JP2013246917A - Electron gun - Google Patents

Abstract

PROBLEM TO BE SOLVED: To form a proper electron beam by easily producing an electro gun cathode.SOLUTION: An electron gun cathode 104 is in the shape of a square pole and emits an electron when heated. The electron gun cathode 104 is inserted into a cylindrical recessed part 103a provided at a tip part of a truncated conical holding tool 103. A filler 120 is filled around the electron gun cathode 104 in the recessed part 103a, and the electron gun cathode 104 is held in the recessed part 103a.

Description

  The present invention relates to an electron gun that emits electrons.

  Electron beam exposure technology is used in the lithography field in which circuit patterns in semiconductor (LSI) manufacturing processes are exposed. That is, in the semiconductor lithography technology, a photomechanical technology (optical lithography) has been mainly used in which a mask to be an original drawing is usually created by an electron beam exposure apparatus, and the mask image is transferred to a semiconductor substrate (wafer) by light. .

  The electron beam exposure method began with a method called single-stroke writing with a finely focused electron beam, and developed an exposure method such as a variable rectangle method and a character projection (CP) method that collectively exposes several square microns using a micro mask. I let you.

  Here, in such an electron beam exposure apparatus, an electron gun for generating an electron beam is important. For example, Non-Patent Document 1 uses a method for holding an electron gun cathode and a heating method called a Vogel mount type. This electron gun has a structure in which an electron gun cathode serving as an electron generation source is sandwiched from both sides by PG (pyrolytic) graphite serving as a heating element and further pressed and held by metal springs from both sides. The heat generation state of PG graphite is controlled by the current passed through PG graphite, and thermionic emission conditions are obtained. This conventional electron gun will be described with reference to FIG.

  In this electron gun cathode, two pyrolytic graphites are obtained by cutting a LaB6 or CeB6 single crystal chip 801 having a conductivity and a work function for generating electrons in the vicinity of 2.6 eV along a plane perpendicular to the C-axis direction. It is made of a material sandwiched between 802a and 802b. This is held by metal supports 803a and 803b, and held by moderate pressure by the parts 804a and 804b constituting the spring. The spring force is adjusted by rotating the screws 806a and 806b for tightening from the supports 805a and 805b to change the amount of protrusion. The ends of the supports 805a and 805b are fixed to an alumina ceramic disc 807, and 805a and 805b are electrically insulated from each other. The legs of the supports 805a and 805b are in electrical contact with the electrical lead-in terminals 808a and 808b, and by flowing a current of several amperes, the pyrolytic graphite 802a and 802b are heated, and a single crystal chip of LaB6 or CeB6 801 is kept at a high temperature around 1500 ° C. and operated as a thermionic gun cathode or a thermal field emission cathode.

  In the Vogel mount type electron gun cathode described above, the LaB6 or CeB6 single crystal chip is fixed with two pyrolytic graphites from both sides by springs, so the electron gun cathode structure is complicated and it is relatively difficult to align the center axis of electrons. There was a drawback. In addition, in order to carry out current heating, when manufacturing a multi-column high-voltage power supply of several tens or more, a total of several tens of amperes to several hundreds of amperes on a high-voltage power supply of several tens kV (for example, approximately -50 kV) In order to mount a circuit that generates a large current, the capacity of the high-voltage power supply is increased. Further, in order to transmit a current of several amperes to an individual electron gun, for example, an electric wire having a diameter of several millimeters or more is required. If high-voltage insulation is taken into consideration, it is covered with an insulating material such as rubber and has a diameter of at least about 10 mm. The above thickness is necessary, it is doubled for current heating, and several tens or more are required, and it becomes a power cable having a cross-sectional area of about tens of centimeters or more, and is mounted on a vibration isolator. Mechanical vibration was transmitted from the power cable to the multi-column, and a pattern could not be drawn with an accuracy of 1 nm or less.

  Further, Patent Document 1 and Patent Document 2 disclose a technique for irradiating laser light in a non-contact manner from the front side or the back side of the tip portion of the electron gun cathode material, efficiently heating it, and extracting many electron beams. To do.

JP-A-8-212952 Japanese Patent Laid-Open No. 6-181029

"Electron / Ion Beam Handbook 3rd Edition", Japan Society for the Promotion of Science, 132nd Committee, Nikkan Kogyo Shimbun, October 28, 1998 P119

Here, as the electron gun cathode material, hexaboronated lanthanoid compounds such as LaB6 (LaB ₆ ) and CeB6 (CeB ₆ ) are often used. Generally used at high temperatures. In a field emission electron gun that draws electrons by an electric field, an electron gun cathode (for example, LaB6) has a large surface area of several square millimeters and is exposed as a whole.

  In this case, many electrons are emitted from the entire surface including the side surface of the tip, and the operating temperature is as high as 1800 K or higher, so that the material sublimation is also large. Accordingly, whiskers of sublimation deposits are formed on the surfaces of the anode and the extraction electrode, and when this occurs, it cannot be used any more. Further, the volume of the electron gun material is reduced, the tip surface is lowered, and the side surface is thinned and thinned. In this way, the desired electron can no longer be extracted by changing the shape of the tip. Furthermore, when used at a high temperature of 1800 K for a long time, for example, if it is LaB6, boron (B) atoms and lanthanum (La) lanthanum atoms will escape from the crystal, the crystal will become brittle, the density will decrease, cracks And the crystal becomes faint and not dense. As a result, since the work function becomes high, it is impossible to maintain a high luminance state (a state in which sufficient electrons are extracted) unless the temperature is further increased. Therefore, when the temperature is raised, the sublimation and evaporation of the electron gun cathode material become more and more intense.

  In addition, when a strong electric field is applied to increase the electric field at the tip of the electron gun and it is used as a field emission electron gun, a lower temperature can be used as a result of applying the strong electric field. The temperature can be relatively low, such as 1700 K or lower, 1650 K, 1600 K, and the like, and sublimation of the material can be reduced. However, in this case as well, the whisker of sublimation deposits is formed on the surface of the anode / extraction electrode or the shape of the cathode material changes due to long-term use. Therefore, it is desired to further reduce sublimation and evaporation of the cathode material.

  An electron gun according to the present invention has a truncated cone shape that is tapered toward the tip, a cathode support member in which a cylindrical recess is formed along the central axis direction from the tip, and is inserted into the recess from the tip side. A square columnar electron gun cathode, a powder composed mainly of a carbon element that fills the periphery of the electron gun cathode in the recess and bonds the two, and a mixture of organic adhesives. By heating and using, the adhesive in the mixture of the carbon powder and the adhesive is denatured to become a carbon powder aggregate.

  In one embodiment, the tip of the electron gun cathode protrudes from the tip of the cathode support.

  In another aspect, the cathode support portion is made of a refractory metal.

  In another aspect, the cathode support portion is made of a transparent material having a conductive material on the surface, and receives laser light from the rear end side, which is irradiated to the electron gun cathode to heat the electron gun cathode. The

  According to the present invention, an electron gun cathode can be easily manufactured and an appropriate electron beam can be formed.

It is a figure which shows the structure of the electron gun which concerns on embodiment. It is a figure which shows the structure of a holder and an electron gun cathode. It is a figure which shows the structure of a holder and an electron gun cathode. It is a figure explaining manufacture of an electron gun cathode. It is a figure explaining manufacture of an electron gun cathode. It is a figure which shows the structure of a holder and an electron gun cathode. It is a figure explaining the consumption state of an electron gun cathode. It is a figure which shows the other structural example of a holder and an electron gun cathode. It is a figure which shows schematic structure of an electron beam exposure apparatus. It is a figure which shows a single column. It is a figure which shows the structure of the voltage supply control to an electron gun. It is a figure of the conventional Vogel mount type electron gun. It is a figure which shows the state of the electric field around an electron gun cathode.

  Hereinafter, embodiments of the present invention will be described with reference to the drawings.

"Configuration of electron gun"
FIG. 1 is a diagram illustrating a configuration of an electron gun 100 according to the embodiment. In this example, the electron gun 100 employs a light heating method.

  In FIG. 1, light is light with high energy density, and is incident from one end portion (lower light incident end in the figure) of a cylindrical optical waveguide 102 made of sapphire or the like, and on the opposite side of the optical waveguide 102. Is incident on the holder 103 installed at the end portion (tip portion). In this example, the holder 103 is composed of a conical portion on the distal end side of the cylindrical portion on the base side, and is composed of rhenium as a whole. A cylindrical recess 103 a is formed on the base side of the holder 103, and the distal end portion of the optical waveguide 102 is accommodated therein. Note that a metal film 101 is formed on the peripheral surface of the optical waveguide 102 to enable external electrical connection with the holder 103 and the electron gun cathode 104.

  The conical portion of the holder 103 has a truncated cone shape with its tip portion cut off, and a cylindrical recess 103a is formed on the tip surface in the direction of the central axis and inward. A quadrangular prism-shaped electron gun cathode 104 is inserted into the recess 103a from the front end side.

  Here, FIG. 2 shows a cross-sectional view of the optical waveguide 102, the holder 103, and the electron gun cathode 104 in two directions. FIG. 3 is a view of the holder 103, into which the electron gun cathode 104 is inserted, as viewed from the distal direction. In this way, the concave portion 103a is cylindrical, and the quadrangular prism-shaped electron gun cathode 104 is inserted into the concave portion 103a, so that the four corners of the electron gun cathode 104 are in contact with the inner wall of the concave portion 103 and around each side of the electron gun cathode 104. There is a gap. If the diagonal length of the electron gun cathode 104 in FIG. 3 is made smaller than the diameter of the recess 103 a, the four corners of the electron gun cathode 104 will not contact the inner wall of the recess 103, but this is also possible.

  The gap between the recess 103a and the electron gun cathode 104 is filled with a filler 120 made of a mixture of carbon powder and adhesive, thereby fixing the electron gun cathode 104 in the recess 103a. Here, the filler 120 includes a powder containing carbon element as a main component (one powder or a mixture of plural kinds of carbon powder, graphite, carbon nanotube, fullerene, graphene) and an organic adhesive (epoxy). Organic adhesive made of carbon, hydrogen, oxygen such as resin, vinyl resin, acrylic resin, etc.). It is a liquid with a large viscosity when filled, and solidifies after filling. It is desirable that the recess 103a and the electron gun cathode 104 be bonded by releasing moisture and leaving only the carbon component in the process of raising the temperature to about 1800K.

  Therefore, when the electron gun 100 is used, it is heated to a predetermined high temperature. The organic adhesive is volatilized or carbonized by such heating, and after heating, the filler 120 is in a state where the carbon powder is condensed, and the electron gun cathode 104 is held in the recess 103 a of the holder 103.

  The light is introduced from the light source into the optical waveguide 102 by, for example, an optical fiber, is incident on the holder 103 and absorbed, and the electron gun cathode 104 is heated to a high temperature via the holder 103. Therefore, by adjusting the light intensity, it is possible to obtain conditions for emitting electrons from the electron gun cathode 104 into the vacuum.

  Here, the light is, for example, light emitted from a semiconductor laser. Visible light is suitable for aligning the optical axis, but it is also possible to use ultraviolet rays to infrared rays.

  The optical waveguide 102 is a light propagation path, and the light incident from the incident end is totally reflected by the side surface and guided forward, and propagates to the holder 103 without being scattered. The optical waveguide 102 is also a support that mechanically supports the holder 103 and the electron gun cathode 104, and the electron gun cathode 104 has heat resistance that can withstand a high temperature (approximately 1500 ° C.) at which electron emission conditions are obtained. is necessary. Further, the optical waveguide 102 has a function of an electron supply path to the electron gun cathode 104. This function as an electron supply path is a function necessary for supplying electrons emitted from the electron gun cathode 104 into the vacuum via the holder 103.

  Suitable materials for the optical waveguide 102 include sapphire, ruby, diamond, and quartz glass that transmit light and have a high melting point. Here, since these materials have high insulating properties, conductivity is added in order to provide an electron supply path for supplying emitted electrons from the electron gun cathode 104. In this example, a high melting point metal film 101 having a thickness of about several hundreds of nanometers is attached to the surface of the optical waveguide 102 by vapor deposition or sputtering. In addition, by using an ion implantation technique on the surface layer of the optical waveguide 102, one kind of ion selected from bromine, nitrogen, oxygen, fluorine, aluminum, phosphorus, sulfur, chlorine, gallium, and arsenic is implanted. You may provide electroconductivity.

  Further, even if the optical waveguide 102 itself is an insulator, electrons may be supplied to the electron gun cathode 104 by another conducting wire. In this case, the electron gun cathode 104 is provided with an electron supply terminal, and an electron gun power source is connected to the electron gun cathode 104 by an electric wire, and electrons emitted from the electron gun cathode 104 are supplied from the electron gun power source.

  Note that sapphire is most suitable due to light transparency, heat resistance, and workability. In this embodiment, sapphire is selected from sapphire, ruby, diamond, and quartz glass materials as the optical waveguide 102.

  The shape of the optical waveguide 102 is preferably a cylindrical shape having a diameter that allows easy incidence from an optical fiber propagating from the light source to the optical waveguide 102. It is also possible to use a tapered conical shape that becomes thinner toward the tip. Further, the structure may be a structure that changes the material and shape, reflects light on the inner surface of a hollow metal tube, and propagates the light to the tip.

  The holder 103 is a heating element that receives and absorbs light, and is also a structure that supports the electron gun cathode 104. It must be made of a substance that can provide a protective function that does not chemically react with the electron gun cathode material LaB6 or CeB6 at the operating temperature (approximately 1500 ° C) as an electron gun, and rhenium, tantalum, carbon, etc. can be used. It is. However, rhenium has the least reaction with the electron gun cathode material at high temperatures, and rhenium is most suitable. Therefore, in the present embodiment, rhenium is used for the holder 103.

  The reason why the chemical reaction protection function is necessary is that electron gun cathode materials such as LaB6 and CeB6 can be easily combined with many substances excluding some substances such as rhenium, tantalum and graphite (carbon) at the operating temperature as an electron gun. This is due to the need to prevent chemical loss and alteration of the electron gun characteristics.

  Here, as described above, there are carbon and tantalum as those that do not chemically react with LaB6 and CeB6. Although carbon was actually tested, it is considered to be practically difficult to use because it rags and falls off near 1700K. Moreover, although it is said that tantalum does not react relatively, it still reacts with LaB6, TaB2 is generated, and La escapes. For this reason, in the electron gun cathode 104 of a small crystal like this embodiment, it is thought that a component will change in a comparatively short time, for example, one month or less, and it is not practical.

  As described above, the shape of the holder 103 is such that the base side is a cylinder having a diameter larger than the diameter of the optical waveguide 102, and has a hole (concave portion) into which the optical waveguide 102 is inserted and fitted at the end portion. It has a truncated cone shape, and has a hole (concave portion) into which the electron gun cathode 104 is inserted and fitted.

  The electron gun cathode 104 is used by selecting one material from a hexaboronated lanthanoid compound such as LaB6 or CeB6, which is a refractory metal material that emits thermoelectrons or thermal field emission electrons at a high temperature. The lanthanoid is a generic name of 15 elements from the third (3A) group of the 6th period of the periodic table, up to 71th ruthenium Lu having similar chemical properties as typified by the lanthanum La of atomic number 57.

  As an electron gun characteristic, the electron gun cathode 104 is preferably a single crystal. Further, the operating temperature of the electron gun cathode 104 being high (approximately 1500 ° C.) means that the work function of LaB6 or CeB6 is 2.6 eV, and a temperature at which thermionic emission is possible.

  An electron beam passage is opened in front of the tip of the electron gun cathode 104, and a suppressor electrode 105 is provided in the vicinity thereof. The suppressor electrode 105 suppresses electron emission from the side surface of the optical waveguide 102 at zero potential with respect to the electron gun cathode 104.

  In front of the suppressor electrode 105, an extraction electrode 106 is provided by opening an electron beam passage. The extraction electrode 106 is applied with a potential of about +3 kV to about +10 kV with respect to the electron gun cathode 104, and is applied to the vicinity of the upper surface of the tip of the 100 μm diameter cylinder of the electron gun cathode 104. It is injected toward the gun anode 107.

  The electron gun anode 107 is normally at a ground potential (0 V), and a voltage for accelerating an electron beam of minus several tens of kV (eg, minus 50 kV) is applied to the electron gun cathode 104 to give a kinetic energy of several tens of keV (eg, 50 keV). An electron beam 108 is obtained by applying the thermal field emission electrons. As a result, the electron gun cathode 104 has a potential of approximately minus 50 kV, and the extraction electrode 106 has a potential of approximately minus 47 kV to approximately minus 40 kV. Thereby, the entire structure of FIG. 1 functions as the electron gun 100.

  The insulating base 109 is an alumina ceramic disk, and the optical waveguide 102 is fixed to the center of the disk. The insulating base 109 can insulate the suppressor electrode 105 and the optical waveguide 102, but the suppressor electrode 105 may have the same potential as the optical waveguide 102.

  The insulating base 110 has a larger diameter than the insulating base 109, holds the insulating base 109 from below, supports the optical waveguide 102 at the center, and provides the bases of the suppressor electrode 105 and the extraction electrode 106 outside the insulating base 109. They are concentrically held apart from each other. The insulating base 110 insulates the extraction electrode 106 and the optical waveguide 102 from each other.

  The conductive ring 112 is at the end of the optical waveguide 102, contacts the outer surface of the insulating base 109, and contacts the metal film 101 made of a conductive material on the outer surface of the optical waveguide 102. An electron beam acceleration power source is connected to the conductive ring 112 to supply electrons emitted from the electron gun cathode 104 through the metal film 101 of the optical waveguide 102 and the holder 103.

  Here, the electron gun cathode 104 shown in FIGS. 2 and 3 is a square column of about 100 μm in length of 50 μm (micrometer) × 50 μm, and the corresponding hole is a round hole with a diameter of about 70 μm. It is preferable that the tip of the gun cathode 104 protrudes.

  In this embodiment, the electron gun cathode 104 has a quadrangular prism shape. This is because the electron gun cathode 104 has a rectangular shape because it is easier to manufacture. As shown in FIG. 4, a plate-like LaB6 crystal is provided with a plurality of slits in the horizontal and vertical directions from the surface with a blade. If this is seen in a cross section parallel to one of the cut grooves, it becomes as shown in FIG. Then, as shown in FIG. 5B, an adhesive is injected into the cut groove and hardened. Thereafter, as shown in FIG. 5 (c), the blade is cut so as to cross the groove in a direction parallel to the surface (shown as a cut line) with a blade, as shown in FIG. 5 (d). A set of square pillars hardened with an agent is obtained. Next, by dissolving the adhesive with a solvent and removing it, a large number of square columnar electron gun cathodes 104 shown in FIG. 5E can be obtained.

  For example, the electron gun cathode 104 has a tip plane of about 50 μm × 50 μm and a length of about 100 μm. It is very difficult to process such a small electron gun cathode 104 with an ordinary lathe or the like. In addition, even when the blade is cut, it will fly away from the crystal substrate. By the processing method as described above, the small electron gun cathode 104 can be effectively manufactured.

  Here, the crystal chip of LaB6 is often cracked. Chips with cracks often have unstable temperature characteristics when heated, and the temperature cannot be maintained in a steady state, so they tend to have unstable characteristics. Therefore, the position where the electron beam is emitted fluctuates and the radiation direction fluctuates angularly, and the electron gun characteristics tend to become unstable.

  However, the electron gun cathode 104 of the present embodiment has a size of 50 μm × 50 μm × 100 μm and a small volume as a crystal. For this reason, cracks hardly occur. Therefore, the temperature characteristics during heating are stable, the beam position is less changed, and the electron emission characteristics are extremely stable.

In this embodiment, a thermal field emission (TFE) type electron gun 100 that heats the electron gun cathode 104 and draws electrons by applying an electric field to the electron gun cathode 104 is used. An electric field of about 0.5 to 1.0 × 10 ⁶ V / cm is applied, and the temperature is set to about 1650-1700K. Then, LaB6 or CeB6 is used as the material of the electron gun cathode 104, and this is held by a rhenium holder 103. At such a temperature, rhenium hardly reacts with LaB6 or CeB6, and therefore it is possible to effectively prevent the electron gun cathode 104 from being altered by a chemical reaction.

  Further, in the present embodiment, as shown in FIG. 6, the tip of the electron gun cathode 104 is a flat surface of about 50 μm × 50 μm, and only the tip protrudes from the rhenium holder 103. This protrusion amount is set to 2 to 15 μm. As described above, most of the side surface of the electron gun cathode 104 having a length of about 100 μm is covered with the holder 103, so that sublimation of electrons and materials from the side surface of the electron gun cathode 104 can be reduced. . Further, the electron irradiation from the side surface of the electron gun cathode 104 is small, and extra heating to the peripheral members can be minimized.

  That is, the number of electrons emitted from the entire surface including the electron gun cathode 104 and the tip side surface can be reduced, and the sublimation and evaporation of the material can be reduced. Conventional sublimation area of several square millimeters is 2500 square microns, and the area ratio is less than 1/200. Therefore, the formation of whisker of sublimation deposits on the surfaces of the electron gun anode 107 and the extraction electrode 106 can be suppressed, and the time until the discharge occurs can be lengthened and the life can be extended.

  In addition, the side surface of the electron gun cathode material can be prevented from thinning and becoming thin, and the initial electron extraction state can be maintained for a long time. Furthermore, if it is LaB6, it can suppress that a boron (B) atom or a lanthanum (La) lanthanum atom escapes from the crystal | crystallization, and can maintain the initial electron extraction state for a long period of time.

  The holder 103 made of rhenium is one having a base diameter of 1000 μm, a tip diameter of about 100 μm, and a length of about 1 mm to 2 mm.

  Thus, in this embodiment, the consumption by using the electron gun cathode 104 is relatively small. However, it is inevitable that the electron gun cathode 104 is consumed by use. In the present embodiment, for example, as shown in FIG. 7, the volume of the electron gun cathode 104 gradually decreases from the tip surface. Fig. 7 (a) schematically shows an example after the start of use, Fig. 7 (b) after two years, and Fig. 7 (c) schematically after three years.

  If the protruding amount of the electron gun cathode 104 is large, it is not preferable because emission and sublimation of electrons from the side surface increase accordingly. On the other hand, consumption due to use is unavoidable, and when the tip of the electron gun cathode 104 enters the hole of the holder 103 and becomes as shown in FIG. Therefore, in order to extend the life as much as possible and reduce the formation of whiskers on the extraction electrode 106 and the like, it is preferable that the protrusion amount of the electron gun cathode 104 from the holder 103 is about 2 to 15 μm at the start of use. In particular, the thickness is preferably about 10 μm.

  Here, if the surface areas of the upper surface flat portions of the electron gun cathode 104 and the holder 103 are reduced, the electric field concentration becomes conspicuous, the electric field strength increases, and the electron generation efficiency increases. Therefore, the brightness can be further increased by reducing the plane area of the tip. That is, in the above-described embodiment, the flat surface of the tip is set to about 50 × 50 μm, but high luminance can be achieved by reducing the area. At this time, it is necessary to reduce the area of the holder 103 at the same time. A variable shaped beam, cell projection beam (CP) or the like needs to irradiate a certain area uniformly. This is said to require uniform irradiation. It is also said that a large emittance is necessary.

  Further, in the present embodiment, the holder 103 made of rhenium has a shape that tapers sharply toward the tip. The electron gun cathode 104 is held by covering the bottom and side surfaces of the electron gun holding portion at the tip. Therefore, as shown in FIG. 13, the electric field around the electron gun cathode has an equipotential line having a sharp mountain shape corresponding to the tip shape of the holder 103, and a strong electric field is applied to the tip portion. Therefore, the emission of the electron beam from the tip of the electron gun cathode 104 is promoted.

  Also, the electron gun cathode 104 having a flat tip as shown in the above-described embodiment is suitable for a variable shaped beam or cell projection beam (CP) exposure apparatus.

  In the present embodiment, the electron gun cathode 104 has a quadrangular prism shape, and the tip surface has a flat quadrangular shape. Thereby, the electron beam from the electron gun cathode 104 can be formed into a quadrangular shape, and when the multi-column is formed, the target can be irradiated with the electron beam as a set of quadrangles, and appropriate drawing can be performed.

  In addition, the holder 103 has a truncated cone shape, and the presence of the corner portion eliminates the adverse effect on the equipotential lines as shown in FIG. 13 and generates an appropriate electric field as a whole.

"Other configuration examples of electron gun"
FIG. 8 shows another configuration example of the electron gun 100. In this example, the holder 103 is made of the same sapphire as the optical waveguide 102, the tip portion of the sapphire holder 103 has a truncated cone shape, a recess 103a is provided at the tip portion, and the electron gun cathode 104 is inserted therein. ing. In this example, the metal film 101 is formed on the surfaces of the sapphire optical waveguide 102, the holder 103, and the recess 103a, thereby enabling electrical connection between the electron gun cathode 104 and the outside. In this case, the laser beam is applied to the electron gun 100, and the electron gun cathode 104 is heated.

"Configuration of electron beam equipment"
FIG. 9 shows a schematic configuration of an electron beam exposure apparatus using the electron gun 100 described above. The lens barrel 204 is a hermetically sealed cylinder, and an electron gun chamber 201 is partitioned and formed by a partition wall 202 at the top. Inside the lens barrel 204, a lens / deflection functioning as a beam control unit including a coil, a magnetic lens, and the like for deflecting, shaping, and converging the electron beam 205 extracted from the electron gun 100 An optical system 203 is arranged. A target chamber 210 is disposed below the lens barrel 204, and a target 206, which is a substrate (wafer) drawn thereon, is placed thereon.

  As a result, the electron beam 205 drawn from the electron gun 100 is controlled to converge at an arbitrary position of the target 206, and drawing with the electron beam is performed. The ion pump 207 exhausts the inside of the electron gun chamber 201, the turbo molecular pump 208 exhausts the inside of the lens barrel 204, and the turbo molecular pump 209 exhausts the inside of the target chamber 210, and each maintains a desired vacuum state. This apparatus includes a secondary electron or backscattered electron detector 211, so that not only electron beam drawing but also image observation can be performed by scanning the electron beam. It can also be used as an electron beam inspection apparatus for inspecting an image of a wafer or a mask substrate.

"Multi-column configuration"
The electron gun of this embodiment can be suitably applied to a multi-column electron beam exposure apparatus. In this multi-column electron beam exposure apparatus, a plurality of single column elements having a thickness of about 15 mm to about 50 mm, for example, are arranged two-dimensionally in the number of several tens or more (for example, 30 to 250 or more), A multi-column group that irradiates a plurality of electron beams onto one wafer is formed. With such a configuration, high-speed exposure processing can be performed.

  FIG. 10 shows a diagram of a multi-column electron beam drawing apparatus. 89 fine columns having a column element of about 25 mm in diameter as a unit are arranged on a 300 mm wafer. A schematic configuration of one single column element 301 is shown. The electron beam emitted from the electron gun 304 is shaped into a rectangle by the first rectangular aperture 305 and imaged on the second rectangular aperture or CP mask 308 by the lens / deflection optical system 306 in the previous stage. The position of the electron beam on the second rectangular aperture or CP mask 308 is reshaped to a beam of the intended size or shape by a beam deflector. Further, the lens / deflection optical system 309 in the subsequent stage deflects and forms an image at an appropriate position on the wafer located below. These lens / deflection optical systems 306 and 309 function as a beam control unit, and are further constituted by a magnetic lens 307 when further disassembled.

"Configuration of light heating power supply"
As described above, it is preferable to use light for heating the electron gun. FIG. 11 is a configuration diagram of the light heating type electron gun of this embodiment and a control unit of the electron gun.

  The electron beam accelerating power source 403 is a high voltage generating unit that supplies a high voltage of minus several tens kV (for example, approximately −50 kV) to the electron gun cathode 104, and the voltage is applied to the metal on the surfaces of the conductive ring 112 and the optical waveguide 102. Application is made to the electron gun cathode 104 through the film 101.

  The extraction electric field power supply 402 generates a voltage of plus several kV (approximately +3 kV to +10 kV) with respect to the electron beam acceleration power supply 403 and applies the voltage to the extraction electrode 106.

  The light source unit 504 is a unit that generates light and adjusts the intensity of light by the semiconductor laser and its control unit.

  The optical fiber 505 is an optical transport path that guides the light from the light source unit 504 to the optical waveguide 102. Each optical fiber 505 has a thickness of about 250 microns and can be bundled by several tens or more. The thickness is about 2.5 mm in diameter. The optical fiber 505 is an insulator such as glass or plastic, and unlike an electric wire, it is not necessary to provide special electrical insulation. Can be introduced. In addition, the conventional heating method uses a thick conductive cable with a diameter of several centimeters or more that is high-voltage insulated for current heating, so it is heavy and rigid and hard, so floor vibration is transmitted and the electron optical column vibrates As a result, the beam vibrates and the drawing accuracy deteriorates.

  The energy of light input to the electron gun 100 is radiated as radiant heat of these members and conduction heat through the optical waveguide 102 by setting the holder 103 and the electron gun cathode 104 to a high temperature around 1500 ° C. Therefore, the light intensity is adjusted so that the temperature of the electron gun cathode 104 becomes a constant value around 1500 ° C. In practice, it is difficult to detect the temperature of individual electron guns with multi-columns of several tens or more, so that they are extracted as thermal field emission electron currents by the extraction electrode 106, accelerated by the electron gun anode 107, and accelerated by the wafer 303. The intensity of the electron beam flowing into the light source is measured, and the light source unit 504 is controlled so as to keep the measured value constant. Secondarily, since the light amount monitor is included in the semiconductor laser, the output of the semiconductor laser is controlled so as to keep it constant.

  Thus, in this embodiment, since light is used for heating, the optical fiber 505 is separated from the high voltage system, and the handling becomes easy. In the present embodiment, the cable for transmitting the light energy is thin, lightweight, and the rigidity is small, so that the floor vibration is hardly transmitted, so that drawing with high accuracy is possible.

  The problem with the multi-column electron gun is the heat generation of the electron gun cathode. When the area of the holder 103 of one electron gun is several square millimeters and the temperature is 1700 K, the number of multi-column electron guns is multiplied by several watts, which is a calorific value determined by the product of the area of the high temperature portion and the fourth power of the temperature. Value, that is, a calorific value of several hundred watts. For this reason, the degree of vacuum of the electron gun chamber 201 may deteriorate. In order to avoid the deterioration of the degree of vacuum, it is effective to reduce the surface area of the holder 103. For example, by halving the thickness and length, the calorific value can be reduced to about a quarter, the calorific value can be reduced to 100 watts or less, and the degree of vacuum can be reduced. Thus, it is important to reduce the temperature and area of the high-temperature part of the electron gun. Accordingly, it is preferable that the holder 103 has a shape in which the base portion is short and the thin portion is long. In order to further reduce the area, the holder may be configured with a thin wire within a range in which the entire structure is not changed.

When a flat electron gun cathode having a 50-um square tip is used in this embodiment, the luminance is 3 to 6 × 10 ⁶ A / cm ² steradian when applied to an electron beam lithography apparatus, A value of 7 to 10 mrad um is obtained as the electron gun emittance representing the irradiation uniformity of the rectangular aperture, and the lifetime is 2 to 3 years, so that it can be used as an ideal electron gun. This can greatly contribute to the practical application of the electron beam drawing apparatus. Further, it is possible to greatly contribute to the improvement of the scanning transmission electron microscope and the electron beam inspection apparatus.

  In the above-described embodiment, the holder 103 is formed of rhenium as a whole. This is to suppress a chemical reaction with the electron gun cathode 104 made of LaB6 or the like. Therefore, if the portion of the holder 103 that is in contact with the electron gun cathode is formed of rhenium, the other portion of the holder 103 may be formed of another material such as tungsten, tantalum, or molybdenum having high rigidity.

  100, 304 electron gun, 101 metal film, 102 optical waveguide, 103 holder, 103a recess, 104 electron gun cathode, 105 suppressor electrode, 106 extraction electrode, 107 electron gun anode, 108, 205 electron beam, 109, 110 insulating base , 112 conductive ring, 130 filler, 201 electron gun chamber, 202 partition wall, 203 lens / deflection optical system, 204 barrel, 206 target, 207 ion pump, 208,209 turbo molecular pump, 210 target chamber, 211 secondary Electron or backscattered electron detector, 301 single column element, 303 wafer, 305 first rectangular aperture, 306, 309 lens / deflection optics, 307 magnetic lens, 308 second rectangular aperture or CP mask, 402 power supply for extraction electric field, 403 Electron beam acceleration power source, 504 light source unit, 505 optical fiber, 801 LaB6 or CeB6 single crystal electron gun cathode material, 802a, 802b Pyrolytic graphite cut in C-axis direction, 803a, 803b Metal support, 804a 804b Metal spring, 805a, 805b Spring adjusting screw support base, 806a, 806b Spring adjusting screw, 807 Alumina ceramics, 808a, 808b Electron gun cathode heating current introduction terminal.

Claims (4)

A cathode support member having a truncated cone shape that is tapered toward the tip, in which a cylindrical recess is formed from the tip along the central axis direction;
A quadrangular prism-shaped electron gun cathode inserted into the recess from the tip side;
In the recess, filled in the peripheral part of the electron gun cathode, a powder mainly composed of a carbon element that joins both, and a mixture of an organic adhesive,
Including
An electron gun in which the adhesive in the mixture of the carbon powder and the adhesive is denatured and becomes a condensed product of the carbon powder when heated and used. The electron gun according to claim 1,
The electron gun cathode has a tip that protrudes from a tip of the cathode support portion. The electron gun according to claim 1 or 2,
The cathode support part is an electron gun made of a refractory metal. The electron gun according to claim 1 or 2,
The cathode support portion is an electron gun made of a transparent material having a conductive material on the surface, receiving laser light from the rear end side, and irradiating the electron gun cathode to heat the electron gun cathode.