JP2013125691A - Power storage device and vehicle - Google Patents

Power storage device and vehicle Download PDF

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Publication number
JP2013125691A
JP2013125691A JP2011274653A JP2011274653A JP2013125691A JP 2013125691 A JP2013125691 A JP 2013125691A JP 2011274653 A JP2011274653 A JP 2011274653A JP 2011274653 A JP2011274653 A JP 2011274653A JP 2013125691 A JP2013125691 A JP 2013125691A
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electrode sheet
positive electrode
case
negative electrode
positioning member
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Atsushi Minamigata
厚志 南形
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Toyota Industries Corp
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

PROBLEM TO BE SOLVED: To ensure mutual positional accuracy of a positive electrode, a negative electrode and a separator not only during assemblage of an electrode body but also after the electrode body is housed in a battery case, and to laminate the positive electrode, the negative electrode and the separator in a shorter time when compared with a case where a positioning member is not used.SOLUTION: In a secondary battery 10, an electrode body 11 is housed in a battery case 12. The electrode body 11 is configured by laminating a plurality of positive electrode sheets 13 and a plurality of negative electrode sheets 14 alternately, in a state where a sheet-like separator 15 exists between the positive electrode sheet 13 and the negative electrode sheet 14. Holes 13d, 14d, 15a are formed, respectively, in the positive electrode sheet 13, the negative electrode sheet 14 and the separator 15, which are thereby housed in the battery case 12 while being positioned by means of a positioning member 21 penetrating the holes 13d, 14d, 15a.

Description

本発明は、蓄電装置及び車両に係り、詳しくは複数の正極シート及び複数の負極シートが、正極シートと負極シートとの間にシート状のセパレータが存在する状態で交互に積層されて構成された電極体が、ケース内に収容された二次電池やキャパシタのような蓄電装置及びその蓄電装置が搭載された車両に関する。   The present invention relates to a power storage device and a vehicle, and more specifically, a plurality of positive electrode sheets and a plurality of negative electrode sheets are alternately stacked in a state where a sheet-like separator exists between the positive electrode sheet and the negative electrode sheet. The present invention relates to a power storage device such as a secondary battery or a capacitor housed in a case, and a vehicle on which the power storage device is mounted.

積層型の電極体を有する二次電池として、電池ケース内に電解液とともに電極体が収容された構成のものがある。一般に、電極体は電池ケースの外部で、複数の正極シート、複数の負極シート及びセパレータが積層された後、電池ケース内に収容される。従来の積層機で電極シート及びセパレータの積層を行う場合、積層精度を要するために積層に時間がかかるという問題がある。また、積層中に徐々に電極シートとセパレータの位置がずれるという問題もある。また、二次電池に限らず、キャパシタにおいても同様な問題がある。   As a secondary battery having a stacked electrode body, there is a structure in which an electrode body is accommodated together with an electrolytic solution in a battery case. Generally, an electrode body is accommodated in a battery case after a plurality of positive electrode sheets, a plurality of negative electrode sheets, and a separator are laminated outside the battery case. When laminating electrode sheets and separators with a conventional laminating machine, there is a problem that it takes a long time for laminating because it requires laminating accuracy. In addition, there is a problem that the positions of the electrode sheet and the separator gradually shift during lamination. In addition to the secondary battery, the capacitor has the same problem.

積層中の位置ずれを防止するため、図10に示すように、積層用治具51として板状の治具本体52と、治具本体52の所定位置に立設された正極用のガイドピン53及び負極用のガイドピン54を備えたものを使用する方法が開示されている(特許文献1参照)。そして、正極61aの正極集電片62aに位置決め孔(図示せず)を形成し、負極61bの負極集電片62bに位置決め孔(図示せず)を形成し、位置決め孔がガイドピン53,54に挿通された状態で位置決めしつつ、正極61a、負極61b及びセパレータ63を積層して電極積層体(電極体)Dを製作している。また、積層完了後の電極積層体Dは、ガイドピン53,54から取り外されて、電池ケースに収容される。   In order to prevent misalignment during lamination, as shown in FIG. 10, a plate-like jig body 52 as a lamination jig 51 and a positive guide pin 53 erected at a predetermined position of the jig body 52. And the method of using the thing provided with the guide pin 54 for negative electrodes is disclosed (refer patent document 1). Then, a positioning hole (not shown) is formed in the positive electrode current collecting piece 62a of the positive electrode 61a, a positioning hole (not shown) is formed in the negative electrode current collecting piece 62b of the negative electrode 61b, and the positioning holes serve as the guide pins 53 and 54. The electrode laminate (electrode body) D is manufactured by laminating the positive electrode 61a, the negative electrode 61b, and the separator 63 while positioning in a state of being inserted into the electrode. In addition, the electrode laminate D after completion of lamination is removed from the guide pins 53 and 54 and accommodated in the battery case.

特開2002−270242号公報JP 2002-270242 A

特許文献1の方法ではガイドピン53,54は電極積層体Dの組立時には正極61a及び負極61bの位置決めに寄与する。しかし、電極積層体Dが組み立てられた後は、電極積層体Dがガイドピン53,54から取り外されるため、電極積層体Dを電池ケースまで移動させる場合や電池ケース内に収容する際及び電池ケース内に収容された後は、ガイドピン53,54は正極61a及び負極61bの位置決めに寄与しない。   In the method of Patent Document 1, the guide pins 53 and 54 contribute to the positioning of the positive electrode 61a and the negative electrode 61b when the electrode laminate D is assembled. However, after the electrode laminate D is assembled, the electrode laminate D is removed from the guide pins 53 and 54. Therefore, when the electrode laminate D is moved to the battery case or when it is accommodated in the battery case, the battery case After being accommodated in the guide pins 53 and 54, they do not contribute to the positioning of the positive electrode 61a and the negative electrode 61b.

本発明は、前記の問題に鑑みてなされたものであって、その目的は、電極体の組立時に限らず、電極体がケース内に収容された後も、正極、負極及びセパレータの相互の位置関係の精度を確保することができ、しかも、位置決め部材を使用しない場合に比べて、短時間で正極、負極及びセパレータの積層が可能な蓄電装置を提供することにある。また、他の目的はその蓄電装置を搭載した車両を提供することにある。   The present invention has been made in view of the above problems, and its purpose is not limited to the assembly of the electrode body, and the positions of the positive electrode, the negative electrode, and the separator after the electrode body is accommodated in the case. It is an object of the present invention to provide a power storage device that can ensure the accuracy of the relationship and can stack the positive electrode, the negative electrode, and the separator in a shorter time than when no positioning member is used. Another object is to provide a vehicle equipped with the power storage device.

前記の目的を達成するため、請求項1に記載の発明は、複数の正極シート及び複数の負極シートが、前記正極シートと前記負極シートとの間にシート状のセパレータが存在する状態で交互に積層されて構成された電極体が、ケース内に収容された蓄電装置であって、前記正極シート、前記負極シート及び前記セパレータにはそれぞれ孔が形成され、それぞれの前記孔を貫通した位置決め部材により前記ケース内に位置決めされた状態で収容されている。   In order to achieve the above object, the invention according to claim 1 is characterized in that a plurality of positive electrode sheets and a plurality of negative electrode sheets are alternately arranged in a state in which a sheet-like separator exists between the positive electrode sheet and the negative electrode sheet. The electrode body configured by stacking is a power storage device housed in a case, and a hole is formed in each of the positive electrode sheet, the negative electrode sheet, and the separator, and a positioning member that penetrates each of the holes. It is accommodated in a state of being positioned in the case.

位置決め部材は、ケースのケース本体や蓋体に設けても、あるいはケースとは別体に形成されてもよい。この発明の蓄電装置を構成する電極体は、正極シート、負極シート及びセパレータにそれぞれ形成された孔が位置決め部材に挿通された状態で正極シート、負極シート及びセパレータを積層することによりそれらが位置決めされた状態で積層されるため、位置決め部材を使用しない場合に比べて短時間で正極、負極及びセパレータの積層が可能になる。また、電極体の組立時に限らず、電極体がケース内に収容された後も、位置決め部材の存在により正極、負極及びセパレータの相互の位置関係の精度を確保することができる。   The positioning member may be provided on the case body or lid of the case, or may be formed separately from the case. The electrode body constituting the power storage device of the present invention is positioned by laminating the positive electrode sheet, the negative electrode sheet, and the separator in a state where the holes formed in the positive electrode sheet, the negative electrode sheet, and the separator are inserted into the positioning member, respectively. Therefore, the positive electrode, the negative electrode, and the separator can be stacked in a shorter time than when the positioning member is not used. Further, not only when the electrode body is assembled, but also after the electrode body is accommodated in the case, the accuracy of the positional relationship among the positive electrode, the negative electrode, and the separator can be ensured by the presence of the positioning member.

請求項2に記載の発明は、請求項1に記載の発明において、前記位置決め部材は、前記ケースのケース本体とは別体に構成されている。ここで、「ケース本体」とは、ケースの電極体を収容する部分を意味する。また、「別体」とは、電極体を組み立てた後に溶接等によりケースに接合されているものも含む。   According to a second aspect of the present invention, in the first aspect of the present invention, the positioning member is configured separately from the case main body of the case. Here, the “case body” means a portion that accommodates the electrode body of the case. The “separate body” includes those that are joined to the case by welding or the like after the electrode body is assembled.

位置決め部材をケースのケース本体に設けた場合は、電極体の組立時にケース本体の側壁に囲まれた位置に正極シート、負極シート及びセパレータを積層するため、側壁に囲まれていない場合に比べて積層作業がし難い。しかし、この発明では、位置決め部材は、ケースのケース本体とは別体に構成されているため、正極シート、負極シート及びセパレータを積層する際に、ケース本体の側壁が積層作業に影響せず、積層作業が容易になる。   When the positioning member is provided on the case body of the case, the positive electrode sheet, the negative electrode sheet, and the separator are stacked at a position surrounded by the side wall of the case body when the electrode body is assembled. Lamination work is difficult. However, in this invention, since the positioning member is configured separately from the case main body of the case, when laminating the positive electrode sheet, the negative electrode sheet and the separator, the side wall of the case main body does not affect the laminating operation, Lamination work becomes easy.

請求項3に記載の発明は、請求項1又は請求項2に記載の発明において、前記位置決め部材は棒状をしており、前記ケースのケース本体には、前記位置決め部材の延びる方向に開口部が形成され、前記開口部を覆う蓋体は前記ケース本体内に収容された前記電極体における積層方向と直交する方向における外面に当接した状態で前記開口部を覆うように前記ケース本体に固定されている。   The invention according to claim 3 is the invention according to claim 1 or 2, wherein the positioning member has a rod shape, and the case main body of the case has an opening in the extending direction of the positioning member. A lid that is formed and covers the opening is fixed to the case main body so as to cover the opening while being in contact with an outer surface in a direction orthogonal to the stacking direction of the electrode body housed in the case main body. ing.

電極体を構成する正極シート、負極シート及びセパレータは積層方向に圧縮された状態でケース内に収容されている方が、蓄電装置の体積エネルギー密度が大きくなる。この発明では、電極体は棒状の位置決め部材の延びる方向、即ち正極シート等の積層方向に移動させてケース本体内に収容することができるため、収容された状態で正極シート等を押圧して圧縮することが容易となる。また、蓋体が電極体を構成する正極シート等の積層方向と直交する方向における外面に当接した状態で、ケース本体の開口部を覆うようにケース本体に固定されているため、蓋体で電極体を押圧して、その状態で蓋体をケース本体に固定することができ、電極体の正極シート等を押圧して圧縮することがより容易となる。   When the positive electrode sheet, the negative electrode sheet, and the separator constituting the electrode body are accommodated in the case in a compressed state in the stacking direction, the volume energy density of the power storage device is increased. In this invention, since the electrode body can be accommodated in the case body by moving in the direction in which the rod-shaped positioning member extends, that is, in the stacking direction of the positive electrode sheet or the like, the positive electrode sheet or the like is pressed and compressed in the accommodated state. Easy to do. In addition, since the lid is fixed to the case body so as to cover the opening of the case body in a state in which the lid is in contact with the outer surface in the direction orthogonal to the stacking direction of the positive electrode sheet or the like constituting the electrode body, By pressing the electrode body, the lid body can be fixed to the case body in that state, and it becomes easier to press and compress the positive electrode sheet or the like of the electrode body.

請求項4に記載の発明は、請求項1〜請求項3のいずれか一項に記載の発明において、前記蓄電装置はリチウムイオン二次電池であり、前記正極シートの面積が前記負極シートの面積より小さくなるように前記正極シート及び前記負極シートに前記孔が形成されている。   The invention according to claim 4 is the invention according to any one of claims 1 to 3, wherein the power storage device is a lithium ion secondary battery, and an area of the positive electrode sheet is an area of the negative electrode sheet. The holes are formed in the positive electrode sheet and the negative electrode sheet so as to be smaller.

正極シート及び負極シートに形成された孔の周囲において、正極シートの活物質層の面積と負極シートの活物質層の面積が同じであればよいが、孔を形成する際の活物質の脱落や寸法精度等が原因で、負極の活物質層の面積が正極の活物質層の面積より小さくなる虞もある。負極の活物質層の面積が小さくなると、負極の活物質層にリチウムが析出する状態になり、好ましくない。しかし、この発明では、正極シート及び負極シートに形成された孔は、正極シートの面積が負極シートの面積より小さくなるように形成されているため、孔を形成する際の活物質の脱落や寸法精度等が原因で、負極の活物質層の面積が正極の活物質層の面積より小さくなる虞がない。   The area of the active material layer of the positive electrode sheet and the area of the active material layer of the negative electrode sheet may be the same around the holes formed in the positive electrode sheet and the negative electrode sheet. Due to dimensional accuracy, the area of the active material layer of the negative electrode may be smaller than the area of the active material layer of the positive electrode. If the area of the active material layer of the negative electrode is reduced, lithium is deposited on the active material layer of the negative electrode, which is not preferable. However, in the present invention, the holes formed in the positive electrode sheet and the negative electrode sheet are formed so that the area of the positive electrode sheet is smaller than the area of the negative electrode sheet. There is no possibility that the area of the active material layer of the negative electrode is smaller than the area of the active material layer of the positive electrode due to accuracy or the like.

請求項5に記載の発明は、請求項1〜請求項4のいずれか一項に記載の蓄電装置が搭載された車両である。したがって、この発明の車両は請求項1〜請求項4のいずれか一項に記載の蓄電装置の効果が得られる。   The invention according to claim 5 is a vehicle in which the power storage device according to any one of claims 1 to 4 is mounted. Therefore, the vehicle of the present invention can achieve the effect of the power storage device according to any one of claims 1 to 4.

請求項1〜請求項4に記載の発明によれば、電極体の組立時に限らず、電極体がケース内に収容された後も、正極、負極及びセパレータの相互の位置関係の精度を確保することができ、しかも、位置決め部材を使用しない場合に比べて、短時間で正極、負極及びセパレータの積層が可能な蓄電装置を提供することができる。また、請求項5に記載の発明によれば、前記蓄電装置を搭載した車両を提供することができる。   According to the first to fourth aspects of the invention, not only when the electrode body is assembled, but also after the electrode body is accommodated in the case, the accuracy of the positional relationship among the positive electrode, the negative electrode, and the separator is ensured. In addition, it is possible to provide a power storage device in which the positive electrode, the negative electrode, and the separator can be stacked in a shorter time than in the case where the positioning member is not used. Moreover, according to the invention of Claim 5, the vehicle carrying the said electrical storage apparatus can be provided.

(a)は第1の実施形態の二次電池の断面図、(b)は(a)のA−A線断面図、(c)は負極シート及びセパレータに形成された孔の形状を示す模式図、(d)は正極シートに形成された孔の形状を示す模式図、(e)は正極シート及び負極シートの詳細を示す模式図。(A) is sectional drawing of the secondary battery of 1st Embodiment, (b) is AA sectional view taken on the line of (a), (c) is a model which shows the shape of the hole formed in the negative electrode sheet and the separator. FIG. 4D is a schematic diagram illustrating the shape of holes formed in the positive electrode sheet, and FIG. 4E is a schematic diagram illustrating details of the positive electrode sheet and the negative electrode sheet. ケース本体、電極体及び蓋体の概略分解斜視図。The schematic exploded perspective view of a case main body, an electrode body, and a lid. 電極体を組み立てる場合の位置決め部材の配置を示す概略斜視図。The schematic perspective view which shows arrangement | positioning of the positioning member in the case of assembling an electrode body. (a)は電極体がケース本体に収容される途中の状態を示す模式断面図、(b)は蓋体を取り付けた状態の模式断面図。(A) is a schematic cross section which shows the state in the middle of the electrode body being accommodated in a case main body, (b) is a schematic cross section of the state which attached the cover body. 第2の実施形態の二次電池の蓋体の斜視図。The perspective view of the cover body of the secondary battery of 2nd Embodiment. 電極体がケース本体に収容された状態を示す模式断面図。The schematic cross section which shows the state in which the electrode body was accommodated in the case main body. (a)は第3の実施形態の二次電池の断面図、(b)は電極体がケース本体に収容される途中の状態を示す模式断面図。(A) is sectional drawing of the secondary battery of 3rd Embodiment, (b) is a schematic cross section which shows the state in the middle of the electrode body being accommodated in a case main body. 同じく蓋体がケース本体に固定された状態を示す模式断面図。The schematic cross section which shows the state by which the cover body was similarly fixed to the case main body. (a),(b)は別の実施形態の孔の形状を示す模式図。(A), (b) is a schematic diagram which shows the shape of the hole of another embodiment. 従来技術の断面図。Sectional drawing of a prior art.

(第1の実施形態)
以下、本発明をリチウムイオン二次電池に具体化した第1の実施形態を図1〜図4にしたがって説明する。
(First embodiment)
A first embodiment in which the present invention is embodied in a lithium ion secondary battery will be described below with reference to FIGS.

図1(a),(b)に示すように、蓄電装置としての二次電池10は、電極体11が、ケースとしての電池ケース12内に収容されている。電極体11は、複数の正極シート13及び複数の負極シート14が、正極シート13と負極シート14との間にシート状のセパレータ15が存在する状態で交互に積層されて構成されている。   As shown in FIGS. 1A and 1B, a secondary battery 10 as a power storage device has an electrode body 11 housed in a battery case 12 as a case. The electrode body 11 is configured by alternately laminating a plurality of positive electrode sheets 13 and a plurality of negative electrode sheets 14 with a sheet-like separator 15 between the positive electrode sheet 13 and the negative electrode sheet 14.

図1(e)に示すように、正極シート13は金属製の集電体13aとその両面に形成された活物質層13bとで構成されている。負極シート14は金属製の集電体14aとその両面に形成された活物質層14bとで構成されている。集電体13aは略矩形状に形成され、活物質層13bが形成されていない活物質非塗布部13cが矩形の一部から膨出するように形成されている。集電体14aも略矩形状に形成され、活物質層14bが形成されていない活物質非塗布部14cが矩形の一部から膨出するように形成されている。   As shown in FIG.1 (e), the positive electrode sheet 13 is comprised by the metal electrical power collector 13a and the active material layer 13b formed in the both surfaces. The negative electrode sheet 14 includes a metal current collector 14a and an active material layer 14b formed on both surfaces thereof. The current collector 13a is formed in a substantially rectangular shape, and is formed so that an active material non-applied portion 13c in which the active material layer 13b is not formed bulges out from a part of the rectangle. The current collector 14a is also formed in a substantially rectangular shape, and is formed so that the active material non-applied portion 14c in which the active material layer 14b is not formed bulges out from a part of the rectangle.

図1(a)に示すように、電極体11は、活物質非塗布部13cに正極用集電端子16が溶接で電気的に接続され、活物質非塗布部14cに負極用集電端子17が溶接で電気的に接続されている。また、正極用集電端子16は二次電池10の正極端子18に固定されて正極端子18に電気的に接続され、負極用集電端子17は二次電池10の負極端子19に固定されて負極端子19に電気的に接続されている。そして、電極体11は電池ケース12に注入された電解液20と共に二次電池10を構成する。   As shown in FIG. 1A, in the electrode body 11, the positive electrode current collector terminal 16 is electrically connected to the active material non-applied portion 13c by welding, and the negative electrode current collector terminal 17 is connected to the active material non-applied portion 14c. Are electrically connected by welding. The positive current collector terminal 16 is fixed to the positive terminal 18 of the secondary battery 10 and is electrically connected to the positive terminal 18, and the negative current collector terminal 17 is fixed to the negative terminal 19 of the secondary battery 10. It is electrically connected to the negative terminal 19. The electrode body 11 constitutes the secondary battery 10 together with the electrolytic solution 20 injected into the battery case 12.

なお、図1(a),(b)は二次電池10の構成を分かり易くするため模式的に描いたものであり、実際は、正極シート13及び負極シート14の枚数は数十枚である。また、図1(a),(b)では活物質層13b,14bの図示を省略している。   1A and 1B are schematically drawn to make the configuration of the secondary battery 10 easy to understand. Actually, the number of the positive electrode sheets 13 and the negative electrode sheets 14 is several tens. In FIGS. 1A and 1B, the active material layers 13b and 14b are not shown.

正極シート13、負極シート14及びセパレータ15にはそれぞれ孔13d,14d,15aが形成され、それぞれの孔13d,14d,15aを貫通した位置決め部材21により電池ケース12内に位置決めされた状態で収容されている。位置決め部材21は棒状に形成されている。   The positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are formed with holes 13d, 14d, and 15a, respectively, and are accommodated in a state of being positioned in the battery case 12 by a positioning member 21 that passes through the holes 13d, 14d, and 15a. ing. The positioning member 21 is formed in a rod shape.

図1(b)、図2に示すように、電池ケース12は、ケース本体22と、ケース本体22の二つの開口部22a,22bを覆う二つの蓋体23a,23bとを備えている。第1の開口部22aは、電極体11を位置決め部材21の延びる方向に移動させてケース本体22に収容可能な位置に形成されている。具体的には、第1の開口部22aは位置決め部材21の延びる方向に形成され、開口部22aを覆う蓋体23aはケース本体22内に収容された電極体11における積層方向と直交する方向における外面に当接した状態で開口部22aを覆うようにケース本体22に固定されている。   As shown in FIGS. 1B and 2, the battery case 12 includes a case main body 22 and two lids 23 a and 23 b that cover the two openings 22 a and 22 b of the case main body 22. The first opening 22 a is formed at a position where the electrode body 11 can be accommodated in the case body 22 by moving the electrode body 11 in the extending direction of the positioning member 21. Specifically, the first opening 22 a is formed in the direction in which the positioning member 21 extends, and the lid 23 a covering the opening 22 a is in a direction orthogonal to the stacking direction of the electrode body 11 accommodated in the case body 22. It is fixed to the case body 22 so as to cover the opening 22a while being in contact with the outer surface.

第2の開口部22bは電極体11がケース本体22内に収容された状態で、活物質非塗布部13c及び活物質非塗布部14cと対向する位置に形成されている。開口部22bを覆う蓋体23bには正極端子18及び負極端子19が固定されている。   The second opening 22b is formed at a position facing the active material non-applied portion 13c and the active material non-applied portion 14c in a state where the electrode body 11 is accommodated in the case main body 22. A positive electrode terminal 18 and a negative electrode terminal 19 are fixed to the lid body 23b covering the opening 22b.

位置決め部材21は、電池ケース12のケース本体22外で電極体11を組み立て可能に構成されている。詳述すると、位置決め部材21はケース本体22及び蓋体23aとは別体に形成されている。一方、ケース本体22の開口部22aと対向する側壁及び蓋体23aには、電極体11がケース本体22の所定位置に収容された状態で、位置決め部材21の端部を収容可能な位置に凹部22c,23cが形成されている。そして、位置決め部材21は、蓋体23aが開口部22aを覆う状態でケース本体22に固定された状態で、位置決め部材21の先端がケース本体22の凹部22cに係合し、基端が蓋体23aの凹部23cに係合した状態で電池ケース12に固定されている。   The positioning member 21 is configured such that the electrode body 11 can be assembled outside the case body 22 of the battery case 12. More specifically, the positioning member 21 is formed separately from the case main body 22 and the lid body 23a. On the other hand, the side wall and the lid 23a facing the opening 22a of the case main body 22 are recessed at a position where the end of the positioning member 21 can be stored in a state where the electrode body 11 is stored at a predetermined position of the case main body 22. 22c and 23c are formed. The positioning member 21 is fixed to the case main body 22 with the lid 23a covering the opening 22a, the distal end of the positioning member 21 is engaged with the recess 22c of the case main body 22, and the proximal end is the lid. It is being fixed to the battery case 12 in the state engaged with the recessed part 23c of 23a.

位置決め部材21は、断面形状が非円形(この実施形態では長円形)で太さが一様な真っ直ぐな棒状に形成されている。位置決め部材21は、正極シート13及び負極シート14との電気的絶縁を確保する必要があるため、金属製の棒材の表面に絶縁被膜が形成されている。   The positioning member 21 is formed in a straight bar shape having a non-circular cross section (in this embodiment, an oval shape) and a uniform thickness. Since the positioning member 21 needs to ensure electrical insulation from the positive electrode sheet 13 and the negative electrode sheet 14, an insulating coating is formed on the surface of a metal bar.

負極シート14及びセパレータ15にそれぞれ形成された孔14d,15aは、位置決め部材21の断面と同じ非円形(この実施形態では長円形)に形成されている。図1(c),(d)に示すように、正極シート13の孔13dは、負極シート14の孔14dと同じ大きさの長円形の周の一部に沿って複数の切り欠き24が形成されており、厳密に言うと長円形ではない。そして、孔13dの周囲に切り欠き24が形成されていることにより、正極シート13の面積は負極シート14の面積より小さくなるように形成されている。即ち、正極シート13の面積が負極シート14の面積より小さくなるように、正極シート13及び負極シート14に孔13d,14dが形成されている。   The holes 14d and 15a formed in the negative electrode sheet 14 and the separator 15 are formed in the same non-circular shape (oval shape in this embodiment) as the cross section of the positioning member 21. As shown in FIGS. 1C and 1D, the hole 13 d of the positive electrode sheet 13 is formed with a plurality of notches 24 along a part of an oval circumference having the same size as the hole 14 d of the negative electrode sheet 14. Strictly speaking, it is not oval. The notch 24 is formed around the hole 13d so that the area of the positive electrode sheet 13 is smaller than the area of the negative electrode sheet 14. That is, the holes 13 d and 14 d are formed in the positive electrode sheet 13 and the negative electrode sheet 14 so that the area of the positive electrode sheet 13 is smaller than the area of the negative electrode sheet 14.

次に前記のように構成された二次電池の製造方法を説明する。
正極シート13及び負極シート14は、金属箔製の帯状材料に正極用活物質あるいは負極用活物質の塗布と、活物質非塗布部13cあるいは活物質非塗布部14cの形成と、孔13d,14dの形成が行われた後、それぞれ1枚ずつ所定の大きさに切り離されて形成される。孔13d,14dの形成は、型で打ち抜くことにより行われる。また、セパレータ15は、帯状のセパレータ材料に孔15aが所定間隔で形成された後、それぞれ1枚ずつ所定の大きさに切り離されて形成される。
Next, a method for manufacturing the secondary battery configured as described above will be described.
The positive electrode sheet 13 and the negative electrode sheet 14 are formed by applying a positive electrode active material or a negative electrode active material to a metal foil strip, forming an active material non-applied portion 13c or an active material non-applied portion 14c, and holes 13d and 14d. Are formed, and each sheet is cut into a predetermined size. The holes 13d and 14d are formed by punching with a mold. In addition, the separator 15 is formed by forming the holes 15a in the strip-shaped separator material at a predetermined interval, and then separating each of them into a predetermined size.

電極体11を組み立てる場合は、図3に示すように、支持板25上に位置決め部材21を立設した状態で正極シート13、負極シート14及びセパレータ15を、孔13d,14d,15aが位置決め部材21に挿通される状態で積層する。このとき、位置決め部材21は断面形状が非円形の真っ直ぐな棒材で形成されているため、正極シート13、負極シート14及びセパレータ15は、位置決め部材21によって、回転方向の位置ずれもない状態に位置決めされて積層される。   When assembling the electrode body 11, as shown in FIG. 3, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are positioned in the state where the positioning member 21 is erected on the support plate 25, and the holes 13d, 14d, and 15a are positioning members. Laminate in a state of being inserted through 21. At this time, since the positioning member 21 is formed of a straight bar having a non-circular cross-sectional shape, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are not displaced by the positioning member 21 in the rotational direction. Positioned and stacked.

正極シート13、負極シート14及びセパレータ15は、平坦ではなく多少湾曲しているため、単に積層した状態では正極シート13とセパレータ15及びセパレータ15と負極シート14との間に隙間が存在する状態になり、電極体11が嵩高になる。そのため、積層途中や電極体11を構成する所定枚数の積層が終了した状態で積層体を圧縮して電極体11の積層厚さを小さくするのが好ましい。   Since the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are not flat but slightly curved, there is a gap between the positive electrode sheet 13 and the separator 15, and between the separator 15 and the negative electrode sheet 14 when simply stacked. Thus, the electrode body 11 becomes bulky. For this reason, it is preferable to reduce the thickness of the electrode body 11 by compressing the multilayer body in the middle of the lamination or after the predetermined number of layers constituting the electrode body 11 have been completed.

正極シート13、負極シート14及びセパレータ15の積層終了後、正極シート13の活物質非塗布部13cに正極用集電端子16を溶接で接続し、負極シート14の活物質非塗布部14cに負極用集電端子17を溶接で接続する。次に位置決め部材21を電極体11と共に支持板25から取り外して、ケース本体22に収容する。このとき、電極体11の移動中に正極シート13、負極シート14及びセパレータ15の一部が位置決め部材21から外れるのを防止するため、電極体11を図示しない挟持部材で挟持した状態でケース本体22の第1の開口部22aと対応する位置まで移動させるのが好ましい。   After the lamination of the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15, the positive electrode current collector terminal 16 is connected to the active material non-applied part 13c of the positive electrode sheet 13 by welding, and the negative electrode is connected to the active material non-applied part 14c of the negative electrode sheet 14 The current collecting terminal 17 is connected by welding. Next, the positioning member 21 is removed from the support plate 25 together with the electrode body 11 and accommodated in the case main body 22. At this time, in order to prevent the positive electrode sheet 13, the negative electrode sheet 14, and a part of the separator 15 from being detached from the positioning member 21 during the movement of the electrode body 11, the case body is held in a state where the electrode body 11 is held by a holding member (not shown). It is preferable to move to a position corresponding to the first opening 22a of 22.

図4(a)に示すように、電極体11は、位置決め部材21の一端がケース本体22に形成された凹部22cと対向する状態で開口部22aからケース本体22内に挿入される。そして、電極体11を挟持している挟持部材を、開口部22bを経て電極体11から取り外した後、図4(b)に示すように、位置決め部材21の一端がケース本体22の凹部22cに係合(嵌合)する状態で、電極体11をケース本体22内に収容する。次に蓋体23aをその凹部23cが位置決め部材21の他端と係合する状態で、第1の開口部22aを覆うようにケース本体22に固定する。   As shown in FIG. 4A, the electrode body 11 is inserted into the case body 22 from the opening 22 a in a state where one end of the positioning member 21 faces the recess 22 c formed in the case body 22. And after removing the clamping member which clamps the electrode body 11 from the electrode body 11 through the opening part 22b, as shown in FIG.4 (b), one end of the positioning member 21 becomes the recessed part 22c of the case main body 22. As shown in FIG. The electrode body 11 is accommodated in the case main body 22 in the engaged (fitted) state. Next, the lid 23 a is fixed to the case body 22 so as to cover the first opening 22 a in a state where the concave portion 23 c is engaged with the other end of the positioning member 21.

電極体11を構成する正極シート13、負極シート14及びセパレータ15は積層方向に圧縮された状態で電池ケース12内に収容されている方が、二次電池10の体積エネルギー密度が大きくなる。この実施形態では、電極体11は位置決め部材21の延びる方向、即ち正極シート13等の積層方向に移動させてケース本体22内に収容することができるため、収容された状態で正極シート13等を押圧して圧縮することが容易となる。また、蓋体23aはケース本体22内に収容された電極体11における積層方向と直交する方向における外面に当接した開口部22aを覆うようにケース本体22に固定されているため、蓋体23aで電極体11を押圧して、その状態で蓋体23aをケース本体22に固定することができ、電極体11の正極シート13等を押圧して圧縮することがより容易となる。   The volume energy density of the secondary battery 10 increases when the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 constituting the electrode body 11 are accommodated in the battery case 12 in a compressed state in the stacking direction. In this embodiment, since the electrode body 11 can be moved in the direction in which the positioning member 21 extends, i.e., in the stacking direction of the positive electrode sheet 13 and the like, and accommodated in the case body 22, the positive electrode sheet 13 and the like are accommodated in the accommodated state. It becomes easy to press and compress. Further, since the lid body 23a is fixed to the case body 22 so as to cover the opening 22a in contact with the outer surface in the direction orthogonal to the stacking direction of the electrode body 11 accommodated in the case body 22, the lid body 23a In this state, the lid body 23a can be fixed to the case main body 22 and the positive electrode sheet 13 and the like of the electrode body 11 can be pressed and compressed more easily.

次に図1(a),(b)に示すように、第2の開口部22bを覆う蓋体23bがケース本体22に取り付けられ、正極端子18に正極用集電端子16が固定され、負極端子19に負極用集電端子17が固定される。その後、ケース本体22内に電解液が注入されて二次電池10が完成する。   Next, as shown in FIGS. 1A and 1B, a lid body 23 b that covers the second opening 22 b is attached to the case body 22, the positive electrode current collector terminal 16 is fixed to the positive electrode terminal 18, and the negative electrode A negative electrode current collecting terminal 17 is fixed to the terminal 19. Thereafter, the electrolytic solution is injected into the case body 22 to complete the secondary battery 10.

二次電池10は種々の用途に使用されるが、例えば車両に搭載した状態でも使用される。
次に前記のように構成された二次電池10の作用を説明する。
Although the secondary battery 10 is used for various purposes, for example, it is also used in a state where it is mounted on a vehicle.
Next, the operation of the secondary battery 10 configured as described above will be described.

電極体11を構成する正極シート13、負極シート14及びセパレータ15は積層方向に圧縮された状態で電池ケース12内に収容されているため、二次電池10の体積エネルギー密度が大きくなる。   Since the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 constituting the electrode body 11 are accommodated in the battery case 12 in a compressed state in the stacking direction, the volume energy density of the secondary battery 10 is increased.

リチウムイオン電池の場合、正極シート13及び負極シート14に形成された孔13d,14dの周囲において、正極シート13の活物質層13bの面積と負極シート14の活物質層14bの面積が同じであればよい。しかし、孔13d,14dを形成する際の活物質の脱落や寸法精度等が原因で、負極シート14(負極)の活物質層14bの面積が正極シート13(正極)の活物質層13bの面積より小さくなる虞もある。負極シート14の活物質層14bの面積が小さくなると、負極シート14の活物質層14bにリチウムが析出する状態になり、好ましくない。しかし、正極シート13の面積が負極シート14の面積より小さくなるように正極シート13及び負極シート14に孔13d,14dが形成されている。そのため、孔13d,14dを形成する際の活物質の脱落や寸法精度等が原因で、負極シート14の活物質層14bの面積が正極シート13の活物質層13bの面積より小さくなる虞がなく、リチウムの析出が防止される。   In the case of a lithium ion battery, the area of the active material layer 13b of the positive electrode sheet 13 and the area of the active material layer 14b of the negative electrode sheet 14 are the same around the holes 13d and 14d formed in the positive electrode sheet 13 and the negative electrode sheet 14. That's fine. However, the area of the active material layer 14b of the negative electrode sheet 14 (negative electrode) is equal to the area of the active material layer 13b of the positive electrode sheet 13 (positive electrode) due to dropout of the active material and dimensional accuracy when forming the holes 13d and 14d. There is also a risk of becoming smaller. When the area of the active material layer 14b of the negative electrode sheet 14 is reduced, lithium is deposited on the active material layer 14b of the negative electrode sheet 14, which is not preferable. However, holes 13 d and 14 d are formed in the positive electrode sheet 13 and the negative electrode sheet 14 so that the area of the positive electrode sheet 13 is smaller than the area of the negative electrode sheet 14. Therefore, there is no possibility that the area of the active material layer 14b of the negative electrode sheet 14 is smaller than the area of the active material layer 13b of the positive electrode sheet 13 due to dropout or dimensional accuracy of the active material when forming the holes 13d and 14d. Lithium precipitation is prevented.

この実施形態によれば、以下に示す効果を得ることができる。
(1)二次電池10は電極体11が電池ケース12内に収容されており、電極体11は複数の正極シート13及び複数の負極シート14が、正極シート13と負極シート14との間にシート状のセパレータ15が存在する状態で交互に積層されて構成されている。正極シート13、負極シート14及びセパレータ15にはそれぞれ孔13d,14d,15aが形成され、それぞれの孔13d,14d,15aを貫通した位置決め部材21により電池ケース12内に位置決めされた状態で収容されている。そのため、二次電池10を構成する電極体11は、正極シート13、負極シート14及びセパレータ15にそれぞれ形成された孔13d,14d,15aが位置決め部材21に挿通された状態で正極シート13、負極シート14及びセパレータ15を積層することによりそれらが位置決めされた状態で積層される。したがって、位置決め部材21を使用しない場合に比べて、短時間で正極シート13、負極シート14及びセパレータ15の積層が可能なる。また、電極体11の組立時に限らず、電極体11が電池ケース12内に収容された後も、位置決め部材21の存在により正極シート13、負極シート14及びセパレータ15の相互の位置関係の精度を確保することができる。その結果、電極体11をケース本体22に収容する際に必要となるケース本体22の内面との隙間が小さくなり、デッドスペースが低減されて二次電池10の体積エネルギー密度(容量)が増加する。
According to this embodiment, the following effects can be obtained.
(1) In the secondary battery 10, the electrode body 11 is accommodated in the battery case 12, and the electrode body 11 includes a plurality of positive electrode sheets 13 and a plurality of negative electrode sheets 14 between the positive electrode sheet 13 and the negative electrode sheet 14. The sheet-like separators 15 are alternately stacked in the presence of the sheet-like separators 15. The positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are formed with holes 13d, 14d, and 15a, respectively, and are accommodated in a state of being positioned in the battery case 12 by a positioning member 21 that passes through the holes 13d, 14d, and 15a. ing. Therefore, the electrode body 11 constituting the secondary battery 10 includes the positive electrode sheet 13, the negative electrode sheet 14, and the negative electrode sheet 14, and the positive electrode sheet 13, the negative electrode sheet 15, and the negative electrode sheet 14, and the separator 15, with the holes 13 d, 14 d, 15 a inserted through the positioning member 21 By laminating the sheet 14 and the separator 15, the sheet 14 and the separator 15 are laminated in a positioned state. Therefore, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 can be stacked in a shorter time than when the positioning member 21 is not used. Further, not only when the electrode body 11 is assembled, but also after the electrode body 11 is accommodated in the battery case 12, the presence of the positioning member 21 increases the accuracy of the positional relationship among the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15. Can be secured. As a result, the gap between the electrode body 11 and the inner surface of the case main body 22 required when the electrode body 11 is accommodated in the case main body 22 is reduced, the dead space is reduced, and the volume energy density (capacity) of the secondary battery 10 is increased. .

(2)位置決め部材21は、電池ケース12のケース本体22とは別体に構成されている。したがって、正極シート13、負極シート14及びセパレータ15を積層する際に、ケース本体22の側壁が積層作業に影響せず、積層作業が容易になる。   (2) The positioning member 21 is configured separately from the case main body 22 of the battery case 12. Therefore, when laminating the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15, the side wall of the case body 22 does not affect the laminating operation, and the laminating operation is facilitated.

(3)位置決め部材21は棒状をしており、電池ケース12のケース本体22には、位置決め部材21の延びる方向に第1の開口部22aが形成され、第1の開口部22aを覆う蓋体23aはケース本体22内に収容された電極体11における積層方向と直交する方向における外面に当接した状態で、第1の開口部22aを覆うようにケース本体22に固定されている。そのため、電極体11はケース本体22内に収容された状態で正極シート13等が押圧されて圧縮されることが容易となる。また、蓋体23aで電極体11を押圧して、その状態で蓋体23aをケース本体22に固定することができ、電極体11の正極シート13等を押圧して圧縮した状態で電池ケース12内に収容することがより容易となる。   (3) The positioning member 21 has a rod shape, and the case main body 22 of the battery case 12 is formed with a first opening 22a in the extending direction of the positioning member 21 and covers the first opening 22a. 23a is in contact with the outer surface of the electrode body 11 accommodated in the case body 22 in the direction orthogonal to the stacking direction, and is fixed to the case body 22 so as to cover the first opening 22a. Therefore, it becomes easy for the electrode body 11 to be compressed by being pressed by the positive electrode sheet 13 or the like while being accommodated in the case main body 22. Moreover, the electrode body 11 can be pressed by the cover body 23a, and the cover body 23a can be fixed to the case main body 22 in this state, and the battery case 12 can be pressed in a state where the positive electrode sheet 13 or the like of the electrode body 11 is pressed and compressed. It becomes easier to accommodate inside.

(4)二次電池10はリチウムイオン電池であり、正極シート13の面積が負極シート14の面積より小さくなるように正極シート13及び負極シート14に孔13d,14dが形成されている。そのため、孔13d,14dを形成する際の活物質の脱落や寸法精度等が原因で、負極シート14の活物質層14bの面積が正極シート13の活物質層13bの面積より小さくなる虞がない。したがって、負極シート14の活物質層14bにリチウムが析出する状態になることが防止される。   (4) The secondary battery 10 is a lithium ion battery, and holes 13 d and 14 d are formed in the positive electrode sheet 13 and the negative electrode sheet 14 so that the area of the positive electrode sheet 13 is smaller than the area of the negative electrode sheet 14. Therefore, there is no possibility that the area of the active material layer 14b of the negative electrode sheet 14 is smaller than the area of the active material layer 13b of the positive electrode sheet 13 due to dropout of the active material or dimensional accuracy when forming the holes 13d and 14d. . Therefore, lithium is prevented from being deposited on the active material layer 14b of the negative electrode sheet 14.

(5)孔13d,14d,15aは非円形で、断面非円形の位置決め部材21により位置決めされている。したがって、回転方向の位置決めも行うことができ、円形の場合に比べて、位置決めの精度が高くなる。   (5) The holes 13d, 14d, and 15a are non-circular and are positioned by the positioning member 21 having a non-circular cross section. Therefore, positioning in the rotational direction can also be performed, and positioning accuracy is higher than in the case of a circular shape.

(6)位置決め部材21は金属製の棒材の表面に電気的絶縁性被膜が形成されている。したがって、位置決め部材21全体を電気的絶縁材で形成した場合に比べて熱伝導性が良くなり、電極体11を備えた二次電池10が使用されて発熱した場合に、放熱性が良くなる。また、位置決め部材21を同じ外径の筒状体で形成した場合に比べて、熱容量が大きくなり、同じ発熱の場合に温度上昇が小さくなる。   (6) The positioning member 21 has an electrically insulating coating formed on the surface of a metal bar. Therefore, the thermal conductivity is improved as compared with the case where the entire positioning member 21 is formed of an electrical insulating material, and the heat dissipation is improved when the secondary battery 10 including the electrode body 11 is used to generate heat. Moreover, compared with the case where the positioning member 21 is formed with a cylindrical body having the same outer diameter, the heat capacity is increased, and the temperature rise is reduced when the heat generation is the same.

(7)二次電池10を搭載した車両は、その二次電池10が有する効果を得ることができる。
(第2の実施形態)
次に、第2の実施形態を図5及び図6にしたがって説明する。この実施形態では、位置決め部材21が電池ケース12の蓋体23aに対して一体に、垂直に設けられている点が前記第1の実施形態と異なっている。第1の実施形態と同一部分は同一符号を付して詳しい説明を省略する。
(7) The vehicle equipped with the secondary battery 10 can obtain the effects of the secondary battery 10.
(Second Embodiment)
Next, a second embodiment will be described with reference to FIGS. This embodiment is different from the first embodiment in that the positioning member 21 is provided integrally and perpendicularly to the lid body 23a of the battery case 12. The same parts as those in the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

図5及び図6に示すように、位置決め部材21は蓋体23aのほぼ中央部において蓋体23aに対して垂直に突出するように形成されている。蓋体23aの位置決め部材21が突出する側と反対側の面は平坦に形成されている。この実施形態の電極体11は、図5に示すように、位置決め部材21が上向きに突出する状態に蓋体23aを図示しない台上に固定した状態で、正極シート13、負極シート14及びセパレータ15を、孔13d,14d,15aが位置決め部材21に挿通される状態で積層する。   As shown in FIGS. 5 and 6, the positioning member 21 is formed so as to protrude perpendicularly to the lid body 23 a at a substantially central portion of the lid body 23 a. The surface of the lid 23a opposite to the side from which the positioning member 21 projects is formed flat. As shown in FIG. 5, the electrode body 11 of this embodiment includes a positive electrode sheet 13, a negative electrode sheet 14, and a separator 15 in a state where the lid member 23 a is fixed on a table (not shown) so that the positioning member 21 protrudes upward. Are stacked in a state where the holes 13d, 14d, and 15a are inserted through the positioning member 21.

正極シート13、負極シート14及びセパレータ15の積層終了後、正極シート13の活物質非塗布部13c及び負極シート14の活物質非塗布部14cに、正極用集電端子16及び負極用集電端子17がそれぞれ溶接で接続された後、電極体11は蓋体23aと共に移動されて、ケース本体22に収容される。このとき、位置決め部材21が蓋体23aと一体のため、電極体11を図示しない挟持部材で挟持しなくても、電極体11の移動中に正極シート13、負極シート14及びセパレータ15の一部が位置決め部材21から外れるのを防止した状態でケース本体22の第1の開口部22aと対応する位置まで移動させることが容易になる。   After the lamination of the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15, the positive electrode current collector terminal 16 and the negative electrode current collector terminal are connected to the active material non-applied part 13 c of the positive electrode sheet 13 and the active material non-applied part 14 c of the negative electrode sheet 14. After the 17 is connected by welding, the electrode body 11 is moved together with the lid body 23 a and accommodated in the case body 22. At this time, since the positioning member 21 is integrated with the lid body 23a, a part of the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 is moved during the movement of the electrode body 11 without the electrode body 11 being clamped by a clamping member (not shown). Can be easily moved to a position corresponding to the first opening 22a of the case body 22 in a state in which it is prevented from coming off from the positioning member 21.

したがって、この実施形態によれば、前記第1の実施形態の(1)〜(5)の効果に加えて次の効果を得ることができる。
(8)位置決め部材21と蓋体23aが一体のため、部品点数が少なくなり、電極体11を組み立てる際、位置決め部材21を支持するための支持板25が不要になる。また、位置決め部材21に対する電極体11の組み立て、即ち正極シート13、負極シート14及びセパレータ15の積層が完了して電極体11が形成された後、蓋体23aを電極体11と共に移動して、位置決め部材21の一端(先端)をケース本体22の凹部22cに係合させる作業を行うと、蓋体23aはケース本体22の第1の開口部22aを覆う状態になる。そのため、電極体11の電池ケース12への収容及び固定作業が第1の実施形態に比べて簡単になる。
Therefore, according to this embodiment, in addition to the effects (1) to (5) of the first embodiment, the following effects can be obtained.
(8) Since the positioning member 21 and the lid body 23a are integrated, the number of parts is reduced, and the support plate 25 for supporting the positioning member 21 is not required when the electrode body 11 is assembled. Further, after the assembly of the electrode body 11 with respect to the positioning member 21, that is, the electrode body 11 is formed by completing the lamination of the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15, the lid body 23a is moved together with the electrode body 11, When the operation of engaging one end (tip) of the positioning member 21 with the concave portion 22 c of the case main body 22 is performed, the lid 23 a covers the first opening 22 a of the case main body 22. Therefore, the housing and fixing work of the electrode body 11 in the battery case 12 is simplified as compared with the first embodiment.

(第3の実施形態)
次に、第3の実施形態を図7及び図8にしたがって説明する。この実施形態では、位置決め部材21は、電池ケース12内に収容された状態で、その一端が電池ケース12の蓋体23aに固定される締結体としてのボルトに螺合された状態で電池ケース12に固定されている点が前記第1の実施形態と異なっている。第1の実施形態と同一部分は同一符号を付して詳しい説明を省略する。
(Third embodiment)
Next, a third embodiment will be described with reference to FIGS. In this embodiment, the positioning member 21 is housed in the battery case 12, and one end of the positioning member 21 is screwed into a bolt as a fastening body fixed to the lid body 23 a of the battery case 12. The point which is fixed to is different from the first embodiment. The same parts as those in the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

図7(a)に示すように、位置決め部材21の基端、即ちケース本体22の凹部22cと係合する先端と反対側の端部には雌ねじ部21aが形成されており、蓋体23aには21と対向する位置にボルト挿通孔26が形成されている。そして、ボルト挿通孔26にパッキン27が配置され、ボルト28がボルト挿通孔26を貫通した状態で雌ねじ部21aに螺合されて蓋体23aが位置決め部材21に固定されている。   As shown in FIG. 7 (a), a female thread portion 21a is formed at the base end of the positioning member 21, that is, the end opposite to the distal end that engages with the recess 22c of the case body 22, and the lid 23a has a female thread portion 21a. A bolt insertion hole 26 is formed at a position facing 21. A packing 27 is disposed in the bolt insertion hole 26, and the bolt 28 is screwed into the female screw portion 21 a while passing through the bolt insertion hole 26, so that the lid 23 a is fixed to the positioning member 21.

この構成の場合、電極体11の組み立て時には、位置決め部材21に位置決め部材21と断面形状が同じで、雌ねじ部21aに螺合する雄ねじ部(図示せず)を有する延長部材29を連結した状態で使用して、正極シート13、負極シート14及びセパレータ15の積層を行う。位置決め部材21及び延長部材29の合計長さは、電極体11を構成するのに必要な数の正極シート13、負極シート14及びセパレータ15を圧縮せずに積層した場合の厚さより十分長くなっている。そのため、積層途中で圧縮を行わずに積層して、積層が完了した状態で、電極体11を位置決め部材21と共に支持板25から取り外しても、積層されている正極シート13等が電極体11と位置決め部材21の移動途中に位置決め部材21から脱落することが回避される。   In the case of this configuration, when assembling the electrode body 11, the positioning member 21 has the same cross-sectional shape as the positioning member 21, and an extension member 29 having a male screw portion (not shown) that is screwed into the female screw portion 21 a is connected. In use, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are stacked. The total length of the positioning member 21 and the extending member 29 is sufficiently longer than the thickness of the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15, which are necessary for constituting the electrode body 11, without being compressed. Yes. Therefore, even if the electrode body 11 is removed from the support plate 25 together with the positioning member 21 in a state where the lamination is completed without being compressed in the middle of the lamination, the laminated positive electrode sheet 13 and the like are It is avoided that the positioning member 21 falls off from the positioning member 21 during the movement.

図7(b)に示すように、位置決め部材21の先端がケース本体22の凹部22cに係合した状態では、延長部材29がケース本体22から突出した状態にある。この状態から蓋体23aのボルト挿通孔26を延長部材29が貫通する状態で、正極シート13等を押圧するように蓋体23aを移動させ、図8に示すように、蓋体23aがケース本体22に当接する位置まで移動させる。次に延長部材29を位置決め部材21から取り外す。そして、ボルト挿通孔26にパッキン27を挿入した状態でボルト28を雌ねじ部21aに螺合させて、位置決め部材21を蓋体23aに固定する。   As shown in FIG. 7B, the extension member 29 protrudes from the case body 22 when the tip of the positioning member 21 is engaged with the recess 22 c of the case body 22. From this state, with the extension member 29 passing through the bolt insertion hole 26 of the lid body 23a, the lid body 23a is moved so as to press the positive electrode sheet 13 and the like, and as shown in FIG. It is moved to a position where it abuts 22. Next, the extension member 29 is removed from the positioning member 21. Then, with the packing 27 inserted in the bolt insertion hole 26, the bolt 28 is screwed into the female screw portion 21a, and the positioning member 21 is fixed to the lid body 23a.

この実施形態では第1の実施形態の(1)〜(6)の効果に加えて次の効果を得ることができる。
(9)位置決め部材21に延長部材29を連結した状態で電極体11の組み立てを行うことができる。そのため、正極シート13、負極シート14及びセパレータ15の積層途中で圧縮を行わずに積層しても、積層完了後、位置決め部材21と共に電極体11を移動させる際、積層されている正極シート13等が位置決め部材21から脱落する虞がなく、挟持部材を用いなくても移動を簡単に行うことができる。また、挟持部材を取り外す作業が不要になると共に、正極シート13、負極シート14及びセパレータ15の積層枚数を増やすことが容易になる。
In this embodiment, the following effects can be obtained in addition to the effects (1) to (6) of the first embodiment.
(9) The electrode body 11 can be assembled with the extension member 29 connected to the positioning member 21. Therefore, even if the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are laminated without being compressed, when the electrode body 11 is moved together with the positioning member 21 after the lamination is completed, the laminated positive electrode sheets 13, etc. Can be removed from the positioning member 21 and can be easily moved without using a clamping member. In addition, it is not necessary to remove the clamping member, and it is easy to increase the number of stacked positive electrode sheets 13, negative electrode sheets 14, and separators 15.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
○ 正極シート等をその回動も規制した状態で位置決めを行うための位置決め部材21の断面形状は長円状に限らず、非円形であればよく、例えば、楕円形や多角形であってもよい。多角形のように角部が有る場合は、それに対応する孔14d,15aの形状は角部から亀裂が入るのを防止するため、例えば、図9(a)に示すように、多角形の角部の位置に円弧部を設けるのが好ましい。
The embodiment is not limited to the above, and may be embodied as follows, for example.
○ The cross-sectional shape of the positioning member 21 for positioning the positive electrode sheet or the like in a state in which the rotation of the positive electrode sheet is restricted is not limited to an oval shape, and may be a non-circular shape, for example, an elliptical shape or a polygonal shape. Good. When there are corners such as polygons, the shapes of the holes 14d and 15a corresponding to the corners prevent polygons from cracking. For example, as shown in FIG. It is preferable to provide an arc portion at the position of the portion.

○ 孔14d,15aの形状は円形であってもよい。その場合、正極シート13の孔13dは、例えば、図9(b)に示すように、円の周囲に凹部(切り欠き)が設けられた形状になる。   The shape of the holes 14d and 15a may be circular. In this case, the hole 13d of the positive electrode sheet 13 has a shape in which a recess (notch) is provided around the circle as shown in FIG. 9B, for example.

○ 位置決め部材21は金属製の棒材に絶縁被膜が形成されたものに限らない。例えば、熱伝導性の良い絶縁材で形成してもよい。
○ 位置決め部材21は熱伝導性の良好でない絶縁材で形成してもよい。
The positioning member 21 is not limited to a metal bar having an insulating film formed thereon. For example, an insulating material with good thermal conductivity may be used.
The positioning member 21 may be formed of an insulating material with poor thermal conductivity.

○ 位置決め部材21をケース本体22の第1の開口部22aと対向する側壁から突出する状態に設けてもよい。この場合、孔14d,15aと同じ断面形状の位置決め用の柱が立設された治具を用いてケース本体22の外部で、正極シート13、負極シート14及びセパレータ15を積層して電極体11を形成した後、電極体11を治具から取り外してケース本体22に設けられた位置決め部材21に挿通される状態で収容してもよい。また、ケース本体22の外部で積層せずに、ケース本体22に設けられた位置決め部材21に孔13d,14d,15aが挿通されるようにして、正極シート13、負極シート14及びセパレータ15をケース本体22内で積層して電極体11を形成してもよい。   O You may provide the positioning member 21 in the state which protrudes from the side wall facing the 1st opening part 22a of the case main body 22. As shown in FIG. In this case, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are stacked outside the case body 22 using a jig in which positioning columns having the same cross-sectional shape as the holes 14 d and 15 a are erected, and the electrode body 11 is stacked. After forming the electrode body 11, the electrode body 11 may be removed from the jig and accommodated in a state of being inserted into the positioning member 21 provided in the case main body 22. In addition, the positive electrode sheet 13, the negative electrode sheet 14, and the separator 15 are attached to the case so that the holes 13 d, 14 d, and 15 a are inserted into the positioning member 21 provided in the case main body 22 without being stacked outside the case main body 22. The electrode body 11 may be formed by stacking in the main body 22.

○ 位置決め部材21が電池ケース12と別体に形成されている場合、ケース本体22及び蓋体23aに位置決め部材21の端部が係合する凹部22c,23cを設けずに、位置決め部材21の端面がケース本体22及び蓋体23aに当接して固定される構成としてもよい。また、位置決め部材21の端部に凹部を形成し、ケース本体22及び蓋体23aに前記凹部と係合(嵌合)する凸部を設けてもよい。   When the positioning member 21 is formed separately from the battery case 12, the end surface of the positioning member 21 is provided without providing the case main body 22 and the lid 23a with the recesses 22c and 23c with which the end of the positioning member 21 is engaged. It is good also as a structure which contact | abuts to the case main body 22 and the cover body 23a, and is fixed. Further, a recess may be formed at the end of the positioning member 21, and a protrusion that engages (fits) the recess may be provided on the case body 22 and the lid body 23a.

○ 電池ケース12と別体に形成された位置決め部材21を用いて電極体11を組み立て、その電極体11を電池ケース12に収容した後、位置決め部材21を溶接等で電池ケース12に接合してもよい。   ○ After assembling the electrode body 11 using the positioning member 21 formed separately from the battery case 12, and housing the electrode body 11 in the battery case 12, the positioning member 21 is joined to the battery case 12 by welding or the like. Also good.

○ 位置決め部材21の外面に、位置決め部材21の長手方向全長に亘って延びる溝を設けてもよい。溝は1本でも複数本でもよい。この場合、二次電池10を製造する際に活物質層13b,14bへの電解液20の含浸を行う際、位置決め部材21の表面に形成された溝からも電解液20が活物質層13b,14bに含浸するようになるため、電解液の含浸が早くなり、含浸に要する時間の短縮を図ることができる。   A groove extending over the entire length in the longitudinal direction of the positioning member 21 may be provided on the outer surface of the positioning member 21. One groove or a plurality of grooves may be provided. In this case, when the active material layers 13b and 14b are impregnated with the electrolytic solution 20 when the secondary battery 10 is manufactured, the electrolytic solution 20 also flows from the grooves formed on the surface of the positioning member 21. 14b is impregnated, so that the electrolytic solution is impregnated quickly, and the time required for the impregnation can be shortened.

○ ケース本体22に電極体11を挿入するための第1の開口部22aの他に、正極用集電端子16及び負極用集電端子17と、正極端子18及び負極端子19との接続を行うための第2の開口部22bは設けなくてもよい。そして、正極端子18及び負極端子19を蓋体23aに設けてもよい。   ○ In addition to the first opening 22 a for inserting the electrode body 11 into the case body 22, the positive electrode current collector terminal 16 and the negative electrode current collector terminal 17 are connected to the positive electrode terminal 18 and the negative electrode terminal 19. Therefore, the second opening 22b may not be provided. And you may provide the positive electrode terminal 18 and the negative electrode terminal 19 in the cover body 23a.

○ 第3の実施形態において延長部材29を位置決め部材21に対して螺合ではなく、凸部と凹部との嵌合により連結可能に構成してもよい。この場合、ボルト28に代えて位置決め部材21に対して凹凸の関係で蓋体23aを位置決め部材21に固定する部材を使用する。   In the third embodiment, the extension member 29 may be connected to the positioning member 21 not by screwing but by fitting of the convex portion and the concave portion. In this case, instead of the bolt 28, a member that fixes the lid 23a to the positioning member 21 in an uneven relationship with respect to the positioning member 21 is used.

○ 電極体11は、正極シート13の活物質非塗布部13cと、負極シート14の活物質非塗布部14cとが同じ側に突出する構成に限らず、反対側に突出する構成としてもよい。例えば、二次電池10の正極端子18及び負極端子19が設けられている側を上側とした場合、電極体11の左側及び右側の一方の側に活物質非塗布部13cが存在し、他方の側に活物質非塗布部14cが存在するように構成してもよい。   The electrode body 11 is not limited to a configuration in which the active material non-applied portion 13c of the positive electrode sheet 13 and the active material non-applied portion 14c of the negative electrode sheet 14 protrude to the same side, and may be configured to protrude to the opposite side. For example, when the side on which the positive electrode terminal 18 and the negative electrode terminal 19 of the secondary battery 10 are provided is the upper side, the active material non-applied portion 13c exists on one side of the left side and the right side of the electrode body 11, and the other side You may comprise so that the active material non-application part 14c may exist in the side.

以下の技術的思想(発明)は前記実施形態から把握できる。
(1)請求項1〜請求項4のいずれか1項に記載の発明において、前記位置決め部材は前記電池ケースの蓋体に対して一体に、垂直に設けられている。
The following technical idea (invention) can be understood from the embodiment.
(1) In the invention according to any one of claims 1 to 4, the positioning member is provided integrally and perpendicularly to the lid of the battery case.

(2)請求項2に記載の発明において、前記位置決め部材は、前記電池ケース内に収容された状態で、その一端が前記電池ケースの蓋体に固定される締結体に螺合された状態で前記電池ケースに固定されている。   (2) In the invention according to claim 2, in the state where the positioning member is housed in the battery case, one end of the positioning member is screwed into a fastening body fixed to the lid of the battery case. It is fixed to the battery case.

11…電極体、12…ケースとしての電池ケース、13…正極シート、13d,14d,15a…孔、14…負極シート、15…セパレータ、21…位置決め部材、22…ケース本体、22a,22b…開口部、23a,23b…蓋体。   DESCRIPTION OF SYMBOLS 11 ... Electrode body, 12 ... Battery case as a case, 13 ... Positive electrode sheet, 13d, 14d, 15a ... Hole, 14 ... Negative electrode sheet, 15 ... Separator, 21 ... Positioning member, 22 ... Case main body, 22a, 22b ... Opening Part, 23a, 23b ... lid.

Claims (5)

複数の正極シート及び複数の負極シートが、前記正極シートと前記負極シートとの間にシート状のセパレータが存在する状態で交互に積層されて構成された電極体が、ケース内に収容された蓄電装置であって、
前記正極シート、前記負極シート及び前記セパレータにはそれぞれ孔が形成され、それぞれの前記孔を貫通した位置決め部材により前記ケース内に位置決めされた状態で収容されていることを特徴とする蓄電装置。
An electrode body in which a plurality of positive electrode sheets and a plurality of negative electrode sheets are alternately stacked in a state where a sheet-like separator is present between the positive electrode sheet and the negative electrode sheet is housed in a case A device,
A hole is formed in each of the positive electrode sheet, the negative electrode sheet, and the separator, and the power storage device is housed in a state of being positioned in the case by a positioning member penetrating each hole.
前記位置決め部材は、前記ケースのケース本体とは別体に構成されている請求項1に記載の蓄電装置。   The power storage device according to claim 1, wherein the positioning member is configured separately from a case main body of the case. 前記位置決め部材は棒状をしており、
前記ケースのケース本体には、前記位置決め部材の延びる方向に開口部が形成され、前記開口部を覆う蓋体は前記ケース本体内に収容された前記電極体における積層方向と直交する方向における外面に当接した状態で前記開口部を覆うように前記ケース本体に固定されている請求項1又は請求項2に記載の蓄電装置。
The positioning member has a rod shape,
An opening is formed in the case body of the case in the direction in which the positioning member extends, and a lid that covers the opening is formed on an outer surface in a direction perpendicular to the stacking direction of the electrode body housed in the case body. The power storage device according to claim 1 or 2, wherein the power storage device is fixed to the case main body so as to cover the opening in a contact state.
前記蓄電装置はリチウムイオン二次電池であり、前記正極シートの面積が前記負極シートの面積より小さくなるように前記正極シート及び前記負極シートに前記孔が形成されている請求項1〜請求項3のいずれか一項に記載の蓄電装置。   The said electrical storage apparatus is a lithium ion secondary battery, The said hole is formed in the said positive electrode sheet and the said negative electrode sheet so that the area of the said positive electrode sheet may become smaller than the area of the said negative electrode sheet. The electrical storage apparatus as described in any one of these. 請求項1〜請求項4のいずれか一項に記載の蓄電装置が搭載された車両。   A vehicle on which the power storage device according to any one of claims 1 to 4 is mounted.
JP2011274653A 2011-12-15 2011-12-15 Power storage device and vehicle Pending JP2013125691A (en)

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JP2020030961A (en) * 2018-08-22 2020-02-27 トヨタ自動車株式会社 Manufacturing method for layered type battery
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