JP2015168757A5 - - Google Patents

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JP2015168757A5
JP2015168757A5 JP2014044476A JP2014044476A JP2015168757A5 JP 2015168757 A5 JP2015168757 A5 JP 2015168757A5 JP 2014044476 A JP2014044476 A JP 2014044476A JP 2014044476 A JP2014044476 A JP 2014044476A JP 2015168757 A5 JP2015168757 A5 JP 2015168757A5
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Prior art keywords
general formula
compound represented
active energy
energy ray
hydrocarbon group
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JP2014044476A
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JP2015168757A (en
JP6337523B2 (en
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Claims (5)

(a)下記一般式(1)で表される芳香環含有脂環式エポキシ化合物のエポキシ基1当量に対してアクリル酸又はメタクリル酸を0.5〜1.1当量添加して反応させて得られる不飽和脂環式エポキシエステル化合物と、(b)光重合開始剤および/または光酸発生剤とを含むことを特徴とする活性エネルギー線重合性樹脂組成物。
一般式(1)
Figure 2015168757
(一般式(1)中、Arはn価の芳香族炭化水素基を表す。
1は、単結合、−O−、−S−、−N(R3)−、−CO−、−SO−、−SO2−、またはこれらの組合せからなる2価の結合基を表す。
1は、脂環式エポキシ基を表す。
1は、単結合または2価の炭化水素基を表し、
2は、単結合または2価の炭化水素基を表し、
3は、水素原子または1価の炭化水素基を表し、
m、nは1以上の整数を表す。分子内に含まれるn個のR1、m×n個のA1、m×n個のR2、n個のE1、m×n個のR3は同一であっても異なっていてもよい。)
(A) Obtained by adding 0.5 to 1.1 equivalents of acrylic acid or methacrylic acid to 1 equivalent of epoxy group of an aromatic ring-containing alicyclic epoxy compound represented by the following general formula (1) An active energy ray-polymerizable resin composition comprising: an unsaturated alicyclic epoxy ester compound to be produced; and (b) a photopolymerization initiator and / or a photoacid generator.
General formula (1)
Figure 2015168757
(In the general formula (1), Ar represents an n-valent aromatic hydrocarbon group.
A 1 represents a divalent linking group consisting of a single bond, —O—, —S—, —N (R 3 ) —, —CO—, —SO—, —SO 2 —, or a combination thereof.
E 1 represents an alicyclic epoxy group.
R 1 represents a single bond or a divalent hydrocarbon group,
R 2 represents a single bond or a divalent hydrocarbon group,
R 3 represents a hydrogen atom or a monovalent hydrocarbon group,
m and n represent an integer of 1 or more. N R 1 , m × n A 1 , m × n R 2 , n E 1 , m × n R 3 contained in the molecule may be the same or different. Good. )
Arがベンゼン環であり、mが1であることを特徴とする、請求項1記載の活性エネルギー線重合性樹脂組成物。   2. The active energy ray-polymerizable resin composition according to claim 1, wherein Ar is a benzene ring and m is 1. 一般式(1)で表される化合物が、下記一般式(2)で表される化合物、下記一般式(3)で表される化合物、および、下記一般式(4)で表される化合物のいずれかであることを特徴とする、請求項2記載の活性エネルギー線重合性樹脂組成物。
一般式(2)
Figure 2015168757
一般式(3)
Figure 2015168757
一般式(4)
Figure 2015168757
(式中E2、E3、E4は脂環式エポキシ基を、
Xは2価の脂肪族炭化水素基を、
nは1〜6の整数を表す)
The compound represented by the general formula (1) is a compound represented by the following general formula (2), a compound represented by the following general formula (3), and a compound represented by the following general formula (4). The active energy ray polymerizable resin composition according to claim 2, wherein the composition is any one.
General formula (2)
Figure 2015168757
General formula (3)
Figure 2015168757
General formula (4)
Figure 2015168757
(In the formula, E 2 , E 3 and E 4 are alicyclic epoxy groups,
X represents a divalent aliphatic hydrocarbon group,
n represents an integer of 1 to 6)
請求項1〜3いずれか記載の活性エネルギー線重合性樹脂組成物を活性エネルギー線照射によって硬化させた硬化物 Hardened | cured material which hardened the active energy ray polymeric resin composition in any one of Claims 1-3 by active energy ray irradiation . 請求項4記載の硬化物と基材とからなる積層体。A laminate comprising the cured product according to claim 4 and a substrate.
JP2014044476A 2014-03-07 2014-03-07 Active energy ray polymerizable resin composition and laminate Expired - Fee Related JP6337523B2 (en)

Priority Applications (1)

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JP2014044476A JP6337523B2 (en) 2014-03-07 2014-03-07 Active energy ray polymerizable resin composition and laminate

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Application Number Priority Date Filing Date Title
JP2014044476A JP6337523B2 (en) 2014-03-07 2014-03-07 Active energy ray polymerizable resin composition and laminate

Publications (3)

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JP2015168757A JP2015168757A (en) 2015-09-28
JP2015168757A5 true JP2015168757A5 (en) 2016-12-22
JP6337523B2 JP6337523B2 (en) 2018-06-06

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6993766B2 (en) 2016-03-30 2022-01-14 株式会社Adeka Curable composition, method for producing cured product, and cured product thereof
WO2017170881A1 (en) 2016-03-30 2017-10-05 株式会社Adeka Curable composition, cured product production method, and cured product therefrom
JP7216470B2 (en) 2016-03-30 2023-02-01 株式会社Adeka Curable composition, method for producing cured product, and cured product thereof
KR102265025B1 (en) 2016-03-31 2021-06-14 가부시키가이샤 아데카 Curable composition, manufacturing method of cured product, and cured product thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225880B2 (en) * 1972-09-12 1977-07-11
US4389520A (en) * 1982-04-05 1983-06-21 Ciba-Geigy Corporation Advancement catalysts for epoxy resins
JP2962805B2 (en) * 1990-11-02 1999-10-12 ダイセル化学工業株式会社 Curable resin composition
EP0506616B1 (en) * 1991-03-27 1998-01-21 Ciba SC Holding AG Photosensitive acrylate mixture
JP2005343868A (en) * 2004-06-07 2005-12-15 Daicel Chem Ind Ltd Method for producing dieopoxidized oxalic ester compound
JP4511439B2 (en) * 2005-09-28 2010-07-28 日東電工株式会社 Photosensitive epoxy resin adhesive film

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