JP2013179842A - Quality improving agent for rice cracker and rice cracker - Google Patents

Quality improving agent for rice cracker and rice cracker Download PDF

Info

Publication number
JP2013179842A
JP2013179842A JP2012043742A JP2012043742A JP2013179842A JP 2013179842 A JP2013179842 A JP 2013179842A JP 2012043742 A JP2012043742 A JP 2012043742A JP 2012043742 A JP2012043742 A JP 2012043742A JP 2013179842 A JP2013179842 A JP 2013179842A
Authority
JP
Japan
Prior art keywords
rice
tapioca starch
starch
acetylated
rice cracker
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2012043742A
Other languages
Japanese (ja)
Other versions
JP5936880B2 (en
Inventor
Hitoshi Takaguchi
均 高口
Ryuichi Ando
竜一 安東
Masayasu Takada
正保 高田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Maize Products Co Ltd
Nihon Shokuhin Kako Co Ltd
Original Assignee
Japan Maize Products Co Ltd
Nihon Shokuhin Kako Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Maize Products Co Ltd, Nihon Shokuhin Kako Co Ltd filed Critical Japan Maize Products Co Ltd
Priority to JP2012043742A priority Critical patent/JP5936880B2/en
Publication of JP2013179842A publication Critical patent/JP2013179842A/en
Application granted granted Critical
Publication of JP5936880B2 publication Critical patent/JP5936880B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Confectionery (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a quality improving agent for rice cracker giving excellent palate feeling to rice cracker having Indica rice as a main raw material, capable of forming dough suitable for handling when producing, and capable of suppressing crack when drying and baking.SOLUTION: A rice cracker having Indica rice as a main raw material includes, as a quality improving agent for rice cracker, processed tapioca starch of one kind or two or more kinds selected from bleached tapioca starch, oxidized tapioca starch, acetylated tapioca starch, acetylated bleached tapioca starch, and acetylated oxidized tapioca starch. The processed tapioca starch preferably has a heat dissolution degree of ≥20% and a heat swelling degree of ≥35 times.

Description

本発明はインディカ米米菓の品質改良剤及び該品質改良剤を含有する米菓に関する。   The present invention relates to a quality improver for indica rice rice crackers and a rice cracker containing the quality improver.

米菓は米から製造される菓子であり、主原料となる米、米粉若しくは酒粉に、副原料となる澱粉、小麦粉、そば粉等を加えた後に、蒸練することで生地を得、これを搗き及び/又は圧延した後に冷却、乾燥、切断、成形して、焼成又は油ちょうし、醤油、塩、砂糖等の調味料で味付けして調製される。せんべい、おかき、あられ、柿の種等が知られ、軽く、サクサクした米菓特有の食感を有する菓子である。   Rice confectionery is a confectionery produced from rice. After adding starch, wheat flour, buckwheat flour, etc. as auxiliary ingredients to rice, rice flour or sake powder as the main ingredient, the dough is obtained by steaming. After cooling and / or rolling, it is cooled, dried, cut, shaped, baked or oiled, seasoned with seasonings such as soy sauce, salt, sugar and the like. Rice crackers, rice crackers, hail, persimmon seeds, etc. are known and are light and crispy rice confectionery with a unique texture.

米菓の主原料としては、主にモチ種及びウルチ種のジャポニカ米が利用されているが、近年の農作物価格高騰に伴い、ジャポニカ米の安価代替食品素材として、生産量がジャポニカ米の5倍程度と多く安価であるインディカ米が注目されている。しかしながら、インディカ米はジャポニカ米と比較して含有する澱粉のアミロース含有率が高く、澱粉の老化性が著しく高いため、米菓に利用した場合には生地の乾燥、焼成及び/又は油ちょうのときにひび割れが発生し易い傾向にあった。また、米菓に好ましくない硬くボリボリとした食感を付与してしまうという問題があった。   The main ingredient of rice crackers is mainly mochi and uruchi japonica rice, but with the recent increase in crop prices, as a cheap alternative food material for japonica rice, the production volume is five times that of japonica rice. Indica rice, which is moderate and inexpensive, is attracting attention. However, indica rice has a higher amylose content in starch compared to japonica rice, and the aging of starch is extremely high, so when used in rice crackers, when dough is dried, baked and / or oiled There was a tendency for cracks to occur easily. Moreover, there existed a problem of giving the unpleasant hard and crunchy texture to rice crackers.

インディカ米を米菓として利用するために、従来、様々な検討がなされてきた。例えば特許文献1にはジャポニカ米と同様の工程で米菓を製造するためインディカ米に細胞壁組成成分分解酵素セルラーゼを作用させることが記載されている。また、特許文献2にはインディカ米にアルカリ性カルシウム剤を添加することで糊化特性が改変され、食味、食感、風味などに優れた米菓が得られることが記載されている。また、特許文献3には高アミロース米とタピオカ澱粉を主成分として含有してなることを特徴とする米を素材とした加工食品が記載されている。また、特許文献4には米及び/又は米粉に架橋又はアセチル化したワキシーポテト澱粉を添加することで、加工特性に優れたドウを形成することができ、製品形状及び食感に優れた米菓が得られることが記載されている。また、特許文献5には主原料としてワキシーコーンスタ−チを約10重量%以上含有する米菓の製造に際し、タピオカ澱粉、サゴ澱粉、馬鈴薯澱粉及びワキシーコーンスタ−チから選ばれた一種又は2種以上の原料澱粉から製造されたアセチル化澱粉及び/又はヒドロキシプロピル化澱粉100重量部に対し架橋タピオカ澱粉0〜100重量部からなる加工澱粉を、主原料に対し5〜95重量%添加することで、乾燥、焼成時の米菓のひび割れを改善できることが記載されている。また、特許文献6には米菓の副原料の澱粉としてタピオカ澱粉に架橋による処理と次亜塩素酸ソーダによる処理を併用処理した澱粉を配合することで、膨化に優れ、食感のよい米菓が得られることが記載されている。   In order to use indica rice as rice crackers, various studies have been made in the past. For example, Patent Document 1 describes that cell wall composition component degrading enzyme cellulase is allowed to act on indica rice in order to produce rice crackers in the same process as japonica rice. Patent Document 2 describes that by adding an alkaline calcium agent to indica rice, gelatinization characteristics are modified, and rice confectionery having excellent taste, texture, flavor and the like can be obtained. Patent Document 3 describes a processed food made from rice, characterized by containing high amylose rice and tapioca starch as main components. Patent Document 4 discloses that rice and / or rice flour can be formed into dough having excellent processing characteristics by adding a waxy potato starch that has been cross-linked or acetylated to the rice flour. Is obtained. Patent Document 5 discloses that one or two kinds selected from tapioca starch, sago starch, potato starch and waxy corn starch are used in the manufacture of rice crackers containing waxy corn starch as a main ingredient in an amount of about 10% by weight or more. 5 to 95% by weight of a modified starch comprising 0 to 100 parts by weight of crosslinked tapioca starch to 100 parts by weight of acetylated starch and / or hydroxypropylated starch produced from more than one kind of raw material starch It is described that cracking of rice crackers during drying and baking can be improved. In addition, Patent Document 6 is a rice confectionery that is excellent in swelling and has a good texture by adding starch obtained by using a combination of crosslinking treatment and sodium hypochlorite treatment to tapioca starch as an auxiliary material starch of rice confectionery. Is obtained.

特開平7−163297号公報JP-A-7-163297 特開平10−191893号公報JP-A-10-191893 特開平9−28331号公報Japanese Patent Laid-Open No. 9-28331 特開2007−151517号公報JP 2007-151517 A 特開平6−276949号公報JP-A-6-276949 特開2005−27644号公報JP-A-2005-27644

しかしながら、上記特許文献1〜2の技術では、酵素処理やアルカリ処理の工程が煩雑であり、生産性が良い方法とはいえなかった。また、上記特許文献3には、高アミロース米を素材とした加工食品として米麺や、春巻き、ギョーザ、ワンタン、ラビオリ、タコス等の皮などが挙げられているが、米菓については記載されていない。更に、上記特許文献4〜6では、ジャポニカ米を原料とする米菓についての記載にとどまり、インディカ米を原料とする米菓に対して良好な食感及び形状の安定化を付与することは記載されていない。   However, the techniques of Patent Documents 1 and 2 are complicated methods for enzyme treatment and alkali treatment, and cannot be said to be a method with good productivity. In addition, Patent Document 3 includes rice noodles, spring rolls, gyoza, wonton, ravioli, tacos and other skins as processed foods made from high amylose rice. However, rice confections are not described. Absent. Furthermore, in the said patent documents 4-6, it is only description about the rice cracker which uses japonica rice as a raw material, and providing favorable food texture and shape stabilization with respect to the rice cracker which uses indica rice as a raw material is described. It has not been.

したがって、本発明の目的は、インディカ米を主原料とする米菓に良好な食感を付与すると共に、製造時のハンドリングに好適なドウを形成することができ、更に乾燥、焼成時のひび割れを抑制することができる、米菓の品質改良剤及びそれを含有してなる米菓を提供することにある。   Therefore, the object of the present invention is to impart a good texture to rice crackers made mainly of indica rice, to form a dough suitable for handling during production, and to further prevent cracks during drying and baking. An object of the present invention is to provide a rice cracker quality improver that can be suppressed and a rice cracker containing the same.

本発明者らは、上記目的を達成するため鋭意研究し、本発明を完成するに至った。   The inventors of the present invention have intensively studied to achieve the above object and have completed the present invention.

即ち、本発明の1つは、漂白タピオカ澱粉、酸化タピオカ澱粉、アセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上の加工タピオカ澱粉を含有することを特徴とするインディカ米米菓の品質改良剤を提供するものである。   That is, one of the present invention contains one or two or more kinds of processed tapioca starch selected from bleached tapioca starch, oxidized tapioca starch, acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch. The quality improving agent of the indica rice rice cracker characterized by this is provided.

本発明の米菓の品質改良剤においては、前記加工タピオカ澱粉は、加熱溶解度が20%以上であり且つ加熱膨潤度が35倍以上であることが好ましい。   In the rice cracker quality improving agent of the present invention, the processed tapioca starch preferably has a heat solubility of 20% or more and a heat swelling degree of 35 times or more.

また、前記加工タピオカ澱粉は、カルボキシル基含量が0.4質量%以下であることが好ましい。   The processed tapioca starch preferably has a carboxyl group content of 0.4% by mass or less.

また、前記加工タピオカ澱粉は、アセチル基含量が0.9質量%以上のアセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上であることが好ましい。   The processed tapioca starch is preferably one or more selected from acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch having an acetyl group content of 0.9% by mass or more.

また、前記加工タピオカ澱粉は、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種以上であることが好ましい。   The processed tapioca starch is preferably at least one selected from acetylated bleached tapioca starch and acetylated oxidized tapioca starch.

一方、本発明のもう1つは、インディカ米を主原料とし、上記のインディカ米米菓の品質改良剤を含有することを特徴とする米菓を提供するものである。   On the other hand, another aspect of the present invention is to provide a rice cracker characterized in that it contains indica rice as a main ingredient and contains the above-described quality improver for indica rice crackers.

本発明によれば、インディカ米を主原料とする米菓に、特定の加工を施したタピオカ澱粉を含有せしめることによって、米菓特有の軽く、サクサクした食感を付与すると共に、生地調製直後は柔らかく冷却後に硬化する生地物性を付与し、更に乾燥、焼成時のひび割れを抑制することができる。   According to the present invention, rice confectionery mainly made of indica rice is added with tapioca starch that has been subjected to a specific process to give a light and crispy texture unique to rice confectionery, and immediately after dough preparation. The material property which softens and hardens | cures after cooling can be provided, and also the crack at the time of drying and baking can be suppressed.

本発明においては、漂白タピオカ澱粉、酸化タピオカ澱粉、アセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上の加工タピオカ澱粉が用いられる。   In the present invention, one or two or more kinds of processed tapioca starch selected from bleached tapioca starch, oxidized tapioca starch, acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch are used.

本発明に用いる漂白タピオカ澱粉は、例えば、以下の方法により、弱酸性からアルカリ性条件下での漂白処理により得ることができる。   The bleached tapioca starch used in the present invention can be obtained, for example, by a bleaching treatment under mildly acidic to alkaline conditions by the following method.

原料となるタピオカ澱粉に予め水を添加して30〜45質量%のスラリー状にする。塩酸等の酸、あるいは水酸化ナトリウム等のアルカリ剤を添加してpH5〜12に調整する。調製後の澱粉糊が低粘度化せず、澱粉中のカルボキシル基含量が0.1質量%未満となる量の次亜塩素酸ナトリウム水溶液(例えば有効塩素濃度が澱粉に対して0.01%程度の量)をスラリーに添加し、30〜120分間反応する。その後、水洗、脱水した後、乾燥させる。   Water is previously added to the tapioca starch used as a raw material to form a slurry of 30 to 45% by mass. An acid such as hydrochloric acid or an alkali agent such as sodium hydroxide is added to adjust the pH to 5-12. An aqueous sodium hypochlorite solution in which the starch paste after the preparation does not have a low viscosity and the carboxyl group content in the starch is less than 0.1% by mass (for example, the effective chlorine concentration is about 0.01% with respect to the starch) Is added to the slurry and reacted for 30-120 minutes. Thereafter, it is washed with water, dehydrated and then dried.

本発明に用いる酸化タピオカ澱粉は、例えば、以下の方法で得ることができる。   The oxidized tapioca starch used in the present invention can be obtained, for example, by the following method.

原料となるタピオカ澱粉に予め水を添加して30〜45質量%のスラリー状にする。塩酸等の酸、あるいは水酸化ナトリウム等のアルカリ剤を添加してpH5〜12に調整する。調製後の澱粉糊が低粘度化し、澱粉中のカルボキシル基含量が0.1質量%以上1.1質量%以下となる量の次亜塩素酸ナトリウム水溶液(例えば有効塩素濃度が澱粉に対して1%程度の量)をスラリーに添加し、30〜120分間反応する。その後、水洗、脱水した後、乾燥させる。   Water is previously added to the tapioca starch used as a raw material to form a slurry of 30 to 45% by mass. An acid such as hydrochloric acid or an alkali agent such as sodium hydroxide is added to adjust the pH to 5-12. An aqueous sodium hypochlorite solution (for example, having an effective chlorine concentration of 1 with respect to starch) such that the starch paste after the preparation has a reduced viscosity and the carboxyl group content in the starch is 0.1% by mass or more and 1.1% by mass or less. %) Is added to the slurry and reacted for 30-120 minutes. Thereafter, it is washed with water, dehydrated and then dried.

本発明に用いるアセチル化タピオカ澱粉は、例えば、以下の方法で得ることができる。   The acetylated tapioca starch used in the present invention can be obtained, for example, by the following method.

原料となるタピオカ澱粉に予め水を添加して30〜45質量%のスラリー状にする。水酸化ナトリウム等のアルカリ剤を添加してpH8〜12に調整する。澱粉に対して1〜10質量%の無水酢酸、あるいは酢酸ビニルをスラリーに添加し、10〜180分間反応する。その後、水洗、脱水した後、乾燥させる。   Water is previously added to the tapioca starch used as a raw material to form a slurry of 30 to 45% by mass. An alkaline agent such as sodium hydroxide is added to adjust the pH to 8-12. Add 1 to 10% by weight of acetic anhydride or vinyl acetate to the starch and react for 10 to 180 minutes. Thereafter, it is washed with water, dehydrated and then dried.

本発明に用いるアセチル化漂白タピオカ澱粉は、例えば、以下の方法で得ることができる。   The acetylated bleached tapioca starch used in the present invention can be obtained, for example, by the following method.

原料となるタピオカ澱粉に予め水を添加して30〜45質量%のスラリー状にする。塩酸等の酸、あるいは水酸化ナトリウム等のアルカリ剤を添加してpH5〜12に調整する。調製後の澱粉糊が低粘度化せず、澱粉中のカルボキシル基含量が0.1質量%未満となる量の次亜塩素酸ナトリウム水溶液(例えば有効塩素濃度が澱粉に対して0.01%程度の量)をスラリーに添加し、30〜120分間反応する。次いで、澱粉に対して1〜10質量%の無水酢酸、あるいは酢酸ビニルをスラリーに添加し、10〜180分間反応する。その後、水洗、脱水した後、乾燥させる。   Water is previously added to the tapioca starch used as a raw material to form a slurry of 30 to 45% by mass. An acid such as hydrochloric acid or an alkali agent such as sodium hydroxide is added to adjust the pH to 5-12. An aqueous sodium hypochlorite solution in which the starch paste after the preparation does not have a low viscosity and the carboxyl group content in the starch is less than 0.1% by mass (for example, the effective chlorine concentration is about 0.01% with respect to the starch) Is added to the slurry and reacted for 30-120 minutes. Next, 1 to 10% by mass of acetic anhydride or vinyl acetate based on the starch is added to the slurry and reacted for 10 to 180 minutes. Thereafter, it is washed with water, dehydrated and then dried.

本発明に用いるアセチル化酸化タピオカ澱粉は、例えば、以下の方法で得ることができる。   The acetylated oxidized tapioca starch used in the present invention can be obtained, for example, by the following method.

原料となるタピオカ澱粉に予め水を添加して30〜45質量%のスラリー状にする。塩酸等の酸、あるいは水酸化ナトリウム等のアルカリ剤を添加してpH5〜12に調整する。調製後の澱粉糊が低粘度化し、澱粉中のカルボキシル基含量が0.1質量%以上1.3質量%以下となる量の次亜塩素酸ナトリウム水溶液(例えば有効塩素濃度が澱粉に対して1%程度の量)をスラリーに添加し、30〜120分間反応する。次いで、澱粉に対して1〜10質量%の無水酢酸、あるいは酢酸ビニルをスラリーに添加し、10〜180分間反応する。その後、水洗、脱水した後、乾燥させる。   Water is previously added to the tapioca starch used as a raw material to form a slurry of 30 to 45% by mass. An acid such as hydrochloric acid or an alkali agent such as sodium hydroxide is added to adjust the pH to 5-12. An aqueous sodium hypochlorite solution (for example, having an effective chlorine concentration of 1 with respect to starch) such that the starch paste after the preparation has a reduced viscosity and the carboxyl group content in the starch is from 0.1% by mass to 1.3% by mass. %) Is added to the slurry and reacted for 30-120 minutes. Next, 1 to 10% by mass of acetic anhydride or vinyl acetate based on the starch is added to the slurry and reacted for 10 to 180 minutes. Thereafter, it is washed with water, dehydrated and then dried.

本発明に用いる加工タピオカ澱粉は、その加熱溶解度が20%以上であり且つ加熱膨潤度が35倍以上であることが好ましく、その加熱溶解度が40〜60%であり且つ加熱膨潤度が40〜60倍であることがより好ましい。加熱溶解度や加熱膨潤度の値がこれらの範囲より小さいと、米菓の食感が硬くなり、且つ膨化度が低くなる傾向がある。また、生地の冷却硬化速度がやや遅くなり、製造時のハンドリング性が悪くなる傾向がある。   The processed tapioca starch used in the present invention preferably has a heat solubility of 20% or more and a heat swelling degree of 35 times or more, a heat solubility of 40 to 60% and a heat swelling degree of 40 to 60. More preferably, it is double. When the value of the heat solubility or the heat swelling degree is smaller than these ranges, the texture of rice crackers tends to be hard and the degree of swelling tends to be low. Also, the cooling and curing rate of the dough tends to be slightly slow, and the handling properties during production tend to be poor.

加熱溶解度とは澱粉を加熱糊化させた際に澱粉粒から溶出する糖量度合であり、本明細書においては以下のようにして算出される値を意味する。   The heat solubility is the amount of sugar eluted from starch granules when starch is gelatinized by heating, and means a value calculated as follows in this specification.

澱粉試料0.2gを水19.8mlに分散して、沸騰水浴中で30分間加熱を行った後、25℃水道水浴中で30分間冷却する。次いで、この液を遠心分離(3000rpm、10分間)して沈澱層と上層に分ける。この上層に含まれる全糖量をフェノール硫酸法で測定し、その容量に対する質量%濃度として加熱溶解度を算出する。   A starch sample (0.2 g) is dispersed in 19.8 ml of water, heated in a boiling water bath for 30 minutes, and then cooled in a 25 ° C. tap water bath for 30 minutes. Subsequently, this liquid is centrifuged (3000 rpm, 10 minutes) to separate the precipitate layer and the upper layer. The total amount of sugar contained in the upper layer is measured by the phenol-sulfuric acid method, and the heating solubility is calculated as the concentration by mass with respect to the volume.

本明細書において加熱膨潤度は、以下のようにして算出される値を意味する。   In the present specification, the degree of thermal swelling means a value calculated as follows.

澱粉試料1.0gを水100mlに分散し、沸騰水中で時々撹拌しながら30分間加熱後、30℃に冷却する。次いで、この糊液を遠心分離(3000rpm、10分間)して糊層と上澄液層に分け、糊層の重量を測定してこれをcとする。次いで、重量測定した糊層を105℃で乾固した後、重量を測定してこれをdとし、c/dの値を加熱膨潤度(倍)とする。尚、糊層と上澄液層とが分離しない場合には、膨潤度が「極めて大きい」ものと評価できる。   A starch sample (1.0 g) is dispersed in 100 ml of water, heated for 30 minutes with occasional stirring in boiling water, and then cooled to 30 ° C. Next, this paste solution is centrifuged (3000 rpm, 10 minutes) to be divided into a paste layer and a supernatant layer, and the weight of the paste layer is measured to obtain c. Next, after the weight-measured adhesive layer is dried at 105 ° C., the weight is measured and set to d, and the value of c / d is set to the degree of heating swelling (times). When the glue layer and the supernatant layer are not separated, it can be evaluated that the degree of swelling is “very large”.

加熱溶解度及び加熱膨潤度は、トリメタリン酸ソーダ、塩化ホスホリル等架橋剤の処理により澱粉分子内に結合様式が導入された場合に、その値が減少する。一方、次亜塩素酸ナトリウム水溶液、糖化酵素、酸等の処理により、澱粉分子の低分子化が進行した場合に、その値が増加する。したがって、当業者に周知の方法に準じて、本発明の効果を損なわない範囲で適宜これらの処理を行って、加熱溶解度及び/又は加熱膨潤度を調整することもできる。   The values of the heat solubility and the heat swell degree decrease when a binding mode is introduced into starch molecules by treatment with a crosslinking agent such as sodium trimetaphosphate and phosphoryl chloride. On the other hand, when the starch molecules are reduced in molecular weight by treatment with an aqueous sodium hypochlorite solution, saccharifying enzyme, acid, or the like, the value increases. Therefore, according to a method well known to those skilled in the art, these treatments can be appropriately performed within a range not impairing the effects of the present invention to adjust the heating solubility and / or the heating swelling degree.

本発明に用いる加工タピオカ澱粉は、そのカルボキシル基含量が0.4質量%以下であることが好ましく、0.02質量%以下であることがより好ましい。カルボキシル基含量の値がこれらの範囲より大きいと、冷却硬化後の生地が硬く、切れ易くなる傾向がある。また、乾燥、焼成時に米菓がひび割れを起こし易くなる傾向がある。尚、カルボキシル基含量は、前述した漂白や酸化などの加工調製時に用いられる次亜塩素酸ナトリウム等の酸化剤の添加量に依存して増減する。よってそれら加工タピオカ澱粉の調製のときに、酸化剤の濃度や処理時間等を適宜調整することで、そのカルボキシル基含量を調整することができる。   The processed tapioca starch used in the present invention preferably has a carboxyl group content of 0.4% by mass or less, and more preferably 0.02% by mass or less. If the value of the carboxyl group content is larger than these ranges, the dough after cooling and hardening tends to be hard and easy to cut. In addition, rice crackers tend to crack during drying and baking. The carboxyl group content increases or decreases depending on the amount of an oxidizing agent such as sodium hypochlorite used during the processing preparation such as bleaching and oxidation described above. Therefore, when preparing these processed tapioca starches, the carboxyl group content can be adjusted by appropriately adjusting the concentration of the oxidizing agent, the treatment time, and the like.

本明細書においてカルボキシル基含量は、以下のようにして算出される値を意味する。   In the present specification, the carboxyl group content means a value calculated as follows.

絶乾した加工タピオカ澱粉を吸湿しないように注意しながらすりつぶし、標準網ふるい850μmを通過させたものを3g正確に秤量する。これに0.1N塩酸25mlを加え、時々かき混ぜながら30分間放置した後、吸引ろ過し、ビーカーの残留物を水でろ過器に洗い込む。ろ紙上の残留物を洗液が塩化物の反応を呈さなくなるまで水で洗浄し、洗浄後の残留物を採取する。これをビーカーに入れ、水300mlを加えて懸濁し、撹拌しながら水浴中で加熱して糊化させ、更に15分間加熱する。水浴から取り出し、熱いうちに0.1mol/L水酸化ナトリウム溶液で滴定し(指示薬:フェノールフタレイン)、その滴定量(ml)をSとする。別途、同量の未加工澱粉を正確に秤量し、ビーカーに入れ水10mlを加えて30分間撹拌して懸濁する。その懸濁液を吸引ろ過し、ビーカーの残留物をろ過器に洗い込む。ろ紙上の残留物を水200mlで洗浄し、洗浄後の残留物を採取する。これをビーカーに入れ、水300mlを加えて懸濁し、以下上記と同様に操作し、0.1mol/L水酸化ナトリウム溶液での滴定量(ml)をBとする。下記式(1)によりカルボキシル基含量を算出する。   The dried tapioca starch is crushed with care so as not to absorb moisture, and 3 g is accurately weighed through a standard mesh sieve of 850 μm. To this is added 25 ml of 0.1N hydrochloric acid, and the mixture is allowed to stand for 30 minutes with occasional stirring, followed by suction filtration. The residue of the beaker is washed into the filter with water. The residue on the filter paper is washed with water until the washing solution does not react with chloride, and the residue after washing is collected. This is put into a beaker, 300 ml of water is added and suspended, heated in a water bath with stirring and gelatinized, and further heated for 15 minutes. Remove from the water bath, and titrate with a 0.1 mol / L sodium hydroxide solution while hot (indicator: phenolphthalein). Separately, the same amount of raw starch is accurately weighed, placed in a beaker, added with 10 ml of water, and stirred for 30 minutes to be suspended. The suspension is suction filtered and the beaker residue is washed into the filter. The residue on the filter paper is washed with 200 ml of water, and the residue after washing is collected. This is put into a beaker, 300 ml of water is added and suspended, and the operation is performed in the same manner as above, and the titer (ml) with 0.1 mol / L sodium hydroxide solution is defined as B. The carboxyl group content is calculated by the following formula (1).

カルボキシル基含量(%)={(S−B)×0.45}/澱粉試料乾燥物重量(g)…(1)   Carboxyl group content (%) = {(SB) × 0.45} / starch sample dry matter weight (g) (1)

本発明に用いる加工タピオカ澱粉は、アセチル基含量が0.9質量%以上のアセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上であることが好ましく、アセチル基含量が1.9質量%以上の該加工タピオカ澱粉の1種又は2種以上であるであることがより好ましい。アセチル基含量の値がこれらの範囲より小さいと、生地の冷却硬化速度がやや遅くなり、製造時のハンドリング性が悪くなる傾向がある。尚、アセチル基含量は、前述したアセチル化などの加工調製時に用いられる無水酢酸あるいは酢酸ビニル等のアセチル化剤の添加量に依存して増減する。よってそれら加工タピオカ澱粉の調製のときに、アセチル化剤の濃度や処理時間等を適宜調整することで、そのアセチル基含量を調整することができる。   The processed tapioca starch used in the present invention is preferably one or more selected from acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch having an acetyl group content of 0.9% by mass or more. More preferably, the processed tapioca starch has an acetyl group content of 1.9% by mass or more. When the value of the acetyl group content is smaller than these ranges, the cooling and curing rate of the dough tends to be slightly slow, and the handling property during production tends to be poor. The acetyl group content increases or decreases depending on the amount of acetylating agent such as acetic anhydride or vinyl acetate used at the time of processing preparation such as acetylation. Therefore, when preparing these processed tapioca starches, the acetyl group content can be adjusted by appropriately adjusting the concentration of the acetylating agent, the treatment time, and the like.

本明細書においてアセチル基含量は、以下のようにして算出される値を意味する。   In the present specification, the acetyl group content means a value calculated as follows.

澱粉試料5.0gを正確に秤量し、水50mlに懸濁し、フェノールフタレイン試薬数滴を加え、液が微紅色を呈するまで0.1mol/l水酸化ナトリウム溶液を滴下後、0.45mol/l水酸化ナトリウム溶液25mlを正確に加え、温度が30℃以上にならないように注意しながら栓をして30分間激しく振り混ぜる。0.2mol/l塩酸で過量の水酸化ナトリウムを滴定する。終点は液の微紅色が消えるときとし、その滴定量(ml)をbとする。別途、澱粉試料を加えない空試験を行い、その滴定量(ml)をaとする。下記式(2)によりアセチル基含量を算出する。   A starch sample (5.0 g) was accurately weighed and suspended in 50 ml of water, a few drops of phenolphthalein reagent were added, and 0.1 mol / l sodium hydroxide solution was added dropwise until the solution turned a slight red color. Add exactly 25 ml of sodium hydroxide solution, cap and shake vigorously for 30 minutes, being careful not to let the temperature rise above 30 ° C. Titrate excess sodium hydroxide with 0.2 mol / l hydrochloric acid. The end point is when the faint red color of the liquid disappears, and the titer (ml) is b. Separately, a blank test without adding a starch sample is performed, and the titer (ml) is defined as a. The acetyl group content is calculated by the following formula (2).

アセチル基含量(%)=(a−b)×n×0.043×100/w…(2)
(上記式(2)中、a:空試験滴定量(ml)、b:試料滴定量(ml)、n:0.2mol/l塩酸の力価、w:澱粉試料乾燥物重量(g)を意味する。)
Acetyl group content (%) = (ab) × n × 0.043 × 100 / w (2)
(In the above formula (2), a: blank test titration (ml), b: sample titration (ml), n: titer of 0.2 mol / l hydrochloric acid, w: weight of dried starch sample (g) means.)

本発明の米菓の品質改良剤は、一般に米菓の原料となるジャポニカ米ではなく、インディカ米を主原料とするインディカ米米菓に適用する。インディカ米は長粒種、長粒米、アミロース米、タイ米等とも称され、澱粉中のアミロース含量が高いため、この澱粉が糊化した際の粘性が低いことが知られる。また、インディカ米にもアミロース含量の相違により粳種及び糯種が知られる。本発明は、それらインディカ米の種類に特に制限されることなく、適用される。更に、原料として利用する際のインディカ米の形態としては、米、米粉、酒粉等が知られる。本発明は、それらインディカ米の原料形態に特に制限されることなく、適用される。   The quality improving agent for rice crackers of the present invention is not applied to japonica rice, which is generally used as a raw material for rice crackers, but to indica rice rice crackers mainly made of indica rice. Indica rice is also called long grain seed, long grain rice, amylose rice, Thai rice, etc., and since the amylose content in starch is high, it is known that the viscosity when this starch is gelatinized is low. Indica rice is also known to be varieties and varieties due to the difference in amylose content. The present invention is not particularly limited to these types of indica rice and is applied. Furthermore, rice, rice flour, sake powder and the like are known as forms of indica rice when used as a raw material. The present invention is applied without particular limitation to the raw material form of these indica rice.

本発明の米菓の品質改良剤においては、上記に説明した加工タピオカ澱粉をそのまま、該品質改良剤としてもよく、あるいは適宜、リン酸塩、有機酸塩、炭酸塩、蛋白質(大豆蛋白、乳蛋白、小麦蛋白)、糖化品等の副原料を更に配合して、該品質改良剤としてもよい。また、加工タピオカ澱粉として、異なる種類の加工のものを2種以上併用してもよい。そして、この品質改良剤を、インディカ米を主原料とする米菓の原料配合中に添加して、上記加工タピオカ澱粉を米菓やその生地中に含有せしめることによって、食感や製造時のハンドリング性が改良され、乾燥、焼成時のひび割れの抑制された、インディカ米米菓を得ることができる。   In the rice cracker quality improving agent of the present invention, the processed tapioca starch described above may be used as it is, or as appropriate, phosphate, organic acid salt, carbonate, protein (soy protein, milk Protein, wheat protein), saccharified products and other auxiliary materials may be further blended to provide the quality improver. Moreover, you may use together 2 or more types of a different kind of processed tapioca starch as a processed tapioca starch. And this quality improver is added to the ingredients of rice crackers made mainly of indica rice, and the above processed tapioca starch is incorporated into the rice crackers and their dough, so that the texture and handling during production Indica rice crackers with improved properties and reduced cracking during drying and baking can be obtained.

一方、本発明の米菓は、インディカ米(米、米粉、酒粉等)を主原料とし、上記に説明した加工タピオカ澱粉を副原料とすることを特徴としている。典型的には、米菓中に固形分換算でインディカ米を55〜98質量%、上記加工タピオカ澱粉を2〜45質量%含有せしめることが好ましく、インディカ米を65〜90質量%、上記加工タピオカ澱粉を10〜35質量%含有せしめることがより好ましい。また、その他の原料として、小麦粉、そば粉、調味料、各種食品添加物等を適宜加えてもよい。   On the other hand, the rice confectionery of the present invention is characterized by using indica rice (rice, rice flour, sake powder, etc.) as a main raw material and the processed tapioca starch described above as a secondary raw material. Typically, it is preferable to contain 55 to 98% by mass of Indica rice and 2 to 45% by mass of the above-described processed tapioca starch in terms of solid content, and 65 to 90% by mass of Indica rice and the above-mentioned processed tapioca. It is more preferable to contain 10 to 35% by mass of starch. Moreover, you may add suitably wheat flour, buckwheat flour, a seasoning, various food additives, etc. as another raw material.

本発明の米菓は、当業者に周知の方法に準じて調製することができ、例えば、原料を水とともに混合し、蒸練して生地を作り、これを搗き及び/又は圧延した後に、冷却、乾燥、切断、成形、焼成、油ちょう等する工程を経て、更に醤油、塩、砂糖等の調味料で味付けすることにより調製することができる。尚、ここに記載の調製工程は一例であり、米菓の各種形態に応じて、工程を省略したり適宜他の工程を追加したりすることができることは、勿論である。   The rice cracker of the present invention can be prepared according to a method well known to those skilled in the art. For example, the raw material is mixed with water and steamed to make a dough, which is sown and / or rolled, and then cooled. It can be prepared by seasoning with seasonings such as soy sauce, salt, sugar, etc., through steps such as drying, cutting, molding, baking, and oiling. In addition, the preparation process described here is an example, and of course, according to the various forms of rice crackers, a process can be abbreviate | omitted or another process can be added suitably.

以下に実施例を挙げて本発明の詳細を説明するが、本発明は以下の実施例に限定されるものではない。   Hereinafter, the present invention will be described in detail with reference to examples. However, the present invention is not limited to the following examples.

(各種澱粉)
以下のようにして各種澱粉を調製し又は入手した。
(Various starches)
Various starches were prepared or obtained as follows.

<澱粉試料1:漂白タピオカ澱粉>
未加工のタピオカ澱粉300gに水を添加して40質量%のスラリーを調製し、30℃となるように調整した。この澱粉スラリーに3%水酸化ナトリウム水溶液を添加してpH10に調整した後、澱粉の質量に対して0.08%の有効塩素となる量の次亜塩素酸ナトリウム水溶液を添加してから1時間攪拌を維持した。更に、9%塩酸を用いてpH5に調整した後、澱粉の質量に対して0.05%の亜硫酸ナトリウムを添加してから30分間攪拌を維持して残留塩素を消去した。この澱粉スラリーを250メッシュの篩にかけて脱水し、更に2Lの水を加えて同様に脱水し、棚式乾燥機で乾燥することにより得られた漂白タピオカ澱粉を澱粉試料1とした。
<Starch Sample 1: Bleached Tapioca Starch>
Water was added to 300 g of raw tapioca starch to prepare a 40% by mass slurry, which was adjusted to 30 ° C. After adding 3% sodium hydroxide aqueous solution to this starch slurry and adjusting to pH 10, 1 hour after adding sodium hypochlorite aqueous solution in an amount of 0.08% effective chlorine based on the mass of starch. Stirring was maintained. Furthermore, after adjusting to pH 5 using 9% hydrochloric acid, 0.05% sodium sulfite was added to the mass of the starch, and then stirring was maintained for 30 minutes to eliminate residual chlorine. The starch slurry was dehydrated through a 250-mesh sieve, and further 2 L of water was added for dehydration in the same manner. The bleached tapioca starch obtained by drying with a shelf dryer was used as starch sample 1.

<澱粉試料2:酸化タピオカ澱粉>
酸化タピオカ澱粉である Asia Modified Starch Co., Ltd. 製の「TOFF#07(商品名)」を澱粉試料2とした。
<Starch sample 2: oxidized tapioca starch>
Starch sample 2 was “TOFF # 07 (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is oxidized tapioca starch.

<澱粉試料3:酸化タピオカ澱粉>
酸化タピオカ澱粉である Asia Modified Starch Co., Ltd. 製の「TO#5(商品名)」を澱粉試料3とした。
<Starch sample 3: oxidized tapioca starch>
Starch sample 3 was “TO # 5 (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is oxidized tapioca starch.

<澱粉試料4:酸化タピオカ澱粉>
酸化タピオカ澱粉である Asia Modified Starch Co., Ltd. 製の「TO#3(商品名)」を澱粉試料4とした。
<Starch sample 4: oxidized tapioca starch>
Starch sample 4 was “TO # 3 (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is oxidized tapioca starch.

<澱粉試料5:アセチル化タピオカ澱粉>
アセチル化タピオカ澱粉である日本食品化工株式会社製の「MT−01(商品名)」を澱粉試料5とした。
<Starch Sample 5: Acetylated Tapioca Starch>
Starch sample 5 was “MT-01 (trade name)” manufactured by Nippon Shokuhin Kako Co., Ltd., which is an acetylated tapioca starch.

<澱粉試料6:アセチル化タピオカ澱粉>
未加工のタピオカ澱粉300gに水を添加して40質量%のスラリーを調製し、30℃となるように調整した。この澱粉スラリーに10%の炭酸ナトリウム水溶液を添加してpH10に調整した後、澱粉の重量に対して2.0質量%の酢酸ビニルを添加してから30分間攪拌を維持した。更に、9%塩酸を用いてpH5に調整することでアセチル化反応を終え、250メッシュの篩にかけて脱水し、更に2Lの水を加えて同様に脱水した。この脱水物を棚式乾燥機で乾燥することにより得られたアセチル化タピオカ澱粉を澱粉試料6とした。
<Starch Sample 6: Acetylated Tapioca Starch>
Water was added to 300 g of raw tapioca starch to prepare a 40% by mass slurry, which was adjusted to 30 ° C. A 10% aqueous sodium carbonate solution was added to the starch slurry to adjust the pH to 10, and then 2.0 mass% vinyl acetate was added to the weight of the starch, and stirring was maintained for 30 minutes. Further, the acetylation reaction was completed by adjusting the pH to 5 using 9% hydrochloric acid, and the mixture was dehydrated through a 250 mesh sieve, and further dehydrated by adding 2 L of water. Acetyl tapioca starch obtained by drying this dehydrated product with a shelf dryer was used as a starch sample 6.

<澱粉試料7:アセチル化タピオカ澱粉>
アセチル化タピオカ澱粉である日本食品化工株式会社製の「MT−01B(商品名)」を澱粉試料7とした。
<Starch Sample 7: Acetylated Tapioca Starch>
Starch sample 7 was “MT-01B (trade name)” manufactured by Nippon Shokuhin Kako Co., Ltd., which is an acetylated tapioca starch.

<澱粉試料8:アセチル化漂白タピオカ澱粉>
アセチル化漂白タピオカ澱粉である Asia Modified Starch Co., Ltd. 製の「TEMPUFF#08(商品名)」を澱粉試料8とした。
<Starch Sample 8: Acetylated Bleached Tapioca Starch>
Starch sample 8 was “TEMPUFFF # 08 (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is an acetylated bleached tapioca starch.

<澱粉試料9:アセチル化漂白タピオカ澱粉と漂白タピオカ澱粉の混合物>
澱粉試料1及び8を等質量比で混合したものを澱粉試料9とした。
<Starch Sample 9: Mixture of Acetylated Bleached Tapioca Starch and Bleached Tapioca Starch>
A starch sample 9 was prepared by mixing starch samples 1 and 8 at an equal mass ratio.

<澱粉試料10:アセチル化酸化タピオカ澱粉>
アセチル化酸化タピオカ澱粉である日本食品化工株式会社製の「MS#6100(商品名)」を澱粉試料10とした。
<Starch sample 10: acetylated oxidized tapioca starch>
Starch sample 10 was “MS # 6100 (trade name)” manufactured by Nippon Shokuhin Kako Co., Ltd., which is acetylated oxidized tapioca starch.

<澱粉試料11:リン酸架橋タピオカ澱粉>
リン酸架橋タピオカ澱粉である Asia Modified Starch Co., Ltd. 製の「NEOVIS T−205(商品名)」を澱粉試料11とした。
<Starch Sample 11: Phosphoric Acid Crosslinked Tapioca Starch>
The starch sample 11 was “NEOVIS T-205 (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is a phosphate-crosslinked tapioca starch.

<澱粉試料12:未加工タピオカ澱粉>
未加工のタピオカである Asia Modified Starch Co., Ltd. 製の「TAPIOCA STARCH(商品名)」を澱粉試料12とした。
<Starch Sample 12: Raw Tapioca Starch>
The starch sample 12 was “TAPIOCA STARCH (trade name)” manufactured by Asia Modified Starch Co., Ltd., which is an unprocessed tapioca.

<澱粉試料13:ワキシーコーンスターチ>
未加工のワキシーコーンスターチである日本食品化工株式会社製の「日食ワキシースターチY(商品名)」を澱粉試料13とした。
<Starch Sample 13: Waxy Corn Starch>
The starch sample 13 was “eclipse waxy starch Y (trade name)” manufactured by Nippon Shokuhin Kako Co., Ltd., which is an unprocessed waxy corn starch.

各種澱粉の特性を表1にまとめて示す。   Table 1 summarizes the characteristics of various starches.

(米菓用生地の調製)
ニーダー(株式会社森山製作所製 S0.5−0.GH−E)をパドル回転数30rpm、ジャケット温度50℃の設定で運転し、ミキシングボックス内に水道水230gを投入した後に、表1記載の各種澱粉50gともち種インディカ米粉200gを投入して3分間混練した。その後、ジャケット温度を130℃に設定してミキシングボックスの蓋を閉めて20分間混練することで、米菓用の生地を調製した。また、各種澱粉を配合せずに、もち種インディカ米粉250gを使用して同様に生地を調製した。
(Preparation of dough for rice crackers)
After operating a kneader (S0.5-0.GH-E manufactured by Moriyama Seisakusho Co., Ltd.) at a paddle rotation speed of 30 rpm and a jacket temperature of 50 ° C. 50 g of starch and 200 g of glutinous indica rice flour were added and kneaded for 3 minutes. Thereafter, the jacket temperature was set to 130 ° C., the lid of the mixing box was closed, and kneading was carried out for 20 minutes to prepare a dough for rice crackers. Moreover, dough was similarly prepared using 250 g of glutinous seed indica rice flour without blending various starches.

(米菓の調製)
上記操作により得られた生地を筒状容器(内径20mm、内高90mm)に封入して、5℃の条件下で24時間冷却硬化を行った。その後、筒状容器から硬化した生地を取り出し、厚さ2mmに切り出し、揚げ網上で生地水分が25%となるまで強制送風乾燥器(ADVANTEC社製 DRK633DB)を用いて45℃で乾燥した。尚、乾燥中は生地の反りを防ぐために、5分間ごとに生地を反転させた。生地水分が25%まで低下した乾燥生地を、電気マッフル炉(ADVANTEC社製 KM−420)を用いて240℃、5分間の条件下で焼成して米菓試料を得た。評価に必要な量の米菓試料を得るために同様の操作を繰り返した。各種米菓の配合を表2にまとめて示す。
(Preparation of rice crackers)
The dough obtained by the above operation was sealed in a cylindrical container (inner diameter 20 mm, inner height 90 mm), and cooled and cured under the condition of 5 ° C. for 24 hours. Thereafter, the cured dough was taken out from the cylindrical container, cut into a thickness of 2 mm, and dried at 45 ° C. using a forced air dryer (DRK633DB manufactured by ADVANTEC) until the moisture content of the dough became 25% on the frying net. During drying, the dough was inverted every 5 minutes in order to prevent warping of the dough. The dried dough with the dough moisture decreased to 25% was baked under the conditions of 240 ° C. and 5 minutes using an electric muffle furnace (KM-420 manufactured by ADVANTEC) to obtain a rice cracker sample. The same operation was repeated to obtain an amount of rice cracker sample necessary for the evaluation. Table 2 shows the composition of various rice crackers.

[試験例1](米菓の食感)
米菓試料1〜14について、これらを食したときの食感を、「◎:米菓として良好な軽くてクリスピー感のある食感」、「○:米菓として良好な軽い食感」、「△:やや軽い食感」、「×:ボリボリとした硬い食感」の基準にて、8名のパネラーの平均評価で評価した。その結果を表3にまとめて示す。尚、表中にはパネラーの代表的な評価コメントを付記した。
[Test Example 1] (Rice texture of rice crackers)
About rice cracker samples 1-14, the texture when eating these is "◎: Light and crispy texture that is good as rice cake", "○: Light texture that is good as rice cake", " The evaluation was based on an average evaluation of eight panelists based on the criteria of “△: Slightly light texture” and “×: Hard texture that was crunchy”. The results are summarized in Table 3. In addition, representative evaluation comments of panelists are added in the table.

表3に示すように、米菓試料11〜14はボリボリとした硬い食感を示しただけでなく、「歯に付く」、「詰まる」等の食感もあった。これに対して、米菓試料1〜10は総じて軽い食感を示した。特に米菓試料1〜4、8〜10は軽くてクリスピー感のある食感を示し、米菓として良好であった。以上より、インディカ米米菓の品質改良剤として、漂白タピオカ澱粉、酸化タピオカ澱粉、アセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉が適しており、その中でも特に加熱溶解度が20%以上且つ加熱膨潤度が35倍以上のものが優れることが示された。   As shown in Table 3, the rice cracker samples 11 to 14 not only showed a crunchy and hard texture, but also had a texture such as “stick to teeth” and “clogged”. On the other hand, rice cracker samples 1 to 10 generally showed a light texture. Especially rice cracker samples 1-4 and 8-10 showed light and crispy texture and were good as rice crackers. From the above, bleached tapioca starch, oxidized tapioca starch, acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch are suitable as quality improvers for Indica rice rice crackers, and in particular, the heating solubility is 20%. As described above, it was shown that the heat swelling degree is 35 times or more.

[試験例2](米菓のひび割れ)
米菓試料1〜14について、各米菓試料を20点無作為に抽出して、これらのひび割れの割合を、「◎:ひび割れた米菓の割合が0〜10%」、「○:ひび割れた米菓の割合が11〜40%」、「△:ひび割れた米菓の割合が41〜60%」、「×:ひび割れた米菓の割合が61〜100%」の基準にて、目視により評価した。その結果を表4にまとめて示す。
[Test Example 2] (Rice cracks)
About rice cracker samples 1-14, 20 points of each rice cracker sample were extracted at random, and the ratio of these cracks was “◎: the ratio of cracked rice crackers was 0-10%”, “O: cracked. Visual evaluation based on the criteria of “rice cracker ratio of 11-40%”, “△: cracked rice cracker ratio of 41-60%”, “x: cracked rice cracker ratio of 61-100%” did. The results are summarized in Table 4.

表4に示すように、米菓試料14は得られた米菓の85%にひび割れが生じていたのに対して、米菓試料1〜13は米菓試料14と比較してひび割れの発生率が大きく低下した。更に、米菓試料1、4〜10、12は大幅な改善が見られ、特に米菓試料8は5%の発生率にとどまった。   As shown in Table 4, rice cracker sample 14 was cracked in 85% of the obtained rice cracker, whereas rice cracker samples 1 to 13 were cracked compared to rice cracker sample 14. Decreased significantly. Furthermore, the rice cracker samples 1, 4 to 10 and 12 showed a significant improvement. In particular, the rice cracker sample 8 remained at an incidence of 5%.

[試験例3](製造時のハンドリング)
一般に米菓特有の製造時のハンドリング条件としては、加工適性及び機械耐性を高めるために蒸練後の生地は柔らかくコシがある物性が求められ、且つ製造時間を短縮するために冷却による硬化速度が速い生地物性が求められる。そこで、米菓試料1〜14について、以下の方法にて製造時のハンドリングを評価した。
[Test Example 3] (Handling during manufacture)
In general, the handling conditions during the manufacture of rice crackers are as follows: the dough after steaming is required to have a soft and firm physical property in order to improve processability and mechanical resistance, and the curing rate by cooling is required to shorten the manufacturing time. Fast fabric properties are required. Then, the handling at the time of manufacture was evaluated about the rice cracker samples 1-14 with the following method.

(生地調製1時間後の最大荷重)
調製した直後の生地をガラスセル(内径30mm、内高12mm)に擦り切りで充填し、乾燥防止のためにパラフィルムで生地上部を覆って28℃で1時間放置し、硬度分析用サンプル3点を得た。その後、生地上部のパラフィルムを除去し、クリープメータ(株式会社山電製、RE2-33005B)に供して生地の硬度を分析した。測定には20Nのロードセル及びφ12mm円柱型プランジャーを使用し、予備荷重(0.03N与えた後にプランジャーを戻し、0.01Nまで減衰させた)を生地に与えた後に、1.0mm/secの速度で歪率70%まで荷重を与えたときの最大荷重の平均値を記録した。
(Maximum load 1 hour after dough preparation)
The dough immediately after preparation is filled into a glass cell (inner diameter 30 mm, inner height 12 mm), covered with parafilm to prevent drying and left at 28 ° C. for 1 hour, and three samples for hardness analysis are obtained. Obtained. Thereafter, the parafilm at the top of the dough was removed, and the hardness of the dough was analyzed using a creep meter (manufactured by Yamaden Co., Ltd., RE2-30005B). A 20 N load cell and a φ12 mm cylindrical plunger were used for the measurement, and a preload (0.03 N was applied, the plunger was returned and attenuated to 0.01 N) was applied to the fabric, and then 1.0 mm / sec. The average value of the maximum load when a load was applied up to a strain rate of 70% at a speed of was recorded.

(冷却硬化後の歪率20%時の荷重)
5℃の条件下で24時間冷却硬化した生地を筒状容器より取り出し、厚さ10mmにカッターで切り出して室温に戻し、硬度分析用サンプル3点を得た。その後、クリープメータ(株式会社山電製、RE2-33005B)に供して生地の硬度を分析した。測定には20Nのロードセル及び楔形プランジャー(30mm)を使用し、予備荷重(0.03N与えた後にプランジャーを戻し、0.01Nまで減衰させた)を生地に与えた後に1.0mm/secの速度で荷重を与え、歪率20%のときの荷重の平均値を記録した。
(Load at 20% distortion after cooling)
The dough cooled and hardened for 24 hours under the condition of 5 ° C. was taken out from the cylindrical container, cut into a thickness of 10 mm with a cutter and returned to room temperature, and three samples for hardness analysis were obtained. Then, it used for the creep meter (the Yamaden Co., Ltd. product, RE2-30005B), and analyzed the hardness of the dough. A 20 N load cell and a wedge-shaped plunger (30 mm 2 ) were used for the measurement, and a preload (0.03 N was applied and the plunger was returned and attenuated to 0.01 N) was applied to the dough to 1.0 mm / A load was applied at a speed of sec, and the average value of the load when the strain rate was 20% was recorded.

上記の硬度の測定で、生地調製1時間後の最大荷重が8.0Nを上回る場合、生地が硬く切れ易い物性であったため、加工適性及び機械耐性が低いと予想された。また、冷却硬化後の生地の歪率20%のときの荷重が12.0以下の場合、生地の柔らかさが際立ち、硬化時間が遅いことが予想された。従って、製造時のハンドリングの評価は、「○:調製一時間後の生地の最大荷重が8.0N以下且つ冷却硬化後の生地の歪率20%時の荷重が12.0以上」、「△:一方の条件が範囲外」、「×:米菓用生地として明らかに適さない物性」の基準で行った。その結果を表5にまとめて示す。尚、表中には製造時のハンドリングについての評価コメントを付記した。   In the measurement of the above hardness, when the maximum load after 1 hour of preparation of the dough exceeds 8.0 N, the dough is hard and easily cut, so that it is expected that the workability and the mechanical resistance are low. Moreover, when the load at the time of the distortion rate of 20% of the dough after cooling and hardening was 12.0 or less, the softness of the dough was conspicuous, and the hardening time was expected to be slow. Therefore, the evaluation of handling at the time of manufacture is as follows: “◯: The maximum load of the fabric after one hour of preparation is 8.0 N or less and the load when the strain rate of the fabric after cooling is 20% is 12.0 or more”, “△ : One condition is out of range ", and" X: Physical properties that are clearly unsuitable as a rice cracker dough ". The results are summarized in Table 5. In the table, evaluation comments regarding handling at the time of manufacture were added.

表5に示すように、米菓試料14の生地は冷却硬化後の生地硬度が著しく低く、米菓用生地として望ましい値を示さなかった。米菓試料1、4〜9、11〜13の生地は調製1時間後の生地物性が米菓用生地として適しており、米菓試料2〜4、7〜10、13の生地は冷却硬化後の生地物性が米菓用生地として適していた。更に、米菓試料4、7〜9、13の生地は調製1時間後及び冷却硬化後の双方の生地物性が米菓用生地として適しており、製造時のハンドリングが特に良好に行えることが明らかとなった。   As shown in Table 5, the dough of the rice cracker sample 14 had a remarkably low dough hardness after cooling and curing, and did not show a desirable value as a dough for rice crackers. The dough of rice confectionery samples 1, 4-9, 11-13 is suitable as the dough for rice confectionery 1 hour after preparation, and the dough of rice confectionery samples 2-4, 7-10, 13 after cooling and curing The dough physical properties were suitable as a rice cracker dough. Furthermore, the dough of rice confectionery samples 4, 7-9, and 13 is suitable as a dough for rice confectionery both after 1 hour of preparation and after cooling and curing, and it is clear that handling during manufacture can be performed particularly well. It became.

[試験例4](米菓の膨化性)
米菓試料1〜14について、冷却硬化後に厚さ2mmに切り出した生地が焼成後に膨化した高さを計測し、膨化度(倍)を算出した。また、「◎:米菓として適度に丸く膨化」、「○:米菓として適度に膨化」、「△:やや膨化」、「×:膨化しすぎ又は膨化しない」の基準で膨化性の評価を行なった。行い、各米菓試料を20点無作為に抽出して、膨化性を調べた。膨化度及び膨化性の評価は、各試料20点の平均値又は平均評価で行なった。その結果を表6にまとめて示す。尚、表中には膨化についての評価コメントを付記した
[Test Example 4] (Puffiness of rice crackers)
About rice cracker samples 1-14, the height which the dough cut out to thickness 2mm after cooling hardening expanded after baking was measured, and the degree of expansion (times) was computed. In addition, the evaluation of puffiness was made according to the criteria of “◎: moderately rounded and expanded as rice cracker”, “○: moderately expanded as rice cracker”, “△: slightly swollen”, and “×: not excessively expanded or expanded”. I did it. Each rice cracker sample was randomly extracted to examine the swelling property. The evaluation of the degree of expansion and the expandability was performed by the average value or average evaluation of 20 samples. The results are summarized in Table 6. In the table, an evaluation comment on expansion was added.

表6に示すように、米菓試料14では膨化しすぎのために生地の層が薄くなり、ひび割れが見られたのに対して、米菓試料1〜4、6〜9、13は適度に膨化した。更に、米菓試料7〜9は適度に丸く膨化し、米菓として特に良好な膨化性を示した。   As shown in Table 6, while the rice cracker sample 14 was too expanded, the dough layer was thinned and cracks were observed, whereas the rice cracker samples 1-4, 6-9, and 13 were moderately It expanded. Furthermore, the rice cracker samples 7 to 9 swelled moderately roundly and showed particularly good swelling properties as rice crackers.

Claims (6)

漂白タピオカ澱粉、酸化タピオカ澱粉、アセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上の加工タピオカ澱粉を含有することを特徴とするインディカ米米菓の品質改良剤。   Indica rice rice confectionery characterized by containing one or more kinds of processed tapioca starch selected from bleached tapioca starch, oxidized tapioca starch, acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch Quality improver. 前記加工タピオカ澱粉は、加熱溶解度が20%以上であり且つ加熱膨潤度が35倍以上である請求項1に記載のインディカ米米菓の品質改良剤。   The quality improving agent for indica rice rice crackers according to claim 1, wherein the processed tapioca starch has a heat solubility of 20% or more and a heat swelling degree of 35 times or more. 前記加工タピオカ澱粉は、カルボキシル基含量が0.4質量%以下である請求項1又は2に記載のインディカ米米菓の品質改良剤。   The quality improving agent for indica rice rice crackers according to claim 1 or 2, wherein the processed tapioca starch has a carboxyl group content of 0.4 mass% or less. 前記加工タピオカ澱粉は、アセチル基含量が0.9質量%以上のアセチル化タピオカ澱粉、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種又は2種以上である請求項1〜3のいずれか1項に記載のインディカ米米菓の品質改良剤。   The processed tapioca starch is one or more selected from acetylated tapioca starch, acetylated bleached tapioca starch and acetylated oxidized tapioca starch having an acetyl group content of 0.9 mass% or more. The quality improving agent for indica rice crackers according to any one of the above items. 前記加工タピオカ澱粉は、アセチル化漂白タピオカ澱粉及びアセチル化酸化タピオカ澱粉から選ばれる1種以上である請求項1〜4のいずれか1項に記載のインディカ米米菓の品質改良剤。   The quality improving agent for Indica rice confectionery according to any one of claims 1 to 4, wherein the processed tapioca starch is at least one selected from acetylated bleached tapioca starch and acetylated oxidized tapioca starch. インディカ米を主原料とし、請求項1〜5のいずれか1項に記載のインディカ米米菓の品質改良剤を含有することを特徴とする米菓。   A rice cracker comprising indica rice as a main raw material and containing the quality improver for indica rice cracker according to any one of claims 1 to 5.
JP2012043742A 2012-02-29 2012-02-29 Rice cracker quality improver and rice cracker Active JP5936880B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012043742A JP5936880B2 (en) 2012-02-29 2012-02-29 Rice cracker quality improver and rice cracker

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012043742A JP5936880B2 (en) 2012-02-29 2012-02-29 Rice cracker quality improver and rice cracker

Publications (2)

Publication Number Publication Date
JP2013179842A true JP2013179842A (en) 2013-09-12
JP5936880B2 JP5936880B2 (en) 2016-06-22

Family

ID=49270957

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2012043742A Active JP5936880B2 (en) 2012-02-29 2012-02-29 Rice cracker quality improver and rice cracker

Country Status (1)

Country Link
JP (1) JP5936880B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160076470A (en) 2014-12-22 2016-06-30 가부시기가이샤하야시바라 Hardening accelerator for gelatinized starch dough
KR20180034073A (en) * 2016-09-27 2018-04-04 한국식품연구원 Manufacturing method of rice pastry for easily digest and rice pastry prepared therefrom

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06276949A (en) * 1993-03-26 1994-10-04 Matsutani Chem Ind Ltd Preparation of rice cracker
JPH07163297A (en) * 1993-12-14 1995-06-27 Kameda Seika Kk Production of rice cracker
JPH0928331A (en) * 1995-05-17 1997-02-04 Q P Corp Processed food using rice as raw material and its production
JP2001069915A (en) * 1999-08-31 2001-03-21 Honen Corp Emulsion composition for rice cracker
JP2002204660A (en) * 2001-01-10 2002-07-23 Yamazaki Baking Co Ltd Fried rice cracker and method for producing the same
JP2002354985A (en) * 2001-05-30 2002-12-10 Honen Corp Method for producing rice confectionery
JP2005027644A (en) * 2003-07-10 2005-02-03 Glyco Eiyou Shokuhin Kk Method for producing rice cracker
JP2007151517A (en) * 2005-12-08 2007-06-21 Matsutani Chem Ind Ltd Method for producing rice cracker
WO2007117012A1 (en) * 2006-04-10 2007-10-18 Bourbon Corporation Rice cake and process for producing the same
JP2008220216A (en) * 2007-03-09 2008-09-25 Iwatsuka Confectionery Co Ltd Method for producing rice cracker bound with rice grain
JP2009232701A (en) * 2008-03-26 2009-10-15 Ezaki Glico Co Ltd Method for easily producing rice confectionery
US20090263553A1 (en) * 2008-04-18 2009-10-22 Licker Jonathan L Method for developing a dairy protein cake

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06276949A (en) * 1993-03-26 1994-10-04 Matsutani Chem Ind Ltd Preparation of rice cracker
JPH07163297A (en) * 1993-12-14 1995-06-27 Kameda Seika Kk Production of rice cracker
JPH0928331A (en) * 1995-05-17 1997-02-04 Q P Corp Processed food using rice as raw material and its production
JP2001069915A (en) * 1999-08-31 2001-03-21 Honen Corp Emulsion composition for rice cracker
JP2002204660A (en) * 2001-01-10 2002-07-23 Yamazaki Baking Co Ltd Fried rice cracker and method for producing the same
JP2002354985A (en) * 2001-05-30 2002-12-10 Honen Corp Method for producing rice confectionery
JP2005027644A (en) * 2003-07-10 2005-02-03 Glyco Eiyou Shokuhin Kk Method for producing rice cracker
JP2007151517A (en) * 2005-12-08 2007-06-21 Matsutani Chem Ind Ltd Method for producing rice cracker
WO2007117012A1 (en) * 2006-04-10 2007-10-18 Bourbon Corporation Rice cake and process for producing the same
JP2008220216A (en) * 2007-03-09 2008-09-25 Iwatsuka Confectionery Co Ltd Method for producing rice cracker bound with rice grain
JP2009232701A (en) * 2008-03-26 2009-10-15 Ezaki Glico Co Ltd Method for easily producing rice confectionery
US20090263553A1 (en) * 2008-04-18 2009-10-22 Licker Jonathan L Method for developing a dairy protein cake

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160076470A (en) 2014-12-22 2016-06-30 가부시기가이샤하야시바라 Hardening accelerator for gelatinized starch dough
KR20180034073A (en) * 2016-09-27 2018-04-04 한국식품연구원 Manufacturing method of rice pastry for easily digest and rice pastry prepared therefrom
KR101886339B1 (en) * 2016-09-27 2018-08-07 한국식품연구원 Manufacturing method of rice pastry for easily digest and rice pastry prepared therefrom

Also Published As

Publication number Publication date
JP5936880B2 (en) 2016-06-22

Similar Documents

Publication Publication Date Title
JP6147688B2 (en) Bakery product and manufacturing method thereof
JP4682117B2 (en) Flour substitute for bakery food and bakery food
JPS58107147A (en) Composition containing unheated rice flour
JP5431607B1 (en) Noodle manufacturing method and noodle
JP6362573B2 (en) Technology to increase grain flour dough strength with bionanofiber
Vernon‐Carter et al. Canola oil/candelilla wax oleogel improves texture, retards staling and reduces in vitro starch digestibility of maize tortillas
JP7101242B2 (en) Vermicelli with low stabilization pea starch
MXPA04006751A (en) Modified starches for use in gluten-free baked products.
JP5936880B2 (en) Rice cracker quality improver and rice cracker
JP5855427B2 (en) Confectionery mix
JP6803697B2 (en) A method for producing dried noodles and a composition for making noodles used therein.
JP2013531507A (en) Hydroxypropyl-substituted starch as a source of soluble fiber
JP4957379B2 (en) Processed starch production method, food and feed
JP2020178645A (en) Cake composition, cake using the cake composition, and method of improving keeping quality of cake
JP5127826B2 (en) Starch-containing composition and method for producing the same
JP6998297B2 (en) Food composition containing starch
JP5770545B2 (en) Fishery paste product and method for producing fish paste product
JP2015136311A (en) Texture improver for laminar swelled food and use thereof
JP3968714B2 (en) Polysaccharide-coated starch and method for producing the same
CN114401644A (en) Highly acetylated pea starch for instant noodles
JP2017214602A (en) Production method of acetylated adipic acid crosslinked starch and noodle texture modifier containing the starch, and production method of noodles using the starch and the texture modifier
KR101303864B1 (en) Starch Octenyl Succinate for noodles, manufacturing method of the same, and noodles composition comprising the same
JPS5955156A (en) Preparation of non-fried instant noodle
JP7241560B2 (en) Flour composition for noodles and composition for noodles
JP7382676B1 (en) Agent for preventing punctures during baking or elongation after baking in starch dough derived from grains or potatoes

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20141127

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20150924

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20151006

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20160510

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20160511

R150 Certificate of patent or registration of utility model

Ref document number: 5936880

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250