JP2014034617A5 - - Google Patents
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- JP2014034617A5 JP2014034617A5 JP2012175904A JP2012175904A JP2014034617A5 JP 2014034617 A5 JP2014034617 A5 JP 2014034617A5 JP 2012175904 A JP2012175904 A JP 2012175904A JP 2012175904 A JP2012175904 A JP 2012175904A JP 2014034617 A5 JP2014034617 A5 JP 2014034617A5
- Authority
- JP
- Japan
- Prior art keywords
- monomer component
- emulsion
- resin
- topcoat
- resin emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000178 monomer Substances 0.000 claims description 25
- 239000000839 emulsion Substances 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 125000000129 anionic group Chemical group 0.000 claims description 16
- 239000003995 emulsifying agent Substances 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims 4
- 239000002365 multiple layer Substances 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000379 polymerizing Effects 0.000 description 1
Description
本発明は、
（１） 単量体成分を乳化重合させてなるエマルション粒子を含有するトップコート用樹脂エマルションであって、前記単量体成分に対する反応性を有するアニオン性乳化剤および前記単量体成分に対する非反応性を有するアニオン性乳化剤を含有することを特徴とするトップコート用樹脂エマルション、
（２） エマルション粒子が複数層で形成され、当該複数層のうち最外層を構成する樹脂の原料が単量体成分に対する反応性を有するアニオン性乳化剤および単量体成分に対する非反応性を有するアニオン性乳化剤を含有する単量体成分である前記（１）に記載のトップコート用樹脂エマルション、
（３） 単量体成分を乳化重合させてなるエマルション粒子を含有するトップコート用樹脂エマルションを製造する方法であって、前記単量体成分に対する反応性を有するアニオン性乳化剤および前記単量体成分に対する非反応性を有するアニオン性乳化剤の存在下で前記単量体成分を乳化重合させることを特徴とするトップコート用樹脂エマルションの製造方法、
（４） 樹脂エマルションに含まれるエマルション粒子を複数層で形成させる際に、当該複数層のうち最外層を、単量体成分に対する反応性を有するアニオン性乳化剤および単量体成分に対する非反応性を有するアニオン性乳化剤の存在下で単量体成分を乳化重合させることによって形成させる前記（３）に記載のトップコート用樹脂エマルションの製造方法、
（５） 前記（１）または（２）に記載のトップコート用樹脂エマルションを含有してなる塗料用樹脂組成物、および
（６） 前記（５）に記載の塗料用樹脂組成物を含有してなる上塗り塗料。
に関する。
The present invention
(1) A resin emulsion topcoat containing Rue Marushon particles with the monomer component is emulsion polymerization, non against anionic emulsifier and the monomer component reactive with the monomer component topcoat resin emulsion which is characterized that you containing anionic emulsifiers having reactive,
(2) the emulsion particles are formed of a plurality of layers, the non-reactivity to anionic emulsifiers and single-mer component material of the resin constituting the outermost layer has a reactivity to the monomer component of the plurality of layers The resin emulsion for topcoats according to (1) above, which is a monomer component containing an anionic emulsifier ,
(3) A method for producing a resin emulsion for topcoat containing emulsion particles obtained by emulsion polymerization of a monomer component, the anionic emulsifier having reactivity with the monomer component and the monomer component Top method of manufacturing coated resin emulsion, wherein in presence of anionic emulsifiers be emulsified polymerizing the monomer component having a non-reactivity to,
(4) When the emulsion particles contained in the resin emulsion are formed in a plurality of layers, the outermost layer of the plurality of layers is an anionic emulsifier having reactivity to the monomer component and non-reactivity to the monomer component. The method for producing a resin emulsion for top coat according to (3), wherein the monomer component is formed by emulsion polymerization in the presence of an anionic emulsifier,
(5) The resin composition for coatings containing the resin emulsion for topcoats as described in said (1) or (2), and
(6) A top coating composition comprising the coating resin composition according to (5).
About.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012175904A JP2014034617A (en) | 2012-08-08 | 2012-08-08 | Coating resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012175904A JP2014034617A (en) | 2012-08-08 | 2012-08-08 | Coating resin composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017087878A Division JP6853726B2 (en) | 2017-04-27 | 2017-04-27 | Resin composition for paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014034617A JP2014034617A (en) | 2014-02-24 |
| JP2014034617A5 true JP2014034617A5 (en) | 2015-12-10 |
Family
ID=50283802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012175904A Pending JP2014034617A (en) | 2012-08-08 | 2012-08-08 | Coating resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2014034617A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6693705B2 (en) * | 2015-03-31 | 2020-05-13 | 株式会社日本触媒 | Method for producing aqueous resin dispersion |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU3708797A (en) * | 1997-08-04 | 1999-03-01 | Nippon Bee Chemical Co. Ltd. | Emulsion and process for preparing the same |
| JP2002012816A (en) * | 2000-06-30 | 2002-01-15 | Nippon Paint Co Ltd | Aqueous coating material composition |
| JP3940297B2 (en) * | 2002-02-06 | 2007-07-04 | 株式会社日本触媒 | Aqueous resin dispersion and method for producing the same |
| JP3901000B2 (en) * | 2002-04-19 | 2007-04-04 | Ｊｓｒ株式会社 | Aqueous dispersion |
| JP2005281339A (en) * | 2004-03-26 | 2005-10-13 | Nippon Shokubai Co Ltd | Resin particle dispersion, method for producing the same and application thereof |
| JP2008133361A (en) * | 2006-11-28 | 2008-06-12 | Dainippon Toryo Co Ltd | Resin composition |
| JP5468741B2 (en) * | 2008-02-18 | 2014-04-09 | 株式会社日本触媒 | Water-based resin composition and paint for building exterior topcoat containing the same |
| JP2010059379A (en) * | 2008-09-08 | 2010-03-18 | Asahi Kasei Chemicals Corp | Highly durable acrylic emulsion |
| JP5468802B2 (en) * | 2009-03-25 | 2014-04-09 | 株式会社日本触媒 | Aqueous paint composition and topcoat paint |
| JP5588885B2 (en) * | 2010-01-20 | 2014-09-10 | 株式会社日本触媒 | Aqueous resin composition for architectural paints |
| JP5627928B2 (en) * | 2010-05-28 | 2014-11-19 | 株式会社日本触媒 | Aqueous resin composition and method for producing the same |
-
2012
- 2012-08-08 JP JP2012175904A patent/JP2014034617A/en active Pending
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