JP2013040116A5 - - Google Patents
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- JP2013040116A5 JP2013040116A5 JP2011176689A JP2011176689A JP2013040116A5 JP 2013040116 A5 JP2013040116 A5 JP 2013040116A5 JP 2011176689 A JP2011176689 A JP 2011176689A JP 2011176689 A JP2011176689 A JP 2011176689A JP 2013040116 A5 JP2013040116 A5 JP 2013040116A5
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- solvents
- solvent
- butanol
- ether
- hydrocarbon solvents
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Description
上記した、連鎖移動可能重合体（２）の存在下に行われるリビングラジカル重合（可逆的付加開裂連鎖移動重合）の実施では、溶媒を使用しても、また使用しなくても良い。使用できる溶媒としては、重合反応を阻害しないものであれば何れでも使用することができるが、例えば、ベンゼン、トルエン及びキシレン等の芳香族炭化水素系溶媒、ペンタン、ヘキサン、ヘプタン、オクタン、ノナン及びデカン等の脂肪族炭化水素系溶媒、シクロヘキサン、メチルシクロヘキサン及びデカヒドロナフタレンのような脂環族炭化水素系溶媒、クロロベンゼン、ジクロロベンゼン、トリクロロベンゼン、塩化メチレン、クロロホルム、四塩化炭素及びテトラクロルエチレン等の塩素化炭化水素系溶媒、メタノール、エタノール、ｎ−プロパノール、イソプロパノール、ｎ−ブタノール、ｓｅｃ−ブタノール及びｔｅｒｔ−ブタノールなどのアルコール系溶媒、アセトン、メチルエチルケトン及びメチルイソブチルケトン等のケトン系溶媒；酢酸エチル及びジメチルフタレート等のエステル系溶媒、ジメチルエーテル、ジエチルエーテル、ジ−ｎ−アミルエーテル、テトラヒドロフラン及びジオキシアニソールのようなエーテル系溶媒等をあげることができる。また、水を溶媒とすることもできる。これらの溶媒は、単独もしくは２種以上を混合して使用してもよい。 In the above-described living radical polymerization (reversible addition-fragmentation chain transfer polymerization) performed in the presence of the chain transferable polymer (2), a solvent may or may not be used. As the solvent that can be used, any solvent that does not inhibit the polymerization reaction can be used. For example, aromatic hydrocarbon solvents such as benzene, toluene and xylene, pentane, hexane, heptane, octane, nonane and Aliphatic hydrocarbon solvents such as decane, alicyclic hydrocarbon solvents such as cyclohexane, methylcyclohexane and decahydronaphthalene, chlorobenzene, dichlorobenzene, trichlorobenzene, methylene chloride, chloroform, carbon tetrachloride and tetrachloroethylene Chlorinated hydrocarbon solvents, methanol, ethanol, n-propanol, isopropanol, n-butanol, alcohol solvents such as sec-butanol and tert-butanol, acetone, methyl ethyl ketone and methyl isobutyl ketone Ton solvents; ester solvents such as ethyl acetate and dimethyl phthalate, dimethyl ether, diethyl ether, di -n- amyl ether, may be mentioned ether solvents such as tetrahydrofuran and dioxy anisole and the like. Water can also be used as a solvent. These solvents may be used alone or in combination of two or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011176689A JP5818142B2 (en) | 2011-08-12 | 2011-08-12 | Vinyl ethers and polymers containing reversible addition-fragmentation chain transfer polymerizable sites and methods for their production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011176689A JP5818142B2 (en) | 2011-08-12 | 2011-08-12 | Vinyl ethers and polymers containing reversible addition-fragmentation chain transfer polymerizable sites and methods for their production |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013040116A JP2013040116A (en) | 2013-02-28 |
| JP2013040116A5 true JP2013040116A5 (en) | 2014-09-11 |
| JP5818142B2 JP5818142B2 (en) | 2015-11-18 |
Family
ID=47888857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011176689A Active JP5818142B2 (en) | 2011-08-12 | 2011-08-12 | Vinyl ethers and polymers containing reversible addition-fragmentation chain transfer polymerizable sites and methods for their production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5818142B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5828472B2 (en) * | 2011-08-12 | 2015-12-09 | 国立大学法人福井大学 | Process for producing block copolymer |
| JP6550908B2 (en) * | 2015-05-08 | 2019-07-31 | 国立大学法人福井大学 | Method for producing alkenyl ether polymer |
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2011
- 2011-08-12 JP JP2011176689A patent/JP5818142B2/en active Active
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