JP2015078139A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
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- JP2015078139A JP2015078139A JP2013214881A JP2013214881A JP2015078139A JP 2015078139 A JP2015078139 A JP 2015078139A JP 2013214881 A JP2013214881 A JP 2013214881A JP 2013214881 A JP2013214881 A JP 2013214881A JP 2015078139 A JP2015078139 A JP 2015078139A
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- fatty acid
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000003599 detergent Substances 0.000 title abstract description 11
- 239000006260 foam Substances 0.000 claims abstract description 42
- 150000004665 fatty acids Chemical group 0.000 claims abstract description 32
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 26
- 239000000194 fatty acid Substances 0.000 claims abstract description 26
- 229930195729 fatty acid Natural products 0.000 claims abstract description 26
- -1 polyoxyethylene Polymers 0.000 claims abstract description 14
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 229910001413 alkali metal ion Inorganic materials 0.000 claims abstract description 4
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 31
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 230000007794 irritation Effects 0.000 abstract description 13
- 210000004379 membrane Anatomy 0.000 abstract description 6
- 239000012528 membrane Substances 0.000 abstract description 6
- 238000007599 discharging Methods 0.000 abstract description 2
- 210000004400 mucous membrane Anatomy 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000002193 fatty amides Chemical class 0.000 abstract 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 10
- 210000004877 mucosa Anatomy 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 239000003346 palm kernel oil Substances 0.000 description 6
- 235000019865 palm kernel oil Nutrition 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000972773 Aulopiformes Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000017 mucous membrane irritation Toxicity 0.000 description 3
- 235000019515 salmon Nutrition 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- 241000238424 Crustacea Species 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- DUKURNFHYQXCJG-UHFFFAOYSA-N Lewis A pentasaccharide Natural products OC1C(O)C(O)C(C)OC1OC1C(OC2C(C(O)C(O)C(CO)O2)O)C(NC(C)=O)C(OC2C(C(OC3C(OC(O)C(O)C3O)CO)OC(CO)C2O)O)OC1CO DUKURNFHYQXCJG-UHFFFAOYSA-N 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229940124274 edetate disodium Drugs 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 229950006780 n-acetylglucosamine Drugs 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 210000001672 ovary Anatomy 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 244000061508 Eriobotrya japonica Species 0.000 description 1
- 235000009008 Eriobotrya japonica Nutrition 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940110456 cocoa butter Drugs 0.000 description 1
- 235000019868 cocoa butter Nutrition 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
Abstract
Description
本発明は洗浄剤組成物に関し、詳しくは、ノンガスタイプの容器から泡状態で吐出される毛髪や皮膚用の洗浄剤組成物であって、眼粘膜に対する刺激が弱く、泡質が良く、泡吐出容器内部の多孔質膜で目詰まりしにくい洗浄剤組成物に関する。 The present invention relates to a cleaning composition, and more particularly, is a cleaning composition for hair and skin that is discharged in a foamed state from a non-gas type container and has low irritation to the eye mucosa, good foam quality, and foam discharge. The present invention relates to a detergent composition that is not easily clogged with a porous film inside a container.
従来、眼粘膜に対する刺激の弱い洗浄剤が乳幼児向けのシャンプー、ボディソープ、洗顔料などとして開発されてきた。このようなものとして、カルボキシベタイン型界面活性剤を洗浄成分として用いた低刺激性洗浄剤組成物（例えば特許文献１参照。）や、スルホコハク酸塩型界面活性剤を洗浄成分として用いることで刺激の少ない洗浄剤組成物（例えば、特許文献２参照。）などが提案されている。 Conventionally, detergents that are mildly irritating to the ocular mucosa have been developed as shampoos, body soaps, and facial cleansers for infants. As such, a mild stimulant composition using a carboxybetaine surfactant as a cleaning component (see, for example, Patent Document 1) or a sulfosuccinate surfactant as a cleaning component can be used as a stimulant. A detergent composition with a low content (see, for example, Patent Document 2) has been proposed.
一方、洗浄剤成分がノンガスタイプの泡吐出容器に収容されており、使用時に洗浄剤成分と空気が一緒になって、容器内部の多孔質膜を通過することにより泡が形成され、容器から泡状態で吐出される洗浄剤組成物も多数提案されている。このような洗浄剤組成物では、多孔質膜での目詰まりが発生することがあるため、目詰まりを抑制するための方法（例えば、特許文献３〜６参照。）が提案されている。また、泡質や起泡力を良くする方法（例えば、特許文献７〜９参照。）も提案されている。 On the other hand, the cleaning agent component is contained in a non-gas type foam discharge container, and when used, the cleaning agent component and air are combined together, and bubbles are formed by passing through the porous film inside the container. Many cleaning compositions ejected in a state have been proposed. In such a cleaning composition, clogging in the porous membrane may occur, and therefore a method for suppressing clogging (see, for example, Patent Documents 3 to 6) has been proposed. Moreover, the method (for example, refer patent documents 7-9) which improves foam quality and foaming power is also proposed.
しかしながらこれらの方法において、眼粘膜に対する刺激を弱くすること、泡質を良くすること、泡吐出容器の多孔質膜で目詰まりしにくくすることの全てを十分満足できるものはなかった。 However, none of these methods can sufficiently satisfy all of the weakening of irritation to the ocular mucosa, the improvement of foam quality, and the prevention of clogging with the porous film of the foam discharge container.
上記の状況に鑑み、本発明は、ノンガスタイプの容器から泡状態で吐出され、眼粘膜に対する刺激が弱く、泡質が良く、泡吐出容器内部の多孔質膜で目詰まりしにくい、毛髪や皮膚用の洗浄剤組成物を提供することを課題とする。 In view of the above situation, the present invention is a hair or skin that is discharged from a non-gas type container in a foam state, weakly irritating to the eye mucous membrane, has good foam quality, and is not easily clogged with a porous film inside the foam discharge container. It is an object of the present invention to provide a detergent composition for use.
本発明者は鋭意研究を重ねた結果、スルホコハク酸ポリオキシエチレン脂肪酸アミド塩、脂肪酸アミドプロピルベタイン及び多価アルコールを必須成分とし、それぞれの成分を特定量含有した洗浄剤組成物によって上記課題を解決し得ることを見出し、本発明を完成するに至った。 As a result of extensive research, the present inventor solved the above problems with a detergent composition containing sulfosuccinic acid polyoxyethylene fatty acid amide salt, fatty acid amidopropyl betaine and polyhydric alcohol as essential components, and each component containing a specific amount. As a result, the present invention has been completed.
すなわち本発明の洗浄剤組成物は、下記成分（Ａ）〜（Ｃ）を含有し、ノンガスタイプ容器内の多孔質膜を通り泡状で吐出されることを特徴とするものである。
（Ａ）下記一般式（Ｉ）で表されるスルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩 ３〜２０質量％
（Ｂ）下記一般式（ＩＩ）で表される脂肪酸アミドプロピルベタイン １〜１０質量％
（Ｃ）常温、常圧で液状の多価アルコール ３〜３０質量％
That is, the cleaning composition of the present invention contains the following components (A) to (C), and is characterized by being discharged in the form of foam through a porous film in a non-gas type container.
(A) 3 to 20% by mass of a sulfosuccinic acid polyoxyethylene fatty acid ethanolamide salt represented by the following general formula (I)
(B) Fatty acid amide propyl betaine 1-10 mass% represented by the following general formula (II)
(C) 3 to 30% by mass of polyhydric alcohol that is liquid at normal temperature and pressure
本発明の洗浄剤組成物は、ノンガスタイプの容器から泡状態で吐出され、眼粘膜に対する刺激が弱く、泡質が良く、泡吐出容器内部の多孔質膜で目詰まりしにくいという点に特に優れている。さらに、泡立ちの良さ、指通りの滑らかさ、高い洗浄性、すすぎやすさ、保存安定性という利点も備えている。 The cleaning composition of the present invention is particularly excellent in that it is discharged from a non-gas type container in a foamed state, is less irritating to the ocular mucosa, has good foam quality, and is not easily clogged by the porous film inside the foam discharge container. ing. Furthermore, it also has the advantages of good foaming, smoothness of fingers, high cleanability, ease of rinsing and storage stability.
本発明に用いられる（Ａ）スルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩は下記一般式（Ｉ）で表されるものであり、洗浄を主な目的として配合されるものである。
上記一般式（Ｉ）中のＲＣＯは炭素数８〜２２の脂肪酸残基である。脂肪酸としてはオクタン酸、デカン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、べヘン酸、パーム核油脂肪酸、ヤシ油脂肪酸などが挙げられ、ラウリン酸、パーム核油脂肪酸、ヤシ油脂肪酸が特に好ましい。ｎは２〜１０であり、好ましいのは３〜７である。Ｘ＋はアルカリ金属イオンであり、好ましいのはカリウムイオン、ナトリウムイオンである。 RCO in the above general formula (I) is a fatty acid residue having 8 to 22 carbon atoms. Examples of fatty acids include octanoic acid, decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, palm kernel oil fatty acid, coconut oil fatty acid, etc., lauric acid, palm kernel oil fatty acid, coconut Oil fatty acids are particularly preferred. n is 2 to 10, and preferably 3 to 7. X + is an alkali metal ion, preferably a potassium ion or a sodium ion.
本発明に用いられる（Ａ）スルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩の配合量は、これを含有する洗浄剤組成物全体を１００質量％として、３〜２０質量％である。３質量％未満では泡の均質性、洗浄効果などで満足の得られる結果とはならない。２０質量％を超えると眼粘膜に対する刺激が強くなる場合がある。 The compounding amount of the (A) sulfosuccinic acid polyoxyethylene fatty acid ethanolamide salt used in the present invention is 3 to 20% by mass, based on 100% by mass of the entire detergent composition containing the same. If it is less than 3% by mass, satisfactory results are not obtained in terms of foam homogeneity and cleaning effect. If it exceeds 20% by mass, irritation to the ocular mucosa may become strong.
本発明に用いられる（Ｂ）脂肪酸アミドプロピルベタインは下記一般式（ＩＩ）で表されるものであり、洗浄を主な目的として配合されるものである。
上記一般式（ＩＩ）中のＲＣＯは炭素数８〜２２の脂肪酸残基である。脂肪酸としてはオクタン酸、デカン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、べヘン酸、パーム核油脂肪酸、ヤシ油脂肪酸などが挙げられ、ラウリン酸、パーム核油脂肪酸、ヤシ油脂肪酸が特に好ましい。 RCO in the general formula (II) is a fatty acid residue having 8 to 22 carbon atoms. Examples of the fatty acid include octanoic acid, decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, palm kernel oil fatty acid, coconut oil fatty acid, etc., lauric acid, palm kernel oil fatty acid, coconut Oil fatty acids are particularly preferred.
本発明に用いられる（Ｂ）脂肪酸アミドプロピルベタインの配合量は、これを含有する洗浄剤組成物全体を１００質量％として、１〜１０質量％である。１質量％未満では泡の均質性、洗浄効果などで満足の得られる結果とはならない。１０質量％を超えると眼粘膜に対する刺激が強くなる場合がある。 The compounding quantity of (B) fatty acid amide propyl betaine used for this invention is 1-10 mass% by making the whole cleaning composition containing this into 100 mass%. If it is less than 1% by mass, satisfactory results are not obtained in terms of foam homogeneity and cleaning effect. If it exceeds 10% by mass, irritation to the ocular mucosa may become strong.
スルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩と脂肪酸アミドプロピルベタインはどちらも眼粘膜に対する刺激が比較的弱い洗浄成分である。一般的に、眼粘膜や皮膚に対する刺激の弱い洗浄成分は起泡力が弱く、泡質も良くない場合が多い。そのため泡吐出容器には適さない。しかし特定のスルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩と脂肪酸アミドプロピルベタインを組み合わせて用いることにより、刺激の弱さと泡質の良さを両立することができる。 Both the polyoxyethylene fatty acid ethanolamide salt of sulfosuccinic acid and fatty acid amidopropyl betaine are cleaning ingredients with relatively weak irritation to the ocular mucosa. In general, a cleaning ingredient with weak irritation to the ocular mucosa and skin often has low foaming power and poor foam quality. Therefore, it is not suitable for a foam discharge container. However, the combination of specific sulfosuccinic acid polyoxyethylene fatty acid ethanolamide salt and fatty acid amidopropyl betaine makes it possible to achieve both weakness of stimulation and good foam quality.
本発明に用いられる（Ｃ）常温、常圧で液状の多価アルコールは、泡吐出容器内にある多孔質膜の目詰まりを抑制すること、保湿効果などを目的として配合されるものである。泡を吐出させた際、泡吐出ノズル内部に残った洗浄剤組成物は、再び多孔質膜を通りボトル内部まで戻る。洗浄剤組成物の乾燥が速いと、ボトル内部に戻る前に多孔質膜で乾燥固化して目詰まりを起こしてしまう場合がある。多価アルコールは洗浄剤組成物の乾燥を遅らせ、目詰まりを抑制する。 The (C) polyhydric alcohol that is liquid at normal temperature and normal pressure used in the present invention is blended for the purpose of suppressing clogging of the porous film in the foam discharge container, moisturizing effect, and the like. When the foam is discharged, the cleaning composition remaining inside the foam discharge nozzle returns to the inside of the bottle again through the porous membrane. If the cleaning composition is dried quickly, it may become clogged by drying and solidifying with the porous film before returning to the inside of the bottle. The polyhydric alcohol delays drying of the cleaning composition and suppresses clogging.
本発明に用いられる（Ｃ）常温、常圧で液状の多価アルコールとしてはジプロピレングリコール、１，３−ブチレングリコール、グリセリン、ジグリセリン、ポリグリセリン、ジエチレングリコール、トリエチレングリコールなどが挙げられる。 Examples of the polyhydric alcohol (C) used in the present invention at room temperature and normal pressure include dipropylene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyglycerin, diethylene glycol, and triethylene glycol.
本発明に用いられる（Ｃ）常温、常圧で液状の多価アルコールの配合量は、これを含有する洗浄剤組成物全体を１００質量％として、３〜３０質量％である。３質量％未満では多孔質膜での目詰まり抑制で満足の得られる結果とはならない。３０質量％を超えると洗浄剤組成物の粘度が上昇し、逆に目詰まりの原因となったり、泡になりにくい場合もある。また眼粘膜に対する刺激が強くなる場合もあり好ましくない。 (C) The compounding quantity of the polyhydric alcohol which is liquid at normal temperature and normal pressure used in the present invention is 3 to 30% by mass based on 100% by mass of the entire detergent composition containing the same. If it is less than 3% by mass, satisfactory results cannot be obtained by suppressing clogging in the porous membrane. If it exceeds 30% by mass, the viscosity of the cleaning composition increases, and on the contrary, it may cause clogging or foam. Moreover, the irritation | stimulation with respect to an ocular mucosa may become strong, and is unpreferable.
本発明の洗浄剤組成物には、上記必須成分の他、一般に洗浄剤に適用される各種の原料や成分を、本発明の効果を損ねない範囲で適宜配合することができる。このような原料・成分としては、（Ａ）、（Ｂ）成分以外の界面活性剤、（Ｃ）成分以外のアルコール類、糖類、水溶性高分子、油性成分、香料、色素、防腐剤、殺菌剤、酸化防止剤、金属イオン封鎖剤、薬剤、植物エキス等が挙げられる。 In the cleaning composition of the present invention, in addition to the above essential components, various raw materials and components generally applied to cleaning agents can be appropriately blended within a range that does not impair the effects of the present invention. As such raw materials and components, surfactants other than the components (A) and (B), alcohols other than the component (C), saccharides, water-soluble polymers, oily components, fragrances, pigments, preservatives, bactericides Agents, antioxidants, sequestering agents, drugs, plant extracts and the like.
本発明の洗浄剤組成物としては、頭髪用シャンプー、全身用シャンプー、ボディソープ、洗顔料、ハンドソープ等が挙げられる。 Examples of the cleaning composition of the present invention include shampoo for hair, shampoo for whole body, body soap, face wash, hand soap and the like.
以下、実施例と比較例をもって本発明をさらに詳しく説明する。本発明は、以下の実施例や比較例によって何ら限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples. The present invention is not limited at all by the following examples and comparative examples.
実施例に先立ち、各実施例、比較例で用いた試験法、評価法を説明する。 Prior to the examples, test methods and evaluation methods used in the examples and comparative examples will be described.
（眼粘膜刺激）
実施例、比較例の洗浄剤組成物を精製水で十倍に希釈し、パネルメンバー１０名の眼にスポイトで一滴滴下し、刺激の有無について官能評価を行った。各洗浄剤組成物の評価基準は下記の通りである。
（評価基準）
◎・・・パネルメンバー８名以上が刺激を感じなかった。
○・・・パネルメンバー６名以上８名未満が刺激を感じなかった。
△・・・パネルメンバー３名以上６名未満が刺激を感じなかった。
×・・・パネルメンバーのうち刺激を感じなかったのが３名未満。
(Eye mucous membrane irritation)
The cleaning compositions of Examples and Comparative Examples were diluted ten-fold with purified water, and one drop was dropped onto the eyes of 10 panel members with a dropper, and sensory evaluation was performed for the presence or absence of irritation. The evaluation criteria for each cleaning composition are as follows.
(Evaluation criteria)
◎ ... More than 8 panel members did not feel irritation.
○ ... 6 or more and less than 8 panel members did not feel irritation.
Δ: 3 or more and less than 6 panel members did not feel irritation.
×: Less than 3 panel members did not feel irritation.
（泡質）
実施例、比較例の洗浄剤組成物を泡吐出容器から吐出させ、泡の状態についてパネルメンバー１０名が目視による評価を行った。各洗浄剤組成物の評価基準は下記の通りである。（評価基準）
◎・・・パネルメンバー８名以上が泡は均質であると評価した。
○・・・パネルメンバー６名以上８名未満が泡は均質であると評価した。
△・・・パネルメンバー３名以上６名未満が泡は均質であると評価した。
×・・・パネルメンバーのうち泡は均質であると評価したのが３名未満。
(Foam quality)
The cleaning agent compositions of Examples and Comparative Examples were discharged from the foam discharge container, and 10 panel members evaluated visually about the state of the foam. The evaluation criteria for each cleaning composition are as follows. (Evaluation criteria)
◎ ... Eight or more panel members evaluated the foam as homogeneous.
○ 6 or more panel members and less than 8 panel members evaluated the foam as homogeneous.
Δ: Three or more panel members and less than six panel members evaluated the bubbles to be homogeneous.
X: Less than 3 panel members evaluated foam as homogeneous.
（容器の目詰まり）
実施例、比較例の洗浄剤組成物を泡吐出容器１０個に充填し、泡を１回吐出させた後、そのまま２５℃、４０％の相対湿度に調節した恒温恒湿室内に２日間放置した。その後、再度吐出操作を行ない、目詰まりを確認した。各洗浄剤組成物の評価基準は下記の通りである。
（評価基準）
◎・・・泡吐出容器８個以上が目詰まりを起こさなかった。
○・・・泡吐出容器６個以上８個未満が目詰まりを起こさなかった。
△・・・泡吐出容器３個以上６個未満が目詰まりを起こさなかった。
×・・・泡吐出容器が目詰まりを起こさなかったのは３個未満。
(Clogged container)
The detergent compositions of Examples and Comparative Examples were filled into 10 foam discharge containers, and the foam was discharged once, and then left for 2 days in a constant temperature and humidity room adjusted to 25 ° C. and 40% relative humidity. . Thereafter, the discharging operation was performed again, and clogging was confirmed. The evaluation criteria for each cleaning composition are as follows.
(Evaluation criteria)
A: Eight or more foam discharge containers were not clogged.
○: 6 or more and less than 8 foam discharge containers were not clogged.
Δ: 3 or more and less than 6 foam discharge containers were not clogged.
X: Less than 3 foam discharge containers did not clog.
実施例１〜９、比較例１〜６
表１、２に示した処方の洗浄料組成物を調整し、前記各試験を実施した。その結果を表１、２に併せて示す。各成分の配合量の単位は質量％である。
Examples 1-9, Comparative Examples 1-6
The cleaning compositions having the formulations shown in Tables 1 and 2 were prepared, and the above tests were performed. The results are also shown in Tables 1 and 2. The unit of the amount of each component is mass%.
表１の通り、本発明の実施例１〜９の洗浄剤組成物は、眼粘膜刺激、泡質、容器の目詰まりのどの項目の評価においても◎か○であった。一方表２の通り、比較例１〜６の洗浄剤組成物はいずれかの項目に△あるいは×の評価があった。これらの結果より、実施例が比較例より優れていることは明らかである。 As shown in Table 1, the cleaning compositions of Examples 1 to 9 of the present invention were evaluated as ◎ or ○ in any evaluation items of eye mucous membrane irritation, foam quality, and clogging of the container. On the other hand, as shown in Table 2, the cleaning compositions of Comparative Examples 1 to 6 were evaluated as Δ or × in any item. From these results, it is clear that the example is superior to the comparative example.
以下に、本発明の洗浄剤組成物のその他の処方例を実施例として挙げる。なお、これらの実施例の洗浄剤組成物についても、上記の眼粘膜刺激、泡質、容器の目詰まりについて評価したところ、いずれの実施例においても優れた特性を有していた。 Below, the other formulation example of the cleaning composition of this invention is given as an Example. The cleaning compositions of these examples were also evaluated for the above-mentioned eye mucous membrane irritation, foam quality, and clogging of the container, and all of the examples had excellent characteristics.
実施例１０（乳幼児用全身シャンプー）
（質量％）
１．スルホコハク酸ポリオキシエチレンラウロイル
エタノールアミド二ナトリウム（５Ｅ．Ｏ．） １０．０
２．パーム核油脂肪酸アミドプロピルベタイン ５．０
３．ジプロピレングリコール １０．０
４．グリセリン ５．０
５．精製水 ２０．０
６．塩化グリシジルトリメチルアンモニウム
ヒドロキシエチルセルロース ０．１
７．安息香酸ナトリウム ０．２
８．エデト酸二ナトリウム ０．１
９．ビワ葉抽出液 ０．１
１０．桃葉抽出液 ０．１
１１．加水分解サケ卵巣膜抽出液 ０．１
１２．塩水湖水塩 ０．０１
１３．酵素分解デンプン水素添加物 ０．１
１４．甲殻類由来アセチルグルコサミン ０．０１
１５．マカデミアナッツ油脂肪酸フィトステリル ０．０１
１６．乳酸球菌発酵ヒアルロン酸ナトリウム ０．１
１７．鱈浮袋由来水溶性コラーゲン ０．１
１８．精製水 残 余
Example 10 (Full-body shampoo for infants)
(mass%)
1. Sulfosuccinic acid polyoxyethylene lauroyl ethanolamide disodium (5E.O.) 10.0
2. Palm kernel oil fatty acid amidopropyl betaine 5.0
3. Dipropylene glycol 10.0
4). Glycerin 5.0
5. Purified water 20.0
6). Glycidyltrimethylammonium chloride hydroxyethylcellulose 0.1
7). Sodium benzoate 0.2
8). Edetate disodium 0.1
9. Loquat leaf extract 0.1
10. Peach leaf extract 0.1
11. Hydrolyzed salmon ovary membrane extract 0.1
12 Saltwater Lake Salt 0.01
13. Enzymatic hydrogenated starch starch 0.1
14 Crustacean-derived acetylglucosamine 0.01
15. Macadamia nut oil fatty acid phytosteryl 0.01
16. Lactococcal fermented sodium hyaluronate 0.1
17. Water-soluble collagen derived from salmon float 0.1
18. Purified water residue
（製造方法）
成分５に成分６を加え、分散させながら８０℃まで加温、それに成分７、８を加え溶解させた。その後、残りの成分を加え混合分散し、室温まで冷却した。
(Production method)
Component 6 was added to component 5, heated to 80 ° C. while being dispersed, and components 7 and 8 were added and dissolved therein. Thereafter, the remaining components were added, mixed and dispersed, and cooled to room temperature.
実施例１１（シャンプー）
（質量％）
１．スルホコハク酸ポリオキシエチレンラウロイル
エタノールアミド二ナトリウム（５Ｅ．Ｏ．） １５．０
２．パーム核油脂肪酸アミドプロピルベタイン ８．０
３．ジプロピレングリコール １０．０
４．１，３−ブチレングリコール ５．０
５．安息香酸ナトリウム ０．２
６．エデト酸二ナトリウム ０．１
７．レモン抽出液 ０．１
８．ハス種子乳酸菌発酵液 ０．１
９．加水分解サケ卵巣膜抽出液 ０．１
１０．ヨクイニンエキス ０．１
１１．酵素分解デンプン水素添加物 ０．１
１２．甲殻類由来アセチルグルコサミン ０．１
１３．カカオ脂 ０．０１
１４．シア脂 ０．０１
１５．精製水 ｔｏ１００
Example 11 (Shampoo)
(mass%)
1. Sulfosuccinic acid polyoxyethylene lauroylethanolamide disodium (5E.O.) 15.0
2. Palm kernel oil fatty acid amidopropyl betaine 8.0
3. Dipropylene glycol 10.0
4.1,3-Butylene glycol 5.0
5. Sodium benzoate 0.2
6). Edetate disodium 0.1
7). Lemon extract 0.1
8). Lotus seed lactic acid bacteria fermentation solution 0.1
9. Hydrolyzed salmon ovary membrane extract 0.1
10. Yokuinin extract 0.1
11. Enzymatic hydrogenated starch starch 0.1
12 Crustacean-derived acetylglucosamine 0.1
13. Cocoa butter 0.01
14 Shea fat 0.01
15. Purified water to100
（製造方法）
成分１５に成分１〜１２を混合分散し、それに成分１３、１４を加温溶解したものを加え分散させた。
(Production method)
Components 1 to 12 were mixed and dispersed in component 15, and components 13 and 14 were dissolved by heating and dispersed therein.
本発明の洗浄剤組成物は、ノンガスタイプの容器から泡状態で吐出され、眼粘膜に対する刺激が弱く、泡質が良く、泡吐出容器内部の多孔質膜で目詰まりしにくいという点に特に優れているが、泡立ちの良さ、指通りの滑らかさ、高い洗浄性、すすぎやすさ、保存安定性という利点も備えている。そのため毛髪や肌を洗浄する為に用いる医薬品、医薬部外品または化粧品分野での応用が可能であり、産業上極めて有用なものである。 The cleaning composition of the present invention is particularly excellent in that it is discharged from a non-gas type container in a foamed state, is less irritating to the ocular mucosa, has good foam quality, and is not easily clogged by the porous film inside the foam discharge container. However, it also has the advantages of good foaming, smoothness of fingers, high cleanability, ease of rinsing and storage stability. Therefore, it can be applied in the field of pharmaceuticals, quasi-drugs and cosmetics used for washing hair and skin, and is extremely useful industrially.
Claims (1)
（Ａ）下記一般式（Ｉ）で表されるスルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩 ３〜２０質量％
（Ｂ）下記一般式（ＩＩ）で表される脂肪酸アミドプロピルベタイン １〜１０質量％
（Ｃ）常温、常圧で液状の多価アルコール ３〜３０質量％ A cleaning composition comprising the following components (A) to (C) and discharged in the form of foam through a porous film in a non-gas type container.
(A) 3 to 20% by mass of a sulfosuccinic acid polyoxyethylene fatty acid ethanolamide salt represented by the following general formula (I)
(B) Fatty acid amide propyl betaine 1-10 mass% represented by the following general formula (II)
(C) 3 to 30% by mass of polyhydric alcohol that is liquid at normal temperature and pressure
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| JPWO2009028339A1 (en) * | 2007-08-30 | 2010-11-25 | ライオン株式会社 | Skin cleansing material and skin cleansing method using the same |
| JP2011148772A (en) * | 2009-12-22 | 2011-08-04 | Lion Corp | Skin detergent |
| JP2013155332A (en) * | 2012-01-31 | 2013-08-15 | Mandom Corp | Transparent liquid detergent |
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