JP2014083695A - Manufacturing apparatus of a cylindrical resin molding and manufacturing method of a cylindrical resin molding - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing apparatus of a cylindrical resin molding and a manufacturing method of a cylindrical resin molding each capable of easily manufacturing a cylindrical resin molding unaccompanied by cracks.SOLUTION: The manufacturing apparatus of the present invention possesses an extrusion die 20, a sizing die 30, and a gas evacuation tube 41. The extrusion die 20 extrudes a cylindrical molten resin composition Rf toward the sizing die 30. The sizing die 30 cools the cylindrical molten resin composition Rf contacted with the outer circumferential wall surface thereof. The gas evacuation tube 41 evacuates air from a space surrounded by the extrusion die 20, sizing die 30, and cylindrical molten resin composition Rf. The space is maintained at a negative pressure. The cylindrical molten resin composition Rf is contacted homogeneously with the outer circumferential wall surface of the sizing die 30 along the circumferential direction thereof.

Description

  The present invention relates to a manufacturing apparatus for a cylindrical resin molded product and a method for manufacturing a cylindrical resin molded product.

  As an electrophotographic image forming apparatus, an image forming apparatus having a plurality of image forming units for forming toner images and an intermediate transfer member onto which the toner images formed by the respective image forming units are transferred is known. It has been. As the intermediate transfer body, an endless belt-like intermediate transfer belt is known. The intermediate transfer belt is generally manufactured by cutting a cylindrical resin molded product made of a conductive resin molded product with a desired length.

  As an apparatus for producing such a cylindrical resin molded product, for example, an extrusion die for extruding a molten resin composition into a cylindrical shape, and a cylindrical molten resin composition extruded from the extrusion die are cooled. An apparatus having a cylindrical sizing die for forming a cylindrical resin molded product is known. The sizing die is arranged apart from the extrusion die and has an outer peripheral wall that contacts the cylindrical molten resin composition extruded from the extrusion die. The sizing die cools the cylindrical molten resin composition in contact with the outer peripheral wall to generate a cylindrical resin molded product (see, for example, Patent Document 1).

JP 2011-167918 A

  The cylindrical molten resin composition extruded from the extrusion die is shaken immediately before it sticks to the outer peripheral wall of the sizing die due to the influence of the pulling force of the molten resin composition and the slight turbulence of the air current around the molten resin composition. Cheap. For this reason, the cylindrical molten resin composition may not stick uniformly to the outer peripheral wall of the sizing die in the circumferential direction. If the cylindrical molten resin composition is unevenly adhered to the outer peripheral wall of the sizing die in the circumferential direction, the molten resin composition is crystallized at the portion of the cylindrical molten resin composition that does not stick to the outer peripheral wall of the sizing die. May occur. When this crystallization occurs, when the cylindrical resin molded product is bent, a crack occurs in the crystallized portion of the cylindrical resin molded product.

  On the other hand, when the cooling temperature of the sizing die is slightly lowered, the uniformity when the cylindrical molten resin composition sticks to the outer peripheral wall of the sizing die in the circumferential direction can be improved. However, when the cooling temperature of the sizing die is lowered too much, a wavy pattern appears on the surface of the cylindrical resin molded product. For this reason, the range of the cooling temperature of the sizing die that can improve the uniformity is narrow. Therefore, it is difficult to sufficiently improve the uniformity by adjusting the cooling temperature of the sizing die.

The objective of this invention is providing the manufacturing apparatus of the cylindrical resin molding which can manufacture the cylindrical resin molding which a crack does not produce easily.
Another object of the present invention is to provide a method for producing a cylindrical resin molded product that can easily produce a cylindrical resin molded product that is not cracked.

  The present invention provides, as means for solving the above-described problems, a cylindrical resin molded product manufacturing apparatus and a cylindrical resin molded product manufacturing method shown below.

[1] An extrusion die for extruding the molten resin composition into a cylindrical shape;
It is located inside the cylindrical molten resin composition extruded from the extrusion die, has an outer peripheral wall in contact with the cylindrical molten resin composition, and while cooling the cylindrical molten resin composition in contact with the outer peripheral wall A sizing die for molding,
An apparatus for producing a cylindrical resin molded article, comprising: an extrusion die, a sizing die, and a gas exhaust mechanism for exhausting a gas in a space surrounded by the cylindrical molten resin composition from the space.
[2] The apparatus for producing a cylindrical resin molded product according to [1], wherein the maximum height roughness of the surface of the outer peripheral wall is 10 to 40 μm.
[3] A method for producing a cylindrical resin molded product using the production apparatus according to [1] or [2],
A step of extruding the molten resin composition in a cylindrical shape from the extrusion die toward the sizing die; and
Cooling the cylindrical molten resin composition extruded from the extrusion die and contacting the outer peripheral wall of the sizing die;
And a step of lowering the pressure of the space by discharging the gas in the space surrounded by the extrusion die, the sizing die, and the tubular molten resin composition by a gas exhaust mechanism.
[4] The method for producing a cylindrical resin molded product according to [3], wherein the molten resin composition contains nylon.

  In this invention, gas can be discharged | emitted from the space enclosed with an extrusion die, a sizing die, and a cylindrical molten resin composition. For this reason, the pressure of the said space falls and the cylindrical molten resin composition sticks uniformly on the outer peripheral wall of the sizing die in the circumferential direction. Therefore, it is possible to easily manufacture a cylindrical resin molded product that does not crack.

It is a figure which shows roughly the whole structure of the manufacturing apparatus of the cylindrical resin molding which concerns on one Embodiment of this invention. It is a figure which shows roughly the manufacturing apparatus of the cylindrical resin molding which concerns on one Embodiment of this invention. It is a figure which shows roughly the manufacturing apparatus of the cylindrical resin molding which concerns on other embodiment of this invention. It is a figure which shows roughly the manufacturing apparatus of the cylindrical resin molding which does not have a gas exhaust pipe. It is a figure which shows roughly the manufacturing apparatus of the cylindrical resin molding which has an adsorption member.

  The apparatus for manufacturing a cylindrical resin molded product according to the present invention includes an extrusion die, a sizing die, and a gas exhaust mechanism.

  The extrusion die extrudes the molten resin composition into a cylindrical shape. The extrusion die has a cylindrical flow path for flowing the molten resin composition. As such an extrusion die, for example, a “molding die” described in Patent Document 1 can be used.

  The sizing die cools the cylindrical molten resin composition. The sizing die has an outer peripheral wall with which the cylindrical molten resin composition extruded from the extrusion die contacts. Such a sizing die is preferably a member having a cylindrical heat transfer property, and more preferably excellent in heat transfer property. For the sizing die, for example, a sizing die described in Patent Document 1 can be used.

  The maximum height roughness (Rz) of the surface of the outer peripheral wall of the sizing die is 10 to 40 μm, from the viewpoint of obtaining a cylindrical resin molded product having a desired surface state, and the cylindrical resin on the surface of the sizing die It is preferable from the viewpoint of slipperiness of the molded product. The maximum height roughness (Rz) is represented by the sum (Zp + Zv) of the maximum peak height (Zp) and the maximum valley depth (Zv) of the contour curve at the reference length. The maximum height roughness Rz of the outer peripheral wall is obtained, for example, by blasting the outer peripheral wall surface of the sizing die.

  Of the end portions of the sizing die, it is preferable that at least the peripheral portion of the end portion on the extrusion die side is an R surface from the viewpoint of smoothly contacting the cylindrical molten resin composition and the outer peripheral surface of the sizing die. The radius of curvature of the R surface is preferably 2 to 10 mm from the above viewpoint.

  The gas exhaust mechanism exhausts the gas in the space surrounded by the extrusion die, the sizing die, and the cylindrical molten resin composition from the space. The “space gas” is usually air, but may be a gas inert to the resin composition, such as nitrogen or a rare gas. The gas exhaust mechanism is usually composed of an exhaust device and an exhaust passage communicating the space and the exhaust device. Examples of the exhaust device include a vacuum ejector and a vacuum pump.

  The exhaust passage can be arranged along the extrusion direction of the molten resin composition. Examples of the exhaust passage include a pipe that penetrates the extrusion die along the extrusion direction and a pipe that penetrates the sizing die along the extrusion direction. The diameter and number of the exhaust passages are not particularly limited, but when the exhaust passage is a pipe that penetrates the extrusion die, the diameter of the exhaust passage (from the viewpoint of achieving both the original function of the extrusion die and the function of the exhaust passage) The tube diameter is preferably 8 to 25 mm, and more preferably 10 to 20 mm. Moreover, it is preferable that the number of exhaust passages is 2-4 from the above-mentioned viewpoint.

  The apparatus for producing a cylindrical resin molded product according to the present invention may further have another configuration within a range where the effects of the present invention can be obtained. Such other configurations include, for example, an extruder for supplying the molten resin composition to the extrusion die, a refrigerant circulation mechanism for circulating the refrigerant inside and outside the sizing die, and a cylinder cooled by the sizing die Examples thereof include a take-out machine that draws the shaped resin molded product in the extrusion direction of the extrusion die, and a cutting machine that cuts the drawn tubular resin molded product with a desired length. For these other configurations, for example, a known device described in Patent Document 1 can be used.

  The manufacturing method of the cylindrical resin molding in this invention is a method of manufacturing a cylindrical resin molding using the manufacturing apparatus of this invention mentioned above.

  The production method of the present invention includes a step of extruding a molten resin composition in a cylindrical shape from an extrusion die toward a sizing die, and a cylindrical molten resin composition extruded from the extrusion die and in contact with the outer peripheral wall of the sizing die Cooling. These steps can be performed by a known method, for example, based on the matters described in Patent Document 1.

  The manufacturing method of the present invention further includes a step of lowering the pressure of the space by discharging the gas in the space surrounded by the extrusion die, the sizing die, and the cylindrical molten resin composition by the gas exhaust mechanism.

  The pressure in the space can be appropriately determined within a range in which the cylindrical molten resin composition is uniformly contacted in the circumferential direction. On the other hand, from the viewpoint of preventing the generation of streaks in the cylindrical resin molded product, the space pressure does not cause excessive constriction in the cylindrical molten resin composition positioned between the extrusion die and the sizing die. Is preferred. From such a viewpoint, the pressure in the space is preferably 0.2 to 1.5 kPa, and more preferably 0.6 to 1.4 kPa. The pressure in the space can be detected by measuring the pressure in the space or the exhaust passage. The pressure in the space can be detected and adjusted by operating the gas exhaust mechanism. Examples of the operation method of the gas exhaust mechanism include intermittent operation of the exhaust device, increase / decrease in the exhaust amount by the exhaust device, and opening / closing of the exhaust passage to the outside.

  The production method of the present invention is suitable for production of a resin molded product made of a molten resin composition that partially crystallizes due to uneven cooling. An example of such a molten resin composition is a molten resin composition containing nylon.

The production method of the present invention may further include other steps as long as the effects of the present invention are obtained. Examples of such other steps include a step of supplying a molten resin composition to an extrusion die, a step of circulating a refrigerant inside and outside of a sizing die, a step of drawing a cylindrical resin molded product in an extrusion direction, and a cylindrical shape A step of cutting the resin molded product with a desired length. These steps can be performed by a known method, for example, based on the matters described in Patent Document 1.
Hereinafter, the present invention will be further described with reference to the drawings.

  As shown in FIG. 1, the apparatus for manufacturing a cylindrical resin molded product according to the present invention includes an extruder 10, an extrusion die 20, a sizing die 30, and a gas exhaust mechanism. Below the sizing die 30, a take-up machine (not shown) that draws the cylindrical resin molded product produced by the sizing die 30 downward, and the cylindrical resin molded product below the sizing die 30 in a horizontal direction with a desired length. And a cutting machine (not shown) that cuts into two. In addition, in order to show the state of the sizing die 30 and its surroundings, the outer mandrel 22, which will be described later, the cylindrical molten resin composition Rf, and the cylindrical resin molded product that is cooled in the figure are shown in cross section. Sometimes.

  The extruder 10 includes a cylinder 11, a screw 12 accommodated in the cylinder 11, a heater 13 for heating the cylinder 11, and a vent 14 for discharging a gaseous component generated in the cylinder 11 to the outside. Have. A hopper 15 for supplying a resin material to the cylinder 11 is disposed at the upstream end of the cylinder 11. Connected to the downstream end of the cylinder 11 is a filter 16 for removing foreign substances in the molten resin material (molten resin composition). The screw 12 is connected to a motor 17 for rotating the screw 12. The motor 17 has a speed reducer (not shown), for example.

  The extrusion die 20 injects the molten resin composition into the gap between the inner mandrel 21, the outer mandrel 22 arranged coaxially with a predetermined distance from the inner mandrel 21, and the inner mandrel 21 and the outer mandrel 22. And a heater 24 that covers the peripheral surface of the outer mandrel 22. The extrusion die 20 is connected to the filter 16 of the extruder 10 via a neck 25.

  The inner mandrel 21 includes an upper cylindrical portion 21a, a die land portion 21b that is a cylindrical portion having a smaller diameter than the upper cylindrical portion 21a, and a tapered portion 21c that connects the upper cylindrical portion 21a and the die land portion 21b. The inner mandrel 21 has a resin flow path 26 on the outer peripheral surface of the upper cylindrical portion 21a. The resin flow path 26 is a groove formed on the outer peripheral surface of the upper cylindrical portion 21 a that is inclined downward from the resin injection port 23. The resin flow path 26 may be a so-called coat hanger type resin flow path in Patent Document 1.

  The outer mandrel 22 includes an upper cylindrical portion 22a that covers the peripheral surface of the upper cylindrical portion 21a, a die land portion 22b that is a cylindrical portion having a smaller diameter than the upper cylindrical portion 22a that covers the peripheral surface of the die land portion 21b, and an upper cylindrical portion 22a. It is comprised from the taper part 22c which connects the die land part 22b.

  Between the die land part 21b and the die land part 22b, there is a gap larger than the thickness of the cylindrical resin molded product to be produced, for example, a gap of about 0.8 to 3.0 mm, preferably about 0.9 to 1.2 mm. Is formed.

  The sizing die 30 is disposed away from the extrusion die 20 on the downstream side (lower side) in the extrusion direction of the extrusion die 20 (arrow X in FIG. 2). The sizing die 30 is supported by a metal fitting that passes through the central portion of the extrusion die 20 along the axial direction of the extrusion die 20. The distance between the lower end of the extrusion die 20 and the upper end of the sizing die 30 is, for example, 20 to 40 mm.

  As shown in FIG. 2, the sizing die 30 is a cylindrical member having heat conductivity. The sizing die 30 is, for example, an aluminum cylinder. The outer diameter of the sizing die 30 is usually the same as or slightly smaller than the outer diameter of the die land portion 21b. For example, the outer diameter of the sizing die 30 is determined so that the outer diameter of the sizing die 30 is 80 to 90% of the outer diameter at the lower end of the die land portion 21b (the dropping rate is 10 to 20%). Moreover, the outer diameter of the sizing die 30 can be determined according to the use of the cylindrical resin molded product.

  For example, the outer diameter of the sizing die 30 is the dimension of the peripheral length of the product (intermediate transfer belt), the shrinkage ratio of the molten resin composition, and the dimensions of the main part of the apparatus for the post-process of the cylindrical resin molded product if necessary (For example, the inner cylinder size of the shape correcting machine when the product is an intermediate transfer belt). Based on the outer diameter of the sizing die 30, the outer diameter of the die land portion 21b of the extrusion die 20 can be determined as appropriate (for example, to a value that facilitates processing and measurement) from the range of the pulling rate. In the case of manufacturing a normal intermediate transfer belt, more specifically, the outer diameter of the sizing die 30 is preferably 100 to 400 mm, and more preferably 100 to 310 mm.

  The sizing die 30 has a hollow portion 31. The hollow portion 31 is connected to a refrigerant supply pipe 32 that is inserted through the central portion of the extrusion die 20 to the bottom of the hollow portion 31 and a refrigerant discharge pipe 33 that opens to the ceiling of the hollow portion 31. The refrigerant supply pipe 32 and the refrigerant discharge pipe 33 are connected to a refrigerant tank or a refrigerant pump (not shown) having a temperature adjusting device, for example. These constitute a refrigerant circulation mechanism for circulating a refrigerant having a desired temperature through the hollow portion 31.

  The outer peripheral surface of the sizing die 30 has an appropriate surface roughness. The surface roughness of the sizing die 30 can be determined based on the desired surface state of the cylindrical resin molded product and the slipperiness of the cylindrical resin molded product on the surface of the sizing die 30. From these viewpoints, the maximum height roughness Rz of the surface of the sizing die 30 can be set to 15 to 35 μm, for example, if it is a cylindrical resin molded product for an intermediate transfer belt. Further, the peripheral portion of the outer peripheral surface of the sizing die 30 is an R surface 34. As described above, the outer peripheral surface of the sizing die 30 includes the R surfaces 34 at both ends and the straight body portion therebetween (see FIG. 2). The radius of curvature of the R surface 34 can be set to, for example, 2 to 10 mm from the viewpoint of smoothly bringing the cylindrical molten resin composition from the extrusion die 20 into contact with the outer peripheral surface of the sizing die 30.

  As shown in FIG. 2, the gas exhaust mechanism includes a gas exhaust pipe 41 that passes through the center of the extrusion die 20 and opens at the lower end of the extrusion die 20. The gas exhaust pipe 41 is connected to a vacuum ejector (not shown). Thus, the gas exhaust mechanism is constituted by the gas exhaust pipe 41 and the vacuum ejector.

  Next, a method for producing a cylindrical resin molded product using the production apparatus of the present embodiment will be described. The cylinder 11 and the extrusion die 20 of the extruder 10 are heated by heaters 13 and 24, respectively, and maintained at a temperature (for example, 300 ° C.) equal to or higher than the melting temperature of the resin composition. Further, the sizing die 30 circulates a coolant (for example, water) adjusted to a desired temperature inside and outside the hollow portion 31 to cool the tubular molten resin composition continuously extruded from the extrusion die 20. It is maintained at a suitable temperature (for example, a temperature not higher than Tg of the resin composition (eg, about 80 ° C.)). Further, the vacuum ejector (not shown) is operated at an appropriate set value (for example, so that the back pressure of the vacuum ejector is 0.2 to 1.5 kPa), and is formed between the extrusion die 20 and the sizing die 30. The gas (for example, air) in the space to be discharged is continuously discharged from the gas exhaust pipe 41.

  The material of the resin composition is supplied from the hopper 15 to the cylinder 11. The material of the resin composition is, for example, a thermoplastic resin and an additive. Each of these materials may be supplied directly to the hopper 15 or may be supplied to the hopper 15 as resin pellets obtained by kneading, cooling and granulating an additive in a thermoplastic resin.

  Examples of the thermoplastic resin include polyphenylene sulfide (PPS), polyamide (nylon), polyether sulfone, polyester, polycarbonate, and a mixture thereof. Specific examples of the polyester include, for example, polybutylene terephthalate (PBT) and polyethylene terephthalate (PET). In the production of an intermediate transfer belt, polyphenylene sulfide (PPS), polyamide (nylon), or a mixture thereof is preferably used as the thermoplastic resin.

  Examples of the additive include a conductive filler, a lubricant, and a colorant. In particular, in the case of producing an intermediate transfer belt, conductive fillers and lubricants are preferably used as additives. As the conductive filler and the lubricant, those conventionally used as the conductive filler and the lubricant in the field of the intermediate transfer belt can be used, respectively. Examples of the conductive filler include carbon black and ionic conductive liquid. Examples of the lubricant include calcium montanate, calcium stearate, and montanate ester wax.

  The material of the resin composition supplied to the cylinder 11 is melted in the cylinder 11 and kneaded by the screw 12 to become a molten resin composition. The molten resin composition is conveyed toward the extrusion die 20, and foreign matters in the molten resin composition are removed from the molten resin composition by the filter 16. The molten resin composition that has passed through the filter 16 is supplied to the extrusion die 20.

  The molten resin composition flows into the extrusion die 20 through the neck 25 and the resin injection port 23. The molten resin composition that has flowed into the extrusion die 20 flows uniformly through the resin flow path 26 to the entire circumference of the inner mandrel 21, and flows down while diffusing the cylindrical gap between the inner mandrel 21 and the outer mandrel 22. To do. Thus, a cylindrical molten resin composition-like flow is formed. The molten resin composition flows through the upper cylindrical portion 21a (upper cylindrical portion 22a), the tapered portions 21c and 22c, and the die land portions 21b and 22b, and continuously from the die land portions 21b and 22b as a cylindrical molten resin composition Rf. leak. Thus, the molten resin composition is extruded from the extrusion die 20 toward the sizing die 30 in a cylindrical shape.

  On the other hand, when the cylindrical molten resin composition Rf approaches the outer peripheral surface of the sizing die 30, the gap between the extrusion die 20 and the sizing die 30 becomes slightly negative due to the exhaust by the gas exhaust pipe 41. For this reason, the cylindrical molten resin composition Rf extruded from the extrusion die 20 uniformly contacts the outer peripheral wall (straight barrel portion) of the sizing die 30 in the circumferential direction. The molten resin composition in contact with the outer peripheral wall of the sizing die 30 becomes amorphous and becomes a cylindrical resin molded product. Thus, the extruded cylindrical molten resin composition Rf comes into contact with the outer peripheral wall of the sizing die 30 and is cooled.

  Further, when the cylindrical molten resin composition Rf comes into contact with the outer peripheral wall of the sizing die 30, the extrusion die 20, the sizing die 30, and the cylindrical molten resin composition are interposed between the extrusion die 20 and the sizing die 30. A space surrounded by Rf is formed. A gas exhaust pipe 41 is opened facing this space. Air is exhausted from the gas exhaust pipe 41 by the vacuum ejector. Set the back pressure of the vacuum ejector to an appropriate range (for example, 0.2 to 1.5 kPa) and adjust the exhaust by the gas exhaust mechanism as appropriate (for example, whether the vacuum ejector is turned on or off, the vacuum ejector and the gas exhaust pipe) 41), the pressure in the space becomes a predetermined negative pressure (for example, 0.2 to 1.5 kPa). Thus, by slightly reducing the pressure of the space from the space outside the cylindrical molten resin composition Rf, the fluctuation of the cylindrical molten resin composition Rf is reduced, and the cylindrical molten resin composition is reduced. The object Rf uniformly contacts the outer peripheral wall of the sizing die 30 in the circumferential direction. As a result, the cylindrical molten resin composition Rf is uniformly cooled in the circumferential direction by the sizing die 30 and becomes a cylindrical resin molded product.

  By the way, when the molten resin composition is made amorphous by cooling with the sizing die 30, a gaseous component derived from the resin component may be generated from the molten resin composition. The “gaseous component” is, for example, an unreacted monomer of the resin in the resin composition or a decomposition component of the resin. When this gaseous component stays in the space, for example, it may condense on the surface of the sizing die 30, adhere to the inner peripheral surface of the cylindrical resin molded product, and stain the cylindrical resin molded product. However, as described above, the air in the space is exhausted from the space by the gas exhaust pipe 41. For this reason, the gaseous component is removed from the space as the air is discharged from the space.

  The cylindrical resin molded product generated by being cooled by the sizing die 30 is taken down by the take-up machine, and is cut in the horizontal direction by the cutter as necessary. For example, the cylindrical resin molded product is inspected for contamination on the inner peripheral surface and the surface state of the outer peripheral surface, and is sent to a subsequent process, for example, mounted on an electrophotographic image forming apparatus. It becomes an endless belt-like intermediate transfer belt. The cylindrical resin molded product can be used for applications other than the intermediate transfer belt.

  In the present embodiment, a gas exhaust pipe 41 that passes through the extrusion die 20 and opens between the extrusion die 20 and the sizing die 30 is disposed. Thereby, the air in the space is discharged, and the pressure in the space is maintained at a negative pressure. For this reason, the cylindrical molten resin composition Rf extruded from the extrusion die 20 uniformly contacts the outer peripheral wall of the sizing die 30 in the circumferential direction. Therefore, crystallization in the molten resin composition is suppressed, and generation of cracks in the cylindrical resin molded product can be suppressed.

  Further, by appropriately maintaining the pressure (negative pressure) in the space, it is possible to prevent the constriction of the tubular molten resin composition Rf in the space. The prevention of the occurrence of the constriction is performed by adjusting the amount of air discharged from the space while monitoring the outer shape of the cylindrical molten resin composition during molding or within the set range of the negative pressure. be able to. Thereby, it is possible to suppress the generation of streaks in the cylindrical resin molded product.

  In addition, as shown in FIG. 5, it is effective from a viewpoint of preventing adhesion of the gaseous component to a cylindrical resin molding, if the adsorption | suction member 91 is arrange | positioned between the extrusion die 20 and the sizing die 30. FIG. The adsorbing member 91 may be the adsorbing material itself, or may be composed of an adsorbing material and a breathable container that accommodates the adsorbing material. The adsorbent is selected from those having the property of adsorbing gaseous components. Examples of the adsorbent include activated carbon, silica gel, and alumina.

[Example 1]
A cylindrical resin molded product was manufactured using a manufacturing apparatus having one gas exhaust pipe 41 shown in FIG.
The outer diameter of the die land portion 21b of the extrusion die 20 is 250 mm. The set temperature of the heater 24 of the extrusion die 20 is 300 ° C.
The sizing die 30 is made of aluminum. The outer diameter of the sizing die 30 is 240 mm. The outer peripheral wall surface of the sizing die 30 is uniformly roughened by # 46 alumina air blasting. The maximum height roughness of the outer peripheral wall surface of the sizing die 30 measured along the axial direction of the sizing die 30 (X direction in FIG. 3) is 35 to 40 μm. The radius of curvature of the R surface 34 is 10 mm. The temperature of water as a refrigerant supplied to the hollow portion 31 is 80 ° C.
The gas exhaust pipe 41 has a pipe diameter (inner diameter) of 16.1 mm.
The resin composition consists of 84.7 parts by mass of polyphenylene sulfide (E2180; manufactured by Toray Industries, Inc.), 6.0 parts by mass of nylon resin (Amilan CM1021T; manufactured by Toray Industries, Inc.), and acidic carbon black (Printex U; manufactured by Evonik Degussa) 9 3 parts by mass.

  In addition to the above conditions, air was sucked out from the gas exhaust pipe 41 using a vacuum ejector to produce a cylindrical resin molded product. The vacuum ejector was operated so that the back pressure of the vacuum ejector was in the range of 0.6 to 1.2 kPa, and a cylindrical resin molded product was obtained.

  The obtained cylindrical resin molded product was cut at a length of 1,000 mm to obtain a plurality of cut products having a size used for the intermediate transfer belt. Whether or not all of the obtained cut products (about 100) were cracked was inspected by the method shown below and evaluated according to the following criteria. The results are shown in Table 1.

The portion of the cylindrical resin molded product where cracking occurs due to crystallization during cooling is the same as other portions that are normal in appearance, and cannot be visually confirmed. For this reason, the cut product was inspected for cracks after being bent 180 ° at a plurality of locations over almost the entire surface. Based on the inspection results, the cylindrical resin molded product obtained in this example was evaluated according to the following criteria.
◯: Good (the number of cut products in which cracks are detected is 0 in all cut products obtained from one cylindrical resin molded product)
Δ: Requires determination by image confirmation (among all cut products obtained from one cylindrical resin molded product, the number of cut products in which cracks are detected is 1)
×: Production discontinued (the number of cut products in which cracks were detected was 2 or more in all cut products obtained from one cylindrical resin molded product)

  Note that “judgment based on image confirmation” means that an image is formed by an electrophotographic image forming apparatus using an appropriate number of intermediate transfer belts made from other cut products in which no cracks have been detected. In other words, it is determined whether or not image noise is included in the image, and a case where no image noise is detected in all of the inspected intermediate transfer belts is determined as a non-defective product. When image noise is detected, all cut products obtained from the cylindrical resin molded product are determined as defective products.

[Example 2]
A cylindrical resin molded product was produced in the same manner as in Example 1 except that a manufacturing apparatus having two gas exhaust pipes 41 shown in FIG. 2 was used, and a cut product was obtained. And the cylindrical resin molding was evaluated similarly to Example 1. The results are shown in Table 1.

[Comparative Example 1]
A cylindrical resin molded product was produced in the same manner as in Example 1 except that the manufacturing apparatus having no gas exhaust pipe 41 shown in FIG. 4 was used, and a cut product was obtained. And the cylindrical resin molding was evaluated similarly to Example 1. The results are shown in Table 1.

  As is clear from Table 1, in Examples 1 and 2, the occurrence of cracks in the tubular resin molded product when bent can be suppressed to a level that does not cause production problems. In particular, by increasing the back pressure of the vacuum ejector, it is possible to further suppress the occurrence of cracks in the tubular resin molded product when bent.

  According to the present invention, it is possible to manufacture a cylindrical resin molded product that does not substantially have a defect that a crack is generated when it is bent, which is difficult to find in appearance inspection. Therefore, further improvement in yield in the production of cylindrical resin moldings, further improvement in the production rate of cylindrical resin moldings, and reduction in waste due to improved yield, resulting in an environmental burden. Further reduction is expected.

DESCRIPTION OF SYMBOLS 10 Extruder 11 Cylinder 12 Screw 13, 24 Heater 14 Vent 15 Hopper 16 Filter 17 Motor 20 Extrusion die 21 Inner mandrel 21a Upper cylindrical part 21b, 22b Dyland part 21c, 22c Taper part 22 Outer mandrel 22a Upper cylindrical part 23 Resin injection port 25 Neck 26 Resin flow path 30 Sizing die 31 Hollow part 32 Refrigerant supply pipe 33 Refrigerant discharge pipe 34 R surface 41 Gas exhaust pipe 91 Adsorption member Rf Cylindrical molten resin composition

Claims (4)

An extrusion die for extruding the molten resin composition into a cylindrical shape;
The cylindrical molten resin composition is located inside the cylindrical molten resin composition extruded from the extrusion die, has an outer peripheral wall in contact with the cylindrical molten resin composition, and is in contact with the outer peripheral wall. Sizing die to mold while cooling,
An apparatus for producing a cylindrical resin molded article, comprising: the extrusion die, the sizing die, and a gas exhaust mechanism for exhausting a gas in a space surrounded by the cylindrical molten resin composition from the space.   The manufacturing apparatus of the cylindrical resin molding of Claim 1 whose maximum height roughness of the surface of the said outer peripheral wall is 10-40 micrometers. A method for producing a cylindrical resin molding using the production apparatus according to claim 1,
Extruding the molten resin composition in a cylindrical shape from the extrusion die toward the sizing die; and
Cooling the tubular molten resin composition extruded from the extrusion die and in contact with the outer peripheral wall of the sizing die; and
A step of lowering the pressure of the space by discharging the gas in the space surrounded by the extrusion die, the sizing die, and the tubular molten resin composition by the gas exhaust mechanism. Manufacturing method.   The manufacturing method of the cylindrical resin molding of Claim 3 in which a molten resin composition contains nylon.

Images