JP2014219640A - Edge material for image display device, manufacturing method of image display device, and image display device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an edge material for an image display device that prevents, when a frame is used in a formation process of a transparent resin layer of the image display device, the occurrence of streaks and enables the application of a photocurable resin composition while preventing the leakage thereof without the need of photo-curing of the frame; and an image display device using the same and a manufacturing method of the same.SOLUTION: An edge material for an image display device is used to form an edge material on a transparent protective substrate, touch panel, or image display unit and apply a transparent material on the inside of the edge material to form a transparent adhesive layer, where the edge material is an edge material for an image display device constituted of a gel-like curable resin composition, and the gel-like curable resin composition includes (A) a component having a (meth)acryloyl group, (B) an oil gelatinizer, and (C) a polymerization initiator.

Description

  The present invention relates to an edge member for an image display device, a method for manufacturing the image display device, and an image display device.

  A liquid crystal display device is illustrated as a typical image display device. A liquid crystal display device includes a liquid crystal cell in which liquid crystal is filled and sealed through a gap of about several microns between a glass substrate having a thickness of about 1 mm on which transparent electrodes, pixel patterns and the like are formed, and the liquid crystal cell The liquid crystal panel which consists of a polarizing plate affixed on both outer sides of this and light sources, such as a backlight system, is included.

  The polarizing plate that makes up this liquid crystal panel is thin and easily scratched. In particular, in mobile phones, game consoles, digital cameras, and in-vehicle applications, a transparent front plate (transparent protective film) is placed with a certain space in front of the liquid crystal panel. A liquid crystal display device having a structure provided with a substrate is generally used.

  Furthermore, in recent years, touch panels have been mounted on mobile phones, game machines, digital cameras, in-vehicle parts, notebook computers, desktop computers, personal computer monitors, large liquid crystal monitors, and the like. Such a liquid crystal display device has a laminated structure in which a transparent protective substrate, a touch panel, and a liquid crystal panel are laminated in this order, and is constant between the transparent protective substrate and the touch panel, and between the touch panel and the liquid crystal panel. There exists a space.

When only the air is present in the space in the liquid crystal display device described above, this space causes light scattering, resulting in a decrease in contrast, brightness, and transmittance, and further, the image quality due to double projection. A decline can occur.
As a method for preventing such light scattering, Patent Document 1 discloses a method of filling a liquid material in a space between a transparent protective substrate and a liquid crystal panel, and Patent Document 2 discloses a sheet obtained by copolymerizing an acrylic monomer. A method of interposing the film between the transparent protective substrate and the liquid crystal panel has been proposed.

In addition, a plasma display panel (PDP), which is one of flat panel displays (FPD), is provided with a space of about 1 to 5 mm from the PDP to prevent cracking of the PDP, and transparent protection of glass or the like having a thickness of about 3 mm. The substrate is provided on the front surface (viewing surface side).
As a method for preventing such cracking of the display and light scattering, Patent Documents 3 and 4 disclose a space between a transparent protective substrate and an image display unit such as a plasma display panel or a liquid crystal panel, and transparent protection. The space between the substrate and the touch panel and the space between the touch panel and the image display unit (hereinafter collectively referred to as “space between the transparent protective substrate and the image display unit”) are made of a specific resin. A method of interposing an optical film has been proposed.

JP 2008-281997 A JP 2004-125868 A JP 2004-058376 A JP 2009-024160 A

However, when the photocurable resin composition is polymerized into a sheet (solid) as in Patent Documents 2 to 4, there is no problem of leakage, but it deforms sufficiently according to the shape of a predetermined location. There is a problem that a gap or the like is likely to be generated at the predetermined location without.
On the other hand, when the photocurable resin composition is in a liquid state as in Patent Document 1, there is a problem that it is likely to leak from the predetermined portion when formed at the predetermined portion. In order to solve this problem, when applying a liquid composition, in order to prevent the leakage, a place where a liquid photocurable resin composition (this is referred to as an inner resin material) is to be applied in advance. There is a method in which a photo-curable resin composition (referred to as an edge resin material) is applied so as to surround, and after photo-curing to form a frame, an inner resin material is applied to the inside of the frame. Thereby, leakage of the liquid inner resin material can be prevented. However, since the photocured frame and the liquid inner resin material are not compatible, there is a problem that streaks occur at the interface between the frame and the inner resin material after the inner resin material is photocured. Moreover, since it is necessary to carry out another photocuring only for formation of a frame, there exists a problem that a process becomes long.
The present invention solves the above problems, and when a frame is used in the process of forming a transparent resin layer of an image display device, no streaking occurs, and the photocurable resin composition can be obtained without photocuring the frame. An object of the present invention is to provide an edge member for an image display device that can be applied without omission, an image display device using the same, and a method for manufacturing the image display device.

The present inventors have found that the above-mentioned problems can be solved by using a gel-like curable resin composition as an edge material for an image display device (hereinafter sometimes simply referred to as an edge material), and the present invention has been completed. I let you. Here, the gel-like curable resin composition means that, for example, a compound capable of interacting with a photopolymerizable compound and a photopolymerizable compound such as an oil gelling agent forms a physical gel by intermolecular forces such as hydrogen bonding. The intermolecular force is easily broken by external stimuli such as heating or shearing. As a result, the gel-like curable resin composition can be easily applied at room temperature or in a heated state.
That is, the present invention provides the following [1] to [10].
[1] An edge material for an image display device that is used to form an edge material on a transparent protective substrate, a touch panel, or an image display unit, and apply a transparent material to the inside of the edge material to form a transparent adhesive layer. An edge material for an image display device, wherein the edge material is composed of a gel-like curable resin composition.
[2] A frame formed by using the edge material for an image display device so as to surround an edge of the touch panel or the image display unit.
[3] The image display according to [1], wherein the gel-like curable resin composition includes (A) a compound having a (meth) acryloyl group, (B) an oil gelling agent, and (C) a polymerization initiator. Edge material for equipment.
[4] The edge material for an image display device according to [3], wherein the gel-like curable resin composition further includes (D) a plasticizer.
[5] The edge material for an image display device according to [3] or [4], wherein the content of the component (A) is 1 to 90% by mass with respect to the total amount of the gel-like curable resin composition. .
[6] A step of forming an edge material using a gel-like curable resin composition on a transparent protective substrate, a touch panel or an image display unit, and a liquid transparent material is applied to the inside of the edge material to form a transparent adhesive The manufacturing method of an image display table | surface apparatus including the process of forming a layer, the process of irradiating light to the said transparent adhesion layer and a gel-like curable resin composition, and forming a transparent resin layer.
[7] An image display device having a transparent protective substrate, an image display unit, and a transparent resin layer, wherein the transparent resin layer is formed on the transparent protective substrate or the image display unit. The image display table | surface apparatus comprised from the edge material of the hardened | cured material of a thing, and the hardened | cured material of the liquid transparent material formed inside the said edge material.
[8] An image display device having a transparent protective substrate, a touch panel, an image display unit, and a transparent resin layer, wherein the transparent resin layer is formed on the transparent protective substrate, the touch panel, or the image display unit. The image display table | surface apparatus comprised from the edge material of the hardened | cured material of a curable resin composition, and the hardened | cured material of a liquid transparent material formed inside the said edge material.
[9] A dam material for an image display device used for forming a dam material on a transparent protective substrate, a touch panel or an image display unit, and applying a transparent material to the inside of the dam material to form a transparent adhesive layer. A dam material for an image display device, wherein the dam material comprises a gel-like curable resin composition.
[10] A transparent resin layer used in an image display device, which contains an oil gelling agent within a range of 10 mm from the outer edge of the transparent resin layer, and substantially contains an oil gelling agent in the center of the transparent resin layer Transparent resin layer not included in.

  In the transparent resin layer obtained by curing a liquid transparent material for the transparent adhesive layer, the edge material for an image display device of the present invention has a streak at the interface between the edge material and the transparent adhesive layer. Generation can be suppressed.

It is side surface sectional drawing which shows typically one Embodiment of the liquid crystal display device which is an example of the image display device of this invention. It is side surface sectional drawing which shows typically the liquid crystal display device which mounts the touchscreen which is one Embodiment of the liquid crystal display device which is an example of the image display device of this invention. It is side surface sectional drawing which shows typically one Embodiment of the manufacturing method of the liquid crystal display device which is an example of the manufacturing method of the image display device of this invention. It is side surface sectional drawing which shows typically one Embodiment of the manufacturing method of the liquid crystal display device which is an example of the manufacturing method of the image display device of this invention. It is a top view which shows typically the structure of the structure of the edge material and middle material of this invention. In the figure, (a) shows a case where a frame is formed so as to surround the inside of the outer edge of the four sides of the adherend, (b) shows a case where a frame is formed inside the outer edge of at least two sides of the adherend, (c) The case where a frame is discontinuously formed inside the outer edges of the four sides of the adherend is shown. It is a top view which shows typically the sample preparation method for evaluating the stripe of the Example of this invention. It is a top view which shows typically the sample preparation method for evaluating the stripe of a comparative example. It is a microscope picture (400 times) of the interface of the edge material of Example 1 of this invention, and an intermediate material. It is a microscope picture (400 time) of the interface of the rim material of the comparative example 1, and a middle material.

DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of an edge member for an image display device, a method for manufacturing the image display device, and an image display device according to the present invention will be described in detail below. In addition, this invention is not limited by this embodiment.
In the drawings, the same or corresponding parts are denoted by the same reference numerals, and redundant description is omitted.
Further, “(meth) acrylate” in the present specification means one or both of “acrylate” and “methacrylate” corresponding thereto. Similarly, “(meth) acryl” means one or both of “acryl” and “methacryl” corresponding thereto, and “(meth) acryloyl” means one or both of “acryloyl” and corresponding “methacryloyl” or Mean both.
In the present specification, the molecular weight is a value measured by gel permeation chromatography (GPC) and converted using a standard polystyrene calibration curve, specifically a value measured by the method described in the examples. is there. Further, the number average molecular weight, the weight average molecular weight, and the degree of dispersion are defined as follows. Here, M _i is the molecular weight, and N _i is the number of moles of the molecule having the molecular weight M _i .
(A) Number average molecular weight (Mn)
Mn = Σ (N _i M _i ) / ΣNi = ΣX _i M _i
(X _i = Mole fraction of molecules with molecular weight M _i = N _i / ΣN _i )
(B) Weight average molecular weight (Mw)
Mw = Σ (N _i M _i ² ) / ΣN _i M _i = ΣW _i M _i
(W _i = weight fraction of molecules of molecular weight M _i = N _i M _i / ΣN _i M _i )
(C) Dispersity (molecular weight distribution)
Dispersity = Mw / Mn

[Edge material]
The edge material of the present invention is preferably formed substantially flush with the outer edge of the adherend, but may be formed 0.1 mm to 20 mm inside the outer edge of the adherend depending on the application.
The width of the edge material of the present invention is preferably 0.1 to 50 mm, more preferably 1 to 30 mm, and still more preferably 2 to 20 mm, from the viewpoint of formability of the edge material. .
Moreover, it is preferable that the film thickness of the edge material of this application is 20 micrometers-1 mm, It is more preferable that it is 50 micrometers-500 micrometers, It is still more preferable that they are 80 micrometers-300 micrometers.
The edge material of the present invention only needs to be formed inside the outer edge of the adherend. For example, when the adherend is a substantially square plate, a frame formed so as to surround the inside of the outer edge of the four sides of the adherend (FIG. 5). (See (a) of FIG. 5), the inner side of the outer edge of at least two sides of the adherend (see (b) of FIG. 5), or the frame formed discontinuously on the inner side of the outer edge of the four sides (see (c) of FIG. 5). Etc. In particular, it is preferable to use it as a frame formed so as to surround the inner sides of the four sides.

Moreover, it is preferable that the edge material of this invention has a function as a dam material.
A dam material is a material for forming a portion for damming a low-viscosity fluid.
The rim material or dam material of the present invention uses a gel-like curable resin composition (hereinafter sometimes simply referred to as “resin composition”).

Examples of the gel-like curable resin composition include (A) a compound having a (meth) acryloyl group, (B) an oil gelling agent, and (C) a polymerization initiator. Moreover, it is preferable that a gel-like curable resin composition further contains (D) a plasticizer, and can contain other additives, such as a stabilizer and a thiol compound, as needed.
In addition, the compound which has (A) (meth) acryloyl group is called (A) component, (B) oil gelling agent is called (B) component, (C) polymerization initiator is called (C) component, D) The plasticizer is sometimes referred to as the component (D).
The gel-like curable resin composition according to the present invention is gelled by (B) an oil gelling agent, and the resin composition is not polymerized into a sheet-like cured product. Compared to the case, it can be easily formed into a desired shape. Furthermore, the gel-like curable resin composition according to the present invention is preferably in the form of a physical gel, which makes it difficult to leak and facilitates edge material molding.
In the gel-like curable resin composition according to the present invention, the storage elastic modulus at 25 ° C. is preferably 0.01 to 10 kPa.
Next, each component of the gel-like curable resin composition will be described.

[(A) component: a compound having a (meth) acryloyl group]
The resin composition of the present invention contains a compound having a (meth) acryloyl group as the component (A).
The content of the component (A) is preferably 1 to 90 with respect to the total amount of the resin composition from the viewpoint of improving the curability of the cured product obtained by curing the resin composition and expressing the effects of other components. It is 10 mass%, More preferably, it is 10-90 mass%, More preferably, it is 20-70 mass%, Most preferably, it is 30-60 mass%.

As a compound having a (meth) acryloyl group, a polymer having a (meth) acryloyl group in the molecule (hereinafter also referred to as “component (A1)”) and one or more (meth) acryloyl groups in the molecule. Examples include at least one monomer (hereinafter, also referred to as “component (A2)”). From the viewpoint of curability and adhesiveness, it is preferable to use the component (A1) and the component (A2) in combination.
Hereinafter, the component (A1) and the component (A2) will be described.

<(A1) component: a polymer having a (meth) acryloyl group in the molecule>
Examples of the polymer having a (meth) acryloyl group in the molecule as the component (A1) include a polyester oligomer having a (meth) acryloyl group, a urethane polymer having a (meth) acryloyl group, and a polyethylene glycol mono (meth). At least of acrylate, polyethylene glycol di (meth) acrylate, polypropylene glycol mono (meth) acrylate, polypropylene glycol di (meth) acrylate, butadiene polymer having (meth) acryloyl group, and isoprene polymer having (meth) acryloyl group One type is mentioned.
Among these, a butadiene polymer having a (meth) acryloyl group or an isoprene polymer having a (meth) acryloyl group is preferable from the viewpoint of transparency, yellowing resistance, and balance of various properties.

Examples of the butadiene polymer having a (meth) acryloyl group include compounds obtained by reacting a polybutadienediol and a monoisocyanate compound having a (meth) acryloyl group.
Some of the polybutadiene diols have “1,4-structural units” or “1,2-structural units”. Here, in the polybutadiene, “1,4-structural unit” is a structural unit represented by the following chemical formula (1t) or (1c), and “1,2-structural unit” means the following chemical formula This is a structural unit represented by (1d).
As polybutadiene diol mainly having 1,4-structural units, for example, Poly bd R-45HT, Poly bd R-15HT (content ratio of 1,4-structural units: 80%, manufactured by Idemitsu Kosan Co., Ltd., trade name) Is mentioned.
Examples of the polybutadiene diol mainly having 1,2-structural units include compounds represented by the following general formula (1). Specifically, G-1000 (content ratio of 1,2-structural units: 85 %), G-2000 (content ratio of 1,2-structural units: 85%), G-3000 (content ratio of 1,2-structural units: 90%) (above, trade name, manufactured by Nippon Soda Co., Ltd.) Is mentioned.
(In formula (1), n1 represents an integer of 1 to 60.)

In the polybutadiene polymer having a (meth) acryloyl group, the content ratio of 1,2-structural units and 1,4-structural units [1,2-structural units / 1,4-structural units] is preferably 10 / It is 90-98 / 2, More preferably, it is 60 / 40-98 / 2, More preferably, it is 70 / 30-97 / 3, More preferably, it is 80 / 20-95 / 5.
As a monoisocyanate compound which has the said (meth) acryloyl group, 2-isocyanate ethyl (meth) acrylate, 2-isocyanate propyl (meth) acrylate, 3-isocyanate propyl (meth) acrylate etc. are mentioned, for example.
The reaction between polybutadienediol and a monoisocyanate compound having a (meth) acryloyl group is produced by a conventionally known method in the presence of a polymerization inhibitor such as p-methoxyphenol and a catalyst such as dibutyltin dilaurate. Can do.
The weight average molecular weight (Mw) of the polybutadiene polymer having a (meth) acryloyl group is 1,000 to 30,000, more preferably 2,000 to 2,000, from the viewpoints of curability, flexibility, and workability. 20,000, more preferably 3,000 to 10,000.

As the isoprene polymer having the (meth) acryloyl group, for example, a compound represented by the following general formula (2) is preferable.

In the general formula (2), p represents an integer of 50 to 1000, q is an integer of 1 to 5, R ¹¹ represents a hydrogen atom or a methyl group.
Although p is 50-1000, Preferably it is 100-800, More preferably, it is 150-700, More preferably, it is 200-600.
Although q is 1-5, Preferably it is 1.5-4.0, More preferably, it is 2.0-3.5, More preferably, it is 2.0-3.0.
As a commercial item of the compound represented by the general formula (2), UC-102, UC-203 (both product names, manufactured by Kuraray Co., Ltd.) and the like can be mentioned.

The average number of functional groups in the component (A1) is preferably 0.5 to 5.0, more preferably 1.5 to 4.0, and still more preferably from the viewpoint of further reducing the curing shrinkage rate and elastic modulus of the resin composition. Is 2.0 to 3.5, particularly preferably 2.0 to 3.0.
The “functional group number” indicates the number of functional groups ((meth) acryloyl group) in one molecule of the component (A1), and the “average functional group number” indicates the number of functional groups per molecule in the entire component (A1). The average value is shown. The average functional group number can be calculated from the amount of each material charged when the component (A1) is synthesized, but can also be calculated from the ¹ H-NMR integrated value of the component (A1).

  The number average molecular weight (Mn) of the isoprene polymer having a (meth) acryloyl group is preferably 10,000 to 40,000, more preferably from the viewpoints of viscosity after blending, workability, toughness of the cured product, and elastic modulus. Is 12,500 to 30,000, more preferably 15,000 to 20,000.

The content of the component (A1) in the resin composition is preferably 1 to 55% by mass, more preferably 10 to 55%, based on the total amount of the resin composition, from the viewpoints of curability, curing shrinkage, and elastic modulus. % By mass, more preferably 15-50% by mass, particularly preferably 20-45% by mass.
When the content of the component (A1) is 1% by mass or more, the curability of the resin composition can be improved and the dielectric constant can be reduced. On the other hand, when the content of the component (A1) is 55% by mass or less, the curing shrinkage rate is good and the elastic modulus of the cured product is not excessively increased, which is preferable.

<(A2) component: monomer having one or more (meth) acryloyl groups in the molecule>
As a monomer which has 1 or more (meth) acryloyl groups in the molecule | numerator which is (A2) component, it is preferable that it is liquid at normal temperature (25 degreeC).
As a monomer having one or more (meth) acryloyl groups in the molecule, for example, an alkyl (meth) acrylate represented by the following general formula (3) (hereinafter, also referred to as “component (A2-1)”) ), A monomer having a (meth) acryloyl group in the molecule and having at least one selected from a hydroxyl group, an ether bond, an amide group and an alicyclic hydrocarbon group (hereinafter referred to as “component (A2-2)”) A monomer having one (meth) acryloyl group in the molecule, a monomer having two (meth) acryloyl groups in the molecule (hereinafter referred to as “component (A2-3)”) And a monomer having 3 to 6 (meth) acryloyl groups in the molecule (hereinafter, also referred to as “component (A2-4)”).

In the general formula (3), R ²¹ represents a hydrogen atom or a methyl group, and R ²² represents an alkyl group having 4 to 20 carbon atoms. From the viewpoint of imparting more flexibility, R ²² is preferably an alkyl group having 6 to 18 carbon atoms, and more preferably an alkyl group having 8 to 16 carbon atoms.

<(A2-1) component>
Examples of the alkyl (meth) acrylate represented by the general formula (3) include n-butyl (meth) acrylate, tert-butyl (meth) acrylate, isobutyl (meth) acrylate, n-pentyl (meth) acrylate, n-octyl (meth) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, isodecyl (meth) acrylate, n-hexyl (meth) acrylate, stearyl (meth) acrylate, lauryl (meth) acrylate, tridecyl ( And (meth) acrylate.
These compounds may be used alone or in combination of two or more.

<(A2-2) component>
As a monomer having a (meth) acryloyl group in the molecule and having at least one selected from a hydroxyl group, an ether bond, an amide group and an alicyclic hydrocarbon group, for example, 2-hydroxyethyl (meth) Acrylate, 1-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 1-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 3-hydroxy Hydroxyl group-containing (meth) acrylates such as butyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate and 1-hydroxybutyl (meth) acrylate; hydroxyl group-containing (meth) acrylamides such as hydroxyethyl (meth) acrylamide; diethylene glycol, Polyethylene glycol mono (meth) acrylates such as reethylene glycol; Polypropylene glycol mono (meth) acrylates such as dipropylene glycol and tripropylene glycol; Polybutylene glycol mono (meth) acrylates such as dibutylene glycol and tributylene glycol; Acrylyl morpholine, etc. Morpholine group-containing (meth) acrylates; (meth) acrylamides such as dimethyl (meth) acrylamide, isopropyl (meth) acrylamide, dimethylaminopropyl (meth) acrylamide, hydroxyethyl (meth) acrylamide; dicyclopentenyloxyethyl (meth) Ether bond-containing (meth) acrylate such as acrylate; dicyclopentanyl (meth) acrylate, dicyclopentenyl Meth) acrylate, cyclohexyl (meth) acrylate, dicyclopentenyl oxyethyl (meth) acrylate, (meth) acrylate having an alicyclic hydrocarbon group, such as isobornyl (meth) acrylate.
These compounds may be used alone or in combination of two or more.
Among these, dicyclopentenyloxyethyl acrylate is preferable from the viewpoint of adhesiveness and workability during application.

<(A2-3) component>
Examples of the monomer having two (meth) acryloyl groups in the molecule include alkanediol di having 1 to 18 carbon atoms of alkane such as butanediol di (meth) acrylate and nonanediol di (meth) acrylate. (Meth) acrylate; ethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, polypropylene glycol di (meth) acrylate, ethoxylated bisphenol A di (meth) acrylate, propoxylated bisphenol A di (meth) acrylate, tricyclodecane dimethanol di (meth) acrylate, 9,9-bis [4- (2-acryloyloxyethoxy) phenyl] fluorene, and the like.

<(A2-4) component>
Examples of the monomer having 3 to 6 (meth) acryloyl groups in the molecule include trimethylolpropane tri (meth) acrylate, tetramethylolmethanetri (meth) acrylate, and tetramethylolmethanetetra (meth). Examples include acrylate, dipentaerythritol penta (meth) acrylate, and dipentaerythritol hexa (meth) acrylate.

In the case of using the component (A2) in the resin composition, the content of the resin composition is from the viewpoint of obtaining a resin composition having an appropriate viscosity, and from the viewpoint of adjusting the curing shrinkage rate and the elastic modulus of the cured product. Preferably it is 0.5-30 mass% with respect to the total amount, More preferably, it is 5-30 mass%, More preferably, it is 10-25 mass%, More preferably, it is 15-25 mass%.
If the content of the component (A2) is 0.5% by mass or more, a resin composition having an appropriate viscosity can be obtained, workability at the time of application can be improved, and the curing shrinkage rate can be increased. Can be lowered. Moreover, while being able to make favorable the sclerosis | hardenability in the light-shielding part of the resin composition obtained, transparency of hardened | cured material can be improved.
If content of (A2) component is 30 mass% or less, it can suppress that a cure shrinkage rate becomes high too much, and when it is used for the apparatus for image display, generation | occurrence | production of a display nonuniformity can be suppressed. .

<(B) component: oil gelling agent (B)>
Examples of the oil gelling agent (B) include hydroxystearic acid, particularly hydroxy fatty acids such as 12-hydroxystearic acid, n-lauroyl-L-glutamic acid-α, β-dibutylamide, di-p-methylbenzylidene sorbitol glu Cytol, 1,3: 2,4-bis-O-benzylidene-D-glucitol, 1,3: 2,4-bis-O- (4-methylbenzylidene) -D-sorbitol, bis (2-ethylhexa) Noato) hydroxyaluminum, compounds represented by the following general formulas (4) to (15), and the like. These may be used alone or in combination of two or more. Among these, at least one of 12-hydroxystearic acid and n-lauroyl-L-glutamic acid-α, β-dibutyramide is more preferable.

In general formula (4), m is an integer of 3 to 10, n is an integer of 2 to 6, R ₁ is a saturated hydrocarbon group having 1 to 20 carbon atoms, and X is sulfur or oxygen.
In the general formula (5), R ₂ is a saturated hydrocarbon group having 1 to 20 carbon atoms, Y ₁ is a bond or a benzene ring.
In general formula (6), R ₃ is a saturated hydrocarbon group having 1 to 20 carbon atoms, Y ₂ is a bond or a benzene ring.
In the general formula (7), R ₄ is a saturated hydrocarbon group having 1 to 20 carbon atoms.
In General Formula (9), R ₅ and R ₆ are each independently a saturated hydrocarbon group having 1 to 20 carbon atoms.
In the general formula (10), R ₇ is a saturated hydrocarbon group of 1-20 carbon atoms.
In the general formula (11), R ₈ is a saturated hydrocarbon group having 1 to 20 carbon atoms.
In General Formula (13), R ₉ and R ₁₀ are each independently a saturated hydrocarbon group having 1 to 20 carbon atoms.

  The content of the oil gelling agent (B) is preferably 0.1 to 20% by mass with respect to the total amount of the resin composition. When it is 0.1% by mass or more, it can be sufficiently gelled, and when it is 20% by mass or less, the content of the compound (A) having a photopolymerizable functional group is relatively large, It can be photocured. In this respect, the content is more preferably 0.2 to 10% by mass, still more preferably 0.3 to 5% by mass, and particularly preferably 0.3 to 2% by mass.

<(C) component: polymerization initiator>
The polymerization initiator (C) is a kind of polymerization initiator that generates radicals by irradiation with active energy rays such as ultraviolet rays, electron beams, α rays, β rays, and accelerates the curing reaction of the resin composition. Is preferred.
Examples of the polymerization initiator (C) include 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-propan-1-one, and 1- [4- (2-hydroxyethoxy). Α-hydroxyalkylphenone compounds such as -phenyl] -2-hydroxy-2-methyl-1-propan-1-one; acetophenone compounds such as 2,2-dimethoxy-2-phenylacetophenone; bis (2,4 , 6-trimethylbenzoyl) -phenylphosphine oxide, bis (2,6-dimethoxybenzoyl) -2,4,4-trimethyl-pentylphosphine oxide, 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, etc. And acylphosphine oxide compounds. Among these, 1-hydroxycyclohexyl phenyl ketone or 2,4,6-trimethylbenzoyl-diphenylphosphine oxide is particularly preferable.

In this invention, it is preferable that content of (C) component is 0.1-5 mass% with respect to the total amount of a resin composition. When the content of the component (C) is 0.1% by mass or more, the curing reaction can be sufficiently promoted to obtain a cured product. On the other hand, if the content of the component (C) is 5% by mass or less, the curability is good.
From the above viewpoint, the content of the component (C) is more preferably 0.2 to 3% by mass, and still more preferably 0.3 to 2% by mass with respect to the total amount of the resin composition.

  In the present invention, as the component (C), it is preferable to use a photopolymerization initiator that generates radicals by irradiation with the active energy ray. However, with the photopolymerization initiator or in place of the photopolymerization initiator, A thermal polymerization initiator that generates radicals may be used.

  Examples of the thermal polymerization initiator include benzoyl peroxide, t-butyl perbenzoate, cumene hydroperoxide, diisopropyl peroxydicarbonate, di-n-propyl peroxydicarbonate, and di (2-ethoxyethyl) peroxy. Dicarbonate, t-butyl peroxyneodecanoate, t-butyl peroxypivalate, t-hexyl peroxypivalate, (3,5,5-trimethylhexanoyl) peroxide, dipropionyl peroxide, lauroyl peroxide Organic peroxides such as diacetyl peroxide; 2,2′-azobisisobutyronitrile, 2,2′-azobis (2-methylbutyronitrile), 1,1′-azobis (cyclohexane-1-carbonyl) ), 2,2′-azobis (2,4-dimethylvaleroni Ril), 2,2′-azobis (2,4-dimethyl-4-methoxyvaleronitrile), dimethyl 2,2′-azobis (2-methylpropionate), 4,4′-azobis (4-cyanovale) Rick acid), 2,2′-azobis (2-hydroxymethylpropionitrile), 2,2′-azobis [2- (2-imidazolin-2-yl) propane] and the like.

  When mix | blending a thermal polymerization initiator, Preferably content of the said thermal polymerization initiator is 0.01-1 mass% with respect to the total amount of a resin composition.

<(D) component: Plasticizer>
The resin composition of the present invention may contain a plasticizer as the component (D).
The plasticizer used as the component (D) in the present invention is preferably a component which is substantially liquid at 25 ° C. and has no (meth) acryloyl group.
The number average molecular weight of the component (D) is preferably 350 to 30,000, more preferably 400 to 10,000, from the viewpoint of adjusting the viscosity of the resin composition, and from the viewpoints of volatility and workability.

Examples of the component (D) include butadiene rubber, isoprene rubber, silicon rubber, styrene butadiene rubber, chloroprene rubber, nitrile rubber, butyl rubber, ethylene propylene rubber, urethane rubber, acrylic rubber, chlorosulfonated polyethylene rubber, fluorine rubber, hydrogen. Nitrile rubber, epichlorohydrin rubber liquid;
Poly α-olefins such as polybutene, hydrogenated α-olefin oligomers such as hydrogenated polybutene, polyvinyl oligomers such as atactic polypropylene;
Aromatic oligomers such as biphenyl and triphenyl;
Hydrogenated polyene oligomers such as hydrogenated liquid polybutadiene;
Paraffinic oligomers such as paraffin oil and chlorinated paraffin oil;
Cycloparaffinic oligomers such as naphthenic oil;
Dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di- (2-ethylhexyl) phthalate, di-n-octyl phthalate, diisobutyl phthalate, diheptyl phthalate, diphenyl phthalate, diisodecyl phthalate, ditridecyl phthalate, diundecyl phthalate, di (heptyl, Nonyl, undecyl) phthalate, benzyl phthalate, butyl benzyl phthalate, dinonyl phthalate, dicyclohexyl phthalate, and other phthalic acid derivatives;
Isophthalic acid derivatives such as dimethyl isophthalate, di- (2-ethylhexyl) isophthalate, diisooctyl isophthalate;
Tetrahydrophthalic acid derivatives such as di- (2-ethylhexyl) tetrahydrophthalate, di-n-octyltetrahydrophthalate, diisodecyltetrahydrophthalate;
Adipic acid derivatives such as di-n-butyl adipate, di (2-ethylhexyl) adipate, diisodecyl adipate, diisononyl adipate;
Azelaic acid derivatives such as di- (2-ethylhexyl) azelate, diisooctylazelate, di-n-hexylazelate;
Sebacic acid derivatives such as di-n-butyl sebacate and di- (2-ethylhexyl) sebacate;
Maleic acid derivatives such as di-n-butyl maleate, dimethyl maleate, diethyl maleate, di- (2-ethylhexyl) maleate;
Fumaric acid derivatives such as di-n-butyl fumarate and di- (2-ethylhexyl) fumarate;
Tri- (2-ethylhexyl) trimellitate, tri-n-octyl trimellitate, triisodecyl trimellitate, triisooctyl trimellitate, tri-n-hexyl trimellitate, triisononyl trimellitate, etc. Merit acid derivatives;
Pyromellitic acid derivatives such as tetra- (2-ethylhexyl) pyromellitate and tetra-n-octylpyromellitate;
Citric acid derivatives such as triethyl citrate, tri-n-butyl citrate, acetyl triethyl citrate, acetyl tri- (2-ethylhexyl) citrate;
Itaconic acid derivatives such as monomethyl itaconate, monobutyl itaconate, dimethyl itaconate, diethyl itaconate, dibutyl itaconate, di- (2-ethylhexyl) itaconate;
Oleic acid derivatives such as butyl oleate, glyceryl monooleate, diethylene glycol monooleate;
Ricinoleic acid derivatives such as methylacetylricinoleate, butylacetylricinoleate, glycerylmonoricinoleate, diethylene glycol monoricinoleate;
stearic acid derivatives such as n-butyl stearate, glycerin monostearate, diethylene glycol distearate;
Other fatty acid derivatives such as diethylene glycol monolaurate, diethylene glycol dipelargonate, pentaerythritol fatty acid ester;
Phosphoric acid derivatives such as triethyl phosphate, tributyl phosphate, tri- (2-ethylhexyl) phosphate, tributoxyethyl phosphate, triphenyl phosphate, cresyl diphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tris (chloroethyl) phosphate;
Glycol derivatives such as diethylene glycol dibenzoate, dipropylene glycol dibenzoate, triethylene glycol dibenzoate, triethylene glycol di- (2-ethylbutyrate), triethylene glycol di- (2-ethylhexoate);
Thioglycol derivatives such as dibutylmethylenebisthioglycolate;
Glycerol derivatives such as glycerol monoacetate, glycerol triacetate, glycerol tributyrate;
Examples thereof include epoxy derivatives such as epoxidized soybean oil, epoxyhexahydrophthalate diisodecyl, epoxy triglyceride, epoxidized octyl oleate, and epoxidized decyl oleate.
These compounds can be used alone or in combination of two or more.

Among these, when using a polybutadiene polymer having a (meth) acryloyl group or an isoprene polymer containing a (meth) acryloyl group as the component (A1), volatility, viscosity, workability, yellowing resistance, compatibility, From the viewpoint of heat resistance, butadiene rubber, isoprene rubber, acrylic rubber, poly α-olefin, hydrogenated α-olefin oligomer, and di- (2-ethylhexyl) sebacate are preferable. Butadiene rubber, acrylic rubber, poly α-olefin, di -(2-Ethylhexyl) sebacate is more preferable, and butadiene rubber and acrylic rubber are more preferable.
As said acrylic rubber, the acrylic resin containing the structural unit derived from the alkyl (meth) acrylate whose carbon number of an alkyl group is 4-18 is preferable. An acrylic resin containing a structural unit derived from an alkyl (meth) acrylate having an alkyl group having 4 to 18 carbon atoms and a structural unit derived from styrene or benzyl (meth) acrylate is more preferable.
The butadiene rubber is preferably liquid polybutadiene. Examples of liquid polybutadiene include RICON 130, RICON 131 (all manufactured by CRAY VALLEY), Polybest 110 (all manufactured by Evonik Degussa Japan Co., Ltd.), LBR-307 (manufactured by Kuraray Co., Ltd.), and polyoil (manufactured by Nippon Zeon Co., Ltd.). It is commercially available.
The number average molecular weight (Mn) of the acrylic rubber or butadiene rubber is preferably 500 to 20,000, more preferably 800 to 10,000, and further preferably 1,000 to 8,000. preferable.

  The content when the component (D) is contained is preferably 30 to 98% by mass, more preferably 30%, based on the total amount of the resin composition, from the viewpoint of adjusting the elastic force of the cured product to an appropriate range. It is -85 mass%, More preferably, it is 40-70 mass%, Most preferably, it is 45-65 mass%.

<Other additives>
The resin composition of the present invention can further contain other additives as long as the effects of the present invention are not impaired.
Other additives include stabilizers such as triphenyl phosphite, 1,4-bis (3-mercaptobutyryloxy) butane, 1,3,5-tris (3-mercaptobutyloxyethyl) -1,3 , 5-triazine-2,4,6 (1H, 3H, 5H) -trione, thiol compounds such as pentaerythritol tetrakis (3-mercaptobutyrate), and the like.

It is preferable that the resin composition of the present invention does not substantially contain an organic solvent (solvent) from the viewpoint of resistance to moisture and heat resistance and suppressing the generation of bubbles in the cured product.
Here, “substantially does not contain an organic solvent” means that no organic solvent is intentionally added, and a trace amount of the resin composition of the present invention is not significantly reduced after curing. An organic solvent may be present.
Specifically, the content of the organic solvent in the resin composition may be 1,000 ppm or less with respect to the total amount of the resin composition, preferably 500 ppm or less, more preferably 100 ppm or less, and still more preferably organic. Contains no solvent.
In the present invention, the “organic solvent” means an organic compound that does not have a (meth) acryloyl group, is liquid at 25 ° C., and has a boiling point of 250 ° C. or less at atmospheric pressure.
In the resin composition of the present invention, the total amount of the components (A) to (D) in the resin composition is preferably 80% by mass or more, more preferably 90% by mass or more, and still more preferably. It is 95 mass% or more, Most preferably, it is 99 mass% or more.

[Physical properties of gel-like curable resin composition]
The gel-like curable resin composition according to the present invention preferably has a storage elastic modulus at 25 ° C. of 0.01 to 30 kPa. Thereby, it is difficult to leak and the edge material can be easily formed. From this viewpoint, the storage elastic modulus at 25 ° C. is more preferably 0.05 to 25 kPa, and further preferably 0.1 to 20 kPa. Further, the storage elastic modulus at 25 ° C. of the cured product of the gel-like curable resin composition of the present invention suppresses local stress application to the image display unit or the like when used as a constituent member of the image display device. And from a viewpoint of suppressing generation | occurrence | production of display nonuniformity, Preferably it is 200 kPa or less, More preferably, it is 150 kPa or less, More preferably, it is 100 kPa or less. The lower limit of the storage elastic modulus at 25 ° C. of the cured product of the gel-like curable resin composition is not limited as long as the liquid material is not separated from the cured product or does not sag when heated. Is 1 kPa or more, more preferably 2 kPa or more, still more preferably 5 kPa or more, and particularly preferably 10 kPa or more.
The storage elastic modulus at 25 ° C. can be measured by the method described later.

The viscosity at 25 ° C. of the gel-like curable resin composition of the present invention is preferably 1 to 500 Pa · s, more preferably 10 to 400 Pa · s, and still more preferably 50 to 50 ° C. from the viewpoint of suppression of bleeding out and workability. 400 Pa · s.
In addition, the viscosity at 25 degreeC here is the value measured based on JISZ8803, and can be specifically measured with a B-type viscometer or an E-type viscometer.
The calibration of the viscometer can be performed based on JIS Z 8809-JS14000.

[Inside material]
A transparent material is used as the inner material that is the inner resin material used to fill the inner portion surrounded by the frame formed by the edge material according to the present invention.
Examples of the transparent material include the gel-like curable resin composition and the curable resin composition obtained by removing the component (B) from the gel-like curable resin composition.
The intermediate material of the present invention is preferably liquid from the viewpoint of workability. In the present invention, the liquid state means a state having fluidity at 100 ° C. or lower.
More specifically, when the curable resin composition obtained by removing the component (B) from the gel curable resin composition is used as the intermediate material, the viscosity of the curable resin composition at 25 ° C. From the viewpoint of properties, 500 to 5,000 mPa · s is preferable, 1,000 to 4,000 mPa · s is more preferable, and 2,000 to 3,500 mPa · s is still more preferable. The viscosity at 25 ° C. can be measured using an E-type viscometer according to JIS Z 8803.
Moreover, when using a gel-like curable resin composition as a middle material, since it is a physical gel form at room temperature (25 degreeC), it is preferable to make it liquid by heating to 40-100 degreeC.

[Physical properties after curing of intermediate material]
The curing shrinkage ratio of the intermediate material according to the present invention is preferably 3. from the viewpoint of further suppressing the warpage of the substrate such as the transparent protective substrate and the image display unit when used as a constituent member of the image display device. It is less than 0%, more preferably less than 1.5%. When the curing shrinkage is less than 3.0%, it is possible to sufficiently suppress the warpage of the substrate that may cause display unevenness.

[Transparent resin layer]
The transparent resin layer is obtained by curing a transparent adhesive layer formed by filling an edge material and an intermediate material which is a liquid transparent material inside thereof. Such a transparent resin layer is generally formed on a transparent protective substrate, a touch panel or an image display unit. For example, the transparent resin layer is formed on a support such as a plastic film such as a PET film. The transparent resin layer can be formed on the transparent protective substrate, the touch panel or the image display unit of the image display device to form the transparent resin layer in the image display device.

Therefore, it is preferable that the edged material and the cured material of the intermediate material of the present invention function as a transparent resin layer having excellent adhesion to an adherend such as a glass plate or a plastic plate. Here, transparent means that the light transmittance at a wavelength of 400 nm is 80% or more. The light transmittance can be measured using, for example, a spectrophotometer. The transparent resin layer of the present invention is preferably produced by forming a frame using an edge material and then pouring the intermediate material inside the frame and irradiating it with light. In such a transparent resin layer, the width of the edge material is 0.1 mm or more, and when the gel-like curable resin composition is used for the edge material, the oil gel is within a range of 10 mm from the outer edge of the transparent resin layer. Contains an agent. From the viewpoint of workability, the intermediate material is particularly suitable when a curable resin composition substantially free of an oil gelling agent is used. When the oil gelling agent is not substantially contained, the viscosity can be easily adjusted. When a curable resin composition that substantially does not contain an oil gelling agent is used as the intermediate material, a transparent resin layer that does not substantially contain an oil gelling agent is formed at the center of the transparent resin layer of the present invention. Here, the central portion means, for example, an intersection of diagonal lines when it is substantially square. Further, “substantially free” means that the oil gelling agent may be present in a trace amount (less than 100 ppm in the total amount of the curable resin composition) as long as it does not become a physical gel. However, it is particularly preferably not contained.
The film thickness of the transparent resin layer is preferably 20 μm to 1 mm, more preferably 50 μm to 500 μm, and still more preferably 80 μm to 300 μm.

[Image display device]
Hereinafter, a liquid crystal display device which is an example of an image display device that can be manufactured using the edge material of the present invention will be described.
FIG. 1 is a side sectional view schematically showing an embodiment of a liquid crystal display device which is an example of an image display device of the present invention. The liquid crystal display device shown in FIG. 1 includes an image display unit 1 in which a backlight system 50, a polarizing plate 22, a liquid crystal display cell 10, and a polarizing plate 20 are laminated in this order, and a polarizing plate on the viewing side of the liquid crystal display device. The transparent resin layer 32 provided on the upper surface of 20 and the transparent protective substrate 40 provided on the surface thereof. In addition, the transparent resin layer 32 is comprised from the edge material of this invention, and the hardening body of the middle material.

  FIG. 2 is a side cross-sectional view schematically showing a liquid crystal display device equipped with a touch panel, which is an embodiment of a liquid crystal display device which is an example of the image display device of the present invention. The liquid crystal display device shown in FIG. 2 includes an image display unit 1 in which a backlight system 50, a polarizing plate 22, a liquid crystal display cell 10, and a polarizing plate 20 are laminated in this order, and a polarizing plate on the viewing side of the liquid crystal display device. 20, a transparent resin layer 32 provided on the top surface, a touch panel 30 provided on the top surface of the transparent resin layer 32, a transparent resin layer 31 provided on the top surface of the touch panel 30, and a transparent protective substrate provided on the surface thereof 40.

In the liquid crystal display device of FIG. 2, a transparent resin layer is interposed between the image display unit 1 and the touch panel 30 and between the touch panel 30 and the transparent protective substrate 40. It suffices to intervene in at least one of these. When the touch panel is on-cell, the touch panel and the liquid crystal display cell are integrated. As a specific example, the liquid crystal display cell 10 of the liquid crystal display device of FIG. 1 may be replaced with an on-cell.
In recent years, development of a liquid crystal display cell called an in-cell type touch panel incorporating a touch panel function has been advanced. A liquid crystal display device provided with such a liquid crystal display cell includes, for example, a transparent protective substrate, a polarizing plate, and a liquid crystal display cell (a liquid crystal display cell with a touch panel function). The transparent resin layer can also be used for a liquid crystal display device employing such an in-cell touch panel.

  The liquid crystal display device shown in FIGS. 1 and 2 includes the cured material of the edge material and the middle material of the present invention as the transparent resin layer 31 or 32.

  The liquid crystal display cell 10 can be made of a liquid crystal material well known in the art. Further, depending on the control method of the liquid crystal material, it is classified into a TN (Twisted Nematic) method, a STN (Super-twisted nematic) method, a VA (Virtual Alignment) method, an IPS (In-Place-Switching) method, etc. Then, it may be a liquid crystal display cell using any control method.

As the polarizing plates 20 and 22, a polarizing plate common in this technical field can be used.
The surface of the polarizing plate may be subjected to treatments such as antireflection, antifouling, and hard coat. Such surface treatment may be performed on one side of the polarizing plate or on both sides thereof.
Further, as the touch panel 30, a resistive film method in which an electrode comes in contact with the pressure of a finger or an object touching the surface, a capacitive method for sensing a change in capacitance when a finger or an object touches the surface, electromagnetic induction The transparent resin layer of the present invention is particularly suitable for a liquid crystal display device that employs a capacitive touch panel. As the touch panel 30, a touch panel generally used in this technical field can be used. For example, the capacitive touch panel has a structure in which a transparent electrode is formed on a substrate. Can be mentioned. Examples of the substrate include a glass substrate, a PET film, and a cycloolefin polymer film. Moreover, as a transparent electrode, metal oxides, such as ITO (Indium Tin Oxide), are mentioned, for example. The thickness of the substrate is 20 to 1,000 μm. The transparent electrode has a thickness of 10 to 500 nm.
In addition, when using a transparent resin layer for a capacitive touch panel, it is preferable that the dielectric constant of a transparent resin layer is an appropriate range.

  The transparent resin layer 31 or 32 can be formed with a thickness of 20 μm to 1 mm, for example. In particular, the resin composition of the present invention is easy to form a thick film, and is suitable for forming the transparent resin layer 31 or 32 having a thickness of 50 μm to 500 μm.

As the transparent protective substrate 40, a general optical transparent substrate can be used. Specific examples thereof include inorganic plates such as glass substrates and quartz plates; plastic substrates such as acrylic resin substrates, polycarbonate plates and cycloolefin polymer plates; resin sheets such as thick polyester sheets. Among these, when high surface hardness is required, a glass plate and an acrylic plate are preferable, and a glass plate is more preferable.
The surface of the transparent protective substrate 40 may be subjected to treatments such as antireflection, antifouling, and hard coat. Such surface treatment may be performed on one side of the transparent protective substrate or on both sides. Further, the transparent protective substrate can be used in combination of a plurality of substrates.

  Although there is no restriction | limiting in particular in the structure as the backlight system 50, Generally, it is comprised from illumination means, such as reflection means, such as a reflecting plate, and a lamp. As these reflecting means and illuminating means, a known means or configuration applied in a normal image display device can be applied.

[Method for Manufacturing Image Display Device]
The image display apparatus as shown in FIGS. 1 and 2 using the resin composition of the present invention can be manufactured by the following method.
First, as shown in FIG. 3, a step of forming a frame using the edge material of the present invention on either the image display unit or the transparent protective substrate, and a liquid transparent material ( Pouring the intermediate material), forming the transparent adhesive layer, attaching the image display unit or the transparent protective substrate not formed with the frame to the formed transparent adhesive layer, the image display unit surface side or It can be manufactured through a step of performing light irradiation from at least one side of the transparent protective substrate surface side to form a transparent resin layer.
Further, as shown in FIG. 4, an image display unit or a transparent protective substrate in which a frame is formed on one of the image display unit and the transparent protective substrate using the edge material of the present invention and the frame is not formed. Alternatively, an intermediate material may be applied to the image display unit and the transparent protective substrate.

In addition, an image display device including an image display unit, a touch panel, and a transparent protective substrate as shown in FIG. 2, for example, when a transparent resin layer is formed between the touch panel and the transparent protective substrate, A step of forming a frame using the edge material of the present invention on either the touch panel or the transparent protective substrate, a step of forming a transparent adhesive layer by pouring a liquid transparent material (inner material) inside the frame, The step of bonding the member (touch panel or transparent protective substrate) that did not form the frame to the formed transparent adhesive layer and light irradiation from at least one side of the touch panel surface side or the transparent protective substrate surface side are performed. It can be manufactured through a step of forming a transparent resin layer. Further, in FIG. 2, when a transparent resin layer is formed between the touch panel and the image display unit, a step of forming a frame using the edge material of the present invention on either the touch panel or the image display unit, A step of forming a transparent adhesive layer by pouring a liquid transparent material (inner material) inside the frame, and a step of bonding a member (touch panel or image display unit) not formed with the frame to the formed transparent adhesive layer And it can manufacture through the process of implementing light irradiation from the said touch-panel surface side or the image display unit surface side at least one surface side, and forming a transparent resin layer.
In addition, the transparent resin layer formed on the transparent protective substrate, the touch panel, or the image display unit obtained in this way is a frame formed of an edge material as shown in FIGS. It is preferable that the inside material exists in the inside. Moreover, it is preferable that the edge material of this invention has a function as a dam material which dams up a liquid material, when the said intermediate material is a liquid material.

As a method of forming the rim material and the intermediate material on the image display unit, the touch panel, and the transparent protective substrate, for example, after applying the resin composition using a dispenser, bonding is performed at a vacuum (reduced pressure) or atmospheric pressure. Methods and the like.
In addition, when an edge material is a state of a physical gel at room temperature, it is preferable to heat at 40-100 degreeC at the time of coating, and to make it liquid state. It is more preferable to heat to 60-100 degreeC from a viewpoint which can improve coatability more. In the step of forming the intermediate material inside the edge material, it is preferable to reduce the fluidity of the edge material to less than 40 ° C.
Moreover, also when using a gel-like curable resin composition for an inside material, it is preferable to heat at 40-100 degreeC at the time of coating, and to make it liquid state.

Moreover, the said light irradiation is performed by irradiating active energy rays, such as an ultraviolet-ray, an electron beam, an alpha ray, a beta ray, and can be performed using an ultraviolet irradiation device, for example. In addition, the gel-like curable resin composition (edge material) and the transparent material (medium material) according to the present invention have a sufficient exposure amount of, for example, 50 mJ / cm ^{2 to} 5,000 mJ / cm ² or less. The curing reaction can proceed.
The exposure amount is a value obtained by multiplying the illuminance measured by an ultraviolet irradiation device (manufactured by Oak Co., Ltd., product name “UV-M02 (receiver: UV-36)”) by irradiation time (seconds). Say.
Examples of the light source for ultraviolet irradiation include a low pressure mercury lamp, a medium pressure mercury lamp, a high pressure mercury lamp, a metal halide lamp, and an LED lamp. Among these, a high pressure mercury lamp and a metal halide lamp are preferable.
In the case of light irradiation, irradiation from the transparent protective substrate surface side and irradiation from the side surface may be used in combination. Moreover, hardening can also be accelerated | stimulated by heating the laminated body containing a resin composition simultaneously with light irradiation.

As described above, the liquid crystal display device which is one of the image display devices that can be manufactured by using the resin composition of the present invention has been described. However, the liquid crystal display device is manufactured by using the resin composition of the present invention. However, the image display device that can do this is not limited to this.
For example, the present invention can be applied to a plasma display (PDP), a cathode ray tube (CRT), a field emission display (FED), an organic EL display, a 3D display, electronic paper, and the like.
In particular, when the image display device is 4 inches or more in size, it is more preferable to form a rim material using the resin composition of the present invention to produce a transparent resin layer.

EXAMPLES Hereinafter, although an Example demonstrates this invention further more concretely, this invention is not limited to a following example.
Moreover, the weight average molecular weight (Mw) and the number average molecular weight (Mn) of the compounds used in the following examples are values measured based on the following methods.
[Method of measuring weight average molecular weight (Mw) and number average molecular weight (Mn)]
The determination was carried out using gel permeation chromatography (GPC) using tetrahydrofuran (THF) as a solvent, and a calibration curve was prepared using polystyrene as a standard substance. In preparing the calibration curve, 5 sample sets (PStQuickMP-H, PStQuickB [trade name, manufactured by Tosoh Corporation]) were used as standard polystyrene.
Apparatus: High-speed GPC apparatus HCL-8320GPC (detector: differential refractometer or UV)
(Product name, manufactured by Tosoh Corporation)
Solvent: Tetrahydrofuran (THF)
Column: Column TSKGEL SuperMultipore HZ-H
(Product name, manufactured by Tosoh Corporation)
Column size: Column length is 15 cm, column inner diameter is 4.6 mm
Measurement temperature: 40 ° C
Flow rate: 0.35 ml / min Sample concentration: 10 mg / THF 5 ml
Injection volume: 20 μl

(Preparation of edge material)
In the blending ratios shown in Table 1, the components (A) to (D) are blended, and mixed with heating and stirring at 90 ° C. for 30 minutes. A resin composition was prepared. In Table 1, the units of numerical values for the components (A) to (D) are parts by mass.
In addition, the detail of (A)-(D) component among each component shown in Table 1 is as follows.

Component (A) “Polybutadiene methacrylate”
(Synthesis of polybutadiene methacrylate)
In a reaction vessel equipped with a cooling pipe, a thermometer, a stirrer, a dropping funnel and an air injection pipe, α, ω-polybutadiene glycol (trade name “polybutadiene glycol G-3000” manufactured by Nippon Soda Co., Ltd., [1,2-structure (Unit / 1,4-structural unit) content ratio = 90/10, hydroxyl value = 27 mgKOH / g) as 978.2 parts by mass, a polymerization inhibitor, p-methoxyphenol as 0.5 parts by mass, and a catalyst Dibutyltin dilaurate (trade name “L101” manufactured by Tokyo Fine Chemical Co., Ltd.) was added in an amount of 0.05 part by mass. Then, after raising the temperature to 70 ° C. while flowing air into the reaction vessel, 20.3 parts by mass of 2-isocyanatoethyl methacrylate (trade name “Karenz MOI” manufactured by Showa Denko KK) was stirred at 70 to 75 ° C. The reaction was performed dropwise over 1 hour.
When the reaction was completed for 5 hours after completion of the dropwise addition, the reaction was terminated after confirming that the isocyanate had disappeared as a result of IR (infrared absorption analysis), and polybutadiene methacrylate having a methacryloyl group at the terminal (weight average molecular weight 7, 700). The average value (average number of functional groups) of methacryloyl groups per molecule of this polybutadiene methacrylate was 0.5 (calculated value from the charged amount).
・ "Polyisoprene methacrylate": manufactured by Kuraray Co., Ltd., product name "UC-102"
It has a structure represented by the above general formula (2), R ¹¹ is a methyl group, q = 2 (the number of methacryloyl groups = 2), and Mn = 17000.
・ "Cycloaliphatic acrylate": dicyclopentenyloxyethyl acrylate, manufactured by Hitachi Chemical Co., Ltd., product name "FA-512AS"
FA-129AS: Nonanediol diacrylate, manufactured by Hitachi Chemical Co., Ltd., trade name LA: Lauryl acrylate (manufactured by Hitachi Chemical Co., Ltd., “FA-112A”)
ACMO: acryloylmorpholine (B) component HSA: 12-hydroxystearic acid, manufactured by Wako Pure Chemical Industries, Ltd. GBR: n-lauroyl-L-glutamic acid-α, β-dibutylamide, manufactured by Wako Pure Chemical Industries, Ltd. (C ) Component i-184: 1-hydroxycyclohexyl phenyl ketone, manufactured by BASF Japan KK TPO: 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, manufactured by Ciba Japan KK (D) component LBR-307 : Butadiene rubber, manufactured by Kuraray Co., Ltd., number average molecular weight (Mn) = 8,000
Polyvest 110: butadiene rubber, manufactured by Evonik Degussa Japan, number average molecular weight (Mn) = 2900
RICON-130: butadiene rubber, manufactured by CRAY VALLEY, number average molecular weight (Mn) = 2500
・ "Acrylic rubber 1"
(Synthesis of acrylic rubber 1)
4 g of styrene (manufactured by Wako Pure Chemical Industries, Ltd.), 6 g of lauryl acrylate (manufactured by Hitachi Chemical Co., Ltd., “FA-112A”), 0.15 g of n-octyl mercaptan (manufactured by Wako Pure Chemical Industries, Ltd.) and perbutyl 0.05 g of O (Nippon Oil Co., Ltd.) was added, and after stirring, placed in a water bath at 80 ° C. and heated for 4 hours. Subsequently, it heated in 100 degreeC oven for 1 hour, and obtained the liquid compound (D) (number average molecular weight 2000) at 25 degreeC.
・ "Acrylic rubber 2"
(Synthesis of acrylic rubber 1)
Benzyl acrylate (Hitachi Chemical Co., Ltd., “FA-BZA”) 4 g, lauryl acrylate (Hitachi Chemical Co., Ltd., “FA-112A”) 6 g, n-octyl mercaptan (Wako Pure Chemical Industries, Ltd.) 0.15 g and perbutyl O (NOF Corporation) 0.05 g were added, and after stirring, placed in an 80 ° C. water bath and heated for 4 hours. Subsequently, it heated in 100 degreeC oven for 1 hour, and obtained the liquid compound (D) (number average molecular weight 2000) at 25 degreeC.

Table 1 shows the composition and physical properties of the rim material.
[Light transmittance of edge material]
Preparation examples (1) to (6) and a 175 μm frame-shaped spacer are provided on a glass substrate having a length of 85 mm × width of 55 mm × thickness of 0.7 mm so that the film thickness after photocuring is 175 μm. The curable resin composition of Comparative Preparation Example (7) was applied to the inside of the frame-shaped spacer to form a coating film, and the same glass substrate as above was bonded onto the formed coating film. Then, an ultraviolet ray irradiation device (product name: ELM-3000B-6N, manufactured by Oak Co., Ltd.) is used to irradiate ultraviolet rays at 1,000 mJ / cm ² to cure the coating film of the curable resin composition. A cured product having a film thickness of 175 μm sandwiched between glass substrates was produced.
In the same manner as described above, each of the curable resin compositions of Preparation Examples (1) to (6) and Comparative Preparation Example (7) was used so that the film thickness after curing was 20 μm, and two glass substrates A reference sample sandwiched between two samples was prepared. Using a sample in which a cured product having a thickness of 20 μm is sandwiched between two glass substrates as a reference, light at a wavelength of 400 nm of a cured product having a thickness of 175 μm sandwiched between the two glass substrates corresponding to the reference. The transmittance was measured using a spectrophotometer (manufactured by Shimadzu Corporation, product name “UV-2400PC”).

[Viscosity of gel-like curable resin composition]
Using an E-type viscometer (TV-22 manufactured by Toki Sangyo Co., Ltd.), the viscosity (unit: Pa · s) at 25 ° C. of the resin compositions obtained in each Example and each Comparative Example was measured. Measurement conditions and methods are as shown below.
(Measurement condition)
・ Rotor name: 3 ° × R9.7, Rotor code 06
・ Measurement range: 5M
・ Rotation speed: 0.5rpm
(Measuring method)
The sample heated to 80 ° C. was placed in a measurement container and left at 25 ° C. for 10 minutes. Thereafter, rotation was started, and the value after 3 minutes was taken as the viscosity.

[Storage elastic modulus of gel-like curable resin composition and cured product thereof]
Using a rheometer (manufactured by Anton Paar Co., Ltd., MCR301), irradiating the gel-like curable resin composition obtained in Preparation Examples (1) to (6) and ultraviolet rays having an exposure amount of 2000 mJ / cm ² , The storage elastic modulus (unit: kPa) at 25 ° C. of a cured product obtained by curing the gel-like curable resin composition was measured. Measurement conditions and measurement methods are shown below.
(Sample adjustment conditions)
The gel-like curable resin composition was heated to 80 ° C. to obtain a fluid state, and about 0.5 ml of this was collected with a dropper and applied onto a glass plate (diameter 50 mm, thickness 5 mm). Next, jig PP-12 (parallel plate, diameter 12 mm) was set on the applied gel-like curable resin composition so that the thickness of the gel-like curable resin composition was 150 μm. After wiping off the protruding gel-like curable resin composition, a scattering prevention cover (H-PTD200) was set. In this state, the temperature was set to 20 ° C.
(Conditions for measuring storage elastic modulus of gel-like curable resin composition)
As vibration conditions, the strain was set to 5%, and the frequency at that time was set to 1 Hz. The measurement was started after standing for 60 minutes. The temperature was increased to 100 ° C. at a rate of temperature increase of 2 ° C./min. The storage elastic modulus at 25 ° C. of the obtained data was read and used as the storage elastic modulus of the gel-like curable resin composition.
(Storage modulus of cured product)
The same operation as the above sample adjustment conditions was performed, and the mixture was allowed to stand for 60 minutes. As a vibration condition, the strain is set to 5%, the frequency at that time is set to 1 Hz, and it is vibrated at 20 ° C. for 30 seconds, and then irradiated with ultraviolet rays having an exposure amount of 2000 mJ / cm ² from below the glass plate while vibrating at 20 ° C. Then, it was photocured and then vibrated again at 20 ° C. for 30 seconds. Subsequently, the temperature was increased to 100 ° C. at a rate of temperature increase of 2 ° C./min. The storage elastic modulus at 25 ° C. of the obtained data was read and used as the storage elastic modulus of the cured product.
(Measuring method)
A sample heated to 80 ° C. was placed on a sample stage, set to a thickness of 150 μm, covered, left at 20 ° C. for 60 minutes, and heated to 100 ° C. at a rate of 2 ° C./min. The storage elastic modulus at 25 ° C. at that time was taken as a measured value.

Table 2 shows the composition of the curable resin composition (transparent material) used as the intermediate material.
[Light transmittance of medium material]
A curable resin composition of intermediate materials a to c so that a 175 μm frame spacer is provided on a glass substrate having a length of 85 mm × width of 55 mm × thickness of 0.7 mm so that the film thickness after photocuring is 175 μm. An object was applied to the inside of a frame-shaped spacer to form a coating film, and the same glass substrate as above was bonded onto the formed coating film. And the ultraviolet-ray irradiation apparatus (Product name: ELM-3000B-6N, the product made from Oak Co., Ltd.) is used, 1000 mJ / cm < ² > of ultraviolet rays are irradiated, the coating film of a curable resin composition is hardened, and two glass substrates A cured product having a thickness of 175 μm sandwiched between the layers was prepared.
In the same manner as described above, each of the intermediate materials a to c was used to prepare a reference sample sandwiched between two glass substrates so that the film thickness after curing was 20 μm. . Using a sample in which a cured product having a thickness of 20 μm is sandwiched between two glass substrates as a reference, light at a wavelength of 400 nm of a cured product having a thickness of 175 μm sandwiched between the two glass substrates corresponding to the reference. The transmittance was measured using a spectrophotometer (manufactured by Shimadzu Corporation, product name “UV-2400PC”).

[Viscosity of medium material]
Using an E-type viscometer (TV-22 manufactured by Toki Sangyo Co., Ltd.), the viscosity (unit: Pa · s) at 25 ° C. of the curable resin composition of the intermediate materials a to c was measured. Measurement conditions and methods are as shown below.
(Measurement condition)
・ Rotor name: 3 ° × R9.7, Rotor code 06
・ Measurement range: 5M
・ Rotation speed: 0.5rpm

[Curing shrinkage]
A curable resin composition of intermediate materials a to c is dropped onto a PET film, and another PET film is bonded so as to have a film thickness of 175 μm, and an ultraviolet irradiation device (product name: ELM-3000B-6N, Inc. A transparent film in which the curable resin composition was cured by irradiation with ultraviolet rays at 2,000 mJ / cm ² was produced. The specific gravity of the transparent film and the resin composition before curing is measured using an electronic hydrometer (manufactured by Alpha Mirage Co., Ltd., SD-200L), the curing shrinkage is calculated from the following formula, and evaluated according to the following criteria: did.
Curing shrinkage (%) = {(specific gravity of curable resin composition after curing−specific gravity of curable resin composition before curing) / specific gravity of curable resin composition after curing} × 100

[Evaluation of streak occurrence]
Examples 1 to 8 (when a gel-like curable resin composition is used as an edge material)
A 10 cm × 10 cm × 1 mm silicone sheet provided with a 2 cm × 2 cm opening was prepared. The silicone sheet was brought into close contact with a 10 cm × 10 cm glass substrate, and the right half (1 cm × 2 cm) of the opening was covered with the silicone sheet. In the left half of the silicone sheet (a in FIG. 6), a gel-like curable resin composition (Preparation Examples (1) to (6)) heated to 80 ° C. to have fluidity is prepared using a dropper. It apply | coated so that an opening part might be filled. After returning the gel-like curable resin composition to room temperature (25 ° C.) to be in a gel state, the silicone sheet covering the right half is removed, and the curable resin composition (inner materials (a) to (c)) ) Was applied with a dropper so as to fill the opening (b in FIG. 6). Next, a polyethylene terephthalate fill was applied so as to cover the opening, and then 1000 mJ / cm ² ultraviolet rays were irradiated from above using an ultraviolet irradiation device (FIG. 6). Table 3 shows the evaluation results of using this as an evaluation sample and observing the interface between the frame member and the intermediate member with a microscope (CCD Microscope trade name: SCOPEMAN MS-804, manufactured by Moritex Corporation).
In addition, as a result of observing with a microscope as described above, the case where no streak was observed was evaluated as “A”, and the case where even a slight streak was recognized was evaluated as “B”, and the results are shown in Table 3.

Comparative Examples 1 and 2 (when a curable resin composition that is liquid at 25 ° C. is used as the edge material)
A 10 cm × 10 cm × 1 mm silicone sheet provided with a 2 cm × 2 cm opening was prepared. The silicone sheet was brought into close contact with a 10 cm × 10 cm glass substrate, and the right half (1 cm × 2 cm) of the opening was covered with the silicone sheet. A liquid curable resin composition (Comparative Preparation Example (7), corresponding to an edge material) at 25 ° C. was applied to the left half of the silicone sheet using a dropper so as to fill the opening (a) (FIG. 7). A). Thereafter, a polyethylene terephthalate film (PET) was covered so as not to enter air so as to cover the part a, and was irradiated with 1,000 mJ / cm ² ultraviolet rays using an ultraviolet irradiation device. Next, the silicone sheet covering the PET and the right half was removed, and a curable resin composition (inner material a or c) was applied thereto so as to fill the opening using a dropper. Next, a polyethylene terephthalate fill was applied so as to cover the opening, and then, 1000 mJ / cm ² ultraviolet ray was irradiated from above using an ultraviolet ray irradiator (FIG. 7). Table 3 shows the evaluation results obtained by observing the interface between the edge member and the intermediate member with a microscope using this as an evaluation sample.
Moreover, the microscope picture (400 times) of the interface of the edge material of Example 1 and the comparative example 1 and a middle material is shown in FIG.8 and FIG.9.

When the rim material of the present invention of Examples 1 to 8 is used, no streaks are observed at the interface between the rim material and the middle material in the transparent resin layer, whereas the curable resin compositions of Comparative Examples 1 and 2 are used. When an object was used as an edge material, streaks were generated at the interface between the edge material and the intermediate material.
[Evaluation of adhesiveness of transparent resin layer]
A glass substrate A of 58 mm × 86 mm × 0.7 mm (thickness) and a glass substrate B having the same dimensions as the glass substrate A were prepared.
The gel-like curable resin composition of Preparation Example (4) sealed in a 5 ml syringe at the edge of 4 sides of the glass substrate A (about 1 mm inside from the end of the glass substrate) so that the width is about 10 mm. To form a frame. The inside material a was poured into the inside of the frame to fill the inside of the frame.
Next, the glass substrate B is bonded to the surface of the glass substrate A on which the gel-like curable resin composition and the intermediate material a are applied so that the film thickness of the gel-like curable resin composition and the intermediate material a is about 175 μm. It was. Next, the transparent resin layer was formed by irradiating 2000 mJ / cm ² ultraviolet rays on the glass substrate A using an ultraviolet irradiation device. The glass substrate B was lifted by holding only the glass substrate A so that the glass substrate B would be downward. The glass substrate B was confirmed to have good adhesiveness without peeling off.

  The edge material for an image display device of the present invention is composed of a gel-like curable resin composition, and when a liquid curable resin composition is used as an intermediate material, no streak is generated at the interface between the edge material and the intermediate material. Therefore, it is excellent in visibility and can be suitably used as a constituent member for filling a space between the transparent protective substrate and the image display unit in an image display device such as a liquid crystal display device.

DESCRIPTION OF SYMBOLS 1 Image display unit 10 Liquid crystal display cell 20, 22 Polarizing plate 30 Touch panel 31, 32 Transparent resin layer 40 Transparent protective substrate 50 Backlight system

Claims (10)

  An edge material for an image display device used for forming a rim material on a transparent protective substrate, a touch panel or an image display unit, and forming a transparent adhesive layer by applying a transparent material inside the rim material, An edge material for an image display device, wherein the edge material is composed of a gel-like curable resin composition.   A frame formed using the edge material for an image display device according to claim 1 so as to surround an edge of the touch panel or the image display unit. The gel-like curable resin composition is
(A) a compound having a (meth) acryloyl group,
(B) an oil gelling agent, and (C) a polymerization initiator,
The edge material for image display apparatuses of Claim 1 containing.   The edge material for an image display device according to claim 3, wherein the gel-like curable resin composition further includes (D) a plasticizer.   The edge material for an image display device according to claim 3 or 4, wherein the content of the component (A) is 1 to 90% by mass with respect to the total amount of the gel curable resin composition. Forming a rim material on the transparent protective substrate, the touch panel or the image display unit using the gel-like curable resin composition;
A step of forming a transparent adhesive layer by applying a liquid transparent material inside the edge material;
Irradiating the transparent adhesive layer and the gel-like curable resin composition with light to form a transparent resin layer;
A method for manufacturing an image display device. A transparent protective substrate;
An image display unit;
An image display device having a transparent resin layer,
A transparent resin layer is formed from a rim material of a cured product of a gel-like curable resin composition formed on a transparent protective substrate or an image display unit, and a cured product of a liquid transparent material formed inside the rim material. An image display table device configured. A transparent protective substrate;
A touch panel;
An image display unit;
An image display device having a transparent resin layer,
A transparent resin layer is formed on a transparent protective substrate, a touch panel or an image display unit, an edge material of a cured product of a gel-like curable resin composition, and a cured product of a liquid transparent material formed on the inner side of the edge material An image display table device comprising:   A dam material is formed on a transparent protective substrate, a touch panel or an image display unit, and is used for forming a transparent adhesive layer by applying a transparent material inside the dam material. A dam material for an image display device, wherein the dam material comprises a gel-like curable resin composition.   A transparent resin layer used in an image display device, comprising an oil gelling agent within a range of 10 mm from the outer edge of the transparent resin layer, and a transparent resin layer substantially free of an oil gelling agent at the center of the transparent resin layer Resin layer.