JP2013136710A5 - - Google Patents

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JP2013136710A5
JP2013136710A5 JP2011289345A JP2011289345A JP2013136710A5 JP 2013136710 A5 JP2013136710 A5 JP 2013136710A5 JP 2011289345 A JP2011289345 A JP 2011289345A JP 2011289345 A JP2011289345 A JP 2011289345A JP 2013136710 A5 JP2013136710 A5 JP 2013136710A5
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surfactant
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colored film
transparent colored
pigment
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Claims (21)

基材と、基材上に形成された透明性着色膜とからなり、
該透明性着色膜が、マトリックス成分と、下記式(1)で表される有機珪素化合物で表面処理した無機酸化物微粒子と、少なくとも波長580〜600nmの範囲の光を吸収する界面活性剤処理有機系顔料(A)を含み
該界面活性剤処理有機系顔料(A)の平均粒子径が5〜60nmの範囲にあり、透明性着色膜中の含有量が固形分として0.05〜3重量%の範囲にあり、
前記透明性着色膜が、580〜600cm-1波長範囲の光透過率(i)が50〜90%の範囲にあることを特徴とする透明性着色膜付基材。
n−SiX4-n (1)
(但し、式中、Rは炭素数1〜10の非置換または置換炭化水素基であって、互いに同一であっても異なっていてもよい。X:炭素数1〜4のアルコキシ基、シラノール基、ハロゲン、水素、n:0〜3の整数)
Consisting of a substrate and a transparent colored film formed on the substrate,
The transparent colored film has a matrix component, inorganic oxide fine particles surface-treated with an organosilicon compound represented by the following formula (1), and a surfactant-treated organic that absorbs light in the wavelength range of 580 to 600 nm. including a system pigment (a),
The average particle diameter of the surfactant-treated organic pigment (A) is in the range of 5 to 60 nm, and the content in the transparent colored film is in the range of 0.05 to 3% by weight as the solid content,
A substrate with a transparent colored film, wherein the transparent colored film has a light transmittance (i) in a wavelength range of 580 to 600 cm -1 in a range of 50 to 90%.
R n -SiX 4-n (1 )
(In the formula, R is an unsubstituted or substituted hydrocarbon group having 1 to 10 carbon atoms, and may be the same or different from each other. X: an alkoxy group having 1 to 4 carbon atoms or a silanol group) , Halogen, hydrogen, n: an integer of 0 to 3)
前記透明性着色膜が、さらに少なくとも波長480〜500nmの範囲の光を吸収する界面活性剤処理有機系顔料(B)を含み、
該界面活性剤処理有機系顔料(B)の平均粒子径が5〜60nmの範囲にあり、透明性着色膜中の含有量が固形分として0.05〜3重量%の範囲にあり、
前記透明性着色膜が、480〜500cm-1波長範囲の光透過率(ii)が50〜90%の範囲にあることを特徴とする請求項1に記載の透明性着色膜付基材。
It said transparent colored film further comprises a surfactant treatment organic pigments which absorb light in the range of at least a wavelength 480~500nm (B),
The average particle diameter of the surfactant-treated organic pigment (B) is in the range of 5 to 60 nm, and the content in the transparent colored film is in the range of 0.05 to 3% by weight as the solid content,
The substrate with a transparent colored film according to claim 1 , wherein the transparent colored film has a light transmittance (ii) in a wavelength range of 480 to 500 cm -1 in a range of 50 to 90%.
前記界面活性剤処理有機系顔料(A)中の界面活性剤の処理量が顔料(A)に対して、2〜30重量%の範囲にあることを特徴とする請求項1または2に記載の透明性着色膜付基材。 Processing amount of the surfactant of the surfactant treatment organic pigment (A) is, with respect to the pigment (A), according to claim 1 or 2, characterized in that in the range of 2 to 30 wt% Base material with transparent colored film. 前記界面活性剤処理有機系顔料(B)中の界面活性剤の処理量が顔料(B)に対して、2〜30重量%の範囲にあることを特徴とする請求項2に記載の透明性着色膜付基材。 Processing amount of the surfactant of the surfactant treatment organic pigments (B) in the relative pigment (B), a transparent according to claim 2, characterized in that in the range of 2 to 30 wt% Substrate with conductive coloring film. 前記有機系顔料(A)がキナクリドン系顔料であることを特徴とする請求項1に記載の透明性着色膜付基材。 The base material with a transparent colored film according to claim 1, wherein the organic pigment (A) is a quinacridone pigment. 前記有機系顔料(B)がフタロシアニン系顔料であることを特徴とする請求項2に記載の透明性着色膜付基材。 The base material with a transparent colored film according to claim 2, wherein the organic pigment (B) is a phthalocyanine pigment. 前記界面活性剤が、陽イオン性界面活性剤、陰イオン性界面活性剤、非イオン性界面活性剤から選ばれる少なくとも1種であることを特徴とする請求項1〜6のいずれか1項に記載のハードコート膜付基材。   7. The surfactant according to claim 1, wherein the surfactant is at least one selected from a cationic surfactant, an anionic surfactant, and a nonionic surfactant. The base material with a hard coat film as described. 前記界面活性剤が、エチレンオキサイド変性骨格を有する界面活性剤であることを特徴とする請求項7に記載のハードコート膜付基材。   The base material with a hard coat film according to claim 7, wherein the surfactant is a surfactant having an ethylene oxide-modified skeleton. 前記透明性着色膜の膜厚が0.5〜10μmの範囲にあることを特徴とする請求項1〜8のいずれか1項に記載の透明性着色膜付基材。 The base material with a transparent colored film according to any one of claims 1 to 8, wherein a film thickness of the transparent colored film is in a range of 0.5 to 10 µm. 前記無機酸化物微粒子がSiO2、ZrO2、TiO2、Al23、ZnO、SnO2、Sb25、アンチモンドープ酸化錫、錫ドープ酸化インジウム、リンドープ酸化錫から選ばれる少なくとも1種であることを特徴とする請求項1〜9のいずれか1項に記載の透明性着色膜付基材。 The inorganic oxide fine particles, SiO 2, ZrO 2, TiO 2, Al 2 O 3, ZnO, SnO 2, Sb 2 O 5, antimony-doped tin oxide, tin-doped indium oxide, at least one selected from phosphorus-doped tin oxide The substrate with a transparent colored film according to claim 1, wherein the substrate has a transparent colored film. 前記表面処理無機酸化物微粒子の平均粒子径が5〜100nmの範囲にあることを特徴とする請求項1〜10のいずれか1項に記載の透明性着色膜付基材。 The substrate with a transparent colored film according to any one of claims 1 to 10, wherein an average particle size of the surface-treated inorganic oxide fine particles is in a range of 5 to 100 nm. マトリックス形成成分と、下記式(1)で表される有機珪素化合物で表面処理した無機酸化物微粒子と、少なくとも波長580〜600nmの範囲の光を吸収する界面活性剤処理有機系顔料(A)とを含んでなり、
該界面活性剤処理有機系顔料(A)の平均粒子径が5〜60nmの範囲にあり、塗布液中の濃度が固形分として0.0001〜1.8重量%の範囲にあることを特徴とする透明性着色膜形成用塗布液。
n-SiX4-n (1)
(但し、式中、Rは炭素数1〜10の非置換または置換炭化水素基であって、互いに同一であっても異なっていてもよい。X:炭素数1〜4のアルコキシ基、シラノール基、ハロゲン、水素、n:0〜3の整数)
A matrix-forming component, inorganic oxide fine particles surface-treated with an organosilicon compound represented by the following formula (1), and a surfactant-treated organic pigment (A) that absorbs light having a wavelength in the range of 580 to 600 nm. Comprising
The average particle diameter of the surfactant-treated organic pigment (A) is in the range of 5 to 60 nm, and the concentration in the coating solution is in the range of 0.0001 to 1.8% by weight as the solid content. A coating solution for forming a transparent colored film.
R n -SiX 4-n (1 )
(In the formula, R is an unsubstituted or substituted hydrocarbon group having 1 to 10 carbon atoms, and may be the same or different from each other. X: an alkoxy group having 1 to 4 carbon atoms or a silanol group) , Halogen, hydrogen, n: an integer of 0 to 3)
さらに少なくとも波長480〜500nmの範囲の光を吸収する界面活性剤処理有機系顔料(B)を含み、該界面活性剤処理有機系顔料(B)の平均粒子径が5〜60nmの範囲にあり、塗布液中の濃度が固形分として0.0001〜1.8重量%の範囲にあることを特徴とする請求項12に記載の透明性着色膜形成用塗布液。 Further , it contains a surfactant-treated organic pigment (B) that absorbs at least light having a wavelength in the range of 480 to 500 nm, and the surfactant-treated organic pigment (B) has an average particle size in the range of 5 to 60 nm. The coating solution for forming a transparent colored film according to claim 12, wherein the concentration in the coating solution is in the range of 0.0001 to 1.8% by weight as a solid content. 前記界面活性剤処理有機系顔料(A)中の界面活性剤の処理量が、顔料(A)に対して、2〜30重量%の範囲にあることを特徴とする請求項12または13に記載の透明性着色膜形成用塗布液。   The processing amount of the surfactant in the surfactant-treated organic pigment (A) is in the range of 2 to 30% by weight with respect to the pigment (A). Coating liquid for forming a transparent colored film. 前記界面活性剤処理有機系顔料(B)中の界面活性剤の処理量が、顔料(B)に対して、含有量が2〜30重量%の範囲にあることを特徴とする請求項13に記載の透明性着色膜形成用塗布液。   The amount of the surfactant treated in the surfactant-treated organic pigment (B) is in the range of 2 to 30% by weight based on the pigment (B). The coating liquid for transparent coloring film formation of description. 前記有機系顔料(A)がキナクリドン系顔料であることを特徴とする請求項12に記載の透明性着色膜形成用塗布液。 The coating liquid for forming a transparent colored film according to claim 12, wherein the organic pigment (A) is a quinacridone pigment. 前記有機系顔料(B)がフタロシアニン系顔料であることを特徴とする請求項13に記載の透明性着色膜形成用塗布液。 The coating liquid for forming a transparent colored film according to claim 13, wherein the organic pigment (B) is a phthalocyanine pigment. 前記無機酸化物微粒子がSiO2、ZrO2、TiO2、Al23、ZnO、SnO2、Sb25、アンチモンドープ酸化錫、錫ドープ酸化インジウム、リンドープ酸化錫から選ばれる少なくとも1種であることを特徴とする請求項12〜17のいずれか1項に記載の透明性着色膜形成用塗布液。 The inorganic oxide fine particles, SiO 2, ZrO 2, TiO 2, Al 2 O 3, ZnO, SnO 2, Sb 2 O 5, antimony-doped tin oxide, tin-doped indium oxide, at least one selected from phosphorus-doped tin oxide The coating liquid for forming a transparent colored film according to any one of claims 12 to 17, wherein 前記表面処理無機酸化物微粒子の平均粒子径が5〜100nmの範囲にあることを特徴とする請求項12〜18のいずれか1項に記載の透明性着色膜形成用塗布液。 The coating liquid for forming a transparent colored film according to any one of claims 12 to 18, wherein an average particle size of the surface-treated inorganic oxide fine particles is in a range of 5 to 100 nm. 前記界面活性剤が、陽イオン性界面活性剤、陰イオン性界面活性剤、非イオン性界面活性剤から選ばれる少なくとも1種であることを特徴とする請求項12〜19のいずれか1項に記載の透明性着色膜形成用塗布液。   20. The surfactant according to any one of claims 12 to 19, wherein the surfactant is at least one selected from a cationic surfactant, an anionic surfactant, and a nonionic surfactant. The coating liquid for transparent coloring film formation of description. 前記界面活性剤が、エチレンオキサイド変性骨格を有する界面活性剤であることを特徴とする請求項20に記載の透明性着色膜形成用塗布液。   The coating liquid for forming a transparent colored film according to claim 20, wherein the surfactant is a surfactant having an ethylene oxide-modified skeleton.
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JP6119654B2 (en) * 2014-03-31 2017-04-26 マツダ株式会社 Transparent laminate and method for producing the same
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JP6072134B2 (en) * 2015-05-13 2017-02-01 レジノカラー工業株式会社 Polymerizable composition containing zirconium oxide particles and (meth) acrylates and method for producing the same
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