JP2013174571A - Method for reducing radiation of radioactive material contaminated water - Google Patents

Method for reducing radiation of radioactive material contaminated water Download PDF

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JP2013174571A
JP2013174571A JP2012053727A JP2012053727A JP2013174571A JP 2013174571 A JP2013174571 A JP 2013174571A JP 2012053727 A JP2012053727 A JP 2012053727A JP 2012053727 A JP2012053727 A JP 2012053727A JP 2013174571 A JP2013174571 A JP 2013174571A
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contaminated
water
contaminated water
radiation
particles
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Yoshinori Doi
義則 土居
Norio Abe
宣男 阿部
Tetsuo Nomura
哲雄 野村
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EZOE TOSHIKAZU
HIGUCHI TOKUJI
KOMANO IZUMI
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EZOE TOSHIKAZU
HIGUCHI TOKUJI
KOMANO IZUMI
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Abstract

PROBLEM TO BE SOLVED: To efficiently reduce radiation of water contaminated by radioactive material, and to reduce radiation of fittings used to reduce radiation of contaminated water without discharging radioactive waste in the process of reduction.SOLUTION: A method comprises a first filtering step for removing particles contaminated by radioactive material contained in contaminated water, a second filtering step for removing fine particles contaminated by radioactive material contained in the contaminated water, a third step for reducing radiation of the water by bringing the contaminated water with the particles contaminated by the radioactive material removed therefrom into contact with nano pure silver particle carrier, and a fourth step for reducing radiation of filtered objects from the first and second filtering steps and the fittings used in the respective first, second and third steps. The contaminated water with solid matter removed and the removed solid matter are separated from each other and respectively brought into contact with nano pure silver particles.

Description

本発明は、放射性物質に汚染された水の放射線を低減化する方法に関する。詳しくは、放射性物質に汚染し除染により生じる屋根や建物を洗浄した水あるいは道路洗浄後の水や放射性物質に汚染された池等の水をナノ純銀粒子担持体に接触させ汚染水から放出される放射線を低減する方法に関するものである。      The present invention relates to a method for reducing the radiation of water contaminated with radioactive material. Specifically, water that has been washed by roofs and buildings that are contaminated with radioactive materials and decontaminated, or water after road cleaning or water that has been contaminated with radioactive materials is brought into contact with the nanopure silver particle carrier and released from the contaminated water. The present invention relates to a method for reducing radiation.

東日本大震災により福島第一原子力発電所は、津波の被害を受けたことにより原子炉を冷却することができず水素爆発を起こし、大量の放射性物質が広域に拡散し住民が避難しなければならないという深刻な状況となっている。政府は避難住民が帰郷して安心に生活できるために建物等を高圧洗浄水で洗浄し除染するとしているが、この方法は建物等に堆積した放射性物質を洗い流しているだけで、放射性物質が含まれる洗浄水の処理については明確になっていない。洗浄水をそのまま流すと地中に染み込み地下水を汚染し、さらに川を経て海まで汚染することになり、食物連鎖により高濃度の放射性物質に汚染された生物により最終的に人間が被害を受けるという重大な懸念がある。また、汚染水は凝集剤により汚染水に含まれる放射性物質に汚染される粒子を凝集させフィルターでろ過を行う方法を採用しているが、この方法では放射線を低減化することはできず放射性廃棄物が増えるだけで、その処理にも莫大な処分地と莫大な費用がかかる。しかも水からの放射線を低減化する方法は確立されていない。      The Fukushima Daiichi Nuclear Power Station was unable to cool the reactor due to the damage of the tsunami due to the Great East Japan Earthquake, causing a hydrogen explosion, a large amount of radioactive material diffused over a wide area, and residents had to evacuate It is a serious situation. The government says that the evacuated residents can return home and live safely, and the buildings, etc. are washed with high-pressure washing water to decontaminate, but this method only removes radioactive materials deposited on the buildings, etc. The treatment of the contained wash water is not clear. If washing water is allowed to flow as it is, it will soak into the ground and contaminate the groundwater, and further to the sea through the river, and eventually the human being will be damaged by organisms contaminated with high concentrations of radioactive substances by the food chain. There are serious concerns. Contaminated water uses a method of agglomerating particles contaminated by radioactive substances contained in the contaminated water with a flocculant and filtering with a filter, but this method cannot reduce the radiation and radioactive waste. Just increasing the amount of material, it takes a huge disposal site and a huge expense. Moreover, a method for reducing the radiation from water has not been established.

ナノ純銀粒子は3〜10ナノメートル程度からそれ以下の粒子径にした銀のことであり、ナノ純銀粒子には、銀イオンが飛び出しても瞬時に元の金属の状態に戻る特異性があり、その際に発生する電気的エネルギーの電位差は1600mV以上で、10−6sec以上の極端に短い周期で大きな電気的振動が発生する。この電気的振動により放射線のエネルギーをエネルギー変換し無害なものとすると考えられる。Nanopure silver particles are silver having a particle size of about 3 to 10 nanometers or less, and nanopure silver particles have a specificity that instantly returns to the original metal state even when silver ions jump out, The potential difference of the electric energy generated at that time is 1600 mV or more, and a large electric vibration is generated with an extremely short period of 10 −6 sec or more. It is thought that this electrical vibration converts the energy of the radiation into harmless.

本発明の技術的課題は、放射性物質に汚染された水の放射線を効率よく低減化し、低減化の過程で放射性廃棄物の排出することなく、汚染水の放射線低減化に使用する器具類の放射線を低減化する放射性物質汚染水の放射線低減化方法を提供することにある。      The technical problem of the present invention is to efficiently reduce the radiation of water contaminated with radioactive materials, and to reduce the radiation of instruments used for radiation reduction of contaminated water without discharging radioactive waste in the process of reduction. An object of the present invention is to provide a method for reducing the radiation of radioactive material-contaminated water.

前記課題を解決するため、発明者らは、ナノ純銀粒子を用いた水浄化の研究を続けている。福島原発の爆発事故以降、ナノ純銀粒子あるいはナノ純銀粒子を御影石や骨炭に担持させたナノ純銀粒子担持体を用いて放射能汚染水の浄化試験・計測を行い、初期値20000Bq/kgの汚染水がND(不検出)となることを確認している。また、汚染土壌に対してもナノ純銀粒子を含む溶液を散布することで放射線の数値が低下することも確認している。      In order to solve the above problems, the inventors have continued research on water purification using nanopure silver particles. After the explosion accident at the Fukushima nuclear power plant, we conducted a purification test and measurement of radioactive contaminated water using nanopure silver particles or nanopure silver particles carrying nanopure silver particles on granite or bone charcoal, and the initial value of 20000 Bq / kg of contaminated water Is confirmed to be ND (not detected). Moreover, it has also been confirmed that the numerical value of radiation decreases by spraying a solution containing nanopure silver particles to contaminated soil.

前記の知見に基づき、本発明者らは、安全に効率よく放射性物質汚染水から放出される放射線を低減化する方法に想到した。その要旨とするところは以下の通りである。      Based on the above findings, the present inventors have come up with a method for reducing the radiation emitted from radioactive material contaminated water safely and efficiently. The gist is as follows.

すなわち、本発明の放射性物質汚染水の放射線低減化方法は、汚染水に含まれる放射性物質に汚染された粒子を除去する第1のろ過工程と、汚染水に含まれる放射性物質に汚染された微細な粒子を除去する第2のろ過工程と、放射性物質に汚染されたこれらの粒子が除去された汚染水をナノ純銀粒子担持体に接触させて放射線低減化する第3工程と、第1及び第2のろ過工程からのろ過物と第1、第2、第3の各工程で使用した器具類をナノ純銀粒子液に接触させて放射線低減化する第4工程からなることを特徴とする。      That is, the radiation reducing method for radioactive material contaminated water of the present invention includes a first filtration step for removing particles contaminated with radioactive substances contained in the contaminated water, and a fine contamination contaminated with radioactive substances contained in the contaminated water. A second filtration step for removing particles, a third step for reducing the radiation by bringing the contaminated water from which these particles contaminated with radioactive substances have been removed into contact with the nanopure silver particle support, It consists of the 4th process of reducing the radiation by making the filtrate used from the filtration process of 2 and the instrument used by each 1st, 2nd, 3rd process contact nanopure silver particle liquid.

本発明においては、放射性物質汚染水は放射性物質に汚染された粒子と放射性物質に汚染された水からなり、これらの同時処理では効率よく放射線を低減化することができず、いかに汚染水から放射性物質に汚染された微細な粒子を除去できるかで汚染水の処理効率が決まってしまうことから、汚染水に含まれる放射性物質に汚染された粒子及び微細な粒子を除去する第1及び第2のろ過工程と、放射性物質に汚染された粒子を除去した汚染水をナノ純銀粒子担持体に接触させ水の放射線を低減化する第3工程と、第1、第2工程でろ過された放射性物質を含むろ過物と第1、第2、第3の各工程で使用した器具類をナノ純銀粒子溶液に浸漬・接触させることで効率よく放射性物質汚染水の放射線を低減化することができる。      In the present invention, radioactive material-contaminated water consists of particles contaminated with radioactive material and water contaminated with radioactive material, and these simultaneous treatments cannot efficiently reduce radiation. Since the treatment efficiency of the contaminated water is determined depending on whether the fine particles contaminated with the substance can be removed, the first and second particles for removing the particles contaminated with the radioactive substance contained in the contaminated water and the fine particles are removed. The filtration step, the third step in which contaminated water from which particles contaminated with the radioactive material have been removed are brought into contact with the nanopure silver particle carrier to reduce the radiation of the water, and the radioactive material filtered in the first and second steps. The radioactive material contaminated water radiation can be efficiently reduced by immersing / contacting the filtered product and the instruments used in the first, second, and third steps with the nanopure silver particle solution.

本発明によれば、放射性物質汚染水を放射性物質に汚染された粒子と汚染水に分離して、分離した汚染水をナノ純銀粒子担持体接触させることで効率よく放射線低減化をすることができる。また、低減化に使用した器具類並びに分離した汚染粒子もナノ純銀粒子溶液に浸漬・接触させることで、器具類や汚染粒子の放射線も低減化でき放射性物質を拡散させる心配も無く、安全に放射性物質汚染水の放射線を低減化することができる。      According to the present invention, radioactive substance-contaminated water is separated into radioactive substance-contaminated particles and contaminated water, and the separated contaminated water can be brought into contact with the nanopure silver particle carrier to efficiently reduce radiation. . In addition, the instruments used for reduction and the separated contaminant particles are immersed and brought into contact with the nanopure silver particle solution, so that radiation of the instruments and contaminant particles can be reduced, and there is no fear of diffusing radioactive materials. Radiation of substance-contaminated water can be reduced.

本発明の第1工程から第3工程を示すシステムの概略模式図である。  It is a schematic diagram of a system showing the first to third steps of the present invention. 本発明の第3工程で使用する水ナノ純銀粒子担持体接触部の模式図である。  It is a schematic diagram of the water nano pure silver particle support body contact part used at the 3rd process of this invention.

以下、図面に基づいて本発明の実施の形態を詳細に説明する。
図1乃至図2は本発明に係る放射線汚染水の放射線低減化方法に使用される装置類の一例を示すもので、目的・効果を同じくするものは本発明の要旨の範囲内に含まれることは言うまでも無い。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1 and FIG. 2 show examples of devices used in the radiation reducing method for radiation-contaminated water according to the present invention, and those having the same purpose and effect are included in the scope of the gist of the present invention. Needless to say.

図1は、本発明の放射性物質汚染水の放射線低減化方法の第1工程から第3工程を示すシステムの概略模式図で、1は低減化システムで、原水槽2、原水ポンプ3、フィルタープレス4、フィルター5、中継タンク6、低減部7から構成されている。また、低減部7は、処理ポンプ71、処理水カートリッジ72から構成されている。      FIG. 1 is a schematic diagram of a system showing the first to third steps of the radioactive substance contaminated water radiation reduction method according to the present invention. Reference numeral 1 denotes a reduction system, which is a raw water tank 2, a raw water pump 3, and a filter press. 4, a filter 5, a relay tank 6, and a reduction unit 7. The reduction unit 7 includes a treatment pump 71 and a treatment water cartridge 72.

第1工程において2は、建物を洗浄した水、道路洗浄後の水等の除染作業により生じた水あるいは放射性物質に汚染された池の水等の汚染水を貯留する原水タンクである。3は、原水槽2に貯留された汚染水を第1工程であるフィルタープレス4に送る原水ポンプである。4は、原水ポンプ3で送られてきた汚染水に含まれる放射性物質に汚染された土やゴミ等の固形物をろ過・除去するフィルタープレスで、このフィルタープレス4はフィルターが多段に構成されるもので、フィルターはろ過する汚染水に含まれる粒子構成によりフィルターメッシュが選択され、また、フィルターの段数を変えることによりろ過効率を変えることができるものである。第1工程のろ過処理工程でろ過された土やゴミ等の固形物はプレスされ水分の少ないケーキ状の固形物となり、第4工程でナノ純銀粒子溶液に浸漬することで無害化される。また、使用されたフィルターもナノ純銀粒子溶液に浸漬することで無害化されるので、一般的な廃棄物として焼却処分することができる。      In the first step, reference numeral 2 denotes a raw water tank for storing polluted water such as water generated by decontamination work such as water for washing a building, water after road washing, or pond water contaminated with radioactive substances. 3 is a raw water pump which sends the contaminated water stored in the raw water tank 2 to the filter press 4 which is a 1st process. 4 is a filter press that filters and removes solids such as soil and dirt contaminated with radioactive substances contained in the contaminated water sent by the raw water pump 3, and this filter press 4 is composed of multiple stages of filters. In the filter, the filter mesh is selected depending on the particle composition contained in the contaminated water to be filtered, and the filtration efficiency can be changed by changing the number of stages of the filter. Solids such as soil and dust filtered in the first filtration treatment step are pressed into cake-like solids with little moisture, and are rendered harmless by being immersed in the nanopure silver particle solution in the fourth step. Moreover, since the used filter is detoxified by being immersed in the nanopure silver particle solution, it can be incinerated as a general waste.

第2工程において5は、フィルタープレス4で汚染水から放射性物質に汚染された土やゴミ等の固形物が除去された水から、フィルタープレス4で除去されなかった微細な粒子の固形物を除去するフィルターで、第1工程で使用されるフィルターよりさらに細密なフィルターが装着されている。このフィルター5で微細な粒子の固形物を除去された汚染水は、中継タンク6に送られ貯留する。第2工程では第1工程でろ過された汚染水からさらに放射性物質に汚染された微細な粒子の固形物を除去することで、第3工程で行われる放射線低減化処理の効率を上げるものである。第2工程で使用されたフィルターも第1工程と同様に使用後は第4工程でナノ純銀粒子溶液に浸漬され無害化されるので、一般的な廃棄物として焼却処分することができる。      In the second step 5, fine solid particles that were not removed by the filter press 4 are removed from the water from which the solid matter such as soil and dirt contaminated with radioactive substances has been removed from the contaminated water by the filter press 4. The filter is a finer filter than the filter used in the first step. The contaminated water from which fine solid particles are removed by the filter 5 is sent to the relay tank 6 and stored. In the second step, the solid matter of fine particles contaminated with radioactive substances is further removed from the contaminated water filtered in the first step, thereby increasing the efficiency of the radiation reduction process performed in the third step. . Since the filter used in the second step is made harmless by being immersed in the nanopure silver particle solution in the fourth step after use in the same manner as in the first step, it can be incinerated as a general waste.

第3工程において7は、第1工程、第2工程で放射性物質に汚染された固形物が除去された汚染水の放射線を低減化する低減部で、中継タンク6に貯留された汚染水を処理水ポンプ71で処理水カートリッジ72に送り、処理水カートリッジ72内に装填される例えばナノ純銀粒子御影石及びナノ純銀粒子担持骨炭等で示されるナノ純銀粒子担持体と汚染水を接触させることで汚染水の放射線を低減化するものである。汚染水は処理水カートリッジ72の下部からカートリッジ内に入り、一例として示されるナノ純銀粒子担持体であるナノ純銀粒子担持御影石、ナノ純銀粒子担持骨炭、ナノ純銀粒子担持御影石とそれぞれ接触して放射線が低減された処理水Sとして、カートリッジ上部から出るもので、図2に示されるように処理水カートリッジ72を4個で1セットとし4連続で汚染水を通過させ低減化処理を行うものである。この処理水カートリッジ72を4個で1セットとし4連続での処理構成は基礎試験を通じて得られたものであるが、汚染水の状況に応じ、一例で示されるナノ純銀粒子担持体であるナノ純銀粒子担持御影石、ナノ純銀粒子担持骨炭、ナノ純銀粒子担持御影石のカートリッジ内で汚染水と接触させる順番やナノ純銀粒子担持体量の変更を行ったり、処理水カートリッジ72のセット数を増やすことで対応が可能である。また、処理水カートリッジ72内の上部にはフィルター設置スペースが設けてあるので、必要に応じフィルターを設置することで汚染水に含まれるさらに微細な粒子を除去することができる。      In the third step, 7 is a reduction unit that reduces the radiation of the contaminated water from which the solid substances contaminated with the radioactive substances in the first step and the second step are removed, and the contaminated water stored in the relay tank 6 is treated. Contaminated water is brought into contact with the nanopure silver particle carrier, such as nanopure silver particle granite and nanopure silver particle carrying bone charcoal, which are fed into the treated water cartridge 72 by the water pump 71 and loaded in the treated water cartridge 72. This reduces radiation. The contaminated water enters the cartridge from the lower part of the treated water cartridge 72 and comes into contact with nanopure silver particle-supported granite, nanopure silver particle-supported granite, nanopure silver particle-supported granite, and nanopure silver particle-supported granite, which are shown as examples. The reduced treated water S is discharged from the upper part of the cartridge. As shown in FIG. 2, four treated water cartridges 72 are used as one set, and the contaminated water is allowed to pass through four times to perform a reduction process. The four treatment water cartridges 72 are one set, and a four-continuous treatment configuration is obtained through a basic test. Nanopure silver, which is a nanopure silver particle carrier shown as an example, depending on the situation of contaminated water Corresponding by changing the order of contacting with contaminated water and the amount of nanopure silver particle support in the cartridge of granite, nanopure silver particle support bone charcoal, nanopure silver particle support granite, or increasing the number of sets of treated water cartridges 72 Is possible. Moreover, since a filter installation space is provided in the upper part in the treated water cartridge 72, finer particles contained in the contaminated water can be removed by installing a filter as necessary.

第4工程において、これら処理水カートリッジ72の使用後はナノ純銀粒子溶液に浸漬して放射線を低減化しメンテナンスを行って再利用することができる。また、第1工程でフィルタープレス4から排出されるケーキ状の固形物は、ナノ純銀粒子液に浸漬することで無害化することができる。      In the fourth step, after use of these treated water cartridges 72, they can be reused by being immersed in a nanopure silver particle solution to reduce radiation and perform maintenance. Moreover, the cake-like solid substance discharged | emitted from the filter press 4 at a 1st process can be rendered harmless by being immersed in a nanopure silver particle liquid.

また、汚染水の処理量に合わせて放射線低減化システムを大型化することも可能であり、小型の放射線低減化システムは車載型とすることも可能である。      In addition, the radiation reduction system can be enlarged in accordance with the amount of contaminated water treated, and the small radiation reduction system can be an on-vehicle type.

このように、本発明の放射性物質汚染水の放射線低減化方法によれば、汚染水に含まれる放射性物質に汚染された土やゴミ等の粒子・微粒子を汚染水から除去し、水分と固形分を別々に放射線低減化処理を行うことで、効率よく低減化することができる。また、低減化に使用した器具類並びにろ過された固形物もナノ純銀粒子溶液に浸漬して無害化処理を行うことで、放射性物質を拡散させる恐れがなく、器具類の再利用も可能である。フィルター等再利用できないものも無害化処理されているので一般的な廃棄物として処分することができる。      Thus, according to the radiation reducing method for radioactive material contaminated water of the present invention, particles and fine particles such as soil and garbage contaminated with radioactive material contained in the contaminated water are removed from the contaminated water, and moisture and solid content are removed. Can be efficiently reduced by performing the radiation reduction treatment separately. In addition, the instruments used for reduction and the filtered solid matter are immersed in the nanopure silver particle solution and detoxified, so there is no fear of diffusing radioactive materials and the instruments can be reused. . Those that cannot be reused such as filters are also detoxified and can be disposed of as general waste.

放射性物質の除染に本発明の放射性物質汚染水の放射線低減化方法を用いることで、福島原発をはじめ、爆発事故により大量の放射性物質が飛散し避難を余儀なくされた住民の帰郷が実現でき、放射線の影響を心配せずに安心した生活が送ることができる。      By using the radioactive material contaminated water radiation reduction method of the present invention for decontamination of radioactive materials, it is possible to realize the return home of residents who have been forced to evacuate due to the large amount of radioactive materials scattered from the Fukushima nuclear power plant, You can live a safe life without worrying about the effects of radiation.

1 :低減化システム
4 :フィルタープレス
5 :フィルター
7 :低減部
72 :処理水カートリッジ
S :処理水
1: Reduction system 4: Filter press 5: Filter 7: Reduction unit 72: Treated water cartridge S: Treated water

Claims (1)

汚染水に含まれる放射性物質に汚染された粒子を除去する第1のろ過工程と、汚染水に含まれる放射性物質に汚染された微細な粒子を除去する第2のろ過工程と、放射性物質に汚染されたこれらの粒子が除去された汚染水をナノ純銀粒子担持体に接触させて放射線低減化する第3工程と、第1及び第2のろ過工程からのろ過物と第1、第2、第3の各工程で使用した器具類をナノ純銀粒子液に接触させて放射線低減化する第4工程からなる放射性物質汚染水の放射線低減化方法。A first filtration process for removing particles contaminated with radioactive substances contained in contaminated water, a second filtration process for removing fine particles contaminated with radioactive substances contained in contaminated water, and contamination with radioactive substances A third step of bringing the contaminated water from which these particles have been removed into contact with the nanopure silver particle carrier to reduce radiation, the filtrate from the first and second filtration steps, and the first, second, second A method for reducing the radiation of radioactive material-contaminated water, comprising a fourth step of reducing radiation by bringing the instruments used in each of the steps 3 into contact with a nanopure silver particle liquid.
JP2012053727A 2012-02-23 2012-02-23 Method for reducing radiation of radioactive material contaminated water Pending JP2013174571A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102042487B1 (en) * 2018-06-12 2019-11-11 한국원자력연구원 Apparatus for Treating Uranium-Containing Liquid Waste and Method for Treating Uranium-Containing Liquid Waste

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102042487B1 (en) * 2018-06-12 2019-11-11 한국원자력연구원 Apparatus for Treating Uranium-Containing Liquid Waste and Method for Treating Uranium-Containing Liquid Waste

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