JP2014022325A - Power storage device and secondary battery - Google Patents

Power storage device and secondary battery Download PDF

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JP2014022325A
JP2014022325A JP2012162948A JP2012162948A JP2014022325A JP 2014022325 A JP2014022325 A JP 2014022325A JP 2012162948 A JP2012162948 A JP 2012162948A JP 2012162948 A JP2012162948 A JP 2012162948A JP 2014022325 A JP2014022325 A JP 2014022325A
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separator
positive electrode
negative electrode
electrode
holes
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JP5974704B2 (en
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Atsushi Minamigata
厚志 南形
Motoaki Okuda
元章 奥田
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

PROBLEM TO BE SOLVED: To laminate a positive electrode and a negative electrode constituting a multilayer electrode assembly so that the lamination position of a positive electrode and a negative electrode is not misaligned, without narrowing a current path in a tub.SOLUTION: A secondary battery 10 has a multilayer electrode assembly 12, and a positive electrode 17 and a negative electrode 19 have bodies 17a, 19a including active material layers 17b, 19b, and tubs 17c projecting from the bodies, respectively. The positive electrode 17 is housed in a bag-shaped separator 21 while projecting the tub 17c from the body, and the separator 21 is formed larger than the bodies 17a, 19a. The separator 21 has two holes 21a at positions closer to the tub 17c side than the position facing the body 17a, and the negative electrode 19 has two holes 19f facing the hole 21a in the active material non-coated portion 19d. The positive electrode 17, negative electrode 19 and separator 21 are configured so that they can be positioned in a state where the a positioning rod is inserted into the holes 21a, 19f when assembling the electrode assembly 12.

Description

本発明は、蓄電装置及び二次電池に係り、詳しくは積層型の電極組立体を有する蓄電装置及び二次電池に関する。   The present invention relates to a power storage device and a secondary battery, and more particularly to a power storage device and a secondary battery having a stacked electrode assembly.

二次電池やキャパシタのような蓄電装置は再充電が可能であり、繰り返し使用することができるため電源として広く利用されている。積層型の二次電池は、略矩形状の正極と負極とをセパレータが間に介在する状態で交互に積層した構造の電極組立体を有し、正極及び負極のそれぞれのタブを対応する正極端子あるいは負極端子に接続した構成となっている。積層された正極シート、セパレータ及び負極シートの間で位置ずれが生じると、正極シートと負極シートとが短絡したり、電池の性能が低下したりする。   Power storage devices such as secondary batteries and capacitors are widely used as power sources because they can be recharged and can be used repeatedly. A stacked secondary battery has an electrode assembly having a structure in which a substantially rectangular positive electrode and negative electrode are alternately stacked with a separator interposed therebetween, and a positive electrode terminal corresponding to each tab of the positive electrode and the negative electrode Or it has the structure connected to the negative electrode terminal. When misalignment occurs between the stacked positive electrode sheet, separator, and negative electrode sheet, the positive electrode sheet and the negative electrode sheet are short-circuited or the performance of the battery is degraded.

そのため、電極組立体の製造工程において、正極と負極とをセパレータが間に介在する状態で精度良く積層する必要があり、積層位置がずれないように、例えば、カメラで位置を検出して一枚ずつ積層するため積層に時間とコストがかかる。また、正極、負極及びセパレータの周縁と当接する位置決めピン等で位置決めしながら一枚ずつ積層していく方法もある。しかし、リチウムイオン二次電池では、正極が負極より小さいため、位置決めピンでは精度良く位置決めすることができない。そこで、正極と負極の大きさが異なっていたとしても積層ずれを防止して、正極及び負極を精度良く位置決めする方法が提案されている(特許文献1参照)。   Therefore, in the manufacturing process of the electrode assembly, it is necessary to stack the positive electrode and the negative electrode with high accuracy with the separator interposed therebetween. Lamination is time consuming and expensive. There is also a method of laminating one by one while positioning with a positioning pin or the like that contacts the periphery of the positive electrode, the negative electrode, and the separator. However, in the lithium ion secondary battery, since the positive electrode is smaller than the negative electrode, the positioning pin cannot accurately position. Therefore, a method has been proposed in which even if the positive electrode and the negative electrode are different in size, the misalignment is prevented and the positive electrode and the negative electrode are accurately positioned (see Patent Document 1).

特許文献1の方法では、正極及び負極は、位置決め用の孔を有するタブが正極あるいは負極の重心線に対して線対称に配置されている。そして、位置決め用の孔が軸に挿通された状態で、正極及び負極をタブの部分で吊り下げて位置決めを行う。   In the method of Patent Document 1, the positive electrode and the negative electrode have tabs having positioning holes arranged symmetrically with respect to the center line of the positive electrode or the negative electrode. Then, in a state where the positioning hole is inserted through the shaft, the positive electrode and the negative electrode are suspended at the tab portion to perform positioning.

特開2011−165620号公報JP 2011-165620 A

特許文献1の方法では、タブを正極あるいは負極の重心線に対して線対称の位置に設ける必要があり、正極及び負極のタブ同士が接触しないようにするためには、正極及び負極の少なくとも一方は、タブを2箇所に設ける必要がある。また、タブが1箇所では、タブの孔の部分で吊り下げて位置決めを行う場合に、回転方向の規制を行うためにはタブを2箇所に設ける必要がある。   In the method of Patent Document 1, it is necessary to provide tabs at positions symmetrical with respect to the center line of the positive electrode or the negative electrode. In order to prevent the positive and negative electrode tabs from contacting each other, at least one of the positive electrode and the negative electrode Requires two tabs. In addition, in the case where the tab is provided at one place, it is necessary to provide the tab at two places in order to regulate the rotational direction when the positioning is performed by hanging at the hole portion of the tab.

金属箔のタブに孔を形成すると、タブの強度が弱くなり、正極あるいは負極を吊り下げる際にタブが損傷し易い。また、金属箔のタブを正極端子あるいは負極端子に電気的に接続する場合、溶接した方が電気抵抗を低減できるが、タブに孔があいていると電流の経路が狭くなる。   If a hole is formed in the tab of the metal foil, the strength of the tab becomes weak, and the tab is easily damaged when the positive electrode or the negative electrode is suspended. Further, when the metal foil tab is electrically connected to the positive electrode terminal or the negative electrode terminal, the electric resistance can be reduced by welding, but if the tab has a hole, the current path becomes narrow.

本発明は、前記の問題に鑑みてなされたものであって、その目的は、積層型の電極組立体を構成する正極及び負極の積層位置がずれないように積層することができ、しかも、タブを流れる電流経路を狭くすることがない蓄電装置及び二次電池を提供することにある。   The present invention has been made in view of the above problems, and the object thereof is to allow lamination so that the lamination positions of the positive electrode and the negative electrode constituting the laminated electrode assembly do not deviate, and the tab. It is an object of the present invention to provide a power storage device and a secondary battery that do not narrow a current path flowing through the battery.

前記の目的を達成するため、請求項1に記載の発明は、正極及び負極が両者の間にセパレータが介在する状態で積層された積層型の電極組立体を有する蓄電装置である。そして、前記正極及び前記負極は、活物質層を有する本体部及び前記本体部から突出するタブを有し、前記セパレータは、前記正極及び前記負極の前記本体部より大きく形成されるとともに、少なくとも2個の孔を有する。前記正極及び前記負極は前記セパレータに包まれた状態又は単独の状態で、前記セパレータを介して反対の電極の前記活物質層が対向するように配置されている。前記正極及び前記負極は、前記本体部に前記セパレータの前記孔と対向する位置に孔を有し、前記正極、前記負極及び前記セパレータは、前記電極組立体の組立時に前記孔が位置決め棒に挿通された状態で位置決め可能に構成されている。ここで、「単独の状態」とはセパレータに包まれていない状態を指す。また、「セパレータに包まれた」とは、タブの突出側を除いた辺が接合されて袋状のセパレータに正極あるいは負極の本体部が収容されている状態に限らず、セパレータがシートを二つ折りにして形成され、かつシートの折り曲げ部と反対側の辺が接合されたものや、2枚のシートが対向する2辺で接合されたセパレータに収容されていてもよい。   In order to achieve the above object, an invention according to claim 1 is a power storage device having a stacked electrode assembly in which a positive electrode and a negative electrode are stacked with a separator interposed therebetween. The positive electrode and the negative electrode have a main body portion having an active material layer and a tab protruding from the main body portion, and the separator is formed larger than the main body portion of the positive electrode and the negative electrode, and at least 2 With one hole. The positive electrode and the negative electrode are arranged so that the active material layer of the opposite electrode is opposed through the separator in a state of being wrapped in the separator or in a single state. The positive electrode and the negative electrode have a hole in the body portion at a position facing the hole of the separator, and the positive electrode, the negative electrode, and the separator are inserted into the positioning rod when the electrode assembly is assembled. It is configured so that positioning can be performed in the state. Here, the “single state” refers to a state where the separator is not wrapped. The phrase “wrapped in the separator” is not limited to the state in which the sides excluding the protruding side of the tab are joined and the main body of the positive electrode or the negative electrode is accommodated in the bag-shaped separator. The sheet may be folded and may be accommodated in a separator in which the side opposite to the bent portion of the sheet is joined, or in a separator in which two sheets are joined on two opposite sides.

この発明では、電極組立体として、正極及び負極のいずれもがセパレータに包まれた状態のものと、正極及び負極の一方がセパレータに包まれた状態のものと、正極及び負極のいずれもセパレータに包まれていないものの4種類がある。そして、正極及び負極を両者の間にセパレータが介在する状態に積層する際に、セパレータが有する孔及び本体部が有する孔を位置決め用に使用して積層することにより、積層型の電極組立体を構成する正極及び負極の積層位置がずれないように積層することができる。具体的には、位置決め棒に孔が挿入された状態で正極、セパレータ及び負極が吊り下げられた後、それらが位置決め棒に沿って寄せ集められて積層体となる。蓄電装置の状態では、タブに孔が形成されていないため、タブを流れる電流経路が狭くならない。したがって、積層型の電極組立体を構成する正極及び負極の積層位置がずれないように積層することができ、しかも、タブを流れる電流経路を狭くすることがない蓄電装置及び二次電池を提供することができる。   In the present invention, as the electrode assembly, both the positive electrode and the negative electrode are encased in the separator, the positive electrode and the negative electrode are encased in the separator, and both the positive electrode and the negative electrode are in the separator. There are four types of unwrapped. Then, when laminating the positive electrode and the negative electrode in a state in which the separator is interposed between them, the hole of the separator and the hole of the main body are laminated for positioning, thereby stacking the electrode assembly. The positive electrode and the negative electrode can be stacked so that the stacked positions do not shift. Specifically, after the positive electrode, the separator, and the negative electrode are suspended with the holes inserted in the positioning rods, they are gathered along the positioning rods to form a laminate. In the state of the power storage device, since the hole is not formed in the tab, the current path flowing through the tab is not narrowed. Accordingly, there are provided a power storage device and a secondary battery that can be stacked so that the stacked positions of the positive electrode and the negative electrode constituting the stacked electrode assembly are not shifted and the current path flowing through the tab is not narrowed. be able to.

請求項2に記載の発明は、請求項1に記載の発明において、前記正極及び前記負極の少なくとも一方は、前記タブが前記セパレータから突出する状態で前記セパレータに包まれている。正極及び負極のいずれもセパレータで包まれていない場合は、正極、負極及びセパレータの枚数の回数、それらを位置決め棒に挿通する作業を行う必要がある。しかし、正極及び負極の少なくとも一方が、セパレータに包まれている場合は、それらを位置決め棒に挿通する回数が約2/3になり、工数が低減される。   According to a second aspect of the present invention, in the first aspect of the present invention, at least one of the positive electrode and the negative electrode is wrapped in the separator with the tab protruding from the separator. When neither the positive electrode nor the negative electrode is wrapped with the separator, it is necessary to perform the work of inserting the number of the positive electrode, the negative electrode, and the separator into the positioning rod. However, when at least one of the positive electrode and the negative electrode is wrapped in the separator, the number of times of inserting them through the positioning rod is about 2/3, and the man-hour is reduced.

請求項3に記載の発明は、請求項1又は請求項2に記載の発明において、前記セパレータ及び前記孔を有する本体部には、前記タブが間に位置するように切り込みが形成されている。セパレータや本体部が有する孔を利用して積層時に位置決めを行う構成で、正極又は負極がセパレータに包まれた構成の場合、セパレータはタブの基端を覆った状態であるため、タブが突出する側の辺に孔が形成されている場合は、少なくとも孔を設けるスペースの分、本体部やセパレータがタブの突出側に長くなる。そのため、電極組立体が蓄電装置のケース内に収容される構成では、ケースにその分のデッドスペースが必要になる。しかし、切り込みが形成されている場合は、孔が形成された部分を折り曲げることにより、
わざわざデッドスペースを設ける必要がなくなる。その際、タブは折り曲げる必要がなく、タブ同士を重ねて導電部材に電気的に接合するために支障を来さない。
According to a third aspect of the present invention, in the first or second aspect of the present invention, a notch is formed in the main body portion having the separator and the hole so that the tab is positioned therebetween. In the configuration in which positioning is performed at the time of stacking using the holes of the separator and the main body, in the configuration where the positive electrode or the negative electrode is wrapped in the separator, the tab protrudes because the separator covers the base end of the tab. When a hole is formed on the side, the main body and the separator become longer on the protruding side of the tab by at least the space for providing the hole. Therefore, in the configuration in which the electrode assembly is accommodated in the case of the power storage device, the corresponding dead space is required in the case. However, when the cut is formed, by bending the part where the hole is formed,
It is no longer necessary to provide a dead space. At that time, the tabs do not need to be bent, and the tabs are overlapped to be electrically joined to the conductive member without causing any trouble.

請求項4に記載の発明は、請求項1〜請求項3のいずれか一項に記載の発明において、前記孔は2個である。孔が2個の場合は、孔を3個以上設ける場合に比べて、製造時の工数を低減することができる。   The invention according to claim 4 is the invention according to any one of claims 1 to 3, wherein the number of the holes is two. When the number of holes is two, the number of man-hours during manufacturing can be reduced as compared with the case where three or more holes are provided.

請求項5に記載の発明は、請求項1〜請求項4のいずれか一項に記載の発明において、前記正極のみが前記セパレータに包まれている。リチウムイオン二次電池では、デンドライトと呼ばれるリチウムの針状物の析出を抑制するため、負極が正極より大きく形成される場合が多い。その場合、負極をセパレータで包むと、セパレータが同じ大きさだと、負極はセパレータに包まれない場合より小さくなり、電極組立体の大きさが同じ場合、電池の容量が小さくなる。即ち、正極がセパレータで包まれている方が容量的に有利である。   The invention according to claim 5 is the invention according to any one of claims 1 to 4, wherein only the positive electrode is encased in the separator. In lithium ion secondary batteries, the negative electrode is often formed larger than the positive electrode in order to suppress precipitation of lithium needles called dendrites. In that case, when the negative electrode is wrapped with a separator, if the separator is the same size, the negative electrode is smaller than when the separator is not wrapped, and if the size of the electrode assembly is the same, the capacity of the battery is reduced. That is, it is advantageous in terms of capacity that the positive electrode is wrapped with the separator.

請求項6に記載の発明は、請求項1〜請求項5のいずれか一項に記載の発明において、前記正極及び前記負極は前記タブが前記電極組立体の同じ側に突出し、前記孔は前記タブが突出している側に形成されている。セパレータは正極と負極との短絡を避けるための代を有し、正極及び負極より大きく形成される。代は孔が形成されない辺にもある。そのため、タブが突出している側に孔が形成されれば、代のスペースの一部を、孔を形成するスペースに利用することにより、結果として電極組立体の小型化に寄与する。   The invention according to claim 6 is the invention according to any one of claims 1 to 5, wherein the positive electrode and the negative electrode have the tab protruding on the same side of the electrode assembly, and the hole is the The tab is formed on the protruding side. The separator has a margin for avoiding a short circuit between the positive electrode and the negative electrode, and is formed larger than the positive electrode and the negative electrode. There is also a side where no hole is formed. Therefore, if the hole is formed on the side where the tab protrudes, a part of the substitute space is used as the space for forming the hole, thereby contributing to the miniaturization of the electrode assembly.

請求項7に記載の発明は、請求項1〜請求項6のいずれか一項に記載の発明において、前記本体部及び前記セパレータは矩形状で、短辺側に前記孔が形成されている。電極の大きさが同じ場合、電極が有する活物質層の面積が大きい方が二次電池の容量が大きくなる。本体部に形成される活物質層の形状は矩形が一般的であり、孔は活物質が塗布されていない部分に形成される。そのため、同じ大きさの本体部で、孔を本体部の短辺側に形成した方が、長辺側に形成した場合に比べて、活物質層の面積が大きくなる。   The invention according to claim 7 is the invention according to any one of claims 1 to 6, wherein the main body portion and the separator have a rectangular shape, and the hole is formed on the short side. When the size of the electrode is the same, the capacity of the secondary battery increases as the area of the active material layer included in the electrode increases. The active material layer formed on the main body generally has a rectangular shape, and the holes are formed in portions where no active material is applied. Therefore, the area of the active material layer is larger when the hole is formed on the short side of the main body with the main body having the same size as compared with the case where the hole is formed on the long side.

請求項8に記載の発明は、請求項1〜請求項7のいずれか一項に記載の蓄電装置の構成を備えた二次電池である。したがって、この発明の二次電池は請求項1〜請求項7のいずれか一項に記載の発明と同様の効果を有する。   The invention according to claim 8 is a secondary battery including the configuration of the power storage device according to any one of claims 1 to 7. Therefore, the secondary battery of the present invention has the same effect as that of any one of the first to seventh aspects.

本発明によれば、積層型の電極組立体を構成する正極及び負極の積層位置がずれないように積層することができ、しかも、タブを流れる電流経路を狭くすることがない蓄電装置及び二次電池を提供することができる。   According to the present invention, it is possible to stack the positive electrode and the negative electrode constituting the stacked electrode assembly so that the stacked positions of the positive electrode and the negative electrode do not shift, and the power storage device and the secondary device that do not narrow the current path flowing through the tab A battery can be provided.

(a)は二次電池の断面図、(b)は(a)のB−B線で切断した導電部材と電極組立体との関係を示す模式部分拡大断面図。(A) is sectional drawing of a secondary battery, (b) is a typical partial expanded sectional view which shows the relationship between the electrically-conductive member cut | disconnected by the BB line of (a), and an electrode assembly. (a)はセパレータに包まれた正極の正面図、(b)は負極の正面図。(A) is a front view of the positive electrode wrapped in the separator, (b) is a front view of the negative electrode. (a)は正極、負極及びセパレータ積層方法を示す概略斜視図、(b)は位置決め棒と孔の大きさの関係を示す模式図。(A) is a schematic perspective view which shows a positive electrode, a negative electrode, and the separator lamination | stacking method, (b) is a schematic diagram which shows the relationship between the size of a positioning rod and a hole. 別の実施形態の電極組立体の正面図。The front view of the electrode assembly of another embodiment. 別の実施形態の電極組立体の正面図。The front view of the electrode assembly of another embodiment. 別の実施形態の二次電池の断面図。Sectional drawing of the secondary battery of another embodiment. 別の実施形態の電極組立体のタブと孔との関係を示す概略正面図。The schematic front view which shows the relationship between the tab and hole of the electrode assembly of another embodiment. 別の実施形態の正極、負極及びセパレータの関係を示す概略斜視図。The schematic perspective view which shows the relationship between the positive electrode of another embodiment, a negative electrode, and a separator.

以下、本発明を蓄電装置としての二次電池に具体化した一実施形態を図1〜図3にしたがって説明する。
図1(a)に示すように、蓄電装置としての二次電池10は、ケース本体11a及び蓋11bで構成されたケース11内に収容された積層型の電極組立体12を有する。蓋11bには正極端子13及び負極端子14が絶縁リング15を介して固定されている。正極端子13及び負極端子14は、雄ねじ部13a,14aを有し、蓋11bから突出する雄ねじ部13a,14aに螺合するナット16により、蓋11bに締め付け固定されている。なお、ナット16と蓋11bとの間には図示しない絶縁部材が介装されている。
Hereinafter, an embodiment in which the present invention is embodied in a secondary battery as a power storage device will be described with reference to FIGS.
As shown in FIG. 1A, a secondary battery 10 as a power storage device includes a stacked electrode assembly 12 housed in a case 11 constituted by a case body 11a and a lid 11b. A positive electrode terminal 13 and a negative electrode terminal 14 are fixed to the lid 11 b via an insulating ring 15. The positive electrode terminal 13 and the negative electrode terminal 14 have male screw portions 13a and 14a, and are fastened and fixed to the lid 11b by nuts 16 screwed into the male screw portions 13a and 14a protruding from the lid 11b. An insulating member (not shown) is interposed between the nut 16 and the lid 11b.

電極組立体12は、正極のタブ17cの積層体17pが正極用の導電部材18を介して正極端子13に電気的に接続されており、負極のタブ19cの積層体19nが負極用の導電部材20を介して負極端子14に電気的に接続されている。積層体17pは導電部材18に溶接され、積層体19nは導電部材20に溶接されている。図1(b)に示すように、積層体17pは各タブ17cの先端側が電極組立体12の端面と平行に延びる状態で導電部材18に溶接されている。また、積層体19nも同様に、各タブ19cの先端側が電極組立体12の端面と平行に延びる状態で導電部材20に溶接されている。   In the electrode assembly 12, the laminate 17 p of the positive electrode tab 17 c is electrically connected to the positive electrode terminal 13 through the positive electrode conductive member 18, and the laminate 19 n of the negative electrode tab 19 c is electrically connected to the negative electrode. It is electrically connected to the negative electrode terminal 14 through 20. The laminated body 17p is welded to the conductive member 18, and the laminated body 19n is welded to the conductive member 20. As shown in FIG. 1B, the laminated body 17 p is welded to the conductive member 18 in a state where the tip end side of each tab 17 c extends in parallel with the end face of the electrode assembly 12. Similarly, the laminated body 19n is welded to the conductive member 20 so that the tip side of each tab 19c extends in parallel with the end face of the electrode assembly 12.

図1(b)に示すように、電極組立体12は、正極17及び負極19が両者の間にセパレータ21が介在する状態で積層されている。図1(a),(b)及び図2(a)に示すように、正極17は、金属箔22の両面に活物質層17bを有する本体部17a及び本体部17aから突出するタブ17cを有する。図1(b)及び図2(b)に示すように、負極19は、金属箔22の両面に活物質層19bを有する本体部19a及び本体部19aから突出するタブ19cを有する。本体部17a,19aは矩形状に形成され、矩形の一方の長辺からタブ17c,19cがそれぞれ突出している。   As shown in FIG. 1B, the electrode assembly 12 is laminated with a positive electrode 17 and a negative electrode 19 with a separator 21 interposed therebetween. As shown in FIGS. 1A, 1B, and 2A, the positive electrode 17 has a main body portion 17a having an active material layer 17b on both surfaces of the metal foil 22, and a tab 17c protruding from the main body portion 17a. . As shown in FIGS. 1B and 2B, the negative electrode 19 has a main body portion 19a having an active material layer 19b on both surfaces of a metal foil 22, and a tab 19c protruding from the main body portion 19a. The main body portions 17a and 19a are formed in a rectangular shape, and tabs 17c and 19c protrude from one long side of the rectangle.

図1(a)及び図2(a)に示すように、セパレータ21も矩形状に形成され、セパレータ21は、正極17及び負極19の本体部17a,19aより大きく形成されている。正極17はタブ17cがセパレータ21から突出する状態でセパレータ21に包まれている。この実施形態では、セパレータ21はタブ17cが突出する側が開放された袋状に形成されている。即ち、この実施形態では、電極組立体12は、正極17を収容した袋状のセパレータ21と、負極19とが交互に積層されることにより、正極17及び負極19が両者の間にセパレータ21が介在する状態で積層されている。セパレータ21は、周縁に、正極17と負極19との短絡を避けるための代21dを有する。   As shown in FIGS. 1A and 2A, the separator 21 is also formed in a rectangular shape, and the separator 21 is formed larger than the main body portions 17 a and 19 a of the positive electrode 17 and the negative electrode 19. The positive electrode 17 is wrapped in the separator 21 with the tab 17 c protruding from the separator 21. In this embodiment, the separator 21 is formed in a bag shape in which the side from which the tab 17c protrudes is opened. That is, in this embodiment, the electrode assembly 12 includes a bag-like separator 21 containing the positive electrode 17 and a negative electrode 19 which are alternately stacked, so that the positive electrode 17 and the negative electrode 19 are interposed between the separator 21 and the negative electrode 19. They are stacked in an intervening state. The separator 21 has a margin 21 d at the periphery for avoiding a short circuit between the positive electrode 17 and the negative electrode 19.

セパレータ21は2個の孔21aを有し、孔21aは円形で、本体部17aと対向する位置より開放側の両端に形成されている。セパレータ21には、正極17のタブ17cが間に位置するように切り込み21bが形成されている。また、負極19のタブ19cが間に位置するように切り込み21cが形成されている。切り込み21b,21cはタブ17c,19cの突出方向に延びるように、セパレータ21内に収容された正極17の本体部17aよりセパレータ21の開放側に形成されている。   The separator 21 has two holes 21a. The holes 21a are circular and are formed at both ends on the open side from the position facing the main body portion 17a. The separator 21 is formed with a cut 21b so that the tab 17c of the positive electrode 17 is located therebetween. In addition, a notch 21c is formed so that the tab 19c of the negative electrode 19 is located therebetween. The notches 21b and 21c are formed on the opening side of the separator 21 from the main body portion 17a of the positive electrode 17 accommodated in the separator 21 so as to extend in the protruding direction of the tabs 17c and 19c.

図2(b)に示すように、負極19は本体部19aがセパレータ21と同じ大きさに形成されている。負極19の活物質層19bはタブ19cの突出方向の長さが正極17の活物質層17bと同じに形成され、活物質層19bの面積は正極17の活物質層17bの面積より大きく形成されている。負極19は、タブ19cの突出側に活物質層19bの辺に沿って延びる活物質非塗布部19dを有する。   As shown in FIG. 2B, the negative electrode 19 has a main body portion 19 a having the same size as the separator 21. The active material layer 19b of the negative electrode 19 is formed so that the length of the tab 19c in the protruding direction is the same as the active material layer 17b of the positive electrode 17, and the area of the active material layer 19b is larger than the area of the active material layer 17b of the positive electrode 17. ing. The negative electrode 19 has an active material non-coated portion 19d extending along the side of the active material layer 19b on the protruding side of the tab 19c.

負極19の活物質非塗布部19dには、セパレータ21の切り込み21b,21cと対応する位置にそれぞれ切り込み19eが形成されている。また、活物質非塗布部19dの両端には、セパレータ21の孔21aと対応する位置に孔19fを有する。孔19fは円形で孔21aと同じ大きさに形成されている。   In the active material non-applied portion 19d of the negative electrode 19, cuts 19e are formed at positions corresponding to the cuts 21b and 21c of the separator 21, respectively. Further, at both ends of the active material non-application portion 19d, holes 19f are provided at positions corresponding to the holes 21a of the separator 21. The hole 19f is circular and has the same size as the hole 21a.

次に、電極組立体12の製造方法を説明する。製造方法は正極17が収容された袋状のセパレータ21と、負極19とを正極17及び負極19の活物質層17b,19bの位置関係が精度良く位置決めされた状態で積層する積層工程が従来と異なるため、積層工程について主に説明する。   Next, a method for manufacturing the electrode assembly 12 will be described. The manufacturing method is a conventional stacking process in which the bag-like separator 21 containing the positive electrode 17 and the negative electrode 19 are stacked with the positive electrode 17 and the active material layers 17b, 19b of the negative electrode 19 positioned accurately. Since it is different, the lamination process will be mainly described.

積層工程では、図3(a)に示すように、水平に所定間隔で平行に配置された一対の位置決め棒30を使用する。位置決め棒30は断面円形で、図3(b)に示すように、位置決め棒30の直径は負極19及びセパレータ21の孔19f,21aの直径より小さく形成されている。   In the laminating step, as shown in FIG. 3A, a pair of positioning rods 30 that are horizontally arranged in parallel at a predetermined interval are used. The positioning rod 30 has a circular cross section, and the diameter of the positioning rod 30 is smaller than the diameter of the holes 19f and 21a of the negative electrode 19 and the separator 21, as shown in FIG.

そして、別の工程で製造された、正極17が収容されたセパレータ21及び負極19を孔21a,19fが位置決め棒30に挿通される状態で交互に、位置決め棒30に吊り下げる。所定枚数のセパレータ21及び負極19が吊り下げられた状態で、セパレータ21及び負極19を両側から、位置決め棒30に沿って移動させて寄せ集め、積層体にする。積層体は、図示しない治具で把持された状態で溶接工程に搬送される。溶接工程ではすでに正極端子13に溶接された導電部材18に、タブ17cの積層体17pが溶接され、負極端子14に溶接された導電部材20に、タブ19cの積層体19nが溶接されて電極組立体12が完成する。   Then, the separator 21 and the negative electrode 19 in which the positive electrode 17 is accommodated, which are manufactured in another process, are alternately suspended from the positioning rod 30 with the holes 21 a and 19 f being inserted into the positioning rod 30. In a state where a predetermined number of separators 21 and negative electrodes 19 are suspended, the separators 21 and the negative electrodes 19 are moved from both sides along the positioning rods 30 and gathered to form a laminate. The laminate is transported to the welding process in a state of being gripped by a jig (not shown). In the welding process, the laminated body 17p of the tab 17c is welded to the conductive member 18 already welded to the positive electrode terminal 13, and the laminated body 19n of the tab 19c is welded to the conductive member 20 welded to the negative electrode terminal 14. The solid 12 is completed.

次に前記のように構成された二次電池10の作用を説明する。
二次電池10は、単体でも使用されるが、一般には複数の二次電池10が直列あるいは並列に接続されて構成された組電池として使用される。そして、二次電池10は種々の用途に使用されるが、例えば、車両に搭載されて走行用モータの電源や他の電気機器の電源としても使用される。 走行用モータの電源に使用した場合、大電流での充・放電が必要になる。従来技術のように電極とセパレータとの積層の際の位置決め用の孔をタブに形成した場合は、タブを流れる電流の経路が狭くなり、発熱し易くなる。しかし、この実施形態の電極組立体12は、負極19とセパレータ21との積層の際の位置決め用に使用可能な孔19f,21aはタブ17c、19cには形成されず、負極19の活物質非塗布部19d及びセパレータ21に形成されているため、タブ17c、19cを流れる電流の経路が狭くならず、発熱が抑制される。また、電極組立体12は、正極17が袋状のセパレータ21に収容されているため、車両の走行中、二次電池10に振動が加わって、セパレータ21と負極19とが多少位置ずれしても、短絡が生じることは回避される。
Next, the operation of the secondary battery 10 configured as described above will be described.
Although the secondary battery 10 is used alone, it is generally used as an assembled battery in which a plurality of secondary batteries 10 are connected in series or in parallel. The secondary battery 10 is used for various applications. For example, the secondary battery 10 is mounted on a vehicle and used as a power source for a traveling motor or a power source for other electrical devices. When used as a power source for a motor for traveling, charging / discharging with a large current is required. When the positioning holes for laminating the electrodes and separators are formed in the tab as in the prior art, the path of the current flowing through the tab is narrowed and heat is easily generated. However, in the electrode assembly 12 of this embodiment, the holes 19f and 21a that can be used for positioning when the negative electrode 19 and the separator 21 are stacked are not formed in the tabs 17c and 19c. Since the coating portion 19d and the separator 21 are formed, the path of the current flowing through the tabs 17c and 19c is not narrowed, and heat generation is suppressed. Further, in the electrode assembly 12, since the positive electrode 17 is accommodated in the bag-shaped separator 21, vibration is applied to the secondary battery 10 while the vehicle is running, and the separator 21 and the negative electrode 19 are slightly displaced. However, the occurrence of a short circuit is avoided.

この実施形態によれば、以下に示す効果を得ることができる。
(1)二次電池10は、正極17及び負極19が両者の間にセパレータ21が介在する状態で積層された積層型の電極組立体12を有する蓄電装置である。正極17及び負極19は、活物質層17b,19bを有する本体部17a,19a及び本体部17a,19aから突出するタブ17c,19cを有し、正極17はタブ17cがセパレータ21から突出する状態でセパレータ21に包まれている。セパレータ21は正極17の本体部17aと対向する位置より開放側の両端に2個の孔21aを有する。負極19は本体部19aの活物質非塗布部19dにセパレータ21の孔21aと対向する位置に孔19fを有し、正極17、負極19及びセパレータ21は、電極組立体12の組立時に孔19f,21aが位置決め棒30に挿通された状態で位置決め可能に構成されている。したがって、積層型の電極組立体12を構成する正極17及び負極19の積層位置がずれないように積層することができ、しかも、余分なタブの形成が不要で、タブ17c,19cを流れる電流経路を狭くすることがない。また、正極17及び負極19のいずれもセパレータ21で包まれていない場合は、電極組立体12の製造工程において、正極17、負極19及びセパレータ21の枚数の回数、それらを位置決め棒30に挿通する作業を行う必要がある。しかし、正極17が、セパレータ21に包まれているため、それらを位置決め棒30に挿通する回数が約2/3になり、工数が低減される。
According to this embodiment, the following effects can be obtained.
(1) The secondary battery 10 is a power storage device having a stacked electrode assembly 12 in which a positive electrode 17 and a negative electrode 19 are stacked with a separator 21 interposed therebetween. The positive electrode 17 and the negative electrode 19 have main body portions 17 a and 19 a having active material layers 17 b and 19 b and tabs 17 c and 19 c protruding from the main body portions 17 a and 19 a, and the positive electrode 17 is in a state where the tab 17 c protrudes from the separator 21. It is wrapped in a separator 21. The separator 21 has two holes 21 a at both ends on the open side from the position facing the main body portion 17 a of the positive electrode 17. The negative electrode 19 has a hole 19f at a position facing the hole 21a of the separator 21 in the active material non-application portion 19d of the main body 19a. The positive electrode 17, the negative electrode 19, and the separator 21 are formed in the holes 19f, 21a is configured to be able to be positioned in a state of being inserted through the positioning rod 30. Therefore, the positive electrode 17 and the negative electrode 19 constituting the multilayer electrode assembly 12 can be stacked so that the positions of the positive electrode 17 and the negative electrode 19 do not deviate, and there is no need to form an extra tab, and the current path flows through the tabs 17c and 19c. Is not narrowed. When neither the positive electrode 17 nor the negative electrode 19 is wrapped with the separator 21, the number of the positive electrode 17, the negative electrode 19, and the separator 21 is inserted into the positioning rod 30 in the manufacturing process of the electrode assembly 12. Need to do work. However, since the positive electrode 17 is wrapped in the separator 21, the number of times of inserting the positive electrode 17 through the positioning rod 30 is about 2/3, and the number of man-hours is reduced.

(2)正極17がセパレータ21に包まれている。リチウムイオン二次電池では、デンドライトと呼ばれるリチウムの針状物の析出を抑制するため、負極19が正極17より大きく形成される場合が多い。その場合、負極19をセパレータ21で包むと、セパレータ21が同じ大きさだと、負極19はセパレータ21に包まれない場合より小さくなり、電極組立体12の大きさが同じ場合、二次電池10の容量が小さくなる。しかし、この実施形態では正極17がセパレータ21に包まれているため、容量的に有利である。   (2) The positive electrode 17 is wrapped in the separator 21. In a lithium ion secondary battery, the negative electrode 19 is often formed larger than the positive electrode 17 in order to suppress precipitation of lithium needles called dendrites. In that case, when the negative electrode 19 is wrapped with the separator 21, if the separator 21 has the same size, the negative electrode 19 becomes smaller than when not wrapped with the separator 21, and when the size of the electrode assembly 12 is the same, Capacity is reduced. However, in this embodiment, since the positive electrode 17 is wrapped in the separator 21, it is advantageous in terms of capacity.

(3)セパレータ21にはタブ17c,19cが間に位置するようにそれぞれ一対の切り込み21b,21cが形成され、負極19の活物質非塗布部19dには、セパレータ21の切り込み21b,21cと対応する位置にそれぞれ切り込み19eが形成されている。セパレータ21はタブ17c,19cの基端を覆った状態であり、タブ17c,19cが突出する側の辺に孔21aが形成されているため、少なくとも孔21aを設けるスペースの分、セパレータ21がタブ17c,19cの突出側に長くなる。切り込み21b,21cが無い場合は、電極組立体12がケース11内に収容される構成では、ケース11にその分のデッドスペースが必要になる。しかし、切り込み21b,21cが形成されているため、タブ17c,19c同士を重ねて導電部材18,20に電気的に接合することに支障を来さずに、孔21aが形成された部分を折り曲げることにより、わざわざデッドスペースを設ける必要がなくなる。   (3) The separator 21 is formed with a pair of cuts 21b and 21c so that the tabs 17c and 19c are positioned between them. The active material non-applied portion 19d of the negative electrode 19 corresponds to the cuts 21b and 21c of the separator 21. A cut 19e is formed at each position. The separator 21 is in a state of covering the base ends of the tabs 17c and 19c, and the hole 21a is formed on the side on which the tabs 17c and 19c protrude. Therefore, the separator 21 is a tab at least for the space for providing the hole 21a. It becomes longer on the protruding side of 17c and 19c. In the case where the notches 21b and 21c are not provided, in the configuration in which the electrode assembly 12 is accommodated in the case 11, a corresponding dead space is required in the case 11. However, since the notches 21b and 21c are formed, the portions where the holes 21a are formed are bent without hindering the electrical connection to the conductive members 18 and 20 by overlapping the tabs 17c and 19c. This eliminates the need to provide a dead space.

(4)セパレータ21及び負極19は、孔21a,19fをそれぞれ2個有する。孔21a,19fが2個の場合は、孔21a,19fをそれぞれ3個以上設ける場合に比べて、製造時の工数を低減することができる。   (4) The separator 21 and the negative electrode 19 each have two holes 21a and 19f. When the number of holes 21a and 19f is two, the number of man-hours at the time of manufacture can be reduced compared with the case where three or more holes 21a and 19f are provided.

(5)正極17及び負極19はタブ17c,19cが電極組立体12の同じ側に突出し、孔21a,19fはタブ17c,19cが突出している側に形成されている。セパレータ21は正極17と負極19との短絡を避けるための代21dを有し、正極17及び負極19より大きく形成される。代21dは孔21aが形成されない辺にもある。そのため、タブ17c,19cが突出している側に孔21aが形成されれば、代21dの一部を、孔21aを形成するスペースに利用することが可能になり、結果として電極組立体12の小型化に寄与する。   (5) The positive electrode 17 and the negative electrode 19 have tabs 17c and 19c projecting on the same side of the electrode assembly 12, and the holes 21a and 19f are formed on the side from which the tabs 17c and 19c project. The separator 21 has a margin 21 d for avoiding a short circuit between the positive electrode 17 and the negative electrode 19, and is formed larger than the positive electrode 17 and the negative electrode 19. The margin 21d is also on the side where the hole 21a is not formed. Therefore, if the hole 21a is formed on the side where the tabs 17c and 19c project, a part of the allowance 21d can be used as a space for forming the hole 21a. As a result, the electrode assembly 12 can be reduced in size. Contributes to

(6)電極組立体12の製造方法において、正極17、負極19及びセパレータ21を精度良く位置決めされた状態で積層する方法として、負極19及びセパレータ21を、孔19f,21aを介して位置決め棒30に吊り下げる方法が採用されている。そして、位置決め棒30の断面形状及び孔19f,21aが円形で、孔19f,21aは、位置決め棒30の断面形状より大きく形成されている。位置決め棒30の断面形状が多角形で、孔19f,21aが同じ大きさの多角形の場合、孔19f,21aが正確に所定の位置に形成されていれば、位置決めは精度良く行われる。しかし、一対の多角形の中心位置が正確でも、多角形が目的の位置に対して多少傾いて形成されると、孔19f,21aを位置決め棒30に挿通させる際に孔19f,21aが損傷する。また、孔19f,21aが多角形の場合、金属箔22製の活物質非塗布部19dに形成された孔19fは、僅かの力で角部に亀裂が入り易い。しかし、この実施形態では、孔19fが円形のため、亀裂が入り難い。そして、位置決め棒30が孔19f,21aより小さな直径の円形のため、孔19f,21aを位置決め棒30に挿入し易く、しかも吊り下げることで正確に位置決めを行うことができる。   (6) In the method of manufacturing the electrode assembly 12, as a method of laminating the positive electrode 17, the negative electrode 19 and the separator 21 in a state where they are accurately positioned, the negative electrode 19 and the separator 21 are positioned through the holes 19f and 21a. The method of suspending is used. The sectional shape of the positioning rod 30 and the holes 19f and 21a are circular, and the holes 19f and 21a are formed larger than the sectional shape of the positioning rod 30. In the case where the cross-sectional shape of the positioning rod 30 is a polygon and the holes 19f and 21a are polygons having the same size, if the holes 19f and 21a are accurately formed at predetermined positions, positioning is performed with high accuracy. However, even if the center positions of the pair of polygons are accurate, if the polygons are formed with a slight inclination with respect to the target position, the holes 19f and 21a are damaged when the holes 19f and 21a are inserted through the positioning rod 30. . When the holes 19f and 21a are polygonal, the holes 19f formed in the active material non-application portion 19d made of the metal foil 22 are easily cracked at the corners with a slight force. However, in this embodiment, since the hole 19f is circular, it is difficult to crack. Since the positioning rod 30 has a circular shape with a smaller diameter than the holes 19f and 21a, the holes 19f and 21a can be easily inserted into the positioning rod 30 and can be accurately positioned by being suspended.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
○ 本体部17a,19a及びセパレータ21が矩形状の場合、図4に示すように、短辺側に孔19f,21aを有してもよい。電極の大きさが同じ場合、電極が有する活物質層の面積が大きい方が二次電池10の容量が大きくなる。本体部17a,19aに形成される活物質層17b,19bの形状は矩形が一般的であり、孔19fは活物質非塗布部19dに形成される。そのため、同じ大きさの本体部19aで、孔19fを本体部19aの短辺側に形成した方が、長辺側に形成した場合に比べて、活物質層17b,19bの面積が大きくなる。
The embodiment is not limited to the above, and may be embodied as follows, for example.
When the main body portions 17a and 19a and the separator 21 are rectangular, as shown in FIG. 4, holes 19f and 21a may be provided on the short side. When the size of the electrode is the same, the capacity of the secondary battery 10 increases as the area of the active material layer included in the electrode increases. The active material layers 17b and 19b formed in the main body portions 17a and 19a are generally rectangular in shape, and the holes 19f are formed in the active material non-application portion 19d. Therefore, the area of the active material layers 17b and 19b is larger when the hole 19f is formed on the short side of the main body 19a with the main body 19a having the same size as compared with the case where the hole 19f is formed on the long side.

○ 本体部17a,19a及びセパレータ21が矩形状の場合、活物質非塗布部19dを矩形の短辺側に設けて、タブ17c,19cも短辺側から突出させてもよい。
○ 図5に示すように、孔19f,21aはタブ17c,19cの突出側と反対側の辺に設けてもよい。しかし、負極19及びセパレータ21の外形が同じ場合、タブ17c,19cの突出側に設ける方が、二次電池10の容量の観点からは有利になる。
When the main body portions 17a and 19a and the separator 21 are rectangular, the active material non-applied portion 19d may be provided on the short side of the rectangle, and the tabs 17c and 19c may also protrude from the short side.
As shown in FIG. 5, the holes 19f and 21a may be provided on the side opposite to the protruding side of the tabs 17c and 19c. However, when the negative electrode 19 and the separator 21 have the same external shape, it is advantageous from the viewpoint of the capacity of the secondary battery 10 to be provided on the protruding side of the tabs 17c and 19c.

○ 正極17を袋状のセパレータ21に収容する代わりに、負極19を袋状のセパレータ21に収容してもよい。この場合、正極17は活物質層17bに沿って活物質非塗布部を有し、その活物質非塗布部に孔が設けられる。一方、負極19は活物質層19bを有さずにタブ19cが本体部19aから突出する。   O Instead of accommodating the positive electrode 17 in the bag-shaped separator 21, the negative electrode 19 may be accommodated in the bag-shaped separator 21. In this case, the positive electrode 17 has an active material non-application part along the active material layer 17b, and a hole is provided in the active material non-application part. On the other hand, the negative electrode 19 does not have the active material layer 19b, and the tab 19c protrudes from the main body 19a.

○ 正極17あるいは負極19がセパレータ21に包まれている構成としては、正極17あるいは負極19が袋状のセパレータ21に収容された構成に限らない。例えば、セパレータ21がシートを二つ折りにして形成され、かつシートの折り曲げ部と反対側の辺が接合されたものや、2枚のシートが対向する2辺で接合されたセパレータ21に収容されていてもよい。   The configuration in which the positive electrode 17 or the negative electrode 19 is wrapped in the separator 21 is not limited to the configuration in which the positive electrode 17 or the negative electrode 19 is accommodated in the bag-shaped separator 21. For example, the separator 21 is formed by folding a sheet in two and the side opposite to the folded portion of the sheet is joined, or the two sheets are accommodated in the separator 21 joined at two opposite sides. May be.

○ 正極17及び負極19を共にセパレータ21に包まれている構成にしてセパレータ21にのみ孔21aを設けてもよい。この場合、正極17及び負極19に孔を形成する必要がなく、金属箔22に孔を形成する必要がない。   O The positive electrode 17 and the negative electrode 19 may be both enclosed in the separator 21, and the hole 21 a may be provided only in the separator 21. In this case, it is not necessary to form holes in the positive electrode 17 and the negative electrode 19, and it is not necessary to form holes in the metal foil 22.

○ 電極組立体12の積層体17pと導電部材18との溶接及び積層体19nと導電部材20との溶接は、積層体17p及び積層体19nの先端側を電極組立体12の端面に沿って屈曲させた状態で行わずに、図6に示すように、積層体17p及び積層体19nの先端側が蓋11bに向かって延びる状態で行ってもよい。   The welding of the laminated body 17p of the electrode assembly 12 and the conductive member 18 and the welding of the laminated body 19n and the conductive member 20 are performed by bending the leading end side of the laminated body 17p and the laminated body 19n along the end surface of the electrode assembly 12. As shown in FIG. 6, it may be performed in a state in which the leading ends of the stacked body 17p and the stacked body 19n extend toward the lid 11b.

○ 図7に示すように、正極17のタブ17cと負極19のタブ19cとが電極組立体12の異なる端部から突出する構成にしてもよい。この構成は、例えば、ラミネート型の二次電池で採用される。   As shown in FIG. 7, the tab 17 c of the positive electrode 17 and the tab 19 c of the negative electrode 19 may protrude from different ends of the electrode assembly 12. This configuration is employed in, for example, a laminate type secondary battery.

○ 正極17及び負極19のいずれもセパレータ21に包まれている構成にせずに、図8に示すように、正極17、負極19及びシート状のセパレータ21を交互に積層する構成にしてもよい。正極17及び負極19はそれぞれ活物質非塗布部17d,19dを備え、活物質非塗布部17d,19dはそれぞれセパレータ21の孔21aと対応する位置に孔17f,19fを有する。正極17、負極19及びセパレータ21はそれぞれ切り込み17e,19e,21b,21cを有する。この場合、セパレータ21の孔21aが正極17及び負極19の孔17f,19fより小さい方が、正極17と負極19との電気的絶縁性を確保するのに好ましい。   Instead of the configuration in which both the positive electrode 17 and the negative electrode 19 are wrapped in the separator 21, the positive electrode 17, the negative electrode 19, and the sheet-like separator 21 may be alternately stacked as illustrated in FIG. 8. The positive electrode 17 and the negative electrode 19 include active material non-applied portions 17d and 19d, respectively, and the active material non-applied portions 17d and 19d have holes 17f and 19f at positions corresponding to the holes 21a of the separator 21, respectively. The positive electrode 17, the negative electrode 19, and the separator 21 have cuts 17e, 19e, 21b, and 21c, respectively. In this case, it is preferable that the hole 21 a of the separator 21 is smaller than the holes 17 f and 19 f of the positive electrode 17 and the negative electrode 19 in order to ensure electrical insulation between the positive electrode 17 and the negative electrode 19.

○ 活物質非塗布部17d,19d及びセパレータ21の切り込み17e,19e,21b,21cは必須ではなく、省略してもよい。
○ 正極17あるいは負極19に孔17f,19fを設ける場合、活物質層17b,19bに孔17f,19fを設けてもよい。その場合、孔17f,19fはセパレータ21の孔21aより小さく形成する方が、セパレータ21による正極17と負極19との電気的絶縁を確保し易い。
O The active material non-application parts 17d, 19d and the notches 17e, 19e, 21b, 21c of the separator 21 are not essential and may be omitted.
When holes 17f and 19f are provided in the positive electrode 17 or the negative electrode 19, the holes 17f and 19f may be provided in the active material layers 17b and 19b. In that case, it is easier to ensure electrical insulation between the positive electrode 17 and the negative electrode 19 by the separator 21 if the holes 17 f and 19 f are formed smaller than the hole 21 a of the separator 21.

○ タブ17c,19cが電極組立体12の同じ側に突出する構成の場合、両タブ17c,19cが線対称の位置に配置される必要はない。例えば、タブ17cを正極17の幅方向の中央に設け、タブ19cは負極19が電極組立体12を構成した状態でタブ17cと干渉しない位置に設けてもよい。   In the case where the tabs 17c and 19c protrude on the same side of the electrode assembly 12, the tabs 17c and 19c do not need to be arranged at line-symmetric positions. For example, the tab 17 c may be provided at the center in the width direction of the positive electrode 17, and the tab 19 c may be provided at a position where the negative electrode 19 does not interfere with the tab 17 c in a state where the electrode assembly 12 is configured.

○ 位置決め棒30の断面形状及び孔19f,21aの形状は円形に限らず、三角形、四角形等の多角形や楕円等であってもよい。
○ セパレータ21や正極17あるいは負極19に設けられる孔21a,17f,19fは少なくとも2個あればよく、2個に限らず3個以上設けてもよい。しかし、2個の方が、製造の工数などの点で好ましい。
The cross-sectional shape of the positioning rod 30 and the shapes of the holes 19f and 21a are not limited to a circle, and may be a polygon such as a triangle or a rectangle, an ellipse, or the like.
O There are at least two holes 21a, 17f, and 19f provided in the separator 21, the positive electrode 17, or the negative electrode 19, and the number is not limited to two, and three or more holes may be provided. However, two are preferable in terms of manufacturing man-hours and the like.

○ 蓄電装置は、二次電池10に限らず、例えば、電気二重層キャパシタやリチウムイオンキャパシタ等のようなキャパシタであってもよい。
以下の技術的思想(発明)は前記実施形態から把握できる。
The power storage device is not limited to the secondary battery 10 and may be a capacitor such as an electric double layer capacitor or a lithium ion capacitor.
The following technical idea (invention) can be understood from the embodiment.

(1)正極及び負極の一方がセパレータに包まれた状態で、前記正極及び前記負極が交互に積層された積層型の電極組立体の製造方法であって、
前記セパレータには前記セパレータに包まれた前記正極及び前記負極の一方と重ならない位置に少なくとも2個の孔を形成し、前記セパレータに包まれない前記正極及び前記負極の他方には前記セパレータの孔に対応する位置に少なくとも2個の孔を形成し、前記少なくとも2個の孔の間隔で平行に配置された位置決め棒に対して、前記セパレータを前記少なくとも2個の孔において吊り下げる操作と、前記セパレータに包まれない前記正極及び前記負極の他方を前記少なくとも2個の孔において吊り下げる操作とを交互に行って、予め設定された所定の数の前記セパレータと、前記セパレータに包まれない前記正極及び前記負極の他方とを前記位置決め棒に前記孔において吊り下げ、吊り下げられた前記セパレータと、前記セパレータに包まれない前記正極及び前記負極の他方とを前記位置決め棒に沿って移動させて寄せ集める積層工程を備えている積層型の電極組立体の製造方法。
(1) A manufacturing method of a stacked electrode assembly in which one of a positive electrode and a negative electrode is wrapped in a separator, and the positive electrode and the negative electrode are alternately stacked,
At least two holes are formed in the separator so as not to overlap one of the positive electrode and the negative electrode enclosed by the separator, and the other of the positive electrode and the negative electrode not enclosed by the separator is provided with a hole of the separator. And an operation of suspending the separator in the at least two holes with respect to a positioning rod arranged in parallel at an interval of the at least two holes, A predetermined number of the separators set in advance and the positive electrode not wrapped in the separator are alternately performed by suspending the other of the positive electrode and the negative electrode not wrapped in the separator in the at least two holes. And the other of the negative electrodes are suspended from the positioning rods in the holes, and the suspended separators are wrapped in the separators. The positive electrode and the negative electrode of the other of the manufacturing method of the positioning rod moved so Intention collect a stacked electrode assembly comprising a laminating step along the no.

10…蓄電装置としての二次電池、12…電極組立体、17…正極、17a,19a…本体部、17b,19b…活物質層、17c,19c…タブ、17e,19e,21b,21c…切り込み、17f,19f,21a…孔、19…負極、21…セパレータ、30…位置決め棒。   DESCRIPTION OF SYMBOLS 10 ... Secondary battery as an electrical storage device, 12 ... Electrode assembly, 17 ... Positive electrode, 17a, 19a ... Main part, 17b, 19b ... Active material layer, 17c, 19c ... Tab, 17e, 19e, 21b, 21c ... Notch 17f, 19f, 21a ... holes, 19 ... negative electrode, 21 ... separator, 30 ... positioning rod.

Claims (8)

正極及び負極が両者の間にセパレータが介在する状態で積層された積層型の電極組立体を有する蓄電装置であって、
前記正極及び前記負極は、活物質層を有する本体部及び前記本体部から突出するタブを有し、
前記セパレータは、前記正極及び前記負極の前記本体部より大きく形成されるとともに、少なくとも2個の孔を有し、
前記正極及び前記負極は前記セパレータに包まれた状態又は単独の状態で、前記セパレータを介して反対の電極の前記活物質層が対向するように配置され、
前記正極及び前記負極は、前記本体部に前記セパレータの前記孔と対向する位置に孔を有し、前記正極、前記負極及び前記セパレータは、前記電極組立体の組立時に前記孔が位置決め棒に挿通された状態で位置決め可能に構成されていることを特徴とする蓄電装置。
A power storage device having a stacked electrode assembly in which a positive electrode and a negative electrode are stacked with a separator interposed therebetween,
The positive electrode and the negative electrode have a main body part having an active material layer and a tab protruding from the main body part,
The separator is formed larger than the main body of the positive electrode and the negative electrode, and has at least two holes,
The positive electrode and the negative electrode are arranged so that the active material layers of the opposite electrode face each other through the separator in a state of being wrapped in the separator or in a single state,
The positive electrode and the negative electrode have a hole in the body portion at a position facing the hole of the separator, and the positive electrode, the negative electrode, and the separator are inserted into the positioning rod when the electrode assembly is assembled. A power storage device, wherein the power storage device is configured so that positioning is possible.
前記正極及び前記負極の少なくとも一方は、前記タブが前記セパレータから突出する状態で前記セパレータに包まれている請求項1に記載の蓄電装置。   The power storage device according to claim 1, wherein at least one of the positive electrode and the negative electrode is wrapped in the separator with the tab protruding from the separator. 前記セパレータ及び前記孔を有する本体部には、前記タブが間に位置するように切り込みが形成されている請求項1又は請求項2に記載の蓄電装置。   The power storage device according to claim 1, wherein the main body portion having the separator and the hole is formed with a cut so that the tab is positioned therebetween. 前記孔は2個である請求項1〜請求項3のいずれか一項に記載の蓄電装置。   The power storage device according to any one of claims 1 to 3, wherein the number of the holes is two. 前記正極のみが前記セパレータに包まれている請求項1〜請求項4のいずれか一項に記載の蓄電装置。   The power storage device according to any one of claims 1 to 4, wherein only the positive electrode is encased in the separator. 前記正極及び前記負極は前記タブが前記電極組立体の同じ側に突出し、前記孔は前記タブが突出している側に形成されている請求項1〜請求項5のいずれか一項に記載の蓄電装置。   The electricity storage according to any one of claims 1 to 5, wherein the positive electrode and the negative electrode have the tab protruding on the same side of the electrode assembly, and the hole is formed on a side on which the tab protrudes. apparatus. 前記本体部及び前記セパレータは矩形状で、短辺側に前記孔が形成されている請求項1〜請求項6のいずれか一項に記載の蓄電装置。   The power storage device according to any one of claims 1 to 6, wherein the main body portion and the separator are rectangular, and the hole is formed on a short side. 請求項1〜請求項7のいずれか一項に記載の蓄電装置の構成を備えた二次電池。   The secondary battery provided with the structure of the electrical storage apparatus as described in any one of Claims 1-7.
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