JP2013504152A5 - - Google Patents

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JP2013504152A5
JP2013504152A5 JP2012527305A JP2012527305A JP2013504152A5 JP 2013504152 A5 JP2013504152 A5 JP 2013504152A5 JP 2012527305 A JP2012527305 A JP 2012527305A JP 2012527305 A JP2012527305 A JP 2012527305A JP 2013504152 A5 JP2013504152 A5 JP 2013504152A5
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composition according
weight
composition
organometallic compound
metal
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JP2012527305A
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JP2013504152A (en
JP5984671B2 (en
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Priority claimed from PCT/EP2010/062775 external-priority patent/WO2011026852A1/en
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Publication of JP2013504152A5 publication Critical patent/JP2013504152A5/ja
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Claims (14)

基材上に電極を印刷するための組成物であって、
それぞれ組成物の合計質量に対して、５０〜９０質量％の導電性粒子、０〜７質量％のガラスフリット、０．１〜５質量％の、レーザー照射のための少なくとも１種の吸収剤、０〜８質量％の少なくとも１種のマトリクス材料、０〜８質量％の少なくとも１種の有機金属化合物、３〜５０質量％の、溶媒としての水、０〜６５質量％の少なくとも１種の歩留まり向上剤、及び０〜５質量％の少なくとも１種の添加剤を含み、及び
前記歩留まり向上剤は、水の蒸発を遅らせるための遅延剤であり、及び
前記添加剤として、分散剤、チキソトロープ剤、可塑剤、湿潤剤、消泡剤、乾燥剤、架橋剤、錯化剤、及び／又は伝導性ポリマー粒子が使用される、組成物。 A composition for printing an electrode on a substrate,
50 to 90% by weight of conductive particles, 0 to 7% by weight of glass frit, 0.1 to 5% by weight of at least one absorber for laser irradiation, each based on the total weight of the composition, 0-8% by weight of at least one matrix material, 0-8% by weight of at least one organometallic compound, 3-50% by weight of water as solvent, 0-65% by weight of at least one yield. An improver, and 0 to 5% by weight of at least one additive, and the yield improver is a retarder for delaying water evaporation, and as the additive, a dispersant, a thixotropic agent, A composition in which plasticizers, wetting agents, antifoaming agents, drying agents, crosslinking agents, complexing agents and / or conductive polymer particles are used. 導電性粒子が、銀、金、アルミニウム、白金、パラジウム、スズ、ニッケル、カドミウム、ゲリウム、インジウム、銅、亜鉛、鉄、ビスマス、コバルト、マンガン、クロム、バナジウム、チタニウム、又はこれらの混合物、又は合金を含むことを特徴とする請求項１に記載の組成物。   Conductive particles are silver, gold, aluminum, platinum, palladium, tin, nickel, cadmium, gerium, indium, copper, zinc, iron, bismuth, cobalt, manganese, chromium, vanadium, titanium, or a mixture or alloy thereof The composition of claim 1, comprising: 導電性粒子が、平均粒子径を、３ｎｍ〜１００μｍの範囲に有することを特徴とする請求項１又は２の何れかに記載の組成物。   The composition according to claim 1, wherein the conductive particles have an average particle diameter in the range of 3 nm to 100 μm. 導電性粒子が、基本的に球形であることを特徴とする請求項１〜３の何れか１項に記載の組成物。   The composition according to any one of claims 1 to 3, wherein the conductive particles are basically spherical. 使用するガラスフリットが、酸化ビスマスベースの無鉛ガラスであることを特徴とする請求項１〜４の何れか１項に記載の組成物。   The composition according to any one of claims 1 to 4, wherein the glass frit used is a lead-free glass based on bismuth oxide. ガラスフリットが、０．０１〜１０質量％の酸化テルルを含むことを特徴とする請求項５に記載の組成物。   The composition according to claim 5, wherein the glass frit contains 0.01 to 10% by mass of tellurium oxide. マトリクス材料が、水溶性、又は水分散性のポリマーであることを特徴とする請求項１〜６の何れか１項に記載の組成物。   The composition according to claim 1, wherein the matrix material is a water-soluble or water-dispersible polymer. 歩留まり向上剤が、グリセロール、グリコール、ポリグリコール、アルカノールアミン、Ｎ−メチルピロリドン、ポリエチレンイミン、ポリビニルアミン、ポリビニルホルムアミド、又はこれらの混合物から成る群から選ばれることを特徴とする請求項１〜７の何れか１項に記載の組成物。   The yield improver is selected from the group consisting of glycerol, glycol, polyglycol, alkanolamine, N-methylpyrrolidone, polyethyleneimine, polyvinylamine, polyvinylformamide, or a mixture thereof. The composition according to any one of the above. 有機金属化合物が、金属カルボキシレート、金属プロピオン酸塩、金属アルコキシド、金属の錯体、又はこれらの混合物であることを特徴とする請求項１〜８の何れか１項に記載の組成物。   The composition according to any one of claims 1 to 8, wherein the organometallic compound is a metal carboxylate, a metal propionate, a metal alkoxide, a metal complex, or a mixture thereof. 有機金属化合物の金属が、アルミニウム、ビスマス、亜鉛、及びバナジウムから成る群から選ばれることを特徴とする請求項１〜９の何れか１項に記載の組成物。   10. The composition according to any one of claims 1 to 9, wherein the metal of the organometallic compound is selected from the group consisting of aluminum, bismuth, zinc, and vanadium. 有機金属化合物が、追加的に、ホウ素又はシリコンを含むことを特徴とする請求項１〜１０の何れか１項に記載の組成物。   The composition according to claim 1, wherein the organometallic compound additionally contains boron or silicon. 使用されるレーザー照射のための吸収剤が、無機顔料、及び銀、金、白金、パラジウム、タングステン、ニッケル、スズ、鉄、インジウムチンオキシド、タングステンオキシド、チタニウムカーバイド、又はチタニウムニトリド、ファインカーボンタイプ、又はファインランタンヘキサボライドのナノ粒子であることを特徴とする請求項１〜１１の何れか１項に記載の組成物。   Absorbers for laser irradiation used are inorganic pigments, silver, gold, platinum, palladium, tungsten, nickel, tin, iron, indium tin oxide, tungsten oxide, titanium carbide, or titanium nitride, fine carbon type The composition according to any one of claims 1 to 11, wherein the composition is fine lanthanum hexaboride nanoparticles. ファインカーボンが、カーボンブラック、グラファイト、カーボンナノチューブ、及び／又はグラフェンを含むことを特徴とする請求項１２に記載の組成物。   The composition according to claim 12, wherein the fine carbon contains carbon black, graphite, carbon nanotubes, and / or graphene. 太陽電池のための電極を製造するために使用される、請求項１〜１３の何れか１項に記載の組成物。   The composition according to any one of claims 1 to 13, which is used for producing an electrode for a solar cell.
JP2012527305A 2009-09-04 2010-09-01 Composition for printing electrodes Expired - Fee Related JP5984671B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09169548 2009-09-04
EP09169548.6 2009-09-04
PCT/EP2010/062775 WO2011026852A1 (en) 2009-09-04 2010-09-01 Composition for printing electrodes

Publications (3)

Publication Number Publication Date
JP2013504152A JP2013504152A (en) 2013-02-04
JP2013504152A5 true JP2013504152A5 (en) 2013-09-26
JP5984671B2 JP5984671B2 (en) 2016-09-06

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JP2012527305A Expired - Fee Related JP5984671B2 (en) 2009-09-04 2010-09-01 Composition for printing electrodes

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US (1) US9396833B2 (en)
EP (1) EP2474004B1 (en)
JP (1) JP5984671B2 (en)
KR (1) KR101874125B1 (en)
CN (1) CN102576575B (en)
ES (1) ES2536696T3 (en)
MY (1) MY158807A (en)
SG (1) SG178931A1 (en)
TW (1) TWI553663B (en)
WO (1) WO2011026852A1 (en)

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