JP2013093287A - Unit cell and battery pack - Google Patents

Unit cell and battery pack Download PDF

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JP2013093287A
JP2013093287A JP2011236135A JP2011236135A JP2013093287A JP 2013093287 A JP2013093287 A JP 2013093287A JP 2011236135 A JP2011236135 A JP 2011236135A JP 2011236135 A JP2011236135 A JP 2011236135A JP 2013093287 A JP2013093287 A JP 2013093287A
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positive
battery
bus bar
negative electrode
battery lid
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JP5941654B2 (en
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Yutaka Sato
豊 佐藤
Koichi Kajiwara
浩一 梶原
Hideyuki Shibanuma
英幸 柴沼
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Vehicle Energy Japan Inc
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Hitachi Vehicle Energy Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

PROBLEM TO BE SOLVED: To prevent: short circuit between positive and negative electrode terminals due to dew condensation water; and thermal deformation of an insulating seal member due to heat input when a bus bar is welded to the positive and negative electrode terminals.SOLUTION: A unit cell includes: positive and negative electrode terminals 141 and 151 attached to a through hole 102h of a battery lid 102; and a gasket 130 that is disposed between the positive and negative electrode terminals 141 and 151 and the through hole 102h, and provides insulation between the positive and negative electrode terminals 141 and 151 and the battery lid 102. The positive and negative electrode terminals 141 and 151 are respectively provided with external terminal parts 142 and 152 to which a bus bar 110 for establishing an electrical connection between unit cells is welded. The gasket 130 includes a covering part 130c that covers tightly outer peripheral surfaces of the external terminal parts 142 and 152 of the positive and negative electrode terminals 141 and 151 protruding outward from the through hole 102h of the battery lid 102. The front end of the covering part 130c is located further closer to the battery lid than bus bar contact surfaces 142a and 152a of the external terminal parts 142 and 152.

Description

本発明は、単電池および複数の単電池を電気的に接続した組電池に関する。   The present invention relates to a battery cell and a battery pack in which a plurality of battery cells are electrically connected.

近年、ハイブリッド電気自動車や純粋な電気自動車等の動力源として大容量(Wh)の二次電池が開発されており、その中でもエネルギー密度(Wh/kg)の高い角形のリチウムイオン二次電池が注目されている。   In recent years, secondary batteries with large capacity (Wh) have been developed as power sources for hybrid electric vehicles and pure electric vehicles. Among them, prismatic lithium ion secondary batteries with high energy density (Wh / kg) are of particular interest. Has been.

角形のリチウムイオン二次電池においては、正極電極および負極電極をセパレータを介在させて捲回することで扁平形状の捲回電極群が形成される。捲回電極群は、電池蓋の貫通孔に絶縁シール部材を介して装着された正極端子および負極端子に電気的に接続される。捲回電極群は、電池容器の電池缶に収容され、電池缶の開口部は電池蓋で封止溶接される。二次電池は、捲回電極群を収容した電池容器の注液孔から電解液が注入された後、注液栓が挿入されてレーザ溶接により封止溶接されることで形成される。   In a rectangular lithium ion secondary battery, a flat wound electrode group is formed by winding a positive electrode and a negative electrode with a separator interposed therebetween. The wound electrode group is electrically connected to a positive electrode terminal and a negative electrode terminal attached to the through hole of the battery lid via an insulating seal member. The wound electrode group is accommodated in a battery can of the battery container, and the opening of the battery can is sealed and welded with a battery lid. The secondary battery is formed by injecting an electrolytic solution from a liquid injection hole of a battery container containing a wound electrode group, inserting a liquid injection stopper, and sealing and welding by laser welding.

複数の上記角形の二次電池(単電池)の正極端子と負極端子とをバスバーなどの導電部材により電気的に接続することで組電池が形成される。特許文献1には、バスバーを溶接するのに適した円盤形状の外部端子を備えた二次電池が記載されている。   An assembled battery is formed by electrically connecting the positive electrode terminals and the negative electrode terminals of the plurality of square secondary batteries (single cells) with a conductive member such as a bus bar. Patent Document 1 describes a secondary battery including a disk-shaped external terminal suitable for welding a bus bar.

特開2005−142026号公報JP 2005-142026 A

たとえば、二次電池と外気との間で温度差が生じる使用環境において、外気に含まれる水蒸気が電池容器において結露して水滴となることがある。結露により水滴が電池容器に付着すると、結露水により端子と電池容器との間が導通され、電池容器を介して正負極端子間で短絡が生じることがある。特許文献1に記載の二次電池では、電池容器に付着する結露水による短絡に対しての考慮がなされておらず、結露水に起因した正負極端子間での短絡のおそれがある。   For example, in a usage environment in which a temperature difference occurs between the secondary battery and the outside air, water vapor contained in the outside air may condense in the battery container and form water droplets. When water droplets adhere to the battery container due to condensation, the terminal and the battery container are electrically connected by the condensed water, and a short circuit may occur between the positive and negative terminals via the battery container. In the secondary battery described in Patent Document 1, no consideration is given to a short circuit due to the condensed water adhering to the battery container, and there is a risk of a short circuit between the positive and negative electrode terminals caused by the condensed water.

また、特許文献1に記載の二次電池では、バスバーを端子に溶接する際に発生する熱が、端子と電池蓋との間に介在される絶縁シール部材に与える影響については考慮されておらず、溶接入熱により絶縁シール部材が変形してしまうおそれがある。   Further, in the secondary battery described in Patent Document 1, the effect of heat generated when welding the bus bar to the terminal on the insulating seal member interposed between the terminal and the battery lid is not considered. The insulation seal member may be deformed by welding heat input.

請求項1に係る発明は、正極電極および負極電極をセパレータを介在させて捲回した捲回電極群と、捲回電極群を収容する電池缶と電池缶を封止する電池蓋とから構成される電池容器と、正負極電極のそれぞれに電気的に接続され、電池蓋に設けられた一対の貫通孔のそれぞれに取り付けられた正極端子および負極端子と、正極端子および負極端子のそれぞれと貫通孔との間に介在されて、正極端子および負極端子のそれぞれと電池蓋とを絶縁する絶縁シール部材とを備え、正負極端子のそれぞれには、単電池同士を電気的に接続するためのバスバーが溶接されるバスバー溶接部が設けられ、絶縁シール部材は、電池蓋の貫通孔から外方に向かって突出する正負極端子のそれぞれの外周面を密着して覆う覆い部を有し、覆い部の先端は、バスバー溶接部の頂面よりも電池蓋側に位置していることを特徴とする単電池である。
請求項2に係る発明は、請求項1に記載の単電池において、覆い部の先端から電池蓋までの寸法は、正負極端子と電池容器との間の導通を防止するための沿面距離と、バスバーをバスバー溶接部に溶接するときの入熱とを考慮して決定されることを特徴とする。
請求項3に係る発明は、請求項1または2に記載の単電池において、正負極端子のそれぞれは、円柱形状のバスバー溶接部の一端から電池蓋側に向かって突設されて電池蓋の貫通孔を貫通する円柱形状の貫通部を備え、正負極端子のそれぞれは、貫通部の外径寸法がバスバー溶接部の外径寸法よりも小さくなるように形成され、絶縁シール部材は、貫通部と電池蓋の貫通孔との間に配置される円筒状の筒部と、筒部の一端から外方に延在し、バスバー溶接部の一端面と電池蓋との間に配置される円環状の鍔部とを有し、覆い部は、鍔部の外縁から立ち上がる円筒状に形成されていることを特徴とする。
請求項4に係る発明は、請求項1または2に記載の単電池において、正負極端子のそれぞれは、矩形柱形状のバスバー溶接部の一端から電池蓋側に向かって突設されて電池蓋の貫通孔を貫通する円柱形状の貫通部を備え、正負極端子のそれぞれは、貫通部の外径寸法がバスバー溶接部の外形寸法よりも小さくなるように形成され、絶縁シール部材は、貫通部と電池蓋の貫通孔との間に配置される円筒状の筒部と、筒部の一端から外方に延在し、バスバー溶接部の一端面と電池蓋との間に配置される環状の鍔部とを有し、覆い部は、鍔部の外縁から立ち上がる矩形筒状に形成されていることを特徴とする。
請求項5に係る発明は、請求項3または4に記載の単電池において、正極電極に接続される電極接続部と、正極端子に固着される端子接続部とを有する正極集電体と、負極電極に接続される電極接続部と、負極端子に固着される端子接続部とを有する負極集電体と、正負極集電体の端子接続部のそれぞれと電池蓋との間に介在されて、正負極集電体のそれぞれと電池蓋とを絶縁する絶縁部材とを備え、正負極端子のそれぞれは、貫通部の一端から捲回電極群側に向かって突設された円筒状の突部とを備え、正負極端子のそれぞれは、突部が端子接続部にかしめられることで、正負極集電体のそれぞれに固着されていることを特徴とする。
請求項6に係る発明は、請求項1ないし5のいずれか1項に記載の単電池を複数備え、複数の単電池同士がバスバーにより電気的に接続された組電池であって、覆い部の先端から電池蓋までの寸法は、バスバーと正負極端子との間に形成される溶接金属と、覆い部との間の最短距離を考慮して決定されることを特徴とする組電池である。
The invention according to claim 1 includes a wound electrode group in which a positive electrode and a negative electrode are wound with a separator interposed therebetween, a battery can that houses the wound electrode group, and a battery lid that seals the battery can. A positive electrode terminal, a negative electrode terminal, a positive electrode terminal, a negative electrode terminal, and a through hole that are electrically connected to each of the battery container and the positive and negative electrode electrodes and attached to each of a pair of through holes provided in the battery lid Between each of the positive electrode terminal and the negative electrode terminal and an insulating seal member that insulates the battery cover, and each of the positive and negative electrode terminals has a bus bar for electrically connecting the cells. A welded busbar welded portion is provided, and the insulating seal member has a cover portion that closely contacts and covers the outer peripheral surfaces of the positive and negative electrode terminals protruding outward from the through hole of the battery lid. The tip is a bus It is a single cell, characterized by being located on the battery cover side of the top surface of the over weld.
The invention according to claim 2 is the unit cell according to claim 1, wherein the dimension from the tip of the cover to the battery lid is a creepage distance for preventing electrical conduction between the positive and negative electrode terminals and the battery container, It is determined in consideration of heat input when the bus bar is welded to the bus bar welded portion.
According to a third aspect of the present invention, in the unit cell according to the first or second aspect, each of the positive and negative electrode terminals protrudes from one end of the cylindrical bus bar welded portion toward the battery lid side and penetrates the battery lid. Each of the positive and negative terminals is formed such that the outer diameter of the through portion is smaller than the outer diameter of the bus bar welded portion, and the insulating seal member includes a through portion and a cylindrical through portion that penetrates the hole. A cylindrical tube portion disposed between the through hole of the battery lid and an annular shape extending outward from one end of the tube portion and disposed between one end surface of the bus bar welded portion and the battery cover The cover part is formed in the cylindrical shape which stands | starts up from the outer edge of a collar part, It is characterized by the above-mentioned.
According to a fourth aspect of the present invention, in the unit cell according to the first or second aspect, each of the positive and negative electrode terminals protrudes from one end of the rectangular column-shaped bus bar welded portion toward the battery lid side, and Each of the positive and negative terminals is formed such that the outer diameter of the through portion is smaller than the outer size of the bus bar welded portion, and the insulating seal member includes a through portion and a cylindrical through portion that penetrates the through hole. A cylindrical tube portion disposed between the through hole of the battery lid and an annular flange extending outward from one end of the tube portion and disposed between one end surface of the bus bar welded portion and the battery lid The cover part is formed in the rectangular cylinder shape which stands | starts up from the outer edge of a collar part, It is characterized by the above-mentioned.
According to a fifth aspect of the present invention, there is provided the single battery according to the third or fourth aspect, wherein a positive electrode current collector having an electrode connection portion connected to the positive electrode and a terminal connection portion fixed to the positive electrode terminal, and a negative electrode A negative electrode current collector having an electrode connection part connected to the electrode, a terminal connection part fixed to the negative electrode terminal, and a terminal connection part of the positive and negative electrode current collector and the battery cover, Each of the positive and negative electrode current collectors is provided with an insulating member that insulates the battery lid, and each of the positive and negative electrode terminals includes a cylindrical protrusion protruding from one end of the through portion toward the wound electrode group. Each of the positive and negative electrode terminals is fixed to each of the positive and negative electrode current collectors by caulking the projecting portion to the terminal connection portion.
An invention according to claim 6 is an assembled battery comprising a plurality of the unit cells according to any one of claims 1 to 5, wherein the plurality of unit cells are electrically connected to each other by a bus bar. The dimension from the front end to the battery cover is determined in consideration of the shortest distance between the weld metal formed between the bus bar and the positive and negative electrode terminals and the cover portion.

本発明によれば、結露水に起因した正負極端子間での短絡を防止するとともに、バスバーを正負極端子に溶接するときの入熱に起因した絶縁シール部材の熱変形を防止できる。   ADVANTAGE OF THE INVENTION According to this invention, while preventing the short circuit between positive / negative electrode terminals resulting from condensed water, the thermal deformation of the insulating seal member resulting from the heat input when welding a bus bar to a positive / negative electrode terminal can be prevented.

本発明の第1の実施の形態に係る組電池の斜視図。The perspective view of the assembled battery which concerns on the 1st Embodiment of this invention. 図1の組電池を構成する単電池の外観を示す斜視図。The perspective view which shows the external appearance of the cell which comprises the assembled battery of FIG. 図2の単電池の構成を示す分解斜視図。The disassembled perspective view which shows the structure of the single battery of FIG. 図3の捲回電極群を示す斜視図。FIG. 4 is a perspective view showing the wound electrode group of FIG. 3. (a)は図2のV−V線切断断面図、(b)は図5(a)のA部拡大図。(A) is the VV sectional view taken on the line of FIG. 2, (b) is the A section enlarged view of FIG. 5 (a). 図3の正極端子を示す破断斜視図。The fracture | rupture perspective view which shows the positive electrode terminal of FIG. (a)はバスバーの溶接位置を示す平面模式図、(b)は図1の組電池を構成する単電池の正極端子とバスバーとの接続構造を示す概念図。(A) is a plane schematic diagram which shows the welding position of a bus bar, (b) is a conceptual diagram which shows the connection structure of the positive electrode terminal of a single battery which comprises the assembled battery of FIG. 1, and a bus bar. 本発明の第2の実施の形態に係る組電池の斜視図。The perspective view of the assembled battery which concerns on the 2nd Embodiment of this invention. 図8の組電池を構成する単電池の正極端子とバスバーとの接続構造を示す概念図。The conceptual diagram which shows the connection structure of the positive electrode terminal of the cell which comprises the assembled battery of FIG. 8, and a bus-bar. 本発明の変形例に係る組電池を構成する単電池の正極端子とバスバーとの接続構造を示す概念図。The conceptual diagram which shows the connection structure of the positive electrode terminal and bus bar of the cell which comprise the assembled battery which concerns on the modification of this invention.

以下、図面を参照して、本発明をハイブリッド自動車や純粋な電気自動車に搭載される蓄電装置に組み込まれる組電池であって、角形リチウムイオン二次電池(以下単電池と記す)を複数備えた組電池に適用した実施の形態について説明する。
―第1の実施の形態―
図1は、本発明の第1の実施の形態に係る組電池の斜視図である。図1に示すように、組電池は、複数の単電池100A〜100Cを備えている。単電池100A〜100Cは、扁平な直方体形状であって、側面のうちで広い面積を有する幅広面101a同士が対向するように並べて配置されている。図示するように、単電池100A,100Cは、正極端子141が図中左側に配され、単電池100Bは、負極端子151が図中左側に配されている。すなわち、並置された複数の単電池100A〜100Cは、各単電池100A〜100Cのそれぞれの電池蓋102に取り付けられた正極端子141および負極端子151の位置が逆転するように、向きが反転して配置されている。
Hereinafter, with reference to the drawings, the present invention is an assembled battery incorporated in a power storage device mounted on a hybrid vehicle or a pure electric vehicle, and includes a plurality of prismatic lithium ion secondary batteries (hereinafter referred to as single cells). An embodiment applied to an assembled battery will be described.
-First embodiment-
FIG. 1 is a perspective view of an assembled battery according to the first embodiment of the present invention. As shown in FIG. 1, the assembled battery includes a plurality of single cells 100A to 100C. The cells 100A to 100C have a flat rectangular parallelepiped shape, and are arranged side by side so that the wide surfaces 101a having a large area among the side surfaces face each other. As illustrated, the single cells 100A and 100C have a positive electrode terminal 141 disposed on the left side in the drawing, and the single cell 100B has a negative electrode terminal 151 disposed on the left side in the drawing. That is, the plurality of unit cells 100A to 100C arranged side by side are reversed in direction so that the positions of the positive electrode terminal 141 and the negative electrode terminal 151 attached to the battery cover 102 of each of the unit cells 100A to 100C are reversed. Has been placed.

図1に示すように、単電池100Aの図中左側の正極端子141と単電池100Bの図中左側の負極端子151とは、バスバー110によって電気的に接続される。同様に、単電池100Bの図中右側の正極端子141と単電池100Cの図中右側の負極端子151とは、バスバー110によって電気的に接続される。   As shown in FIG. 1, the positive electrode terminal 141 on the left side of the cell 100 </ b> A and the negative electrode terminal 151 on the left side of the cell 100 </ b> B are electrically connected by a bus bar 110. Similarly, the positive electrode terminal 141 on the right side of the cell 100B in the drawing and the negative electrode terminal 151 on the right side of the cell 100C in the drawing are electrically connected by the bus bar 110.

単電池同士を電気的に接続するバスバー110は、厚さ1〜2mm程度の金属製の矩形平板状導電部材であって、正極端子141に設けられた円柱形状の位置決め凸部144が挿通される位置決め孔110h1と、負極端子151に設けられた円柱形状の位置決め凸部154が挿通される位置決め孔110h2とが設けられている。   The bus bar 110 that electrically connects the cells is a metal rectangular flat plate-shaped conductive member having a thickness of about 1 to 2 mm, and a columnar positioning convex portion 144 provided on the positive electrode terminal 141 is inserted therethrough. A positioning hole 110h1 and a positioning hole 110h2 through which a cylindrical positioning convex portion 154 provided in the negative electrode terminal 151 is inserted are provided.

本実施の形態では、位置決め孔110h1は円形状の貫通孔とされ、位置決め孔110h2は長孔形状とされている。位置決め孔110h1に位置決め凸部144を挿通させ、位置決め孔110h2に位置決め凸部154を挿通させることで、バスバー110を容易に位置決めできる。バスバー110は、後述する正負極端子141,151のバスバー当接面142a,152a上に載置され、バスバー当接面142a,152aとバスバー110の下面とが当接する。バスバー110と正負極端子141,151とは、バスバー110の表面に対して垂直にレーザを照射することで、レーザ溶接される。レーザ溶接の位置については後述する。   In the present embodiment, the positioning hole 110h1 is a circular through hole, and the positioning hole 110h2 is a long hole. The bus bar 110 can be easily positioned by inserting the positioning convex portion 144 into the positioning hole 110h1 and inserting the positioning convex portion 154 into the positioning hole 110h2. The bus bar 110 is placed on bus bar contact surfaces 142a and 152a of positive and negative terminals 141 and 151, which will be described later, and the bus bar contact surfaces 142a and 152a and the lower surface of the bus bar 110 are in contact with each other. The bus bar 110 and the positive and negative terminals 141 and 151 are laser welded by irradiating a laser perpendicular to the surface of the bus bar 110. The position of laser welding will be described later.

図1に示す単電池100Aの図中右側の負極端子151と、単電池100Cの図中左側の正極端子141には、不図示の他の電池に電気的に直列または並列に不図示の導電部材により接続されるか、不図示の電力取り出し用の端子に不図示の導電部材により接続される。   A negative electrode terminal 151 on the right side of the cell 100A shown in FIG. 1 and a positive electrode terminal 141 on the left side of the cell 100C in FIG. 1 are electrically conductive members (not shown) electrically connected in series or in parallel to other batteries (not shown). Or is connected to a power extraction terminal (not shown) by a conductive member (not shown).

組電池を構成する単電池について説明する。各単電池100A〜100Cはそれぞれ同じ構造であるため、以下、代表して単電池100Aについて説明する。図2は単電池100Aを示す外観斜視図であり、図3は単電池100Aの構成を示す分解斜視図である。   A single battery constituting the assembled battery will be described. Since each of the unit cells 100A to 100C has the same structure, the unit cell 100A will be described below as a representative. FIG. 2 is an external perspective view showing the unit cell 100A, and FIG. 3 is an exploded perspective view showing the configuration of the unit cell 100A.

図2に示すように、単電池100Aは、電池缶101と電池蓋102とから構成される電池容器を備えている。電池缶101および電池蓋102の材質は、アルミニウムまたはアルミニウム合金などである。図3に示すように、電池缶101には捲回電極群170が収容されている。電池缶101は、一対の幅広面101aと一対の幅狭面101bと底面101cとを有し、上面が開口された矩形箱状に形成されている。捲回電極群170は絶縁ケース108に覆われた状態で電池缶101に収容されている。絶縁ケース108の材質は、ポリプロピレン等の絶縁性を有する樹脂である。これにより、電池缶101の内面と、捲回電極群170とは電気的に絶縁されている。   As shown in FIG. 2, the unit cell 100 </ b> A includes a battery container including a battery can 101 and a battery lid 102. The material of the battery can 101 and the battery lid 102 is aluminum or an aluminum alloy. As shown in FIG. 3, the wound electrode group 170 is accommodated in the battery can 101. The battery can 101 has a pair of wide surfaces 101a, a pair of narrow surfaces 101b, and a bottom surface 101c, and is formed in a rectangular box shape with an upper surface opened. The wound electrode group 170 is accommodated in the battery can 101 while being covered with the insulating case 108. The material of the insulating case 108 is an insulating resin such as polypropylene. Thereby, the inner surface of the battery can 101 and the wound electrode group 170 are electrically insulated.

図2および図3に示すように、電池蓋102は、矩形平板状であって、電池缶101の開口を塞ぐように溶接されている。つまり、電池蓋102は、電池缶101を封止している。電池蓋102には、捲回電極群170の正極電極174および負極電極175のそれぞれに正極集電体180および負極集電体190を介して電気的に接続された正極端子141および負極端子151が配設されている。   As shown in FIGS. 2 and 3, the battery lid 102 has a rectangular flat plate shape and is welded so as to close the opening of the battery can 101. That is, the battery lid 102 seals the battery can 101. The battery lid 102 has a positive electrode terminal 141 and a negative electrode terminal 151 electrically connected to the positive electrode 174 and the negative electrode 175 of the wound electrode group 170 via the positive electrode current collector 180 and the negative electrode current collector 190, respectively. It is arranged.

正極端子141が正極集電体180を介して捲回電極群170の正極電極174に電気的に接続され、負極端子151が負極集電体190を介して捲回電極群170の負極電極175に電気的に接続されているため、正極端子141および負極端子151を介して外部負荷に電力が供給され、あるいは、正極端子141および負極端子151を介して外部発電電力が捲回電極群170に供給されて充電される。   The positive electrode terminal 141 is electrically connected to the positive electrode 174 of the wound electrode group 170 via the positive electrode current collector 180, and the negative electrode terminal 151 is connected to the negative electrode 175 of the wound electrode group 170 via the negative electrode current collector 190. Since it is electrically connected, power is supplied to the external load via the positive electrode terminal 141 and the negative electrode terminal 151, or external generated power is supplied to the wound electrode group 170 via the positive electrode terminal 141 and the negative electrode terminal 151. And charged.

図3に示すように、電池蓋102には、電池容器内に電解液を注入するための注液孔106aが穿設されている。注液孔106aは、電解液注入後に注液栓106bによって封止される。電解液としては、たとえば、エチレンカーボネート等の炭酸エステル系の有機溶媒に6フッ化リン酸リチウム(LiPF)等のリチウム塩が溶解された非水電解液を用いることができる。 As shown in FIG. 3, the battery lid 102 is provided with a liquid injection hole 106a for injecting an electrolytic solution into the battery container. The liquid injection hole 106a is sealed by a liquid injection plug 106b after the electrolytic solution is injected. As the electrolytic solution, for example, a non-aqueous electrolytic solution in which a lithium salt such as lithium hexafluorophosphate (LiPF 6 ) is dissolved in a carbonate-based organic solvent such as ethylene carbonate can be used.

図2に示すように、電池蓋102には、ガス排出弁103が設けられている。ガス排出弁103は、プレス加工によって電池蓋102を部分的に薄肉化することで形成されている。ガス排出弁103には、開裂時に大きな開口が形成されるように開裂溝が形成されている。ガス排出弁103は、単電池が過充電等の異常により発熱してガスが発生し、電池容器内の圧力が上昇して所定圧力に達したときに開裂して、内部からガスを排出することで電池容器内の圧力を低減させる。   As shown in FIG. 2, the battery cover 102 is provided with a gas discharge valve 103. The gas discharge valve 103 is formed by partially thinning the battery lid 102 by press working. The gas discharge valve 103 is formed with a cleavage groove so that a large opening is formed at the time of cleavage. The gas discharge valve 103 generates heat due to abnormalities such as overcharging of the unit cell, generates gas, and when the pressure in the battery container rises and reaches a predetermined pressure, the gas discharge valve 103 is opened and discharges the gas from the inside. To reduce the pressure in the battery container.

図4を参照して、捲回電極群170について説明する。図4は捲回電極群170を示す斜視図である。蓄電要素である捲回電極群170は、図4に示すように、長尺状の正極電極174および負極電極175をセパレータ173を介在させて捲回軸W周りに扁平形状に捲回することで積層構造とされている。   The wound electrode group 170 will be described with reference to FIG. FIG. 4 is a perspective view showing the wound electrode group 170. As shown in FIG. 4, the wound electrode group 170 that is a power storage element is obtained by winding a long positive electrode 174 and a negative electrode 175 in a flat shape around a winding axis W with a separator 173 interposed therebetween. It is a laminated structure.

正極電極174は、正極箔171と、正極活物質に結着材(バインダ)を配合した正極活物質合剤が正極箔171の両面に塗工されて形成された正極活物質合剤層176とを有する。負極電極175は、負極箔172と、負極活物質に結着材(バインダ)を配合した負極活物質合剤が負極箔172の両面に塗工されて形成された負極活物質合剤層177とを有する。正極活物質と負極活物質との間では、充放電が行われる。   The positive electrode 174 includes a positive electrode foil 171 and a positive electrode active material mixture layer 176 formed by coating a positive electrode active material mixture in which a binder (binder) is mixed with a positive electrode active material on both surfaces of the positive electrode foil 171. Have The negative electrode 175 includes a negative electrode foil 172 and a negative electrode active material mixture layer 177 formed by coating a negative electrode active material mixture in which a binder (binder) is mixed with a negative electrode active material on both surfaces of the negative electrode foil 172. Have Charging / discharging is performed between the positive electrode active material and the negative electrode active material.

正極箔171は、厚さ20〜30μm程度のアルミニウム合金箔であり、負極箔172は、厚さ15〜20μm程度の銅合金箔である。セパレータ173の素材は多孔質のポリエチレン樹脂である。正極活物質は、マンガン酸リチウム等のリチウム含有遷移金属複酸化物であり、負極活物質は、リチウムイオンを可逆に吸蔵、放出可能な黒鉛等の炭素材である。   The positive foil 171 is an aluminum alloy foil having a thickness of about 20 to 30 μm, and the negative foil 172 is a copper alloy foil having a thickness of about 15 to 20 μm. The material of the separator 173 is a porous polyethylene resin. The positive electrode active material is a lithium-containing transition metal double oxide such as lithium manganate, and the negative electrode active material is a carbon material such as graphite capable of reversibly occluding and releasing lithium ions.

捲回電極群170の幅方向(捲回方向に直交する捲回軸W方向)の両端部は、一方が正極活物質合剤層176が形成されていない未塗工部(正極箔171の露出部)が積層された部分とされ、他方が負極活物質合剤層177が形成されていない未塗工部(負極箔172の露出部)が積層された部分とされている。正極側未塗工部の積層体および負極側未塗工部の積層体は、それぞれ予め押し潰され、それぞれ後述の電池蓋組立体107の正極集電体180および負極集電体190(図3参照)と超音波接合により接続される。   One end of both ends of the wound electrode group 170 in the width direction (winding axis W direction orthogonal to the winding direction) is an uncoated portion where the positive electrode active material mixture layer 176 is not formed (exposure of the positive electrode foil 171). Part) is a part where the negative electrode active material mixture layer 177 is not formed, and the other part is a part where the uncoated part (exposed part of the negative electrode foil 172) is laminated. The laminated body of the positive electrode side uncoated part and the laminated body of the negative electrode side uncoated part are respectively crushed in advance, and are respectively positive electrode current collector 180 and negative electrode current collector 190 (see FIG. 3) of battery lid assembly 107 described later. And the ultrasonic bonding.

図3に示すように、電池蓋組立体107は、電池蓋102と、電池蓋102に設けられた一対の貫通孔102hのそれぞれに取り付けられた正極端子141および負極端子151と、正極集電体180および負極集電体190と、一対のガスケット130と、一対の絶縁部材160とを含んで構成されている。   As shown in FIG. 3, the battery lid assembly 107 includes a battery lid 102, a positive terminal 141 and a negative terminal 151 attached to each of a pair of through holes 102 h provided in the battery lid 102, and a positive current collector. 180 and the negative electrode current collector 190, a pair of gaskets 130, and a pair of insulating members 160.

正極端子141および正極集電体180の材質はアルミニウム合金である。正極端子141は、正極集電体180に電気的に接続される。負極端子151および負極集電体190の材質は銅合金である。負極端子151は、負極集電体190に電気的に接続される。絶縁部材160およびガスケット130の材質は、ポリブチレンテレフタレートやポリフェニレンサルファイド、ペルフルオロアルコキシフッ素樹脂等の絶縁性を有する樹脂である。   The material of the positive electrode terminal 141 and the positive electrode current collector 180 is an aluminum alloy. The positive electrode terminal 141 is electrically connected to the positive electrode current collector 180. The material of the negative electrode terminal 151 and the negative electrode current collector 190 is a copper alloy. The negative electrode terminal 151 is electrically connected to the negative electrode current collector 190. The material of the insulating member 160 and the gasket 130 is an insulating resin such as polybutylene terephthalate, polyphenylene sulfide, perfluoroalkoxy fluororesin.

図5(a)は図2のV−V線切断断面図であり、図5(b)は図5(a)のA部拡大図である。図5では正極側の構成を示しているが、正極側と負極側とは、同様の形状、構成であるため、便宜上、かっこ書きで負極側の構成要素の参照番号を付している。なお、図5(a)ではバスバー110を二点鎖線で図示している。   5A is a cross-sectional view taken along the line VV in FIG. 2, and FIG. 5B is an enlarged view of a portion A in FIG. 5A. Although FIG. 5 shows the configuration on the positive electrode side, the positive electrode side and the negative electrode side have the same shape and configuration, and therefore, for convenience, reference numerals of components on the negative electrode side are given in parentheses. In FIG. 5A, the bus bar 110 is indicated by a two-dot chain line.

図5(a)に示すように、電池蓋102には、一対の円形状の貫通孔102hと、電池缶101の内側に向かって突出する一対の円形凸部102cが設けられている。貫通孔102hには、後述するガスケット130を介して正負極端子141,151の貫通部143,153が挿通される。円形凸部102cは、後述する絶縁部材160の円形凹部167に嵌合される。円形凸部102cは、電池蓋102の外表面から内側に向かってプレス加工されることで有底円筒形状に形成されている。   As shown in FIG. 5A, the battery lid 102 is provided with a pair of circular through holes 102 h and a pair of circular convex portions 102 c that protrude toward the inside of the battery can 101. The through-holes 143 and 153 of the positive and negative electrode terminals 141 and 151 are inserted through the through-hole 102h through a gasket 130 described later. The circular convex portion 102c is fitted into a circular concave portion 167 of the insulating member 160 described later. The circular convex portion 102 c is formed into a bottomed cylindrical shape by being pressed from the outer surface of the battery lid 102 toward the inside.

図3に示すように、正極集電体180は、電池蓋102の内面に沿って配置される矩形平板状の端子接続部181と、端子接続部181の長辺側部から略直角に曲がって、電池缶101の幅広面101aに沿いながら電池缶101の底面101cに向かって延在する平面板182と、平面板182の下端に設けた連結部186により接続される接合部183とを備えている。接合部183は、超音波接合により捲回電極群170の正極電極174に電気的に接続される部分であり、正極電極174との接合面183aを有している。端子接続部181には、後述する正極端子141の突部145が挿通される円形状の貫通孔184が設けられている。図5(a)に示すように、端子接続部181には、正極端子141がカシメおよび溶接により固着されている。   As shown in FIG. 3, the positive electrode current collector 180 is bent at a substantially right angle from a rectangular flat terminal connection portion 181 disposed along the inner surface of the battery lid 102 and a long side portion of the terminal connection portion 181. A flat plate 182 extending toward the bottom surface 101c of the battery can 101 along the wide surface 101a of the battery can 101, and a joint 183 connected by a connecting portion 186 provided at the lower end of the flat plate 182. Yes. The joint portion 183 is a portion that is electrically connected to the positive electrode 174 of the wound electrode group 170 by ultrasonic bonding, and has a joint surface 183 a with the positive electrode 174. The terminal connection portion 181 is provided with a circular through hole 184 into which a protrusion 145 of the positive electrode terminal 141 described later is inserted. As shown in FIG. 5A, the positive terminal 141 is fixed to the terminal connecting portion 181 by caulking and welding.

同様に、図3に示すように、負極集電体190は、電池蓋102の内面に沿って配置される矩形平板状の端子接続部191と、端子接続部191の長辺側部から略直角に曲がって、電池缶101の幅広面101aに沿いながら電池缶101の底面101cに向かって延在する平面板192と、平面板192の下端に設けた連結部196により接続される接合部193とを備えている。接合部193は、超音波接合により捲回電極群170の負極電極175に電気的に接続される部分であり、負極電極175との接合面193aを有している。端子接続部191には、後述する負極端子151の突部155が挿通される円形状の貫通孔194が設けられている。図5(a)に示すように、端子接続部191には、負極端子151がカシメおよび溶接により固着されている。   Similarly, as illustrated in FIG. 3, the negative electrode current collector 190 includes a rectangular plate-like terminal connection portion 191 disposed along the inner surface of the battery lid 102 and a substantially right angle from the long side portion of the terminal connection portion 191. A flat plate 192 extending toward the bottom surface 101c of the battery can 101 along the wide surface 101a of the battery can 101, and a joint 193 connected by a connecting portion 196 provided at the lower end of the flat plate 192. It has. The bonding portion 193 is a portion that is electrically connected to the negative electrode 175 of the wound electrode group 170 by ultrasonic bonding, and has a bonding surface 193 a with the negative electrode 175. The terminal connection portion 191 is provided with a circular through hole 194 into which a protrusion 155 of a negative electrode terminal 151 described later is inserted. As shown in FIG. 5A, the negative terminal 151 is fixed to the terminal connecting portion 191 by caulking and welding.

図5(a)に示すように、正負極集電体180,190の端子接続部181,191のそれぞれと、電池蓋102との間には絶縁部材160が配置されている。絶縁部材160は、正負極集電体180,190の端子接続部181,191のそれぞれと電池蓋102との間に介在されるベース部161と、ベース部161の電池蓋102長手方向の一端部から捲回電極群170側に向かって突出するように形成された位置規制部166と、ベース部161の電池蓋102長手方向の他端部から捲回電極群170側に向かって突出するように形成された係合壁164とを有している。   As shown in FIG. 5A, an insulating member 160 is disposed between the terminal connecting portions 181 and 191 of the positive and negative current collectors 180 and 190 and the battery lid 102. The insulating member 160 includes a base portion 161 interposed between each of the terminal connection portions 181 and 191 of the positive and negative electrode current collectors 180 and 190 and the battery lid 102, and one end portion of the base portion 161 in the longitudinal direction of the battery lid 102. The position restricting portion 166 formed so as to protrude from the winding electrode group 170 toward the winding electrode group 170 and the other end portion of the base portion 161 in the longitudinal direction of the battery lid 102 so as to protrude toward the winding electrode group 170 side. And an engagement wall 164 formed.

絶縁性を有する絶縁部材160のベース部161が、正負極集電体180,190の端子接続部181,191のそれぞれと電池蓋102との間に介在されているため、正負極集電体180,190のそれぞれと電池蓋102とは電気的に絶縁されている。   Since the base portion 161 of the insulating member 160 having an insulating property is interposed between each of the terminal connection portions 181 and 191 of the positive and negative current collectors 180 and 190 and the battery cover 102, the positive and negative current collector 180. , 190 and the battery lid 102 are electrically insulated.

位置規制部166は、捲回電極群170に当接される位置規制面166aを有している。捲回電極群170は、この位置規制面166aに面接触した状態で、正負極集電体180,190に超音波接合される。   The position restricting portion 166 has a position restricting surface 166 a that comes into contact with the wound electrode group 170. The wound electrode group 170 is ultrasonically bonded to the positive and negative electrode current collectors 180 and 190 while being in surface contact with the position regulating surface 166a.

絶縁部材160には、ベース部161と、係合壁164と、位置規制部166とによって凹部162が形成されている。正負極集電体180,190の端子接続部181,191は、それぞれ絶縁部材160の凹部162に嵌合されている。   The insulating member 160 has a recess 162 formed by a base portion 161, an engagement wall 164, and a position restricting portion 166. The terminal connection portions 181 and 191 of the positive and negative current collectors 180 and 190 are fitted in the recesses 162 of the insulating member 160, respectively.

図3に示すように、絶縁部材160のベース部161には、後述する正負極端子141,151の貫通部143,153(図5(a)参照)が挿通される円形状の貫通孔161hが設けられている。図5(a)に示すように、位置規制部166には、電池蓋102の円形凸部102cに対向する位置において、電池蓋102側が開口するように円形凹部167が設けられている。円形凹部167は、平面視円形状の底面と、底面から垂直に立ち上がる内周面とを有している。   As shown in FIG. 3, the base portion 161 of the insulating member 160 has circular through holes 161h into which through portions 143 and 153 (see FIG. 5A) of positive and negative electrode terminals 141 and 151 described later are inserted. Is provided. As shown in FIG. 5A, the position restricting portion 166 is provided with a circular concave portion 167 so as to open the battery lid 102 side at a position facing the circular convex portion 102c of the battery lid 102. The circular recess 167 has a circular bottom surface in plan view and an inner peripheral surface that rises perpendicularly from the bottom surface.

図5(a)に示すように、電池蓋102の円形凸部102cは、絶縁部材160の円形凹部167に嵌合されている。円形凹部167に円形凸部102cが嵌合されると、円形凹部167の内周面に円形凸部102cの外周面が当接する。   As shown in FIG. 5A, the circular convex portion 102 c of the battery lid 102 is fitted into the circular concave portion 167 of the insulating member 160. When the circular convex portion 102 c is fitted into the circular concave portion 167, the outer peripheral surface of the circular convex portion 102 c comes into contact with the inner peripheral surface of the circular concave portion 167.

図6は正極端子141を示す破断斜視図である。なお、図6では正極端子141を示しているが、正極端子141と負極端子151とは材質のみが異なり、同様の形状であるため、便宜上、かっこ書きで負極端子151の構成要素の参照番号を付している。   FIG. 6 is a cutaway perspective view showing the positive electrode terminal 141. Although FIG. 6 shows the positive electrode terminal 141, the positive electrode terminal 141 and the negative electrode terminal 151 differ only in material and have the same shape. Therefore, for convenience, the reference numerals of the components of the negative electrode terminal 151 are indicated in parentheses. It is attached.

図6に示すように、正極端子141は、円柱形状の外部端子部142と、外部端子部142の一端から電池蓋102側に向かって突設されて、上記した電池蓋102の貫通孔102hおよび絶縁部材160の貫通孔161hを貫通する円柱形状の貫通部143と、貫通部143の一端から捲回電極群170側に向かって突設された円筒状の突部145とを備えている。正極端子141は、貫通部143の外径寸法が外部端子部142の外径寸法よりも小さく、突部145の外径寸法が貫通部143の外径寸法よりも小さくなるように形成されている。   As shown in FIG. 6, the positive electrode terminal 141 is provided with a cylindrical external terminal portion 142, protruding from one end of the external terminal portion 142 toward the battery lid 102, and the above-described through-hole 102 h and the battery lid 102. A cylindrical penetrating portion 143 penetrating through the through-hole 161h of the insulating member 160 and a cylindrical projecting portion 145 projecting from one end of the penetrating portion 143 toward the wound electrode group 170 side are provided. The positive electrode terminal 141 is formed such that the outer diameter size of the through portion 143 is smaller than the outer diameter size of the external terminal portion 142, and the outer diameter size of the protrusion 145 is smaller than the outer diameter size of the through portion 143. .

図5(a)に示すように、外部端子部142は、バスバー110が溶接される部分であって、その頂面はバスバー110が当接されるバスバー当接面142aとされている。外部端子部142には、バスバー当接面142aから外方に突出するように、円柱形状の位置決め凸部144が設けられている。位置決め凸部144は、バスバー110の位置決めを容易に行うために設けられるものであり、省略することもできる。バスバー110は、バスバー当接面142aに当接された状態で、レーザ溶接される。   As shown in FIG. 5A, the external terminal portion 142 is a portion to which the bus bar 110 is welded, and its top surface is a bus bar abutting surface 142a against which the bus bar 110 abuts. The external terminal portion 142 is provided with a cylindrical positioning convex portion 144 so as to protrude outward from the bus bar abutting surface 142a. The positioning convex portion 144 is provided for easily positioning the bus bar 110 and can be omitted. The bus bar 110 is laser-welded while being in contact with the bus bar contact surface 142a.

正極端子141の貫通部143は、ガスケット130が装着された状態で、電池蓋102の貫通孔102hに挿通される。外部端子部142の円環状端面は、後述するガスケット130の鍔部130bに当接される面であり、この円環状端面には、図6に示すように円環状の第1突起142bおよび第2突起142cが設けられている。   The through portion 143 of the positive terminal 141 is inserted into the through hole 102h of the battery lid 102 with the gasket 130 attached. An annular end surface of the external terminal portion 142 is a surface that comes into contact with a flange portion 130b of the gasket 130, which will be described later, and the annular end surface includes an annular first protrusion 142b and a second projection as shown in FIG. A protrusion 142c is provided.

同様に、図6に示すように、負極端子151は、円柱形状の外部端子部152と、外部端子部152の一端から電池蓋102側に向かって突設されて、上記した電池蓋102の貫通孔102hおよび絶縁部材160の貫通孔161hを貫通する円柱形状の貫通部153と、貫通部153の一端から捲回電極群170側に向かって突設された円筒状の突部155とを備えている。負極端子151は、貫通部153の外径寸法が外部端子部152の外径寸法よりも小さく、突部155の外径寸法が貫通部153の外径寸法よりも小さくなるように形成されている。   Similarly, as shown in FIG. 6, the negative electrode terminal 151 is provided with a cylindrical external terminal portion 152, and protrudes from one end of the external terminal portion 152 toward the battery lid 102, and penetrates the battery lid 102 described above. A cylindrical penetrating portion 153 that passes through the hole 102h and the through hole 161h of the insulating member 160, and a cylindrical projecting portion 155 that protrudes from one end of the penetrating portion 153 toward the wound electrode group 170 side. Yes. The negative electrode terminal 151 is formed such that the outer diameter size of the through portion 153 is smaller than the outer diameter size of the external terminal portion 152, and the outer diameter size of the protrusion 155 is smaller than the outer diameter size of the through portion 153. .

図5(a)に示すように、外部端子部152は、バスバー110が溶接される部分であって、その頂面はバスバー110が当接されるバスバー当接面152aとされている。外部端子部152には、バスバー当接面152aから外方に突出するように、円柱形状の位置決め凸部154が設けられている。位置決め凸部154は、バスバー110の位置決めを容易に行うために設けられるものであり、省略することもできる。バスバー110は、バスバー当接面152aに当接された状態で、レーザ溶接される。   As shown in FIG. 5A, the external terminal portion 152 is a portion to which the bus bar 110 is welded, and its top surface is a bus bar abutting surface 152a against which the bus bar 110 abuts. The external terminal portion 152 is provided with a cylindrical positioning convex portion 154 so as to protrude outward from the bus bar contact surface 152a. The positioning convex portion 154 is provided for easily positioning the bus bar 110 and can be omitted. The bus bar 110 is laser-welded while being in contact with the bus bar contact surface 152a.

負極端子151の貫通部153は、ガスケット130が装着された状態で、電池蓋102の貫通孔102hに挿通される。外部端子部152の円環状端面は、後述するガスケット130の鍔部130bに当接される面であり、この円環状端面には、図6に示すように円環状の第1突起152bおよび第2突起152cが設けられている。   The through portion 153 of the negative electrode terminal 151 is inserted into the through hole 102h of the battery lid 102 with the gasket 130 attached. An annular end surface of the external terminal portion 152 is a surface that comes into contact with a flange portion 130b of a gasket 130, which will be described later, and the annular end surface includes an annular first protrusion 152b and a second projection as shown in FIG. A protrusion 152c is provided.

図5(a)に示すように、ガスケット130は、円筒状の筒部130aと、筒部130aの上端から外方に延在する円環状の鍔部130bと、鍔部130bの外縁から上方に立ち上がる円筒状の覆い部130cとを有している。   As shown in FIG. 5A, the gasket 130 includes a cylindrical tube portion 130a, an annular flange portion 130b extending outward from the upper end of the tube portion 130a, and an upper edge from the outer edge of the flange portion 130b. And a cylindrical cover portion 130c that rises.

正極端子141の円筒状の突部145は、正極集電体180の端子接続部181に形成された貫通孔184に挿通される。外部端子部142の下端面と電池蓋102の外表面とでガスケット130の鍔部130bが挟まれ、貫通部143の下端面が端子接続部181に当接された状態で、円筒状の突部145の先端が正極集電体180の端子接続部181にかしめられる。   The cylindrical protrusion 145 of the positive electrode terminal 141 is inserted into a through hole 184 formed in the terminal connection portion 181 of the positive electrode current collector 180. A cylindrical protrusion with the flange 130b of the gasket 130 sandwiched between the lower end surface of the external terminal portion 142 and the outer surface of the battery lid 102, and the lower end surface of the through portion 143 being in contact with the terminal connection portion 181. The tip of 145 is caulked to the terminal connection portion 181 of the positive electrode current collector 180.

その結果、図5(a)に示すように、正極集電体180の端子接続部181はカシメ部145sと貫通部143の下端面によって挟持され、絶縁部材160、電池蓋102およびガスケット130の鍔部130bは端子接続部181と外部端子部142の下端面とによって挟持されている。カシメ部145sと端子接続部181とは、かしめ固定された後、レーザによりスポット溶接される。   As a result, as shown in FIG. 5A, the terminal connection portion 181 of the positive electrode current collector 180 is sandwiched between the crimping portion 145s and the lower end surface of the through portion 143, and the insulating member 160, the battery lid 102, and the gasket 130 The part 130 b is sandwiched between the terminal connection part 181 and the lower end surface of the external terminal part 142. The caulking portion 145s and the terminal connection portion 181 are spot-welded by laser after being caulked and fixed.

同様に、負極端子151の円筒状の突部155は、負極集電体190の端子接続部191に形成された貫通孔194に挿通される。外部端子部152の下端面と電池蓋102の外表面とでガスケット130の鍔部130bが挟まれ、貫通部153の下端面が端子接続部191に当接された状態で、円筒状の突部155の先端が負極集電体190の端子接続部191にかしめられる。   Similarly, the cylindrical protrusion 155 of the negative electrode terminal 151 is inserted into a through hole 194 formed in the terminal connection portion 191 of the negative electrode current collector 190. A cylindrical protrusion with the flange 130b of the gasket 130 sandwiched between the lower end surface of the external terminal portion 152 and the outer surface of the battery lid 102 and the lower end surface of the through portion 153 in contact with the terminal connection portion 191. The tip of 155 is caulked to the terminal connection portion 191 of the negative electrode current collector 190.

その結果、図5(a)に示すように、負極集電体190の端子接続部191はカシメ部155sと貫通部153の下端面によって挟持され、絶縁部材160、電池蓋102およびガスケット130の鍔部130bは端子接続部191と外部端子部152の下端面とによって挟持されている。カシメ部155sと端子接続部191とは、かしめ固定された後、レーザによりスポット溶接される。   As a result, as shown in FIG. 5A, the terminal connection portion 191 of the negative electrode current collector 190 is sandwiched between the crimping portion 155s and the lower end surface of the through portion 153, and the insulating member 160, the battery lid 102, and the gasket 130 The part 130 b is sandwiched between the terminal connection part 191 and the lower end surface of the external terminal part 152. The caulking portion 155s and the terminal connecting portion 191 are spot-welded by a laser after being caulked and fixed.

このように、正極端子141は、正極集電体180の端子接続部181にカシメおよび溶接により固着され、負極端子151は、負極集電体190の端子接続部191にカシメおよび溶接により固着されている。これにより、正極集電体180と正極端子141とが電気的に接続され、負極集電体190と負極端子151とが電気的に接続される。   Thus, the positive electrode terminal 141 is fixed to the terminal connection part 181 of the positive electrode current collector 180 by caulking and welding, and the negative electrode terminal 151 is fixed to the terminal connection part 191 of the negative electrode current collector 190 by caulking and welding. Yes. Thereby, the positive electrode current collector 180 and the positive electrode terminal 141 are electrically connected, and the negative electrode current collector 190 and the negative electrode terminal 151 are electrically connected.

図5(a)に示すように、ガスケット130の筒部130aは、正負極端子141,151の貫通部143,153のそれぞれと、電池蓋102の貫通孔102hとの間に介在するように配置されている。ガスケット130の鍔部130bは、第1突起142b,152bおよび第2突起142c,152cに押圧され、所定量圧縮された状態で、電池蓋102の外表面と正負極端子141,151の外部端子部142,152の円環状端面との間に介在するように配置されている。   As shown in FIG. 5A, the cylindrical portion 130 a of the gasket 130 is disposed so as to be interposed between the through portions 143 and 153 of the positive and negative electrode terminals 141 and 151 and the through hole 102 h of the battery lid 102. Has been. The flange 130b of the gasket 130 is pressed by the first protrusions 142b and 152b and the second protrusions 142c and 152c and compressed by a predetermined amount, and the outer surface of the battery lid 102 and the external terminal portions of the positive and negative terminals 141 and 151 It arrange | positions so that it may interpose between the annular | circular shaped end surfaces of 142,152.

これにより、正負極端子141,151のそれぞれと電池蓋102との間が封止され、電池容器の気密性が確保されている。ガスケット130は上記したように絶縁性を有しているため、正負極端子141,151のそれぞれと電池蓋102とは電気的に絶縁されている。   Thereby, between each of the positive / negative terminal 141,151 and the battery cover 102 is sealed, and the airtightness of the battery container is ensured. Since the gasket 130 has an insulating property as described above, each of the positive and negative electrode terminals 141 and 151 and the battery cover 102 are electrically insulated.

円環状の第1突起142b,152bおよび第2突起142c,152cにより、ガスケット130の鍔部130bの全周に亘って、鍔部130bを圧縮しているため、圧縮量に偏りがあっても、ガスケット130の鍔部130bと第1突起142b,152bおよび第2突起142c,152cとの接触を全周に亘って維持して、電池容器の気密性の安定度を確保できる。   Since the flange 130b is compressed over the entire circumference of the flange 130b of the gasket 130 by the annular first protrusions 142b and 152b and the second protrusions 142c and 152c, even if the compression amount is uneven, The contact between the flange portion 130b of the gasket 130 and the first protrusions 142b and 152b and the second protrusions 142c and 152c can be maintained over the entire circumference, thereby ensuring the stability of the airtightness of the battery container.

図5(b)に示すように、正負極端子141,151の外部端子部142,152のそれぞれは、電池蓋102の貫通孔102hから外方に向かって突出している。ガスケット130の覆い部130cは、外部端子部142,152のそれぞれの電池蓋側外周面を覆うように、外部端子部142,152に密着している。図5(b)に示すように覆い部130cの先端は、バスバー当接面142a,152aよりも電池蓋102側に位置している。   As shown in FIG. 5B, the external terminal portions 142 and 152 of the positive and negative terminals 141 and 151 protrude outward from the through hole 102 h of the battery lid 102. The cover portion 130c of the gasket 130 is in close contact with the external terminal portions 142 and 152 so as to cover the battery cover side outer peripheral surfaces of the external terminal portions 142 and 152, respectively. As shown in FIG. 5B, the tip of the cover 130c is located closer to the battery lid 102 than the bus bar contact surfaces 142a and 152a.

ガスケット130の覆い部130cの先端から電池蓋102の外表面までの設計寸法L11は、正負極端子141,151と電池蓋102との間の導通を防止するための沿面距離から得られる最小寸法L12と、バスバー110と外部端子部142,152との間に形成される溶接金属とガスケット130との間の最短距離から得られる離間寸法L13とを考慮して決定される。   The design dimension L11 from the tip of the cover part 130c of the gasket 130 to the outer surface of the battery cover 102 is the minimum dimension L12 obtained from the creeping distance for preventing conduction between the positive and negative terminals 141 and 151 and the battery cover 102. And a separation dimension L13 obtained from the shortest distance between the weld metal formed between the bus bar 110 and the external terminal portions 142 and 152 and the gasket 130.

覆い部130cの先端から電池蓋102の外表面までの最小寸法L12は、絶縁性を確保すること、すなわち正負極端子141,151と電池容器との間の導通を防止するための沿面距離を観点に決定される。たとえば、最小寸法L12は、DIN規格などの各種安全規格に示される電圧と沿面距離との関係値を参考に決定することができる。本実施の形態では、単電池の直流電圧を5Vとし、規格資料(DIN VDE 0110b:1972−02)より沿面距離を求めた。沿面距離は、規格表の最低直流電圧を15V、用途を絶縁グループDとして、2.3mmが参考値として得られる。最小寸法L12は、参考値として得られた沿面距離を考慮して決定される。   The minimum dimension L12 from the tip of the cover part 130c to the outer surface of the battery lid 102 is to ensure insulation, that is, from the viewpoint of creepage distance to prevent conduction between the positive and negative terminals 141, 151 and the battery container. To be determined. For example, the minimum dimension L12 can be determined with reference to the relationship value between the voltage and creepage distance indicated in various safety standards such as the DIN standard. In the present embodiment, the creepage distance was determined from the standard document (DIN VDE 0110b: 1972-02) with the DC voltage of the unit cell set to 5V. The creepage distance is 2.3 mm as a reference value with the minimum DC voltage in the specification table being 15 V and the application being the insulation group D. The minimum dimension L12 is determined in consideration of the creepage distance obtained as a reference value.

覆い部130cの先端は、バスバー110を溶接するときの入熱によりガスケット130が熱変形しないように、所定距離だけバスバー当接面142a,152aから離間させる。外部端子部142,152の頂面であるバスバー当接面142a,152aからガスケット130の覆い部130cの先端までの離間寸法L13は、バスバー110を正負極端子141,151の外部端子部142,152にレーザ溶接するときの入熱からガスケット130を保護することを観点に決定される。   The front end of the cover portion 130c is separated from the bus bar abutting surfaces 142a and 152a by a predetermined distance so that the gasket 130 is not thermally deformed by heat input when the bus bar 110 is welded. The separation dimension L13 from the bus bar abutting surfaces 142a, 152a, which are the top surfaces of the external terminal portions 142, 152, to the tip of the cover portion 130c of the gasket 130 is such that the bus bar 110 is connected to the external terminal portions 142, 152 of the positive and negative terminals 141, 151. It is determined from the viewpoint of protecting the gasket 130 from heat input when laser welding is performed.

離間寸法L13は、正負極端子141,151の大きさ、バスバー110の材質、バスバー110の厚み、溶接速度、溶接エネルギー、溶接面積、溶接位置、および、ガスケット130の材質(耐熱性)等を考慮して決定することができる。本実施の形態では、レーザ溶接により形成される溶接金属と、ガスケット130の覆い部130cとの間の最短距離を考慮して離間寸法L13を決定した。   The separation dimension L13 considers the size of the positive and negative terminals 141, 151, the material of the bus bar 110, the thickness of the bus bar 110, the welding speed, the welding energy, the welding area, the welding position, the material of the gasket 130 (heat resistance), and the like. Can be determined. In the present embodiment, the separation dimension L13 is determined in consideration of the shortest distance between the weld metal formed by laser welding and the cover 130c of the gasket 130.

図7(a)はバスバー110の溶接位置を示す平面模式図である。図7(b)は組電池を構成する単電池の正極端子141とバスバー110との接続構造を示す概念図であり、図7(a)のB−B線切断断面を模式的に示している。なお、図7(b)では正極側の接続構造を示しているが、負極側も同様の構成であるため、便宜上、かっこ書きで負極側の構成要素の参照番号を付しており、負極側については、図7(a)のC−C線切断面を模式的に示している。   FIG. 7A is a schematic plan view showing the welding position of the bus bar 110. FIG. 7B is a conceptual diagram showing a connection structure between the positive electrode terminal 141 of the single battery constituting the assembled battery and the bus bar 110, and schematically shows a cross section taken along line BB in FIG. 7A. . 7B shows the connection structure on the positive electrode side, but since the negative electrode side has the same configuration, the reference numerals of the components on the negative electrode side are given in parentheses for convenience, and the negative electrode side is attached. Fig. 7 schematically shows a cut surface taken along the line C-C of Fig. 7A.

図7(a)および図7(b)を参照して、バスバー110の溶接位置、ならびに、溶接金属とガスケット130との間の最短距離L10を説明する。図7(a)および図7(b)に示すように、正負極端子141,151の位置決め凸部144,154と、バスバー110の位置決め孔110h1,110h2の内周面とは突き合わせ溶接されている。レーザは、バスバー110の表面に垂直に、上方からバスバー110に照射される。   With reference to Fig.7 (a) and FIG.7 (b), the welding position of the bus-bar 110 and the shortest distance L10 between a weld metal and the gasket 130 are demonstrated. As shown in FIGS. 7A and 7B, the positioning convex portions 144 and 154 of the positive and negative terminals 141 and 151 and the inner peripheral surfaces of the positioning holes 110h1 and 110h2 of the bus bar 110 are butt welded. . The laser is irradiated on the bus bar 110 from above, perpendicular to the surface of the bus bar 110.

図7(a)および図7(b)に示すように、正極側では、正極端子141の位置決め凸部144の先端側からレーザが照射され、位置決め凸部144の全周に亘ってレーザ溶接され、溶接金属w11が形成される。負極側では、負極端子151の位置決め凸部154の先端側からレーザが照射され、位置決め凸部154の周の一部においてレーザ溶接され、溶接金属w12が形成される。なお、溶接金属w11,w12の溶け込み深さh1は、外部端子部142,152のバスバー当接面142a,152aまでは達していない。   As shown in FIGS. 7A and 7B, on the positive electrode side, laser is irradiated from the tip side of the positioning convex portion 144 of the positive terminal 141, and laser welding is performed over the entire circumference of the positioning convex portion 144. The weld metal w11 is formed. On the negative electrode side, laser is irradiated from the tip side of the positioning convex portion 154 of the negative electrode terminal 151, and laser welding is performed on a part of the circumference of the positioning convex portion 154 to form a weld metal w12. In addition, the penetration depth h1 of the weld metals w11 and w12 does not reach the bus bar contact surfaces 142a and 152a of the external terminal portions 142 and 152.

図7(b)に示す溶接金属w11,w12とガスケット130との間の最短距離L10は、2mm以上とすることが望ましい。離間寸法L13は、最短距離L10が2mm以上となるように考慮して決定される。離間寸法L13が得られると、電池蓋102の外表面からバスバー当接面142a,152aまでの寸法L14から離間寸法L13を差し引くことで、覆い部130cの先端から電池蓋102までの最大寸法L15が決定される(L15=L14−L13)。   The shortest distance L10 between the weld metals w11 and w12 and the gasket 130 shown in FIG. 7B is desirably 2 mm or more. The separation dimension L13 is determined in consideration of the shortest distance L10 being 2 mm or more. When the separation dimension L13 is obtained, the maximum dimension L15 from the front end of the cover 130c to the battery lid 102 is obtained by subtracting the separation dimension L13 from the dimension L14 from the outer surface of the battery lid 102 to the bus bar contact surfaces 142a and 152a. It is determined (L15 = L14-L13).

以上のとおり、正負極端子141,151と電池容器との間の導通を防止するための沿面距離を考慮して最小寸法L12が決定され、バスバー110を外部端子部142,152に溶接するときの入熱を考慮して最大寸法L15が決定される。最小寸法L12と、最大寸法L15とが決定されると、最小寸法L12以上、かつ、最大寸法L15以下となるように、ガスケット130の覆い部130cの先端から電池蓋102の外表面までの設計寸法L11が決定される(L12≦L11≦L15)。   As described above, the minimum dimension L12 is determined in consideration of the creepage distance for preventing conduction between the positive and negative terminals 141 and 151 and the battery case, and the bus bar 110 is welded to the external terminal portions 142 and 152. The maximum dimension L15 is determined in consideration of heat input. When the minimum dimension L12 and the maximum dimension L15 are determined, the design dimension from the tip of the cover 130c of the gasket 130 to the outer surface of the battery lid 102 is equal to or greater than the minimum dimension L12 and equal to or less than the maximum dimension L15. L11 is determined (L12 ≦ L11 ≦ L15).

上述した本実施の形態によれば、以下のような作用効果を奏することができる。
電池蓋102の貫通孔102hから外方に向かって突出する正負極端子141,151の外部端子部142,152のそれぞれの外周面を密着して覆う覆い部130cをガスケット130に設けた。覆い部130cの先端から電池蓋102までの寸法は、正負極端子141,151と電池蓋102との間の導通を防止するための沿面距離と、バスバー110を外部端子部142,152に溶接するときの入熱とを考慮して決定し、覆い部130cの先端が、外部端子部142,152のバスバー当接面142a,152aよりも電池蓋102側に位置するようにガスケット130を形成した。これにより、結露等により電池蓋102に水滴が付着しても正負極端子141,151と電池蓋102との絶縁性を確保することができるとともに、バスバー110を溶接するときの入熱に起因したガスケット130の熱変形を防止できる。
According to this embodiment described above, the following operational effects can be achieved.
The gasket 130 is provided with a cover portion 130c that tightly covers the outer peripheral surfaces of the external terminal portions 142 and 152 of the positive and negative electrode terminals 141 and 151 protruding outward from the through hole 102h of the battery lid 102. The dimensions from the tip of the cover 130 c to the battery lid 102 are the creepage distance to prevent conduction between the positive and negative terminals 141, 151 and the battery lid 102, and the bus bar 110 is welded to the external terminal portions 142, 152. The gasket 130 was formed so that the front end of the cover portion 130c was positioned closer to the battery lid 102 than the bus bar contact surfaces 142a and 152a of the external terminal portions 142 and 152. As a result, even if water droplets adhere to the battery lid 102 due to condensation or the like, it is possible to ensure insulation between the positive and negative electrode terminals 141 and 151 and the battery lid 102 and also due to heat input when the bus bar 110 is welded. Thermal deformation of the gasket 130 can be prevented.

これに対して、特許文献1に記載の従来技術では、円盤形状の外部端子部に、外部端子部を密着して覆う覆い部がガスケットに設けられていない。したがって、従来技術では、電池と外気との間で温度差が生じる使用環境において、外気に含まれる水蒸気が電池容器において結露して水滴となり、結露水により端子と電池容器との間が導通されて、電池容器を介して正負極端子間で短絡が生じるおそれがある。   On the other hand, in the prior art described in Patent Document 1, a cover portion that tightly covers the external terminal portion is not provided in the gasket on the disk-shaped external terminal portion. Therefore, in the conventional technology, in a usage environment in which a temperature difference occurs between the battery and the outside air, water vapor contained in the outside air is condensed into water droplets in the battery container, and the terminal and the battery container are electrically connected by the dew condensation water. There is a possibility that a short circuit may occur between the positive and negative electrode terminals via the battery container.

なお、ガス排出弁103から噴出したガスや電解液のガス排出経路上に正負極端子141,151がある場合には、ガス排出弁103から噴出した電解液が、ガス排出経路上の他の単電池の電池容器に付着することもあるが、本実施の形態によれば、正負極端子141,151と電池容器との間の導通が覆い部130cにより防止されるため、ガス排出弁103の開裂時にも正負極端子141,151と電池蓋102との絶縁性を確保することができる。   When the positive and negative terminals 141 and 151 are on the gas discharge path of the gas or electrolyte solution jetted from the gas discharge valve 103, the electrolyte solution jetted from the gas discharge valve 103 is transferred to another unit on the gas discharge path. Although it may adhere to the battery container of the battery, according to the present embodiment, the continuity between the positive and negative electrode terminals 141 and 151 and the battery container is prevented by the cover 130c, so that the gas discharge valve 103 is cleaved. Sometimes, the insulation between the positive and negative terminals 141 and 151 and the battery cover 102 can be secured.

―第2の実施の形態―
図8および図9を参照して第2の実施の形態に係る二次電池(単電池)および組電池について説明する。図8は本発明の第2の実施の形態に係る組電池の斜視図である。図9は、組電池を構成する単電池の正極端子241とバスバー210との接続構造を示す概念図であり、図8のIX−IX線切断断面を模式的に示している。図9では正極側の接続構造を示しているが、負極側も同様の構成であるため、便宜上、かっこ書きで負極側の構成要素の参照番号も付している。図中、第1の実施の形態と同一もしくは相当部分には同一符号を付し、相違点を主に説明する。
-Second embodiment-
A secondary battery (unit cell) and an assembled battery according to the second embodiment will be described with reference to FIGS. 8 and 9. FIG. 8 is a perspective view of an assembled battery according to the second embodiment of the present invention. FIG. 9 is a conceptual diagram showing a connection structure between the positive electrode terminal 241 of the unit cell constituting the assembled battery and the bus bar 210, and schematically shows a cross section taken along line IX-IX in FIG. Although FIG. 9 shows the connection structure on the positive electrode side, since the negative electrode side has the same configuration, for convenience, reference numerals of components on the negative electrode side are also given in parentheses. In the figure, the same reference numerals are given to the same or corresponding parts as those in the first embodiment, and the differences will be mainly described.

第2の実施の形態では、正負極端子241,251の外部端子部242,252の形状、ならびに、外部端子部242,252の外周面を覆うガスケット230の覆い部230cの形状および鍔部230bの形状が第1実施形態と異なるが、その他の構成は第1実施形態と同一である。なお、第2の実施の形態では、外部端子部242,252に位置決め凸部が設けられておらず、バスバー210には位置決め孔が設けられていない。   In the second embodiment, the shape of the external terminal portions 242 and 252 of the positive and negative terminals 241, 251 and the shape of the cover portion 230c of the gasket 230 that covers the outer peripheral surface of the external terminal portions 242, 252 and the flange portion 230b. Although the shape is different from that of the first embodiment, other configurations are the same as those of the first embodiment. In the second embodiment, the external terminal portions 242 and 252 are not provided with positioning projections, and the bus bar 210 is not provided with positioning holes.

図8に示すように、第2の実施の形態に係る組電池を構成する各単電池200A〜200Cの正負極端子241,251のそれぞれには矩形柱形状の外部端子部242,252が設けられている。外部端子部242,252は、バスバー210が溶接される部分であって、その頂面はバスバー210の下面が当接されるバスバー当接面242a,252aとされている。   As shown in FIG. 8, rectangular column-shaped external terminal portions 242 and 252 are provided on the positive and negative terminals 241 and 251 of each of the unit cells 200A to 200C constituting the assembled battery according to the second embodiment. ing. The external terminal portions 242 and 252 are portions to which the bus bar 210 is welded, and the top surfaces thereof are bus bar abutting surfaces 242a and 252a with which the lower surface of the bus bar 210 abuts.

図9に示すように、外部端子部242,252の下端からは、第1の実施の形態と同様に、円柱形状の貫通部143,153が突設され、貫通部143,153の下端からは円筒状の突部145,155が突設されている。正負極端子241,251のそれぞれは、貫通部143,153の外径寸法が外部端子部242,252の外形寸法(幅寸法および長さ寸法)よりも小さく、突部145,155の外径寸法が貫通部143,153の外径寸法よりも小さくなるように形成されている。正負極端子241,251のそれぞれは、突部145,155が端子接続部181,191にかしめられることで正負極集電体180,190のそれぞれに固着されている(不図示)。   As shown in FIG. 9, cylindrical penetrating portions 143 and 153 project from the lower ends of the external terminal portions 242 and 252 as in the first embodiment, and from the lower ends of the penetrating portions 143 and 153, respectively. Cylindrical protrusions 145 and 155 are projected. Each of the positive and negative terminals 241 and 251 has an outer diameter of the through-portions 143 and 153 smaller than the outer dimensions (width and length) of the external terminals 242 and 252, and the outer diameters of the protrusions 145 and 155. Is formed to be smaller than the outer diameter of the through-holes 143 and 153. The positive and negative electrode terminals 241 and 251 are fixed to the positive and negative electrode current collectors 180 and 190, respectively, by projecting the protrusions 145 and 155 to the terminal connection portions 181 and 191 (not shown).

ガスケット230の鍔部230bは、外形が平面視矩形状の環状に形成され、円筒状の筒部130aの上端から外方に延在し、外部端子部242,252の下端面と電池蓋102との間に配置されている。ガスケット230の覆い部230cは、鍔部230bの外縁から立ち上がる矩形筒状に形成され、外部端子部242,252の外周面を密着して覆っている。   The flange portion 230b of the gasket 230 is formed in an annular shape having a rectangular shape in plan view, extends outward from the upper end of the cylindrical tube portion 130a, the lower end surfaces of the external terminal portions 242, 252 and the battery lid 102. It is arranged between. The cover portion 230c of the gasket 230 is formed in a rectangular cylindrical shape rising from the outer edge of the flange portion 230b, and covers the outer peripheral surfaces of the external terminal portions 242, 252 in close contact with each other.

図8に示すように、バスバー210と正負極端子241,251とは、レーザがバスバー210の表面に垂直に上方から照射されることで、レーザにより重ね貫通溶接される。正極端子241にバスバー210が溶接されると、平面視で相互に平行な一対の溶接金属w21が形成される。同様に、負極端子251にバスバー210が溶接されると、平面視で相互に平行な一対の溶接金属w22が形成される。   As shown in FIG. 8, the bus bar 210 and the positive and negative terminals 241 and 251 are overlapped and welded by laser when the laser is irradiated on the surface of the bus bar 210 vertically from above. When the bus bar 210 is welded to the positive terminal 241, a pair of weld metals w <b> 21 that are parallel to each other in a plan view are formed. Similarly, when the bus bar 210 is welded to the negative electrode terminal 251, a pair of weld metals w22 that are parallel to each other in a plan view are formed.

図9に示すように、溶接金属w21,w22は、中央部でバスバー当接面242a,252aまで達し、溶接金属w21,w22が正負極端子241,251とバスバー210との間の導通経路を形成している。溶接金属w21,w22の溶け込み深さは、正負極端子241,251の中心に向かうにしたがって深くなっている。   As shown in FIG. 9, the weld metals w <b> 21 and w <b> 22 reach the bus bar abutting surfaces 242 a and 252 a at the center, and the weld metals w <b> 21 and w <b> 22 form a conduction path between the positive and negative terminals 241 and 251 and the bus bar 210. doing. The penetration depth of the weld metals w21 and w22 becomes deeper toward the center of the positive and negative terminals 241 and 251.

溶接金属w21,w22とガスケット230との間の最短距離L20は、2mm以上とすることが望ましい。外部端子部242,252の頂面であるバスバー当接面242a,252aからガスケット230の覆い部230cの先端までの離間寸法L23は、最短距離L20が2mm以上となるように考慮して決定される。離間寸法L23が得られると、電池蓋102の外表面からバスバー当接面242a,252aまでの寸法L24から離間寸法L23を差し引くことで、覆い部230cの先端から電池蓋102までの最大寸法L25が決定される(L25=L24−L23)。   The shortest distance L20 between the weld metals w21, w22 and the gasket 230 is preferably 2 mm or more. The separation dimension L23 from the bus bar contact surfaces 242a and 252a, which are the top surfaces of the external terminal portions 242 and 252, to the tip of the cover portion 230c of the gasket 230 is determined in consideration of the shortest distance L20 being 2 mm or more. . When the separation dimension L23 is obtained, the maximum dimension L25 from the front end of the cover 230c to the battery lid 102 is obtained by subtracting the separation dimension L23 from the dimension L24 from the outer surface of the battery lid 102 to the bus bar contact surfaces 242a and 252a. It is determined (L25 = L24-L23).

覆い部230cの先端から電池蓋102の外表面までの最小寸法L22は、第1の実施の形態と同様に、正負極端子241,251と電池容器との間の導通を防止するための沿面距離を考慮して決定される。   The minimum dimension L22 from the front end of the cover 230c to the outer surface of the battery lid 102 is the creepage distance for preventing conduction between the positive and negative terminals 241 and 251 and the battery container, as in the first embodiment. Is determined in consideration of

以上のとおり、正負極端子241,251と電池容器との間の導通を防止するための沿面距離を考慮して最小寸法L22が決定され、バスバー210を外部端子部242,252に溶接するときの入熱を考慮して最大寸法L25が決定される。最小寸法L22と、最大寸法L25とが決定されると、最小寸法L22以上、かつ、最大寸法L25以下となるように、ガスケット230の覆い部230cの先端から電池蓋102の外表面までの設計寸法L21が決定される(L22≦L21≦L25)。   As described above, the minimum dimension L22 is determined in consideration of the creepage distance for preventing conduction between the positive and negative terminals 241 and 251 and the battery case, and the bus bar 210 is welded to the external terminal portions 242 and 252. The maximum dimension L25 is determined in consideration of heat input. When the minimum dimension L22 and the maximum dimension L25 are determined, the design dimension from the tip of the cover 230c of the gasket 230 to the outer surface of the battery lid 102 is equal to or greater than the minimum dimension L22 and not greater than the maximum dimension L25. L21 is determined (L22 ≦ L21 ≦ L25).

第2の実施の形態によれば、第1の実施の形態と同様に、結露等により電池蓋102に水滴が付着しても正負極端子241,251と電池蓋102との絶縁性を確保することができるとともに、バスバー210を溶接するときの入熱に起因したガスケット230の熱変形を防止できる。   According to the second embodiment, as in the first embodiment, the insulation between the positive and negative terminals 241 and 251 and the battery cover 102 is ensured even if water droplets adhere to the battery cover 102 due to condensation or the like. In addition, it is possible to prevent thermal deformation of the gasket 230 due to heat input when the bus bar 210 is welded.

さらに、第2の実施の形態では、外部端子部242,252が矩形柱形状に形成され、バスバー当接面242a,252aが平面視矩形状に形成されている。したがって、第2の実施の形態では、第1の実施の形態に比べて、バスバー210とバスバー当接面242a,252aとの接触面積が大きく、導通経路となる溶接金属の形成領域を第1の実施の形態よりも広く確保することができるため、正負極端子241,251のそれぞれとバスバー210との間の電気抵抗を低くすることができる。   Furthermore, in the second embodiment, the external terminal portions 242 and 252 are formed in a rectangular column shape, and the bus bar contact surfaces 242a and 252a are formed in a rectangular shape in plan view. Therefore, in the second embodiment, compared to the first embodiment, the contact area between the bus bar 210 and the bus bar abutting surfaces 242a, 252a is large, and the weld metal forming region serving as a conduction path is formed in the first embodiment. Since it can be secured wider than in the embodiment, the electrical resistance between each of the positive and negative terminals 241 and 251 and the bus bar 210 can be reduced.

なお、次のような変形も本発明の範囲内であり、変形例の一つ、もしくは複数を上述の実施形態と組み合わせることも可能である。
[変形例]
The following modifications are also within the scope of the present invention, and one or a plurality of modifications can be combined with the above-described embodiment.
[Modification]

(1)第1の実施の形態では、位置決め凸部144,154を設けて、位置決め凸部144,154の外周面と、バスバー110の位置決め孔110h1,110h2の内周面とをレーザにより突合せ溶接し、第2の実施の形態では、レーザによりバスバー210と外部端子部242,252とを重ね貫通溶接したが、本発明はこれに限定されない。たとえば、図10に示すように、側方からレーザを照射して、バスバー310の下面と外部端子部342,352のバスバー当接面342a,352aとをレーザにより突き合わせ溶接してもよい。図10は、本発明の変形例に係る組電池を構成する単電池の正極端子341とバスバー310との接続構造を示す概念図である。図10では、正極側の接続構造を示しているが、負極側も同様の構成であるため、便宜上、かっこ書きで負極側の構成要素の参照番号を付している。   (1) In the first embodiment, the positioning convex portions 144 and 154 are provided, and the outer peripheral surfaces of the positioning convex portions 144 and 154 and the inner peripheral surfaces of the positioning holes 110h1 and 110h2 of the bus bar 110 are butt welded by laser. In the second embodiment, the bus bar 210 and the external terminal portions 242 and 252 are overlapped and welded by laser, but the present invention is not limited to this. For example, as shown in FIG. 10, a laser may be irradiated from the side, and the lower surface of the bus bar 310 and the bus bar abutting surfaces 342a and 352a of the external terminal portions 342 and 352 may be butt welded by the laser. FIG. 10 is a conceptual diagram showing a connection structure between a positive electrode terminal 341 and a bus bar 310 of a unit cell constituting an assembled battery according to a modification of the present invention. In FIG. 10, the connection structure on the positive electrode side is shown, but since the negative electrode side has the same configuration, the reference numerals of the components on the negative electrode side are given in parentheses for convenience.

図10に示すように、溶接金属w31,w32は、バスバー当接面342a,352aに沿って形成される。溶接金属w31,w32とガスケット130との間の最短距離L30は、2mm以上とすることが望ましい。外部端子部342,352の頂面であるバスバー当接面342a,352aからガスケット130の覆い部130cの先端までの離間寸法L33は、最短距離L30が2mm以上となるように決定される。離間寸法L33が得られると、電池蓋102の外表面からバスバー当接面342a,352aまでの寸法L34から離間寸法L33を差し引くことで、覆い部330cの先端から電池蓋102までの最大寸法L35が決定される(L35=L34−L33)。   As shown in FIG. 10, the weld metals w31 and w32 are formed along the bus bar contact surfaces 342a and 352a. The shortest distance L30 between the weld metals w31, w32 and the gasket 130 is preferably 2 mm or more. The distance L33 from the bus bar contact surfaces 342a and 352a, which are the top surfaces of the external terminal portions 342 and 352, to the tip of the cover portion 130c of the gasket 130 is determined so that the shortest distance L30 is 2 mm or more. When the separation dimension L33 is obtained, the maximum dimension L35 from the tip of the cover 330c to the battery lid 102 is obtained by subtracting the separation dimension L33 from the dimension L34 from the outer surface of the battery lid 102 to the bus bar contact surfaces 342a and 352a. It is determined (L35 = L34-L33).

覆い部130cの先端から電池蓋102の外表面までの最小寸法L32は、第1の実施の形態と同様に、正負極端子341,351と電池容器との間の導通を防止するための沿面距離を考慮して決定される。ガスケット330の覆い部330cの先端から電池蓋102の外表面までの設計寸法L31は、最小寸法L32以上、かつ、最大寸法L35以下となるように決定される(L32≦L31≦L35)。   The minimum dimension L32 from the front end of the cover 130c to the outer surface of the battery lid 102 is the creepage distance for preventing conduction between the positive and negative terminals 341 and 351 and the battery container, as in the first embodiment. Is determined in consideration of The design dimension L31 from the tip of the cover 330c of the gasket 330 to the outer surface of the battery lid 102 is determined to be not less than the minimum dimension L32 and not more than the maximum dimension L35 (L32 ≦ L31 ≦ L35).

(2)第1の実施の形態では、バスバー当接面142a,152aから外方に突出するように位置決め凸部144,154を設けたが、本発明はこれに限定されない。たとえば、図10に示すように、バスバー当接面342a,352aから電池蓋102側に向かって窪むように平面視円形状の位置決め凹部344,354を設けてもよい。この場合、バスバー310には、正負極端子341,351の位置決め凹部344,354に挿入される位置決め凸部310cが形成される。   (2) In the first embodiment, the positioning protrusions 144 and 154 are provided so as to protrude outward from the bus bar contact surfaces 142a and 152a, but the present invention is not limited to this. For example, as shown in FIG. 10, positioning concave portions 344 and 354 having a circular shape in plan view may be provided so as to be recessed from the bus bar abutting surfaces 342a and 352a toward the battery lid 102 side. In this case, the bus bar 310 is formed with positioning convex portions 310c to be inserted into the positioning concave portions 344 and 354 of the positive and negative terminals 341 and 351.

(3)位置決め凸部144,154および位置決め凹部344,354の形状は、平面視円形状である場合に限定されない。   (3) The shapes of the positioning convex portions 144 and 154 and the positioning concave portions 344 and 354 are not limited to a circular shape in plan view.

(4)正負極端子141,151のそれぞれに位置決め凸部144,154を形成したが、正負極端子141,151のいずれか一方のみに位置決め凸部を設けてもよい。正負極端子341,351のそれぞれに位置決め凹部344,354を形成したが、正負極端子341,351のいずれか一方のみに位置決め凹部を設けてもよい。正負極端子の一方に位置決め凸部を設け、他方に位置決め凹部を設けてもよい。   (4) Although the positioning convex portions 144 and 154 are formed on the positive and negative electrode terminals 141 and 151, respectively, the positioning convex portion may be provided on only one of the positive and negative electrode terminals 141 and 151. The positioning recesses 344 and 354 are formed in the positive and negative electrode terminals 341 and 351, respectively, but the positioning recess may be provided in only one of the positive and negative electrode terminals 341 and 351. A positioning convex part may be provided on one of the positive and negative terminals, and a positioning concave part may be provided on the other.

(5)リチウムイオン単電池を二次電池の一例として説明したが、ニッケル水素電池などその他の二次電池にも本発明を適用できる。   (5) Although the lithium ion single battery has been described as an example of the secondary battery, the present invention can also be applied to other secondary batteries such as a nickel metal hydride battery.

(6)正極端子141,241,341、正極集電体180および正極箔171の材質は、アルミニウム合金に限定されることなく、アルミニウムとしてもよい。負極端子151,251,351、負極集電体190および負極箔172の材質は、銅合金に限定されることなく、銅としてもよい。   (6) The materials of the positive terminals 141, 241, 341, the positive current collector 180, and the positive foil 171 are not limited to aluminum alloys, and may be aluminum. The material of the negative electrode terminals 151, 251 and 351, the negative electrode current collector 190 and the negative electrode foil 172 is not limited to a copper alloy, and may be copper.

(7)上記した実施の形態では、ハイブリッド電気自動車や純粋な電気自動車に搭載される組電池について説明したが本発明はこれに限定されない。他の電動車両、たとえばハイブリッド電車などの鉄道車両、バスなどの乗合自動車、トラックなどの貨物自動車、バッテリ式フォークリフトトラックなどの産業車両などの蓄電装置に利用可能な組電池に本発明を適用してもよい。   (7) In the above-described embodiment, the assembled battery mounted on the hybrid electric vehicle or the pure electric vehicle has been described, but the present invention is not limited to this. The present invention is applied to an assembled battery that can be used for power storage devices such as other electric vehicles, such as railway vehicles such as hybrid trains, passenger cars such as buses, cargo vehicles such as trucks, and industrial vehicles such as battery-powered forklift trucks. Also good.

(8)上記した実施の形態では、バスバー110,210,310と正負極端子141,151,241,251,341,351とをレーザ溶接により接続したが、本発明はこれに限定されない。たとえば、電子ビーム溶接により、バスバー110,210,310と正負極端子141,151,241,251,341,351とを接続してもよい。   (8) In the above-described embodiment, the bus bars 110, 210, 310 and the positive and negative terminals 141, 151, 241, 251, 341, 351 are connected by laser welding, but the present invention is not limited to this. For example, the bus bars 110, 210, and 310 may be connected to the positive and negative terminals 141, 151, 241, 251, 341, and 351 by electron beam welding.

本発明は、上記した実施の形態に限定されるものでなく、発明の要旨を逸脱しない範囲で自由に変更、改良が可能である。   The present invention is not limited to the embodiment described above, and can be freely changed and improved without departing from the gist of the invention.

100A〜100C 単電池、101 電池缶、102 電池蓋、102h 貫通孔、103 ガス排出弁、110 バスバー、130 ガスケット、130a 筒部、130b 鍔部、130c 覆い部、141 正極端子、142 外部端子部、142a バスバー当接面、143 貫通部、145 突部、145s カシメ部、151 負極端子、152 外部端子部、152a バスバー当接面、153 貫通部、155 突部、155s カシメ部、160 絶縁部材、161 ベース部、161h 貫通孔、170 捲回電極群、173 セパレータ、174 正極電極、175 負極電極、180 正極集電体、181 端子接続部、183 接合部、190 負極集電体、191 端子接続部、193 接合部、200A〜200C 単電池、210 バスバー、230 ガスケット、230b 鍔部、230c 覆い部、241 正極端子、242 外部端子部、242a バスバー当接面、251 負極端子、252 外部端子部、252a バスバー当接面、310 バスバー、330 ガスケット、330c 覆い部、341 正極端子、342 外部端子部、342a バスバー当接面、351 負極端子、352 外部端子部、352a バスバー当接面
100A to 100C single cell, 101 battery can, 102 battery lid, 102h through hole, 103 gas discharge valve, 110 bus bar, 130 gasket, 130a cylinder, 130b collar, 130c cover, 141 positive terminal, 142 external terminal, 142a Bus bar abutting surface, 143 penetrating portion, 145 projecting portion, 145s caulking portion, 151 negative electrode terminal, 152 external terminal portion, 152a bus bar abutting surface, 153 penetrating portion, 155 projecting portion, 155s caulking portion, 160 insulating member, 161 Base part, 161h Through-hole, 170 wound electrode group, 173 separator, 174 positive electrode, 175 negative electrode, 180 positive electrode current collector, 181 terminal connection part, 183 joint part, 190 negative electrode current collector, 191 terminal connection part, 193 Joint, 200A-200C cell, 210 bus bar, 230 Gasket 230b collar part, 230c cover part, 241 positive terminal, 242 external terminal part, 242a bus bar contact surface, 251 negative terminal, 252 external terminal part, 252a bus bar contact surface, 310 bus bar, 330 gasket, 330c cover part, 341 Positive terminal, 342 External terminal, 342a Bus bar contact surface, 351 Negative terminal, 352 External terminal, 352a Bus bar contact surface

Claims (6)

正極電極および負極電極をセパレータを介在させて捲回した捲回電極群と、
前記捲回電極群を収容する電池缶と前記電池缶を封止する電池蓋とから構成される電池容器と、
前記正負極電極のそれぞれに電気的に接続され、前記電池蓋に設けられた一対の貫通孔のそれぞれに取り付けられた正極端子および負極端子と、
前記正極端子および前記負極端子のそれぞれと前記貫通孔との間に介在されて、前記正極端子および前記負極端子のそれぞれと前記電池蓋とを絶縁する絶縁シール部材とを備え、
前記正負極端子のそれぞれには、単電池同士を電気的に接続するためのバスバーが溶接されるバスバー溶接部が設けられ、
前記絶縁シール部材は、前記電池蓋の貫通孔から外方に向かって突出する前記正負極端子のそれぞれの外周面を密着して覆う覆い部を有し、
前記覆い部の先端は、前記バスバー溶接部の頂面よりも電池蓋側に位置していることを特徴とする単電池。
A wound electrode group in which a positive electrode and a negative electrode are wound with a separator interposed therebetween;
A battery container comprising a battery can that houses the wound electrode group and a battery lid that seals the battery can;
A positive terminal and a negative terminal electrically connected to each of the positive and negative electrodes and attached to each of a pair of through holes provided in the battery lid;
An insulating seal member interposed between each of the positive electrode terminal and the negative electrode terminal and the through-hole to insulate each of the positive electrode terminal and the negative electrode terminal and the battery lid;
Each of the positive and negative terminals is provided with a bus bar welding portion to which a bus bar for electrically connecting the cells is welded,
The insulating seal member has a cover portion that tightly covers and covers each outer peripheral surface of the positive and negative electrode terminals protruding outward from the through hole of the battery lid,
The single cell according to claim 1, wherein a tip of the cover portion is located closer to a battery lid than a top surface of the bus bar welded portion.
請求項1に記載の単電池において、
前記覆い部の先端から前記電池蓋までの寸法は、前記正負極端子と前記電池容器との間の導通を防止するための沿面距離と、前記バスバーを前記バスバー溶接部に溶接するときの入熱とを考慮して決定されることを特徴とする単電池。
The single battery according to claim 1,
The dimensions from the front end of the cover part to the battery cover are the creepage distance to prevent conduction between the positive and negative electrode terminals and the battery container, and the heat input when welding the bus bar to the bus bar welded part. A single battery characterized by being determined.
請求項1または2に記載の単電池において、
前記正負極端子のそれぞれは、円柱形状の前記バスバー溶接部の一端から前記電池蓋側に向かって突設されて前記電池蓋の貫通孔を貫通する円柱形状の貫通部を備え、
前記正負極端子のそれぞれは、前記貫通部の外径寸法が前記バスバー溶接部の外径寸法よりも小さくなるように形成され、
前記絶縁シール部材は、前記貫通部と前記電池蓋の貫通孔との間に配置される円筒状の筒部と、前記筒部の一端から外方に延在し、前記バスバー溶接部の一端面と前記電池蓋との間に配置される円環状の鍔部とを有し、
前記覆い部は、前記鍔部の外縁から立ち上がる円筒状に形成されていることを特徴とする単電池。
The single battery according to claim 1 or 2,
Each of the positive and negative terminals includes a cylindrical penetrating portion that protrudes from one end of the cylindrical bus bar welded portion toward the battery lid side and penetrates the through hole of the battery lid,
Each of the positive and negative terminals is formed such that the outer diameter dimension of the through portion is smaller than the outer diameter dimension of the bus bar welded portion,
The insulating seal member includes a cylindrical tube portion disposed between the through portion and the through hole of the battery lid, and extends outward from one end of the tube portion, and one end surface of the bus bar welded portion. And an annular collar disposed between the battery lid and the battery lid,
The cell is characterized in that the cover part is formed in a cylindrical shape rising from an outer edge of the flange part.
請求項1または2に記載の単電池において、
前記正負極端子のそれぞれは、矩形柱形状の前記バスバー溶接部の一端から前記電池蓋側に向かって突設されて前記電池蓋の貫通孔を貫通する円柱形状の貫通部を備え、
前記正負極端子のそれぞれは、前記貫通部の外径寸法が前記バスバー溶接部の外形寸法よりも小さくなるように形成され、
前記絶縁シール部材は、前記貫通部と前記電池蓋の貫通孔との間に配置される円筒状の筒部と、前記筒部の一端から外方に延在し、前記バスバー溶接部の一端面と前記電池蓋との間に配置される環状の鍔部とを有し、
前記覆い部は、前記鍔部の外縁から立ち上がる矩形筒状に形成されていることを特徴とする単電池。
The single battery according to claim 1 or 2,
Each of the positive and negative terminals includes a cylindrical penetrating portion that protrudes from one end of the rectangular bar-shaped bus bar welded portion toward the battery lid side and penetrates the through hole of the battery lid,
Each of the positive and negative terminals is formed such that the outer diameter dimension of the through portion is smaller than the outer dimension of the bus bar welded portion,
The insulating seal member includes a cylindrical tube portion disposed between the through portion and the through hole of the battery lid, and extends outward from one end of the tube portion, and one end surface of the bus bar welded portion. And an annular collar disposed between the battery lid and the battery lid,
The cell is characterized in that the cover part is formed in a rectangular cylindrical shape rising from an outer edge of the flange part.
請求項3または4に記載の単電池において、
前記正極電極に接続される電極接続部と、前記正極端子に固着される端子接続部とを有する正極集電体と、
前記負極電極に接続される電極接続部と、前記負極端子に固着される端子接続部とを有する負極集電体と、
前記正負極集電体の端子接続部のそれぞれと前記電池蓋との間に介在されて、前記正負極集電体のそれぞれと前記電池蓋とを絶縁する絶縁部材とを備え、
前記正負極端子のそれぞれは、前記貫通部の一端から前記捲回電極群側に向かって突設された円筒状の突部とを備え、
前記正負極端子のそれぞれは、前記突部が前記端子接続部にかしめられることで、前記正負極集電体のそれぞれに固着されていることを特徴とする単電池。
The single battery according to claim 3 or 4,
A positive electrode current collector having an electrode connection portion connected to the positive electrode and a terminal connection portion fixed to the positive electrode terminal;
A negative electrode current collector having an electrode connection part connected to the negative electrode and a terminal connection part fixed to the negative electrode terminal;
An insulating member interposed between each of the terminal connection portions of the positive and negative electrode current collectors and the battery lid, and insulating each of the positive and negative electrode current collectors and the battery lid;
Each of the positive and negative terminals includes a cylindrical protrusion protruding from one end of the penetrating part toward the wound electrode group,
Each of the positive and negative electrode terminals is fixed to each of the positive and negative electrode current collectors by caulking the protruding portion to the terminal connection portion.
請求項1ないし5のいずれか1項に記載の単電池を複数備え、前記複数の単電池同士がバスバーにより電気的に接続された組電池であって、
前記覆い部の先端から前記電池蓋までの寸法は、前記バスバーと前記正負極端子との間に形成される溶接金属と、前記覆い部との間の最短距離を考慮して決定されることを特徴とする組電池。
A battery pack comprising a plurality of the unit cells according to any one of claims 1 to 5, wherein the plurality of unit cells are electrically connected by a bus bar,
The dimension from the front end of the cover part to the battery cover is determined in consideration of the shortest distance between the weld metal formed between the bus bar and the positive and negative terminals and the cover part. A battery pack featuring the features.
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CN114204185A (en) * 2020-09-17 2022-03-18 泰星能源解决方案有限公司 Terminal for secondary battery and method for manufacturing terminal for secondary battery
WO2023173249A1 (en) * 2022-03-14 2023-09-21 宁德时代新能源科技股份有限公司 Battery cell, battery, electric device, and device and method for manufacturing battery cell
CN115173002A (en) * 2022-08-04 2022-10-11 西安北方庆华机电有限公司 Special-shaped flow guide column and battery cover for thermal battery
CN115173002B (en) * 2022-08-04 2024-05-14 西安北方庆华机电有限公司 Special-shaped guide column and battery cover for thermal battery

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