JP2013140726A - Fuel battery - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a technique suppressing delay in the startup of power generation using a conventional compressor when a rapid increase in power generation amount is required.SOLUTION: A fuel battery comprises: a fuel battery stack including a fuel battery cell laminate comprising a plurality of fuel battery cells laminated therein; an oxygen gas passage for supplying oxygen gas for power generation to the fuel battery cells; and an oxygen gas storage unit connected to the oxygen gas passage. Response delay in cases where a rapid increase in power generation amount is required is suppressed by using the oxygen gas stored in the oxygen gas storage unit.

Description

  The present invention relates to a fuel cell.

A fuel cell that generates electricity by an electrochemical reaction between a fuel gas (hydrogen) and an oxidant gas (oxygen) has attracted attention as an energy source. In this fuel cell, when a rapid increase in the amount of power generation is required, there is a case where oxygen for generating the power is temporarily insufficient and a response to the request is delayed (hereinafter also referred to as a response delay). Therefore, in the technique described in Patent Document 1, the air flow rate and the air pressure supplied to the fuel cell are controlled so that the time until the power generation amount reaches a predetermined value becomes the target response time.

  However, in the technique described in Patent Document 1, a highly responsive compressor is used, and such a compressor is expensive. Therefore, there has been a demand for a technique for suppressing response delay using a conventional compressor.

JP 2004-327317 A

  In view of the above-described problems, the problem to be solved by the present invention is to provide a technique for suppressing a response delay using a conventional compressor when a rapid increase in power generation amount is required in a fuel cell. .

  SUMMARY An advantage of some aspects of the invention is to solve at least a part of the problems described above, and the invention can be implemented as the following forms or application examples.

[Application Example 1] A fuel cell, a fuel cell stack having a fuel cell stack in which a plurality of fuel cells are stacked, an oxygen gas flow path for supplying oxygen gas to the fuel cells, A fuel cell comprising: an oxygen gas storage unit connected to an oxygen gas flow path and storing a part of the oxygen gas. With such a configuration, when a rapid increase in the amount of power generation is required, oxygen diffuses from a higher concentration to a lower concentration, so the oxygen gas stored in the oxygen gas storage section becomes oxygen gas Diffusion to the missing fuel cells. Therefore, the response delay of the fuel cell can be suppressed even when a conventional compressor is used.

[Application Example 2] The fuel cell according to Application Example 1, wherein the oxygen gas reservoir is provided in at least one of a stack manifold, an end plate, a terminal, and an insulator provided in the fuel cell stack. . With such a configuration, when a rapid increase in the amount of power generation is required, the oxygen gas stored in at least one of the stack manifold, end plate, terminal, and insulator is a fuel cell in which oxygen gas is insufficient. Spread to the cell. Therefore, a response delay can be suppressed using a conventional compressor without providing a new structure in the fuel cell.

[Application Example 3] The fuel cell according to Application Example 1 or Application Example 2, wherein the oxygen gas reservoir is provided by enlarging a cross-sectional area of the oxygen gas flow path in the fuel cell stack. ,Fuel cell. With such a structure, oxygen gas can be stored at a location where the cross-sectional area of the oxygen gas flow path in the fuel cell stack is enlarged. And since the distance of an oxygen gas storage part and a fuel cell is near, oxygen gas tends to reach a fuel cell. Moreover, the oxygen gas storage part can be provided over the entire oxygen gas flow path of the fuel cell stack. For this reason, the oxygen gas stored in the oxygen gas storage part is likely to uniformly diffuse and reach all the fuel cells of the fuel cell. Therefore, the response delay of the fuel cell when a rapid increase in the amount of power generation is required can be effectively suppressed using a conventional compressor.

[Application Example 4] The fuel cell according to any one of application examples from Application Example 1 to Application Example 3, wherein the oxygen gas storage section includes the fuel in an oxygen gas supply pipe connected to the fuel cell stack. A fuel cell provided in the vicinity of the battery stack. With such a structure, oxygen can be stored in the oxygen gas storage part in the vicinity of the fuel cell stack, so that the oxygen gas can be distributed to the entire fuel cell in which oxygen gas is insufficient. Therefore, it is possible to suppress delay in response of the fuel cell without changing the configuration of the fuel cell stack.

  In addition to the configuration as the fuel cell described above, the present invention can also be configured as a stationary power generator installed in a moving vehicle, a building, or the like equipped with the fuel cell.

It is a figure which shows schematic structure of the fuel cell as one Example of this invention. It is a perspective view in the AA cross section of the end plate shown in FIG. It is a figure which shows the flow of the oxygen gas in a fuel cell when the rapid increase of electric power generation is requested | required. It is a figure which shows a fuel cell provided with an oxygen gas storage part in a terminal. It is a figure which shows a fuel cell provided with an oxygen gas storage part in an oxygen gas supply manifold. It is a figure which shows the flow of the oxygen gas in a fuel cell when the rapid increase of electric power generation is requested | required. It is a figure shown about a fuel cell provided with an oxygen gas storage part outside a fuel cell stack. It is a figure which shows the flow of the oxygen gas in a fuel cell when the rapid increase of electric power generation is requested | required. It is a figure shown about a fuel cell provided with the oxygen gas storage part which has a valve | bulb outside a fuel cell stack.

A. First embodiment:
FIG. 1 is a diagram showing a schematic configuration of a fuel cell 10a as an embodiment of the present invention. The fuel cell 10 a includes a fuel cell stack 100, a supply pipe 410 and a discharge pipe 420 connected to the fuel cell stack 100.

  As shown in FIG. 1, the fuel cell stack 100 includes a fuel cell stack 150 in which a plurality of fuel cells 105 are stacked, a pair of terminals 221 and 222, which are current collector plates having output terminals, and an insulating plate. A pair of insulators 211 and 212, a stack manifold 201, and an end plate 202a are formed to be sandwiched. In the fuel cell stack 100, a manifold for supplying and discharging a fuel gas or an oxidizing gas as a reaction gas and a refrigerant for cooling the fuel cell 10a is stacked in a direction in which a plurality of fuel cell cells 105 are stacked (hereinafter referred to as a fuel cell stack 105). , Also referred to as the stacking direction). However, only the oxygen gas supply manifold 411 and the oxygen gas discharge manifold 421 are shown in FIG. 1 for ease of illustration and the following description. The supply pipe 410 and the oxygen gas supply manifold 411 correspond to the “oxygen gas flow path” of the present application, and the supply pipe 410 particularly corresponds to the “oxygen gas supply pipe” of the present application.

  The fuel cell 105 includes a cathode, an anode, an electrolyte, a separator, and the like, and constitutes a minimum unit of power generation. In the present embodiment, a solid polymer fuel cell is used as the fuel cell 105, but various types of fuel cells can be used.

  At the cathode of the fuel cell 105, air compressed by a compressor (not shown) connected to the supply pipe 410 is supplied as oxygen-containing oxidizing gas (oxygen gas) from the supply pipe 410 through the oxygen gas supply manifold 411. Supplied. The oxygen gas flows in the fuel cell 10a as shown by the arrow in FIG. Cathode off-gas discharged from the cathode of each fuel cell 105 is discharged outside the fuel cell stack 100 via a discharge pipe 420 connected to the oxygen gas discharge manifold 421.

  Hydrogen as fuel gas is supplied to the anode of the fuel cell 105 from a hydrogen tank storing high-pressure hydrogen via a hydrogen supply pipe (not shown). The anode off gas discharged from each fuel cell is discharged outside the fuel cell stack 100 via a discharge pipe connected to a manifold (not shown).

  The terminals 221 and 222 are made of dense carbon or a gas-impermeable conductive member such as a copper plate. The terminals 221 and 222 are each provided with an output terminal (not shown) so that the power generated by the fuel cell stack 150 can be output. The insulators 211 and 212 are formed of an insulating member such as rubber or resin. The stack manifold 201 and the end plate 202a are made of metal in order to ensure rigidity. In addition, the end plate 202a of a present Example is provided with the oxygen gas storage part 310a formed by covering the hollow formed in the end plate 202a with an insulator, as shown in FIG.

  FIG. 2 is a perspective view of the end plate 202a shown in FIG. The end plate 202a includes an oxygen gas storage part 310a for storing oxygen gas therein. The oxygen gas reservoir 310a is connected to the oxygen gas supply manifold 411 and is not connected to the oxygen gas discharge manifold 421. Therefore, when the fuel cell 10a is generating power at a constant output (hereinafter also referred to as “normal power generation”), as shown in FIG. 1, the oxygen gas reservoir 310a is supplied with an oxygen gas supply manifold 411. Oxygen gas flows in and is stored.

  FIG. 3 is a diagram illustrating the flow of oxygen gas in the fuel cell 10a when a rapid increase in the amount of power generation is required. Fuel cells do not always output the same amount of power. For example, a vehicle equipped with a fuel cell requires the fuel cell to rapidly increase the amount of power generation when starting from steady operation such as idling. In such a case, the conventional fuel cell increases the amount of oxygen gas supplied to the cathode side of the fuel cell to a target amount in response to a request for increasing the amount of power generation. However, there is usually a response delay before the fuel cell outputs the required amount of power generation. This is because it takes some time for the compressor to increase the flow rate of oxygen gas and for the oxygen gas to reach the fuel cell via the supply pipe.

  In the fuel cell 10a of the present embodiment, the end plate 202a is provided with the oxygen gas storage part 310a. Therefore, even when a rapid increase in the amount of power generation is required, the stored oxygen gas is stored in the oxygen gas storage part 310a. To the fuel cell 105 in which oxygen gas is insufficient via the oxygen gas supply manifold 411. This is because oxygen usually diffuses from a higher concentration to a lower concentration. The oxygen gas stored in the oxygen gas storage unit 310 a is considered to reach some fuel cells 105 earlier than the oxygen gas flowing from the compressor via the supply pipe 410. This is because the oxygen gas storage part 310a is provided on the end plate 202a constituting the fuel cell stack 100, and the distance from the oxygen gas storage part 310a to the fuel cell 105 is short. Accordingly, the fuel cell 10a including the oxygen gas storage unit 310a can generate power using the oxygen gas stored in the oxygen gas storage unit 310a even when a rapid increase in the amount of power generation is required. Therefore, response delay can be suppressed without shortening the supply pipe 410 in order to quickly flow oxygen gas into the fuel cell 105. Therefore, it is possible to improve the degree of freedom in designing the fuel cell. Further, since the response delay can be suppressed by the oxygen gas stored in the oxygen gas storage unit 310a without increasing the capacity of the compressor, it is not necessary to consider the space for installing the large capacity compressor. Further, the response delay can be suppressed by using a conventional compressor without using an expensive compressor with high responsiveness. Furthermore, even if a new structure is not provided in the fuel cell, response delay can be suppressed only by changing the shape of the end plate. Therefore, it is possible to manufacture a fuel cell that can cope with response delay at a low cost.

B. Second embodiment:
In the first embodiment, it has been described that a fuel cell including an oxygen gas reservoir in the end plate can suppress response delay. On the other hand, in the second embodiment, a fuel cell provided with an oxygen gas storage part at a terminal will be described.

  FIG. 4 is a diagram showing a fuel cell 10b having an oxygen gas storage section 310b in the terminal 222b. Similar to the first embodiment, the terminal 222b is also provided with a space inside thereof, so that oxygen gas can be stored during normal power generation. The oxygen gas storage part 310b in the terminal 222b is formed by covering the depression formed in the terminal 222b with an insulator. Note that the oxygen gas storage section 310b provided in the terminal 222b shown in FIG. 4 is connected to the oxygen gas storage section 310a provided in the end plate 202a shown in FIG.

  During normal power generation, oxygen gas flows into the oxygen gas reservoirs 310a and 310b via the oxygen gas supply manifold 411 and is stored. When a rapid increase in the amount of power generation is requested, oxygen gas diffuses from the oxygen gas storage portions 310a and 310b to the oxygen gas supply manifold 411 and reaches the fuel cell 105 as in FIG. 3 of the first embodiment. To do. The fuel cell 105 can generate power using the oxygen gas diffused from the oxygen gas storage portions 310a and 310b. Therefore, the fuel cell 10b of the present embodiment also has the same effect as the fuel cell 10a of the first embodiment. In particular, since the fuel cell 10b of the present embodiment includes the oxygen gas storage unit 310b in the terminal 222b closer to the fuel cell 105, when the rapid increase in the amount of power generation is required, the oxygen can be generated more quickly. To reach. In the fuel cell 10b, the end plate 202a also includes the oxygen gas storage part 310a, so that more oxygen can be stored. Therefore, even when a rapid increase in the amount of power generation is required, it is possible to generate power by causing more oxygen to reach the fuel cell 105.

  Even if the oxygen gas reservoir 310a is not provided in the end plate 202a and the oxygen gas reservoir 310b is provided only in the terminal 222b, it is possible to suppress a response delay when a rapid increase in the amount of power generation is required. The structure provided with the oxygen gas storage part may be the structure of the fuel cell stack 100 other than the end plate 202a shown in the first embodiment and the terminal 222b shown in this embodiment. For example, by providing an oxygen gas storage section in an arbitrary structure such as an insulator 212 adjacent to the end plate 202a, an insulator 211 provided on the supply pipe 410 side, a terminal 221, a stack manifold 201, etc., and storing oxygen gas, It is possible to suppress a response delay when a rapid increase in the amount of power generation is required. Further, the oxygen gas storage portions of the structure of the fuel cell stack 100 may be combined as in this embodiment. For example, more oxygen gas can be stored by combining two or more oxygen gas storage units such as the stack manifold 201 and the end plate 202a, the insulator 211, the terminal 222b, and the terminal 221. In this way, in the fuel cell, it is possible to further suppress a response delay when a rapid increase in the amount of power generation is required.

C. Third embodiment:
In the first embodiment and the second embodiment, it has been described that a fuel cell including an oxygen gas reservoir in an end plate and a terminal that sandwich a fuel cell stack can suppress a response delay. On the other hand, in the third embodiment, a fuel cell will be described in which a cross-sectional area of an oxygen gas supply manifold is expanded to include an oxygen gas reservoir in a fuel cell stack.

  FIG. 5A is a view showing a fuel cell 10c provided with an oxygen gas reservoir 310c in the oxygen gas supply manifold 411. FIG. FIG. 5B is a schematic diagram of the fuel cell 105c in the BB cross section of the fuel cell 10c of FIG. The fuel cell 105c of the fuel cell 10c is provided with an oxygen gas storage portion 310c under the two oxygen gas supply manifolds 411 so as to connect the two oxygen gas supply manifolds 411. That is, the oxygen gas reservoir 310c is provided by expanding the cross-sectional area of the oxygen gas supply manifold 411 in the stacking direction. During normal power generation, oxygen gas flows from the oxygen gas supply manifold 411 and is stored in the oxygen gas storage section 310c as shown in FIG.

  FIG. 6 is a diagram showing the flow of oxygen gas in the fuel cell 10c when a rapid increase in the amount of power generation is required. When a rapid increase in the amount of power generation is required, the oxygen stored in the oxygen gas reservoir 310c diffuses into the oxygen gas supply manifold 411 as shown in FIGS. 6A and 6B, and the fuel cell The cell 105c is reached. The fuel battery cell 105c can generate power using the oxygen gas diffused from the oxygen gas reservoir 310c. Therefore, the fuel cell 10c of this embodiment also has the same effect as the fuel cell 10a of the first embodiment. In particular, in the present embodiment, the oxygen gas reservoir 310 c is connected to the oxygen gas supply manifold 411. Therefore, since the distance between the oxygen gas storage part 310c and the fuel battery cell 105c is short, the oxygen gas stored in the oxygen gas storage part 310c is likely to reach the fuel battery cell 105c. Moreover, the oxygen gas storage part 310c is provided over the whole oxygen gas supply manifold 411 of the fuel cell stack 150c. Therefore, the oxygen gas stored in the oxygen gas storage unit 310c is uniformly diffused to all the fuel cells 105c of the fuel cell 10c. Therefore, it is possible to effectively suppress the delay in response of the fuel cell when a rapid increase in the amount of power generation is required.

  Similar to FIG. 4 shown in the second embodiment, an oxygen gas reservoir is provided in at least one of the terminal 222, the end plate 202, and the other structure of the fuel cell stack 100, and the oxygen gas supply manifold 411 is provided. More oxygen gas can also be stored by combining with this oxygen gas storage part 310c. By doing so, it becomes possible to further suppress the delay in response of the fuel cell when a rapid increase in the amount of power generation is required.

D. Fourth embodiment:
In the first embodiment and the second embodiment, it has been described that the fuel cell provided with the oxygen gas storage portion at the end plate and the terminal sandwiching the fuel cell stack can suppress the response delay. In the third embodiment, it has been described that the fuel cell including the oxygen gas reservoir by expanding the cross-sectional area of the oxygen gas supply manifold can suppress the response delay. In contrast, in the fourth embodiment, a fuel cell provided with an oxygen gas reservoir outside the fuel cell stack will be described.

  FIG. 7 is a diagram showing a fuel cell 10d including an oxygen gas storage unit 310d outside the fuel cell stack 100. As shown in FIG. The fuel cell 10d shown in FIG. 7 is provided with an oxygen gas reservoir 310d connected to the supply pipe 410 near the entrance of the oxygen gas supply manifold 411. Further, in the fuel cell 10d shown in FIG. 7, in addition to the oxygen gas storage part 310d connected to the supply pipe 410, the end plate 202a is also provided with an oxygen gas storage part 310a. As shown in FIG. 7, oxygen gas flows into the oxygen gas storage units 310 a and 310 d from the supply pipe 410 and is stored during normal power generation.

  FIG. 8 is a diagram showing the flow of oxygen gas in the fuel cell 10d when a rapid increase in the amount of power generation is required. When a rapid increase in the amount of power generation is required, the oxygen gas stored in the oxygen gas storage portions 310a and 310d diffuses into the oxygen gas supply manifold 411 as in the first and second embodiments described above. Then, the fuel cell 105 is reached. Specifically, the oxygen gas stored in the oxygen gas storage unit 310 d connected to the supply pipe 410 sequentially reaches the fuel cell 105 near the entrance of the oxygen gas supply manifold 411. Further, the oxygen gas stored in the oxygen gas storage section 310a provided in the end plate 202a sequentially reaches the fuel cell 105 away from the entrance of the oxygen gas supply manifold 411. Therefore, the fuel cell 10d of this embodiment also has the same effect as that of the above-described embodiment. In particular, in the present embodiment, the oxygen gas storage part 310 d is connected to the supply pipe 410 near the entrance of the oxygen gas supply manifold 411. If the oxygen gas storage unit is provided in this way, oxygen gas can easily reach the entire fuel cell 105 even when a rapid increase in the amount of power generation is required.

  In addition, it is also possible to provide only the oxygen gas storage part 310d connected to the supply piping 410, without providing the oxygen gas storage part 310a in the end plate 202. In this case, without changing the configuration of the fuel cell stack 100, it is only necessary to provide the oxygen gas storage part 310d in the supply pipe 410 outside the fuel cell stack 100, and the fuel cell in the case where a rapid increase in the amount of power generation is required. Response delay can be suppressed.

  The fuel cell shown in FIG. 7 includes an oxygen gas reservoir 310a provided in the end plate 202a and an oxygen gas reservoir 310d connected to the supply pipe 410, but fuel other than the end plate 202a. You may combine with the structure of the battery stack 100, and the oxygen gas storage part 310c provided in the oxygen gas supply manifold 411 shown in 3rd Example. By doing so, it becomes possible to further suppress the delay in response of the fuel cell when a rapid increase in the amount of power generation is required.

E. Example 5:
In the first to fourth embodiments, the fuel cell that stores oxygen gas in the oxygen gas storage section during normal operation has been described. In contrast, in the fifth embodiment, a fuel cell that stores oxygen gas in the oxygen gas reservoir using the timing at which the fuel cell stops will be described.

  FIG. 9 is a diagram showing a fuel cell 10e including an oxygen gas storage portion 310e having a valve 515 outside the fuel cell stack 100. As shown in FIG. The oxygen gas reservoir 310e stores the oxygen gas that has flowed in when the oxygen gas reservoir 310e has a negative pressure. Hereinafter, a method for storing oxygen gas in the oxygen gas reservoir 310e will be described.

  The supply pipe 410 of the fuel cell 10e is provided with an inflow valve 510 for starting and stopping the inflow of oxygen gas. Further, the discharge pipe 420 of the fuel cell 10e is provided with a discharge valve 520 for starting and stopping discharge of cathode off gas and the like. During power generation of the fuel cell 10e, the inflow valve 510 and the exhaust valve 520 are opened.

  When stopping the power generation of the fuel cell 10e, in order to prevent deterioration of the fuel cell 105, the fuel gas and oxygen gas staying in the fuel cell stack 100 are discharged, and the inflow valve 510 and the discharge valve 520 is closed. When the fuel cell 10e stops generating power, the temperature inside the fuel cell stack 100 gradually decreases. At this time, since the pressure inside the fuel cell stack 100 decreases as the temperature decreases, the pressure outside the fuel cell stack 100 (on the upstream side of the inflow valve 510 and the downstream side of the discharge valve 520 with respect to the flow of oxygen gas). Lower than pressure.

  Next, when starting the operation of the fuel cell 10e, the inflow valve 510 and the exhaust valve 520 are opened, and the valve 515 of the oxygen gas storage unit 310e is also opened. As a result, the oxygen gas flows into and is stored in the oxygen gas storage portion 310e that is at a negative pressure as in the fuel cell stack 100. And if the valve | bulb 515 with which the oxygen gas storage part 310e is provided is closed, oxygen gas can be reliably stored by the oxygen gas storage part 310e. The oxygen gas stored in the oxygen gas storage unit 310e reaches the fuel cell 105 similarly to the oxygen gas shown in FIG. 8, for example, by opening the valve 515 when a rapid increase in power generation amount is required. Become. Therefore, the fuel cell 10e of this embodiment not only achieves the same effects as the fourth embodiment described above, but also more reliably stores oxygen gas in the oxygen gas storage section 310e and requires a rapid increase in power generation. Therefore, it is possible to more reliably suppress delay in response of the fuel cell. Further, in the fuel cell 10e, as shown in the second and third embodiments, an oxygen gas storage section is also provided in the structure of the fuel cell stack 100 other than the end plate 202a and the oxygen gas supply manifold 411. You can also. By doing so, since more oxygen can be stored, it becomes possible to further suppress the response delay of the fuel cell when a rapid increase in the amount of power generation is required.

F. Variations:
As mentioned above, although various embodiment of this invention was described, this invention is not limited to these embodiment, A various structure can be taken in the range which does not deviate from the meaning. For example, the following modifications are possible.

  In Example 5 described above, the power generation of the fuel cell 10e is stopped, and oxygen gas is stored in the oxygen gas storage unit 310e when power is generated again. However, when the amount of power generation is reduced, the inside of the fuel cell stack 100 is The oxygen gas may be stored even when the pressure is negative compared to the outside of the fuel cell stack 100.

10, 10a, 10b, 10c, 10d, 10e ... Fuel cell 100 ... Fuel cell stack 105, 105c ... Fuel cell 150, 150c ... Fuel cell stack 201 ... Stack manifold 202 ... End plate 203, 212 ... Insulator 222 ... Terminals 310a, 310b, 310c, 310d, 310e ... oxygen gas reservoir 410 ... supply piping 411 ... oxygen gas supply manifold 420 ... discharge piping 421 ... oxygen gas discharge manifold 510 ... inflow valve 515 ... valve 520 ... discharge valve

Claims (4)

A fuel cell,
A fuel cell stack having a fuel cell stack in which a plurality of fuel cells are stacked; and
An oxygen gas flow path for supplying oxygen gas to the fuel cell;
An oxygen gas storage unit connected to the oxygen gas flow path and storing a part of the oxygen gas;
A fuel cell comprising: The fuel cell according to claim 1, wherein
The oxygen gas storage unit is a fuel cell provided in at least one of a stack manifold, an end plate, a terminal, and an insulator included in the fuel cell stack. The fuel cell according to claim 1 or 2, wherein
The fuel cell, wherein the oxygen gas storage part is provided by enlarging a cross-sectional area of the oxygen gas flow path in the fuel cell stack. A fuel cell according to any one of claims 1 to 3, wherein
The oxygen gas storage section is a fuel cell provided in the vicinity of the fuel cell stack of an oxygen gas supply pipe connected to the fuel cell stack.

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