対象物に吹き付けるドライアイスと圧縮空気との混合気体を、以下、洗浄体と称して説明する。 Here, the mixed gas of dry ice and compressed air sprayed on the object to be cleaned will be described below as a cleaning body.
本発明によれば、
まず、洗浄作業者が入っていけないような狭隘部であっても、噴射ノズル部に延長管を複数個接続して狭隘部に挿入し、ノズルからの洗浄体の噴射によって水管ボイラ内の堆積物除去を精度良く、かつ効率よく行うことができる。
According to the present invention,
First, even in a narrow part where a cleaning worker cannot enter, a plurality of extension pipes are connected to the injection nozzle part and inserted into the narrow part, and the deposit in the water pipe boiler is ejected by the cleaning body from the nozzle. Removal can be performed accurately and efficiently.
また、延長管は堆積物を除去する位置に合わせて、数種類の延長管を接続することで、洗浄箇所への位置合わせを容易に行うことができる。噴射ノズル部のノズルについては、延長管の軸線に対して噴射方向が30〜60度とすることが可能であるため、狭隘部であ
っても洗浄体を洗浄箇所に合わせて精度よく噴射させることができる。
Further, the extension pipe can be easily aligned with the cleaning portion by connecting several kinds of extension pipes in accordance with the position where the deposit is removed. About the nozzle of the injection nozzle part, since the injection direction can be 30 to 60 degrees with respect to the axis of the extension pipe, the cleaning body can be accurately injected in accordance with the cleaning location even in a narrow part. Can do.
また、洗浄体がドライアイスと高圧の圧縮空気との混合気体であるため、洗浄後に洗浄体の残差物が残らず、洗浄体の後処理が不要である。 In addition, since the cleaning body is a mixed gas of dry ice and high-pressure compressed air, no residue of the cleaning body remains after cleaning, and no post-treatment of the cleaning body is necessary.
また、本発明の水管ボイラ内の堆積物除去装置は、コンプレッサ、洗浄機本体、噴射ノズル、延長管、ホース類の単位に分離することが可能であり、可搬性に優れている。 Moreover, the deposit removal apparatus in the water tube boiler of the present invention can be separated into units of a compressor, a washing machine body, a spray nozzle, an extension pipe, and hoses, and is excellent in portability.
一般的な堆積物の剥離、洗浄では、約10MPaの高圧洗浄であっても剥離が容易ではないが、本発明では1.6MPa程度の空気圧力で実現できるため、コンプレッサの容量を小さくでき、かつ、圧縮機からノズルまでの構成機器を比較的に低圧仕様とすることができ、安価な設備とすることができる。 In general peeling and cleaning of deposits, peeling is not easy even with high-pressure cleaning of about 10 MPa, but in the present invention, since it can be realized with an air pressure of about 1.6 MPa, the capacity of the compressor can be reduced, and The components from the compressor to the nozzle can be made to have a relatively low pressure specification, and inexpensive equipment can be obtained.
洗浄の品質では、従来の洗浄方法に比べて、本発明の堆積物の剥離、洗浄方法は、剥離、洗浄が確実になされるため、被洗浄対象物の錆び、堆積物の付着を防止することができ、腐食による被洗浄対象物の劣化を防止するとともに、水管ボイラの長寿命化を図ることができる。 Compared to conventional cleaning methods, the quality and quality of the cleaning of the deposit peeling and cleaning method according to the present invention ensures peeling and cleaning, so that the object to be cleaned is prevented from rusting and depositing. It is possible to prevent deterioration of the object to be cleaned due to corrosion, and to extend the life of the water tube boiler.
さらに、従来技術は、水管ボイラ内に内蔵する構成の洗浄装置のため、設備が大掛かりで高価であったが、本発明は分離可能な構成で、可搬性に優れているため、安価な装置とすることができる。 Furthermore, since the conventional technology is a cleaning device built in the water tube boiler, the equipment is large and expensive, but the present invention has a separable configuration and excellent portability, so can do.
本発明の水管ボイラ内の堆積物除去方法ならびに装置は、ドライアイスと圧縮空気とを混合する洗浄機本体と、前記洗浄機本体で製造したドライアイスと圧縮空気との混合気体である洗浄体をノズル部によって水管部外表面に吹き付ける構成とし、水管部外表面に付着した堆積物を剥離する。 The method and apparatus for removing deposits in a water tube boiler of the present invention includes a cleaning machine body that mixes dry ice and compressed air, and a cleaning body that is a mixed gas of dry ice and compressed air manufactured by the cleaning machine body. It is set as the structure sprayed on a water pipe part outer surface by a nozzle part, and the deposit adhering to a water pipe part outer surface is peeled.
前記ノズル部は、複数の延長管を接続した延長管部と、延長管部の軸線方向に対してドライアイスと高圧の圧縮空気との混合気体の吹き出す方向を30〜60度とした噴射ノズル部とで構成する。 The nozzle part includes an extension pipe part connected to a plurality of extension pipes, and an injection nozzle part in which a direction in which a mixed gas of dry ice and high-pressure compressed air is blown out is 30 to 60 degrees with respect to the axial direction of the extension pipe part And consist of
高圧の圧縮空気は、1.6MPa程度の圧力であり一般的なコンプレッサにより製造することができるが、振動、圧縮空気の品質、移動等の作業の容易性などから、スクリューコンプレッサが望ましい。 The high-pressure compressed air has a pressure of about 1.6 MPa and can be manufactured by a general compressor. However, a screw compressor is desirable from the viewpoint of vibration, quality of compressed air, ease of operation such as movement, and the like.
前記ノズル部を構成する延長管は、円筒状のパイプと、該パイプの一端に留め具によって袋ナットを自在に保持し、他端に、他の延長管の袋ナットと接続するための留め具とを備えた構成であり、前記水管部外表面に付着した堆積物を剥離する位置に合わせて、前記延長管を1個乃至複数個を組合わせて接続し延長管部とし、水管部外表面に付着した堆積物を剥離する。 The extension pipe constituting the nozzle part includes a cylindrical pipe and a fastener for freely holding a cap nut at one end of the pipe by a fastener and connecting the cap nut of another extension tube to the other end. In accordance with the position where the deposit attached to the outer surface of the water pipe part is peeled off, one or more of the extension pipes are connected in combination to form an extension pipe part, and the outer surface of the water pipe part The deposit adhering to is peeled off.
また、前記ノズル部を構成する延長管は、圧送する洗浄体の圧力損失を極力少なくする、また、片持ちで洗浄箇所へ挿入することに対する強度、重量を勘案し、丸型の直管とした。1個の延長管の長さは、250〜500mm(250mm以上500mm以下)程度であり、適宜長さを変更して組み合わせて使用することも可能である。ただ、接続した延長管部全体の長さ方向のたわみ等を考慮すると、250mmの単一種類の延長管が好ましい。 In addition, the extension pipe constituting the nozzle part reduces the pressure loss of the cleaning body to be pumped as much as possible, and considers the strength and weight with respect to insertion into the cleaning part by cantilever, and has a round straight pipe. . The length of one extension tube is about 250 to 500 mm (250 mm or more and 500 mm or less), and it is also possible to change the length appropriately and use it in combination. However, considering the deflection in the length direction of the entire connected extension pipe portion, a single type of extension pipe of 250 mm is preferable.
前記洗浄体に使用するドライアイスは、ペレット状および/あるいはパウダー状であり、好ましくは、φ3mm×6〜8mm程度の円筒状のドライアイスペレットである。 The dry ice used for the cleaning body is in the form of pellets and / or powder, and preferably is a cylindrical dry ice pellet of about φ3 mm × 6 to 8 mm.
本発明の水管ボイラ内の堆積物除去方法ならびに装置の構成の概要を、装置を中心に図1に示す。 The outline of the structure of the deposit removal method and apparatus in the water pipe boiler of this invention is shown in FIG. 1 centering on an apparatus.
水管ボイラ内の堆積物除去装置1は、コンプレッサ4から供給される高圧の圧縮空気に、ドライアイスペレットおよび/あるいはドライアイスパウダー(以下、ペレットと称す。)を混合させ、洗浄体を製造してノズル部へ供給する洗浄機本体2と、洗浄機本体2から洗浄体供給ホース11を介して供給される洗浄体を剥離・洗浄箇所へ高圧噴射させるノズル部5で構成される。ペレットは、ドライアイス保冷BOX3から、人為的に、適宜洗浄機本体2へ供給する。 The deposit removing device 1 in the water tube boiler mixes dry ice pellets and / or dry ice powder (hereinafter referred to as pellets) with the high-pressure compressed air supplied from the compressor 4 to produce a cleaning body. The cleaning machine main body 2 is supplied to the nozzle unit, and the cleaning unit supplied from the cleaning machine main body 2 through the cleaning body supply hose 11 is peeled and sprayed at a high pressure to the cleaning part. The pellets are artificially supplied from the dry ice cold storage BOX 3 to the cleaning machine body 2 as appropriate.
ノズル部5は、1乃至複数の延長管7を接続した延長管部6と、洗浄体を剥離・洗浄箇所へ高圧噴射させるノズル部8で構成する。 The nozzle unit 5 includes an extension pipe part 6 to which one or a plurality of extension pipes 7 are connected, and a nozzle part 8 for injecting the cleaning body into the separation / cleaning part at a high pressure.
ここで、洗浄機本体2ならびにコンプレッサ4の詳細な構成ならびに動作内容、たとえばエンジンの起動停止、バルブの開閉動作、圧力調整など、さらには洗浄機本体2でのペレットの粉砕などについては、非特許文献1他、関連文献等で開示されているので、本説明では洗浄に関連する機能に絞った。 Here, the detailed configuration and operation contents of the washing machine body 2 and the compressor 4, such as engine start / stop, valve opening / closing operation, pressure adjustment, etc., and further, pellet pulverization in the washing machine body 2 are non-patented. Since it is disclosed in Document 1 and other related documents, this description focuses on functions related to cleaning.
前記ノズル部5を構成する延長管7について、図2を基に説明する。
図2は延長管7の構成を示すが、洗浄体を搬送するためのパイプ7cと、その一端に袋ナット7aを自在に保持するための留め具A7bを袋ナットに組み込んだ状態でパイプ7cに溶接固着し、パイプ7cの他端に、他の延長管7の袋ナット7aと接続固定する接続ネジ7dとで構成する。この場合の延長管7の長さは、250mmとするが、適宜長さを変更してもよい。
The extension pipe 7 constituting the nozzle unit 5 will be described with reference to FIG.
FIG. 2 shows the configuration of the extension pipe 7. The pipe 7c is assembled with a pipe 7c for transporting the cleaning body and a fastener A7b for freely holding the cap nut 7a at one end of the pipe 7c. The connecting screw 7d is fixedly welded and connected to the other end of the pipe 7c with the cap nut 7a of the other extension pipe 7. In this case, the length of the extension tube 7 is 250 mm, but the length may be changed as appropriate.
本発明の洗浄を行う作業員は、一定の場所で固定的に噴射ノズルを操作しながら洗浄が出来る方法が作業効率から言っても理想である。 From the viewpoint of work efficiency, the worker who performs the cleaning according to the present invention can perform cleaning while operating the injection nozzle fixedly at a fixed location.
水管ボイラの場合、その構造的特徴より洗浄対象となる「水管」と洗浄作業者の距離は、最前列の水管と最後尾の水管とでは、大きく離れており、最大で数m以上も差がある場合もある。 In the case of a water pipe boiler, the distance between the "water pipe" to be cleaned and the cleaning operator is greatly separated between the water pipe in the front row and the last water pipe due to its structural characteristics, and there is a difference of several meters or more at the maximum. There can be.
一定の場所で固定的に噴射ノズルを操作しながら洗浄をするためには、洗浄対象物との距離に応じて、その最大延長管長が変えられる、すなわち複数の延長管を接続する可変型(ジョイントによる継ぎ足し接続型)が望ましい。 In order to perform cleaning while operating the injection nozzle fixedly at a fixed location, the maximum extension pipe length can be changed according to the distance to the object to be cleaned, i.e., a variable type that connects multiple extension pipes (joint (Additional connection type) is desirable.
この点から、延長管7は、水管部外表面に付着した堆積物を剥離するときに片持ち式となるための曲げ強度を確保、途中経路である延長管内での不要なペレット詰まりを防止するために、材質はステンレスで外径16mm×内径12mm×肉厚2mm、長さを250
mmとした。
From this point, the extension pipe 7 ensures a bending strength for becoming a cantilever type when peeling deposits adhering to the outer surface of the water pipe section, and prevents unnecessary pellet clogging in the extension pipe which is a midway path. Therefore, the material is stainless steel, outer diameter 16mm × inner diameter 12mm × wall thickness 2mm, length 250
mm.
前記ノズル部5を構成する噴射ノズル部8について、図3を基に説明する。
噴射ノズル部8は、延長管7にカラー8dと留め具B8bを袋ナットを自在に可動可能な状態でノズル8cに溶接固着した構成とし、延長管7との接続は、該袋ナット8aと延長管7の接続ネジ7dとでネジ固定する。
The injection nozzle part 8 which comprises the said nozzle part 5 is demonstrated based on FIG.
The injection nozzle portion 8 has a configuration in which a collar 8d and a fastener B8b are welded and fixed to the nozzle 8c in a state in which the cap nut can be moved freely, and the extension tube 7 is connected to the cap nut 8a. The tube 7 is fixed with a connection screw 7d.
ノズル8は、軽く、強く、取扱いが楽で、かつ噴射時における洗浄体の詰まり、圧損等が少なく、内部気流が乱流とならない形状として、材質はステンレスで外径10mm×内径6mm×肉厚2mmの円筒型ノズルとした。 The nozzle 8 is light, strong, easy to handle, has little clogging of the cleaning body during injection, pressure loss, etc., and the internal airflow is not turbulent. The material is stainless steel and the outer diameter is 10 mm x inner diameter 6 mm x wall thickness. A 2 mm cylindrical nozzle was used.
〔実施例1〕
実施例1として、前記従来例(図5)に示した水管ボイラの洗浄例を図4を基に説明する。
[Example 1]
As Example 1, an example of cleaning the water pipe boiler shown in the conventional example (FIG. 5) will be described with reference to FIG.
水管ボイラの仕様は、図5a)に示す通りであるが、外寸は奥行6,175mm、幅3,407mm(水管収納部の幅1,460mm)の中型の水管ボイラである。水管収納部には、上下に配置されている水ドラム(図5d)の下側)と蒸気ドラム(図5d)の上側)との間を、1,400本程度の水管で接続され、隣同士の水管の隙間は30mmと非常の狭隘な状態である。 The specification of the water tube boiler is as shown in FIG. 5a), but the outer size is a medium-sized water tube boiler having a depth of 6,175 mm and a width of 3,407 mm (width of the water tube storage portion of 1,460 mm). About 1,400 water pipes are connected to the water pipe storage section between the water drum (the lower side of FIG. 5d) and the steam drum (the upper side of FIG. 5d) arranged vertically. The water pipe gap is very narrow at 30 mm.
堆積物除去装置1は、1.6MPaのスクリューコンプレッサ4、(株)グリーンテックジャパン販売のドライアイス洗浄機を洗浄機本体2、ペレットは、φ3mm×6〜8mm程度の円筒状のものを使用した。 The deposit removing apparatus 1 is a 1.6 MPa screw compressor 4, a dry ice cleaning machine sold by Greentech Japan Co., Ltd., a cleaning machine body 2, and a pellet having a cylindrical shape of about φ3 mm × 6 to 8 mm. .
ノズル部5の延長管部6は、図2に記載の構造であり、パイプ7cは、材質がステンレスで外径16mm×内径12mm×肉厚2mm、長さを250mm、袋ナット7aは隣同士の水管の隙間が30mmの狭隘であるため、M20の内径ネジ(袋ナット7aの最大径が25mmとなるように)を持つ構造とした。パイプ7cの一端に袋ナット7aを挿入した状態で、留め具Aをパイプ7cに溶接固着し、袋ナット7aを自在に回転できるようにした。一方、パイプ7cの他端部には、他の延長管7の袋ナット7aと組み合わせて接続するために、接続ネジ7dをパイプ7cの他端部に溶接固着した構造のものを使用した。なお、袋ナットA7a、留め具A7b、接続ネジ7dのいずれも材質をステンレスとした。 The extension pipe portion 6 of the nozzle portion 5 has the structure shown in FIG. 2, and the pipe 7 c is made of stainless steel, the outer diameter is 16 mm × the inner diameter is 12 mm × the thickness is 2 mm, the length is 250 mm, and the cap nut 7 a is adjacent to each other. Since the gap between the water pipes is 30 mm, the structure has an inner diameter screw of M20 (so that the maximum diameter of the cap nut 7a is 25 mm). With the cap nut 7a inserted into one end of the pipe 7c, the fastener A is welded and fixed to the pipe 7c so that the cap nut 7a can be freely rotated. On the other hand, in order to connect the other end of the pipe 7c in combination with the cap nut 7a of the other extension pipe 7, a structure in which a connection screw 7d is fixed to the other end of the pipe 7c by welding is used. The cap nut A7a, the fastener A7b, and the connection screw 7d are all made of stainless steel.
延長管7の接続数は、図1の「水管ボイラへのノズル部の挿入」に記載のA、B両端からノズル部5を挿入し、延長管7の必要長さを短縮し、延長管7の接続数を低減した。本実施例では、片側からの延長管7の必要長さは2,400mmであり、延長管の必要接続数を10個とした。この時の延長管部6の総重量は2kgと軽量であり、洗浄作業において何ら支障ない重さである。 The number of connections of the extension pipe 7 is such that the nozzle part 5 is inserted from both ends A and B described in “Insertion of the nozzle part into the water pipe boiler” in FIG. Reduced the number of connections. In this embodiment, the required length of the extension pipe 7 from one side is 2,400 mm, and the required number of connections of the extension pipe is ten. At this time, the total weight of the extension pipe part 6 is as light as 2 kg, which is a weight that does not interfere with the cleaning operation.
噴射ノズル部8は、図3に記載の材質がステンレスで外径10mm×内径6mm×肉厚2mmの円筒型ノズル8cとし、ノズルの噴射方向は延長管部7の軸心に対して45度の傾斜を持たせた。なお、袋ナットB8a、留め具B8b、ノズル8c、カラー8dのいずれも材質をステンレスとした。 The injection nozzle portion 8 is a cylindrical nozzle 8c having the outer diameter of 10 mm, the inner diameter of 6 mm, and the thickness of 2 mm as shown in FIG. 3, and the injection direction of the nozzle is 45 degrees with respect to the axis of the extension pipe portion 7. Has a slope. All of the cap nut B8a, the fastener B8b, the nozzle 8c, and the collar 8d are made of stainless steel.
この条件で、水管ボイラの水ドラムに接続されている水管の接続部の洗浄を実施した結果を図4で説明する。
図4の左側の上部は洗浄前の水管の接続部、下部は洗浄前の水管の途中の部分を示したも
のであり、右側の上部は洗浄後の水管の接続部、下部は洗浄後の水管の途中の部分を示したものである。
The result of cleaning the connecting portion of the water pipe connected to the water drum of the water pipe boiler under these conditions will be described with reference to FIG.
The upper part on the left side of FIG. 4 shows the connection part of the water pipe before washing, the lower part shows the middle part of the water pipe before washing, the upper part on the right side shows the connection part of the water pipe after washing, and the lower part shows the water pipe after washing. The middle part of is shown.
この図からも判るとおり、水管部外表面に付着した堆積物の剥離を十分に行うことができた。 As can be seen from this figure, the deposits adhering to the outer surface of the water pipe part could be sufficiently removed.
以上述べたとおり、水管ボイラ内が複雑かつ狭隘であっても、安価で、かつ簡略な構造で、洗浄対象物である水管に付着した堆積物の剥離を効率よく行うことができる水管ボイラ内の堆積物除去方法及び装置が実現できた。 As described above, even if the inside of the water tube boiler is complicated and narrow, the inside of the water tube boiler that can efficiently peel off the deposits attached to the water pipe that is the object to be cleaned with an inexpensive and simple structure. A deposit removal method and apparatus could be realized.
1…堆積物除去装置
2…洗浄機本体
3…ドライアイス保冷BOX
4…コンプレッサ
5…ノズル部
6…延長管部
7…延長管
7a…袋ナットA
7b…留め具A
7c…パイプ
7d…接続ネジ
8…噴射ノズル部
8a…袋ナットB
8b…留め具B
8c…ノズル
8d…カラー
9…継手
10…エア供給ホース
11…洗浄体供給ホース
DESCRIPTION OF SYMBOLS 1 ... Deposit removal apparatus 2 ... Main body of washing machine 3 ... Dry ice cold storage BOX
4 ... Compressor 5 ... Nozzle part 6 ... Extension pipe part 7 ... Extension pipe 7a ... Cap nut A
7b ... Fastener A
7c ... Pipe 7d ... Connection screw 8 ... Injection nozzle part 8a ... Cap nut B
8b ... Fastener B
8c ... Nozzle 8d ... Collar 9 ... Joint 10 ... Air supply hose 11 ... Cleaner supply hose
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014104370A JP6304629B2 (en) | 2014-05-20 | 2014-05-20 | Method and apparatus for removing deposits in water tube boiler |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014104370A JP6304629B2 (en) | 2014-05-20 | 2014-05-20 | Method and apparatus for removing deposits in water tube boiler |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015218981A true JP2015218981A (en) | 2015-12-07 |
JP6304629B2 JP6304629B2 (en) | 2018-04-04 |
Family
ID=54778500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014104370A Active JP6304629B2 (en) | 2014-05-20 | 2014-05-20 | Method and apparatus for removing deposits in water tube boiler |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6304629B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110487109A (en) * | 2019-09-20 | 2019-11-22 | 江阴市亚龙换热设备有限公司 | There is the cleaning method of coking fouling plate heat exchanger |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6094333U (en) * | 1983-11-30 | 1985-06-27 | 大阪瓦斯株式会社 | flaring tools |
JP2000042505A (en) * | 1998-07-30 | 2000-02-15 | Toshiba Corp | Method of washing turbine blade and device therefor |
JP2004223410A (en) * | 2003-01-23 | 2004-08-12 | Iwatani Internatl Corp | Frozen carbon dioxide blast washing device |
JP2006226580A (en) * | 2005-02-16 | 2006-08-31 | Chugoku Electric Power Co Inc:The | Ash dropping tool for boiler tube |
JP2008275277A (en) * | 2007-05-02 | 2008-11-13 | Sangreen Systems:Kk | Removing processing method of chimney inner surface attachment and its device |
JP2008281332A (en) * | 2002-02-07 | 2008-11-20 | Ohbayashi Corp | Method and device for removing sticking object |
JP2010064027A (en) * | 2008-09-11 | 2010-03-25 | Mitachi:Kk | Nozzle for dry ice washing |
JP2012073247A (en) * | 2010-09-28 | 2012-04-12 | Soonchunhyang Univ Industry Academy Cooperation Foundation | Physicochemical cleaning method of deposited sludge |
-
2014
- 2014-05-20 JP JP2014104370A patent/JP6304629B2/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6094333U (en) * | 1983-11-30 | 1985-06-27 | 大阪瓦斯株式会社 | flaring tools |
JP2000042505A (en) * | 1998-07-30 | 2000-02-15 | Toshiba Corp | Method of washing turbine blade and device therefor |
JP2008281332A (en) * | 2002-02-07 | 2008-11-20 | Ohbayashi Corp | Method and device for removing sticking object |
JP2004223410A (en) * | 2003-01-23 | 2004-08-12 | Iwatani Internatl Corp | Frozen carbon dioxide blast washing device |
JP2006226580A (en) * | 2005-02-16 | 2006-08-31 | Chugoku Electric Power Co Inc:The | Ash dropping tool for boiler tube |
JP2008275277A (en) * | 2007-05-02 | 2008-11-13 | Sangreen Systems:Kk | Removing processing method of chimney inner surface attachment and its device |
JP2010064027A (en) * | 2008-09-11 | 2010-03-25 | Mitachi:Kk | Nozzle for dry ice washing |
JP2012073247A (en) * | 2010-09-28 | 2012-04-12 | Soonchunhyang Univ Industry Academy Cooperation Foundation | Physicochemical cleaning method of deposited sludge |
Non-Patent Citations (2)
Title |
---|
ドライアイス洗浄の特長 DRY ICE POWER グリーンテックジャパン ドライアイス洗浄機, JPN6018001755, 11 August 2013 (2013-08-11), JP, ISSN: 0003722613 * |
剥離の原理 DRY ICE POWER グリーンテックジャパン ドライアイス洗浄機, JPN6018001754, 11 August 2013 (2013-08-11), JP, ISSN: 0003722612 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110487109A (en) * | 2019-09-20 | 2019-11-22 | 江阴市亚龙换热设备有限公司 | There is the cleaning method of coking fouling plate heat exchanger |
Also Published As
Publication number | Publication date |
---|---|
JP6304629B2 (en) | 2018-04-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100802522B1 (en) | Water supply and drainage conduit cleaning device and its manufacturing method | |
CN106853450A (en) | A kind of petroleum pipeline inner-wall cleaner | |
JP5386758B2 (en) | Disposer connected drain pipe cleaning method | |
JP2009129857A (en) | Polymer bushing cleaning device | |
CN102989827B (en) | The online outer cleaning by degreasing equipment of steel pipe | |
CN102989728A (en) | Push type brush for degreasing cleaning of steel pipe inner wall | |
CN105149272A (en) | High-pressure flushing device | |
CN104353632B (en) | Gas-liquid mixing high-pressure washer | |
JP6304629B2 (en) | Method and apparatus for removing deposits in water tube boiler | |
KR100991831B1 (en) | Cleaner for duct | |
CN212081273U (en) | Purging device for heat exchanger tube bank of waste heat boiler and waste heat boiler with purging device | |
JP2005288420A (en) | Structure of tank and method for cleaning tank | |
JP2011169521A (en) | Boiler device and method of removing attached ash for the same | |
CN104633913A (en) | Electric water heater | |
CN201223866Y (en) | Pipeline scar cleaner | |
CN202506638U (en) | Pipeline descaling device with elastic chattering and cavitation jet functions | |
JP2011115735A (en) | Nozzle for drying inner surface of steel pipe for oil well pipe | |
CN204194168U (en) | A kind of insulating spray gun | |
CN207308493U (en) | A kind of rigidly connected pipe cleaning tool | |
CN104353650A (en) | Cleaning device for pipelines | |
JP2008184632A (en) | Apparatus for cleaning deposit of the inside of a bundled steel pipe | |
CN204220535U (en) | Gas-liquid mixed jetting machine | |
CN203750248U (en) | Filter with good filtering effect | |
CN207308494U (en) | A kind of pipe cleaning tool of flexible connection | |
CN109876571B (en) | Pressure type atomizing nozzle for conveniently backwashing large-particle impurities |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170413 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20170413 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180117 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180124 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180208 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20180221 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180223 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6304629 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |