JP2014172037A - Gravure roll for transferring hot melt adhesive - Google Patents

Gravure roll for transferring hot melt adhesive Download PDF

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JP2014172037A
JP2014172037A JP2013050126A JP2013050126A JP2014172037A JP 2014172037 A JP2014172037 A JP 2014172037A JP 2013050126 A JP2013050126 A JP 2013050126A JP 2013050126 A JP2013050126 A JP 2013050126A JP 2014172037 A JP2014172037 A JP 2014172037A
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melt adhesive
hot melt
gravure roll
roll
transferring
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JP6031384B2 (en
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Takayuki Haneno
隆之 羽野
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Resonac Packaging Corp
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Showa Denko Packaging Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a gravure roll for transferring a hot melt adhesive not generating a cobwebbing phenomenon in the hot melt adhesive transferred onto a laminate material by the gravure roll.SOLUTION: The shape of a mesh-like cell (2) formed on a gravure roll (1) for transferring a hot melt adhesive is a rhombic shape in which one (A) of two facing angles is positioned on the rotation direction side, the other one angle (B) is positioned on the opposite side to the rotation direction of the roll (1), and each angle of the two angles (A), (B) is 140° respectively.

Description

本発明は、ホットメルト接着剤転写用グラビアロールに関する。   The present invention relates to a gravure roll for transferring a hot melt adhesive.

ヨーグルト等の食品用コップ状容器の蓋材として、高分子材料とアルミニウム箔を張り合わせたラミネート材が用いられており、ラミネート材の熱封緘材層の形成にはホットメルト接着剤が使用されている。このホットメルト接着剤は、シール剤として融点が比較的低く、融解させてグラビアロールで転写して塗布することが多い。   As a lid for a cup-shaped container for food such as yogurt, a laminate material in which a polymer material and an aluminum foil are laminated is used, and a hot-melt adhesive is used to form a heat sealing material layer of the laminate material. . This hot melt adhesive has a relatively low melting point as a sealant, and is often melted and transferred with a gravure roll.

特許第2587986号公報Japanese Patent No. 2587986

食品用コップ状容器の蓋材に使用せられるホットメルト接着剤は、エチレン−酢酸ビニル共重合体(EVA)、ワックス、粘着付与剤およびその他微量の添加剤からなるものが殆どであるが、要求せられる性能によって様々な組み合わせで構成せられる。ところが、耐熱性などの要求性能によっては、ホットメルト接着剤の粘度の高いものが必要となり、グラビアロールではホットメルト接着剤の塗布が困難になることがある。何故なら、グラビアロールからラミネート材にホットメルト接着剤を転写するさいに、その粘度の高さから、ロールの回転方向に糸を引いてしまうからである。何故なら、グラビアロールには、上記特許文献に開示されているように、正方形の網目状のセルが設けられており、このセルの中にホットメルト接着剤を充填してラミネート材に転写するのであるが、転写するさいに網目状のセルを区画する土手からの切れが悪く、ロールの回転によって引きずられて糸を引いてしまう。このように糸を引くと、転写後のホットメルト接着剤は滑らかなゆるい山状にはならずに鋭角に上向きに尖った形状になる(図5参照)。すると、鋭角に上向きに尖った形状は、製品をコイル状に巻いた際に総厚が厚くなって取り扱い難いという欠点があった。また、糸引きが発生すると、糸状になったホットメルト接着剤がラミネート材の表面に付着したり、鋭角状のホットメルト接着剤が後工程で削られて異物となってしまうという不具合があった。   Most hot melt adhesives used for food cup-shaped container lids consist of ethylene-vinyl acetate copolymer (EVA), wax, tackifiers, and other trace amounts of additives. It can be configured in various combinations depending on the performance. However, depending on the required performance such as heat resistance, a hot melt adhesive having a high viscosity is required, and it may be difficult to apply the hot melt adhesive with a gravure roll. This is because when the hot melt adhesive is transferred from the gravure roll to the laminate, the yarn is pulled in the rotation direction of the roll due to its high viscosity. This is because gravure rolls are provided with square mesh-like cells, as disclosed in the above-mentioned patent document, and hot melt adhesive is filled in these cells and transferred to the laminate material. However, when transferring, the cut from the bank that divides the net-like cells is poor, and the yarn is pulled by being dragged by the rotation of the roll. When the yarn is pulled in this way, the hot-melt adhesive after the transfer does not have a smooth loose mountain shape, but has a sharp pointed upward shape (see FIG. 5). Then, the shape sharpened upward at an acute angle has a drawback that it is difficult to handle because the total thickness becomes thick when the product is wound in a coil shape. In addition, when stringing occurs, there is a problem that the hot melt adhesive in the form of a thread adheres to the surface of the laminate material, or the sharp-angled hot melt adhesive is scraped off in a subsequent process and becomes a foreign matter. .

要するに、グラビアロールのセルの回転方向反対側の角度が120゜未満であると、転写したホットメルト接着剤に上記糸引き現象が生じ易い。   In short, if the angle on the opposite side of the rotation direction of the gravure roll cell is less than 120 °, the threading phenomenon is likely to occur in the transferred hot melt adhesive.

本発明の目的は、グラビアロールによりラミネート材に転写したホットメルト接着剤に糸引き現象が生じないホットメルト接着剤転写用グラビアロールを提供することにある。   An object of the present invention is to provide a gravure roll for transferring a hot melt adhesive in which a stringing phenomenon does not occur in a hot melt adhesive transferred to a laminate by a gravure roll.

請求項1の発明によるホットメルト接着剤転写用グラビアロールは、グラビアロールに形成せられている網目状のセルの形状が菱形かまたは六角形であって、対向する2つの角の1つがロールの回転方向側に、他の1つの角がロールの回転方向の反対側にあり、2つの角の角度がともに120゜〜160゜であるものである。   The gravure roll for transferring a hot melt adhesive according to the invention of claim 1 is such that the shape of a mesh-like cell formed on the gravure roll is a rhombus or a hexagon, and one of two opposing corners is a roll. On the rotation direction side, the other angle is on the opposite side of the rotation direction of the roll, and the angles of the two angles are both 120 ° to 160 °.

上記角の角度が120゜未満であると、グラビアロールからラミネート材にホットメルト接着剤を転写するさいに、ロールの回転方向に糸を引く可能性があ り、160゜を超えるとホットメルト接着剤を転写するさいに網目状セルを区画する土手部からの切れが悪く、ロールの回転によって引きずられ、セル形状が崩れ易くなる。
請求項2の発明は、請求項1記載のホットメルト接着剤転写用グラビアロールにおいて、セルの深さが0.05mm〜0.2mmであるものである。
If the angle is less than 120 °, the hot melt adhesive may be pulled from the gravure roll to the laminate, and the yarn may be pulled in the direction of roll rotation. When transferring the agent, the cut off from the bank portion that divides the reticulated cell is bad, and dragged by the rotation of the roll, the cell shape tends to collapse.
According to a second aspect of the present invention, in the gravure roll for transferring a hot melt adhesive according to the first aspect, the depth of the cell is 0.05 mm to 0.2 mm.

上記セルの深さが0.05mm未満であると、ホットメルト接着剤の転写量が少なくなり、シール強度が低下し、0.2mmを超えると、セルの容積が増大するため、ホットメルト接着剤の転写量が多く、シール強度が不必要に大きくなり、コスト高を招く。   When the cell depth is less than 0.05 mm, the transfer amount of the hot melt adhesive is reduced and the sealing strength is lowered. When the cell depth exceeds 0.2 mm, the volume of the cell is increased. The transfer amount is large, the seal strength becomes unnecessarily large, and the cost increases.

請求項3の発明は、請求項1または2記載のホットメルト接着剤転写用グラビアロールにおいて、セル間の土手部の幅が0.01mm〜0.10mmであるものである。   A third aspect of the present invention is the gravure roll for transferring a hot melt adhesive according to the first or second aspect, wherein the width of the bank portion between the cells is 0.01 mm to 0.10 mm.

土手部の幅が0.01mm未満であってもまた0.10mmを超えてもホットメルト接着剤のラミネート材に対する塗布量が不均一になる。   Even if the width of the bank portion is less than 0.01 mm or more than 0.10 mm, the amount of the hot melt adhesive applied to the laminate becomes non-uniform.

本発明によるホットメルト接着剤転写用グラビアロールは、グラビアロールに形成せられている網目状のセルの形状が菱形かまたは六角形であって、対向する2つの角の1つがロールの回転方向側に、他の1つの角がロールの回転方向の反対側にあり、2つの角の角度がともに120゜〜160゜であるから、グラビアロールからラミネート材にホットメルト接着剤を転写するさいに、その粘度が高くてもロールの回転方向に糸を引くことがないから、糸引き現象の結果生じる諸々の問題点がなくなる。   The gravure roll for transferring a hot melt adhesive according to the present invention has a rhomboid or hexagonal shape of the mesh-like cells formed on the gravure roll, and one of the two opposite corners is on the rotation direction side of the roll In addition, since the other one corner is on the opposite side of the rotation direction of the roll and the angles of the two corners are both 120 ° to 160 °, when transferring the hot melt adhesive from the gravure roll to the laminate, Even if the viscosity is high, the yarn is not pulled in the rotation direction of the roll, so that various problems resulting from the yarn drawing phenomenon are eliminated.

網目状のセルの形状が菱形である本発明のグラビアロールの展開部分平面図である。It is an expansion | deployment partial top view of the gravure roll of this invention whose shape of a mesh-shaped cell is a rhombus. 図1のII−II線にそう拡大断面図である。FIG. 2 is an enlarged cross-sectional view taken along line II-II in FIG. 1. 網目状のセルの形状が六角である本発明のグラビアロールの展開部分平面図である。It is an expansion | deployment partial top view of the gravure roll of this invention whose shape of a mesh-shaped cell is a hexagon. 本発明のグラビアロールが用いられてラミネート材に熱封緘材層が形成された蓋材の部分拡大断面図である。It is a partial expanded sectional view of the cover material in which the gravure roll of this invention was used and the heat sealing material layer was formed in the laminate material. 従来のグラビアロールが用いられてラミネート材に熱封緘材層が形成された蓋材の部分拡大断面図である。It is the elements on larger scale of the cover material in which the conventional gravure roll was used and the heat sealing material layer was formed in the laminate material.

図1および図2は、ホットメルト接着剤転写用グラビアロール(1)に形成せられている網目状のセル(2)の形状が菱形のものを示し、対向する2つの角の1つ(A)がロール(1)の回転方向側に、他の1つの角(B)がロール(1)の回転方向の反対側にあり、2つの角(A) (B)の角度がともに140゜である。そして、セル(2)の深さ(C)は0.15mmである。また、土手部(3)の幅は0.2mmである。     FIG. 1 and FIG. 2 show that the shape of the mesh-like cell (2) formed on the gravure roll (1) for transferring the hot melt adhesive is a rhombus, and one of two opposing corners (A ) Is on the rotation direction side of the roll (1), the other corner (B) is on the opposite side of the rotation direction of the roll (1), and the two angles (A) and (B) are both 140 °. is there. The depth (C) of the cell (2) is 0.15 mm. The width of the bank portion (3) is 0.2 mm.

図3は、ホットメルト接着剤転写用グラビアロール(4)に形成せられている網目状のセル(5)の形状が六角形のものを示し、対向する2つの角の1つ(D)がロール(4)の回転方向側に、他の1つの角(E)がロール(4)の回転方向の反対側にあり、2つの角(D) (E)の角度がともに145゜である。そして、セル(5)の深さは、図2のものと同様に0.15 mmである。また、土手部(6)の幅は0.2mmである。     Fig. 3 shows that the shape of the mesh cell (5) formed on the gravure roll (4) for transferring the hot melt adhesive is hexagonal, and one of the two opposite corners (D) is On the rotation direction side of the roll (4), another angle (E) is on the opposite side of the rotation direction of the roll (4), and the angles of the two angles (D) (E) are both 145 °. The depth of the cell (5) is 0.15 mm as in the case of FIG. The width of the bank portion (6) is 0.2 mm.

いま、厚さ12μmのポリエチレンテレフタレートフィルム(7)の片面に厚さ30μmのアルミニウム箔(8)をポリウレタン系ドライラミネート系接着剤で貼り合わせて基材層とした。つぎに、アルミニウム箔(8)の表面に厚さ20μmのポリエチレンフィルム(9)を前記と同様の接着剤で接着して中間樹脂層を形成し、その上に網目状のセル(2)の形状が菱形のホットメルト接着剤転写用グラビアロール(1)を用い、粘度が150゜Cで6000mPa・sのホットメルト接着剤を転写して熱封緘材層(10)を形成した。このようにして得られた基材層、中間樹脂層および熱封緘材層(10)よりなる積層体により食品用コップ状容器の蓋材を形成した。転写後のホットメルト接着剤は、網目状のセル(2)に対応する部分が図4に示すように滑らかなゆるい山状部(10a)となる。     Now, an aluminum foil (8) having a thickness of 30 μm is bonded to one side of a polyethylene terephthalate film (7) having a thickness of 12 μm with a polyurethane dry laminate adhesive to form a base material layer. Next, a polyethylene film (9) having a thickness of 20 μm is adhered to the surface of the aluminum foil (8) with the same adhesive as described above to form an intermediate resin layer, and the shape of the mesh cell (2) is formed thereon. Was used to transfer a hot melt adhesive having a viscosity of 150 ° C. and a viscosity of 6000 mPa · s to form a heat sealing material layer (10). A lid for a cup-shaped container for food was formed from the laminate composed of the base material layer, the intermediate resin layer and the heat sealing material layer (10) thus obtained. In the hot-melt adhesive after transfer, the portion corresponding to the mesh-like cell (2) becomes a smooth and loose crest portion (10a) as shown in FIG.

ところが、正方形の網目状のセルが設けられている従来のグラビアロールでホットメルト接着剤を転写して熱封緘材層(11)を形成すると、転写するさいに網目状のセルを区画する土手からの切れが悪く、ロールの回転によって引きずられて糸を引いてしまうので、転写後のホットメルト接着剤は図5に示すように鋭角に上向きに尖った形状の山状部(11a)となる。   However, when the hot-melt adhesive is transferred by a conventional gravure roll provided with square mesh-like cells to form the heat-sealing material layer (11), from the bank partitioning the mesh-like cells during the transfer. Since the cut is poor and the yarn is pulled by the rotation of the roll, the hot-melt adhesive after the transfer becomes a mountain-shaped portion (11a) having a sharply sharp upward shape as shown in FIG.

(1) (4) ホットメルト接着剤転写用グラビアロール
(2) (5) 網目状のセル
(3) (6) セル間の土手部
(A)(B)(D) (E) セルの対向する角
(C) セルの深さ
(1) (4) Gravure roll for transferring hot melt adhesive
(2) (5) Mesh cell
(3) (6) Bank part between cells
(A) (B) (D) (E) Opposite corners of the cell
(C) Cell depth

Claims (3)

グラビアロールに形成せられている網目状のセルの形状が菱形かまたは六角形であって、対向する2つの角の1つがロールの回転方向側に、他の1つの角がロールの回転方向の反対側にあり、2つの角の角度がともに120゜〜160゜であるホットメルト接着剤転写用グラビアロール。   The shape of the mesh-like cell formed on the gravure roll is a rhombus or hexagon, and one of the two opposing corners is on the rotation direction side of the roll, and the other corner is on the rotation direction of the roll. A gravure roll for transferring a hot melt adhesive, which is on the opposite side and has two angles of 120 ° to 160 °. セルの深さが0.05mm〜0.2mmである請求項1記載のホットメルト接着剤転写用グラビアロール。   The gravure roll for transferring a hot melt adhesive according to claim 1, wherein the cell has a depth of 0.05 mm to 0.2 mm. セル間の土手部の幅が0.01mm〜0.10mmである請求項1または2記載のホットメルト接着剤転写用グラビアロール。   The gravure roll for transferring a hot melt adhesive according to claim 1 or 2, wherein the width of the bank between the cells is 0.01 mm to 0.10 mm.
JP2013050126A 2013-03-13 2013-03-13 Gravure roll for hot melt adhesive transfer Active JP6031384B2 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019059327A1 (en) * 2017-09-20 2019-03-28 株式会社サンツール Roll transfer application method for thick application surface
WO2020217613A1 (en) * 2019-04-25 2020-10-29 日東電工株式会社 Method for manufacturing laminated polarizing film and device for manufacturing laminated polarizing film

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JPH09323055A (en) * 1996-06-05 1997-12-16 Sanwa Kakoshi Kk Wax supplying method, vat tank used therefor and wax melting tank
WO2009011177A1 (en) * 2007-07-19 2009-01-22 Dic Corporation Moisture-curable polyurethane hot-melt adhesive, laminates made with the same, and moisture-permeable film

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JPS6242765A (en) * 1985-08-19 1987-02-24 Takiron Co Ltd Method for coating electrically conductive paint
JPH02292042A (en) * 1989-03-14 1990-12-03 Inta Roto Gravure Inc Engraved plate cylinder coated with micro-ceramics and coating method thereof
JPH09323055A (en) * 1996-06-05 1997-12-16 Sanwa Kakoshi Kk Wax supplying method, vat tank used therefor and wax melting tank
WO2009011177A1 (en) * 2007-07-19 2009-01-22 Dic Corporation Moisture-curable polyurethane hot-melt adhesive, laminates made with the same, and moisture-permeable film

Cited By (7)

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Publication number Priority date Publication date Assignee Title
WO2019059327A1 (en) * 2017-09-20 2019-03-28 株式会社サンツール Roll transfer application method for thick application surface
JPWO2019059327A1 (en) * 2017-09-20 2020-09-03 株式会社サンツール Roll transfer coating method for thick coated surfaces
WO2020217613A1 (en) * 2019-04-25 2020-10-29 日東電工株式会社 Method for manufacturing laminated polarizing film and device for manufacturing laminated polarizing film
JP2020181114A (en) * 2019-04-25 2020-11-05 日東電工株式会社 Method and device for manufacturing laminate polarization film
CN113613799A (en) * 2019-04-25 2021-11-05 日东电工株式会社 Method for manufacturing laminated polarizing film and apparatus for manufacturing laminated polarizing film
JP7224729B2 (en) 2019-04-25 2023-02-20 日東電工株式会社 LAMINATED POLARIZED FILM MANUFACTURING METHOD AND LAMINATED POLARIZED FILM MANUFACTURING APPARATUS
TWI816974B (en) * 2019-04-25 2023-10-01 日商日東電工股份有限公司 Manufacturing method of laminated polarizing film and manufacturing device of laminated polarizing film

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