JP2014141448A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a detergent composition which can sufficiently remove a makeup, which hardly removes, such as water proof mascara, and refreshes skin after removing or rinsing.SOLUTION: A detergent composition comprises: (A) 0.001 to 5 mass% of a polymer selected from (acrylates/steareth-20 methacrylate) copolymer, (acrylates/steareth-20 methacrylate) crosspolymer and (acrylates/beheneth-25 methacrylate) copolymer; and (B) 1 to 50 mass% of one or more kinds of oil selected from (b1) an ether oil and (b2) a hydrocarbon oil in which the viscosity at 30°C is 18 mPa s or less; and (C) water. The detergent composition does not comprise (D) a nonionic detergent having HLB of 8 or more, or comprises less than 5 mass% of (D) the nonionic detergent.

Description

  The present invention relates to a cleaning composition.

  Conventionally, as a cleansing composition for wiping off makeup or rinsing off, a combination of acrylic acid / alkyl methacrylate copolymer and oil has been studied (Patent Documents 1 to 3).

Japanese National Patent Publication No. 11-503461 JP 2004-339212 A JP 2009-242340 A

These cleaning compositions have problems that their detergency is insufficient and that oily feeling remains on the skin after wiping or rinsing.
The present invention relates to a cleaning composition that can sufficiently remove difficult makeup such as waterproof mascara, and the skin after wiping or rinsing is refreshed.

  The present inventors have found that when a specific copolymer and a specific oil agent are used in combination, a cleaning composition that solves the above problems can be obtained.

The present invention includes the following components (A), (B) and (C):
(A) 0.001 to 5% by mass of a polymer selected from (A-1), (A-2) and (A-3),
(A-1) a copolymer containing a monomer selected from (a1), (a2) and (a3) as a structural unit, and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers,
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) a monomer selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid;
(A-2) It has a polyoxyalkylene chain having an average molecular weight of 300 to 100,000, and has the general formula (1)

[In the formula, R is the same or different, and (d) a hydrogen atom, a methyl group, an ethyl group, a hydroxyethyl group, a hydroxypropyl group, (e) a substituent containing a polyoxyalkylene group, (f) a sulfoalkyl group, (g) a carboxyalkyl group, (h) a group selected from cationic substituents, Q being the same or different, an alkylene group having 2 to 4 carbon atoms, a, b and c being the same or different The number of 0-10 is shown. QO group, R group, a, b and c may be the same or different within a repeating unit or between repeating units, and when the substituents (e) to (h) have a hydroxy group, the hydroxy group May be further substituted with other substituents (e) to (h). Provided that R has at least one substituent (e).
A polysaccharide derivative having a structural unit represented by:
(A-3) General formula (2)

[In the formula, A ² is an alkylene group having 2 to 6 carbon atoms, n is an average value of 5 to 1000, p is an average value of 5 to 100, and (n × p) A ² is It may be the same or different. ]
A polyether polycarbonate having a structural unit represented by:
(B) 1 type or 2 types or more of oil agents chosen from (b1) and (b2) 1-50 mass%,
(B1) ether oil (b2) a hydrocarbon oil having a viscosity at 30 ° C. of 18 mPa · s or less,
(C) contains water,
(D) It is related with the cleaning composition which does not contain HLB8 or more nonionic surfactant, or contains less than 5 mass%.

The cleaning composition of the present invention provides a high cleaning power even for makeup that is difficult to remove, such as a waterproof mascara, and the skin after cleaning is refreshed to provide a feeling of cleaning.
In the present invention, the feeling of cleaning refers to a feeling that dirt has been completely removed and nothing remains on the skin, a feeling of being washed out, or a feeling of becoming bare skin.

The polymer of component (A) used in the present invention is selected from (A-1), (A-2) and (A-3).
(A-1) a copolymer containing a monomer selected from (a1), (a2) and (a3) as a structural unit and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers (a1) acrylic acid and methacrylic A monomer selected from acids,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) Monomer selected from polyoxyethylene alkyl ester of acrylic acid and polyoxyethylene alkyl ester of methacrylic acid:
The copolymer of component (A-1) is a copolymer containing a monomer selected from (a1), (a2) and (a3) as a constituent unit, and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers. It is not limited, and the content ratio and the bonding mode such as block bonding and random bonding are not limited. Moreover, the other monomer may be contained and you may have a crosslinked structure.
In the copolymer of component (A-1), when a monomer other than the monomer selected from (a1), (a2) and (a3) is included as a constituent unit, it is preferably less than 10 mol% based on the total monomers. 5 mol% or less is more preferable, and 1 mol% or less is still more preferable.

In the acrylic acid alkyl ester and methacrylic acid alkyl ester of (a2), the alkyl group of the alkyl ester preferably has 1 to 22 carbon atoms, more preferably 1 to 18 carbon atoms.
The molar ratio of (a2) in the copolymer of (A-1) is 10 mol% or more, preferably 15 mol% or more, in terms of the molar ratio with respect to the total monomers, from the viewpoint of obtaining a clean feeling on the washed skin. From the viewpoint of obtaining stability, it is preferably 70 mol% or less, more preferably 65 mol% or less, and even more preferably 60 mol% or less. The molar ratio of (a2) in the copolymer is preferably 10 to 70 mol%, more preferably 15 to 65 mol%, and still more preferably 20 to 60 mol%, based on the total monomer. The molar ratio refers to the number of moles of the structural unit (e2) in the number of moles of all monomers of the structural unit in one polymer molecule.

As the polymer of (A-1), for example, a copolymer containing a monomer selected from acrylic acid and methacrylic acid and a monomer selected from an alkyl acrylate ester and an alkyl methacrylate ester, polyquaternium-51, polyquaternium-61, (Glyceryl amide ethyl methacrylate / stearyl methacrylate) copolymer and the like.
Moreover, as a copolymer containing a monomer selected from acrylic acid and methacrylic acid and a monomer selected from alkyl acrylate and alkyl methacrylate as a structural unit, a structural unit represented by the following general formula (3) and the following general formula ( 4) At least one structural unit selected from the structural units represented by 4) (hereinafter sometimes referred to as an anionic structural unit) is represented by 50 to 90% by mass in the total structural units and represented by the following general formula (5). A non-crosslinked anionic amphiphilic polymer containing 10 to 50% by mass of all the structural units (hereinafter sometimes referred to as hydrophobic structural units) composed of structural units can be used.

In general formula (3), R ¹ , R ² and R ³ each represent a hydrogen atom or a methyl group, and R ¹ and R ² are preferably a hydrogen atom. In general formulas (3) and (4), M ¹ , M ² and M ³ each represent a hydrogen atom or a cationic group. Examples of the cationic group include alkali metal ions such as sodium and potassium; ammonium ions, and sodium and potassium are preferable. Moreover, it is preferable that 5 mol% or more of the carboxyl group is a salt.

In the general formula (5), R ⁴ represents a hydrogen atom or a methyl group, R ⁵ represents a linear or branched alkyl group or alkenyl group having 4 to 30 carbon atoms, from the viewpoint of detergency and emulsion stability. And those having 8 to 30 carbon atoms are preferred, and those having 12 to 22 carbon atoms are more preferred. Specific examples include an octyl group, 2-ethylhexyl group, decyl group, lauryl group, myristyl group, cetyl group, stearyl group, oleyl group, and behenyl group.

The proportion of the anionic structural unit in all the structural units of the anionic amphiphilic polymer as described above is 50 to 90% by mass, preferably 50 to 85% by mass, from the viewpoint of detergency and emulsion stability. 50 to 80% by mass is more preferable. Moreover, the ratio of the hydrophobic structural unit in all the structural units of anionic amphiphilic polymer is 10-50 mass% from the point of detergency and emulsification stability, and 15-50 mass% is preferable, 20 -50 mass% is more preferable.
Such an anionic amphiphilic polymer can be produced, for example, by the method described in JP-A-2007-238549, and in Synthesis Examples 1, 2, and 3 described in JP-A-2007-238549 A compound, (acrylic acid / stearyl acrylate) copolymer can be used.

  Further, as polyquaternium-51, lipid PMB, lipid B, lipid NR, lipid NA (manufactured by NOF Corporation); as polyquaternium-61, lipid S (manufactured by NOF Corporation); (glyceryl amidoethyl methacrylate / stearyl methacrylate) Commercially available products such as Seracute F, Cute L, and Cute V (manufactured by NOF Corporation) can be used as the copolymer.

Component (A-1) is more preferably a copolymer containing the monomers (a1), (a2) and (a3) as structural units, and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers.
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) A monomer selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid.
The copolymer is not limited as long as it contains the monomers (a1), (a2), and (a3) as structural units, and the content ratio and the bonding mode such as block bonding and random bonding are not limited. Moreover, the other monomer may be contained and you may have a crosslinked structure.

In the acrylic acid alkyl ester and methacrylic acid alkyl ester of (a2), the alkyl group of the alkyl ester preferably has 1 to 22 carbon atoms, more preferably 1 to 18 carbon atoms.
In addition, as the polyoxyethylene alkyl ester of acrylic acid and the polyoxyethylene alkyl ester of methacrylic acid (a3), the added mole number of polyoxyethylene is preferably 10-30, more preferably 12-25. Yes, the alkyl group of the alkyl ester preferably has 12 to 22 carbon atoms, and more preferably has 18 to 22 carbon atoms. As (a3), an ester of acrylic acid and polyoxyethylene (20) stearyl ether, an ester of methacrylic acid and polyoxyethylene (20) stearyl ether, an ester of acrylic acid and polyoxyethylene (25) behenyl ether An ester of methacrylic acid and polyoxyethylene (25) behenyl ether is more preferred.

As the component (A-1), from the viewpoint of high detergency and feeling of washing, (Acrylates / Stearless Methacrylic Acid-20) Copolymer, (Acrerants / Stearless Methacrylic Acid-20) Cross Polymer, and (Acrylates / Beheneth Methacrylate-25) ) Copolymers are preferred.
Moreover, as a component (A-1), commercial items, such as Aculin 22, Aculin 88, Aculin 28 (above, Rohm and Haas company make), can be used. In addition, Aculin 22 is a 30% by mass aqueous solution, Curin 28 is a 20% by mass aqueous solution, and Aculin 88 is a 29% by mass aqueous solution.

  As a component (A-1), a copolymer containing 10 mol% or more of (a2) in a molar ratio with respect to the total monomers, Polyquaternium-51, Lipidure PMB, Lipidure B (manufactured by NOF Corporation); JP 2007-238549 A (Acrylic acid / stearyl acrylate) copolymer; (acrylates / steare methacrylate-20) copolymer, (acrylates / steare methacrylate-20) cross-polymer, (acrylates) / Behynes methacrylate-25) Examples of the copolymer include Aculin 22, Aculin 88, Aculin 28 (manufactured by Rohm and Haas). Moreover, as a copolymer containing less than 10 mol% of (a2) in the molar ratio with respect to all the monomers, acrylic acid / alkyl methacrylate copolymer, PEMULEN TR-1, PEMULEN TR-2, Carbopol ETD2020 ( As mentioned above, Lubrizol Advanced Materials) etc. are mentioned.

(A-2) It has a polyoxyalkylene chain having an average molecular weight of 300 to 100,000, and has the general formula (1):

[In the formula, R is the same or different, and (d) a hydrogen atom, a methyl group, an ethyl group, a hydroxyethyl group, a hydroxypropyl group, (e) a substituent containing a polyoxyalkylene group, (f) a sulfoalkyl group, (g) a carboxyalkyl group, (h) a group selected from cationic substituents, Q being the same or different, an alkylene group having 2 to 4 carbon atoms, a, b and c being the same or different The number of 0-10 is shown. QO group, R group, a, b and c may be the same or different within a repeating unit or between repeating units, and when the substituents (e) to (h) have a hydroxy group, the hydroxy group May be further substituted with other substituents (e) to (h). Provided that R has at least one substituent (e).
A polysaccharide derivative having a structural unit represented by:

(A-2) is preferably a polysaccharide derivative in which part or all of the hydrogen atoms of the hydroxy group in the polysaccharide or derivative thereof are substituted with a substituent containing (e) a polyoxyalkylene group, (e) A group represented by the following general formula (6) is preferable.
-E ^1- (OA ¹ ) _q -E ² -R ⁶ (6)
Wherein, E ¹ represents a divalent saturated hydrocarbon group having 1 to 6 carbon hydroxy group or a C oxo group which may be substituted, q is a number of 8-300, q-number of A ¹ Are the same or different and represent a divalent saturated hydrocarbon group having 1 to 6 carbon atoms, E ² represents an ether bond or an oxycarbonyl group, and R ⁶ represents 4 to 4 carbon atoms that may be substituted by a hydroxy group. Represents 30 alkyl groups)

The hydrocarbon group E ¹ in the general formula (6) may be either a straight chain or branched chain having 1 to 6 carbon atoms which may be substituted by a hydroxy group or an oxo group, and preferably has 2 or 3 carbon atoms. . Specifically, ethylene group, propylene group, trimethylene group, 2-hydroxytrimethylene group, 1-hydroxymethylethylene group, 1-oxoethylene group, 1-oxotrimethylene group, 1-methyl-2-oxoethylene group, etc. Is mentioned.

The divalent hydrocarbon group A ¹ in the general formula (6) may be linear or branched having 1 to 6 carbon atoms, and preferably has 2 or 3 carbon atoms. Specific examples include an ethylene group, a propylene group, and a trimethylene group. q is the average number of repeating units of — (OA ¹ ) —, preferably 8 to 100, more preferably 10 to 60, from the viewpoint of detergency and emulsion stability, and q A may be the same or different. good. E ² represents an ether bond (—O—) or an oxycarbonyl group (—OCO— or —COO—), and an ether bond is preferred.

The long chain alkyl group R ⁶ in the general formula (6) has 4 to 30 carbon atoms, preferably 5 to 25 carbon atoms, and more preferably a linear or branched alkyl group having 6 to 20 carbon atoms. Specific examples include an octyl group, a decyl group, a dodecyl group, a tetradecyl group, a hexadecyl group, an octadecyl group, and an isostearyl group. Among these, a linear alkyl group is preferable from the viewpoints of detergency and emulsion stability.

  The degree of substitution of the group represented by the general formula (6) in the polysaccharide derivative is preferably 0.0001 to 1.0, more preferably 0.0005 to 0.5, and more preferably 0.001 per constituent monosaccharide residue. -0.1 is more preferable.

  In addition to the above substituent (e), the polysaccharide derivative (A-2) may be further substituted with one or more groups selected from the following substituents (f), (g) and (h). . Moreover, the hydrogen atom of the hydroxy group of substituent (e)-(h) may be further substituted by substituent (e)-(h).

(F) a C1-C5 sulfoalkyl group which may be substituted by a hydroxy group or a salt thereof:
Examples of the substituent (f) include 2-sulfoethyl group, 3-sulfopropyl group, 3-sulfo-2-hydroxypropyl group, 2-sulfo-1- (hydroxymethyl) ethyl group, and the like. From the viewpoint of production, a 3-sulfo-2-hydroxypropyl group is preferred. All or part of these substituents (f) may be a salt with a group 1 or group 2 element such as Na, K, Ca, Mg, an organic cation such as an amine, or ammonium. The degree of substitution with these substituents (f) is preferably 0 to 1.0, more preferably 0 to 0.8, and still more preferably 0 to 0.5 per constituent monosaccharide residue.

(G) a carboxyalkyl group having 2 to 6 carbon atoms which may be substituted by a hydroxy group or a salt thereof:
Examples of the substituent (g) include a carboxymethyl group, a carboxyethyl group, a carboxypropyl group, a carboxybutyl group, and a carboxypentyl group, and among them, a carboxymethyl group is preferable from the viewpoint of stability and production. All or part of these substituents (g) may be a salt with a group 1 or group 2 element such as Na, K, Ca or Mg, or an organic cation such as amine or ammonium. The degree of substitution with these substituents (g) is preferably from 0 to 1.0, more preferably from 0 to 0.8, and even more preferably from 0 to 0.5 per constituent monosaccharide residue.

(H) Group represented by the following general formula (7):

[Wherein D ¹ represents a linear or branched divalent saturated hydrocarbon group having 1 to 6 carbon atoms which may be substituted by a hydroxy group, and R ⁷ , R ⁸ and R ⁹ are the same or different. And a C 1-3 linear or branched alkyl group which may be substituted by a hydroxy group, and X ⁻ represents a hydroxy ion, a halogen ion or an organic acid ion. ]
D ¹ in the cationic substituent (h) is preferably one having 2 or 3 carbon atoms, and specifically, ethylene, propylene, trimethylene, 2-hydroxytrimethylene, 1-hydroxymethylethylene and the like are preferable.
Examples of R ⁷ , R ⁸ and R ⁹ in the cationic substituent (h) include a methyl group, an ethyl group, a propyl group, and a 2-hydroxyethyl group, and among them, a methyl group and an ethyl group are preferable.
Examples of the halogen ion represented by X ⁻ in the cationic substituent (h) include chlorine ion, bromine ion and iodine ion, and examples of the organic acid ion include CH ₃ COO ⁻ , CH ₃ CH ₂ COO ⁻ and CH. ₃ (CH ₂ ) ₂ COO _2- ^{and the} like. X ⁻ is preferably a hydroxy ion, a chlorine ion or a bromine ion.
The degree of substitution with these cationic substituents (h) is preferably from 0 to 0.5, more preferably from 0 to 0.3 per constituent monosaccharide residue.

As such polysaccharide derivatives, for example, those described in International Publication No. 00/73351 pamphlet and JP-A-2005-336116 can be used, and hydroxyethyl (hydroxypropyl polyethylene glycol dodecyl ether) cellulose, (Laureth-13 PG-hydroxyethyl cellulose) and the like.
(A-2) is preferably hydroxyethyl (hydroxypropyl polyethylene glycol dodecyl ether) cellulose and (laureth-13 PG-hydroxyethyl cellulose) from the viewpoint of obtaining a feeling of washing.

(A-3) General formula (2)

[In the formula, A ² is an alkylene group having 2 to 6 carbon atoms, n is an average value of 5 to 1000, p is an average value of 5 to 100, and (n × p) A ² is It may be the same or different. ]
Polyether polycarbonate having a structural unit represented by:
In the general formula (2), A ² represents an alkylene group having 2 to 6 carbon atoms, and (n × p) A ² may be the same or different, but (n × p) A ² is And preferably at least two alkylene groups. A ² is preferably an alkylene group having 2 to 4 carbon atoms, more preferably an alkylene group having 2 or 3 carbon atoms, and further preferably a mixed group of an ethylene group and a propylene group. Moreover, when it consists of different alkyleneoxy groups, these may have a block structure or a random structure, but a random structure is more preferable.

In General formula (2), n is a number of 5-1000 which shows the average added mole number of an alkyleneoxy group, and the number of 10-500 is preferable. p is a number of 5 to 100 showing an average number of repetitions of _{^{[(A 2 O) n COO}} ] group, preferably the number of 5 to 50.

  The weight average molecular weight of the polyether polycarbonate is preferably 50,000 or more, more preferably 100,000 or more, still more preferably 150,000 or more, and particularly preferably 200,000 or more from the viewpoint of detergency. From the viewpoint of detergency, 1 million or less is preferable, 700,000 or less is more preferable, and 500,000 or less is more preferable.

The polyether polycarbonate of component (A-3) can be produced, for example, by the method described in JP 2009-41004 A, and the compounds of Synthesis Examples 1, 2, and 3 in JP 2009-41004 A Can be used.
As (A-3), the compound of the synthesis example 1, 2, and 3 of Unexamined-Japanese-Patent No. 2009-41004 is preferable from the point from which a feeling of cleaning is obtained.

  As the component (A), (A-1) is preferable from the viewpoint that the cleaning power, the skin after cleaning is refreshed, and a feeling of cleaning is obtained. In (A-1), (a1), (a2) and (A A copolymer containing a3) as a structural unit and containing (a2) in a molar ratio of 10 mol% or more with respect to the total monomers is more preferable. (Acrylates / Stearless Methacrylate-20) Copolymer, (Acrylates / Steareth Methacrylate-20) Cross Even more preferred are polymers, (acrylates / Beheneth-25 methacrylate) copolymers.

  Component (A) can be used singly or in combination of two or more, and the content is preferably 0.001% by mass or more in the total composition from the viewpoint of reducing the oil remaining on the skin after washing. , 0.005% by mass or more is more preferable, 0.01% by mass or more is more preferable, 0.03% by mass or more is more preferable, and 5% by mass or less is preferable and 3% by mass or less is preferable in terms of suppressing stickiness. Is more preferable, and 2 mass% or less is still more preferable. In addition, the content of the component (A) is preferably 0.001 to 5% by mass, more preferably 0.005 to 3% by mass, still more preferably 0.01 to 2% by mass in the total composition, and 0.03 More preferably, ˜2% by mass.

  Among the components (B), examples of the (b1) ether oil include cetyl-1,3-dimethylbutyl ether, dicaprylyl ether, dicapryl ether, dilauryl ether, diisostearyl ether, and the like. Of these, cetyl-1,3-dimethylbutyl ether and dicaprylyl ether are preferred from the viewpoint that high detergency and a refreshing feeling can be obtained.

  Component (b1) can be used singly or in combination of two or more, and from the viewpoint of detergency, the content is preferably 1% by mass or more, more preferably 3% by mass or more in the total composition, 5 mass% or more is further more preferable, 50 mass% or less is preferable from the point of a refreshing feeling, 30 mass% or less is more preferable, and 15 mass% or less is further more preferable. Moreover, 1-50 mass% is preferable in the whole composition, as for content of a component (b1), 3-30 mass% is more preferable, and 5-15 mass% is further more preferable.

  In the present invention, the mass ratio (b1) / (A) of the component (A) to the component (b1) is preferably 0.5 or more, more preferably 1 or more, further preferably 2 or more, from the viewpoint of detergency. 3 or more is more preferable, and 400 or less is preferable, 300 or less is more preferable, and 200 or less is more preferable from the viewpoint of obtaining a feeling of cleaning. Moreover, 0.5-400 are preferable, as for mass ratio (b1) / (A) of a component (A) and a component (b1), 1-300 are more preferable, 2-200 are more preferable, and 3-200 are more. Further preferred.

Among the components (B), the (b2) hydrocarbon oil has a viscosity at 30 ° C. of 18 mPa · s or less, preferably 10 mPa · s or less. Here, the viscosity is measured with a BM viscometer (manufactured by Tokimec, measurement conditions: rotor No. 1, 60 rpm).
Examples of the component (b2) include liquid isoparaffins such as light liquid isoparaffin and hydrogenated polyisobutene, isododecane, and isohexadecane. Among these, light liquid isoparaffin, isododecane, and isohexadecane are preferable because high detergency and a refreshing feeling can be obtained.

  Component (b2) can be used singly or in combination of two or more, and from the viewpoint of detergency, the content is preferably 1% by mass or more, more preferably 3% by mass or more in the total composition, 4 mass% or more is further more preferable, and 50 mass% or less is preferable from the point of a refreshing feeling, 40 mass% or less is more preferable, and 30 mass% or less is further more preferable. Moreover, 1-50 mass% is preferable in the whole composition, as for content of a component (b2), 3-40 mass% is more preferable, and 4-30 mass% is further more preferable.

  In the present invention, the mass ratio (b2) / (A) of the component (A) to the component (b2) is preferably 0.5 or more, more preferably 1 or more, and even more preferably 2 or more, from the viewpoint of detergency. 400 or less are preferable, 300 or less are more preferable, and 200 or less are more preferable from the point of obtaining a feeling of washing. Moreover, 0.5-400 are preferable, as for mass ratio (b2) / (A) of a component (A) and a component (b2), 1-300 are more preferable, and 2-200 are more preferable.

In addition, in the component (B), from the viewpoint of reducing detergency and the amount of oil remaining on the skin, (b2) exceeds 35% by mass in all oils excluding (b1), and more than 40% by mass. Preferably there is.
Further, when the components (b1) and (b2) are used in combination, the mass ratio (b1) / (b2) of the components (b1) and (b2) reduces the squeaky feeling of the skin after wiping. The above is preferable, 0.1 or more is more preferable, 0.3 or more is more preferable, and 30 or less is preferable, 10 or less is more preferable, and 3.5 or less is more preferable in order to reduce the stickiness of the skin after wiping. Moreover, 0.05-30 are preferable, as for mass ratio (b1) / (b2) of a component (b1) and (b2), 0.1-10 are more preferable, and 0.3-3.5 are more preferable.

As the component (B), one or two or more selected from components (b1) and (b2) can be used. The component (B) preferably contains the component (b1), and more preferably contains both the components (b1) and (b2) at the same time.
In the case where (b1) and (b2) are used in combination, the total content is preferably 1% by mass or more, more preferably 3% by mass or more, still more preferably 4% by mass or more, and more preferably 9% by mass or more. More preferably, 50 mass% or less is preferable, 40 mass% or less is more preferable, and 30 mass% or less is further more preferable. Moreover, content of a component (B) is 1-50 mass% in all compositions in total, 3-40 mass% is more preferable, 4-30 mass% is more preferable, 9-30 mass% is total. Even more preferred.

  In the present invention, the mass ratio (B) / (A) of the component (A) to the component (B) is preferably 0.5 or more, more preferably 1 or more, and even more preferably 2 or more, from the viewpoint of detergency. 400 or less is preferable from the point of obtaining a feeling of washing, 300 or less is more preferable, and 200 or less is more preferable. Moreover, 0.5-400 are preferable, as for mass ratio (B) / (A) of a component (A) and a component (B), 1-300 are more preferable, and 2-200 are more preferable.

  In the present invention, the water of component (C) forms the balance of each component, and the content is preferably 20% by mass or more, more preferably 30% by mass or more, and further preferably 40% by mass or more in the total composition. 95 mass% or less is preferable, 90 mass% or less is more preferable, and 85 mass% or less is further more preferable.

Component (D) used in the present invention is a nonionic surfactant having HLB of 8 or more, preferably HLB of 8 to 15, and more excellent stability can be obtained.
Here, HLB is an index indicating a hydrophilic-lipophilic balance (Hydrophilic-Lypophilic Balance). In the present invention, a value calculated using the following equation by Oda and Teramura et al. Is used.

  Examples of the component (D) include polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene polyoxypropylene glycol, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxy Ethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl ether fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, (poly) alkyl glyceryl ether, etc. Is mentioned. Among these, from the viewpoint of improving stability, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and polyoxyethylene hydrogenated castor oil fatty acid ester are preferable.

  The component (D) is not contained or, when contained, can be used alone or in combination of two or more. From the viewpoint of stability, the content is 0.005 mass in the entire composition. % Or more, preferably 0.05% by weight or more, more preferably 0.1% by weight or more, less than 5% by weight, preferably 2% by weight or less, more preferably 1% by weight or less. Moreover, 0.005 mass% or more and less than 5 mass% are preferable in content of a component (D), 0.05-2 mass% is more preferable, and 0.1-1 mass% is further more preferable.

  Moreover, it is more preferable from a stability viewpoint to use a component (D) and the nonionic surfactant below HLB8 in combination. Examples of nonionic surfactants less than HLB8 include ethylene glycol fatty acid esters such as ethylene glycol monostearate, polyethylene glycol fatty acid esters such as polyethylene glycol (2) monostearate, polyethylene glycol (5) decylpentadecyl. Polyethylene glycol surfactants such as polyethylene glycol alkyl ethers such as ether, polyethylene glycol hardened castor oil such as polyethylene glycol (5) hydrogenated castor oil monopropylene; propylene glycol fatty acid ester, polypropylene glycol fatty acid ester, propylene glycol alkyl ether , Polypropylene glycol alkyl ether, ethylene oxide of propylene glycol alkyl ether Propylene glycol surfactants, such as conductors; glycerin alkyl ethers such as glycerin monoisostearyl ethers; glycerol fatty acid esters such as glycerin monoisostearate esters such as sorbitan fatty acid esters such as sorbitan monostearate ester. Of these, glycerin fatty acid ester, sorbitan fatty acid ester, and glycerin alkyl ether are preferable.

  Nonionic surfactants of less than HLB8 can be used alone or in combination of two or more, and from the viewpoint of stability, the content is not contained in the whole composition or less than 5% by mass. Preferably, 0.005 mass% or more is preferable, 0.05 mass% or more is more preferable, 0.1 mass% or more is more preferable, less than 5 mass% is preferable, and 2 mass% or less is preferable, and 1 mass is preferable. % Or less is more preferable. Moreover, 0.005 mass% or more and less than 5 mass% are preferable in the whole composition, and, as for content of the nonionic surfactant less than HLB8, 0.05-2 mass% is more preferable, 0.1-1 mass % Is more preferable.

The cleaning composition of the present invention may further contain (E) a polyol. Examples of the polyol include polyhydric alcohol, polyglycerin, polyethylene glycol, polypropylene glycol, and sugar.
More specifically, examples of the polyhydric alcohol include ethylene glycol, propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol, trimethylolpropane, and glycerin. Among these, propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol and glycerin are preferable, and 1,3-butylene glycol, propylene glycol, isoprene glycol and glycerin are points of moisturizing feeling on the skin after wiping. Is more preferable.

  Examples of polyglycerin, polyethylene glycol, and polypropylene glycol include polyglycerin having a molecular weight of 2000 or less, polyethylene glycol having a molecular weight of 10,000 or less, and polypropylene glycol having a molecular weight of 1000 or less. Among these, diglycerin, polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 1000, polyethylene glycol 1540, dipropylene glycol, polypropylene glycol (3), and polypropylene glycol (7) are from the point of moisturizing feeling of the skin after wiping. preferable.

  Examples of the saccharide include sorbitol, erythritol, pentaerythritol, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like, and alkyl glucosides having 2 or less carbon atoms in the alkyl chain are preferable. Among these, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, and polyoxypropylene methyl glucoside are preferable, and polyoxyethylene methyl glucoside and polyoxypropylene methyl glucoside are more preferable from the viewpoint of the moisturizing feeling of the skin after wiping.

  The polyol of the component (E) can be used alone or in combination of two or more, and the content is preferably from 0.1 to 30% by mass in the whole composition from the viewpoint of both moisturizing feeling and reduction in stickiness. 0.5-20 mass% is more preferable, and 1-15 mass% is still more preferable.

  The cleaning composition of the present invention can further contain (F) ethanol, and can further enhance the feeling of cleaning. (F) As for content of ethanol, 0.1-30 mass% is preferable in the whole composition, 0.5-20 mass% is more preferable, 1-15 mass% is still more preferable.

The cleaning composition of the present invention can contain, in addition to the above components, components used in ordinary cleaning compositions as long as the effects of the present invention are not impaired. For example, oil agents other than the component (B), thickeners other than the component (A), anionic surfactants, cationic surfactants, amphoteric surfactants, bactericides, anti-inflammatory agents, antiseptics, chelating agents, salts , Pearlizing agents, fragrances, cooling agents, pigments, antioxidants, plant extracts and the like.
Examples of the oil agent other than the component (B) include hydrocarbon oils such as liquid paraffin having a viscosity at 30 ° C. exceeding 18 mPa · s. Oils other than the component (B) can be used alone or in combination of two or more, and the content is preferably 0.01% by mass or more, preferably 50% by mass or less, and 40% by mass in the total composition. % Or less is more preferable, 30 mass% or less is more preferable, and 20 mass% or less is still more preferable.
It is preferable not to contain an anionic surfactant, a cationic surfactant, and an amphoteric surfactant unless they are irreversibly mixed within a range that does not inhibit the effects of the present invention.

  The cleaning composition of the present invention is obtained by uniformly mixing the copolymer of component (A) and an aqueous phase containing water, adding an alkaline agent such as sodium hydroxide or potassium hydroxide, and then neutralizing. It can manufacture by adding the component of. In the case of containing a raw material that is solid at room temperature, it can be produced by uniformly mixing all the components after heating and melting or dissolving in other components.

The cleaning composition of the present invention is suitable as a skin cleaning composition such as a facial cleanser and a cleansing agent, and a cleansing agent is more preferable. Further, it is preferably used for cleansing makeup cosmetics applied to the face.
The cleaning composition of the present invention is, for example, a method in which the composition is left as it is or shaken and homogenized, and then wiped by immersing it in cotton or the like. It can be used by a method, a method of washing by hand and washing, a method of washing by soaking in cotton or the like, a method of washing after washing, a method of washing after wiping by the above method, and the like. Furthermore, it can also be used as a form impregnated into the sheet. Moreover, the method of immersing in cotton etc. and wiping off is preferable, and the method of wiping with cotton etc. is more preferable after picking up and getting used.
This invention discloses the following compositions further regarding embodiment mentioned above.

<1> The following components (A), (B) and (C):
(A) 0.001 to 5% by mass of a polymer selected from (A-1), (A-2) and (A-3),
(A-1) a copolymer containing a monomer selected from (a1), (a2) and (a3) as a structural unit, and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers,
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) a monomer selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid;
(A-2) It has a polyoxyalkylene chain having an average molecular weight of 300 to 100,000, and has the general formula (1)

[In the formula, R is the same or different, and (d) a hydrogen atom, a methyl group, an ethyl group, a hydroxyethyl group, a hydroxypropyl group, (e) a substituent containing a polyoxyalkylene group, (f) a sulfoalkyl group, (g) a carboxyalkyl group, (h) a group selected from cationic substituents, Q being the same or different, an alkylene group having 2 to 4 carbon atoms, a, b and c being the same or different The number of 0-10 is shown. QO group, R group, a, b and c may be the same or different within a repeating unit or between repeating units, and when the substituents (e) to (h) have a hydroxy group, the hydroxy group May be further substituted with other substituents (e) to (h). Provided that R has at least one substituent (e).
A polysaccharide derivative having a structural unit represented by:
(A-3) General formula (2)

[In the formula, A ² is an alkylene group having 2 to 6 carbon atoms, n is an average value of 5 to 1000, p is an average value of 5 to 100, and (n × p) A ² is It may be the same or different. ]
A polyether polycarbonate having a structural unit represented by:
(B) 1 type or 2 types or more of oil agents chosen from (b1) and (b2) 1-50 mass%,
(B1) ether oil (b2) a hydrocarbon oil having a viscosity at 30 ° C. of 18 mPa · s or less,
(C) contains water,
(D) A detergent composition that does not contain HLB8 or more nonionic surfactant or contains less than 5% by mass.

<2> Component (A) is (A-1), and (a1), (a2) and (a3):
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) a monomer selected from polyoxyethylene alkyl ester of acrylic acid and polyoxyethylene alkyl ester of methacrylic acid,
The cleaning composition according to the above <1>, which is a copolymer containing at least 10 mol% of (a2) in a molar ratio with respect to the total monomers.

<3> Component (A) is (A-1),
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) A monomer selected from alkyl esters of acrylic acid alkyl esters and methacrylic acid alkyl esters, wherein the alkyl group preferably has 1 to 22 carbon atoms, and more preferably has 1 to 18 carbon atoms. Monomers selected from esters and alkyl methacrylates, and (a3) monomers selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid, the number of added moles of polyoxyethylene being preferably Is 10-30, more preferably 12-25, and the alkyl group of the alkyl ester is preferably 12-22 carbon atoms, more preferably 18-22 carbon atoms of polyoxyethylene alkyl acrylate. Esters and meta The detergent composition according to <1> or <2>, wherein the composition comprises a monomer selected from polyoxyethylene alkyl esters of lauric acid as a constituent unit, and is a copolymer containing (a2) in a molar ratio of 10 mol% or more based on the total monomers. object.

<4> Component (A) is (A-1),
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) A monomer selected from alkyl esters of acrylic acid alkyl esters and methacrylic acid alkyl esters, wherein the alkyl group preferably has 1 to 22 carbon atoms, and more preferably has 1 to 18 carbon atoms. Monomers selected from esters and alkyl methacrylates, and (a3) monomers selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid, acrylic acid and polyoxyethylene (20) stearyl Esters with ethers, esters of methacrylic acid and polyoxyethylene (20) stearyl ether, esters of acrylic acid and polyoxyethylene (25) behenyl ether, methacrylic acid and polyoxyethylene (25) A monomer selected from a polyoxyethylene alkyl ester of acrylic acid and a polyoxyethylene alkyl ester of methacrylic acid is preferred as an ester with henyl ether, and (a2) is contained in a molar ratio of 10 mol% or more with respect to the total monomers. The cleaning composition according to any one of <1> to <3>, wherein the cleaning composition is a copolymer.

<5> The above <1>, wherein the component (A) is selected from an (acrylates / stealeless methacrylate-20) copolymer, an (acrylates / stealemethacrylate methacrylate-20) cross-polymer, and an (acrylates / Beheneth-25 methacrylate) copolymer. The cleaning composition according to any one of <4>.
The content of <6> component (A) is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and 0.03% by mass in the total composition. % Or more is more preferable, 5 mass% or less is preferable, 3 mass% or less is more preferable, 2 mass% or less is more preferable, and content of a component (A) is 0.001-5 mass% in all compositions. Preferably, 0.005 to 3% by mass is more preferable, 0.01 to 2% by mass is more preferable, and 0.03 to 2% by mass is still more preferable. <1> to <5> Cleaning composition.

<7> Among the components (B), (b1) ether oil is preferably cetyl-1,3-dimethylbutyl ether, dicaprylyl ether, dicapryl ether, dilauryl ether, diisostearyl ether, and cetyl-1,3- The cleaning composition according to any one of <1> to <6>, wherein dimethylbutyl ether and dicaprylyl ether are more preferable.
The content of the <8> component (b1) is preferably 1% by mass or more, more preferably 3% by mass or more, further preferably 5% by mass or more, preferably 50% by mass or less, and 30% by mass in the total composition. The following is more preferable, 15% by mass or less is further preferable, and the content of the component (b1) is preferably 1 to 50% by mass in the total composition, more preferably 3 to 30% by mass, and further more preferably 5 to 15% by mass. The cleaning composition according to any one of <1> to <7>, preferably.
<9> The mass ratio (b1) / (A) of the component (A) to the component (b1) is preferably 0.5 or more, more preferably 1 or more, further preferably 2 or more, and still more preferably 3 or more, 400 or less is preferable, 300 or less is more preferable, 200 or less is more preferable, and the mass ratio (b1) / (A) of the component (A) to the component (b1) is preferably 0.5 to 400, and 1 to 300. The cleaning composition according to any one of <1> to <8>, more preferably 2 to 200, and still more preferably 3 to 200.

<10> Among the components (B), the (b2) hydrocarbon oil preferably has a viscosity at 30 ° C. of 10 mPa · s or less, according to any one of the above <1> to <9>.
<11> The component (b2) is preferably light liquid isoparaffin, hydrogenated polyisobutene, isododecane or isohexadecane, more preferably light liquid isoparaffin, isododecane or isohexadecane. Agent composition.
The content of the <12> component (b2) is preferably 1% by mass or more, more preferably 3% by mass or more, further preferably 4% by mass or more, preferably 50% by mass or less, and 40% by mass in the total composition. The following is more preferable, 30% by mass or less is further preferable, and the content of the component (b2) is preferably 1 to 50% by mass in the total composition, more preferably 3 to 40% by mass, and further more preferably 4 to 30% by mass. The cleaning composition according to any one of <1> to <11>, preferably.

<13> The mass ratio (b2) / (A) of the component (A) to the component (b2) is preferably 0.5 or more, more preferably 1 or more, further preferably 2 or more, preferably 400 or less, and 300 or less. Is more preferable, 200 or less is further preferable, and the mass ratio (b2) / (A) of the component (A) to the component (b2) is preferably 0.5 to 400, more preferably 1 to 300, and 2 to 200. The cleaning composition according to any one of <1> to <12>, which is more preferable.
The content of <14> component (b2) is preferably an amount exceeding 35% by mass in all oils excluding (b1), and more preferably 40% by mass or more <1> to <13>. The cleaning composition according to any one of the above.

<15> When the components (b1) and (b2) are used in combination, the mass ratio (b1) / (b2) of the components (b1) and (b2) is preferably 0.05 or more, more preferably 0.1 or more. 0.3 or more, more preferably 30 or less, more preferably 10 or less, still more preferably 3.5 or less, and the mass ratio (b1) / (b2) of the components (b1) and (b2) is 0. The cleaning composition according to any one of <1> to <14>, wherein 05 to 30 is preferable, 0.1 to 10 is more preferable, and 0.3 to 3.5 is more preferable.
<16> As the component (B), the total content when the components (b1) and (b2) are used in combination is preferably 1% by mass or more, more preferably 3% by mass or more, and more preferably 4% by mass or more. Is more preferably 9% by mass or more, more preferably 50% by mass or less, more preferably 40% by mass or less, still more preferably 30% by mass or less, and the total content of component (B) is in the total composition. 1-50 mass% is preferable, 3-40 mass% is more preferable, 4-30 mass% is further more preferable, 9-30 mass% is still more preferable 9 <1>-<15> in any one of the cleaning Agent composition.

<17> The mass ratio (B) / (A) of the component (A) to the component (B) is preferably 0.5 or more, more preferably 1 or more, further preferably 2 or more, preferably 400 or less, and 300 or less. Is more preferable, 200 or less is more preferable, and the mass ratio (B) / (A) of the component (A) to the component (B) is preferably 0.5 to 400, more preferably 1 to 300, and 2 to 200. The cleaning composition according to any one of <1> to <16>, which is more preferable.
<18> The cleaning composition according to any one of <1> to <17>, wherein the component (D) is preferably a nonionic surfactant having an HLB of 8 to 15.

<19> Component (D) is preferably polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene polyoxypropylene glycol, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester , Polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl ether fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, (poly) alkyl Examples include glyceryl ether, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin. Fatty acid esters, polyoxyethylene sorbitan fatty acid esters, wherein the polyoxyethylene hydrogenated castor oil fatty acid ester <1> to any one detergent composition according to <18>.
The content of the <20> component (D) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and preferably 2% by mass or less in the entire composition, and 1% by mass or less. More preferably, the content of the component (D) is preferably 0.05 to 2% by mass in the total composition, and more preferably 0.1 to 1% by mass in the above <1> to <19> The cleaning composition of any one.

<21> The cleaning composition according to any one of <1> to <20>, further comprising (E) a polyol.
<22> The polyol of component (E) is preferably a polyhydric alcohol, more preferably ethylene glycol, propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol, trimethylolpropane, glycerin, propylene glycol, The cleaning composition according to <21>, wherein isoprene glycol, 1,3-butylene glycol, hexylene glycol, and glycerin are more preferable, and 1,3-butylene glycol, propylene glycol, isoprene glycol, and glycerin are still more preferable.

<23> The polyol of component (E) is preferably polyglycerin, polyethylene glycol, or polypropylene glycol, more preferably polyglycerin having a molecular weight of 2000 or less, polyethylene glycol having a molecular weight of 10,000 or less, or polypropylene glycol having a molecular weight of 1000 or less, diglycerin, The cleaning composition according to <21>, wherein polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 1000, polyethylene glycol 1540, dipropylene glycol, polypropylene glycol (3), and polypropylene glycol (7) are more preferable.
<24> The polyol of component (E) is preferably a sugar, more preferably sorbitol, erythritol, pentaerythritol, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, and an alkyl chain having 2 carbon atoms. The following alkyl glucoside is more preferable, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside is more preferable, and polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside is more preferable <21> described above Cleaning composition.

The content of <25> component (E) is preferably from 0.1 to 30% by mass, more preferably from 0.5 to 20% by mass, and even more preferably from 1 to 15% by mass in the entire composition. The cleaning composition according to any one of <24>.
<26> The cleaning composition according to any one of <1> to <25>, further comprising (F) ethanol.
The content of <27> component (F) is preferably from 0.1 to 30% by mass, more preferably from 0.5 to 20% by mass, and even more preferably from 1 to 15% by mass in the entire composition. Cleaning composition.

Examples 1-2 and Comparative Examples 1-2
A skin cleanser composition having the composition shown in Table 1 was produced, and the detergency, clean feeling and residual oil level were evaluated. The results are also shown in Table 1.

(Production method)
At room temperature, the copolymer was added to water and stirred to mix uniformly. Thereafter, while stirring, the ether oil of component (B) was added and dispersed, and 48% potassium hydroxide was further added to obtain a skin cleansing composition.

(Evaluation method)
(1) Detergency for oily mascara:
As an oily mascara (waterproof mascara), Kose Sports Beauty Facio Powerstay Mascara (Karl Long) BK001 (trade name) 0.005 g is uniformly applied in a circular shape with a diameter of 1.2 cm on a slide glass and left for 12 hours. And dried. Approximately 2 g of each cleaning composition is evenly soaked in cosmetic cotton (Lilybell Lilanpuff / Suzuran Co., Ltd .; the same cosmetic cotton is used in the following evaluations). Wiping was performed at (7.8 kPa), and the number of wipings required to remove the mascara was measured.

(2) Cleaning feeling after wiping:
10 female panelists soaked each cleaning composition in cosmetic cotton, wiped the face with makeup cosmetics applied, and “5: good”, “4: slightly good” The sensory evaluation was performed in five stages, “3: Neither”, “2: Not good”, and “1: Not good”, and the total score of 10 people was obtained.

(3) Level of residual oil after wiping:
The forearm was washed with a dishwashing detergent (Kao, manufactured by Kao Corporation), wiped with a paper towel, and dried at room temperature for 10 minutes. About 2 g of each detergent composition is evenly soaked in commercially available cosmetic cotton, the forearm is wiped off with cosmetic cotton, and the forearm is set in a measuring device within 10 seconds. Area ratio: evaluated based on the difference between the measured value of the arm after washing with the dishwashing detergent and the measured value after this test). As the measuring apparatus, a Fourier transform infrared spectrophotometer (manufactured by Thermo Scientific) was used.

Examples 3-12, Comparative Examples 3-5
A skin cleanser composition having the composition shown in Table 2 was produced, and the cleaning power and the feeling of cleaning were evaluated in the same manner as in Examples 1 and 2. The results are also shown in Table 2.

(Production method)
At 80 ° C., the surfactant of component (D) and the polyol of component (E) were added to water as necessary, and the mixture was stirred and mixed uniformly. Thereafter, the copolymer of component (A) was added, stirred and mixed uniformly, and cooled to 30 ° C. or lower. Furthermore, the oil agent of component (B) and other oil agents were added and stirred, and 48% potassium hydroxide and a fragrance were added and stirred to obtain a skin cleansing composition.
In addition, when all the components were liquid at room temperature or the gel component was not generated by mixing at room temperature, the production was performed at room temperature.

Claims (10)

The following components (A), (B) and (C):
(A) 0.001 to 5% by mass of a polymer selected from (A-1), (A-2) and (A-3),
(A-1) a copolymer containing a monomer selected from (a1), (a2) and (a3) as a structural unit, and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers,
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) a monomer selected from polyoxyethylene alkyl esters of acrylic acid and polyoxyethylene alkyl esters of methacrylic acid;
(A-2) It has a polyoxyalkylene chain having an average molecular weight of 300 to 100,000, and has the general formula (1)

[In the formula, R is the same or different, and (d) a hydrogen atom, a methyl group, an ethyl group, a hydroxyethyl group, a hydroxypropyl group, (e) a substituent containing a polyoxyalkylene group, (f) a sulfoalkyl group, (g) a carboxyalkyl group, (h) a group selected from cationic substituents, Q being the same or different, an alkylene group having 2 to 4 carbon atoms, a, b and c being the same or different The number of 0-10 is shown. QO group, R group, a, b and c may be the same or different within a repeating unit or between repeating units, and when the substituents (e) to (h) have a hydroxy group, the hydroxy group May be further substituted with other substituents (e) to (h). Provided that R has at least one substituent (e).
A polysaccharide derivative having a structural unit represented by:
(A-3) General formula (2)

[In the formula, A ² is an alkylene group having 2 to 6 carbon atoms, n is an average value of 5 to 1000, p is an average value of 5 to 100, and (n × p) A ² is It may be the same or different. ]
A polyether polycarbonate having a structural unit represented by:
(B) 1 type or 2 types or more of oil agents chosen from (b1) and (b2) 1-50 mass%,
(B1) ether oil (b2) a hydrocarbon oil having a viscosity at 30 ° C. of 18 mPa · s or less,
(C) contains water,
(D) A detergent composition that does not contain HLB8 or more nonionic surfactant or contains less than 5% by mass. Component (A) is (A-1), and (a1), (a2) and (a3):
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) a monomer selected from an acrylic acid alkyl ester and a methacrylic acid alkyl ester,
(A3) A copolymer containing a monomer selected from polyoxyethylene alkyl ester of acrylic acid and polyoxyethylene alkyl ester of methacrylic acid as a structural unit, and containing 10 mol% or more of (a2) in a molar ratio with respect to the total monomers. Item 2. A cleaning composition according to Item 1. Component (A) is
(A1) a monomer selected from acrylic acid and methacrylic acid,
(A2) Monomer selected from alkyl acrylate and alkyl methacrylate having from 1 to 22 carbon atoms of the alkyl ester, and (a3) the added mole number of polyoxyethylene is from 10 to 30, and the alkyl group is carbon. A monomer selected from polyoxyethylene alkyl ester of acrylic acid and polyoxyethylene alkyl ester of methacrylic acid, which is formula 12-22, is contained as a structural unit, and (a2) is contained in a molar ratio of 10 mol% or more with respect to the total monomers. The cleaning composition according to claim 2, which is a copolymer. Component (A) is
(A1) acrylic acid and / or methacrylic acid,
(A2) a monomer selected from an alkyl ester of alkyl ester having 1 to 22 carbon atoms and an alkyl ester of methacrylic acid, and (a3) an ester of acrylic acid and polyoxyethylene (20) stearyl ether, methacrylic acid and Consists of a monomer selected from an ester with polyoxyethylene (20) stearyl ether, an ester of acrylic acid with polyoxyethylene (25) behenyl ether, and / or an ester of methacrylic acid with polyoxyethylene (25) behenyl ether The detergent composition according to claim 2 or 3, which is a copolymer containing a unit and containing (a2) in a molar ratio of 10 mol% or more based on the total monomers.   Component (A) is selected from (Acrylates / Stearless Methacrylic Acid-20) Copolymer, (Acrylates / Stearless Methacrylic Acid-20) Crosspolymer, and (Acrylates / Beheneth Methacrylate-25) Copolymer. The cleaning composition according to any one of the above.   The cleaning composition according to any one of claims 1 to 5, wherein the mass ratio (B) / (A) of the component (A) to the component (B) is 0.5 to 400.   The cleaning composition according to any one of claims 1 to 6, wherein the mass ratio (b1) / (b2) of the component (b1) to the component (b2) is 0.05 to 30.   The cleaning composition according to any one of claims 1 to 7, wherein the content of the component (b2) is an amount exceeding 35% by mass in the total oil excluding the component (b1).   Furthermore, the cleaning composition of any one of Claims 1-8 which contains 15 mass% or less of (E) polyol.   Furthermore, (F) The cleaning composition of any one of Claims 1-9 which contains 15 mass% or less of ethanol.