JP2014019867A - Lubricating oil composition for fluid dynamic pressure bearing and motor for hdd using the same - Google Patents

Lubricating oil composition for fluid dynamic pressure bearing and motor for hdd using the same Download PDF

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JP2014019867A
JP2014019867A JP2013108711A JP2013108711A JP2014019867A JP 2014019867 A JP2014019867 A JP 2014019867A JP 2013108711 A JP2013108711 A JP 2013108711A JP 2013108711 A JP2013108711 A JP 2013108711A JP 2014019867 A JP2014019867 A JP 2014019867A
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lubricating oil
oil composition
fluid dynamic
dynamic pressure
pressure bearing
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Hyung Kyu Kim
キム・ヒュン・キュ
Ha Yong Jung
ジョン・ハ・ヨン
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Samsung Electro Mechanics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
    • C10M105/34Esters of monocarboxylic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • C10M2207/2815Esters of (cyclo)aliphatic monocarboxylic acids used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/071Branched chain compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/74Noack Volatility
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/18Electric or magnetic purposes in connection with recordings on magnetic tape or disc

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Sliding-Contact Bearings (AREA)
  • Connection Of Motors, Electrical Generators, Mechanical Devices, And The Like (AREA)
  • Lubricants (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide: a lubricating oil composition for a fluid dynamic pressure bearing with low viscosity, low evaporation loss, and improved oxidation stability at operating temperature; and a motor for an HDD containing the lubricating oil composition with improved reliability and quality.SOLUTION: The lubricating oil composition for a fluid dynamic pressure bearing includes, as a base oil, an aliphatic monocarboxylic acid ester specified in the figure having 16 to 46 carbon atoms in total, obtained by an esterification reaction of a specific carboxylic acid and a primary or secondary alcohol having 8 to 38 carbon atoms. The composition exhibits low viscosity, low evaporation loss, and improved oxidation stability at operating temperature.

Description

本発明は、粘度が低く、蒸発損失が少なく、酸化安定性も向上した流体動圧軸受用の潤滑油組成物及びこれを用いたHDD用モータに関する。 The present invention relates to a lubricating oil composition for a fluid dynamic pressure bearing having a low viscosity, low evaporation loss, and improved oxidation stability, and an HDD motor using the same.

情報保存装置の一つであるハードディスクドライブ(HDD;Hard Disk Drive)は、記録再生ヘッド(read/write head)を用いてディスクに保存されているデータを再生したり、ディスクにデータを記録する装置である。 A hard disk drive (HDD; Hard Disk Drive), which is one of information storage devices, reproduces data stored on a disk using a recording / playback head (read / write head) and records data on the disk It is.

このようなハードディスクドライブは、ディスクを駆動させるためのディスク駆動装置を必要とし、上記ディスク駆動装置には小型のスピンドルモータが用いられる。 Such a hard disk drive requires a disk drive for driving the disk, and a small spindle motor is used for the disk drive.

このような小型のスピンドルモータには流体動圧軸受アセンブリが利用されており、上記流体動圧軸受アセンブリのシャフトとスリーブとの間には潤滑流体が介され、上記潤滑流体から生じる流体圧力でシャフトを支持する。 A fluid dynamic pressure bearing assembly is used for such a small spindle motor, and a lubricating fluid is interposed between the shaft and the sleeve of the fluid dynamic pressure bearing assembly, and the shaft is driven by the fluid pressure generated from the lubricating fluid. Support.

スピンドルモータの回転時に潤滑流体が低温で高い粘度を有すると、モータ回転時に生じる動力発生溝に対する潤滑流体の粘性抵抗が大きくなり、結果、モータの電力損失が増加する。 If the lubricating fluid has a high viscosity at a low temperature when the spindle motor rotates, the viscous resistance of the lubricating fluid to the power generation groove generated during the rotation of the motor increases, and as a result, the power loss of the motor increases.

反面、モータの回転時に高温領域において潤滑流体の熱膨張及び粘度が低下すると、支持機能を十分に発揮できないという問題がある。 On the other hand, if the thermal expansion and viscosity of the lubricating fluid are reduced in the high temperature region during the rotation of the motor, there is a problem that the support function cannot be sufficiently exhibited.

このような理由により、潤滑流体は、低温領域では低い粘度を維持し、高温領域では粘度が低下しない、相反する粘度の挙動特性を有する必要がある。 For this reason, the lubricating fluid needs to have a behavior characteristic of contradictory viscosity that maintains a low viscosity in the low temperature region and does not decrease in the high temperature region.

このような粘度特性を満足するために、特定のエステル(Ester)化合物を主成分とする基油に、酸化防止剤や極圧添加剤などの物質を添加するなど様々な開発が行われている。 In order to satisfy such viscosity characteristics, various developments such as addition of substances such as antioxidants and extreme pressure additives to base oils mainly composed of specific ester (Ester) compounds have been conducted. .

しかし、上記様々な添加剤を用いた潤滑流体は、最初は効果を示すものの長期にわたって使用すると潤滑剤が蒸発し、粘度特性が変化するため、このような効果を維持し続けることは困難である。 However, although the lubricating fluids using the various additives described above are effective at the beginning, the lubricant evaporates and the viscosity characteristics change when used over a long period of time, so it is difficult to maintain such effects. .

また、モータの小型化、高精度化、高速回転化、低消費電力化に伴い、潤滑流体もまた耐熱性、酸化安定性、低蒸発性及び摩耗防止性などの特性が要求されている。 In addition, as motors become smaller, more accurate, faster rotated, and consume less power, lubricating fluids are also required to have characteristics such as heat resistance, oxidation stability, low evaporation, and wear resistance.

一方、上記基油は、底粘度化すると蒸発損失が増加する傾向があるため、実用温度で底粘度であるとともに蒸発損失が抑制される特性が要求されている。 On the other hand, since the base oil tends to increase the evaporation loss when the bottom viscosity is increased, the base oil is required to have a bottom viscosity at a practical temperature and to suppress the evaporation loss.

以下の先行技術文献には、2−エチルヘキサン酸を含むグリース組成物が開示されているが、上記実用温度で底粘度であるとともに蒸発損失が抑制される効果は大きくない。 Although the grease composition containing 2-ethylhexanoic acid is disclosed in the following prior art documents, the effect of suppressing evaporation loss as well as the bottom viscosity at the practical temperature is not great.

特開2007−154032号公報JP 2007-154032 A

本発明は、粘度が低く、蒸発損失が少なく、酸化安定性も向上した流体動圧軸受用の潤滑油組成物及びこれを用いたHDD用モータに関する。 The present invention relates to a lubricating oil composition for a fluid dynamic pressure bearing having a low viscosity, low evaporation loss, and improved oxidation stability, and an HDD motor using the same.

本発明の一実施例による流体動圧軸受用の潤滑油組成物は、下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含むことができる。 A lubricating oil composition for a fluid dynamic bearing according to an embodiment of the present invention includes a carboxylic acid represented by the following formula 1, and a primary alcohol or secondary alcohol (alcohol) having 8 to 38 carbon atoms. An aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 obtained by the esterification reaction can be contained as a base oil.

Figure 2014019867
式1
Figure 2014019867
Formula 1

上記脂肪族モノカルボン酸エステルは、エチルヘキサン酸パルミチル(Palmityl Ethylhexanoate)またはエチルヘキサン酸セチル(Cetyl Ethylhexanoate)であることができる。 The aliphatic monocarboxylic acid ester may be palmityl ethylhexanoate (Calethyl Ethylhexanoate) or cetyl ethylhexanoate (Cetyl Ethylhexanoate).

上記流体動圧軸受用の潤滑油組成物は、オイルの酸化防止剤0.01〜2重量部をさらに含むことができ、上記オイルの酸化防止剤は、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol))であることができる。 The lubricating oil composition for a fluid dynamic bearing may further include 0.01 to 2 parts by weight of an oil antioxidant, and the oil antioxidant may contain 2,2′-methylene-bis (4 -Methyl-6-tert-butylphenol) (2,2'-methylene-bis (4-methyl-6-tert-butylphenol)).

上記流体動圧軸受用の潤滑油組成物は、金属酸化防止剤0.01〜2重量部をさらに含むことができ、上記金属酸化防止剤は、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)であることができる。 The lubricating oil composition for a fluid dynamic bearing may further include 0.01 to 2 parts by weight of a metal antioxidant, and the metal antioxidant may include barium diphenylamine-4. -Sulfonate).

上記流体動圧軸受用の潤滑油組成物は、内圧防止剤0.01〜2重量部をさらに含むことができ、上記内圧防止剤は、リン酸トリクレジル(Tricresyl Phosphate)であることができる。 The lubricating oil composition for a fluid dynamic pressure bearing may further include 0.01 to 2 parts by weight of an internal pressure inhibitor, and the internal pressure inhibitor may be tricresyl phosphate.

本発明の他の実施例によるHDD用モータは、下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含む流体動圧軸受用の潤滑油組成物を含むことができる。 The HDD motor according to another embodiment of the present invention is obtained by an esterification reaction between a carboxylic acid represented by the following formula 1 and a primary alcohol or secondary alcohol (alcohol) having 8 to 38 carbon atoms. A lubricating oil composition for fluid dynamic pressure bearings containing an aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 as a base oil can be included.

Figure 2014019867
式1
Figure 2014019867
Formula 1

上記脂肪族モノカルボン酸エステルはエチルヘキサン酸パルミチル(Palmityl Ethylhexanoate)またはエチルヘキサン酸セチル(Cetyl Ethylhexanoate)であることができる。 The aliphatic monocarboxylic acid ester may be palmityl ethylhexanoate (Calethyl Ethylhexanoate) or cetyl ethylhexanoate (Cetyl Ethylhexanoate).

上記流体動圧軸受用の潤滑油組成物は、オイルの酸化防止剤0.01〜2重量部をさらに含むことができ、上記オイルの酸化防止剤は、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol))であることができる。 The lubricating oil composition for a fluid dynamic bearing may further include 0.01 to 2 parts by weight of an oil antioxidant, and the oil antioxidant may contain 2,2′-methylene-bis (4 -Methyl-6-tert-butylphenol) (2,2'-methylene-bis (4-methyl-6-tert-butylphenol)).

上記流体動圧軸受用の潤滑油組成物は、金属酸化防止剤0.01〜2重量部をさらに含むことができ、上記金属酸化防止剤は、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)であることができる。 The lubricating oil composition for a fluid dynamic bearing may further include 0.01 to 2 parts by weight of a metal antioxidant, and the metal antioxidant may include barium diphenylamine-4. -Sulfonate).

上記流体動圧軸受用の潤滑油組成物は、内圧防止剤0.01〜2重量部をさらに含むことができ、上記内圧防止剤は、リン酸トリクレジル(Tricresyl Phosphate)であることができる。 The lubricating oil composition for a fluid dynamic pressure bearing may further include 0.01 to 2 parts by weight of an internal pressure inhibitor, and the internal pressure inhibitor may be tricresyl phosphate.

本発明によると、実用温度で粘度が低く、蒸発損失が少なく、酸化安定性も向上した流体動圧軸受用の潤滑油組成物を含んでHDD用モータを製作することにより、モータの長期使用による信頼性品質を向上させることができる。 According to the present invention, by manufacturing a motor for HDD containing a lubricating oil composition for fluid dynamic pressure bearings having low viscosity at practical temperature, low evaporation loss, and improved oxidation stability, the motor can be used for a long time. Reliability quality can be improved.

本発明の一実施例による流体動圧軸受アセンブリを含むHDD用モータを図示した概略断面図である。1 is a schematic cross-sectional view illustrating an HDD motor including a fluid dynamic bearing assembly according to an embodiment of the present invention.

本発明の実施形態は様々な他の形態に変形することができ、本発明の範囲は以下で説明する実施形態に限定されるものではない。また、本発明の実施形態は当業界で平均的な知識を有する者に本発明をより完全に説明するために提供されるものである。従って、図面における要素の形状及び大きさ等はより明確な説明のために誇張されることがあり、図面上において同一の符号で表される要素は同一の要素である。 The embodiments of the present invention can be modified in various other forms, and the scope of the present invention is not limited to the embodiments described below. Also, the embodiments of the present invention are provided to more fully explain the present invention to those skilled in the art. Accordingly, the shape and size of elements in the drawings may be exaggerated for a clearer description, and elements denoted by the same reference numerals in the drawings are the same elements.

以下、添付の図面を参照して、本発明の好ましい実施形態について説明する。 Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings.

図1は本発明の一実施例による流体動圧軸受アセンブリを含むHDD用モータを図示した概略断面図である。 FIG. 1 is a schematic cross-sectional view illustrating a HDD motor including a fluid dynamic bearing assembly according to an embodiment of the present invention.

図1を参照すると、本発明の一実施例による流体動圧軸受用の潤滑油組成物170は、下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含むことができる Referring to FIG. 1, a lubricating oil composition 170 for a fluid dynamic bearing according to an embodiment of the present invention includes a carboxylic acid represented by the following formula 1 and a primary alcohol or a second alcohol having 8 to 38 carbon atoms. An aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 obtained by an esterification reaction with a secondary alcohol (alcohol) can be contained as a base oil.

Figure 2014019867
式1
Figure 2014019867
Formula 1

以下、上記構成について詳細に説明する。 Hereinafter, the above configuration will be described in detail.

上記式1で表されるカルボン酸は、2−エチルヘキサン酸(2−Ethyl Hexanoic Acid)であることができる。 The carboxylic acid represented by Formula 1 may be 2-ethylhexanoic acid (2-Ethyl Hexanoic Acid).

一方、本発明の一実施例によると、上記式1で表されるカルボン酸とのエステル化反応を行うために用いられるアルコール(alcohol)としては炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)が挙げられるが、これに制限されるものではない。 On the other hand, according to one embodiment of the present invention, the alcohol used for the esterification reaction with the carboxylic acid represented by the above formula 1 may be a primary alcohol having 8 to 38 carbon atoms or a second alcohol. Examples include, but are not limited to, grade alcohol (alcohol).

本発明の一実施例による流体動圧軸受用の潤滑油組成物170は、上記式1で表されるカルボン酸と、上記炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる脂肪族モノカルボン酸エステルを基油として含むことができる。 A lubricating oil composition 170 for a fluid dynamic bearing according to an embodiment of the present invention includes a carboxylic acid represented by the above formula 1 and a primary or secondary alcohol (alcohol) having 8 to 38 carbon atoms. An aliphatic monocarboxylic acid ester obtained by the esterification reaction with can be contained as a base oil.

上記脂肪族モノカルボン酸エステルは特に制限されないが、例えば、総炭素数が16〜46であることができる。 Although the said aliphatic monocarboxylic acid ester is not restrict | limited in particular, For example, a total carbon number can be 16-46.

上記脂肪族モノカルボン酸エステルは特に制限されないが、例えば、エチルヘキサン酸パルミチル(Palmityl Ethylhexanoate)またはエチルヘキサン酸セチル(Cetyl Ethylhexanoate)が挙げられ、下記式2及び式3で表すことができる。 The aliphatic monocarboxylic acid ester is not particularly limited, and examples thereof include palmityl ethylhexanoate (palmityl ethylhexanoate) and cetyl ethylhexanoate (cetyl ethylhexanoate), which can be represented by the following formulas 2 and 3.

Figure 2014019867
式2
Figure 2014019867
Formula 2

Figure 2014019867
式3
Figure 2014019867
Formula 3

具体的に、上記式2はエチルヘキサン酸パルミチル(Palmityl Ethylhexanoate)を表し、上記式3はエチルヘキサン酸セチル(Cetyl Ethylhexanoate)を表す式である。 Specifically, the above formula 2 represents palmityl ethylhexanoate (palmityl ethylhexanoate), and the above formula 3 represents a formula representing cetyl ethylhexanoate (cetyl ethylhexanoate).

本発明の一実施例による流体動圧軸受用の潤滑油組成物170は、上記2−エチルヘキサン酸(2−Ethyl Hexanoic Acid)と、上記炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる脂肪族モノカルボン酸エステルを基油として含むことにより、粘度が低く、蒸発損失が少なく、酸化安定性にも優れる。 The lubricating oil composition 170 for a fluid dynamic bearing according to an embodiment of the present invention includes the 2-ethylhexanoic acid (2-Ethyl Hexanoic Acid) and the primary alcohol or the secondary alcohol having 8 to 38 carbon atoms. By containing an aliphatic monocarboxylic acid ester obtained by esterification with alcohol as a base oil, the viscosity is low, evaporation loss is small, and oxidation stability is excellent.

本発明の一実施例による上記脂肪族モノカルボン酸エステルの動粘度は−20℃、25℃及び85℃の粘度を共に測定することができる。 The kinematic viscosity of the aliphatic monocarboxylic acid ester according to one embodiment of the present invention can be measured at -20 ° C, 25 ° C and 85 ° C.

上記粘度は、ブルックフィールドDB−III粘度計(Brookfield DB−III Rheometer)を用いて測定することができ、温度による傾向を確認するために、それぞれの成分を三つの温度区間(−20℃、25℃及び85℃)で測定することができる。 The viscosity can be measured using a Brookfield DB-III Rheometer, and each component is divided into three temperature intervals (−20 ° C., 25 ° C.) in order to confirm the tendency due to temperature. ° C and 85 ° C).

上記三つの温度のうち、−20℃は通常のモータの信頼性試験における低温保管温度に相当し、25℃はモータの常温動作温度に相当し、85℃は上記モータの高温での動作温度に相当することができる。 Of the above three temperatures, −20 ° C. corresponds to a low temperature storage temperature in a normal motor reliability test, 25 ° C. corresponds to a normal operating temperature of the motor, and 85 ° C. corresponds to a high operating temperature of the motor. Can be equivalent.

本発明の一実施例によると、上記脂肪族モノカルボン酸エステルは、通常用いられるアジピン酸ジオクチル(Dioctyl adipate;DOA)、セバシン酸ジオクチル(Dioctyl sebacate;DOS)またはアゼライン酸ジオクチル(Dioctyl azelate;DOZ)の脂肪族モノカルボン酸エステルより粘度が低く、高温蒸発量も少ないことができる。 According to one embodiment of the present invention, the aliphatic monocarboxylic acid ester may be a dioctyl adipate (DOA), dioctyl sebacate (DOS), or dioctyl azelate (DOZ). The viscosity is lower than that of the aliphatic monocarboxylic acid ester, and the amount of high-temperature evaporation can be reduced.

従って、上記脂肪族モノカルボン酸エステルを基油として用いる場合、低い粘度を有するとともに、装置の摩擦損失をより効果的に減少させることができ、蒸発量が少なく高温で非常に優れた安定性を有することができる。 Therefore, when the above aliphatic monocarboxylic acid ester is used as a base oil, it has a low viscosity, can reduce friction loss of the apparatus more effectively, has a small amount of evaporation, and has excellent stability at high temperatures. Can have.

上記脂肪族モノカルボン酸エステルを基油として含む潤滑油組成物は特に制限されないが、例えば、ハードディスクドライブ(Hard Disc Drive;HDD)用モータの流体軸受として用いるために好適である。 The lubricating oil composition containing the aliphatic monocarboxylic acid ester as a base oil is not particularly limited, but is suitable for use as, for example, a fluid bearing of a motor for a hard disk drive (HDD).

小型のハードディスクドライブの場合、電力消費量が少ない必要があり、モータの高速回転のために高温での安定性が非常に重要な要素であり得る。 In the case of a small hard disk drive, power consumption needs to be low, and stability at high temperatures can be a very important factor due to the high speed rotation of the motor.

本発明の一実施例による上記潤滑油組成物は、摩擦損失が少なく、高温での安定性を有することで、小型のハードディスクの上記条件を満足することができる。 The lubricating oil composition according to an embodiment of the present invention can satisfy the above-mentioned conditions for a small hard disk by having a low friction loss and stability at a high temperature.

上記流体動圧軸受用の潤滑油組成物は、オイルの酸化防止剤0.01〜2重量部をさらに含むことができ、上記オイルの酸化防止剤は特に制限されず、例えば、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol))が挙げられる。 The lubricating oil composition for a fluid dynamic bearing may further include 0.01 to 2 parts by weight of an oil antioxidant, and the oil antioxidant is not particularly limited. For example, 2, 2 ′ -Methylene-bis (4-methyl-6-tert-butylphenol) (2,2'-methylene-bis (4-methyl-6-tert-butylphenol)).

上記オイルの酸化防止剤は、上記潤滑油組成物の性能を低下させない範囲内で0.01〜2重量部を含むことができ、0.01重量部未満の場合には酸化防止剤を添加した効果が十分に現れないことがあり、2重量部を超える場合には上記潤滑油組成物の性能を低下させることがある。 The oil antioxidant may contain 0.01 to 2 parts by weight within a range not deteriorating the performance of the lubricating oil composition. When the amount is less than 0.01 parts by weight, an antioxidant is added. The effect may not be sufficiently exhibited, and if it exceeds 2 parts by weight, the performance of the lubricating oil composition may be deteriorated.

また、上記流体動圧軸受用の潤滑油組成物は、金属酸化防止剤0.01〜2重量部をさらに含むことができ、上記金属酸化防止剤は特に制限されず、例えば、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)が挙げられる。 The lubricating oil composition for fluid dynamic pressure bearings may further include 0.01 to 2 parts by weight of a metal antioxidant, and the metal antioxidant is not particularly limited. For example, diphenylamine-4- A barium sulfonate (Barium diphenylamine-4-sulfonate) is mentioned.

上記金属酸化防止剤の添加量が0.01重量部未満の場合には酸化安定の効果が十分に現れないことがあり、2重量部を超える場合には上記潤滑油組成物の性能を低下させることがあるため、その添加量は0.01〜2重量部の範囲内であることが好ましい。 When the added amount of the metal antioxidant is less than 0.01 parts by weight, the effect of oxidation stability may not be sufficiently exhibited. When the added amount exceeds 2 parts by weight, the performance of the lubricating oil composition is deteriorated. Therefore, the amount added is preferably in the range of 0.01 to 2 parts by weight.

上記流体動圧軸受用の潤滑油組成物は内圧防止剤0.01〜2重量部をさらに含むことができ、上記内圧防止剤は特に制限されず、例えば、リン酸トリクレジル(Tricresyl Phosphate)が挙げられる。 The lubricating oil composition for a fluid dynamic pressure bearing may further include 0.01 to 2 parts by weight of an internal pressure inhibitor, and the internal pressure inhibitor is not particularly limited, and examples thereof include tricresyl phosphate (Tricresyl Phosphate). It is done.

上記内圧防止剤の添加量が0.01重量部未満の場合には内圧防止の効果が十分に現れないことがあり、2重量部を超える場合には上記潤滑油組成物の性能を低下させることがあるため、その添加量は0.01〜2重量部の範囲内であることが好ましい。 When the added amount of the internal pressure inhibitor is less than 0.01 parts by weight, the effect of preventing the internal pressure may not be sufficiently exhibited. When the added amount exceeds 2 parts by weight, the performance of the lubricating oil composition is deteriorated. Therefore, the amount added is preferably in the range of 0.01 to 2 parts by weight.

本発明の他の実施例によるHDD用モータは、下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含む流体動圧軸受用の潤滑油組成物を含むことができる The HDD motor according to another embodiment of the present invention is obtained by an esterification reaction between a carboxylic acid represented by the following formula 1 and a primary alcohol or secondary alcohol (alcohol) having 8 to 38 carbon atoms. A lubricating oil composition for fluid dynamic pressure bearings containing an aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 as a base oil can be included.

Figure 2014019867
式1
Figure 2014019867
Formula 1

以下、本発明の他の実施例によるHDD用モータについて詳細に説明するが、上述の本発明の一実施例における説明と重複する部分は省略する。 Hereinafter, the HDD motor according to another embodiment of the present invention will be described in detail, but the description overlapping with the description of the above-described embodiment of the present invention will be omitted.

上記HDD用モータ400は、固定部材120、140と、回転部材110、130、212との間にオイルシール部160が形成されることができ、特に、スリーブ(sleeve)120、スラストプレート(thrust plate)130及びキャップ(cap)140の間に形成されることができる。 In the HDD motor 400, an oil seal 160 may be formed between the fixing members 120 and 140 and the rotating members 110, 130, and 212. In particular, the sleeve 120 and the thrust plate may be used. ) 130 and a cap 140.

上記キャップ140は、上記スラストプレート130の上側で圧入され、上記スラストプレート130との間に潤滑流体がシールされるようにする部材であり、上記スラストプレート130及び上記スリーブ120に圧入されるように、外径方向に円周方向の溝が形成されることができる。 The cap 140 is a member that is press-fitted on the upper side of the thrust plate 130 so that the lubricating fluid is sealed between the cap and the thrust plate 130, and is pressed into the thrust plate 130 and the sleeve 120. In the outer diameter direction, a circumferential groove can be formed.

上記キャップ140は、潤滑流体がシールされるようにするために、下面に突出部が形成されることができ、これはモータの駆動時に潤滑流体が外部に漏れることを防止するために毛管現象及び潤滑流体の表面張力を用いたものである。 The cap 140 may be formed with a protrusion on a lower surface thereof to allow the lubricating fluid to be sealed, and this may cause capillary action and leakage to prevent the lubricating fluid from leaking to the outside when the motor is driven. The surface tension of the lubricating fluid is used.

一方、本発明の他の実施例によるHDD用モータ400は、シャフト110、スリーブ120、スラストプレート130、キャップ部材140及びオイルシール部160を含むことができる。 Meanwhile, the HDD motor 400 according to another embodiment of the present invention may include a shaft 110, a sleeve 120, a thrust plate 130, a cap member 140, and an oil seal portion 160.

上記スリーブ120は、上記シャフト110の上端が軸方向上側に突出されるように上記シャフト110を支持することができ、CuまたはAlを鍛造したり、Cu−Fe系合金粉末またはSUS系粉末を焼結することで形成されることができる。 The sleeve 120 can support the shaft 110 such that the upper end of the shaft 110 protrudes upward in the axial direction, and forges Cu or Al, or burns Cu-Fe alloy powder or SUS powder. It can be formed by tying.

ここで、上記シャフト110は、上記スリーブ120の軸孔と微小間隙を有するように挿入され、上記微小間隙には潤滑流体が充填される。また、上記シャフト110の外径及び上記スリーブ120の内径のうち少なくとも一つに形成されるラジアル動圧溝によって、上記ロータ200の回転をよりスムーズに支持することができる。 Here, the shaft 110 is inserted so as to have a minute gap with the shaft hole of the sleeve 120, and the minute gap is filled with a lubricating fluid. Further, the rotation of the rotor 200 can be more smoothly supported by a radial dynamic pressure groove formed in at least one of the outer diameter of the shaft 110 and the inner diameter of the sleeve 120.

上記ラジアル動圧溝は、上記スリーブ120の軸孔の内部である上記スリーブ120の内側面に形成され、上記シャフト110の回転時に一側に偏るように圧力を形成することができる。 The radial dynamic pressure groove is formed on the inner surface of the sleeve 120, which is the inside of the shaft hole of the sleeve 120, and can generate pressure so as to be biased to one side when the shaft 110 rotates.

但し、上記ラジアル動圧溝は、上述したように上記スリーブ120の内側面に設けられることに限定されず、上記シャフト110の外径部に設けられることも可能であり、個数にも制限がない。 However, the radial dynamic pressure grooves are not limited to being provided on the inner side surface of the sleeve 120 as described above, and can be provided on the outer diameter portion of the shaft 110, and the number is not limited. .

上記スリーブ120にはスリーブ120の上部及び下部を連通するように形成されるバイパス水路125が備えられ、流体動圧軸受アセンブリ100の内部の潤滑流体の圧力を分散させてバランスを取ることができ、上記流体動圧軸受アセンブリ100の内部に存在する気泡などが、循環によって排出されるように移動させることができる。 The sleeve 120 is provided with a bypass water passage 125 formed so as to communicate with the upper and lower portions of the sleeve 120, and the pressure of the lubricating fluid inside the fluid dynamic bearing assembly 100 can be distributed and balanced, Bubbles and the like existing in the fluid dynamic bearing assembly 100 can be moved so as to be discharged by circulation.

ここで、上記スリーブ120の下部には、間隙を維持した状態で上記スリーブ120と結合し、上記間隙には潤滑流体を収容するカバープレート150が結合されることができる。 Here, a lower plate of the sleeve 120 may be coupled to the sleeve 120 while maintaining a gap, and a cover plate 150 containing a lubricating fluid may be coupled to the gap.

上記カバープレート150は、上記スリーブ120との間の間隙に潤滑流体を収容し、それ自体が上記シャフト110の下面を支持する軸受としての機能を果たすことができる。 The cover plate 150 accommodates a lubricating fluid in a gap between the sleeve 120 and the cover plate 150 itself can function as a bearing that supports the lower surface of the shaft 110.

スラストプレート130は、上記スリーブ120の軸方向上部に配置され、中央にシャフト110の断面に相当するホールを備え、このホールに上記シャフト110が挿入されることができる。 The thrust plate 130 is disposed at the upper part of the sleeve 120 in the axial direction, and has a hole corresponding to the cross section of the shaft 110 at the center, into which the shaft 110 can be inserted.

この際、上記スラストプレート130は別に製造されて上記シャフト110と結合することもできるが、製造時から上記シャフト110と一体に形成されることもでき、上記シャフト110の回転運動時に上記シャフト110に沿って回転運動する。 At this time, the thrust plate 130 may be separately manufactured and coupled to the shaft 110. However, the thrust plate 130 may be integrally formed with the shaft 110 from the time of manufacture. Rotating movement along.

また、上記スラストプレート130の上面には上記シャフト110にスラスト動圧を提供するスラスト動圧溝が形成されることができる。 A thrust dynamic pressure groove for providing a thrust dynamic pressure to the shaft 110 may be formed on the upper surface of the thrust plate 130.

上記スラスト動圧溝は、上述したように上記スラストプレート130の上面に形成されることに限定されず、上記スラストプレート130の下面に対応するスリーブ120の上面にも形成されることができる。 The thrust dynamic pressure groove is not limited to being formed on the upper surface of the thrust plate 130 as described above, and may be formed on the upper surface of the sleeve 120 corresponding to the lower surface of the thrust plate 130.

ステータ300は、コイル320、コア330及びベース部材310を含むことができる。 The stator 300 may include a coil 320, a core 330, and a base member 310.

即ち、上記ステータ300は、電源が印加される際に所定の大きさの電磁気力を発生するコイル320と、上記コイル320が巻線される複数のコア330と、を備える固定構造物であることができる。 That is, the stator 300 is a fixed structure including a coil 320 that generates an electromagnetic force having a predetermined magnitude when power is applied, and a plurality of cores 330 around which the coil 320 is wound. Can do.

上記コア330は、パターン回路が印刷された印刷回路基板(不図示)が備えられるベース部材310の上部に固定配置され、上記巻線コイル320に対応するベース部材310の上部面には、上記巻線コイル320を下部に露出させるために所定サイズを有する複数のコイル孔が貫通形成されることができる。また、上記巻線コイル320は、外部電源が供給されるように上記印刷回路基板(不図示)と電気的に連結されることができる。 The core 330 is fixedly disposed on an upper part of a base member 310 provided with a printed circuit board (not shown) on which a pattern circuit is printed, and the upper surface of the base member 310 corresponding to the winding coil 320 is disposed on the upper surface of the base member 310. A plurality of coil holes having a predetermined size may be formed through to expose the wire coil 320 in the lower part. In addition, the winding coil 320 may be electrically connected to the printed circuit board (not shown) so that external power is supplied.

上記ベース部材310は、上記スリーブ120の外周面に圧入固定され、その内部に上記コイル320が巻線されるコア330が挿入されることができる。 The base member 310 is press-fitted and fixed to the outer peripheral surface of the sleeve 120, and a core 330 around which the coil 320 is wound can be inserted.

また、上記ベース部材310及び上記スリーブ120は、上記ベース部材310の内面または上記スリーブ120の外面に接着剤を塗布することで互いに組み立てられることができる。 In addition, the base member 310 and the sleeve 120 can be assembled to each other by applying an adhesive to the inner surface of the base member 310 or the outer surface of the sleeve 120.

ロータ200は、上記ステータ300に対して回転可能に備えられる回転構造物であり、上記コア330と所定間隔を隔てて互いに対応する環状リング型のマグネット220を外周面に備えるロータケース210を含むことができる。 The rotor 200 is a rotating structure provided to be rotatable with respect to the stator 300, and includes a rotor case 210 including annular ring-shaped magnets 220 corresponding to each other at a predetermined interval from the core 330 on an outer peripheral surface. Can do.

また、上記マグネット220は円周方向にN極、S極が交互に着磁され、所定強度の磁気力を発生させる永久磁石として備えられることができる。 The magnet 220 may be provided as a permanent magnet that is alternately magnetized with N and S poles in the circumferential direction to generate a magnetic force with a predetermined strength.

ここで、上記ロータケース210は、シャフト110の上端に圧入固定されるようにするハブベース212と、上記ハブベース212から外径方向に延長され、軸方向下側に折り曲げられて上記マグネット220を支持するマグネット支持部214と、からなることができる。 Here, the rotor case 210 is press-fitted and fixed to the upper end of the shaft 110, and is extended from the hub base 212 in the outer diameter direction and bent downward in the axial direction to support the magnet 220. And a magnet support part 214.

本発明の他の実施例によるHDD用モータは、上記流体動圧軸受用の潤滑油組成物170を含むことにより、低い粘度を有するとともに、装置の摩擦損失をより効果的に減少させることができ、蒸発量が少なく高温で非常に優れた安定性を有することができる。 The HDD motor according to another embodiment of the present invention includes the lubricating oil composition 170 for the fluid dynamic pressure bearing, thereby having a low viscosity and more effectively reducing the friction loss of the apparatus. The amount of evaporation is small, and it can have very good stability at high temperatures.

また、実用温度で粘度が低く、蒸発損失が少なく、酸化安定性も向上した流体動圧軸受用の潤滑油組成物を含んでHDD用モータを製作することにより、モータの長期使用による信頼性品質を向上させることができる。 In addition, by manufacturing a motor for HDDs containing a lubricating oil composition for fluid dynamic pressure bearings that has low viscosity at practical temperatures, low evaporation loss, and improved oxidation stability, the reliability quality of the motor after long-term use Can be improved.

上記HDD用モータ400の製造方法は、上記流体動圧軸受用の潤滑油組成物170を含む以外には通常の製造方法と同様である。 The manufacturing method of the HDD motor 400 is the same as a normal manufacturing method, except that the lubricating oil composition 170 for the fluid dynamic pressure bearing is included.

以下、実施例を参照して本発明をより詳細に説明するが、本発明はこれによって制限されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated in detail with reference to an Example, this invention is not restrict | limited by this.

(実施例)
実施例1は、アルドリッチ(Aldrich)社、メルク(Merck)社及びティーシーアイ(TCI)社などで販売する2−エチルヘキサン酸(2−Ethyl Hexanoic Acid)とヘキサデカン−7−オール(Hexadecan−7−ol)とを反応させて下記式4のようにヘキサデカン−7−イル−ヘキサン酸エチル(Hexadecan−7−yl−Ethylhexanoate)を合成した。
(Example)
Example 1 is an example of 2-ethylhexanoic acid and hexadecan-7-7 sold by Aldrich, Merck, and TCI. ol) and hexahexan-7-yl-ethylhexanoate was synthesized as shown in Formula 4 below.

Figure 2014019867
式4
Figure 2014019867
Formula 4

上記反応は、アルコール及び酸を反応器に投入して200℃の条件下で24時間反応させ、上記反応後、精製する工程を行った。 In the above reaction, an alcohol and an acid were charged into a reactor and reacted at 200 ° C. for 24 hours. After the reaction, purification was performed.

上記ヘキサデカン−7−イル−ヘキサン酸エチル(Hexadecan−7−yl−Ethylhexanoate)は全体重量比で約95wt%の割合を占めており、残り5wt%はその他の特性を向上させるための添加剤を追加した。 Hexadecan-7-yl-ethylhexanoate accounts for about 95 wt% of the total weight ratio, and the remaining 5 wt% is added with additives for improving other properties. did.

具体的に、オイルの酸化を防止するために、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol)を2wt%添加し、内圧防止剤としてリン酸トリクレジル(Tricresyl Phosphate)を2wt%添加した。 Specifically, in order to prevent oxidation of the oil, 2,2′-methylene-bis (4-methyl-6-tert-butylphenol) (2,2′-methylene-bis (4-methyl-6-tert- butylphenol) was added at 2 wt%, and tricresyl phosphate (tricresyl phosphate) was added at 2 wt% as an internal pressure inhibitor.

また、オイルと接触する金属表面の酸化を防止するために、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)を1wt%添加した。 Moreover, in order to prevent the oxidation of the metal surface which contacts oil, 1 wt% of diphenylamine-4-sulfonate (Barium diphenylamine-4-sulfonate) was added.

(比較例1、2)
比較例1は、セバシン酸ジオクチル(Dioctyl sebacate;DOS)65wt%と、2−エチルヘキシルオレアート(Ethylhexyloleate;EHO)30wt%との混合物に、実施例1と同様に添加剤5wt%を添加して潤滑油組成物を製造し、比較例2は、アジピン酸ジオクチル(Dioctyl adipate;DOA)を全体重量比で約95wt%用いる以外には実施例1と同様に製造した。
(Comparative Examples 1 and 2)
Comparative Example 1 was lubricated by adding 5 wt% of additive to a mixture of 65 wt% of dioctyl sebacate (DOS) and 30 wt% of 2-ethylhexyl oleate (EHO) in the same manner as in Example 1. An oil composition was produced, and Comparative Example 2 was produced in the same manner as Example 1 except that dioctyl adipate (DOA) was used in an overall weight ratio of about 95 wt%.

上記比較例1及び2のエステルは下記式5及び式6で表されることができる。 The esters of Comparative Examples 1 and 2 can be represented by the following formulas 5 and 6.

Figure 2014019867
式5
Figure 2014019867
Formula 5

Figure 2014019867
式6
Figure 2014019867
Equation 6

以下の表1は、上記実施例及び比較例による潤滑油組成物の性能を比較するために、粘度及び信頼性を比較するための蒸発量を測定して表したものである。 Table 1 below shows the measured amounts of evaporation for comparing the viscosity and reliability in order to compare the performances of the lubricating oil compositions according to the above Examples and Comparative Examples.

上記粘度はブルックフィールドDB−III粘度計(Brookfield DB−III Rheometer)を用いて測定し、温度による傾向を確認するために、それぞれの成分を三つの温度区間(−20℃、25℃及び85℃)で測定した。 The viscosity is measured using a Brookfield DB-III viscometer and each component is divided into three temperature intervals (−20 ° C., 25 ° C. and 85 ° C.) in order to confirm the tendency due to temperature. ).

蒸発量は、各成分を含む流体動圧軸受用の潤滑油組成物をSUS材質の蒸発皿に5gずつ載せて100℃の恒温槽に投入して実験を行うことで測定した。 The amount of evaporation was measured by placing 5 g of a lubricating oil composition for a fluid dynamic pressure bearing containing each component on a SUS material evaporating dish and putting it in a thermostatic bath at 100 ° C. to perform an experiment.

上記実験は144時間(6日)行われ、蒸発皿に上記潤滑油組成物を載せた最初の重量と、100℃にて144時間経過した後の重量とを測定して蒸発量を比較した。 The above experiment was conducted for 144 hours (6 days), and the amount of evaporation was compared by measuring the initial weight when the lubricating oil composition was placed on the evaporating dish and the weight after 144 hours had passed at 100 ° C.

Figure 2014019867
Figure 2014019867

上記表1を参照すると、本発明による潤滑油組成物(実施例1)は、セバシン酸ジオクチル(Dioctyl sebacate;DOS)65wt%及び2−エチルヘキシルオレアート(Ethylhexyloleate;EHO)30wt%の混合物を用いた潤滑油組成物(比較例1)と、アゼライン酸ジオクチル(Dioctyl azelate;DOZ)を用いた潤滑油組成物(比較例2)と、に比べて粘度も低く、蒸発量も少ないことが分かる。 Referring to Table 1 above, the lubricating oil composition according to the present invention (Example 1) used a mixture of dioctyl sebacate (DOS) 65 wt% and 2-ethylhexyl oleate (EHO) 30 wt%. It can be seen that the viscosity is lower and the amount of evaporation is smaller than the lubricating oil composition (Comparative Example 1) and the lubricating oil composition (Comparative Example 2) using dioctyl azelate (DOZ).

従って、本発明の一実施形態によると、実用温度で粘度が低く、蒸発損失が少なく、酸化安定性も向上した流体動圧軸受用の潤滑油組成物を含んでHDD用モータを製作することにより、モータの長期使用による信頼性品質を向上させることができる。 Therefore, according to one embodiment of the present invention, by manufacturing a HDD motor including a lubricating oil composition for a fluid dynamic pressure bearing having a low viscosity at a practical temperature, a low evaporation loss, and an improved oxidation stability. The reliability quality can be improved by long-term use of the motor.

本発明は上述の実施例及び添付の図面により限定されず、添付の請求範囲により限定される。従って、請求範囲に記載された本発明の技術的思想を外れない範囲内で様々な形態の置換、変形及び変更が出来るということは当技術分野の通常の知識を有する者には明白であり、これも添付の請求範囲に記載された技術的思想に属する。 The present invention is not limited by the above embodiments and the accompanying drawings, but is limited by the appended claims. Accordingly, it is apparent to those skilled in the art that various forms of substitution, modification, and change can be made without departing from the technical idea of the present invention described in the claims. This also belongs to the technical idea described in the appended claims.

100 流体動圧軸受アセンブリ
110 シャフト
120 スリーブ
125 バイパス水路
130 スラストプレート
140 キャップ部材
150 カバープレート
160 オイルシール部
170 潤滑油組成物
200 ロータ
210 ロータケース
212 ハブベース
214 マグネット支持部
220 マグネット
300 ステータ
310 ベース部材
320 巻線コイル
330 コア
400 モータ
DESCRIPTION OF SYMBOLS 100 Fluid dynamic pressure bearing assembly 110 Shaft 120 Sleeve 125 Bypass water channel 130 Thrust plate 140 Cap member 150 Cover plate 160 Oil seal part 170 Lubricating oil composition 200 Rotor 210 Rotor case 212 Hub base 214 Magnet support part 220 Magnet 300 Stator 310 Base member 320 Winding coil 330 Core 400 Motor

Claims (16)

下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含む、流体動圧軸受用の潤滑油組成物。
Figure 2014019867
式1
Aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 obtained by esterification reaction of a carboxylic acid represented by the following formula 1 and a primary or secondary alcohol (alcohol) having 8 to 38 carbon atoms A lubricating oil composition for fluid dynamic pressure bearings, comprising
Figure 2014019867
Formula 1
前記脂肪族モノカルボン酸エステルは、エチルヘキサン酸パルミチル(Palmityl Ethylhexanoate)またはエチルヘキサン酸セチル(Cetyl Ethylhexanoate)である、請求項1に記載の流体動圧軸受用の潤滑油組成物。 2. The lubricating oil composition for a fluid dynamic bearing according to claim 1, wherein the aliphatic monocarboxylic acid ester is palmityl ethylhexanoate (Palmityl Ethylhexanoate) or cetyl ethylhexanoate (Cetyl Ethylhexanoate). 3. 前記流体動圧軸受用の潤滑油組成物は、オイルの酸化防止剤0.01〜2重量部をさらに含む、請求項1に記載の流体動圧軸受用の潤滑油組成物。 The lubricating oil composition for a fluid dynamic pressure bearing according to claim 1, wherein the lubricating oil composition for a fluid dynamic pressure bearing further comprises 0.01 to 2 parts by weight of an oil antioxidant. 前記オイルの酸化防止剤は、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol))である、請求項3に記載の流体動圧軸受用の潤滑油組成物。 The oil antioxidant is 2,2′-methylene-bis (4-methyl-6-tert-butylphenol) (2,2′-methylene-bis (4-methyl-6-tert-butylphenol)). The lubricating oil composition for fluid dynamic pressure bearings according to claim 3. 前記流体動圧軸受用の潤滑油組成物は、金属酸化防止剤0.01〜2重量部をさらに含む、請求項1に記載の流体動圧軸受用の潤滑油組成物。 The lubricating oil composition for a fluid dynamic pressure bearing according to claim 1, wherein the lubricating oil composition for a fluid dynamic pressure bearing further includes 0.01 to 2 parts by weight of a metal antioxidant. 前記金属酸化防止剤は、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)である、請求項5に記載の流体動圧軸受用の潤滑油組成物。 The lubricating oil composition for a fluid dynamic bearing according to claim 5, wherein the metal antioxidant is barium diphenylamine-4-sulfonate. 前記流体動圧軸受用の潤滑油組成物は、内圧防止剤0.01〜2重量部をさらに含む、請求項1に記載の流体動圧軸受用の潤滑油組成物。 The lubricating oil composition for a fluid dynamic pressure bearing according to claim 1, wherein the lubricating oil composition for a fluid dynamic pressure bearing further includes 0.01 to 2 parts by weight of an internal pressure inhibitor. 前記内圧防止剤は、リン酸トリクレジル(Tricresyl Phosphate)である、請求項7に記載の流体動圧軸受用の潤滑油組成物。 The lubricating oil composition for a fluid dynamic bearing according to claim 7, wherein the internal pressure inhibitor is tricresyl phosphate. 下記式1で表されるカルボン酸と、炭素数8〜38の第1級アルコールまたは第2級アルコール(alcohol)とのエステル化反応により得られる総炭素数16〜46の脂肪族モノカルボン酸エステルを基油として含む流体動圧軸受用の潤滑油組成物を含む、HDD用モータ。
Figure 2014019867
式1
Aliphatic monocarboxylic acid ester having a total carbon number of 16 to 46 obtained by esterification reaction of a carboxylic acid represented by the following formula 1 and a primary or secondary alcohol (alcohol) having 8 to 38 carbon atoms An HDD motor comprising a lubricating oil composition for a fluid dynamic pressure bearing that contains a base oil.
Figure 2014019867
Formula 1
前記脂肪族モノカルボン酸エステルは、ヘキサデカン−7−イル−ヘキサン酸エチル(Hexadecan−7−yl−Ethylhexanoate)である、請求項9に記載のHDD用モータ。 The HDD motor according to claim 9, wherein the aliphatic monocarboxylic acid ester is Hexadecan-7-yl-Ethylhexanoate. 前記流体動圧軸受用の潤滑油組成物は、オイルの酸化防止剤0.01〜2重量部をさらに含む、請求項9に記載のHDD用モータ。 The HDD motor according to claim 9, wherein the lubricating oil composition for a fluid dynamic pressure bearing further includes 0.01 to 2 parts by weight of an oil antioxidant. 前記オイルの酸化防止剤は、2、2´−メチレン−ビス(4−メチル−6−tert−ブチルフェノール)(2、2´−methylene−bis(4−methyl−6−tert−butylphenol))である、請求項11に記載のHDD用モータ。 The oil antioxidant is 2,2′-methylene-bis (4-methyl-6-tert-butylphenol) (2,2′-methylene-bis (4-methyl-6-tert-butylphenol)). The HDD motor according to claim 11. 前記流体動圧軸受用の潤滑油組成物は、金属酸化防止剤0.01〜2重量部をさらに含む、請求項9に記載のHDD用モータ。 The HDD motor according to claim 9, wherein the lubricating oil composition for a fluid dynamic pressure bearing further includes 0.01 to 2 parts by weight of a metal antioxidant. 前記金属酸化防止剤は、ジフェニルアミン−4−スルホン酸バリウム(Barium diphenylamine−4−sulfonate)である、請求項13に記載のHDD用モータ。 The HDD motor according to claim 13, wherein the metal antioxidant is barium diphenylamine-4-sulfonate. 前記流体動圧軸受用の潤滑油組成物は、内圧防止剤0.01〜2重量部をさらに含む、請求項9に記載のHDD用モータ。 The HDD motor according to claim 9, wherein the lubricating oil composition for a fluid dynamic pressure bearing further includes 0.01 to 2 parts by weight of an internal pressure inhibitor. 前記内圧防止剤は、リン酸トリクレジル(Tricresyl Phosphate)である、請求項15に記載のHDD用モータ。 The HDD motor according to claim 15, wherein the internal pressure preventing agent is tricresyl phosphate.
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