JP2014019684A - Agricultural and horticultural water wettable powders with improved physicochemical properties - Google Patents
Agricultural and horticultural water wettable powders with improved physicochemical properties Download PDFInfo
- Publication number
- JP2014019684A JP2014019684A JP2012162282A JP2012162282A JP2014019684A JP 2014019684 A JP2014019684 A JP 2014019684A JP 2012162282 A JP2012162282 A JP 2012162282A JP 2012162282 A JP2012162282 A JP 2012162282A JP 2014019684 A JP2014019684 A JP 2014019684A
- Authority
- JP
- Japan
- Prior art keywords
- wettable powder
- agricultural
- horticultural
- water
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 23
- 239000000843 powder Substances 0.000 title description 15
- 239000004563 wettable powder Substances 0.000 claims abstract description 53
- 239000000417 fungicide Substances 0.000 claims abstract description 29
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 23
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 16
- ZUQAPLKKNAQJAU-UHFFFAOYSA-N acetylenediol Chemical compound OC#CO ZUQAPLKKNAQJAU-UHFFFAOYSA-N 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical group CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 15
- 150000002009 diols Chemical class 0.000 abstract description 9
- 238000010790 dilution Methods 0.000 abstract description 6
- 239000012895 dilution Substances 0.000 abstract description 6
- 239000006260 foam Substances 0.000 abstract description 5
- -1 flowable Substances 0.000 description 44
- 235000002639 sodium chloride Nutrition 0.000 description 14
- 239000004480 active ingredient Substances 0.000 description 13
- 239000003905 agrochemical Substances 0.000 description 13
- 238000002156 mixing Methods 0.000 description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 10
- 239000004927 clay Substances 0.000 description 10
- 238000005187 foaming Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
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- 239000003814 drug Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000013256 coordination polymer Substances 0.000 description 5
- 238000003898 horticulture Methods 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
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- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 4
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- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 3
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical compound COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- 239000002253 acid Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
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- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- IKNXXTIMVROREQ-WXXKFALUSA-N (e)-but-2-enedioic acid;[2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl]-imidazol-1-ylmethanone Chemical compound OC(=O)\C=C\C(O)=O.C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1.C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 IKNXXTIMVROREQ-WXXKFALUSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 239000005760 Difenoconazole Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000003254 anti-foaming effect Effects 0.000 description 2
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- 239000003093 cationic surfactant Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 2
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- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
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- AGKSTYPVMZODRV-UHFFFAOYSA-N imibenconazole Chemical compound C1=CC(Cl)=CC=C1CSC(CN1N=CN=C1)=NC1=CC=C(Cl)C=C1Cl AGKSTYPVMZODRV-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
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- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
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- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical class O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 description 1
- KZAUOCCYDRDERY-UHFFFAOYSA-N oxamyl Chemical compound CNC(=O)ON=C(SC)C(=O)N(C)C KZAUOCCYDRDERY-UHFFFAOYSA-N 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- AMEKQAFGQBKLKX-UHFFFAOYSA-N oxycarboxin Chemical compound O=S1(=O)CCOC(C)=C1C(=O)NC1=CC=CC=C1 AMEKQAFGQBKLKX-UHFFFAOYSA-N 0.000 description 1
- LKPLKUMXSAEKID-UHFFFAOYSA-N pentachloronitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LKPLKUMXSAEKID-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 description 1
- CRFYLQMIDWBKRT-LPYMAVHISA-N pyribencarb Chemical compound C1=C(Cl)C(CNC(=O)OC)=CC(C(\C)=N\OCC=2N=C(C)C=CC=2)=C1 CRFYLQMIDWBKRT-LPYMAVHISA-N 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 description 1
- ITKAIUGKVKDENI-UHFFFAOYSA-N pyrimidifen Chemical compound CC1=C(C)C(CCOCC)=CC=C1OCCNC1=NC=NC(CC)=C1Cl ITKAIUGKVKDENI-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- SHBDDIJUSNNBLQ-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SHBDDIJUSNNBLQ-UHFFFAOYSA-M 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
- FAUOSXUSCVJWAY-UHFFFAOYSA-N tetrakis(hydroxymethyl)phosphanium Chemical class OC[P+](CO)(CO)CO FAUOSXUSCVJWAY-UHFFFAOYSA-N 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- RSOBJVBYZCMJOS-CYBMUJFWSA-N tolprocarb Chemical compound FC(F)(F)COC(=O)N[C@@H](C(C)C)CNC(=O)C1=CC=C(C)C=C1 RSOBJVBYZCMJOS-CYBMUJFWSA-N 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- JARYYMUOCXVXNK-CSLFJTBJSA-N validamycin A Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-CSLFJTBJSA-N 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Abstract
Description
本発明は、ジチオカーバメート系殺菌剤及びアセチレンジオール系界面活性剤を含有する農園芸用水和剤組成物に関する。更に詳しくは、使用時に水に希釈する際に速やかに水に馴染み、且つ特に高濃度における泡立ちが少ない農園芸用水和剤に関する。 The present invention relates to a wettable composition for agricultural and horticultural use containing a dithiocarbamate fungicide and an acetylenic diol surfactant. More specifically, the present invention relates to a wettable powder for agricultural and horticultural use that quickly adjusts to water when diluted in water and has less foaming particularly at a high concentration.
ジチオカーバメート系殺菌剤は非常に広範囲の病害に卓効を持ち、特に亜鉛イオン配位マンガニーズエチレンビスジチオカーバメート（以下「マンゼブ」と略記する。）は作物に対する安全性も高いことから、長年農園芸用殺菌剤として使用されている。農園芸用農薬組成物の使用場面では、乳剤、フロアブル、水和剤及び顆粒水和剤などに製剤化した薬剤を水で一定割合に希釈した薬液として、専用の散布装置を用いて対象となる作物に散布する処理方法が一般的である。このような水希釈製剤の求められる性能として、希釈時に薬剤が速やかに水になじみ、均一に分散し、また、分散状態を長く保持する、即ち懸垂性に優れることが望まれる。また、散布機器によっては実使用濃度よりも濃厚な希釈液を作製し、使用時に所定の濃度に再度希釈するような場合もあり、このような施用場面では高濃度水希釈液における分散安定性も重要である。水和剤においてこのような濡れ性、均一分散性を向上するためには濡れ効果の高い湿潤剤ならびに分散性の高い分散剤を併用して用いる技術が一般的に採用される。一方で、このように濡れ効果の高い湿潤剤ならびに分散性の高い分散剤を配合した場合、希釈液の泡立ちが問題となる場合があり、特に希釈倍率２００倍以下の高濃度で希釈する場面では顕著である。すなわち、泡立ちが過剰に起こった場合、希釈のための撹拌を行なっている間に容器から泡が溢れ出してきたり、また泡が薬液を送出するポンプに影響し、薬液の送液が不安定になるなどの問題が発生する。また、粉末状の水和剤は一般的に使用時の粉立ち防止や使用者と薬剤との接触を避けるため必要に応じて水溶性フィルム袋に包装することがあるが、水溶性のフィルムで一般に使用されることが多い成分であるポリビニルアルコールは単独でも泡立ちやすく、希釈液の泡立ちをさらに助長していることがある。 Dithiocarbamate fungicides are extremely effective in a wide range of diseases, and zinc ion-coordinated Manganese ethylenebisdithiocarbamate (hereinafter abbreviated as “manzeb”) is highly safe for crops. Used as a horticultural fungicide. In the use situation of agricultural and horticultural agricultural chemical compositions, the drug formulated into emulsion, flowable, wettable powder and granule wettable powder is diluted with water at a certain ratio and is targeted using a special spraying device. Treatment methods that are spread on crops are common. As the performance required for such a water-diluted preparation, it is desired that the drug quickly adapts to water during dilution, is uniformly dispersed, and maintains a dispersed state for a long time, that is, has excellent suspension properties. In addition, depending on the application equipment, there may be a case where a diluted solution that is thicker than the actual use concentration is prepared and diluted again to a predetermined concentration at the time of use. is important. In order to improve such wettability and uniform dispersibility in the wettable powder, a technique using a wetting agent having a high wetting effect and a dispersing agent having a high dispersibility is generally employed. On the other hand, when a wetting agent having a high wetting effect and a dispersing agent having a high dispersibility are blended in this way, foaming of the diluent may become a problem, particularly in a scene where dilution is performed at a high concentration of 200 times or less. It is remarkable. In other words, if excessive foaming occurs, bubbles may overflow from the container while stirring for dilution, or the bubbles may affect the pump that delivers the chemical solution, making the chemical solution unstable. The problem of becoming. In addition, powdered wettable powders are generally packaged in water-soluble film bags as needed to prevent dusting during use and to avoid contact between the user and the drug. Polyvinyl alcohol, which is a commonly used component, tends to foam even when used alone, and may further promote foaming of the diluted solution.
一般的にこのように泡立ちが問題となる場合、薬剤とは別に使用時に消泡剤を添加することがある。例えば農業分野では薬剤希釈液の調製時に外部からタンクに添加する消泡剤が市販されている。しかし、これらは泡が発生するたびに薬剤を添加する処理が必要で、それだけ手間や費用を要するという問題がある。また消泡効果が高い消泡剤としてシリコーン系の消泡剤が一般に知られており、これを水和剤にあらかじめ内添しておくこともできるが、保存期間が長いと消泡効果が低下すること、またシリコーン系消泡剤は親油性であるため、これを含有する水和剤は水に馴染みにくいという問題が発生する。 In general, when foaming becomes a problem in this way, an antifoaming agent may be added at the time of use separately from the drug. For example, in the agricultural field, an antifoaming agent that is added to the tank from the outside when preparing a drug diluent is commercially available. However, there is a problem that these require a process of adding a drug every time bubbles are generated, which requires much labor and cost. In addition, silicone-based antifoaming agents are generally known as antifoaming agents with high antifoaming effects, which can be pre-added into the wettable powder, but the antifoaming effect decreases with a long storage period. In addition, since the silicone-based antifoaming agent is oleophilic, there arises a problem that a wettable powder containing it is difficult to adjust to water.
一方、アセチレンジオール系界面活性剤と農薬の組み合わせについては、主に水で希釈せず水田などにそのまま施用される水面浮遊性製剤（ジャンボ剤）や水性懸濁製剤（フロアブル）の有効成分の拡展性向上に高い効果があることが知られている（例えば、特許文献１、２）。
また、特許文献３にはテトラキス（ヒドロキシメチル）ホスホニウム塩および界面活性剤との組み合わせで発生しうる泡をアセチレンジオール系界面活性剤が効果的に抑えることが可能であると記されている。しかしながら、農薬、特にジチオカーバメート系殺菌剤を配合した農園芸用水和剤の希釈液で発生する泡に対する効果については何ら記されていない。
On the other hand, for the combination of acetylenic diol surfactants and agricultural chemicals, the active ingredients in water-floating preparations (jumbo preparations) and aqueous suspension preparations (floorable) that are applied directly to paddy fields without being diluted with water are expanded. It is known that there is a high effect in improving malleability (for example, Patent Documents 1 and 2).
Patent Document 3 describes that acetylenic diol surfactants can effectively suppress bubbles that can be generated in combination with tetrakis (hydroxymethyl) phosphonium salts and surfactants. However, there is no description about the effect on the foam generated in the dilute solution of agricultural and horticultural wettable powder containing agrochemicals, especially dithiocarbamate fungicides.
本発明は、薬液調整時に水に馴染みやすく、また高濃度においても泡立ちの少ない農園芸用水和剤を提供することを目的とする。 An object of the present invention is to provide an agricultural and horticultural wettable powder which is easy to adjust to water at the time of preparation of a chemical solution and has less foaming even at a high concentration.
本発明者らは、上記の課題を解決するために鋭意研究を重ねた結果、マンゼブを含むジチオカーバメート系殺菌剤とアセチレンジオール系界面活性剤を含む水和剤が、水に馴染み易く、さらに高濃度における泡立ちが極めて少ないことを見出し、本発明を完成した。 As a result of intensive research to solve the above problems, the present inventors have found that a dithiocarbamate fungicide containing manzeb and a wettable powder containing an acetylenic diol surfactant are easy to adapt to water, and have a higher level. The inventors found that there was very little foaming at the concentration and completed the present invention.
すなわち本発明は、１種以上のジチオカーバメート系殺菌剤と、１種以上のアセチレンジオール系界面活性剤とを含むことを特徴とする農園芸用水和剤である。 That is, the present invention is an agricultural and horticultural wetting agent comprising one or more dithiocarbamate fungicides and one or more acetylenic diol surfactants.
本発明によれば、従来の組み合わせでは困難であった水への馴染みやすさ（水和性）と、特に希釈倍率２００倍以下の高濃度溶液における低起泡性とを両立する組成物を得ることができる。 According to the present invention, a composition that achieves both compatibility with water (hydratability), which has been difficult with conventional combinations, and low foaming in a high-concentration solution with a dilution ratio of 200 times or less is obtained. be able to.
本発明は、殺菌活性成分としての１種以上のジチオカーバメート系殺菌剤と、界面活性剤として１種以上のアセチレンジオール系界面活性剤とを含むことを特徴とする農園芸用水和剤である。 The present invention is an agricultural and horticultural wettable powder characterized by containing at least one dithiocarbamate fungicide as a fungicidal active ingredient and at least one acetylenic diol surfactant as a surfactant.
［成分及び組成］
本発明において使用するジチオカーバメート系殺菌剤としては、例えば、マンゼブ、プロピネブ、ジネブ、メチラム、マンネブ、ジラム、チウラム等が挙げられ、好適にはマンゼブである。ジチオカーバメート系殺菌剤としては、任意のジチオカーバメート系殺菌剤の１種又は２種以上が使用される。２種以上のジチオカーバメート系殺菌剤の組み合わせとしては、マンゼブと、マンゼブ以外のジチオカーバメート系殺菌剤の１種以上との組合せ、例えば、マンゼブと、プロピネブ、ジネブ、メチラム、マンネブ、ジラム及びチウラムから選択した１種以上との組合せが好ましい。
本発明に係るジチオカーバメート系殺菌剤の配合量は、農園芸用水和剤中に、通常、０．５〜９５質量％であり、好適には、１０〜９２質量％である。
[Ingredients and composition]
Examples of the dithiocarbamate fungicide used in the present invention include manzeb, propineb, dineb, methylam, manneb, ziram, thiuram and the like, and preferably manzeb. As the dithiocarbamate fungicide, one or more arbitrary dithiocarbamate fungicides are used. As a combination of two or more kinds of dithiocarbamate fungicides, a combination of manzeb and one or more dithiocarbamate fungicides other than manzeb, for example, manzeb and propineb, zineb, methylam, manneb, dilam and thiuram A combination with one or more selected is preferred.
The amount of the dithiocarbamate fungicide according to the present invention is usually 0.5 to 95% by mass, preferably 10 to 92% by mass, in the wettable powder for agriculture and horticulture.
本発明の農園芸用水和剤は、ジチオカーバメート系殺菌剤以外に、更にもう１種類以上の公知の農薬、例えば、殺菌剤、殺虫剤等を配合することもでき、それ自体の物理的性状に特に限定はない。ジチオカーバメート系殺菌剤と、ジチオカーバメート系殺菌剤以外のその他の農薬との組み合わせとして、（１）マンゼブと、１種以上のジチオカーバメート系殺菌剤以外のその他の農薬との組み合わせ、たとえば、マンゼブと、以下に具体的に述べる、ジチオカーバメート系殺菌剤以外のその他の殺菌剤及び殺虫剤から選択した１種以上との組み合わせ、（２）マンゼブと、１種以上のマンゼブ以外のジチオカーバメート系殺菌剤と、１種以上のジチオカーバメート系殺菌剤以外のその他の農薬との組み合わせ、例えば、マンゼブと、プロピネブ、ジネブ、メチラム、マンネブ、ジラム及びチウラムから選択した１種以上と、以下に具体的に述べる、ジチオカーバメート系殺菌剤以外のその他の殺菌剤及び殺虫剤から選択した１種以上との組み合わせが好ましい。
その他の農薬の配合量は、農園芸用水和剤中に、通常、０．５〜３０質量％であり、好適には、１〜２０質量％である。
In addition to the dithiocarbamate fungicide, the agricultural and horticultural wettable powder of the present invention may further contain one or more other known agricultural chemicals, such as fungicides, insecticides, etc. There is no particular limitation. As a combination of a dithiocarbamate fungicide and other agrochemicals other than the dithiocarbamate fungicide, (1) a combination of manzeb and one or more other agrochemicals other than the dithiocarbamate fungicide, for example, manzeb A combination of one or more selected from the other fungicides and insecticides other than dithiocarbamate fungicides, specifically described below, (2) Manzeb and one or more dithiocarbamate fungicides other than manzeb In combination with one or more other pesticides other than dithiocarbamate fungicides, such as manzeb and one or more selected from propineb, dineb, methylam, manneb, ziram and thiuram, specifically described below , With one or more selected from other fungicides and insecticides other than dithiocarbamate fungicides Seen together is preferable.
The blending amount of other agricultural chemicals is usually 0.5 to 30% by mass, preferably 1 to 20% by mass in the agricultural and horticultural wettable powder.
更なる殺菌剤としては、例えば、シメコナゾール、ヒドロキシイソキサゾール、テクロフタラム、ジクロメジン、フルスルファミド、ペンチオピラド、フルオピラム、フルキサピロキサド、アミスルブロム、シアゾファミド、ペンフルフェン、ボスカリド、アゾキシストロビン、ピコキシストロビン、ピラクロストロビン、ピリベンカルブ、ピロキロン、ジラム、チウラム、キャプタン、ＴＰＮ、フサライド、トリクロホスメチル、ホセチル、チオファネートメチル、ベノミル、カルベンタゾール、チアベンタゾール、ジフェノコナゾール、イミベンコナゾール、オキスポコナゾールフマル酸塩、ミクロブタニル、ジエトフェンカルブ、イプロジオン、メパニピリム、ビンクロゾリン、プロシミドン、フルオルイミド、オキシカルボキシン、メプロニル、フルトラニル、ペンシクロン、メタラキシル、メタラキシルＭ、オキサジキシル、トリアジメホン、ヘキサコナゾール、テブコナゾール、トリホリン、ブラストサイジンＳ、カスガマイシン、ポリオキシン、バリダマイシンＡ、ＰＣＮＢ、ダゾメット、トリアジン、プロベナゾール、イソプロチオラン、トリシクラゾール、テトラコナゾール、トリクラミド、オキソリニック酸、ジメトモルフ、シモキサニル、トルプロカルブ、チフルザミド、テブフロキンなどが挙げられる。好適には、シメコナゾール、シモキサニル、ペンチオピラド、メタラキシル、メタラキシルＭ、ジフェノコナゾール、イミベンコナゾール、オキスポコナゾールフマル酸塩、ミクロブタニルである。 Further fungicides include, for example, cimeconazole, hydroxyisoxazole, teclophthalam, diclomedin, fursulfamide, penthiopyrad, fluopyram, floxapyroxad, amisulbrom, cyazofamide, penflufen, boscalid, azoxystrobin, picoxystrobin, pyra Clostrobin, pyribencarb, pyroxylone, dilam, thiuram, captan, TPN, fusalide, triclofosmethyl, fosetyl, thiophanate methyl, benomyl, carbentazole, thiabendazole, difenoconazole, imibenconazole, oxpoconazole fumarate, microbutanyl , Dietofencarb, iprodione, mepanipyrim, vinclozolin, procymidone, fluorimide, oxycarboxin, Pronyl, flutolanil, pencyclon, metalaxyl, metalaxyl M, oxadixil, triadimethone, hexaconazole, tebuconazole, triphorin, blasticidin S, kasugamycin, polyoxin, validamycin A, PCNB, dazomet, triazine, probenazole, isoprothiolane, tricyclazole, tetraconazole , Triclamide, oxolinic acid, dimethomorph, simoxanyl, tolprocarb, tifluzamide, tebufloquine and the like. Preferred are cimeconazole, simoxanyl, penthiopyrad, metalaxyl, metalaxyl M, difenoconazole, imibenconazole, oxpoconazole fumarate, and microbutanyl.
更なる殺虫剤としては、例えば、インドキサカルブ、クロマフェノジド、ピリミジフェン、ミルベメクチン、レピメクチン、エマメクチン安息香酸塩、メソミル、アセフェート、ジノテフラン、チオシクラム、イミダクロプリド、ニテンピラム、アセタミプリド、クロチアニジン、チアメトキサム、チアクロプリド、ピリダフェンチオン、ジメトエート、ＰＭＰ、ＣＶＭＰ、ジメチルビンホス、ＤＥＰ、ＮＡＣ、ＭＴＭＣ、ＭＩＰＣ、ＰＨＣ、ＭＰＭＣ、ＸＭＣ、ベンフラカルブ、ピリミカルブ、オキサミル、チオジカルブ、シペルメトリン、カルタップ、ベンスルタップ、ジフルベンズロン、テフルベンズロン、クロルフルアズロン、ブプロフェジン、ヘキシチアゾクス、酸化フェンブタスズ、ピリダベン、クロフェンテジン、バチルス・チューリンゲンシス及びそれらが生産する毒素、ＭＰＰ、ＭＥＰ、ダイアジノン、イソキサチオン、エチルチオメトン、エトフェンプロックス、トラロメトリン、シラフルオフェン、シクロプロトリン、ベンフラカルブ、メタフルミゾン、クロラントラニリプロール、フィプロニル、ピメトロジン、フルベンジアミド、シアントラニリプロール、スピネトラム、ピリダリルなどが挙げられる。 Further insecticides include, for example, indoxacarb, chromafenozide, pyrimidifen, milbemectin, lepimectin, emamectin benzoate, mesomil, acephate, dinotefuran, thiocyclam, imidacloprid, nitenpyram, acetamiprid, clothianidone, thiamethoxidithia, thiapridoxithate, thiaprixam PMP, CVMP, dimethylvinphos, DEP, NAC, MTMC, MIPC, PHC, MPMC, XMC, benfracarb, pirimicarb, oxamyl, thiodicarb, cypermethrin, cartap, bensultap, diflubenzuron, teflubenzuron, chlorfluazuron, buprofezin, hexithiazox, Fenbutazin oxide, pyridaben, clofentezine, bacillus Thuringiensis and the toxins they produce, MPP, MEP, diazinon, isoxathion, ethylthiomethone, etofenprox, tralomethrin, silafluophene, cycloprotorin, benfuracarb, metaflumizone, chlorantraniliprolol, fipronil, pymetrozine, fulvendiamide, cyantranilip Roll, spinetoram, pyridalyl, etc. are mentioned.
本発明において使用するアセチレンジオール系界面活性剤には、アセチレンジオール及びアセチレンジオールのアルキレンオキサイド付加物が含まれる。 The acetylene diol surfactant used in the present invention includes acetylene diol and an alkylene oxide adduct of acetylene diol.
アセチレンジオールは、一般式ＨＯＣＲ1Ｒ2−Ｃ≡Ｃ−ＣＲ３Ｒ４ＯＨ（Ｒ1 , Ｒ2 , Ｒ3及びＲ4は、同一又は異なって、Ｃ1〜Ｃ8のアルキル基を示す。）で表される化合物であり、アルキル基として、メチル、エチル、ｎ−プロピル、イソプロピル、ｎ−ブチル、ｓｅｃ-ブチル、イソブチル、tert-ブチル等が挙げられる。アセチレンジオールには、例えば、2,5−ジメチル−3−ヘキシン−2,5−ジオール、3,6−ジメチル−4−オクチン−3,6−ジオール、2,4,7,9−テトラメチル−5−デシン−4,7−ジオール等が挙げられる。
アセチレンジオールのアルキレンオキサイド付加物は、例えば、上記アセチレンジオールにエチレンオキサイド及び／又はプロピレンオキサイド等のアルキレンオキサイドを付加した界面活性剤である。
アセチレンジオール系界面活性剤の配合量は、農園芸用水和剤中に、通常、０．０１〜１０質量％であり、好適には、０．１〜２質量％である。
また、アセチレンジオールを他のグリコール類やアルコールで希釈し、ホワイトカーボンに吸着させることで粉末化して使用することもできる。
Acetylene diol is represented by the general formula HOCR 1 R 2 —C≡C—CR 3 R 4 OH (R 1 , R 2 , R 3 and R 4 are the same or different and represent a C 1 to C 8 alkyl group. And alkyl groups include methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl and the like. Acetylene diols include, for example, 2,5-dimethyl-3-hexyne-2,5-diol, 3,6-dimethyl-4-octyne-3,6-diol, 2,4,7,9-tetramethyl- And 5-decyne-4,7-diol.
The alkylene oxide adduct of acetylene diol is, for example, a surfactant obtained by adding an alkylene oxide such as ethylene oxide and / or propylene oxide to the acetylene diol.
The blending amount of the acetylenic diol-based surfactant is usually 0.01 to 10% by mass and preferably 0.1 to 2% by mass in the agricultural and horticultural wettable powder.
Moreover, acetylene diol can also be used by diluting with other glycols and alcohol, and making it adsorb | suck to white carbon and making it powder.
本発明の農園芸用水和剤は、必要に応じて、その他の界面活性剤又は補助剤を配合することができる。 The agricultural and horticultural wettable powder of the present invention can be blended with other surfactants or adjuvants as necessary.
１つの実施形態において使用されるその他の界面活性剤としては、通常の農薬に用いられるものであれば特に限定はなく、陰イオン性界面活性剤、非イオン性界面活性剤、陽イオン性界面活性剤、両性イオン性界面活性剤などのいずれの界面活性剤をも用いることができ、これらの１種又は２種以上を用いることができる。 The other surfactant used in one embodiment is not particularly limited as long as it is used for ordinary agricultural chemicals, and is an anionic surfactant, a nonionic surfactant, a cationic surfactant. Any surfactant such as an agent and a zwitterionic surfactant can be used, and one or more of these can be used.
陰イオン性界面活性剤としては、例えば、α−オレフィンスルホン酸、α−スルホ脂肪酸、ナフタレンスルホン酸、ナフタレンスルホン酸の縮合物、フェノールスルホン酸、アルキルナフタレンスルホン酸、アルケニルスルホン酸、アルキルスルホン酸、アルキルアリールスルホン酸、ポリスチレンスルホン酸、ポリアクリル酸、ポリカルボン酸、スチレンスルホン酸とカルボン酸の縮合物、ポリオキシエチレンアルキルエーテル硫酸エステル、ポリオキシエチレンアルキルアリールエーテル硫酸エステル、アルキル又はジアルキルスルホコハク酸、高級脂肪酸等のアルカリ金属塩、アルカリ土類金属塩、アンモニウム塩、又は種々のアミン塩、ポリオキシエチレンアルキルエーテルリン酸エステル、ポリオキシエチレンアルキルアリールエーテルリン酸エステル、ポリオキシエチレンアリールアリールエーテルリン酸エステル及びこれらリン酸エステルのアルカリ金属塩、アルカリ土類金属塩、アンモニウム塩、又は種々のアミン塩などが挙げられ、好適には、アルキルナフタレンスルホン酸縮合物の塩、リグニンスルホン酸塩、ポリアクリル酸塩、アルキルベンゼンスルホン酸塩、アルキル硫酸エステル塩又は（ジ）アルキルスルホコハク酸塩である。 Examples of the anionic surfactant include α-olefin sulfonic acid, α-sulfo fatty acid, naphthalene sulfonic acid, condensate of naphthalene sulfonic acid, phenol sulfonic acid, alkyl naphthalene sulfonic acid, alkenyl sulfonic acid, alkyl sulfonic acid, Alkylarylsulfonic acid, polystyrenesulfonic acid, polyacrylic acid, polycarboxylic acid, condensate of styrenesulfonic acid and carboxylic acid, polyoxyethylene alkyl ether sulfate ester, polyoxyethylene alkyl aryl ether sulfate ester, alkyl or dialkyl sulfosuccinic acid, Alkali metal salts such as higher fatty acids, alkaline earth metal salts, ammonium salts, or various amine salts, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl aryl amines Examples thereof include telluric acid esters, polyoxyethylene arylaryl ether phosphoric acid esters, and alkali metal salts, alkaline earth metal salts, ammonium salts, and various amine salts of these phosphoric acid esters, preferably alkyl naphthalenesulfonic acid. A salt of a condensate, a lignin sulfonate, a polyacrylate, an alkylbenzene sulfonate, an alkyl sulfate ester salt, or a (di) alkylsulfosuccinate.
非イオン性界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンアリールアリールエーテル、ポリオキシエチレンアルキルエステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンとポリオキシプロピレンの共重合物、高級脂肪酸アルカノールアマイドなどが挙げられ、水に対する溶解度や湿潤作用の点から、好適には、ＨＬＢ値が９〜１３の範囲のものである。 Examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene aryl aryl ether, polyoxyethylene alkyl ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene A copolymer of ethylene and polyoxypropylene, a higher fatty acid alkanol amide, and the like can be mentioned. From the viewpoint of water solubility and wet action, the HLB value is preferably in the range of 9-13.
尚、これらエチレンオキサイドを付加したタイプの界面活性剤においては、その一部にプロピレンオキサイドを含有してもよい。 In addition, in the type of surfactant to which these ethylene oxides are added, propylene oxide may be contained in a part thereof.
陽イオン性界面活性剤としては、例えば、アルキルアミン塩、第４級アンモニウム塩、ピリジニウム塩、アミンオキサイドなどが挙げられる。 Examples of the cationic surfactant include alkylamine salts, quaternary ammonium salts, pyridinium salts, amine oxides, and the like.
両性イオン性界面活性剤としては、例えば、アミノ酸型やベタイン型の界面活性剤が挙げられる。 Examples of the zwitterionic surfactant include amino acid type and betaine type surfactants.
本発明の１つの実施形態で用いられるその他の界面活性剤としては、好適には、陰イオン性界面活性剤又は非イオン性界面活性剤であり、より好適には、アルキルナフタレンスルホン酸ナトリウムホルマリン縮合物、ポリアクリル酸ナトリウム、リグニンスルホン酸ナトリウム、リグニンスルホン酸カルシウム、ジオクチルスルホコハク酸ナトリウム又はＨＬＢ値が９〜１３の非イオン性界面活性剤である。 The other surfactant used in one embodiment of the present invention is preferably an anionic surfactant or a nonionic surfactant, and more preferably sodium alkylnaphthalene sulfonate formalin condensation. Products, sodium polyacrylate, sodium lignin sulfonate, calcium lignin sulfonate, sodium dioctyl sulfosuccinate, or a nonionic surfactant having an HLB value of 9-13.
本発明の１つの実施形態で用いられるその他の界面活性剤の量は、通常、農園芸用水和剤中に、０．０１〜２０質量％であり、好適には、０．１〜１０質量％である。 The amount of the other surfactant used in one embodiment of the present invention is generally 0.01 to 20% by mass, preferably 0.1 to 10% by mass in the wettable powder for agriculture and horticulture. It is.
本発明の農園芸用水和剤には、通常の農園芸用水和剤に用いられるその他の添加剤を含有させることができ、添加剤としては、例えば、着色剤、無機及び有機担体、防腐剤、ｐＨ調節剤などが挙げられ、これらは使用される農薬活性成分の種類に応じて選択すればよい。 The agricultural and horticultural wettable powder of the present invention can contain other additives used in ordinary agricultural and horticultural wettable powders. Examples of the additive include colorants, inorganic and organic carriers, preservatives, A pH adjuster etc. are mentioned, These should just be selected according to the kind of pesticidal active ingredient used.
着色剤としては、通常農薬に用いられるものであれば特に限定はなく、例えば、色素が挙げられ、好適には、ブリリアントブルーＦＣＦ、シアニングリーンＧ又はエリオグリーンＧである。用いられる着色剤の量は、通常、農園芸用水和剤中に、０．０５〜０．５質量％であり、好適には、０．１〜０．３質量％である。 The colorant is not particularly limited as long as it is usually used for agricultural chemicals, and examples thereof include pigments, and brilliant blue FCF, cyanine green G, and Erio green G are preferable. The amount of the colorant to be used is usually 0.05 to 0.5% by mass, preferably 0.1 to 0.3% by mass in the agricultural and horticultural wettable powder.
本発明の農園芸用水和剤に配合出来る担体としては、例えば、ベントナイト、タルク、クレー、カオリン、珪藻土、無晶形二酸化ケイ素、炭酸カルシウム及び炭酸マグネシウムのような、一般的に農薬の担体として用いられる鉱物質微粉；グルコース、砂糖及び乳糖のような糖類、カルボキシメチルセルロース及び／又はその塩類、澱粉、デキストリン及び／又はその誘導体並びに微結晶セルロースのような有機物；硫酸ナトリウム、硫酸アンモニウム及び塩化カリウムのような水溶性無機塩類；又は尿素であり得、好適にはデキストリンである。担体の配合量は、本発明の農園芸用水和剤の必須成分を除いた必要な最小量であり、担体の種類により異なるが、通常、農園芸用水和剤中に、０．１〜９０質量％であり、好適には、０．５〜７０質量％である。 Carriers that can be blended in the agricultural and horticultural wettable powder of the present invention are generally used as agrochemical carriers such as bentonite, talc, clay, kaolin, diatomaceous earth, amorphous silicon dioxide, calcium carbonate and magnesium carbonate. Mineral fine powder; sugars such as glucose, sugar and lactose, carboxymethylcellulose and / or its salts, starch, dextrin and / or derivatives thereof and organic substances such as microcrystalline cellulose; water-soluble such as sodium sulfate, ammonium sulfate and potassium chloride Inorganic salts; or urea, preferably dextrin. The blending amount of the carrier is a necessary minimum amount excluding essential components of the agricultural and horticultural wettable powder of the present invention, and varies depending on the type of the carrier, but usually 0.1 to 90 mass in the agricultural and horticultural wettable powder. %, And preferably 0.5 to 70% by mass.
防腐剤としては、通常農薬に用いられるものであれば特に限定はなく、好適には、ソルビン酸、ソルビン酸カリウム、パラクロロメタキシレノ−ル、パラオキシ安息香酸ブチル、又はデヒドロ酢酸ナトリウムである。用いられる防腐剤の量は、通常、農園芸用水和剤中に、０．１〜３質量％であり、好適には、０．２〜２質量％である。 The preservative is not particularly limited as long as it is usually used for agricultural chemicals, and is preferably sorbic acid, potassium sorbate, parachlorometaxylenol, butyl paraoxybenzoate, or sodium dehydroacetate. The amount of the preservative used is usually 0.1 to 3% by mass, preferably 0.2 to 2% by mass in the wettable powder for agriculture and horticulture.
ｐＨ調節剤としては、通常農薬に用いられるものであれば特に限定はなく、例えば、塩酸、リン酸のような無機酸；クエン酸、フタル酸、コハク酸のような有機酸；クエン酸ナトリウム、フタル酸水素カリウムのような有機金属塩；リン酸水素二ナトリウム、リン酸二水素ナトリウム、リン酸水素二カリウム、リン酸二水素カリウム、炭酸ナトリウム、炭酸カリウム、ホウ酸ナトリウムのような無機金属塩；水酸化ナトリウム、水酸化カリウムのような水酸化物；及び、トリエタノールアミンのような有機アミン類等を挙げることができ、好適には、無機酸、無機金属塩、水酸化物であり、より好適には、塩酸、クエン酸、コハク酸、水酸化ナトリウム、水酸化カリウム又は炭酸ナトリウムである。また、使用されるｐＨ調節剤は、１種又は２種以上を併用することができる。 The pH adjuster is not particularly limited as long as it is usually used for agricultural chemicals. For example, inorganic acids such as hydrochloric acid and phosphoric acid; organic acids such as citric acid, phthalic acid and succinic acid; sodium citrate, Organometallic salts such as potassium hydrogen phthalate; inorganic metal salts such as disodium hydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate, potassium dihydrogen phosphate, sodium carbonate, potassium carbonate, sodium borate And hydroxides such as sodium hydroxide and potassium hydroxide; and organic amines such as triethanolamine, etc., preferably inorganic acids, inorganic metal salts and hydroxides; More preferred is hydrochloric acid, citric acid, succinic acid, sodium hydroxide, potassium hydroxide or sodium carbonate. Moreover, the pH adjuster used can use 1 type (s) or 2 or more types together.
ｐＨ調節剤は、通常、水で０．１〜５規定の適当な濃度に希釈し、その希釈液を０．０１〜５質量％添加することにより使用される。 The pH adjuster is usually used by diluting with water to an appropriate concentration of 0.1 to 5 N and adding the diluted solution in an amount of 0.01 to 5% by mass.
［製造方法］
本発明の農園芸用水和剤は、種々の方法で製造することができる。例えば、乾式粉砕する場合は、ジチオカーバメート系殺菌剤及びアセチレンジオール系界面活性剤を少なくとも含み、また必要に応じてその他の界面活性剤及び担体と共に混合し、以下のような乾式粉砕機を用いて、所定の粒度まで乾式粉砕する。次いで必要に応じてその他補助成分を加えて混合することにより、本発明の農園芸用水和剤を得ることができる。これらの成分は一度に配合してもよく、または成分ごとに分割して配合し、その都度粉砕しながら所定の粒度に調整しても良い。
[Production method]
The agricultural and horticultural wettable powder of the present invention can be produced by various methods. For example, in the case of dry pulverization, it contains at least a dithiocarbamate fungicide and an acetylenic diol surfactant, and if necessary, is mixed with other surfactants and carriers, using a dry pulverizer as described below. Then, dry-grind to a predetermined particle size. Then, if necessary, other auxiliary components are added and mixed to obtain the wettable powder for agriculture and horticulture of the present invention. These components may be blended at once, or may be blended separately for each component, and adjusted to a predetermined particle size while being pulverized each time.
乾式粉砕機は、例えば、ＳＫ−ジェット・オー・マイザー（株式会社セイシン企業）、シングルトラック・ジェットミル（株式会社セイシン企業）等のジェットミル、ＡＣＭパルペライザー（ホソカワミクロン株式会社）、サンプルミル（株式会社ダルトン）等のハンマーミル、ピンミル、ボールミル、ターボミル等が挙げられる。 Examples of the dry pulverizer include jet mills such as SK-Jet O-Mizer (Seishin Enterprise Co., Ltd.), Single Track Jet Mill (Seishin Enterprise Co., Ltd.), ACM Pulperizer (Hosokawa Micron Corp.), Sample Mill (Co., Ltd.) Dalton) hammer mill, pin mill, ball mill, turbo mill and the like.
［使用方法］
本発明の農園芸用水和剤の使用方法としては、通常の農薬散布方法を用いることができる。本発明の農園芸用水和剤を水に希釈して使用する場合、通常、２〜２００００倍程度に希釈して散布液を調製し、この散布液を散布することができる。また散布液の調整にあたっては、通常行なわれているように一度で所定濃度に希釈するという方法の他に、一旦実使用濃度よりも濃厚な希釈液を作製しておき、使用時に所定の濃度に再度希釈するという方法を取ってもよい。散布液の散布方法としては、希釈液をスプリンクラー等の噴霧器やジョロ等による散布、又は近年普及してきているラジコンヘリ（ＲＣヘリ）等のラジコンによる方法などが挙げられる。
[how to use]
As a method for using the wettable powder for agricultural and horticultural use of the present invention, an ordinary agricultural chemical spraying method can be used. When diluting and using the agricultural and horticultural wettable powder of the present invention in water, it is usually possible to prepare a spray liquid by diluting to about 2 to 20000 times and spray this spray liquid. In addition, when adjusting the spray solution, in addition to the method of diluting to a predetermined concentration at once, as usual, prepare a diluted solution that is thicker than the actual use concentration, and adjust the concentration to the predetermined concentration during use. You may take the method of diluting again. Examples of the spraying method of the spraying liquid include spraying the diluting liquid with a sprayer such as a sprinkler or a sprinkler, or a method using a radio control such as a radio control helicopter (RC helicopter) that has become popular in recent years.
本発明の農園芸用水和剤は湿気を避けるため、防湿性の容器などに保存するのが好ましい。このような容器としては、例えば、樹脂、アルミ、紙等を必要に応じて貼り合わせた材料や、樹脂や紙等の表面にアルミや珪酸を蒸着させた材料からなる瓶、袋、箱などが望ましい。また、使用時の粉立ち防止や使用者と薬剤の接触を避けるため、必要に応じて水溶性フィルム袋に包装して防湿性の容器などに保存して使用することができる。水溶性フィルムは、水に迅速に溶解あるいは分散するフィルムが適当であり、フィルムの素材としては、ポリビニルアルコール、ポリオキシポリアルキレングリコール、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、メチルセルロース、カルボキシメチルセルロースナトリウム、ポリアクリル酸ナトリウム、アルギン酸、ゼラチン、プルラン及び可溶化澱粉等が例示される。また、用いられる水溶性フィルムの厚さは特に限定されないが、一般に２０μｍ〜１００μｍ程度が好ましい。 In order to avoid moisture, the agricultural and horticultural wettable powder of the present invention is preferably stored in a moisture-proof container or the like. Examples of such containers include bottles, bags, and boxes made of a material obtained by laminating resin, aluminum, paper, or the like as needed, or a material obtained by depositing aluminum or silicic acid on the surface of resin, paper, etc. desirable. Moreover, in order to prevent powdering at the time of use and to avoid contact between the user and the medicine, it can be used after being packaged in a water-soluble film bag and stored in a moisture-proof container. As the water-soluble film, a film that dissolves or disperses quickly in water is suitable. The material of the film is polyvinyl alcohol, polyoxypolyalkylene glycol, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylcellulose, sodium carboxymethylcellulose, polyacrylic. Examples thereof include sodium acid, alginic acid, gelatin, pullulan, and solubilized starch. Moreover, the thickness of the water-soluble film used is not particularly limited, but generally about 20 μm to 100 μm is preferable.
以下に、実施例、比較例及び試験例を示して、本発明をさらに詳細に説明するが、本発明はこれらに限定されるものではない。なお、ここにおいて用いられる％及び部は、特に記載がない限り、全て質量に関する％及び部を示す。 Hereinafter, the present invention will be described in more detail with reference to Examples, Comparative Examples, and Test Examples, but the present invention is not limited thereto. In addition, unless otherwise indicated,% and part used here show% and part regarding mass.
[実施例１]
マンゼブ原体 ９１部、サーフィノール１０４Ｓ（２，４，７，９−テトラメチル−５−デシン−４，７−ジオール、日信化学工業製）０．２部、パールレックスＮＰ（リグニンスルホン酸ナトリウム、日本製紙ケミカル製）３部、カオリンＨＡ（カオリン、山陽クレー工業製）５．８部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Example 1]
Manzeb active ingredient 91 parts, Surfynol 104S (2,4,7,9-tetramethyl-5-decyne-4,7-diol, manufactured by Nissin Chemical Industry) 0.2 parts, Pearl Rex NP (sodium lignin sulfonate) , Nippon Paper Chemicals Co., Ltd.) 3 parts and kaolin HA (Kaolin, Sanyo Clay Industry Co., Ltd.) 5.8 parts were uniformly mixed, then mixed and pulverized by Fuji powder sample mill to obtain a wettable powder.
[実施例２]
マンゼブ原体 ９１部、サーフィノール１０４Ｓ １部、パールレックスＣＰ（リグニンスルホン酸カルシウム、日本製紙ケミカル製）３部、昭和微粉クレー（クレー、昭和ＫＤＥ製）５部を均一に混合後、ジェット・オー・マイザー０１０１型により混合、粉砕し、水和剤を得た。
[Example 2]
91 parts Manzeb active ingredient, 1 part Surfinol 104S, 3 parts Pearl Rex CP (calcium lignin sulfonate, Nippon Paper Chemicals), 5 parts Showa fine clay (clay, Showa KDE) 5 parts, -Mixing and pulverizing with Mizer 0101 type gave a wettable powder.
［実施例３］
マンゼブ原体 ７４．５部、シメコナゾール原体 ２．４部、サーフィノール１０４Ｓ ２部、パールレックスＣＰ １部、カオリンＨＡ ２０．１部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Example 3]
74.5 parts of Manzeb base, 2.4 parts of Cimeconazole base, 2 parts of Surfinol 104S, 1 part of Pearlex CP, 20.1 parts of Kaolin HA, and then mixed and pulverized by Fuji powder sample mill To obtain a wettable powder.
［実施例４］
マンゼブ原体 ７４．５部、シモキサニル原体 １２．３部、サーフィノール１０４Ｓ １部、サンエキスＰ２５２（リグニンスルホン酸ナトリウム、日本製紙ケミカル製）１部、昭和微粉クレー １１．２部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Example 4]
Uniform mixing of 74.5 parts of Manzeb base, 12.3 parts of Simoxanil base, 1 part of Surfynol 104S, 1 part of Sun Extract P252 (sodium lignin sulfonate, manufactured by Nippon Paper Chemicals), and 11.2 parts of Showa fine clay Then, it mixed and grind | pulverized with the Fuji powder sample mill, and the wettable powder was obtained.
［実施例５］
マンゼブ原体 ７４．５部、ペンチオピラド原体 ４．５部、サーフィノール１０４Ｓ ０．５部、パールレックスＣＰ ２部、モルウェットＤ４２５パウダー（アルキルナフタレンスルホン酸ナトリウムホルマリン縮合物、アクゾノーベル製）２部、ソルポール５０５０ （ジアルキルスルホコハク酸塩、東邦化学工業製）０．５部、昭和微粉クレー １６部を均一に混合後、ジェット・オー・マイザー０１０１型により混合、粉砕し、水和剤を得た。
[Example 5]
Manzeb active ingredient 74.5 parts, Penthiopyrad active substance 4.5 parts, Surfynol 104S 0.5 part, Pearl Rex CP 2 parts, Morwet D425 powder (alkyl naphthalene sodium sulfonate formalin condensate, Akzo Nobel) 2 parts Solpol 5050 (dialkylsulfosuccinate, manufactured by Toho Chemical Industry Co., Ltd.) 0.5 part and Showa fine powder clay 16 parts were uniformly mixed, and then mixed and pulverized by Jet-O-Mizer 0101 type to obtain a wettable powder.
[比較例１]
マンゼブ原体９１部、サンエキスＰ２５２ ３部、昭和微粉クレー ６部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Comparative Example 1]
After mixing uniformly 91 parts of Manzeb, 3 parts of Sun Extract P252, and 6 parts of Showa Fine Clay, it was mixed and pulverized by Fuji Powder Sample Mill to obtain a wettable powder.
[比較例２]
マンゼブ原体 ９１部、サンエキスＰ２０１（リグニンスルホン酸カルシウム、日本製紙ケミカル製）３部、ソルポール５０５０ １部、昭和微粉クレー ５部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Comparative Example 2]
91 parts of Manzeb active ingredient, 3 parts of sun extract P201 (calcium lignin sulfonate, manufactured by Nippon Paper Chemicals), 1 part of Solpol 5050, 5 parts of Showa fine clay are mixed and ground by Fuji powder sample mill. A wettable powder was obtained.
[比較例３]
マンゼブ原体 ９１部、パールレックスＣＰ ３部、ニューカルゲンＳＸ−Ｃ（アルキルベンゼンスルホン酸金属塩、竹本油脂製）１部、昭和微粉クレー ５部を均一に混合後、ジェット・オー・マイザー０１０１型により混合、粉砕し、水和剤を得た。
[Comparative Example 3]
Manzeb base 91 parts, Pearl Rex CP 3 parts, New Calgen SX-C (alkyl benzene sulfonic acid metal salt, made by Takemoto Yushi) 1 part, Showa fine powder clay 5 parts after uniform mixing, Jet Ohmizer 0101 type Mixing and grinding gave a wettable powder.
［比較例４］
マンゼブ原体 ７４．５部、シメコナゾール原体 ２．４部、hostapon TPHC（脂肪酸メチルタウリンナトリウム、クラリアント製）３部、パールレックスＣＰ １部、カオリンＨＡ １９．１部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Comparative Example 4]
74.5 parts of Manzeb active ingredient, 2.4 parts of simeconazole active ingredient, 3 parts of hostapon TPHC (sodium fatty acid methyltaurine, Clariant), 1 part of Pearl Rex CP and 19.1 parts of Kaolin HA are mixed uniformly. The powder was mixed and pulverized by a powder sample mill to obtain a wettable powder.
［比較例５］
マンゼブ原体７４．５部、シモキサニル原体１２．３部、パールレックスＮＰ １部、昭和微粉クレー １２．２部を均一に混合後、不二パウダルサンプルミルにより混合、粉砕し、水和剤を得た。
[Comparative Example 5]
After uniformly mixing 74.5 parts of Manzeb active ingredient, 12.3 parts of Simoxanil active ingredient, 1 part of Pearl Rex NP, 12.2 parts of Showa fine clay, mixed and pulverized by Fuji Powder Sample Mill, wettable powder Got.
［比較例６］
マンゼブ原体 ７４．５部、ペンチオピラド原体 ４．５部、パールレックスＣＰ ２部、モルウェットＤ４２５パウダー ２部、ソルポール５０５０ ２部、昭和微粉クレー １５部を均一に混合後、ジェット・オー・マイザー０１０１型により混合、粉砕し、水和剤を得た。
[Comparative Example 6]
Uniform mixing of 74.5 parts of Manzeb active ingredient, 4.5 parts of pentiopyrad active ingredient, 2 parts of Pearl Rex CP, 2 parts of Morwet D425 powder, 2 parts of Solpol 5050, 15 parts of Showa fine clay, Jet-O-Mizer A wettable powder was obtained by mixing and grinding with 0101 type.
［試験例１］（水和性の測定）
５００ｍｌのビーカーに２０℃の３度硬水２００ｍｌを入れ、これに試料５ｇを３５５μｍの標準ふるいを通過させて、水面上約１０ｃｍの位置よりうすく広がるように落した。試料を落し終わってから水面下に没するまでの時間を測定して水和性とした。結果を表１に示す。
[Test Example 1] (Measurement of hydration property)
A 500 ml beaker was charged with 200 ml of 3 degree hard water at 20 ° C., and 5 g of the sample was passed through a 355 μm standard sieve and dropped so as to spread slightly from a position of about 10 cm above the water surface. The time from when the sample was dropped to when it was submerged under the surface of the water was measured to make it hydrated. The results are shown in Table 1.
［試験例２］（起泡性の測定）
試料４．１７ｇを２０℃の蒸留水を定量入れた２５０ｍｌ有栓シリンダーにとり、３０秒間に１５回倒立した後、静置した。静置１分後、泡の高さを測定した。結果を試験例１の結果と併せて表１に示す。
試験例１〜２より明らかなように、本発明による農園芸用水和剤は比較例として挙げた公知技術等による製剤では達成困難であった良好な水和性と、良好な起泡性との両立した農園芸用水和剤を得ることができた。
[Test Example 2] (Measurement of foamability)
4.17 g of the sample was placed in a 250 ml stoppered cylinder filled with distilled water at 20 ° C., inverted 15 times for 30 seconds, and allowed to stand. After 1 minute of standing, the height of the foam was measured. The results are shown in Table 1 together with the results of Test Example 1.
As is clear from Test Examples 1 and 2, the agricultural and horticultural wettable powder according to the present invention has good hydrating properties that were difficult to achieve with the preparations according to the known techniques listed as comparative examples, and good foaming properties. A consistent wettable powder for agriculture and horticulture could be obtained.
［試験例３］
試料１００ｇを水溶性ＰＶＡフィルムで作製した袋（縦２１０ｍｍ横１４８ｍｍの長方形の形状）に入れ、水溶性パック入り水和剤を作製した。作製したパック１つを蒸留水６Ｌに溶解した後、その溶液を定量入れた２５０ｍｌ有栓シリンダーにとり、３０秒間に１５回倒立した後、静置した。静置１分後、泡の高さを測定した。結果を試験例２の結果と合わせて表２に示す。
試験例３より明らかなように、本発明による農園芸用水和剤は水溶性ＰＶＡフィルムに入れて溶解した場合、水和剤単独よりさらに低い起泡性を得ることができる。
[Test Example 3]
100 g of a sample was placed in a bag made of a water-soluble PVA film (rectangular shape having a length of 210 mm and a width of 148 mm) to prepare a wettable powder containing a water-soluble pack. After dissolving one prepared pack in 6 L of distilled water, the solution was placed in a 250 ml stoppered cylinder containing a fixed amount of the solution, inverted 15 times for 30 seconds, and allowed to stand. After 1 minute of standing, the height of the foam was measured. The results are shown in Table 2 together with the results of Test Example 2.
As apparent from Test Example 3, when the wettable powder for agriculture and horticultural use according to the present invention is dissolved in a water-soluble PVA film, the foamability lower than that of the wettable powder alone can be obtained.
本発明は、従来の組み合わせでは困難であった水への馴染みやすさ（水和性）と、特に希釈倍率２００倍以下の高濃度溶液における低起泡性を両立するので、農園芸用水和剤として有用である。 The present invention achieves both compatibility with water (hydration), which has been difficult with conventional combinations, and low foaming in a high-concentration solution with a dilution ratio of 200 times or less. Useful as.
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