JP2014221898A - Pressure-sensitive adhesive composition, pressure-sensitive adhesive, and pressure-sensitive adhesive sheet - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a pressure-sensitive adhesive composition which is excellent in both light leakage resistance and durability when applied to an optical member such as a polarizing plate, and to provide a method for producing the pressure-sensitive adhesive composition, a pressure-sensitive adhesive, and a pressure-sensitive adhesive sheet.SOLUTION: The pressure-sensitive adhesive composition contains: 100 pts.mass of a first (meth)acrylate polymer (A) having a weight-average molecular weight of 700,000-2,500,000; 5-40 pts.mass of a second (meth)acrylate polymer (B) having a weight-average molecular weight of 8,000-250,000; and a crosslinking agent (C). The polymer (B) contains as a constituent only a monomer having a functional group (b1) reactive with the crosslinking agent (C) in an amount of 1-50 mass%. The polymer (A) does not contain as a constituent a monomer having a functional group reactive with the crosslinking agent (C) or contains as a constituent a monomer having a functional group (a1) which has lower reactivity with the crosslinking agent (C) than the functional group (b1) of the polymer (B).

Description

  The present invention relates to a pressure-sensitive adhesive composition, a method for producing a pressure-sensitive adhesive composition, a pressure-sensitive adhesive (a material obtained by crosslinking a pressure-sensitive adhesive composition), and a pressure-sensitive adhesive sheet, and is particularly suitable for optical members such as polarizing plates. The present invention relates to an adhesive composition, a method for producing an adhesive composition, an adhesive, and an adhesive sheet.

  In general, in a liquid crystal panel, a pressure-sensitive adhesive layer formed from a pressure-sensitive adhesive composition is often used to bond a polarizing plate or a retardation plate to a glass substrate or the like. However, since optical members such as polarizing plates and retardation plates are easily shrunk by heat, etc., shrinkage occurs due to thermal history, and as a result, the adhesive layer laminated on the optical member cannot follow the shrinkage. Problems have been pointed out, such as peeling at the interface (so-called floating or peeling), or light leakage (so-called white spots) due to displacement of the optical axis of the optical member due to stress during contraction of the optical member. .

  As a method for preventing this, (1) a method of suppressing the contraction of the optical member itself by bonding a pressure-sensitive adhesive layer having high adhesive strength and excellent shape stability to an optical member such as a polarizing plate. Or (2) a method using a pressure-sensitive adhesive layer having a small stress when the optical member is contracted. As the method (1), it is effective to use a pressure-sensitive adhesive layer having a high storage elastic modulus as disclosed in Patent Document 1. On the other hand, as the method (2), it is effective to use a pressure-sensitive adhesive layer having excellent stress relaxation properties that can flexibly cope with deformation of the optical member. However, conventionally, when it was attempted to form such an adhesive layer having excellent stress relaxation properties, it was necessary to design a low crosslinking density in the adhesive layer. If it does so, there existed a problem that the intensity | strength of adhesive layer itself fell and durability deteriorated.

  Therefore, in Patent Documents 2 to 4, by adding a plasticizer, liquid paraffin, urethane elastomer or the like to the acrylic pressure-sensitive adhesive instead of lowering the cross-linking density of the pressure-sensitive adhesive layer, the resulting pressure-sensitive adhesive composition becomes moderately soft. Thus, stress relaxation is imparted to the pressure-sensitive adhesive layer, thereby obtaining light leakage resistance and durability.

JP 2006-235568 A Japanese Patent Laid-Open No. 5-45517 Japanese Patent Laid-Open No. 9-137143 JP 2005-194366 A

  However, the pressure-sensitive adhesive composition to which a plasticizer or liquid paraffin is added has a drawback that the formed pressure-sensitive adhesive layer bleeds out the plasticizer and liquid paraffin over time. As a result, various problems such as contamination of the liquid crystal cell as an adherend have occurred. Moreover, since the upper limit of the addition amount of a urethane elastomer will be limited if it is going to maintain compatibility, the adhesive composition which added the urethane elastomer is inadequate in improvement of stress relaxation property. Furthermore, when the addition amount of the urethane elastomer is increased in order to improve the stress relaxation property, the compatibility with the acrylic pressure-sensitive adhesive is lowered, and problems such as cloudiness have occurred. As described above, it has been difficult for the conventional technology to fundamentally improve the light leakage resistance and durability of the pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition for optical members.

  The present invention has been made in view of such a situation, and when applied to an optical member such as a polarizing plate, the pressure-sensitive adhesive composition excellent in both light leakage resistance and durability, the pressure-sensitive adhesive composition It aims at providing the manufacturing method of this, an adhesive, and an adhesive sheet.

  In order to achieve the above object, first, the present invention includes a first (meth) acrylate polymer (A) having a weight average molecular weight of 700,000 to 2,500,000 and a weight average molecular weight of 8,000 to 250,000. The second (meth) acrylic acid ester polymer (B) and the crosslinking agent (C), and the second (meth) acrylic acid ester polymer (A) with respect to 100 parts by mass The ratio of the (meth) acrylate polymer (B) is 5 to 40 parts by mass, and the second (meth) acrylate polymer (B) is a functional group that reacts with the crosslinking agent (C). A monomer having (b1) is contained as a constituent component, and the proportion of the monomer having the functional group (b1) is 1% by mass in the second (meth) acrylic acid ester polymer (B). And less than 50% by mass The functional group that reacts with the crosslinking agent (C) contained in the second (meth) acrylic acid ester polymer (B) is substantially only the functional group (b1), and the first ( The (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the crosslinking agent (C) as a constituent component, or the second (meth) acrylic acid ester polymer (B). Provided is a pressure-sensitive adhesive composition comprising a monomer having a functional group (a1) that is less reactive with the cross-linking agent (C) than the functional group (b1) (invention 1). .

Second, the present invention relates to a first (meth) acrylic acid ester polymer (A) having a weight average molecular weight of 700,000 to 2.5 million and a second (meth) acrylic acid having a weight average molecular weight of 8,000 to 250,000. The second (meth) acrylate polymer (100) containing 100 parts by mass of the first (meth) acrylate polymer (A), which contains an ester polymer (B) and a crosslinking agent (C). The ratio of B) is 5 to 40 parts by mass, and the second (meth) acrylic acid ester polymer (B) has a functionality satisfying the following formula (I) with the reactivity with the crosslinking agent (C). The monomer having the group (b1) is contained as a constituent component, and the proportion of the monomer having the functional group (b1) is 1 mass in the second (meth) acrylate polymer (B). % And less than 50% by mass The second (meth) acrylic acid ester polymer (B) includes a monomer having a functional group (b2) having reactivity with the crosslinking agent (C) satisfying the following formula (I). The first (meth) acrylic ester polymer (A) is contained as a constituent component in an amount (mass ratio) of 1/5 or less of the content of the monomer having b1), and the cross-linking agent (C) It does not contain a monomer having a functional group that reacts as a constituent component, or is more reactive with the cross-linking agent (C) than the functional group (b1) of the second (meth) acrylic acid ester polymer (B). A pressure-sensitive adhesive composition comprising a monomer having a low functional group (a1) as a constituent component is provided (Invention 2).
Reactivity with crosslinking agent (C): functional group (b2) <functional group (b1) (I)

  In the pressure-sensitive adhesive obtained by crosslinking the pressure-sensitive adhesive composition according to the above inventions (Inventions 1 and 2), a low molecular weight polymer (B) conventionally used as a plasticizer is a three-dimensional network formed by chemical crosslinking. Form a structure. Then, by inserting a plurality of high molecular weight polymers (A) into the three-dimensional network structure, the high molecular weight polymers (A) are constrained to each other, and the high molecular weight polymers (A) are simulated. Form a cross-linked structure. Thereby, the obtained adhesive exhibits appropriate cohesive force and excellent stress relaxation properties. By using this pressure-sensitive adhesive having excellent stress relaxation properties, a pressure-sensitive adhesive sheet excellent in both light leakage resistance and durability can be obtained when applied to an optical member such as a polarizing plate.

  In the said invention (invention 1 and 2), the said 1st (meth) acrylic acid ester polymer (A) may not contain the monomer which has a functional group which reacts with the said crosslinking agent (C) as a structural component. Preferred (Invention 3).

In the above inventions (Inventions 1 and 3), the functional group (a1) in the first (meth) acrylic acid ester polymer (A) is a hydroxyl group , and the second (meth) acrylic acid ester polymer. The functional group (b1) in (B) is a carboxyl group , and the crosslinking agent (C) is at least one selected from an epoxy crosslinking agent, an aziridine crosslinking agent and a metal chelate crosslinking agent. Is preferred (Invention 4).

In the said invention (invention 2 and 3), the said functional group (a1) in said 1st (meth) acrylic acid ester polymer (A) is a hydroxyl group , and said 2nd (meth) acrylic acid ester polymer The functional group (b1) in (B) is a carboxyl group , the functional group (b2) is a hydroxyl group , and the crosslinking agent (C) is an epoxy crosslinking agent, an aziridine crosslinking agent, and a metal chelate crosslinking agent. It is preferable that it is at least one selected from (Invention 5).

In the said invention (invention 4 and 5), the said 1st (meth) acrylic acid ester polymer (A) contains 0-15 mass% of hydroxyl-containing monomers as a monomer unit which comprises the said polymer. Preferred (Invention 6).

In the said invention (invention 4-6), said 2nd (meth) acrylic acid ester polymer (B) contains 3-40 mass% of carboxy group containing monomers as a monomer unit which comprises the said polymer. Is preferable (Invention 7).

In the above invention (invention 4 to 7), the content of the crosslinking agent (C), the crosslinkable group of the crosslinking agent (C) is in the second (meth) acrylic acid ester polymer (B) functional The amount is preferably 0.1 to 3.5 equivalents relative to the amount of the group (b1) (Invention 8).

  3rdly, this invention is a method of manufacturing the said adhesive composition (invention 1-8), Comprising: Said 1st (meth) acrylic acid ester polymer (A) and said 2nd (meth). Provided is a method for producing a pressure-sensitive adhesive composition characterized by mixing the acrylic ester polymer (B) and adding the crosslinking agent (C) at an arbitrary stage (Invention 9).

  4thly this invention provides the adhesive formed by bridge | crosslinking the said adhesive composition (invention 1-8) (invention 10).

  5thly this invention is an adhesive sheet provided with the base material and the adhesive layer, Comprising: The said adhesive layer consists of the said adhesive (invention 10), The adhesive sheet characterized by the above-mentioned is provided. Invention 11).

  In the said invention (invention 11), it is preferable that the said base material is an optical member (invention 12).

  Sixth, the present invention is an adhesive sheet comprising two release sheets and an adhesive layer sandwiched between the release sheets so as to be in contact with the release surfaces of the two release sheets. A layer provides the adhesive sheet characterized by consisting of the said adhesive (invention 10) (invention 13).

  In the pressure-sensitive adhesive obtained by crosslinking the pressure-sensitive adhesive composition according to the present invention, a three-dimensional network structure is formed by chemical crosslinking with a low molecular weight polymer that has been conventionally used as a plasticizer. Then, by inserting a plurality of high molecular weight polymers into the three-dimensional network structure, the high molecular weight polymers are constrained to form a pseudo-crosslinked structure between the high molecular weight polymers. Thereby, the obtained adhesive exhibits appropriate cohesive force and excellent stress relaxation properties. By using this pressure-sensitive adhesive having excellent stress relaxation properties, a pressure-sensitive adhesive sheet excellent in both light leakage resistance and durability can be obtained when applied to an optical member such as a polarizing plate.

It is sectional drawing of the adhesive sheet which concerns on the 1st Embodiment of this invention. It is sectional drawing of the adhesive sheet which concerns on the 2nd Embodiment of this invention. It is a figure which shows the measurement area | region of the light leak test in a polarizing plate with an adhesive layer.

Hereinafter, embodiments of the present invention will be described.
[Adhesive composition]
The pressure-sensitive adhesive composition according to this embodiment includes a first (meth) acrylic acid ester polymer (A) having a weight average molecular weight of 700,000 to 2,500,000, and a second (meth) acrylate having a weight average molecular weight of 8,000 to 250,000. It contains a (meth) acrylic acid ester polymer (B) and a crosslinking agent (C), and preferably further contains a silane coupling agent (D). In this specification, (meth) acrylic acid ester means both acrylic acid ester and methacrylic acid ester. The same applies to other similar terms. Further, the “polymer” includes the concept of “copolymer”.

The second (meth) acrylic acid ester polymer (B) is
(1) A monomer having a functional group (b1) that reacts with the crosslinking agent (C) is a constituent component, and the functional group that reacts with the crosslinking agent (C) contained in the polymer (B) is substantially functional. Or only the group (b1)
(2) A functional group in which the reactivity with the crosslinking agent (C) satisfies the following formula (I) and the reactivity of the monomer having the functional group (b1) with the crosslinking agent (C) satisfies the following formula (I) ( The monomer having b2) is used as a constituent component.
Reactivity with crosslinking agent (C): functional group (b2) <functional group (b1) (I)
That is, in the polymer (B) of (2), the reactivity of the functional group (b1) with the crosslinking agent (C) is higher than the reactivity of the functional group (b2) with the crosslinking agent (C).

  In any of the polymers (B) of (1) and (2) above, the constituent ratio of the monomer having the functional group (b1) in the polymer (B) is more than 1% by mass and less than 50% by mass. is there. In addition, the polymer (B) of (2) comprises the monomer having the functional group (b2) in an amount (mass ratio) of 1/5 or less of the content of the monomer having the functional group (b1). Contains as a component.

  In addition, “substantially only the functional group (b1)” in the polymer (B) of the above (1) means other functional groups that react with the crosslinking agent (C), the functional group (b1) and the crosslinking agent ( It is allowed to be included to such an extent that the reactivity with C) is not hindered. Accordingly, the polymer (B) containing a small amount of the functional group (b2) is also included in the polymer (B). In that case, the polymer (B) and the polymer (2) (1) ( B) is duplicated.

  On the other hand, the first (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the crosslinking agent (C) as a constituent unit, or the second (meth) acrylic acid ester. A monomer having a functional group (a1) that is less reactive with the crosslinking agent (C) than the functional group (b1) of the polymer (B) is used as a constituent component.

  The (meth) acrylic acid ester polymer (A) or (B) has a functional group that reacts with the (meth) acrylic acid ester having 1 to 20 carbon atoms in the alkyl moiety of the ester moiety and the crosslinking agent (C). A copolymer of the monomer (reactive functional group-containing monomer) and other monomers used as desired is preferable. In addition, what does not contain the said reactive functional group containing monomer as a structural unit is also preferable for a 1st (meth) acrylic acid ester polymer (A).

  Examples of the (meth) acrylic acid ester having 1 to 20 carbon atoms in the alkyl group of the ester moiety include, for example, methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, and (meth) acrylic acid. n-butyl, n-pentyl (meth) acrylate, n-hexyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, isooctyl (meth) acrylate, (meth) acrylic acid Examples include n-decyl, n-dodecyl (meth) acrylate, myristyl (meth) acrylate, palmityl (meth) acrylate, stearyl (meth) acrylate, and the like. These may be used alone or in combination of two or more.

  On the other hand, the reactive functional group-containing monomer includes a monomer having a hydroxyl group in the molecule (hydroxyl group-containing monomer), a monomer having a carboxyl group in the molecule (carboxyl group-containing monomer), and a monomer having an amino group in the molecule (amino group). Preferred monomer).

  Examples of the hydroxyl group-containing monomer include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, (meth And (meth) acrylic acid hydroxyalkyl esters such as 3-hydroxybutyl acrylate and 4-hydroxybutyl (meth) acrylate. These may be used alone or in combination of two or more.

  Examples of the carboxyl group-containing monomer include ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid, and citraconic acid. These may be used alone or in combination of two or more.

  Examples of the amino group-containing monomer include aminoethyl (meth) acrylate, n-butylaminoethyl (meth) acrylate, and the like. These may be used alone or in combination of two or more.

  Furthermore, as said other monomer, (meth) acrylic acid ester which has aromatic rings, such as (meth) acrylic acid ester which has aliphatic rings, such as (meth) acrylic acid cyclohexyl, and (meth) acrylic acid phenyl, for example Non-crosslinkable acrylamide such as acrylamide, methacrylamide, etc., and non-crosslinkable tertiary amino groups such as N, N-dimethylaminoethyl (meth) acrylate and N, N-dimethylaminopropyl (meth) acrylate (Meth) acrylic acid ester, vinyl acetate, styrene and the like can be mentioned. These may be used alone or in combination of two or more.

  The reactive functional group (a1) -containing monomer used in the first (meth) acrylic acid ester polymer (A) and the reactivity used in the second (meth) acrylic acid ester polymer (B). The selection of the functional group (b1) -containing monomer and the reactive functional group (b2) -containing monomer is determined by the reactivity relationship with the crosslinking agent (C) used. Details will be described later.

  Here, the second (meth) acrylic acid ester polymer (B) contains the reactive functional group (b1) -containing monomer in excess of 1% by mass, and the upper limit is less than 50% by mass. Preferably, the reactive functional group (b1) -containing monomer is contained in an amount of 3 to 40% by mass, particularly preferably 5 to 25% by mass. By containing the reactive functional group (b1) -containing monomer in the above range, the degree of crosslinking of the second (meth) acrylic acid ester polymer (B) becomes preferable, and the first (meth) acrylic acid ester weight In combination with the coalescence (A), the resulting pressure-sensitive adhesive has excellent stress relaxation properties. On the other hand, when the content of the reactive functional group (b1) -containing monomer is 1% by mass or less, the second (meth) acrylic acid ester polymer (B) is not sufficiently cross-linked, thereby reducing durability. On the other hand, when the content of the reactive functional group (b1) -containing monomer is 50% by mass or more, the second (meth) acrylic acid ester polymer (B) is excessively cross-linked, thereby to the adherend. There is a possibility that the bonding suitability of the resin may decrease. In addition, durability of the adhesive sheet obtained becomes more excellent by making the upper limit of content of a reactive functional group (b1) containing monomer into 40 mass%.

  The second (meth) acrylic acid ester polymer (B) is a monomer (reactive functional group) having a functional group (b2) that is less reactive with the crosslinking agent (C) than the functional group (b1). It is particularly preferable not to contain (b2) containing monomer) as a constituent component, but when the reactive functional group (b2) containing monomer is contained as a constituent component, the reactive functional group (b1) containing monomer as a mass ratio. It is preferable to contain in an amount of 1/5 or less of the content of, particularly 1/10 or less.

  The second (meth) acrylic acid ester polymer (B) has a reactive functional group (b2) -containing monomer in an amount exceeding 1/5 of the content of the reactive functional group (b1) -containing monomer as a mass ratio. When it contains, durability of the adhesive layer obtained will fall. If there are too many reactive functional groups (b2) in the second (meth) acrylic acid ester polymer (B), many reactive functional groups (b2) remain in the three-dimensional network structure formed thereby. Therefore, it is estimated that the compatibility between the three-dimensional network structure and the first (meth) acrylic acid ester polymer (A) is changed. As a result, the haze value may increase. In addition, the three-dimensional network structure in which a large amount of the reactive functional group (b2) remains has excessive mobility of the first (meth) acrylate polymer (A) inserted in the three-dimensional network structure. It is also estimated that it is limited to. As a result, durability may deteriorate.

  Furthermore, when the adhesive composition which concerns on this embodiment contains a silane coupling agent (D), a silane coupling agent (D) is the reactivity of a 1st (meth) acrylic acid ester polymer (A). A glass substrate or the like that is an adherend in the resulting pressure-sensitive adhesive when it reacts with the functional group (a1) (particularly a carboxyl group) and binds to the high molecular weight first (meth) acrylate polymer (A). However, if the second (meth) acrylic acid ester polymer (B) contains an excessive amount of the reactive functional group (b2) -containing monomer, the silane coupling agent (D) The alkoxysilyl group or the like reacts with the reactive functional group (b2) (particularly the carboxyl group) of the second (meth) acrylic acid ester polymer (B) to produce a low molecular weight second (meth) acrylic acid ester. Bonded with polymer (B) Then, it is estimated. As a result, the obtained pressure-sensitive adhesive is inferior in adhesion to a glass substrate as an adherend, thereby reducing the durability of the pressure-sensitive adhesive layer.

  Here, the 2nd (meth) obtained by superposing | polymerizing the (meth) acrylic acid ester whose carbon number of the alkyl group of an ester part is 1-20, and the monomer which has a functional group which reacts with a crosslinking agent (C). The polymerization mode of the acrylate polymer (B) may be a random copolymer or a block copolymer. In particular, if the second (meth) acrylic acid ester polymer (B) is a block copolymer, the size of the three-dimensional network structure can be controlled, so the second (meth) acrylic acid ester polymer (B) is also preferably a block copolymer. Specifically, in the second (meth) acrylic acid ester polymer (B), a monomer having a reactive functional group (b1) at both ends is converted to a (meth) acrylic acid ester having 1 to 20 carbon atoms. An embodiment in which copolymerization is carried out in a block manner is also preferred.

  In this embodiment, said 2nd (meth) acrylic-ester type polymer (B) may be used individually by 1 type, and may be used in combination of 2 or more type.

  The weight average molecular weight of the second (meth) acrylic acid ester polymer (B) is 8000 to 250,000, preferably 20,000 to 150,000. That is, the second (meth) acrylic acid ester polymer (B) is a low molecular weight polymer component. In addition, the weight average molecular weight in this specification is the value of polystyrene conversion measured by the gel permeation chromatography (GPC) method.

  When the weight average molecular weight of the second (meth) acrylic acid ester polymer (B) is within the above range, a three-dimensional network structure peculiar to the pressure-sensitive adhesive composition according to this embodiment is formed, and excellent stress is obtained. This will contribute to relaxation. That is, when the weight average molecular weight of the second (meth) acrylic acid ester polymer (B) is less than 8000, a good three-dimensional network structure cannot be obtained. On the other hand, when the weight average molecular weight of the second (meth) acrylic acid ester polymer (B) exceeds 250,000, the compatibility is lowered and the three-dimensional network structure formed by the polymer (B) is introduced. Insertion of the polymer (A) becomes insufficient, resulting in poor durability and reworkability.

  The first (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the crosslinking agent (C) as a constituent component, or the second (meth) acrylic acid ester polymer (B ) As a constituent component, and preferably a crosslinker than the functional group (b1). The monomer having a functional group (a1) that is less reactive with the crosslinker (C) than the functional group (b1) A monomer having a functional group highly reactive with (C) is not contained as a constituent component.

  The first (meth) acrylic acid ester polymer (A) may not contain a monomer having a functional group that reacts with the cross-linking agent (C), but the second (meth) acrylic acid ester polymer ( When a monomer having a reactive functional group (a1) that is less reactive than the reactive functional group (b1) of B) (a reactive functional group (a1) -containing monomer) is contained, the second (meth) acrylic acid ester When the reaction between the polymer (B) and the crosslinking agent (C) is promoted or the silane coupling agent (D) is used, the reaction of the first (meth) acrylate polymer (A) The functional group (a1) reacts with the alkoxysilyl group or the like of the silane coupling agent (D), and the degree of aggregation of the first (meth) acrylate polymer (A) can be adjusted. It is possible to obtain the adhesiveness of Correct in some cases.

  When the first (meth) acrylic acid ester polymer (A) contains the reactive functional group (a1) -containing monomer, the content is usually 20% by mass or less and 15% by mass or less. It is preferable that it is 10 mass% or less especially. If the content of the reactive functional group (a1) -containing monomer exceeds 20% by mass, the first (meth) acrylic acid ester polymer (A) may be aggregated too much and the desired stress relaxation property may not be obtained. There is. In addition, from the viewpoint of imparting reworkability, the content of the reactive functional group (a1) -containing monomer is preferably 15% by mass or less.

  Moreover, in comparison with the reactive functional group (b1) -containing monomer contained in the second (meth) acrylic acid ester polymer (B), the first (meth) acrylic acid ester polymer (A) is contained. The proportion of the reactive functional group (a1) -containing monomer in the first (meth) acrylate polymer (A) is the reactivity contained in the second (meth) acrylate polymer (B). It is preferably smaller than the proportion of the functional group (b1) -containing monomer in the second (meth) acrylic acid ester polymer (B). Thereby, reaction with the reactive functional group (a1) and the crosslinking agent (C) contained in the first (meth) acrylic acid ester polymer (A) is suppressed, and the second (meth) acrylic acid ester weight is reduced. The reactive functional group (b1) contained in the coalescence (B) and the crosslinking agent (C) can be reacted reliably.

  The first (meth) acrylic acid ester polymer (A) has the same reactivity with the crosslinking agent (C) as the reactive functional group (b1) of the second (meth) acrylic acid ester polymer (B). Although it is preferable not to contain the monomer which has the above functional groups in a molecule | numerator, when it contains, the content of the monomer which has the said functional group in a molecule | numerator is 1 mass% in a polymer (A). Or less, and particularly preferably 0.5% by mass or less. When the content of the monomer exceeds 1% by mass, the reaction between the second (meth) acrylic acid ester polymer (B) to be preferentially reacted and the crosslinking agent (C) may be inhibited.

  Here, the 1st (meth) acrylic acid ester polymer (A) obtained by superposing | polymerizing the (meth) acrylic acid ester whose carbon number of the alkyl group of an ester part is 1-20, and a reactive functional group containing monomer (A). ) May be a random copolymer or a block copolymer.

  In this embodiment, said 1st (meth) acrylic acid ester polymer (A) may be used individually by 1 type, and may be used in combination of 2 or more type.

  The weight average molecular weight of the first (meth) acrylic acid ester polymer (A) is 700,000 to 2,500,000, preferably 1,000,000 to 2,000,000. That is, the first (meth) acrylic acid ester polymer (A) is a high molecular weight polymer component.

  When the weight average molecular weight of the first (meth) acrylate polymer (A) is within the above range, the three-dimensional network structure formed by the second (meth) acrylate polymer (B) When the first (meth) acrylic acid ester polymer (A) is satisfactorily inserted and two or more molecules of the polymer (A) are via a pseudo-crosslinked structure, the polymer (A) has a certain degree of freedom. It is estimated that it is restrained in a state having a degree. As a result, the pressure-sensitive adhesive that is formed has both an appropriate cohesive force and excellent stress relaxation properties. As a result, it has excellent light leakage resistance, and has sufficient adhesion durability under high temperature and wet heat conditions. , Can prevent floating and peeling.

  Here, when the weight average molecular weight of the first (meth) acrylic acid ester polymer (A) is less than 700,000, the cohesive force of the component (A) is lowered and the durability and reworkability are inferior. There is a fear. Further, when the weight average molecular weight of the first (meth) acrylic acid ester polymer (A) exceeds 2.5 million, the compatibility with the second (meth) acrylic acid ester polymer (B) and the like deteriorates. There is a possibility that the haze value increases or the desired stress relaxation property cannot be obtained.

  The ratio of the second (meth) acrylic acid ester polymer (B) to 100 parts by mass of the first (meth) acrylic acid ester polymer (A) is 5 to 40 parts by mass, preferably 10 to 30 parts by mass. Part.

  In the pressure-sensitive adhesive obtained from the pressure-sensitive adhesive composition containing the first (meth) acrylic acid ester polymer (A) and the second (meth) acrylic acid ester polymer (B) at the above-mentioned ratio, The (meth) acrylic acid ester polymer (B) (low molecular weight polymer) forms a three-dimensional network structure via the cross-linking agent (C), and the first (meth) acrylic acid ester weight is added to the three-dimensional network structure. It is presumed that the polymer (A) (high molecular weight polymer) has a pseudo-crosslinked structure in which two or more molecules are inserted and the polymer (A) is constrained with a certain degree of freedom. Is done. Thereby, the obtained adhesive exhibits an excellent stress relaxation property while having an appropriate cohesive force. Therefore, the obtained adhesive is excellent in durability and light leakage resistance.

  Preferred examples of the crosslinking agent (C) include an isocyanate crosslinking agent, an epoxy crosslinking agent, an aziridine crosslinking agent, and a metal chelate crosslinking agent.

  The isocyanate-based crosslinking agent contains at least a polyisocyanate compound. Examples of the polyisocyanate compound include aromatic polyisocyanates such as tolylene diisocyanate, diphenylmethane diisocyanate, and xylylene diisocyanate, aliphatic polyisocyanates such as hexamethylene diisocyanate, alicyclic polyisocyanates such as isophorone diisocyanate, and hydrogenated diphenylmethane diisocyanate. , And their biuret bodies, isocyanurate bodies, and adduct bodies that are a reaction product with low molecular active hydrogen-containing compounds such as ethylene glycol, propylene glycol, neopentyl glycol, trimethylolpropane, castor oil, and the like.

  Examples of the epoxy crosslinking agent include 1,3-bis (N, N′-diglycidylaminomethyl) cyclohexane, N, N, N ′, N′-tetraglycidyl-m-xylylenediamine, ethylene glycol diglycidyl. Examples include ether, 1,6-hexanediol diglycidyl ether, trimethylolpropane diglycidyl ether, diglycidylaniline, diglycidylamine and the like.

  Examples of the aziridine-based crosslinking agent include diphenylmethane-4,4′-bis (1-aziridinecarboxamide), trimethylolpropane tri-β-aziridinylpropionate, tetramethylolmethanetri-β-aziridinyl. Propionate, toluene-2,4-bis (1-aziridinecarboxamide), triethylenemelamine, bisisophthaloyl-1- (2-methylaziridine), tris-1- (2-methylaziridine) phosphine, And trimethylolpropane tri-β- (2-methylaziridine) propionate.

  Metal chelate crosslinking agents include chelate compounds whose metal atoms are aluminum, zirconium, titanium, zinc, iron, tin, etc., but aluminum chelate compounds are preferred from the viewpoint of performance. Examples of the aluminum chelate compound include diisopropoxy aluminum monooleyl acetoacetate, monoisopropoxy aluminum bis oleyl acetoacetate, monoisopropoxy aluminum monooleate monoethyl acetoacetate, diisopropoxy aluminum monolauryl acetoacetate, diisopropoxy Examples thereof include aluminum monostearyl acetoacetate and diisopropoxy aluminum monoisostearyl acetoacetate.

  The content of the crosslinking agent (C) is such that the crosslinking group (for example, isocyanate group) of the crosslinking agent (C) is the reactive functional group (b1) of the second (meth) acrylate polymer (B) ( For example, the amount is usually 0.05 to 5 equivalents, preferably 0.1 to 3.5 equivalents, particularly preferably 0.2 to 1.8 equivalents relative to the amount of hydroxyl groups). This is the amount. If the amount of the crosslinkable group is 0.1 equivalent or more, the gel fraction of the pressure-sensitive adhesive obtained is 40% or more, can exhibit sufficient cohesive force, and if it is 0.2 equivalent or more, The resulting pressure-sensitive adhesive can be made more excellent in durability. On the other hand, if the amount of the crosslinkable group is 3.5 equivalents or less, the resulting pressure-sensitive adhesive can be made excellent in reworkability, and if it is 1.8 equivalents or less, The haze value can be kept low.

  In the present embodiment, as the crosslinking agent (C), a plurality of types of crosslinking agents may be used as long as the types of crosslinking agents have the same reactivity relationship with both the reactive functional group (b1) and the reactive functional group (a1). May be used in combination. From the viewpoint of facilitating control of the three-dimensional network structure formed by the second (meth) acrylic acid ester polymer (B), for example, only one type of crosslinking agent is used, such as using only an isocyanate-based crosslinking agent. It is particularly preferable to use only one crosslinking agent.

  On the other hand, as another embodiment, as the crosslinking agent (C), preferably one type of crosslinking agent, particularly preferably one crosslinking agent is used, and the reactive functional group (b1) and the reactive functional group (a1) The other cross-linking agent (CR) whose reactivity relationship with both is opposite to that of the cross-linking agent (C) is preferably 1/20 or less, particularly preferably 1/30 or less in terms of mass ratio to the cross-linking agent (C). Can be used in the amount of. For example, the aspect which uses a crosslinking agent (C) as an isocyanate type crosslinking agent and uses a small amount of epoxy type crosslinking agents as another crosslinking agent (CR) can be mentioned preferably. Addition of such other crosslinking agents is effective when the polymer (A) is not sufficiently inserted into the three-dimensional network structure formed by the polymer (B) and the cohesive force is insufficient. The other crosslinking agent (CR) is not included in the crosslinking agent (C) and is excluded from the crosslinking agent (C) in the quantitative relationship.

  Here, as a combination of the crosslinking agent (C) and the reactive functional group-containing monomers of the (meth) acrylic acid ester polymers (A) and (B), the crosslinking agent (C) is an isocyanate crosslinking agent. In this case, the reactive functional group (a1) -containing monomer of the polymer (A) is a carboxyl group-containing monomer, the reactive functional group (b1) -containing monomer of the polymer (B) is a hydroxyl group-containing monomer or an amino group-containing monomer, As the reactive functional group (b2) -containing monomer of the polymer (B), a carboxyl group-containing monomer is preferably selected.

  On the other hand, when the crosslinking agent (C) is an epoxy crosslinking agent, an aziridine crosslinking agent or a metal chelate crosslinking agent, the reactive functional group (a1) -containing monomer of the polymer (A) is a hydroxyl group-containing monomer or polymer. A carboxyl group-containing monomer is preferably selected as the reactive functional group (b1) -containing monomer of (B), and a hydroxyl group-containing monomer is preferably selected as the reactive functional group (b2) -containing monomer of the polymer (B).

  The flexibility of the bond formed between the cross-linking agent (C) and the polymer (B), and the mildness of the cross-linking reaction. Furthermore, the reactive group of the polymer (A) is combined with the silane coupling agent (D). Since it reacts appropriately and contributes to the improvement of the cohesive strength of the polymer (A), the crosslinking agent (C) is an isocyanate-based crosslinking agent, and the reactive functional group (a1) -containing monomer of the polymer (A) is a carboxyl group-containing monomer. It is particularly preferable that the reactive functional group (b1) -containing monomer of the polymer (B) is a hydroxyl group-containing monomer, and the reactive functional group (b2) -containing monomer of the polymer (B) is a carboxyl group-containing monomer.

  The adhesive composition according to this embodiment preferably further contains a silane coupling agent (D). When this silane coupling agent (D) is contained, when the first (meth) acrylic acid ester polymer (A) has a carboxyl group, the organic reactive group and the like of the silane coupling agent (D) and the first The carboxyl group of the (meth) acrylic acid ester polymer (A) reacts, and on the other hand, the alkoxysilyl group of the silane coupling agent (D) acts on the adherend surface such as a glass substrate. For this reason, when bonding a polarizing plate to a liquid crystal glass cell etc., the adhesiveness between an adhesive and a liquid crystal glass cell becomes more favorable, for example.

  The silane coupling agent (D) is an organosilicon compound having at least one alkoxysilyl group in the molecule, having good compatibility with the pressure-sensitive adhesive component, and having light transmittance, for example, substantially A transparent one is preferred. The amount of the silane coupling agent (D) added is preferably 0.01 to 0.5 parts by mass with respect to 100 parts by mass of the first (meth) acrylic acid ester polymer (A). In particular, it is preferably 0.05 to 0.3 parts by mass.

  Specific examples of the silane coupling agent (D) include polymerizable unsaturated group-containing silicon compounds such as vinyltrimethoxysilane, vinyltriethoxysilane, and methacryloxypropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, Silicon compounds having an epoxy structure such as 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-aminopropyltrimethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, N- Examples include amino group-containing silicon compounds such as (2-aminoethyl) -3-aminopropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, and 3-isocyanatopropyltriethoxysilane. These may be used individually by 1 type and may be used in combination of 2 or more type.

  In the above-mentioned adhesive composition, various additives usually used for acrylic adhesives, for example, tackifiers, antioxidants, ultraviolet absorbers, light stabilizers, softeners, fillers, antistatic agents, are optionally used. An agent, a refractive index adjusting agent, etc. can be added.

[Method for producing adhesive composition]
While the said adhesive composition mixes a 1st (meth) acrylic acid ester polymer (A) and a 2nd (meth) acrylic acid ester polymer (B), it is a crosslinking agent ( C) and, if desired, can be produced by adding a silane coupling agent (D).

  As a preferred specific example, the (meth) acrylic acid ester polymers (A) and (B) are separately prepared by a normal radical polymerization method. The polymerization of the (meth) acrylic acid ester polymers (A) and (B) can be carried out by a solution polymerization method or the like using a polymerization initiator as desired. Examples of the polymerization solvent include ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, acetone, hexane, methyl ethyl ketone, and the like. Two or more kinds may be used in combination.

  Examples of the polymerization initiator include azo compounds and organic peroxides, and two or more kinds may be used in combination. Examples of the azo compound include 2,2′-azobisisobutyronitrile, 2,2′-azobis (2-methylbutyronitrile), 1,1′-azobis (cyclohexane 1-carbonitrile), 2 2,2′-azobis (2,4-dimethylvaleronitrile), 2,2′-azobis (2,4-dimethyl-4-methoxyvaleronitrile), dimethyl 2,2′-azobis (2-methylpropionate) 4,4′-azobis (4-cyanovaleric acid), 2,2′-azobis (2-hydroxymethylpropionitrile), 2,2′-azobis [2- (2-imidazolin-2-yl) Propane] and the like.

  Examples of the organic peroxide include benzoyl peroxide, t-butyl perbenzoate, cumene hydroperoxide, diisopropyl peroxydicarbonate, di-n-propyl peroxydicarbonate, and di (2-ethoxyethyl) peroxy. Examples include dicarbonate, t-butyl peroxyneodecanoate, t-butyl peroxybivalate, (3,5,5-trimethylhexanoyl) peroxide, dipropionyl peroxide, diacetyl peroxide and the like.

  Next, the solutions of the obtained polymers (A) and (B) are mixed, and a diluting solvent is added. Thereafter, the cross-linking agent (C) and, if desired, the silane coupling agent (D) are added and mixed thoroughly to obtain an adhesive composition (coating solution) diluted with a solvent.

  Examples of the dilution solvent for diluting the adhesive composition to form a coating solution include aliphatic hydrocarbons such as hexane, heptane, and cyclohexane, aromatic hydrocarbons such as toluene and xylene, methylene chloride, and ethylene chloride. Halogenated hydrocarbons, alcohols such as methanol, ethanol, propanol, butanol and 1-methoxy-2-propanol, ketones such as acetone, methyl ethyl ketone, 2-pentanone, isophorone and cyclohexanone, esters such as ethyl acetate and butyl acetate, ethyl cellosolve A cellosolve solvent such as is used.

  The concentration / viscosity of the coating solution thus prepared is not particularly limited as long as it can be coated, and can be appropriately selected depending on the situation. For example, it dilutes so that the density | concentration of an adhesive composition may be 10-40 mass%. In addition, when obtaining an application | coating solution, addition of a dilution solvent etc. is not a necessary condition, and if a viscosity etc. which can be coated with an adhesive composition, it is not necessary to add a dilution solvent. In this case, the adhesive composition becomes the coating solution as it is.

[Adhesive]
The pressure-sensitive adhesive according to this embodiment is obtained by crosslinking the pressure-sensitive adhesive composition. Crosslinking of the pressure-sensitive adhesive composition can be performed by heat treatment. In addition, this heat processing can also serve as the drying process at the time of volatilizing the dilution solvent etc. of an adhesive composition.

  When performing heat processing, it is preferable that heating temperature is 50-150 degreeC, and it is especially preferable that it is 70-120 degreeC. The heating time is preferably 30 seconds to 3 minutes, particularly preferably 50 seconds to 2 minutes. Furthermore, it is particularly preferable to provide a curing period of about 1 to 2 weeks at room temperature (for example, 23 ° C., 50% RH) after the heat treatment.

  By the heat treatment (and curing), it is presumed that the second (meth) acrylic acid ester polymer (B) is crosslinked by the crosslinking agent (C) to form a dense three-dimensional network structure. And, by inserting two or more molecules of the first (meth) acrylate polymer (A) into the three-dimensional network structure without direct chemical bonds or with very few chemical bonds. The polymer (A) is constrained and presumed to form a pseudo-crosslinked structure. When the first (meth) acrylic acid ester polymer (A) has a carboxyl group, the first (meth) acrylic acid ester polymer (A) reacts with the silane coupling agent (D). Agglomerate to a predetermined extent.

  The above-described pressure-sensitive adhesive can be preferably used for an optical member. For example, adhesion between a polarizing plate and a retardation plate, or a polarizing plate (polarizing film) or a retardation plate (retardation film) and a glass substrate. Suitable for bonding. The pressure-sensitive adhesive layer formed by the above-mentioned pressure-sensitive adhesive has excellent stress relaxation properties, so even if the dimensional change of the adherend is large, the pressure-sensitive adhesive layer absorbs / relaxes stress that can be generated by the dimensional change. Therefore, it becomes difficult to peel off from the adherend over a long period of time, and light leakage can be effectively prevented when used in the optical member as described above. That is, the pressure-sensitive adhesive according to this embodiment achieves both light leakage resistance and durability.

[Adhesive sheet]
As shown in FIG. 1, the pressure-sensitive adhesive sheet 1 </ b> A according to the first embodiment is laminated on the pressure-sensitive adhesive layer 11, the pressure-sensitive adhesive layer 11 stacked on the release surface of the release sheet 12, and the pressure-sensitive adhesive layer 11. And the formed base material 13.

  In addition, as shown in FIG. 2, the adhesive sheet 1B according to the second embodiment includes the two release sheets 12a and 12b and the two release sheets 12a and 12b so as to be in contact with the release surfaces of the two release sheets 12a and 12b. And the pressure-sensitive adhesive layer 11 sandwiched between the release sheets 12a and 12b. In addition, the release surface of the release sheet in this specification refers to a surface having peelability in the release sheet, and includes both a surface that has been subjected to a release treatment and a surface that exhibits peelability without being subjected to a release treatment. .

  In any of the pressure-sensitive adhesive sheets 1A and 1B, the pressure-sensitive adhesive layer 11 is made of a pressure-sensitive adhesive formed by crosslinking the above-described pressure-sensitive adhesive composition.

  The thickness of the pressure-sensitive adhesive layer 11 is appropriately determined according to the purpose of use of the pressure-sensitive adhesive sheets 1A and 1B, but is usually in the range of 5 to 100 μm, preferably 10 to 60 μm, for example, for optical members, particularly for polarizing plates. When used as a PSA layer, it is preferably 10 to 50 μm, particularly preferably 10 to 30 μm.

  There is no restriction | limiting in particular as the base material 13, What was used as a base material sheet of a normal adhesive sheet can be used. For example, in addition to desired optical members, woven or non-woven fabrics using fibers such as rayon, acrylic, polyester, etc .; papers such as fine paper, glassine paper, impregnated paper, coated paper; metal foils such as aluminum and copper; urethane Foams, foams such as polyethylene foams; polyester films such as polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyurethane films, polyethylene films, polypropylene films, polyvinyl chloride films, polyvinylidene chloride films, polyvinyl alcohol films, ethylene -Plastic films such as vinyl acetate copolymer film, polystyrene film, polycarbonate film, acrylic resin film, norbornene resin film, cycloolefin resin film; And the like can be given more of the laminate. The plastic film may be uniaxially stretched or biaxially stretched.

  Examples of the optical member include a polarizing plate (polarizing film), a polarizer, a retardation plate (retarding film), a viewing angle compensation film, a brightness enhancement film, a contrast enhancement film, and a liquid crystal polymer film. Among these, since the polarizing plate (polarizing film) easily shrinks and has a large dimensional change, it is suitable as a target for forming the pressure-sensitive adhesive of the present embodiment (the pressure-sensitive adhesive layer 11) from the viewpoint of light leakage resistance.

  Although the thickness of the base material 13 changes with kinds, for example in the case of an optical member, they are 10 micrometers-500 micrometers normally, Preferably they are 50 micrometers-300 micrometers.

  As the release sheets 12, 12a, 12b, for example, polyethylene film, polypropylene film, polybutene film, polybutadiene film, polymethylpentene film, polyvinyl chloride film, vinyl chloride copolymer film, polyethylene terephthalate film, polyethylene naphthalate film, Polybutylene terephthalate film, polyurethane film, ethylene vinyl acetate film, ionomer resin film, ethylene / (meth) acrylic acid copolymer film, ethylene / (meth) acrylic acid ester copolymer film, polystyrene film, polycarbonate film, polyimide film A fluororesin film or the like is used. These crosslinked films are also used. Furthermore, these laminated films may be sufficient.

  The release surface of the release sheet (particularly the surface in contact with the pressure-sensitive adhesive layer 11) is preferably subjected to a release treatment. Examples of the release agent used for the release treatment include alkyd, silicone, fluorine, unsaturated polyester, polyolefin, and wax release agents.

  Although there is no restriction | limiting in particular about the thickness of the peeling sheets 12, 12a, 12b, Usually, it is about 20-150 micrometers.

In order to manufacture the pressure-sensitive adhesive sheet 1A, a solution (coating solution) containing the pressure-sensitive adhesive composition is applied to the release surface of the release sheet 12, and heat treatment is performed to form the pressure-sensitive adhesive layer 11. A base material 13 is laminated on the agent layer 11.
The conditions for the heat treatment are as described above.

  Moreover, in order to manufacture the said adhesive sheet 1B, the coating solution containing the said adhesive composition is apply | coated to the peeling surface of one peeling sheet 12a (or 12b), heat processing is performed, and the adhesive layer 11 is formed. After that, the release surface of the other release sheet 12b (or 12a) is overlaid on the adhesive layer 11.

  As a method for applying the coating solution, for example, a bar coating method, a knife coating method, a roll coating method, a blade coating method, a die coating method, a gravure coating method, or the like can be used.

  Here, for example, to manufacture a liquid crystal display device composed of a liquid crystal cell and a polarizing plate, a polarizing plate is used as the base material 13 of the pressure-sensitive adhesive sheet 1A, and the release sheet 12 of the pressure-sensitive adhesive sheet 1A is peeled off. What is necessary is just to bond the exposed adhesive layer 11 and a liquid crystal cell.

  For example, in order to manufacture a liquid crystal display device in which a retardation plate is disposed between a liquid crystal cell and a polarizing plate, one of the release sheets 12a (or 12b) of the adhesive sheet 1B is peeled off to expose the adhesive. The adhesive layer 11 and the liquid crystal cell are bonded together, then the other release sheet 12b (or 12a) is peeled off, and the exposed adhesive layer 11 and the retardation plate are bonded together. What is necessary is just to peel the peeling sheet 12 of 1 A of adhesive sheets using a board, and to bond the exposed adhesive layer 11 and phase difference plate.

  According to the above pressure-sensitive adhesive sheets 1A and 1B, since the pressure-sensitive adhesive layer 11 is very excellent in stress relaxation properties, even when applied to adhesion of a polarizing plate, for example, the stress that can be generated by deformation of the polarizing plate is generated in the pressure-sensitive adhesive layer 11. It can be assumed that excellent light leakage resistance and high durability can be exhibited.

  The embodiment described above is described for facilitating understanding of the present invention, and is not described for limiting the present invention. Therefore, each element disclosed in the above embodiment is intended to include all design changes and equivalents belonging to the technical scope of the present invention.

  For example, the release sheet 12 of the adhesive sheet 1A may be omitted, or one of the release sheets 12a and 12b in the adhesive sheet 1B may be omitted.

  EXAMPLES Hereinafter, although an Example etc. demonstrate this invention further more concretely, the scope of the present invention is not limited to these Examples etc.

[Example 1]
1. Preparation of polymer (A) In a reaction vessel equipped with a stirrer, a thermometer, a reflux condenser, a dropping device and a nitrogen introduction tube, 95.0 parts by mass of n-butyl acrylate, 5.0 parts by mass of acrylic acid, ethyl acetate 200 parts by mass and 0.02 parts by mass of 2,2′-azobisisobutyronitrile were charged, and the air in the reaction vessel was replaced with nitrogen gas. While stirring in this nitrogen atmosphere, the reaction solution was heated to 60 ° C., reacted for 16 hours, and then cooled to room temperature. Here, a part of the obtained solution was subjected to GPC measurement by a method described later, and production of a polymer (A) having a weight average molecular weight of 1,500,000 was confirmed.

2. Preparation of polymer (B) In a reaction vessel equipped with a stirrer, a thermometer, a reflux condenser, a dropping device and a nitrogen introduction tube, 85.0 parts by mass of n-butyl acrylate, 15.0 masses of 2-hydroxyethyl acrylate Part, 200 parts by mass of ethyl acetate, 0.16 parts by mass of 2,2′-azobisisobutyronitrile, and 0.3 parts by mass of 2-mercaptoethanol were charged, and the air in the reaction vessel was replaced with nitrogen gas. . While stirring in this nitrogen atmosphere, the reaction solution was heated to 70 ° C., reacted for 6 hours, and then cooled to room temperature. Here, GPC measurement was performed on a part of the obtained solution by a method described later, and production of a polymer (B) having a weight average molecular weight of 50,000 was confirmed.

3. Preparation of adhesive composition 100 parts by mass (solid content converted value) of the polymer (A) obtained in the step (1) and 20 parts by mass (solid) of the polymer (B) obtained in the step (2) And a tolylene diisocyanate (TDI) adduct of trimethylolpropane in an amount corresponding to 0.8 equivalent of the hydroxyl group of the polymer (B) as a cross-linking agent (C). Product name, “Coronate L”). Finally, as a silane coupling agent (D), 0.2 part by mass of 3-glycidoxypropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name “KBM403”) is added, and the mixture is sufficiently stirred, thereby allowing adhesion. A diluted solution of the sex composition was obtained.

Here, Table 1 shows the composition of the adhesive composition. Details of the abbreviations and the like described in Table 1 are as follows.
[Polymers (A) and (B)]
BA: n-butyl acrylate AA: acrylic acid HEA: 2-hydroxyethyl acrylate HBA: 4-hydroxybutyl acrylate HEMA: 2-hydroxyethyl methacrylate
[Crosslinking agent (C)]
・ Isocyanate-based cross-linking agent TDI system: Tolylene diisocyanate adduct of trimethylolpropane (trade name “Coronate L”, manufactured by Nippon Polyurethane Co., Ltd.)
Isocyanurate type: Isocyanurate of hexamethylene diisocyanate (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name “Coronate HXR”)
・ Other crosslinking agents (epoxy crosslinking agents)
N, N, N ′, N′-tetraglycidyl-m-xylylenediamine (manufactured by Mitsubishi Gas Chemical Company, trade name “TETRAD-X”)
[Silane coupling agent (D)]
KBM403: 3-glycidoxypropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name “KBM403”)
KBE9007: 3-isocyanatopropyltriethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name “KBE9007”)
KBE403: 3-glycidoxypropyltriethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name “KBE403”)

  After drying the diluted solution of the obtained adhesive composition on the release-treated surface of a release sheet (SP-PET3811, thickness: 38 μm, manufactured by Lintec Co., Ltd.) obtained by releasing one side of a polyethylene terephthalate film with a silicone-based release agent After coating with a knife coater so that the thickness of the adhesive layer became 25 μm, a pressure-sensitive adhesive layer was formed by heat treatment at 90 ° C. for 1 minute.

  Next, a polarizing plate composed of a polarizing film with a discotic liquid crystal layer, in which the polarizing film and the viewing angle widening film are integrated, is bonded so that the pressure-sensitive adhesive layer and the discotic liquid crystal layer are in contact with each other. A polarizing plate with an adhesive layer was obtained by curing with RH for 7 days.

[Examples 2-32 and Comparative Examples 1-7]
As shown in Table 1, the types and ratios of the respective monomers constituting the adhesive composition, the types and addition amounts of the crosslinking agent and the silane coupling agent, and the blending ratio of the polymer (A) and the polymer (B) are changed. A polarizing plate with an adhesive layer was produced in the same manner as in Example 1 except that.

[Test Example 1] (Adhesive strength measurement-Reworkability evaluation)
A 25 mm wide, 100 mm long sample was cut out from the polarizing plate with the pressure-sensitive adhesive layer obtained in Examples or Comparative Examples, the release sheet was peeled off, and the alkali-free glass (Corning Corp., Eagle) was exposed through the exposed pressure-sensitive adhesive layer. After being attached to XG), it was pressurized with an autoclave manufactured by Kurihara Seisakusho at 0.5 MPa and 50 ° C. for 20 minutes. Then, after being allowed to stand for 24 hours under the conditions of 23 ° C. and 50% RH, using a tensile tester (Orientec, Tensilon), the adhesive strength (N / 25 mm). Conditions other than those described here were measured according to JIS Z 0237: 2009.

  Further, after being left for 14 days under conditions of 23 ° C. and 50% RH, the adhesive strength (adhesive strength after 14 days of application; N / 25 mm) was measured in the same manner as described above. In addition, the range of preferable adhesive force is 0.1 N / 25mm or more and less than 25 N / 25mm.

Based on the adhesive strength after 14 days from the pasting, reworkability was evaluated according to the following criteria. The results are shown in Table 2.
Adhesive strength 14 days after application is 20 N / 25 mm or less: ◎
Adhesive strength after 14 days from pasting is over 20 N / 25 mm, less than 25 N / 25 mm: ○
Adhesive strength 14 days after application is 25 N / 25 mm or more: ×

[Test Example 2] (Measurement of gel fraction)
Instead of the polarizing plate used for the production of the polarizing plate with the pressure-sensitive adhesive layer in the examples or comparative examples, a release sheet obtained by peeling one side of the polyethylene terephthalate film with a silicone release agent (manufactured by Lintec Corporation, SP-PET 3801, thickness) S: 38 μm) was used to prepare an adhesive sheet. Specifically, the release sheet is subjected to a release treatment on the exposed adhesive layer of the release sheet / adhesive layer (thickness: 25 μm) obtained in the production process of the example or the comparative example. The layers were laminated so that the surface side was in contact. Thereby, the adhesive sheet which consists of a structure of a peeling sheet / adhesive layer / release sheet was produced.

  The obtained pressure-sensitive adhesive sheet was cured for 7 days under the conditions of 23 ° C. and 50% RH. Thereafter, the pressure-sensitive adhesive sheet was sampled to a size of 80 mm × 80 mm, the pressure-sensitive adhesive layer was wrapped in a polyester mesh (mesh size 200), and the mass of the pressure-sensitive adhesive alone was weighed with a precision balance. The mass at this time is M1.

  Using a soxhlet, a sample of the pressure-sensitive adhesive was immersed in an ethyl acetate solvent and refluxed for 16 hours. Thereafter, the pressure-sensitive adhesive was taken out, air-dried for 24 hours in an environment of a temperature of 23 ° C. and a relative humidity of 50%, and further dried in an oven at 80 ° C. for 12 hours. The mass of only the pressure-sensitive adhesive after drying was weighed with a precision balance. The mass at this time is M2. The gel fraction (%) is represented by (M2 / M1) × 100. The results are shown in Table 2.

[Test Example 3] (Measurement of optical performance)
As a measurement sample, an adhesive sheet (cured for 7 days) similar to the adhesive sheet used for measuring the gel fraction was prepared. About the adhesive layer of the said adhesive sheet, haze value (%) was measured according to JISK7105 using the haze meter (the Nippon Denshoku Industries Co., Ltd. make, NDH2000). The results are shown in Table 2. In addition, the range of a preferable haze value is 0 to 5%.

[Test Example 4] (Durability evaluation)
The pressure-sensitive adhesive layer-attached polarizing plate obtained in Examples or Comparative Examples was adjusted to a size of 233 mm × 309 mm using a cutting device (Super cutter manufactured by Hadano Seisakusho, PN1-600). The release sheet was peeled off and attached to an alkali-free glass (Corning Corp., Eagle XG) through the exposed adhesive layer, and then pressurized at 0.5 MPa and 50 ° C. for 20 minutes in an autoclave manufactured by Kurihara Seisakusho. .

Then, it put into the environment of each following durable conditions, and observed using the 10 time loupe after 500 hours. Appearance change was based on the following. The results are shown in Table 2.
A: No defects on 4 sides. O: No defects on the sides of 0.6 mm or more from the outer peripheral edge on 4 sides. X: 0.6 mm or more from the outer edge on at least one side of the four sides. There are abnormal appearance defects of adhesives of 0.1 mm or more such as floating, peeling, foaming, streaks, etc. <durability conditions>
・ 60 ℃, relative humidity 90%
・ 80 ℃ dry

[Test Example 5] (Light leakage test)
The pressure-sensitive adhesive layer-attached polarizing plate obtained in Examples or Comparative Examples was adjusted to a size of 233 mm × 309 mm using a cutting device (Super cutter manufactured by Hadano Seisakusho, PN1-600). The release sheet was peeled off and attached to an alkali-free glass (Corning Corp., Eagle XG) through the exposed adhesive layer, and then pressurized at 0.5 MPa and 50 ° C. for 20 minutes in an autoclave manufactured by Kurihara Seisakusho. . In addition, the said bonding was performed on the front and back of non-alkali glass so that the polarizing axis may be in a crossed nicols state (polarizing axis: ∠45 °, ∠135 °). In this state, after leaving for 500 hours in an 80 ° C. dry environment, light leakage was evaluated by the following method. The results are shown in Table 2.

<Evaluation of light leakage>
Using the MCPD-2000 manufactured by Otsuka Electronics Co., Ltd., the brightness of each region shown in FIG. 3 is measured, and the brightness difference ΔL ^* is expressed by the formula ΔL ^* = [(b + c + d + e) / 4] −a
(Where a, b, c, d, and e are the lightness values at predetermined measurement points (one central portion of each region) in the A region, B region, C region, D region, and E region, respectively. ) To obtain light leakage. A smaller value of ΔL ^* indicates less light leakage.

Here, the above-mentioned weight average molecular weight is a polystyrene-reduced weight average molecular weight measured under the following conditions (GPC measurement) using gel permeation chromatography (GPC).
<Measurement conditions>
GPC measurement device: manufactured by Tosoh Corporation, HLC-8020
GPC column (passed in the following order): TSK guard column HXL-H manufactured by Tosoh Corporation
TSK gel GMHXL (× 2)
TSK gel G2000HXL
・ Measurement solvent: Tetrahydrofuran ・ Measurement temperature: 40 ° C.

  As is apparent from Table 2, the polarizing plate with the pressure-sensitive adhesive layer obtained in the examples has no problem in durability and is excellent in light leakage resistance. In addition, about Example 30, since the content of the carboxyl group in the first (meth) acrylic acid ester polymer (A) is slightly larger than the preferred amount, the reworkability is inferior. Moreover, about Example 31 and Example 32, since content of an isocyanate type crosslinking agent is a little more than a preferable quantity, it is inferior to rework property.

  About the comparative example 1, since there is too much content of the hydroxyl group in a 2nd (meth) acrylic acid ester polymer (B), it is inferior to durability. About the comparative example 2, since the weight average molecular weight of a 1st (meth) acrylic acid ester polymer (A) is too small, it is inferior to durability and rework property. About the comparative example 3, since there is too little content of the hydroxyl group in a 2nd (meth) acrylic acid ester polymer (B), a gel fraction (degree of bridge | crosslinking) is low, and it is inferior to durability. About the comparative example 4, since the weight average molecular weight of the 2nd (meth) acrylic acid ester polymer (B) is too small, it is inferior to durability. About the comparative example 5, since the weight average molecular weight of the 2nd (meth) acrylic acid ester polymer (B) is too large, it is inferior to durability and rework property. About comparative example 6, since there is too much content of the 2nd (meth) acrylic acid ester polymer (B), it is inferior to durability. About comparative example 7, since there is too little content of the 2nd (meth) acrylic acid ester polymer (B), a gel fraction (degree of bridge | crosslinking) is low, and it is inferior to durability.

  The pressure-sensitive adhesive composition and pressure-sensitive adhesive of the present invention are suitable for adhesion of optical members such as polarizing plates and retardation plates, and the pressure-sensitive adhesive sheet of the present invention is for optical members such as polarizing plates and phase difference plates. Suitable as an adhesive sheet.

1A, 1B ... Adhesive sheet 11 ... Adhesive layer 12, 12a, 12b ... Release sheet 13 ... Base material

Claims (13)

A first (meth) acrylic acid ester polymer (A) having a weight average molecular weight of 700,000 to 2.5 million;
A second (meth) acrylic acid ester polymer (B) having a weight average molecular weight of 8000 to 250,000,
A crosslinking agent (C),
The ratio of the second (meth) acrylic acid ester polymer (B) to 100 parts by mass of the first (meth) acrylic acid ester polymer (A) is 5 to 40 parts by mass,
The second (meth) acrylic acid ester polymer (B) contains a monomer having a functional group (b1) that reacts with the crosslinking agent (C) as a constituent component, and further, the functional group (b1 ) In the second (meth) acrylic acid ester polymer (B) is more than 1% by mass and less than 50% by mass,
The functional group that reacts with the crosslinking agent (C) contained in the second (meth) acrylic acid ester polymer (B) is substantially only the functional group (b1),
The first (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the crosslinking agent (C) as a constituent component or the second (meth) acrylic acid ester polymer. A pressure-sensitive adhesive composition comprising a monomer having a functional group (a1) that is less reactive with the cross-linking agent (C) than the functional group (b1) of the union (B). A first (meth) acrylic acid ester polymer (A) having a weight average molecular weight of 700,000 to 2.5 million;
A second (meth) acrylic acid ester polymer (B) having a weight average molecular weight of 8000 to 250,000,
A crosslinking agent (C),
The ratio of the second (meth) acrylic acid ester polymer (B) to 100 parts by mass of the first (meth) acrylic acid ester polymer (A) is 5 to 40 parts by mass,
The second (meth) acrylic acid ester polymer (B) contains a monomer having a functional group (b1) whose reactivity with the crosslinking agent (C) satisfies the following formula (I) as a constituent component. Furthermore, the proportion of the monomer having the functional group (b1) is more than 1% by mass and less than 50% by mass in the second (meth) acrylic acid ester polymer (B),
The second (meth) acrylic acid ester polymer (B) is a monomer having a functional group (b2) whose reactivity with the crosslinking agent (C) satisfies the following formula (I). (B1) containing as a constituent component in an amount (mass ratio) of 1/5 or less of the content of the monomer having
The first (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the crosslinking agent (C) as a constituent component or the second (meth) acrylic acid ester polymer. A pressure-sensitive adhesive composition comprising a monomer having a functional group (a1) that is less reactive with the cross-linking agent (C) than the functional group (b1) of the union (B).
Reactivity with crosslinking agent (C): functional group (b2) <functional group (b1) (I)   The first (meth) acrylic acid ester polymer (A) does not contain a monomer having a functional group that reacts with the cross-linking agent (C) as a constituent component. An adhesive composition. The functional group (a1) in the first (meth) acrylic acid ester polymer (A) is a hydroxyl group ,
The functional group (b1) in the second (meth) acrylic acid ester polymer (B) is a carboxyl group ,
The pressure-sensitive adhesive composition according to claim 1 or 3, wherein the crosslinking agent (C) is at least one selected from an epoxy crosslinking agent, an aziridine crosslinking agent, and a metal chelate crosslinking agent . The functional group (a1) in the first (meth) acrylic acid ester polymer (A) is a hydroxyl group ,
The functional group (b1) in the second (meth) acrylic acid ester polymer (B) is a carboxyl group , and the functional group (b2) is a hydroxyl group ,
The pressure-sensitive adhesive composition according to claim 2 or 3, wherein the crosslinking agent (C) is at least one selected from an epoxy-based crosslinking agent, an aziridine-based crosslinking agent, and a metal chelate-based crosslinking agent . The said 1st (meth) acrylic acid ester polymer (A) contains 0-15 mass% of hydroxyl-containing monomers as a monomer unit which comprises the said polymer, It is characterized by the above-mentioned. An adhesive composition. The second (meth) acrylic acid ester polymer (B) contains 3 to 40% by mass of a carboxy group-containing monomer as a monomer unit constituting the polymer. The adhesive composition as described in any one of Claims. The content of the crosslinking agent (C), 0 relative to the amount of the crosslinking agent (C) of the crosslinkable group is the second (meth) acrylic acid ester polymer wherein the (B) the functional group (b1) The pressure-sensitive adhesive composition according to any one of claims 4 to 7, wherein the pressure-sensitive adhesive composition is in an amount of 1 to 3.5 equivalents. A method for producing the adhesive composition according to any one of claims 1 to 8,
The first (meth) acrylic acid ester polymer (A) and the second (meth) acrylic acid ester polymer (B) are mixed, and the crosslinking agent (C) is added at an arbitrary stage. The manufacturing method of the adhesive composition characterized by doing.   The adhesive which bridge | crosslinks the adhesive composition as described in any one of Claims 1-8. A pressure-sensitive adhesive sheet comprising a base material and a pressure-sensitive adhesive layer,
The said adhesive layer consists of an adhesive of Claim 10, The adhesive sheet characterized by the above-mentioned.   The pressure-sensitive adhesive sheet according to claim 11, wherein the base material is an optical member. Two release sheets,
An adhesive sheet comprising an adhesive layer sandwiched between the release sheets so as to be in contact with the release surfaces of the two release sheets,
The said adhesive layer consists of an adhesive of Claim 10, The adhesive sheet characterized by the above-mentioned.

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