JP2015093258A5 - - Google Patents

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JP2015093258A5
JP2015093258A5 JP2013235288A JP2013235288A JP2015093258A5 JP 2015093258 A5 JP2015093258 A5 JP 2015093258A5 JP 2013235288 A JP2013235288 A JP 2013235288A JP 2013235288 A JP2013235288 A JP 2013235288A JP 2015093258 A5 JP2015093258 A5 JP 2015093258A5
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denitrification
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nitritation
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原水を濃縮処理及び脱水処理することにより、窒素及び有機物を含有する被処理液を調製することと、
前記被処理液を、従属栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理して第1脱窒処理液を得る第1脱窒処理と、
前記第1脱窒処理液中に含まれるアンモニア性窒素の一部をアンモニア酸化菌により亜硝酸性窒素に酸化して亜硝酸化処理液を得る亜硝酸化処理と、
前記亜硝酸化処理液を、独立栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理する第2脱窒処理と、
前記亜硝酸化処理液を前記第1脱窒処理へ循環し、前記従属栄養性細菌を用いた脱窒反応により、前記亜硝酸化処理液中の亜硝酸性窒素を窒素ガスに変換して除去する亜硝酸化処理液循環処理と
を含む脱窒処理方法。
Preparing raw liquid containing nitrogen and organic matter by concentrating and dewatering raw water;
The liquid to be treated, a first denitrification process of obtaining the first denitrified liquid anaerobically denitrified by denitrification with heterotrophic bacteria,
Nitritation treatment in which a part of ammonia nitrogen contained in the first denitrification treatment liquid is oxidized to nitrite nitrogen by ammonia oxidizing bacteria to obtain a nitritation treatment liquid;
A second denitrification treatment in which the nitritation solution is anaerobically denitrified by a denitrification reaction using autotrophic bacteria;
Circulating the nitrite treatment liquid to the first denitrification treatment, and removing the nitrite nitrogen in the nitrite treatment liquid by converting it to nitrogen gas by a denitrification reaction using the heterotrophic bacteria. A denitrification treatment method comprising:
原水を濃縮処理及び脱水処理することにより、窒素及び有機物を含有する被処理液を調製することと、
前記被処理液を、従属栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理して第1脱窒処理液を得る第1脱窒処理と、
前記第1脱窒処理液中に含まれるアンモニア性窒素の一部をアンモニア酸化菌により亜硝酸性窒素に酸化して亜硝酸化処理液を得る亜硝酸化処理と、
前記亜硝酸化処理液を、独立栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理する第2脱窒処理と、
前記第2脱窒処理液の一部を前記第1脱窒処理へ循環する第2脱窒処理液循環処理と
を含む脱窒処理方法。
Preparing raw liquid containing nitrogen and organic matter by concentrating and dewatering raw water;
The liquid to be treated, a first denitrification process of obtaining the first denitrified liquid anaerobically denitrified by denitrification with heterotrophic bacteria,
Nitritation treatment in which a part of ammonia nitrogen contained in the first denitrification treatment liquid is oxidized to nitrite nitrogen by ammonia oxidizing bacteria to obtain a nitritation treatment liquid;
A second denitrification treatment in which the nitritation solution is anaerobically denitrified by a denitrification reaction using autotrophic bacteria;
And a second denitrification treatment liquid circulation treatment for circulating a part of the second denitrification treatment solution to the first denitrification treatment.
前記第2脱窒処理液の一部を前記第1脱窒処理へ循環する第2脱窒処理液循環処理を更に含む請求項1に記載の脱窒処理方法。   The denitrification treatment method according to claim 1, further comprising a second denitrification treatment liquid circulation treatment for circulating a part of the second denitrification treatment solution to the first denitrification treatment. 前記亜硝酸化処理液循環処理は、前記亜硝酸化処理液に含まれる亜硝酸性窒素濃度が、前記第1脱窒処理における脱窒反応において前記被処理液中の生物化学的酸素要求量に対して理論上必要な濃度となるように、前記亜硝酸処理液の循環量を調整することを含む請求項1又は3に記載の脱窒処理方法。   In the nitritation treatment liquid circulation treatment, the concentration of nitrite nitrogen contained in the nitritation treatment liquid is set to the biochemical oxygen demand in the treatment liquid in the denitrification reaction in the first denitrification treatment. The denitrification method according to claim 1 or 3, further comprising adjusting a circulation amount of the nitrous acid treatment solution so as to have a theoretically necessary concentration. 前記亜硝酸化処理液循環処理において、前記被処理液の供給流量に対する前記亜硝酸化処理液の循環流量の比を以下の関係式(1)に基づいて決定することを含む請求項1、3〜のいずれか1項に記載の脱窒処理方法。

r=a×2.32/(1.32×3×(1−a/3)) ・・・(1)

((1)式において、rは被処理液の供給流量に対する前記亜硝酸化処理液の循環流量の比[−]を示し、aは被処理液の全窒素濃度に対する生物化学的酸素要求量の比(BOD/T−N比)を示す。)
In the nitrite treatment liquid circulation process, the ratio of the circulation flow rate of the nitrite treatment liquid to the supply flow rate of the liquid to be treated is determined based on the following relational expression (1). The denitrification method according to any one of to 4 .

r = a × 2.32 / (1.32 × 3 × (1-a / 3)) (1)

(In the formula (1), r represents the ratio [−] of the circulating flow rate of the nitrite treatment liquid to the supply flow rate of the liquid to be treated, and a represents the biochemical oxygen demand for the total nitrogen concentration of the liquid to be treated. Ratio (BOD / TN ratio).
前記第2脱窒処理液循環処理において、前記被処理液の供給流量に対する前記第2脱窒処理液の循環流量の比を以下の関係式(2)に基づいて決定することを含む請求項2〜のいずれか1項に記載の脱窒処理方法。

r<Cn/200−1 ・・・(2)

((2)式において、rは被処理液の供給流量に対する前記第2脱窒処理液の循環流量の比[−]を示し、Cnは被処理液のアンモニア性窒素濃度[mg/L]を示す。)
In the second denitrification treatment liquid circulation process, the ratio of the circulation flow rate of the second denitrification treatment liquid to the supply flow rate of the liquid to be treated is determined based on the following relational expression (2). The denitrification method according to any one of to 5 .

r <Cn / 200-1 (2)

(In the formula (2), r represents the ratio [−] of the circulation flow rate of the second denitrification treatment liquid to the supply flow rate of the treatment liquid, and Cn represents the ammoniacal nitrogen concentration [mg / L] of the treatment liquid. Show.)
前記第2脱窒処理液循環処理は、前記亜硝酸化処理で処理される前記第1脱窒処理液のアンモニア性窒素濃度が200mg/Lよりも高くなるように、前記第2脱窒処理液の循環流量を調整することを含む請求項2〜のいずれか1項に記載の脱窒処理方法。 In the second denitrification treatment liquid circulation treatment, the second denitrification treatment solution is used so that the ammoniacal nitrogen concentration of the first denitrification treatment solution treated in the nitritation treatment is higher than 200 mg / L. The denitrification method according to any one of claims 2 to 6 , comprising adjusting the circulation flow rate. 前記亜硝酸化処理は、活性汚泥共存下に硝化菌を付着固定した高分子流動担体を添加した反応槽中に前記第1脱窒処理液を供給することにより、前記第1脱窒処理液中に含まれるアンモニア性窒素の一部を亜硝酸性窒素に変換する部分亜硝酸化処理を含む請求項1〜のいずれか1項に記載の脱窒処理方法。 The nitritation treatment is performed by supplying the first denitrification treatment liquid into a reaction tank to which a polymer fluid carrier to which nitrifying bacteria are adhered and fixed in the presence of activated sludge is added. The denitrification method according to any one of claims 1 to 7 , further comprising a partial nitritation treatment for converting a part of ammonia nitrogen contained in the nitrite into nitrite nitrogen. 前記第2脱窒処理は、アンモニア脱窒菌を付着固定した高分子流動担体を添加した反応槽に前記亜硝酸化処理液を供給することにより、アンモニア性窒素を水素供与体、亜硝酸性窒素を水素受容体とする独立栄養性脱窒反応を進行させることを含む請求項1〜のいずれか1項に記載の脱窒処理方法。 In the second denitrification treatment, ammonia nitrogen is supplied to a hydrogen donor and nitrite nitrogen is supplied by supplying the nitrite treatment liquid to a reaction vessel to which a polymer fluid carrier to which ammonia denitrifying bacteria are adhered and fixed is added. The denitrification method according to any one of claims 1 to 8 , comprising advancing an autotrophic denitrification reaction as a hydrogen acceptor. 前記第2脱窒処理で発生する窒素ガスを前記反応槽内で循環させて前記高分子流動担体を流動させることを含む請求項1〜のいずれか1項に記載の脱窒処理方法。 The denitrification method according to any one of claims 1 to 9 , further comprising circulating the nitrogen fluid generated in the second denitrification treatment in the reaction tank to cause the polymer fluid carrier to flow. 前記第2脱窒処理で得られた第2脱窒処理液を、従属栄養性脱窒反応により脱窒する第3脱窒処理を行い、該第3脱窒処理により得られる第3脱窒処理液を曝気処理後に沈殿池に導入して固液分離し、該固液分離により得られる沈降濃縮汚泥を前記第1脱窒処理へ返送することを更に含む請求項1〜10のいずれか1項に記載の脱窒処理方法。 A third denitrification treatment obtained by the third denitrification treatment is performed by denitrifying the second denitrification treatment liquid obtained by the second denitrification treatment by heterotrophic denitrification reaction. liquid-solid-liquid separation is introduced into the settling basin after aeration to any one of claim 1 to 10, a thickener sludge obtained further comprising returning to the first denitrified by solid-liquid separation The denitrification method described in 1. 原水を濃縮処理及び脱水処理することにより、窒素及び有機物を含有する被処理液を調製する濃縮・脱水装置と、
前記被処理液を、従属栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理して第1脱窒処理液を得る第1脱窒槽と、
前記第1脱窒処理液中に含まれるアンモニア性窒素の一部をアンモニア酸化菌により亜硝酸性窒素に酸化して亜硝酸化処理液を得る亜硝酸化槽と、
前記亜硝酸化処理液を、独立栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理する第2脱窒槽と、
前記亜硝酸化処理液を前記第1脱窒槽へ循環する亜硝酸化処理液循環手段と
を備え、
前記第1脱窒処理槽内に循環した前記亜硝酸化処理液中の亜硝酸性窒素を前記第1脱窒槽内の前記従属栄養性細菌を用いた脱窒反応により窒素ガスに変換して除去することを特徴とする脱窒処理装置。
A concentration / dehydration device for preparing a liquid to be treated containing nitrogen and organic matter by concentrating and dewatering raw water;
The liquid to be treated, a first denitrification tank to obtain a first denitrified liquid anaerobically denitrified by denitrification with heterotrophic bacteria,
A nitritation tank that oxidizes a part of ammonia nitrogen contained in the first denitrification treatment liquid to nitrite nitrogen by ammonia oxidizing bacteria to obtain a nitritation treatment liquid;
A second denitrification tank for anaerobically denitrifying the nitritation solution by a denitrification reaction using autotrophic bacteria;
A nitrite treatment liquid circulating means for circulating the nitrite treatment liquid to the first denitrification tank,
The nitrite nitrogen in the nitritation treatment liquid circulated in the first denitrification treatment tank is converted into nitrogen gas and removed by a denitrification reaction using the heterotrophic bacteria in the first denitrification treatment tank. The denitrification processing apparatus characterized by performing.
原水を濃縮処理及び脱水処理することにより、窒素及び有機物を含有する被処理液を調製する濃縮・脱水装置と、
前記被処理液を、従属栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理して第1脱窒処理液を得る第1脱窒槽と、
前記第1脱窒処理液中に含まれるアンモニア性窒素の一部をアンモニア酸化菌により亜硝酸性窒素に酸化して亜硝酸化処理液を得る亜硝酸化槽と、
前記亜硝酸化処理液を、独立栄養性細菌を用いた脱窒反応により嫌気的に脱窒処理する第2脱窒槽と、
前記第2脱窒処理液の一部を前記第1脱窒処理へ循環する第2脱窒処理液循環手段と
を備えることを特徴とする脱窒処理装置。
A concentration / dehydration device for preparing a liquid to be treated containing nitrogen and organic matter by concentrating and dewatering raw water;
The liquid to be treated, a first denitrification tank to obtain a first denitrified liquid anaerobically denitrified by denitrification with heterotrophic bacteria,
A nitritation tank that oxidizes a part of ammonia nitrogen contained in the first denitrification treatment liquid to nitrite nitrogen by ammonia oxidizing bacteria to obtain a nitritation treatment liquid;
A second denitrification tank for anaerobically denitrifying the nitritation solution by a denitrification reaction using autotrophic bacteria;
And a second denitrification treatment liquid circulating means for circulating a part of the second denitrification treatment liquid to the first denitrification treatment.
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JP6666165B2 (en) * 2016-02-18 2020-03-13 水ing株式会社 Nitrification and denitrification treatment method for ammoniacal nitrogen-containing liquid to be treated
CN110885160B (en) * 2018-09-07 2022-04-19 斗山重工业建设有限公司 Water treatment apparatus and method for removing nitrogen contained in water to be treated
CN110255711B (en) * 2019-06-18 2021-12-14 江苏南大环保科技有限公司 Rapid low-cost denitrification treatment device and method
CN111646578B (en) * 2020-05-28 2021-05-11 河海大学 Method for removing nitrate in sewage through synergetic denitrification of iron autotrophic bacteria and heterotrophic bacteria
CN111807650B (en) * 2020-08-19 2022-08-09 福建海峡环保集团股份有限公司 Livestock and poultry breeding wastewater CC-HBDP treatment process

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JPS60206498A (en) * 1984-03-30 1985-10-18 Kurita Water Ind Ltd Treatment of excretion sewage
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