JP2015105318A5 - - Google Patents
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- JP2015105318A5 JP2015105318A5 JP2013247689A JP2013247689A JP2015105318A5 JP 2015105318 A5 JP2015105318 A5 JP 2015105318A5 JP 2013247689 A JP2013247689 A JP 2013247689A JP 2013247689 A JP2013247689 A JP 2013247689A JP 2015105318 A5 JP2015105318 A5 JP 2015105318A5
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- carbon atoms
- linear aliphatic
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- monomer
- block polymer
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- -1 aliphatic diol Chemical class 0.000 claims description 20
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 17
- 125000001931 aliphatic group Chemical group 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000005886 esterification reaction Methods 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 150000002596 lactones Chemical class 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
Description
ポリエステル部位およびビニルポリマー部位を有するブロックポリマーであって、
該ポリエステル部位は、下記モノマー群Ａからなるグループから選択されるモノマー（ａ）に由来する部分構造と、
下記モノマー群Ｂからなるグループから選択されるモノマー（ｂ）に由来する部分構造と、を有し、
該ポリエステル部位は、下記式から算出される該モノマー（ｂ）に由来する部分構造の含有率が１．０モル％以上３０．０モル％以下であることを特徴とするブロックポリマー。
｛モノマー（ｂ）［モル］／〔モノマー（ａ）［モル］＋モノマー（ｂ）［モル］〕｝×１００
（モノマー群Ａ：
炭素数２以上１１以下のα，ω−直鎖脂肪族ジオール、
炭素数２以上１３以下のα，ω−直鎖脂肪族ジカルボン酸、該炭素数２以上１３以下のα，ω−直鎖脂肪族ジカルボン酸がアルキルエステル化した化合物または酸無水物化した化合物、
炭素数２以上１２以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸、該炭素数２以上１２以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸がアルキルエステル化した化合物またはラクトン化した化合物。）
（モノマー群Ｂ：
炭素数１２以上２２以下のα，ω−直鎖脂肪族ジオール、
炭素数１４以上２４以下のα，ω−直鎖脂肪族ジカルボン酸、該炭素数１４以上２４以下のα，ω−直鎖脂肪族ジカルボン酸がアルキルエステル化した化合物または酸無水物化した化合物、
炭素数１３以上２３以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸、該炭素数１３以上２３以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸がアルキルエステル化した化合物またはラクトン化した化合物、
炭素数１２以上２２以下の直鎖脂肪族１級モノアルコール、
炭素数１３以上２３以下の直鎖脂肪族１級モノカルボン酸、該炭素数１３以上２３以下の直鎖脂肪族１級モノカルボン酸がアルキルエステル化した化合物。）
A block polymer having a polyester moiety and a vinyl polymer moiety,
The polyester portion has a partial structure derived from the monomer (a) selected from the group consisting of the following monomer group A;
Has a partial structure derived from the monomer (b) is selected from the group consisting of the following group of monomers B, and,
The polyester part is a block polymer characterized in that the content of the partial structure derived from the monomer (b) calculated from the following formula is 1.0 mol% or more and 30.0 mol% or less.
{Monomer (b) [mol] / [monomer (a) [mol] + monomer (b) [mol]]} × 100
( Monomer group A:
Α, ω-linear aliphatic diol having 2 to 11 carbon atoms,
An α, ω-linear aliphatic dicarboxylic acid having 2 to 13 carbon atoms, a compound in which the α, ω-linear aliphatic dicarboxylic acid having 2 to 13 carbon atoms is alkylesterified, or an acid anhydride compound,
Carbon number 2 to 12 of the alpha, .omega.-linear aliphatic monohydroxy monocarboxylic acids, carbon number 2 to 12 of the alpha, compounds .omega. linear aliphatic monohydroxy monocarboxylic acid has alkyl esterification or lactone Compound . )
( Monomer group B:
Α, ω-linear aliphatic diol having 12 to 22 carbon atoms,
An α, ω-linear aliphatic dicarboxylic acid having 14 to 24 carbon atoms, a compound in which the α, ω-linear aliphatic dicarboxylic acid having 14 to 24 carbon atoms is alkylesterified, or an acid anhydride compound,
Α, ω-linear aliphatic monohydroxymonocarboxylic acid having 13 to 23 carbon atoms , compound or lactone obtained by alkyl esterification of α, ω-linear aliphatic monohydroxymonocarboxylic acid having 13 to 23 carbon atoms Compound,
Straight chain aliphatic primary monoalcohol having 12 to 22 carbon atoms ,
Compound carbon number 13 to 23 straight-chain aliphatic primary monocarboxylic acid, straight-chain aliphatic primary monocarboxylic acid carbon number 13 to 23 were alkylesterification. )
Claims (6)
該ポリエステル部位は、下記モノマー群Ａからなる群から選択されるモノマー（ａ）に由来する部分構造と、下記モノマー群Ｂからなる群から選択されるモノマー（ｂ）に由来する部分構造と、を有し、
該ポリエステル部位は、下記式から算出される該モノマー（ｂ）に由来する部分構造の含有率が１．０モル％以上３０．０モル％以下であることを特徴とするブロックポリマー。
｛モノマー（ｂ）［モル］／〔モノマー（ａ）［モル］＋モノマー（ｂ）［モル］〕｝×１００
（モノマー群Ａ：
炭素数２以上１１以下のα，ω−直鎖脂肪族ジオール、
炭素数２以上１３以下のα，ω−直鎖脂肪族ジカルボン酸、該炭素数２以上１３以下のα，ω−直鎖脂肪族ジカルボン酸がアルキルエステル化した化合物または酸無水物化した化合物、
炭素数２以上１２以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸、該炭素数２以上１２以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸がアルキルエステル化した化合物またはラクトン化した化合物。）
（モノマー群Ｂ：
炭素数１２以上２２以下のα，ω−直鎖脂肪族ジオール、
炭素数１４以上２４以下のα，ω−直鎖脂肪族ジカルボン酸、該炭素数１４以上２４以下のα，ω−直鎖脂肪族ジカルボン酸がアルキルエステル化した化合物または酸無水物化した化合物、
炭素数１３以上２３以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸、該炭素数１３以上２３以下のα，ω−直鎖脂肪族モノヒドロキシモノカルボン酸がアルキルエステル化した化合物またはラクトン化した化合物、
炭素数１２以上２２以下の直鎖脂肪族１級モノアルコール、
炭素数１３以上２３以下の直鎖脂肪族１級モノカルボン酸、該炭素数１３以上２３以下の直鎖脂肪族１級モノカルボン酸がアルキルエステル化した化合物。） A block polymer having a polyester moiety and a vinyl polymer moiety,
The polyester portion has a partial structure derived from the monomer (a) selected from the group consisting of the following group of monomers A, a partial structure derived from the monomer (b) selected from the group consisting of the following group of monomers B, and Have
The polyester part is a block polymer characterized in that the content of the partial structure derived from the monomer (b) calculated from the following formula is 1.0 mol% or more and 30.0 mol% or less.
{Monomer (b) [mol] / [monomer (a) [mol] + monomer (b) [mol]]} × 100
( Monomer group A:
Α, ω-linear aliphatic diol having 2 to 11 carbon atoms,
An α, ω-linear aliphatic dicarboxylic acid having 2 to 13 carbon atoms, a compound in which the α, ω-linear aliphatic dicarboxylic acid having 2 to 13 carbon atoms is alkylesterified, or an acid anhydride compound,
Α, ω-linear aliphatic monohydroxymonocarboxylic acid having 2 to 12 carbon atoms, compound or lactone obtained by alkyl esterification of α, ω-linear aliphatic monohydroxymonocarboxylic acid having 2 to 12 carbon atoms Compound. )
( Monomer group B:
Α, ω-linear aliphatic diol having 12 to 22 carbon atoms,
An α, ω-linear aliphatic dicarboxylic acid having 14 to 24 carbon atoms, a compound in which the α, ω-linear aliphatic dicarboxylic acid having 14 to 24 carbon atoms is alkylesterified, or an acid anhydride compound,
Α, ω-linear aliphatic monohydroxymonocarboxylic acid having 13 to 23 carbon atoms , compound or lactone obtained by alkyl esterification of α, ω-linear aliphatic monohydroxymonocarboxylic acid having 13 to 23 carbon atoms Compound,
Straight chain aliphatic primary monoalcohol having 12 to 22 carbon atoms ,
Compound carbon number 13 to 23 straight-chain aliphatic primary monocarboxylic acid, straight-chain aliphatic primary monocarboxylic acid carbon number 13 to 23 were alkylesterification. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013247689A JP6271972B2 (en) | 2013-11-29 | 2013-11-29 | Block polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013247689A JP6271972B2 (en) | 2013-11-29 | 2013-11-29 | Block polymer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015105318A JP2015105318A (en) | 2015-06-08 |
| JP2015105318A5 true JP2015105318A5 (en) | 2016-10-27 |
| JP6271972B2 JP6271972B2 (en) | 2018-01-31 |
Family
ID=53435657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013247689A Active JP6271972B2 (en) | 2013-11-29 | 2013-11-29 | Block polymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6271972B2 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0785179B2 (en) * | 1986-07-22 | 1995-09-13 | コニカ株式会社 | Toner for electrostatic image development |
| JPH02308261A (en) * | 1989-05-24 | 1990-12-21 | Konica Corp | Production of binder resin for toner and toner for developing electrostatic charge image |
| JP2007204614A (en) * | 2006-02-02 | 2007-08-16 | Nisshin Oillio Group Ltd | Plasticizer for resin and resin composition containing the same |
| DE102008034106A1 (en) * | 2008-07-21 | 2010-01-28 | Evonik Röhm Gmbh | Block copolymers based on (meth) acrylate with A-P structure |
-
2013
- 2013-11-29 JP JP2013247689A patent/JP6271972B2/en active Active
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