JP2013118398A - Plasma processing apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To efficiently monitor a plasma process simultaneously with generation of microwave plasma in simple configuration.SOLUTION: In a plasma processing apparatus, a wafer W to be processed is accommodated in a chamber 10 which can be evacuated, plasma of process gas is generated by supplying the process gas and microwave power into the chamber 10, and desired plasma processing is applied to the wafer W. In the plasma processing apparatus, in a microwave transmission line 58 for transmitting microwaves from a microwave generator 60 to the chamber 10, a predetermined section including its terminal portion is comprised of a coaxial tube 66, an inner conductor 68 of the coaxial tube 66 is configured into a hollow tube, and a monitoring section is included which monitors a state of a process or a process condition inside of the chamber 10 via the hollow tube.

Description

  The present invention relates to a microwave plasma processing apparatus that uses microwaves in a plasma process, and more particularly to a plasma processing apparatus that supplies microwave power to plasma in a processing container by electromagnetic wave coupling.

  In a plasma process for manufacturing a semiconductor device, a liquid crystal display, or the like, high frequency (RF) or microwaves are used to discharge or ionize a processing gas in a vacuum processing container. In the RF discharge method, a capacitive coupling type in which a pair of electrodes are arranged in parallel in a processing container with an appropriate gap, one electrode is grounded, and a high frequency is applied to the other electrode through a capacitor has become the mainstream. ing. However, the RF discharge method has problems that it is difficult to generate a high-density plasma under a low pressure and that the elements on the substrate surface are easily damaged due to the high electron temperature. On the other hand, the microwave discharge method has the advantage of being able to generate a high-density plasma with a low electron temperature under a low pressure. By adopting a plate-shaped microwave introduction window structure, a large-diameter plasma can be efficiently used over a wide pressure range. In addition, the plasma processing apparatus can be simplified because it does not require a magnetic field (see, for example, FIGS. 1A and 2 of Patent Document 1).

International Publication WO2005 / 045913

  A conventional microwave plasma processing apparatus using a flat plate-like microwave introduction window as described above, as a method for introducing a processing gas into a processing container, showers a dielectric window on a ceiling surface facing a substrate holder (susceptor). The first method in which processing gas is flowed vertically downward from a number of gas discharge ports formed in a uniform distribution on the shower plate, or one or more gas discharges on the side wall of the processing vessel An outlet is provided, and any one of the second methods is adopted in which the processing gas flows horizontally from the gas discharge ports on the side walls of the container toward the center of the plasma generation space.

  The first method is advantageous for forming plasma with a uniform density distribution above the substrate holder, but the shower plate is a path for microwaves (electromagnetic waves), leading to a decrease in plasma density. In addition to inefficiency, it causes a reduction in the uniformity of the etching rate and further causes contamination. On the other hand, in the second method, since the gas discharge port on the side wall of the container is out of the path of the microwave, instead of causing abnormal discharge, the processing gas is uniformly distributed in the radial direction above the substrate holder. There is a problem that it is difficult to diffuse and the plasma density distribution tends to be non-uniform. In particular, the single-wafer type plasma processing apparatus is introduced across the upper part of the exhaust path because the annular space between the substrate holder and the container wall is an exhaust path that leads to the exhaust port on the bottom of the container. The treated gas tends to be non-uniform due to the influence of the exhaust flow.

  An object of the present invention is to provide a plasma processing apparatus capable of efficiently monitoring a plasma process simultaneously with generation of microwave plasma with a simple configuration.

  The plasma processing apparatus of the present invention accommodates a substrate to be processed in a processing container capable of being evacuated, supplies processing gas and microwave power into the processing container, generates plasma of the processing gas, and the substrate. A plasma processing apparatus for performing a desired plasma processing on a microwave transmission line for transmitting a microwave from a microwave generator to the processing container, and a predetermined section including a terminal portion thereof is configured by a coaxial tube. In addition, the internal conductor of the coaxial tube is configured as a hollow tube, and a monitor unit is provided for monitoring the state of the process or process conditions in the processing vessel via the hollow tube.

  In the above configuration, the microwave output from the microwave generator propagates through the microwave transmission line and is introduced into the processing container, and the gas particles of the processing gas are ionized by the power of the microwave to generate plasma. And a desired plasma process is performed on the substrate to be processed under the plasma. While the plasma processing is being performed in the processing container, the monitor unit is in the processing container through the hollow tube of the inner conductor of the coaxial tube that forms at least the terminal section or terminal section of the microwave transmission line. In-situ monitoring of plasma process or process condition status.

  As a preferred embodiment, this monitor unit optically measures the film thickness of a predetermined film on the substrate held by the plasma luminescence measuring unit for spectroscopically measuring the light emitted from the plasma in the processing container. An optical film thickness measuring unit for measuring the temperature, or a temperature sensor for measuring the temperature in the processing container.

  The plasma processing apparatus of the present invention can efficiently perform monitoring of a plasma process with a simple configuration simultaneously with the generation of microwave plasma by the configuration and operation as described above.

It is a figure which shows the whole structure of the microwave plasma processing apparatus in one structural example of this invention. It is a longitudinal cross-sectional view which shows the structure of the principal part in the microwave plasma processing apparatus of FIG. It is a top view which shows the slot pattern structure of the antenna used with the microwave plasma processing apparatus of FIG. It is a figure which shows the whole structure of the microwave plasma processing apparatus in another structural example of this invention. It is a figure showing the whole microwave plasma processing device composition in one embodiment of the present invention.

  Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings.

  FIG. 1 shows an overall configuration of a microwave plasma etching apparatus according to an exemplary configuration of the present invention. This microwave plasma etching apparatus is configured as a flat plate SWP type plasma processing apparatus that does not require a magnetic field, and has a cylindrical vacuum chamber (processing vessel) 10 made of metal such as aluminum or stainless steel. . The chamber 10 is grounded for safety.

  First, the configuration of each part not related to plasma generation in this microwave plasma etching apparatus will be described.

  A disc-shaped susceptor 12 on which, for example, a semiconductor wafer W is mounted as a substrate to be processed is horizontally disposed as a substrate holding table that also serves as a high-frequency electrode in the lower center of the chamber 10. The susceptor 12 is made of, for example, aluminum, and is supported by an insulating cylindrical support portion 14 that extends vertically upward from the bottom of the chamber 10.

  An annular exhaust path 18 is formed between the conductive cylindrical support section 16 extending vertically upward from the bottom of the chamber 10 along the outer periphery of the cylindrical support section 14 and the inner wall of the chamber 10. An annular baffle plate 20 is attached to the top or the inlet, and an exhaust port 22 is provided at the bottom. In order to make the gas flow in the chamber 10 uniform with respect to the axis of the semiconductor wafer W on the susceptor 12, it is preferable to provide a plurality of exhaust ports 20 at equal intervals in the circumferential direction. An exhaust device 26 is connected to each exhaust port 20 via an exhaust pipe 24. The exhaust device 26 has a vacuum pump such as a turbo molecular pump, and can depressurize the plasma processing space in the chamber 10 to a desired degree of vacuum. A gate valve 28 that opens and closes the loading / unloading port of the semiconductor wafer W is attached to the outside of the sidewall of the chamber 10.

  A high frequency power source 30 for RF bias is electrically connected to the susceptor 12 via a matching unit 32 and a power feed rod 34. The high frequency power supply 30 outputs a relatively low frequency, for example, a high frequency of 13.56 MHz suitable for controlling the energy of ions drawn into the semiconductor wafer W, with a predetermined power. The matching unit 32 accommodates a matching unit for matching between the impedance on the high-frequency power source 30 side and the impedance on the load (mainly electrodes, plasma, chamber) side. A blocking capacitor for generation is included.

  On the upper surface of the susceptor 12, an electrostatic chuck 36 for holding the semiconductor wafer W with an electrostatic attraction force is provided, and a focus ring 38 that surrounds the periphery of the semiconductor wafer W in an annular shape is provided radially outward of the electrostatic chuck 36. Provided. The electrostatic chuck 36 is obtained by sandwiching an electrode 36a made of a conductive film between a pair of insulating films 36b and 36c, and a DC power source 40 is electrically connected to the electrode 36a via a switch 42. The semiconductor wafer W can be attracted and held on the electrostatic chuck 36 by a Coulomb force by a DC voltage applied from the DC power supply 40.

  Inside the susceptor 12, for example, an annular refrigerant chamber 44 extending in the circumferential direction is provided. A refrigerant having a predetermined temperature, such as cooling water, is circulated and supplied to the refrigerant chamber 44 through pipes 46 and 48 from a chiller unit (not shown). The processing temperature of the semiconductor wafer W on the electrostatic chuck 36 can be controlled by the temperature of the coolant. Further, a heat transfer gas such as He gas from a heat transfer gas supply unit (not shown) is supplied between the upper surface of the electrostatic chuck 36 and the back surface of the semiconductor wafer W via the gas supply pipe 50. Further, for loading / unloading of the semiconductor wafer W, lift pins that can vertically move through the susceptor 12 and a lifting mechanism (not shown) and the like are also provided.

  Next, the configuration of each part related to plasma generation in this microwave plasma etching apparatus will be described.

  A circular quartz plate 52 is airtightly attached to the ceiling surface of the chamber 10 facing the susceptor 12 as a dielectric plate for introducing microwaves. On the upper surface of the quartz plate 52, a disc-shaped radial line slot antenna 54 having a large number of concentrically distributed slots is installed as a flat slot antenna. The radial line slot antenna 54 is electromagnetically coupled to a microwave transmission line 58 via a delay plate 56 made of a dielectric material such as quartz.

  The microwave transmission line 58 is a line that transmits the microwave output from the microwave generator 60 to the antenna 54, and includes a waveguide 62, a waveguide-coaxial tube converter 64, and a coaxial tube 66. ing. The waveguide 62 is, for example, a rectangular waveguide, and transmits the microwave from the microwave generator 60 toward the chamber 10 to the waveguide-coaxial tube converter 64 using the TE mode as a transmission mode.

  The waveguide-coaxial tube converter 64 couples the rectangular waveguide 62 and the coaxial tube 66 to convert the transmission mode of the rectangular waveguide 62 into the transmission mode of the coaxial tube 66, and has a high output. In order to prevent electric field concentration when transmitting microwave power, a configuration (so-called doorknob configuration) in which the upper end portion 68a of the inner conductor 68 of the coaxial tube 66 is thickened in a reverse taper shape as shown in the figure is employed. preferable.

  The coaxial tube 66 extends vertically downward from the waveguide-coaxial tube converter 64 to the center of the upper surface of the chamber 10, and the end or lower end of the coaxial line is coupled to the antenna 54 via the delay plate 56. The outer conductor 70 of the coaxial tube 66 is formed of a cylindrical body integrally formed with the rectangular waveguide 62, and the microwave propagates in the space between the inner conductor 68 and the outer conductor 70 in the TEM mode.

  The microwave output from the microwave generator 60 propagates through the microwave transmission line 58 including the waveguide 62, the waveguide-coaxial tube converter 64, and the coaxial tube 66 as described above, and the delay plate 56. Power is supplied to the antenna 54 through the antenna. Then, the microwaves spread in the radial direction by the delay plate 56 are radiated from the slots of the antenna into the chamber 10 and are nearby by the microwave power radiated from the surface wave propagating along the surface of the quartz plate 52. The gas is ionized and plasma is generated.

  An antenna rear plate 72 is provided on the delay plate 56 so as to cover the upper surface of the chamber 10. The antenna rear plate 72 is made of, for example, aluminum and serves also as a cooling jacket that absorbs (dissipates) heat generated in the quartz plate 52. A chiller unit (not shown) is provided in the flow path 74 formed inside. Further, a coolant having a predetermined temperature, for example, cooling water is circulated and supplied through the pipes 76 and 78.

  In this microwave plasma etching apparatus, as clearly shown in FIG. 2, a hollow gas flow path 80 penetrating through the inner conductor 68 of the coaxial tube 66 is provided. A first gas supply pipe 84 communicating with the processing gas supply source 82 is connected to the upper end opening 80 a of the gas flow path 80, and the lower end of the gas flow path 80 of the coaxial pipe 66 is connected to the center of the quartz plate 52. An upper center gas discharge port 86 that is continuous or communicated with the opening 80b is formed. In the first processing gas introduction section 88 having such a configuration, the processing gas sent from the processing gas supply source 82 passes through the first gas supply pipe 84 and the gas flow path 80 of the coaxial pipe 66 from the upper central gas discharge port 86. It is discharged toward the susceptor 12 directly below, and is diffused radially outward to the axial object so as to be drawn toward the annular exhaust path 18 surrounding the susceptor 12. An MFC (mass flow controller) 90 and an on-off valve 92 are provided in the middle of the first gas supply pipe 84.

  The microwave plasma etching apparatus also includes a second processing gas introduction unit 94 that is different from the first processing gas introduction unit 88 in order to introduce a processing gas into the chamber 10. The second processing gas introduction part 94 includes a buffer chamber 96 formed in an annular shape in the side wall of the chamber 10 at a position somewhat lower than the quartz plate 52, and a plasma generation space from the buffer chamber 96 at equal intervals in the circumferential direction. And a gas supply pipe 100 extending from the processing gas supply source 82 to the buffer chamber 96. An MFC 102 and an on-off valve 104 are provided in the middle of the gas supply pipe 100.

  In the second processing gas introduction section 94, the processing gas sent from the processing gas supply source 82 is introduced into the buffer chamber 96 in the side wall of the chamber 10 through the second gas supply pipe 100 and circulates in the buffer chamber 96. After equalizing the pressure in the direction, the gas is discharged from the side gas discharge ports 98 substantially horizontally toward the center of the chamber 10 and diffuses into the plasma processing space. At this time, since the processing gas discharged from each side gas discharge port 98 is drawn to the exhaust port 22 side when crossing the upper portion of the annular exhaust path 18, there is a surface that is difficult to be uniformly supplied onto the semiconductor wafer W. In this embodiment, as described above, the processing gas introduced from the upper central gas discharge port 86 of the first processing gas introduction part 88 is diffused radially from the central part to the axial object, so that the second processing gas introduction part 88 The unstable or indefinite diffusion of the introduced processing gas can be compensated, and the density of the plasma generated immediately above the semiconductor wafer W can be made uniform.

  The processing gases introduced into the chamber 10 from the first processing gas introduction unit 88 and the second processing gas introduction unit 94 are usually the same type of gas, but may be different types of gases. , 102 can be introduced at independent flow rates or at an arbitrary flow rate ratio to improve the gas density in the radial direction, and hence the uniformity of the plasma density.

  FIG. 2 shows a detailed configuration of the waveguide-coaxial tube converter 64 and the coaxial tube 66 in this microwave plasma etching apparatus. The inner conductor 68 of the coaxial tube 66 is made of, for example, aluminum, and a gas channel 80 of a through hole is formed in the inside along the central axis, and a refrigerant channel 106 is also formed in parallel with the gas channel 80. ing. The refrigerant flow path 106 is divided into a forward path 106a and a return path 106b via a vertical partition (not shown), and pipes 108 and 110 leading to a chiller unit (not shown) are connected to the upper end of the reverse taper portion 68a. Refrigerant, for example, cooling water introduced into the refrigerant flow path 106 from the supply pipe 108 flows vertically downward in the refrigerant flow path 106a to reach the lower end portion of the coaxial pipe 66, and then turns back from there to return the return path 106b vertically upward. It flows and exits to the discharge pipe 110.

  As shown in FIG. 2, the antenna 54 has an opening 54 a through which the inner conductor 68 of the coaxial tube 66 passes at the center, and the slot plate extends around the inner conductor 68 (radially outward). Yes. The upper central gas discharge port 86 of the quartz plate 52 that is coaxially continuous with the gas flow path 80 of the inner conductor 68 is off the path of the electromagnetic wave (microwave) radiated from the antenna 54 so that abnormal discharge does not occur. It has become. Note that the upper central gas discharge port 86 can be branched or divided into a plurality of discharge ports within a limited range in the radial direction.

  FIG. 3 shows a slot pattern structure of the radial line slot antenna 54 in this microwave plasma etching apparatus. As shown in the figure, the slot plate of the antenna 54 has a large number of concentric slots. More specifically, two types of slots 54b and 54c whose directions are orthogonal to each other are alternately arranged concentrically, and are arranged at intervals according to the wavelength of the microwave transmitted by the delay plate 56 in the radial direction. . In the slot pattern structure, the microwave is radiated from the slot plate as a circularly polarized substantially plane wave including two orthogonal polarization components. This type of slot antenna is excellent in uniformly radiating microwaves from substantially the entire surface of the slot plate, and is suitable for generating uniform and stable plasma.

  In this microwave plasma etching apparatus, the above-described parts such as the exhaust device 26, the high-frequency power supply 30, the switch 42 of the DC power supply 40, the microwave generator 60, the processing gas introduction parts 88 and 94, and the chiller units (not shown) ), Individual operations of the heat transfer gas supply unit (not shown) and the operation of the entire apparatus are controlled by a control unit (not shown) composed of, for example, a microcomputer.

  In order to perform etching in this microwave plasma etching apparatus, first, the gate valve 28 is opened, and the semiconductor wafer W to be processed is loaded into the chamber 10 and placed on the electrostatic chuck 36. Then, an etching gas (generally a mixed gas) is introduced into the chamber 10 at a predetermined flow rate and flow rate ratio from the first and second processing gas introduction portions 88 and 94, and the pressure in the chamber 10 is set to a set value by the exhaust device 26. Reduce pressure. Further, the high frequency power supply 30 is turned on to output a high frequency with a predetermined power, and this high frequency is applied to the susceptor 12 via the matching unit 34 and the power supply rod 34. Further, the switch 42 is turned on and a DC voltage is applied from the DC power supply 44 to the electrode 36 a of the electrostatic chuck 36, and the semiconductor wafer W is fixed on the electrostatic chuck 36 by the electrostatic adsorption force of the electrostatic chuck 36. Then, the microwave generator 60 is turned on, the microwave output from the microwave generator 60 is fed to the antenna 54 via the microwave transmission line 58, and the microwave radiated from the antenna 54 is passed through the quartz plate 52. Into the chamber 10.

  The etching gas introduced into the chamber 10 from the upper central gas discharge port 86 of the first process gas introduction unit 88 and the side gas discharge port 98 of the second process gas introduction unit 94 is diffused under the quartz plate 52 to form quartz. The gas particles are ionized by the microwave power radiated from the surface waves propagating along the lower surface of the plate 52 (the surface facing the plasma), and surface-excited plasma is generated. Thus, the plasma generated under the quartz plate 52 diffuses downward, and isotropic etching by radicals in the plasma and vertical etching by ion irradiation are performed on the film to be processed on the main surface of the semiconductor wafer W.

  In this microwave plasma etching apparatus, since high-density plasma is generated by surface wave excitation, the electron temperature in the vicinity of the semiconductor wafer W is very low, for example, about 0.7 to 1.5 eV, thereby reducing the energy of ion irradiation. It is possible to suppress the damage to the film to be processed. Further, since the microwave power is uniformly injected into the chamber 10 with a large area using the radial line slot antenna 54, it is possible to easily cope with an increase in the wafer diameter. A through-hole gas flow path 80 is provided in the inner conductor 68 of the coaxial pipe 66 constituting the final section of the microwave transmission line 58, and the gas discharge port at the center of the chamber ceiling (quartz plate 52) is passed through the gas flow path 80. Since the processing gas is introduced into the chamber 10 from 86, the uniformity of the plasma density is improved, and the in-plane uniformity of the etching process is improved. At the same time, the antenna performance is not adversely affected and abnormal discharge may occur. Absent.

  In addition, since this microwave plasma etching apparatus generates microwave plasma without a magnetic field, there is no need to provide a magnetic field forming mechanism such as a permanent magnet or an electronic coil around the chamber 10, and the apparatus configuration is simple. Yes. However, the present invention can be applied to a plasma processing apparatus using electron cyclotron resonance (ECR) as shown in FIG.

  The ECR plasma processing apparatus of FIG. 4 is provided with a magnetic field forming mechanism 112 made of a permanent magnet or an electronic coil around the chamber 10, and an external magnetic field is applied to the plasma generation space in the chamber 10 by the magnetic field forming mechanism 112 to generate plasma. A magnetic field (875 gauss in the case of 2.45 GHz) that makes the frequency of the microwave equal to the electron cyclotron frequency at a certain place in the space can be formed, and high-density plasma can be generated.

  As shown in FIG. 4, only the first processing gas introduction part 88 for introducing the processing gas from the center of the upper top plate of the chamber 10 is provided, and the second processing gas introduction part 94 for introducing the processing gas from the chamber side wall (FIG. 4). It is also possible to omit 1).

  Furthermore, as an embodiment of the present invention, as shown in FIG. 5, the hollow portion formed in the inner conductor 68 of the coaxial tube 66 is used for an optical measurement line for monitoring instead of a gas flow path. Is also possible. For example, when detecting the end point of plasma etching, an optical fiber probe (not shown) is inserted into the hollow portion of the coaxial pipe inner conductor 68 to emit light from the plasma at the center of the upper top plate of the chamber 10. Can be detected by spectroscopic analysis using the monitor unit 114, and the etching end point can be detected from the increase / decrease of the emission spectrum caused by the specific reactive species. It is also possible to measure the film thickness of the antireflection film, resist film, etc. on the semiconductor wafer W by using the hollow portion of the coaxial pipe inner conductor 68 in the laser optical path. Furthermore, it is also possible to measure the temperature near the center of the upper top plate in the chamber 10 by passing a temperature sensor line having a thermocouple attached to the tip through the hollow portion of the coaxial pipe inner conductor 68.

  In the present invention, various other modifications are possible for the configuration or function of the hollow portion of the inner conductor 68 of the coaxial tube 66. For example, although not shown, the hollow portion of the inner conductor 68 of the coaxial tube may be formed in a multiple tube structure such as a double tube, and each tube may be used as an independent line (gas supply system line, measurement system line). it can. In order to introduce the processing gas into the chamber 10, a third processing gas introduction part different from the first and second processing gas introduction parts 88 and 94 may be provided in the internal conductor 68.

  In addition, the configuration and function of each part in the above-described embodiment can be variously modified. For example, another type of slot antenna can be used in place of the radial slot line antenna 54, and a microwave injection method without using an antenna is also possible, particularly when a large-diameter plasma is not required. Also in the microwave transmission line 58, another transmission line is inserted between the microwave generator 60 and the rectangular waveguide 62, or the rectangular waveguide 62 is replaced with, for example, a circular waveguide. In the coaxial tube converter 64, the impedance converter 64a can be configured as a ridge guide instead of a door knob. Furthermore, a configuration in which the end of the circular waveguide is electromagnetically coupled to the chamber without using the waveguide-coaxial tube converter is also possible.

  The present invention is not limited to the microwave plasma etching apparatus in the above embodiment, but can also be applied to processing apparatuses such as plasma CVD (Chemical Vapor Deposition), plasma oxidation, plasma nitridation, and sputtering. Further, the substrate to be processed in the present invention is not limited to a semiconductor wafer, and various substrates for flat panel displays, photomasks, CD substrates, printed substrates, and the like are also possible.

10 chamber 12 susceptor (substrate holder)
26 Exhaust device 30 High frequency power supply 52 Quartz plate (dielectric window)
54 Radial line slot antenna 58 Microwave transmission line 60 Microwave generator 62 Waveguide 64 Waveguide-coaxial tube converter 66 Coaxial tube 68 Inner conductor 70 Outer conductor 82 Processing gas supply source 84 First gas supply tube 86 Upper part Central gas discharge hole 88 First process gas introduction part 94 Second process gas introduction part 98 Side gas discharge hole 100 Second gas supply pipe 112 Magnetic field forming part 114 Monitor part

Claims (4)

A substrate to be processed is accommodated in a processing container that can be evacuated, plasma of the processing gas is generated by supplying processing gas and microwave power into the processing container, and plasma for performing a desired plasma processing on the substrate A processing device comprising:
In the microwave transmission line for transmitting the microwave from the microwave generator to the processing vessel, a predetermined section including a terminal portion thereof is constituted by a coaxial line, and the inner conductor of the coaxial line is constituted by a hollow tube. And a plasma processing apparatus having a monitor unit for monitoring the state of the process or process conditions in the processing container via the hollow tube.   The plasma processing apparatus according to claim 1, wherein the monitor unit includes a plasma light emission measurement unit that spectrally measures light emission from plasma in the processing container.   The plasma processing apparatus according to claim 1, wherein the monitor unit includes an optical film thickness measurement unit for optically measuring a film thickness of a predetermined film on the substrate held on the holding table.   The plasma processing apparatus according to claim 1, wherein the monitor unit includes a temperature sensor for measuring a temperature in the processing container.

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