JP2013241313A - Method for manufacturing glass product using bone ash - Google Patents
Method for manufacturing glass product using bone ash Download PDFInfo
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- JP2013241313A JP2013241313A JP2012116578A JP2012116578A JP2013241313A JP 2013241313 A JP2013241313 A JP 2013241313A JP 2012116578 A JP2012116578 A JP 2012116578A JP 2012116578 A JP2012116578 A JP 2012116578A JP 2013241313 A JP2013241313 A JP 2013241313A
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- bone ash
- glass product
- glass
- aluminum oxide
- phosphorus pentoxide
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Abstract
Description
この発明は骨灰を使用したガラス製品の製造方法に関し、人骨灰又は動物骨灰からガラス製品に製造する場合に使用されるものである。 The present invention relates to a method for producing glass products using bone ash, and is used when producing glass products from human bone ash or animal bone ash.
従来におけるこの種のガラス製品の製造方法においては、ガラス原料に人骨灰又は動物骨灰を調合してガラス製品を製造していたものであり、製造された製品は、装飾用ガラス製品又は人造宝石として遺族等の心を慰めるものとして使用されていた。 In the conventional method for producing glass products of this type, human bone ash or animal bone ash is mixed with glass raw materials to produce glass products, and the manufactured products are used as decorative glass products or artificial jewels. It was used to comfort the hearts of the bereaved.
しかしながら、かかる従来のガラス製品の製造方法にあっては、単に、ガラス原料に添加物として人骨灰又は動物骨灰を調合していたにすぎないため、人骨灰又は動物骨灰がガラスとして結晶化しにくく透明度の高い装飾性の高いガラス製品を製造しにくい結果、心を慰めるための装飾用ガラス製品又は人造宝石としては充分とはいえないという不都合を有した。 However, in such a conventional glass product manufacturing method, human bone ash or animal bone ash is merely prepared as an additive to the glass raw material, and thus human bone ash or animal bone ash is not easily crystallized as glass and has transparency. As a result, it is difficult to produce a glass product having a high decorative property, and as a result, it is not sufficient as a decorative glass product or artificial jewel for comforting the heart.
この発明の課題はかかる不都合を解消することである
An object of the present invention is to eliminate such inconvenience.
この発明に係る骨灰を使用したガラス製品の製造方法においては、骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムとを混合し、加熱して燐酸塩ガラス化したものである。 In the method for producing glass products using bone ash according to the present invention, bone ash, phosphorus pentoxide, aluminum oxide and cerium nitrate are mixed and heated to form phosphate glass.
この場合、骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムとの混合割合（重量比）を、略６３：５８：６：１にすることができる。 In this case, the mixing ratio (weight ratio) of bone ash, phosphorus pentoxide, aluminum oxide, and cerium nitrate can be set to approximately 63: 58: 6: 1.
また、前記骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムに適量の着色材を添加することもできる。 In addition, an appropriate amount of colorant can be added to the bone ash, phosphorus pentoxide, aluminum oxide, and cerium nitrate.
更に、前記骨灰には人骨灰又は動物骨灰が該当する。 Furthermore, human bone ash or animal bone ash corresponds to the bone ash.
この発明に係る骨灰を使用したガラス製品の製造方法においては、骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムとを混合し、加熱して燐酸塩ガラス化したものであるため、骨灰が燐酸塩ガラスの原料として結晶化かし、透明度の高い装飾性の高いガラス製品が製造されるものである。 In the method for producing glass products using bone ash according to the present invention, bone ash, phosphorus pentoxide, aluminum oxide and cerium nitrate are mixed and heated to form phosphate glass. As a raw material, the glass product is crystallized to produce a glass product with high transparency and high decorativeness.
よって、発明に係る骨灰を使用したガラス製品の製造方法を使用すれば、透明度の高くて、遺族等の心を充分に慰めることのできる装飾用ガラス製品又は人造宝石を製造することができる。 Therefore, if the method for producing a glass product using bone ash according to the invention is used, it is possible to produce a decorative glass product or an artificial jewel that has high transparency and can sufficiently comfort the mind of a bereaved family or the like.
この場合、骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムとの混合割合（重量比）を、略６３：５８：６：１にすれば、骨灰を使用して燐酸塩ガラスにおけるガラス化のモル比の条件を満たすことができる。
In this case, if the mixing ratio (weight ratio) of bone ash, phosphorus pentoxide, aluminum oxide and cerium nitrate is approximately 63: 58: 6: 1, the molar ratio of vitrification in phosphate glass using bone ash. The condition of can be satisfied.
また、前記骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムに適量の着色材を添加すれば、着色された透明度の高い装飾性の高いガラス製品を製造することができる。 Moreover, if an appropriate amount of coloring material is added to the bone ash, phosphorus pentoxide, aluminum oxide, and cerium nitrate, a colored glass product with high transparency and high decorativeness can be produced.
この発明に係る骨灰を使用したガラス製品の製造方法は実施するにあたって以下の特徴を有する。 The method for producing a glass product using bone ash according to the present invention has the following characteristics when implemented.
燐酸塩ガラスの成分の重量比
CaO：26 w％、P2O5: 67 w％、Al2O3: 4 w％、Ce2O3: 3 w％
モル比に直すと、
CaO ＝40+16＝56
P2O5 ＝31×2+16×5＝142
Al2O3 ＝ 27×2+16×3=102
Ce2O3 ＝140×2+16×3=328
26/56:67/142:4/102:3/328＝0.464:0.471:0.04:0.01＝1:1:0.1:0.025
Atomic ratio … Ca:P:Al:Ce＝1:2:0.2:0.05
Ca3(PO4)2を1モルとすると、Caは３モル、Pは２モル存在するので、４モル（H3PO4）を加える。Alは0.6,
Ceは0.15 at％
Phosphate glass component weight ratio
CaO: 26 w%, P2O5: 67 w%, Al2O3: 4 w%, Ce2O3: 3 w%
When converted to molar ratio,
CaO = 40 + 16 = 56
P2O5 = 31 × 2 + 16 × 5 = 142
Al2O3 = 27 × 2 + 16 × 3 = 102
Ce2O3 = 140 × 2 + 16 × 3 = 328
26/56: 67/142: 4/102: 3/328 = 0.464: 0.471: 0.04: 0.01 = 1: 1: 0.1: 0.025
Atomic ratio… Ca: P: Al: Ce = 1: 2: 0.2: 0.05
If 3 moles of Ca3 (PO4) 2 is present, 3 moles of Ca and 2 moles of P are present, so 4 moles (H3PO4) are added. Al is 0.6,
Ce 0.15 at%
スケール0.01
Ca3(PO4)2:
Ｍ−310g
3.1g 0.01モル Ca0.03モル P0.02モル
H3PO4：3+31+64＝98 98×0.01＝0.98g
0.98g×4＝4g
Al2O3
Al:0.6―Al2O3 0.3モル 0.3×0.01×102＝0.3g
Ce2O3
Ce＝0.15,
Ce2O3 0.015/2 モル 0.015/2×0.01×328＝0.025g
重要 CaO/P2O5＝0.78-0.86 モル比、ガラス化の条件
:102g×300度 3h
1300度 １ｈ
Scale 0.01
Ca3 (PO4) 2:
M-310g
3.1g 0.01mol Ca0.03mol P0.02mol
H3PO4: 3 + 31 + 64 = 98 98 × 0.01 = 0.98g
0.98g × 4 = 4g
Al2O3
Al: 0.6-Al2O3 0.3 mol 0.3 × 0.01 × 102 = 0.3g
Ce2O3
Ce = 0.15,
Ce2O3 0.015 / 2 mol 0.015 / 2 × 0.01 × 328 ＝ 0.025g
Important CaO / P2O5 = 0.78-0.86 molar ratio, vitrification conditions
: 102g × 300 degrees 3h
1300 degrees 1h
スケール0.01×5
Ca3(PO4)2:
Ｍ−310g 3.1g
0.01モル Ca0.03モル P0.02モル
Atomic ratio … Ca:P:Al:Ce＝1:2:0.2:0.05
Ca3(PO4)2を1モルとすると、Caは３モル、Pは２モル存在するので、P2O5を添加する量は、
Pが４モル必要、P2O5 2モル×0.01×142=2.84ｇ
Ca3(PO4)2:
3.1g
Al2O3
Al:0.6―Al2O3 0.3モル 0.3×0.01×102＝0.3g
Ce2O3
Ce＝0.15,
Ce2O3 0.015/2 モル 0.015/2×0.01×328＝0.025g
Ce(NO3)3 ＝140+3(14+16×3)＝326 0.015×0.01×326＝0.049g
３・２
メタリン酸Ca
メタリン酸は環状あるいは鎖状 (P03)
形式的に Ca(P03)2 これを酸化物の組成に直すと、CaP2O6…Ca0,P2O5(1:1)
Ca:Pの原子比は1:2となる。
Scale 0.01 × 5
Ca3 (PO4) 2:
M-310g 3.1g
0.01 mol Ca0.03 mol P0.02 mol
Atomic ratio… Ca: P: Al: Ce = 1: 2: 0.2: 0.05
If Ca3 (PO4) 2 is 1 mole, there are 3 moles of Ca and 2 moles of P, so the amount of P2O5 added is
4 mol of P is required, 2 mol of P2O5 x 0.01 x 142 = 2.84 g
Ca3 (PO4) 2:
3.1g
Al2O3
Al: 0.6-Al2O3 0.3 mol 0.3 × 0.01 × 102 = 0.3g
Ce2O3
Ce = 0.15,
Ce2O3 0.015 / 2 mol 0.015 / 2 × 0.01 × 328 ＝ 0.025g
Ce (NO3) 3 = 140 + 3 (14 + 16 × 3) = 326 0.015 × 0.01 × 326 = 0.049g
3.2
Metaphosphate Ca
Metaphosphoric acid is cyclic or linear (P03)
Formally Ca (P03) 2 When this is converted to the oxide composition, CaP2O6… Ca0, P2O5 (1: 1)
The atomic ratio of Ca: P is 1: 2.
「骨灰と５酸化リンと酸化アルミニウムと硝酸セリウムとの混合割合（重量比）」を、略６３：５８：６：１にするのが適している。 It is suitable that the “mixing ratio (weight ratio) of bone ash, phosphorus pentoxide, aluminum oxide and cerium nitrate” is approximately 63: 58: 6: 1.
「骨灰と５酸化リンと酸化アルミニウムと硝酸セリウム」に適量の着色材を添加することもできる。 An appropriate amount of coloring material can be added to “bone ash, phosphorus pentoxide, aluminum oxide, and cerium nitrate”.
「骨灰」には人骨灰又は動物骨灰が該当する。 “Bone ash” corresponds to human bone ash or animal bone ash.
「ガラス製品」には人造宝石等の装飾品、ガラス製位牌等の全てのガラス製品が該当する。 "Glass products" includes all glass products such as ornaments such as artificial jewels and glass glazing.
人骨灰（リン酸カルシウム）5g，五酸化リン4.57g, 酸化アルミニウム0.4g, 硝酸セリウム0.078g, コバルト適量を混ぜた混合物約10gをるつぼに入れ、1300°Cで約3時間加熱し、液状する。その後、約500°Cに加熱した型（ステンレス製）に流し込み、約2時間自然冷却することによって、本発明のガラス製品が得られた。なお、前記型はステンレス製で、直径13mm、深さ5mmのかボッシュ状のもの画複数形成されているものである。 About 10 g of a mixture of 5 g of human bone ash (calcium phosphate), 4.57 g of phosphorus pentoxide, 0.4 g of aluminum oxide, 0.078 g of cerium nitrate, and an appropriate amount of cobalt is put in a crucible and heated at 1300 ° C for about 3 hours to become liquid. Thereafter, the glass product of the present invention was obtained by pouring into a mold (made of stainless steel) heated to about 500 ° C. and naturally cooling for about 2 hours. The mold is made of stainless steel, and is formed with a plurality of Bosch-like objects having a diameter of 13 mm and a depth of 5 mm.
この発明に係る骨灰を使用したガラス製品の製造方法は、骨灰が燐酸塩ガラスの原料として結晶化かし、透明度の高い装飾性の高いガラス製品が製造されるものである。透明度の高くて、遺族等の心を充分に慰めることのできる装飾用ガラス製品又は人造宝石を製造することができる。以上のことから、産業上の利用可能性は高いと考える。
In the method for producing a glass product using bone ash according to the present invention, bone ash is crystallized as a raw material of phosphate glass, and a glass product with high transparency and high decorativeness is produced. It is possible to manufacture decorative glass products or artificial jewels that are highly transparent and can comfort the hearts of survivors. Based on the above, the industrial applicability is considered high.
Claims (4)
The said bone ash is human bone ash or animal bone ash, The manufacturing method of the glass product using the bone ash of Claim 1, Claim 2 or Claim 3 characterized by the above-mentioned.
Priority Applications (1)
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|---|---|---|---|
| JP2012116578A JP2013241313A (en) | 2012-05-22 | 2012-05-22 | Method for manufacturing glass product using bone ash |
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| JP2012116578A JP2013241313A (en) | 2012-05-22 | 2012-05-22 | Method for manufacturing glass product using bone ash |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20180059214A (en) * | 2016-11-25 | 2018-06-04 | 주식회사 마일스톤인터내셔널 | Method for manufaturing artificial jewel having unic color and structure depend on trace metal element of human or animal and artificial jewel using the same |
| KR102045890B1 (en) * | 2018-10-24 | 2019-12-04 | 비아로지스 주식회사 | Manufacturing Method of Synthetic Gemstone |
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| JPS6163540A (en) * | 1984-09-01 | 1986-04-01 | Kyushu Refract Co Ltd | Preparation of crystallized calcium phosphate glass for dental material |
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| JPS60180933A (en) * | 1984-02-24 | 1985-09-14 | Kyushu Refract Co Ltd | Artificial ivory |
| JPS6163540A (en) * | 1984-09-01 | 1986-04-01 | Kyushu Refract Co Ltd | Preparation of crystallized calcium phosphate glass for dental material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20180059214A (en) * | 2016-11-25 | 2018-06-04 | 주식회사 마일스톤인터내셔널 | Method for manufaturing artificial jewel having unic color and structure depend on trace metal element of human or animal and artificial jewel using the same |
| KR101878077B1 (en) | 2016-11-25 | 2018-07-23 | 주식회사 마일스톤인터내셔널 | Method for manufaturing artificial jewel having unic color and structure depend on trace metal element of human or animal and artificial jewel using the same |
| KR102045890B1 (en) * | 2018-10-24 | 2019-12-04 | 비아로지스 주식회사 | Manufacturing Method of Synthetic Gemstone |
| WO2020085647A1 (en) * | 2018-10-24 | 2020-04-30 | 비아로지스 주식회사 | Method for manufacturing paste jewelry |
| US10844512B2 (en) | 2018-10-24 | 2020-11-24 | Boram Holdings Co., Ltd. | Method for manufacturing synthetic gemstone |
| JP2021505500A (en) * | 2018-10-24 | 2021-02-18 | ビア ロジス カンパニー リミテッド | How to make artificial gems |
| JP2022009690A (en) * | 2018-10-24 | 2022-01-14 | ビア ロジス カンパニー リミテッド | Method of manufacturing artificial jewel |
| JP7161022B2 (en) | 2018-10-24 | 2022-10-25 | ビア ロジス カンパニー リミテッド | Method for manufacturing artificial gemstones |
| JP7462347B2 (en) | 2018-10-24 | 2024-04-05 | ビア ロジス カンパニー リミテッド | How artificial jewels are made |
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