JP2013207509A - Piezoelectric vibration piece and manufacturing method thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a piezoelectric vibration piece processing method in which it is difficult to generate fragments from a connection portion of a piezoelectric vibrator piece and a wafer when the piezoelectric vibrator piece is cut away from the wafer.SOLUTION: In a piezoelectric vibrator piece manufacturing method, by photo-etching a wafer 11 made of a piezoelectric material, a piezoelectric vibrator piece 12 having an outer shape of a piezoelectric vibration piece, a frame section 15 for supporting the piezoelectric vibrator piece, and a coupling section 13 for coupling the piezoelectric vibrator piece and the frame section are formed. By cutting the coupling section, the piezoelectric vibration piece is cut away from the frame section. An etching residual section 14 generated in photo-etching the wafer is formed on at least one part of an outer shape of the coupling section, and the coupling section is cut on a line passing through a portion, at which a size of the etching residual section is minimum or the etching residual section is not generated.

Description

  The present invention relates to a piezoelectric vibrating piece mounted on a piezoelectric device of a piezoelectric vibrator and a manufacturing method thereof, and more particularly to a technique for processing the outer shape of a piezoelectric vibrating piece by photoetching a wafer made of a piezoelectric material such as quartz.

  Conventionally, piezoelectric fork resonators such as tuning-fork crystal resonators and AT-cut crystal resonators mounted on various piezoelectric devices are processed by photoetching on crystal wafers such as quartz and patterned on the surface. (See, for example, Patent Document 1). Specifically, as illustrated in FIG. 3, a large number of crystal vibrating pieces 2 are attached to a crystal wafer 1 polished to a predetermined thickness, and the remainder of the crystal wafer, that is, a frame, is connected to the base end portion 2 a by a connecting portion 3. The outer shape of a desired tuning fork type crystal vibrating piece is processed so as to be connected and supported integrally with the portion 4. Next, after forming an electrode film on the surface of each crystal vibrating piece 2 in this state, each crystal vibrating piece 2 is broken off from the connecting portion 3 and separated. In general, the connecting portion 3 is formed in a wedge shape with a narrowest connection portion with the crystal vibrating piece 2 so as to be easily broken at a desired location (see, for example, Patent Document 2). The wedge-shaped notches 5 are formed on two sides of the connecting portion 3, respectively, and stress concentration is likely to occur at the notches 5 when the crystal vibrating piece 2 and the frame portion 4 are broken and separated. The connecting portion 3 is easily broken at a cutting line 5 a connecting the formed cuts 5. The crystal vibrating piece is broken, for example, by lowering the folding pin 5 from above and pushing the crystal vibrating piece.

JP 2011-45119 A Microfilm of Japanese Utility Model Application No. 1-113145 (Japanese Utility Model Application Publication No. 3-70421)

  However, an etching residue 10 due to material anisotropy is formed in the connecting portion 3 during external processing by photoetching. The etching residue 10 is very thin. When stress is applied to the etching residue 10, the etching residue 10 is damaged and fragments are generated. When the generated fragments adhere to the crystal vibrating piece 2, there are some prisoners that deteriorate the characteristics of the crystal vibrating piece 2, such as the oscillation frequency and the CI value, and cause the reliability and yield reduction of the crystal vibrating piece. Further, for example, in the case of a tuning fork type crystal vibrating piece, the etching residue 10 may be formed as a wedge-shaped cut 10a made of an etching residue on one side of the connecting portion 3 separately from the notch 5 of the connecting portion 3 described above. is there. When the crystal vibrating piece 2 is folded in a state where such an etching residue 10 is formed, stress concentration occurs in the cuts 5 and 10a. Here, when the notch 5 and the notch 10a of the etching residue 10 are not on the same line as the cutting line 5a, a torsional stress is generated on the surface of the etching residue 10, and the generation of fragments due to the damage of the etching residue 10 is particularly increased. There is a high risk of deterioration of the characteristics of the resonator element 2.

  Accordingly, the present invention has been made in view of the above-described conventional problems, and an object of the present invention is to reduce etching residue fragments that are likely to occur when the piezoelectric vibrating piece is folded from the wafer, thereby improving the yield. Another object of the present invention is to provide a piezoelectric vibrating piece and a method for manufacturing the same that can improve reliability.

  According to the present invention, in order to achieve the above object, a piezoelectric vibrator piece having an outer shape of a piezoelectric vibrating piece and a frame for supporting the piezoelectric vibrator piece by photoetching a wafer made of a piezoelectric material. In the method of manufacturing a piezoelectric vibrating piece in which the piezoelectric vibrating piece is separated from the frame portion by forming a connecting portion that connects the portion, the piezoelectric vibrator piece and the frame portion, and cutting the connecting portion. An etching residue portion generated when the wafer is photoetched is formed on at least a part of the outer shape of the portion, and the size of the etching residue portion is the smallest or the portion where the etching residue portion is not generated A method of manufacturing a piezoelectric vibrating piece in which the connecting portion is cut on a passing line is provided.

  Thereby, the piece which generate | occur | produces when cut | disconnecting the said connection part can be reduced.

  Furthermore, by forming a groove on at least a part of the surface of the piezoelectric vibrating reed on the cutting line of the connecting portion, it is possible to cut accurately and easily at a portion where the etching residue portion is minimal or not generated.

  Furthermore, by providing the groove on the front and back main surfaces of the connecting portion, it is possible to reliably cut at a desired portion.

  Further, the groove can be easily formed by half-etching the wafer.

  According to another aspect of the present invention, there is provided a piezoelectric vibrator piece processed by the above-described method of the present invention.

  In the present invention, as described above, a piezoelectric vibrator piece that has been externally processed by photoetching on a wafer of piezoelectric material is placed on a line that passes through a portion where the etching residue portion formed at the connecting portion with the wafer is minimal or has not occurred. Since the connecting portion is cut, the possibility that the etching residue becomes a fragment at the time of cutting can be reduced. For this reason, it is possible to reduce the deterioration of characteristics such as the oscillation frequency and CI value caused by the fragments adhering to the piezoelectric vibrating piece, and it is possible to improve the yield and reliability.

The figure for demonstrating the manufacturing method of the piezoelectric vibrating piece of this invention. The figure for demonstrating the piezoelectric vibrating piece of this invention. The figure for demonstrating the manufacturing method of the conventional quartz crystal vibrating piece.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

  FIG. 1 is a diagram for explaining a method of manufacturing a piezoelectric vibrating piece according to the present invention. The quartz wafer 11 shows the shape of the quartz crystal vibrating piece 12, the connecting portion 13, the etching residue 14, and the frame portion 15 formed by photoetching. However, as for the etching residue, only the periphery of the connecting portion related to the present invention is shown as an enlarged view in FIG. The crystal resonator 12 is connected to the connecting portion 13. An etching residue 14 generated when the wafer is photo-etched is formed in the connecting portion 13. Etching residue 14 tends to remain largely on one side or corner due to crystal anisotropy. In the present invention, since cutting is performed at a portion where the etching residue is minimal or absent, the linear connecting portion 13 extending from the base end portion 12a of the quartz crystal vibrating piece 12 is formed so that a portion where the etching residue becomes small can be formed. Further, if the base end portion 12a and the cut portion are separated from each other, the outer shape of the crystal vibrating piece 12 becomes large. 16 is provided. As a result, the distance from the base end portion 12a to the portion where the etching residue 14 is minimum or absent is shortened, and the distance between the base end portion 12a and the cut portion can be minimized. In addition, a straight groove 13a is formed by half-etching on a line passing through a portion where the etching residue 14 is minimal or absent.

  The quartz crystal resonator element of this example is processed using photoetching as follows. First, a metal thin film made of Cr, Au or the like is deposited as a corrosion-resistant film on the surface of a quartz wafer 11 having a predetermined thickness polished on both sides by deposition, sputtering, etc., and a resist film is applied thereon to apply a photolithography technique. After patterning the outer shape of the desired tuning-fork type crystal vibrating piece by the above, etching is performed with an appropriate etching solution such as hydrofluoric acid or ammonium fluoride to leave the connecting portion 13 with the frame portion 14 in FIG. A large number of crystal vibrating pieces 12 are processed as shown in FIG.

  Next, while leaving the resist film, the shape of the groove 13a is similarly patterned on both surfaces of the quartz wafer 11, and the groove 13a is formed by half-etching to an appropriate depth using an appropriate etching solution. When a desired electrode film is formed by depositing an electrode material on the surface of the quartz-crystal vibrating piece 12 thus photo-etched by vapor deposition, sputtering, etc., and patterning by a photolithography technique, a large number of quartz-crystal vibrating pieces 12 are arranged. The crystal wafer 11 is completed.

  For example, as described above with reference to the prior art, each crystal vibrating piece 12 is separated from the quartz wafer 11 by being broken using a folding pin as shown in FIG. As a matter of course, the present invention is not limited to folding with a pin, and the quartz vibrating piece 12 may be pulled up by a suction nozzle and broken, or may be cut with a laser or the like. As such, the crystal vibrating piece 12 is cut along the groove 13a provided in the cutting portion.

  In this embodiment, as shown in FIG. 1, there is a portion where the etching residue 14 is not formed in the connecting portion 13, and the etching residue generated at the time of folding by folding from the crystal wafer 11 on the line passing therethrough. 14 pieces are kept to a minimum. Further, for example, as shown in FIG. 3, if there is no portion where no etching residue is formed in the connecting portion, fragments of the etching residue 14 can be obtained by cutting the connecting portion on a line passing through the portion where the etching residue is minimized. Can be minimized. However, in such a case, it is important to cut on the line passing through the portion where the etching residue is minimized, and when there is a cut in the connecting portion as shown in FIG. It is necessary to appropriately determine the position or the like for forming the cut so as to be located on one line.

  FIG. 2 shows a crystal resonator on which a crystal resonator element 12 processed according to the first embodiment of the present invention described above with reference to FIG. 1 and separated into individual pieces is mounted. The package 20 has, for example, a rectangular box-shaped base 21 in which ceramic thin plates are laminated, and a pair of connection terminals 23 are provided near one end at the bottom of a space 22 defined therein. Yes. The quartz crystal resonator element 12 is mechanically and electrically connected with a conductive adhesive 25 by aligning the electrodes provided on the base end portion 12 a with the corresponding connection terminals 23. The package 20 is hermetically sealed by bonding a thin plate-like lid 26 to the upper end of the base 21.

  As described above, the quartz crystal resonator element 12 according to the present embodiment minimizes the distance between the base end portion 12a and the cut portion, and thus can cope with further downsizing of the package. .

  The preferred embodiments of the present invention have been described in detail above. However, as will be apparent to those skilled in the art, the present invention can be carried out with various modifications and variations within the technical scope thereof. . For example, a thin wall portion is provided at the connecting portion between the base end portion 12a and the connecting portion 13 with various shapes and structures other than the groove 13a, such as a linearly continuous small dent, and the connecting portion 13 is connected. The part can always be folded in a substantially constant shape. Furthermore, the present invention can be similarly applied to a crystal vibrating piece other than a tuning fork type and a piezoelectric vibrating piece other than quartz as long as the outer shape is processed by photoetching.

DESCRIPTION OF SYMBOLS 1 Crystal wafer 2 Crystal vibration piece 2a Base end part 3 Connection part 4 Frame part 5 Cut 5a Cutting line 10 Etching residue 10a Cut 11 Crystal wafer 12 Crystal vibration piece 12a Base end part 13 Connection part 13a Groove 14 Etch residue 15 Frame part 16 Recess 20 Package 21 Base 22 Space 23 Connection terminal 25 Conductive adhesive 26 Lid

Claims (6)

  A piezoelectric vibrator piece having an outer shape of a piezoelectric vibrating piece, a frame portion for supporting the piezoelectric vibrator piece, and a connection between the piezoelectric vibrator piece and the frame portion by photoetching a wafer made of a piezoelectric material In the method for manufacturing a piezoelectric vibrating piece in which the piezoelectric vibrating piece is separated from the frame by cutting the connecting portion, the wafer is photoetched on at least a part of the outer shape of the connecting portion. An etching residue portion generated when the etching residue portion is formed, and the connecting portion is cut on a line passing through a portion where the size of the etching residue portion is minimum or the etching residue portion is not generated. A method for manufacturing a piezoelectric vibrating piece.   The method for manufacturing a piezoelectric vibrating piece according to claim 1, wherein a groove is formed on at least a part of the surface of the piezoelectric vibrating piece corresponding to the cutting line of the connecting portion.   The method for manufacturing a piezoelectric vibrating piece according to claim 2, wherein the groove is provided on both front and back main surfaces of the connecting portion.   The method for manufacturing a piezoelectric vibrating piece according to claim 2, wherein the groove is formed by half-etching the wafer.   The method for manufacturing a piezoelectric vibrating piece according to claim 1, wherein the piezoelectric material is quartz.   A piezoelectric vibrating piece manufactured by the method according to claim 1.

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