JP2014231197A - Decorative coating film for decorating surface of base material such as reel body for fishing - Google Patents

Decorative coating film for decorating surface of base material such as reel body for fishing Download PDF

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JP2014231197A
JP2014231197A JP2013113683A JP2013113683A JP2014231197A JP 2014231197 A JP2014231197 A JP 2014231197A JP 2013113683 A JP2013113683 A JP 2013113683A JP 2013113683 A JP2013113683 A JP 2013113683A JP 2014231197 A JP2014231197 A JP 2014231197A
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film
silver mirror
decorative coating
layer
silver
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JP6166589B2 (en
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小池 守
Mamoru Koike
守 小池
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Globeride Inc
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Abstract

PROBLEM TO BE SOLVED: To improve interlayer adhesion in a decorative coating film for decorating a surface of a base material.SOLUTION: A decorative coating film according to one embodiment includes: an inner film formed on a surface of a base material, such as a reel body for fishing; and a translucent layer that is formed on the inner film and is translucent. The translucent layer includes: a silver mirror part formed in a sea-island shape on the inner film; and an outer film formed on the inner film having the silver mirror part formed thereon.

Description

本発明は、装飾用被膜及びこれを形成する方法、魚釣用リールに関し、詳しくは、基材の表面を装飾する装飾用被膜及びこれを形成する方法、魚釣用リールに関する。   The present invention relates to a decorative coating, a method for forming the decorative coating, and a fishing reel. More specifically, the present invention relates to a decorative coating for decorating the surface of a substrate, a method for forming the decorative coating, and a fishing reel.

従来より、金属やプラスチック等の基材に対して鏡面光沢を付与するために、銀鏡反応を利用した装飾用被膜を形成することが行われている(例えば、特許文献1参照)。この装飾用被膜では、基材に対して内側層を形成し、この内側層の上に銀薄膜層を形成し、この銀薄膜層の上に外側層を形成している。また、銀薄膜層を、アミンを配位子とする銀金属錯体で形成し、この銀薄膜層表層のアミンと内側層及び外側層の樹脂とを反応させることにより、銀薄膜層と内側層及び外側層との結合力の増大を図っている。   2. Description of the Related Art Conventionally, a decorative coating using a silver mirror reaction has been formed in order to give a specular gloss to a base material such as metal or plastic (see, for example, Patent Document 1). In this decorative film, an inner layer is formed on the substrate, a silver thin film layer is formed on the inner layer, and an outer layer is formed on the silver thin film layer. Further, the silver thin film layer is formed of a silver metal complex having an amine as a ligand, and the silver thin film layer and the inner layer The bond strength with the outer layer is increased.

特開2012−235707号公報JP 2012-235707 A

しかしながら、こうした装飾用被膜では、内側層及び外側層は、銀薄膜層の下面及び上面のみに接触して結合するから、その密着性には限界がある。   However, in such a decorative coating, the inner layer and the outer layer are in contact with and bonded to only the lower surface and the upper surface of the silver thin film layer, so that there is a limit to the adhesion.

そこで、本発明の様々な実施形態は、基材の表面を装飾する装飾用被膜において層間の密着性を向上させることを目的の一つとする。本発明の様々な実施形態の他の目的は、本明細書全体を参照することにより明らかとなる。   Accordingly, various embodiments of the present invention have an object of improving the adhesion between layers in a decorative coating for decorating the surface of a substrate. Other objects of the various embodiments of the present invention will become apparent by reference to the entire specification.

本発明の一実施形態に係る装飾用被膜は、基材の表面を装飾する装飾用被膜であって、前記基材の表面に形成された内側膜と、前記内側膜上に海島状に形成された銀鏡部と、当該銀鏡部が形成された前記内側膜上に形成された外側膜とを有し、半透明な半透明層と、を備える。   The decorative coating according to an embodiment of the present invention is a decorative coating for decorating the surface of a substrate, and is formed in an island shape on the inner membrane formed on the surface of the substrate and the inner membrane. A semi-transparent layer having a silver mirror part and an outer film formed on the inner film on which the silver mirror part is formed.

本発明の一実施形態に係る魚釣用リールは、リール本体と、前記リール本体の表面の少なくとも一部に形成された内側膜と、前記内側膜上に海島状に形成された銀鏡部と、当該銀鏡部が形成された前記内側膜上に形成された外側膜とを有し、半透明な半透明層と、を備える。   A fishing reel according to an embodiment of the present invention includes a reel body, an inner film formed on at least a part of the surface of the reel body, a silver mirror portion formed in a sea-island shape on the inner film, An outer film formed on the inner film on which the silver mirror portion is formed, and a translucent translucent layer.

本発明の一実施形態に係る方法は、装飾用被膜を形成する方法であって、基材を準備する工程と、前記基材の表面に内側膜を形成する工程と、前記内側膜上に海島状に銀鏡部を形成する工程と、当該銀鏡部が形成された前記内側膜上に外側膜を形成する工程と、を備える。   A method according to an embodiment of the present invention is a method of forming a decorative film, the step of preparing a base material, the step of forming an inner film on the surface of the base material, and a sea island on the inner film Forming a silver mirror part in a shape, and forming an outer film on the inner film on which the silver mirror part is formed.

本発明の様々な実施形態によって、基材の表面を装飾する装飾用被膜において層間の密着性を向上させることができる。   Various embodiments of the present invention can improve adhesion between layers in a decorative coating that decorates the surface of a substrate.

本発明の一実施形態に係る装飾用被膜の模式図。The schematic diagram of the film for decoration concerning one embodiment of the present invention.

以下、様々な実施形態を適宜図面を参照して説明する。なお、図面における共通する構成要素には同一の参照符号が付されている。   Hereinafter, various embodiments will be described with reference to the drawings as appropriate. In addition, the same referential mark is attached | subjected to the common component in drawing.

図1は、本発明の一実施形態に係る装飾用被膜10の断面を模式的に表す模式図である。一実施形態における装飾用被膜10は、図示するように、釣り用リールのリール本体等の基材12の表面に形成された内側膜14と、この内側膜14上に形成され半透明な半透明層16とを備え、半透明層16は、内側膜14上に海島状に疎らに形成された銀鏡部18と、この銀鏡部18が形成された内側膜14上に形成された外側膜20とを有する。なお、図1は、本発明の一実施形態に係る装飾用被膜10の構成を模式的に表すものであり、その寸法は必ずしも正確に図示されていない点に留意されたい。   FIG. 1 is a schematic view schematically showing a cross section of a decorative coating 10 according to an embodiment of the present invention. As shown in the drawing, the decorative coating 10 in one embodiment includes an inner film 14 formed on the surface of a base material 12 such as a reel body of a fishing reel, and a translucent translucent film formed on the inner film 14. The semitransparent layer 16 includes a silver mirror portion 18 formed sparsely in a sea-island shape on the inner film 14, and an outer film 20 formed on the inner film 14 on which the silver mirror portion 18 is formed. Have Note that FIG. 1 schematically shows the configuration of the decorative coating 10 according to an embodiment of the present invention, and the dimensions thereof are not necessarily shown accurately.

基材12は、本発明の一実施形態に係る装飾用被膜10を用いて装飾する様々な被装飾物の表層を構成する基材であり、様々な材質、形状等とすることができる。例えば、釣り用リールのリール本体を装飾する場合、基材12は、アルミニウム合金、マグネシウム合金等の金属や、ABS樹脂、PA樹脂等の高強度樹脂、CFRP、GFRP等の繊維強化樹脂等によって形成される。   The base material 12 is a base material that constitutes the surface layer of various objects to be decorated using the decorative coating 10 according to an embodiment of the present invention, and can have various materials, shapes, and the like. For example, when decorating the reel body of a fishing reel, the base material 12 is formed of a metal such as an aluminum alloy or a magnesium alloy, a high-strength resin such as ABS resin or PA resin, or a fiber reinforced resin such as CFRP or GFRP. Is done.

内側膜14は、銀鏡部18の下地(アンダーコート層)として機能し、例えば、アクリル系樹脂やエポキシ系樹脂、ウレタン系樹脂等を主成分とする樹脂性のコーティング成分を基材12の表面にスプレー等を利用して液状で吹き付け、その後、所定温度での硬化処理(例えば、60℃で180分間加熱する)を行うことにより形成することができる。内側膜14の膜厚は特に限定されず、例えば、5〜30μmの膜厚で形成することができる。   The inner film 14 functions as a base (undercoat layer) for the silver mirror portion 18. For example, a resinous coating component mainly composed of an acrylic resin, an epoxy resin, a urethane resin, or the like is applied to the surface of the substrate 12. It can be formed by spraying in a liquid state using a spray or the like and then performing a curing treatment at a predetermined temperature (for example, heating at 60 ° C. for 180 minutes). The film thickness of the inner film 14 is not particularly limited, and can be formed with a film thickness of 5 to 30 μm, for example.

銀鏡部18は、内側膜14上に銀鏡反応によって形成され、例えば、一般的な銀鏡塗装プロセスを用いて形成することができる。より具体的には、硝酸銀及びアンモニアを含むアンモニア性硝酸銀溶液と、アルデヒド等の還元剤溶液とを内側膜14の表層上で混合されるように塗布することによって形成され、例えば、両溶液を別々のスプレーガン等によって噴射することによって形成される。ここで、図1に示すように、銀鏡部18は内側膜14上に海島状に疎らに形成される。例えば、アンモニア性硝酸銀溶液における銀の含有率を銀鏡部を均一な銀薄膜層として形成する場合の値よりも小さな値としたり、内側膜14の表層上に塗布する時間を短く(塗布スピードを早く)したり、又は、これらを組み合せることにより、銀鏡部18を海島状に疎らに形成することができる。図1においては、銀鏡部18は、略均等な間隔で形成されているように示されているが、スプレーガン等からの溶液の噴射によって形成される場合には、不規則的な間隔、形状で形成される。また、銀鏡部18の膜厚は特に限定されず、例えば、0.05〜0.1μmの膜厚で形成することができる。なお、銀鏡部18を形成する前に、内側膜14上に予め触媒層を形成しても良い。この触媒層は、内側膜14と銀鏡部18との間のカップリング効果を奏し、銀を析出するためのスターターの役割も果たす。こうした触媒層は、例えば、第一塩化スズを水に溶解させた第一塩化スズ溶液を塗布することによって形成することができる。   The silver mirror part 18 is formed on the inner film 14 by a silver mirror reaction, and can be formed using, for example, a general silver mirror coating process. More specifically, it is formed by applying an ammoniacal silver nitrate solution containing silver nitrate and ammonia and a reducing agent solution such as aldehyde so as to be mixed on the surface layer of the inner film 14. It is formed by spraying with a spray gun or the like. Here, as shown in FIG. 1, the silver mirror portion 18 is sparsely formed on the inner film 14 like a sea island. For example, the silver content in the ammoniacal silver nitrate solution is set to a value smaller than the value when the silver mirror portion is formed as a uniform silver thin film layer, or the time for coating on the surface layer of the inner film 14 is shortened (the coating speed is increased). ) Or a combination thereof, the silver mirror portion 18 can be formed sparsely in a sea-island shape. In FIG. 1, the silver mirror portions 18 are shown to be formed at substantially equal intervals, but when formed by spraying of a solution from a spray gun or the like, irregular intervals and shapes are formed. Formed with. Moreover, the film thickness of the silver mirror part 18 is not specifically limited, For example, it can form with a film thickness of 0.05-0.1 micrometer. Note that a catalyst layer may be formed in advance on the inner film 14 before the silver mirror portion 18 is formed. This catalyst layer has a coupling effect between the inner membrane 14 and the silver mirror portion 18 and also serves as a starter for depositing silver. Such a catalyst layer can be formed, for example, by applying a stannous chloride solution in which stannous chloride is dissolved in water.

外側膜20は、銀鏡部18の上塗り(トップコート層)として機能する。外側膜20は、前述した内側膜14と同様に形成することができ、例えば、アクリル系樹脂、エポキシ系樹脂、ウレタン系樹脂等を主成分とする樹脂性のコーティング成分を銀鏡部18が形成された内側膜14の表面にスプレー等を利用して液状で吹きつけ、その後、所定温度での硬化処理(例えば、70℃で60分間加熱する)を行うことにより形成することができる。図1に示すように、銀鏡部18が内側膜14上に海島状に疎らに形成されているから、外側膜20は、銀鏡部18の海島間の隙間に入り込んで、各海島を内側膜14と共に囲い込むように形成される。なお、銀鏡部18を形成した後、腐食防止剤を塗布し、この腐食防止剤の上から外側膜20を形成することもできる。また、外側膜20は、無色透明、又は、着色剤を添加して有色透明に形成されている。さらに、外側膜20の膜厚は特に限定されず、例えば、5〜30μmの膜厚で形成することができる。   The outer film 20 functions as a top coat (top coat layer) of the silver mirror portion 18. The outer film 20 can be formed in the same manner as the inner film 14 described above. For example, the silver mirror portion 18 is formed of a resinous coating component mainly composed of acrylic resin, epoxy resin, urethane resin, or the like. It can be formed by spraying the surface of the inner film 14 in a liquid state using a spray or the like and then performing a curing process at a predetermined temperature (for example, heating at 70 ° C. for 60 minutes). As shown in FIG. 1, since the silver mirror portion 18 is formed sparsely in a sea island shape on the inner membrane 14, the outer membrane 20 enters a gap between the sea islands of the silver mirror portion 18, and each sea island is passed through the inner membrane 14. And is formed so as to be enclosed. In addition, after forming the silver mirror part 18, a corrosion inhibitor can be apply | coated and the outer film | membrane 20 can also be formed on this corrosion inhibitor. Further, the outer film 20 is formed to be colorless and transparent, or colored and transparent by adding a colorant. Furthermore, the film thickness of the outer film | membrane 20 is not specifically limited, For example, it can form with a film thickness of 5-30 micrometers.

ここで、内側膜14上に海島状に疎らに形成された銀鏡部18と、この銀鏡部18が形成された内側膜14上に形成された外側膜20とによって、一実施形態における半透明層16が構成される。半透明層16は、海島状に疎らに形成された銀鏡部18と透明な外側層20とによって半透明となっており、より具体的には、一般的な銀の可視光反射率(98%)より小さな可視光反射率となっており、例えば、80%以下の可視光反射率となっている。こうして構成された半透明層16において、外側膜20の表面からの入射光は、一部が銀鏡部18によって反射し、一部が内側膜14に達する。こうした入射光の挙動によって、一実施形態における装飾用被膜10は、従来の銀鏡塗装では実現されない装飾性を得ることができる。   Here, a semi-transparent layer in one embodiment is formed by a silver mirror portion 18 sparsely formed in a sea-island shape on the inner film 14 and an outer film 20 formed on the inner film 14 on which the silver mirror portion 18 is formed. 16 is configured. The translucent layer 16 is translucent due to the sparsely formed silver mirror portion 18 and the transparent outer layer 20 formed in a sea-island shape. More specifically, the visible light reflectance (98%) of general silver ) The visible light reflectance is smaller, for example, the visible light reflectance is 80% or less. In the translucent layer 16 thus configured, a part of the incident light from the surface of the outer film 20 is reflected by the silver mirror portion 18 and a part of the incident light reaches the inner film 14. Due to the behavior of such incident light, the decorative coating 10 in one embodiment can obtain a decorative property that is not realized by conventional silver mirror coating.

以上説明した一実施形態における装飾用被膜10では、内側膜14上に海島状に疎らに銀鏡部18を形成し、この銀鏡部18が形成された内側膜14上に外側膜20を形成する。従って、外側膜20が、銀鏡部18の海島間の隙間に入り込んで、各海島を内側膜14と共に囲い込むように形成されるから、内側膜14と外側膜20とが直接接触して密着し、装飾用被膜を構成する層間の密着性を向上させることができる。また、銀鏡部18を外側膜20と内側膜14とによって包み込むから、銀鏡部18の耐食性が向上し、仮に銀鏡部18の一部(海島)が腐食しても、腐食が銀鏡部18全体に拡がりに難い。さらに、銀鏡部18と外側膜20とによって構成される半透明な(一般的な銀の可視光反射率よりも小さな可視光反射率である)半透明層16を表層に備えるから、従来の銀鏡塗装では実現されない装飾性を得ることができる。   In the decorative coating 10 according to the embodiment described above, the silver mirror part 18 is formed on the inner film 14 sparsely like a sea island, and the outer film 20 is formed on the inner film 14 on which the silver mirror part 18 is formed. Therefore, since the outer membrane 20 is formed so as to enter the gap between the sea islands of the silver mirror portion 18 and surround each sea island with the inner membrane 14, the inner membrane 14 and the outer membrane 20 are in direct contact and are in close contact with each other. The adhesion between the layers constituting the decorative coating can be improved. Further, since the silver mirror part 18 is encased by the outer film 20 and the inner film 14, the corrosion resistance of the silver mirror part 18 is improved, and even if a part of the silver mirror part 18 (sea island) is corroded, the corrosion is entirely applied to the silver mirror part 18. Difficult to spread. Further, since the translucent layer 16 (having a visible light reflectance smaller than that of general silver) formed of the silver mirror portion 18 and the outer film 20 is provided on the surface layer, the conventional silver mirror is provided. Decorative properties that cannot be achieved by painting can be obtained.

10 装飾用被膜
12 基材
14 内側膜
16 半透明層
18 銀鏡部
20 外側膜
DESCRIPTION OF SYMBOLS 10 Decorative coating 12 Base material 14 Inner film 16 Translucent layer 18 Silver mirror part 20 Outer film

Claims (5)

基材の表面を装飾する装飾用被膜であって、
前記基材の表面に形成された内側膜と、
前記内側膜上に海島状に形成された銀鏡部と、当該銀鏡部が形成された前記内側膜上に形成された外側膜とを有し、半透明な半透明層と、
を備える装飾用被膜。
A decorative coating for decorating the surface of a substrate,
An inner membrane formed on the surface of the substrate;
A silver mirror part formed in a sea-island shape on the inner film, and an outer film formed on the inner film on which the silver mirror part is formed, a translucent translucent layer,
A decorative coating comprising:
前記半透明層は、可視光反射率が80%以下である請求項1記載の装飾用被膜。   The decorative coating according to claim 1, wherein the translucent layer has a visible light reflectance of 80% or less. リール本体と、
前記リール本体の表面の少なくとも一部に形成された内側膜と、
前記内側膜上に海島状に形成された銀鏡部と、当該銀鏡部が形成された前記内側膜上に形成された外側膜とを有し、半透明な半透明層と、
を備える魚釣用リール。
The reel body,
An inner membrane formed on at least a part of the surface of the reel body;
A silver mirror part formed in a sea-island shape on the inner film, and an outer film formed on the inner film on which the silver mirror part is formed, a translucent translucent layer,
Fishing reel equipped with.
装飾用被膜を形成する方法であって、
基材を準備する工程と、
前記基材の表面に内側膜を形成する工程と、
前記内側膜上に海島状に銀鏡部を形成する工程と、
当該銀鏡部が形成された前記内側膜上に外側膜を形成する工程と、
を備える方法。
A method of forming a decorative film,
Preparing a substrate;
Forming an inner membrane on the surface of the substrate;
Forming a silver mirror portion in a sea-island shape on the inner membrane;
Forming an outer film on the inner film on which the silver mirror portion is formed;
A method comprising:
前記銀鏡部と前記外側膜とによって半透明な半透明層を構成する請求項4記載の方法。   The method according to claim 4, wherein the silver mirror part and the outer film constitute a translucent translucent layer.
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* Cited by examiner, † Cited by third party
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