JP2014196422A5 - - Google Patents

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JP2014196422A5
JP2014196422A5 JP2013072912A JP2013072912A JP2014196422A5 JP 2014196422 A5 JP2014196422 A5 JP 2014196422A5 JP 2013072912 A JP2013072912 A JP 2013072912A JP 2013072912 A JP2013072912 A JP 2013072912A JP 2014196422 A5 JP2014196422 A5 JP 2014196422A5
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ethylene
resin composition
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Claims (8)

未使用のポリオレフィン系重合体を含む基材成分100重量部に対して、
(D)多孔質粒子に水性媒体が充填された貯水材であって、前記多孔質粒子が疎水性重合体から構成され、前記水性媒体は両親媒性高分子を含み、水性媒体の充填割合が貯水材全重量に対して30〜70重量%である貯水材1〜5重量部、を溶融混練して得られる樹脂組成物。
For 100 parts by weight of a base component containing an unused polyolefin polymer,
(D) A water storage material in which porous particles are filled with an aqueous medium, wherein the porous particles are composed of a hydrophobic polymer, the aqueous medium contains an amphiphilic polymer, and the filling ratio of the aqueous medium is A resin composition obtained by melt-kneading 1 to 5 parts by weight of a water storage material that is 30 to 70% by weight with respect to the total weight of the water storage material.
ポリプロピレン系樹脂と、
必要に応じて、エチレンと、炭素原子数3〜8のα−オレフィンから選ばれる少なくとも1種のα−オレフィンからなるエチレン・α−オレフィン共重合体、とから構成される基材成分100重量部に対して、
(D)多孔質粒子に水性媒体が充填された貯水材であって、前記多孔質粒子が疎水性重合体から構成され、前記水性媒体は両親媒性高分子を含み、水性媒体の充填割合が貯水材全重量に対して30〜70重量%である貯水材1〜5重量部、を溶融混練して得られる樹脂組成物。
Polypropylene resin,
If necessary, 100 parts by weight of a base component composed of ethylene and an ethylene / α-olefin copolymer composed of at least one α-olefin selected from α-olefins having 3 to 8 carbon atoms Against
(D) A water storage material in which porous particles are filled with an aqueous medium, wherein the porous particles are composed of a hydrophobic polymer, the aqueous medium contains an amphiphilic polymer, and the filling ratio of the aqueous medium is A resin composition obtained by melt-kneading 1 to 5 parts by weight of a water storage material that is 30 to 70% by weight with respect to the total weight of the water storage material.
前記基材成分が、
(A)(a−1)JIS K 7210に準拠した方法で測定したメルトフローレート(MFR、230℃、21.16N荷重)が10〜300g/10minであって、プロピレンから導かれる構成単位の含量が98〜100mol%であり、エチレンと炭素原子数4〜8のα−オレフィンから選ばれる少なくとも1種のα−オレフィンから導かれる構成単位の含量が0〜2mol%であるプロピレン系重合体50〜90重量部、
(a−2)135℃デカリン中で測定した極限粘度[η]が1.5〜9dl/g、エチレンから導かれる構成単位の含量が30〜60mol%であるプロピレン・エチレン共重合体0〜30重量部、
からなり、(a−1)と(a−2)の合計が30〜80重量部であるポリプロピレン系樹脂と、
(B)エチレン含有率が65〜95mol%である、エチレンと、炭素原子数3〜8のα−オレフィンから選ばれる少なくとも1種のα−オレフィンからなるエチレン・α−オレフィン共重合体1〜30重量部((A)と(B)の合計が100重量部)とからなる、請求項2に記載の樹脂組成物。
The base material component is
(A) (a-1) Content of structural unit derived from propylene having a melt flow rate (MFR, 230 ° C., 21.16 N load) measured by a method according to JIS K 7210 of 10 to 300 g / 10 min. Is a propylene-based polymer 50 to 98 having a content of structural units derived from at least one α-olefin selected from ethylene and an α-olefin having 4 to 8 carbon atoms, from 98 to 100 mol%. 90 parts by weight,
(A-2) Propylene / ethylene copolymer 0-30 having an intrinsic viscosity [η] measured in 135 ° C. decalin of 1.5-9 dl / g and a content of structural units derived from ethylene of 30-60 mol% Parts by weight,
A polypropylene resin in which the total of (a-1) and (a-2) is 30 to 80 parts by weight;
(B) ethylene / α-olefin copolymers 1 to 30 consisting of ethylene and at least one α-olefin selected from α-olefins having 3 to 8 carbon atoms and having an ethylene content of 65 to 95 mol% The resin composition of Claim 2 which consists of a weight part (the sum total of (A) and (B) is 100 weight part).
前記(D)貯水材に含まれる両親媒性高分子が、下記一般式(I)で表される構造である請求項1または2に記載の樹脂組成物。
Figure 2014196422
[一般式(I)中、R1は、炭素原子数1〜6のアルキル基であり、
AおよびBは、炭素原子数1〜6のアルキル基、または、−Z−R2−R3で表される基であり、Zは、−Cr2rO−の構造(rは1〜10の整数)を有し、各々同じか異なっていてもよく、
2は、−(C24O−)n(C36O−)mの構造(mは0または1〜4の整数であり、nは1〜12の整数)であり、それぞれn回およびm回繰り返される単位の配列は、ブロックまたはランダムであってよく、
3は、OH基または炭素原子数1〜6のアルキル基であり、
xは、0または1〜3の整数であり、
yは、0または1〜3の整数であり、
一般式(I)であらわされる分子は常に、−Z−R2−R3で表される基を少なくとも1つ有する。]
Wherein (D) amphiphilic polymer contained in the reservoir material, tree fat composition according to claim 1 or 2 is a structure represented by the following general formula (I).
Figure 2014196422
[In General Formula (I), R 1 is an alkyl group having 1 to 6 carbon atoms,
A and B are an alkyl group having 1 to 6 carbon atoms or a group represented by —Z—R 2 —R 3 , wherein Z is a structure of —C r H 2r O— (r is 1 to Each may be the same or different,
R 2 is a structure of — (C 2 H 4 O—) n (C 3 H 6 O—) m (m is 0 or an integer of 1 to 4, and n is an integer of 1 to 12, respectively) The sequence of units repeated n and m times may be block or random,
R 3 is an OH group or an alkyl group having 1 to 6 carbon atoms,
x is 0 or an integer of 1 to 3,
y is an integer of 0 or 1 to 3,
Molecules represented by the general formula (I) always have at least one of the groups represented by -Z-R 2 -R 3. ]
前記一般式(I)において、
Aが、メチル基または−Z−R2−R3の基であり、
Bが、メチル基であり、
2が、−(C24O−)n(C36O−)mの構造(mは1または2であり、nは5〜9の整数)である請求項4に記載の樹脂組成物。
In the general formula (I),
A is a methyl group or a group of —Z—R 2 —R 3 ,
B is a methyl group;
5. The structure according to claim 4, wherein R 2 has a structure of — (C 2 H 4 O—) n (C 3 H 6 O—) m (m is 1 or 2, and n is an integer of 5 to 9). Resin composition.
前記(a−1)プロピレン系重合体のメルトフローレート(MFR、230℃、21.16N荷重)が10〜100g/10minであり、アイソタクティックペンタッド分率(mmmm)が95.0〜99.0である請求項3に記載の樹脂組成物。   The melt flow rate (MFR, 230 ° C., 21.16 N load) of the (a-1) propylene-based polymer is 10 to 100 g / 10 min, and the isotactic pentad fraction (mmmm) is 95.0 to 99. The resin composition according to claim 3, which is 0.0. 前記(a−1)プロピレン系重合体のメルトフローレート(MFR、230℃、21.16N荷重)が10〜100g/10minであり、アイソタクティックペンタッド分率(mmmm)が96.5〜99.0である請求項3に記載の樹脂組成物。   The melt flow rate (MFR, 230 ° C., 21.16 N load) of the (a-1) propylene polymer is 10 to 100 g / 10 min, and the isotactic pentad fraction (mmmm) is 96.5 to 99. The resin composition according to claim 3, which is 0.0. 請求項1〜7のいずれか1項に記載の樹脂組成物からなる成形体。   The molded object which consists of a resin composition of any one of Claims 1-7.
JP2013072912A 2013-03-29 2013-03-29 Resin composition and use thereof Active JP6068231B2 (en)

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JP2014196422A JP2014196422A (en) 2014-10-16
JP2014196422A5 true JP2014196422A5 (en) 2015-09-17
JP6068231B2 JP6068231B2 (en) 2017-01-25

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KR101835343B1 (en) * 2016-09-08 2018-03-08 지에스칼텍스 주식회사 Master batch composition, resin composition including the same and molded article produced therefrom

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DE102007050046A1 (en) * 2007-10-17 2009-04-23 Byk-Chemie Gmbh water-tank
JP2010150417A (en) * 2008-12-25 2010-07-08 Sumitomo Chemical Co Ltd Polypropylene-based resin composition and molded product
CN103044776B (en) * 2012-12-31 2015-01-28 广东银禧科技股份有限公司 Low-odor and yellowing resistant polypropylene composition and preparation method thereof

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