JP2013034414A - Loosening agent for food - Google Patents

Loosening agent for food Download PDF

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JP2013034414A
JP2013034414A JP2011171920A JP2011171920A JP2013034414A JP 2013034414 A JP2013034414 A JP 2013034414A JP 2011171920 A JP2011171920 A JP 2011171920A JP 2011171920 A JP2011171920 A JP 2011171920A JP 2013034414 A JP2013034414 A JP 2013034414A
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food
starch
loosening
rice
noodles
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JP5791183B2 (en
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Shigeaki Maeda
栄彰 前田
Yasuo Katsuta
康夫 勝田
Isao Matsuda
功 松田
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Matsutani Chemical Industries Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a loosening agent for food, effectively improving loosening performance of food without impairing the flavor and eating quality of food itself, and also improving loosening performance of food at a low cost, and to provide a method of manufacturing food having excellent loosening performance and good taste using the loosening agent for food.SOLUTION: This loosening agent includes modified starch ultrasonic processed material which is obtained by ultrasonic processing modified starch to have the viscosity of 100 mPa s or less in 5 mass% aqueous solution. This invention provides the method of manufacturing food having excellent loosening performance and good taste which maintains the flavor and eating quality of the food itself using the loosening agent. Since this loosening agent is prepared by means for ultrasonic processing modified starch, it can be provided at a low cost. In the food eaten after the starch in the food pregelatinized by boiling, steaming or cooking rice, when this loosening agent is used, it is possible to provide the food effectively improved in food loosening performance and having excellent loosening performance and good taste without impairing the flavor and eating quality of the food itself.

Description

本発明は、茹でや蒸煮或いは炊飯等によって食品中の澱粉をα化させて喫食する麺類、米飯等の食品のほぐれ性を改良する食品用ほぐれ剤、及び該食品用ほぐれ剤を用いたほぐれの良好な食品の製造方法に関する。特に、加熱調理され、α化された麺類或いは炊飯米等の食品の製造の段階、又は流通、販売、喫食の段階でのほぐれ性を有効に改善し、しかも、食品本来の風味や食味を損なうことなく、更に、ほぐれ剤の調製に際して煩雑な工程を必要とすることなく、簡便、安価な方法で提供できる食品用ほぐれ剤を提供すること、及び、該食品用ほぐれ剤を用いて、良好なほぐれ性と高い味覚とを有するほぐれ性の良好な食品を製造する方法を提供することに関する。   The present invention relates to noodles to be eaten by boiled, steamed, cooked rice or the like by converting the starch in the food into a food, a loosening agent for foods that improves the looseness of foods such as cooked rice, and a loosening agent using the loosening agent for foods The present invention relates to a method for producing a good food. In particular, it effectively improves the looseness at the stage of production of food such as cooked and pregelatinized noodles or cooked rice, or at the stage of distribution, sales, and eating, and also impairs the original flavor and taste of food. Further, providing a food loosening agent that can be provided by a simple and inexpensive method without the need for complicated steps in the preparation of the loosening agent, and using the food loosening agent, The present invention relates to providing a method for producing a food having good looseness and having looseness and high taste.

うどん、そば、中華麺、スパゲッティ、マカロニ、はるさめ、ビーフン、フォーなどの麺類においては、製麺して得られた麺線を、茹でや蒸煮によって加熱して、澱粉をα化し、可食状態にする。一方、米飯類は、水に浸漬した生米を炊飯或いは蒸煮してα化し、喫食に供する。この麺線や米飯において、α化された澱粉は、糊状を呈し、粘着性の強い状態となる。更に、時間が経過すると、麺線や米飯の表面の水分が減少し、麺線や米飯の表面の粘着力がより強くなる。この加熱後の澱粉のα化による麺線や米飯の表面の粘着力の増加は、麺線や米飯どうしの結着を促進させ、ほぐれを悪くして喫食しにくいという不都合を生じさせる。また、インスタント化した食品においては、湯戻しに際しては、ほぐれが悪くなり、加熱ムラを生じるなどして、食味を低下させる等の問題が発生する。   In noodles such as udon, buckwheat noodles, Chinese noodles, spaghetti, macaroni, harusame, rice noodles, pho, etc., the noodles obtained by making noodles are heated by boiling or steaming to make starch starch edible. To do. On the other hand, the cooked rice is cooked or steamed from raw rice soaked in water to make it alpha, and used for eating. In this noodle string or cooked rice, the pregelatinized starch is pasty and is in a highly sticky state. Furthermore, as time elapses, the moisture on the surface of the noodle strings and cooked rice decreases, and the adhesive force on the surfaces of the noodle strings and cooked rice becomes stronger. The increase in the adhesive strength of the surface of the noodle strings and cooked rice due to the gelatinization of the starch after the heating promotes the binding between the noodle strings and cooked rice, and causes the disadvantage that the loosening becomes worse and it is difficult to eat. In addition, in instant foods, when reconstituted with hot water, the problem of loosening becomes worse and heating unevenness occurs, thereby causing problems such as lowering the taste.

近年、スーパーやコンビニエンスストアー等を介した流通形態では、うどん、そば、中華麺、スパゲッティ、マカロニ、はるさめ、ビーフン、フォーなどの麺類が、加熱調理され、α化された麺類の形態で、流通、販売されている。米飯においても近年、米飯の製造は外食産業のチェーンストア化、無菌包装技術の進歩、冷凍食品の増加等により、工場での一括生産のような形態が多く見られるようになってきた。また、炊飯した米飯自体を、流通販売する形態も多く見られるようになり、おにぎり、焼きおにぎり、かやくご飯、寿司、ちらし寿司などの米飯についても麺類と同様に、コンビニエンスストアー等を介した流通形態が採られるようになった。このような麺類や米飯の製造、流通販売、及び喫食形態で特に問題となるのが、α化された麺線や米飯のほぐれ性の悪化からくる味覚の低下による商品価値の低下ということがある。   In recent years, in the form of distribution through supermarkets, convenience stores, etc., noodles such as udon, soba, Chinese noodles, spaghetti, macaroni, harusame, rice noodles, pho, etc. are cooked and distributed in the form of gelatinized noodles, Sold. In recent years, the production of cooked rice has been seen in many forms such as batch production in factories due to the chain store in the restaurant industry, advances in aseptic packaging technology, an increase in frozen foods, and the like. In addition, there are many forms of distribution and sales of cooked rice itself, and rice balls such as rice balls, grilled rice balls, baked rice, sushi and chirashi sushi are distributed through convenience stores as well as noodles. A form was adopted. A particular problem in the production, distribution and sales of such noodles and cooked rice is that the commercial value may be reduced due to a decrease in taste resulting from the deterioration of the looseness of the gelatinized noodle strings and cooked rice. .

例えば、麺類においては、加熱調理され、α化された麺類の流通、販売形態では、麺線の結着が、麺のほぐれを悪くし、商品価値を低下させることになる。また、α化した麺類を冷凍して流通する冷凍麺においては、喫食時にボイル解凍や流水解凍等のなんらかの方法で解凍して喫食することになるが、ほぐれ性が悪いと解凍時間が遅延され、業務用よりも弱い火力で解凍する家庭用冷凍麺でしばしば問題となっている。即席麺においては、ほぐれ性が悪いと復元が不均一になり、復元不良部分ができて即席性を大きく損なう。また、麺類のおいしさは麺類そのものの味や風味以外に、喫食時に麺類をすする行為からも得られる。喫食時に麺線が一本一本ほぐれていることにより、しなやかでつるみのある食感が感じやすくなる為おいしさを感じることができる。したがって、α化麺のほぐれ性の改善は、麺の喫食時の味覚の向上の点からも重要な課題となる。   For example, in noodles, in the distribution and sales form of cooked and gelatinized noodles, the binding of the noodle strings deteriorates the looseness of the noodles and reduces the commercial value. In addition, in frozen noodles that circulate by freezing pregelatinized noodles, it will be thawed and eaten by some method such as boil thawing or running water thawing at the time of eating, but if the looseness is poor, the thawing time is delayed, It is often a problem with domestic frozen noodles that thaw with less heat than commercial use. In instant noodles, if the looseness is poor, the restoration becomes non-uniform, resulting in a poorly restored part and greatly impairs the instantness. In addition to the taste and flavor of the noodles themselves, the deliciousness of the noodles can be obtained from the act of sipping the noodles at the time of eating. When the noodle strings are loosened one by one at the time of eating, it is easy to feel a supple and slick texture, so you can feel the taste. Therefore, the improvement of the looseness of the pregelatinized noodles is an important issue from the viewpoint of improving the taste when eating the noodles.

一方、米飯類においては、おにぎり、焼きおにぎり、かやくご飯、寿司、ちらし寿司などの米飯類は、米を水で磨いだ後、水に浸漬し加熱して、澱粉をα化し、可食状態に調製されるが、このα化された米飯は、粘着性の強い状態にある。この米飯を用いておにぎりなどを調製後、時間が経過すると、米粒の表面の水分が減少し、米粒の表面の粘着力がより強くなる。この加熱後の澱粉のα化による米粒の表面の粘着力の増加は、米粒どうしの結着を促進させ、おにぎりが喫食しにくい、べたつくという不都合を生じさせる。   On the other hand, in the case of cooked rice, cooked rice such as rice balls, grilled rice balls, baked rice balls, sushi, chirashi sushi, etc., after polishing the rice with water, heat it by immersing it in water, making the starch alpha, edible state However, this pre-gelatinized rice is in a highly sticky state. If time passes after preparing rice balls etc. using this cooked rice, the water | moisture content of the surface of a rice grain will reduce and the adhesive force of the surface of a rice grain will become stronger. The increase in the adhesive strength of the surface of the rice grains due to the gelatinization of the starch after the heating promotes the binding of the rice grains, causing the disadvantage that the rice balls are difficult to eat and are sticky.

また、近年、米飯の製造は外食産業のチェーンストア化、無菌包装技術の進歩、冷凍食品の増加等により、工場での一括生産が多く見られるようになってきた。米飯製品を工場で大量製造する際には、炊き上がった米飯がほぐれやすく機械に付着しないことが求められている。更に、米飯については無菌包装の形態で提供が行われている。無菌包装米飯については、炊飯後の米飯を無菌殺菌して製造される一般的な無菌包装米飯に加え、炊飯と無菌包装を兼ねて製造される加圧加熱殺菌米飯(いわゆるレトルト米飯)がある。このレトルト米飯は、生米と水をレトルト処理することによって製造されるが、このようにして製造された米飯は、餅様の板状となり、ほとんどほぐれないことが問題となっている。   In recent years, the batch production of cooked rice has become more common in factories due to the chain store in the food service industry, advances in aseptic packaging technology, and an increase in frozen foods. When mass-producing cooked rice products at a factory, it is required that cooked cooked rice is easily loosened and does not adhere to the machine. Furthermore, rice is provided in the form of aseptic packaging. Aseptic packaged rice, in addition to general aseptic packaged rice that is produced by aseptically sterilizing cooked rice, there is pressure-heat-sterilized cooked rice (so-called retort cooked rice) that is produced both as cooked rice and aseptic packaging. This retort cooked rice is produced by retorting raw rice and water. However, the rice produced in this way has a problem of being a rice cake-like plate and hardly unraveled.

以上のような理由から、従来、α化麺や米飯のような食品中の澱粉をα化した食品においては、そのほぐれ性の改善について、α化麺や米飯それぞれにおいて、ほぐれを改善するための各種の方法が提案されてきた。   For the reasons described above, conventionally, in foods obtained by pre-gelatinizing starch in foods such as pregelatinized noodles and cooked rice, in order to improve the unraveling, Various methods have been proposed.

例えば、麺類においては、麺線同士が結着するのを防止し、麺線をほぐれやすくする従来の方法として、麺線表面をゼラチンでコーティングする方法(特開昭63−283547号公報)、油脂又は乳化油脂を麺線に付着させる方法(特開平3−247249号公報)、デキストリンを麺線表面に付着させる方法(特開平6−327427号公報)が開示されている。   For example, in the case of noodles, as a conventional method for preventing noodle strings from binding and making the noodle strings easy to loosen, a method of coating the surface of the noodle strings with gelatin (Japanese Patent Laid-Open No. 63-283547), fats and oils Alternatively, a method of attaching emulsified oils and fats to a noodle string (JP-A-3-247249) and a method of attaching dextrin to the surface of a noodle string (JP-A-6-327427) are disclosed.

また、油脂組成物からなるほぐれ剤として、構成脂肪酸中のオレイン酸含量が65%以上の高オレイン酸型油脂に水添処理を施した油脂に、乳化剤を添加した麺用ほぐれ油脂組成物(特開2001−352926号公報)及び油脂、ソルビタン脂肪酸エステル、或いは、ポリグリセリン脂肪酸エステル、及びポリオキシエチレンソルビタン脂肪酸エステルを含む麺類用油脂組成物(特開2006−6132号公報、特開2011−19412号公報)が開示されている。更に、コラーゲンペプチド(特開2000−342209号公報)や、アラビヤガム、ガティガムを含有させた麺類のほぐれ改良剤(特開2008−283888号公報、特開2009−136230号公報、特開2010−187655号公報)や、コラーゲン、大豆食物繊維及びゼラチンに、キサンタガム、グァーガム、カラギーナン及びローカストビーンガムを併用した麺用ほぐれ改良剤(特開2000−139386号公報)が開示されている。また、ポリアクリル酸ナトリウムを含有する麺用ほぐれ向上剤(特開2004−242570号公報)や、油脂、増粘多糖類と、水溶性ヘミセルロースを含む混合物を乳化したほぐれ改良剤(特開2003−265128号公報、特開2005−13135号公報)が開示されている。   Moreover, as a loosening agent comprising an oil and fat composition, a loose oil and fat composition for noodles in which an emulsifier is added to an oil and fat obtained by hydrogenating a high oleic acid type fat and oil having a oleic acid content of 65% or more in the constituent fatty acid (special feature). No. 2001-352926) and fats and oils composition for noodles containing fats and oils, sorbitan fatty acid esters, or polyglycerin fatty acid esters, and polyoxyethylene sorbitan fatty acid esters (Japanese Patent Laid-Open Nos. 2006-6132 and 2011-19412) Publication). Furthermore, a collagen peptide (Japanese Patent Laid-Open No. 2000-342209), a noodle loosening improver containing Arabia gum and gati gum (Japanese Patent Laid-Open No. 2008-283888, Japanese Patent Laid-Open No. 2009-136230, Japanese Patent Laid-Open No. 2010-187655). Japanese Patent Laid-Open No. 2000-139386), and a loosening improver for noodles in which xantha gum, guar gum, carrageenan and locust bean gum are used in combination with collagen, soybean dietary fiber and gelatin. Further, a noodle loosening improver containing sodium polyacrylate (Japanese Patent Laid-Open No. 2004-242570) or a loosening improver emulsified with a mixture containing fats and oils, thickening polysaccharides and water-soluble hemicellulose (Japanese Patent Laid-Open No. 2003-2003). No. 265128 and JP-A-2005-13135 are disclosed.

炭水化物を用いたほぐれ改良剤としては、例えば、大豆由来の水溶性多糖類とたんぱく質の酵素分解物を有効成分として含有するほぐれ剤(特開2001−238622号公報)が、生澱粉の分解物であるデキストリンを含有したほぐれ剤(特開2002−65191号公報)が開示されている。また、ポテトパルプを繊維質分解酵素やペクチン分解活性を持つ酵素で分解し、水抽出して乾燥した食品用ほぐれ剤(特開2006−51012号公報)が、ヒドロキシプロピルセルロース或いはヒドロキシプロピルセルロースと水溶性ヘミセルロースからなる麺ほぐれ改良剤(特開2006−311849号公報)が、タマリンド種子のようなガラクトキシログルカン又は低粘性ガラクトキシログルカンからなるほぐれ性改良剤(特開2006−333796号公報)が開示されている。更に、加工澱粉を酵素等で分解することからなるα化麺用ほぐれ剤(特開2009−11313号公報)が、イヌリンと環状デキストリンとを含むゆで麺のほぐれ向上剤(特開2011−83210号公報)が開示されている。   As a loosening improver using carbohydrates, for example, a loosening agent containing a water-soluble polysaccharide derived from soybean and an enzyme degradation product of protein (Japanese Patent Laid-Open No. 2001-238622) is a degradation product of raw starch. A loosening agent containing a certain dextrin (JP 2002-65191 A) is disclosed. Further, a food-use loosening agent (Japanese Patent Laid-Open No. 2006-51012) obtained by decomposing potato pulp with a fiber-degrading enzyme or an enzyme having pectin-degrading activity, extracting with water and drying is used as hydroxypropylcellulose or hydroxypropylcellulose and water-soluble A noodle loosening improver comprising Japanese hemicellulose (Japanese Patent Laid-Open No. 2006-311849) is disclosed, and a loosening improver comprising Japanese galactoxyloglucan such as tamarind seed or a low-viscosity galactoxyloglucan (Japanese Patent Laid-Open No. 2006-333796) is disclosed. Has been. Furthermore, a loosening agent for pregelatinized noodles (Japanese Patent Laid-Open No. 2009-11313) consisting of decomposing processed starch with an enzyme or the like is a boiled noodle loosening improver (Japanese Patent Laid-Open No. 2011-83210) containing inulin and cyclic dextrin. Publication).

また、米飯類においては、麺線同士が結着するのを防止し、麺線をほぐれやすくする従来の方法として、米飯製品を大量製造する際に、炊き上がった米飯をほぐれやすくして成型や計量を容易にしたり、機械に付着するのを防いだりといった機械適性の向上のために、澱粉質や糖質、乳化剤等を加えた炊飯用油や、油脂と水を乳化剤によって乳化させた乳化油脂、更には卵黄等の蛋白製剤などが添加される。該澱粉質や糖質としては、マルチトール、蔗糖、トレハロース、デキストリン、キサンタンガム、グアーガム、ローカストガム、タラガム、ペクチン、水溶性ヘミセルロースなどが用いられ、乳化剤等を加えた炊飯用油や、油脂と水を乳化剤によって乳化させた乳化油脂には、モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、レシチン、蔗糖脂肪酸エステルなどのような乳化剤が用いられる。   In addition, in the case of cooked rice, as a conventional method for preventing noodle strings from binding and making the noodle strings easy to loosen, when producing a large amount of cooked rice products, Oil for cooking rice with added starch, sugar, emulsifier, etc., or emulsified oil and water emulsified with oil and water to improve the suitability of the machine, such as making it easy to measure and preventing adhesion to the machine Furthermore, protein preparations such as egg yolk are added. Examples of the starch and saccharide include maltitol, sucrose, trehalose, dextrin, xanthan gum, guar gum, locust gum, tara gum, pectin, water-soluble hemicellulose, etc. An emulsifier such as monoglycerin fatty acid ester, polyglycerin fatty acid ester, lecithin, sucrose fatty acid ester and the like is used for the emulsified oil and fat emulsified with emulsifier.

澱粉質や糖質を添加して、米飯のほぐれ性を改善する例としては、デキストランを添加するもの(特開2005−328728号公報)、大豆多糖類に、トレハロース、マルチトール、蔗糖等の少糖類を添加するもの(特開2006−238758号公報)、澱粉分解酵素と、トレハロース、ペクチン等を添加するもの(特開2001−275589号公報、特開2003−52319号公報)、難消化デキストリン及びペクチンを添加するもの(特開平9−75022号公報)、水溶性ヘミセルロースを添加するもの(特開平6−121647号公報)、加工澱粉を含有するもの(特開2002−65184号公報)、及び、アミラーゼと増粘多糖類若しくは寒天を配合したもの(特開2007−228834号公報)などが開示されている。   Examples of improving the looseness of cooked rice by adding starch or sugar are those in which dextran is added (Japanese Patent Laid-Open No. 2005-328728), soy polysaccharides, trehalose, maltitol, sucrose, etc. Those to which saccharides are added (Japanese Patent Laid-Open No. 2006-238758), those that add amylolytic enzymes, trehalose, pectin, etc. (Japanese Patent Laid-Open No. 2001-275589, Japanese Patent Laid-Open No. 2003-52319), indigestible dextrin and Those that add pectin (Japanese Patent Laid-Open No. 9-75022), those that add water-soluble hemicellulose (Japanese Patent Laid-Open No. 6-121647), those containing modified starch (Japanese Patent Laid-Open No. 2002-65184), and A blend of amylase and thickening polysaccharide or agar (Japanese Patent Laid-Open No. 2007-228834) is disclosed. .

また、油脂に乳化剤を加えた乳化油脂を米飯のほぐれ性改善に用いる例としては、例えば、乳化剤として、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステルを用いるもの(特開2004−65216号公報)、ジアセチル酒石酸、コハク酸、クエン酸などの有機酸モノグリセライドを用いるもの(特開2004−49065号公報)、プロピレングリコール脂肪酸エステル、トリグリセリン脂肪酸エステル、テトラグリセリン脂肪酸エステルを用いるもの(特開2009−82025号公報)などが開示されている。更に、蛋白製剤などを米飯のほぐれ性改善に用いる例としては、卵黄又は全卵のホスホリパーゼ処理物を脂質中に分散させた米飯のバラケ性改善剤(特開2004−41046号公報、特開2005−295957号公報)等が開示されている。その他、アルギン酸類の分解物を米飯のほぐれ性の改良剤として用いるもの(特開2006−296259号公報)が開示されている。   Moreover, as an example using the emulsified fats and oils which added the emulsifier to the fats and oils for improving the looseness of cooked rice, what uses a stearoyl sodium lactate and polyoxyethylene sorbitan fatty acid ester as an emulsifier, for example (Unexamined-Japanese-Patent No. 2004-65216), Those using organic acid monoglycerides such as diacetyltartaric acid, succinic acid and citric acid (Japanese Patent Laid-Open No. 2004-49065), those using propylene glycol fatty acid ester, triglycerin fatty acid ester and tetraglycerin fatty acid ester (Japanese Patent Laid-Open No. 2009-82025) Gazette) and the like. Furthermore, as an example of using a protein preparation or the like for improving the looseness of cooked rice, a rice rice cracking improver in which a processed product of egg yolk or whole egg phospholipase is dispersed in lipids (JP 2004-41046 A, JP 2005 JP). -295957) and the like. In addition, a substance using a decomposition product of alginic acid as an agent for improving the looseness of cooked rice is disclosed (Japanese Patent Laid-Open No. 2006-296259).

以上は、炊飯後の米飯を無菌密封して製造される一般的な無菌包装米飯用の米飯改良剤に関する従来技術であるが、炊飯と無菌包装を兼ねて製造される加圧加熱殺菌米飯(いわゆるレトルト米飯)用の米飯改良剤も検討されている。レトルト米飯は、生米と水をレトルト処理することによって製造されるが、このようにして製造された米飯は、餅様の板状となり、ほとんどほぐれず、通常の米飯とは程遠いものとなる。   The above is a conventional technique related to a general rice improving agent for aseptically packaged cooked rice that is produced by aseptically sealing cooked cooked rice. A rice improver for retort rice is also being studied. Retort cooked rice is produced by retorting raw rice and water. The cooked rice produced in this way has a bowl-like plate shape, hardly loosens, and is far from ordinary cooked rice.

レトルト米飯のほぐれ性を改善するための技術として、例えば、加熱時間を延長するレトルト米飯の製造方法(特開2006−158233号公報)、原料米を一部糊化した後冷却し、レトルト殺菌する方法(特開平6−303926号公報)等が開示されているが、いずれも工程が複雑で、既存の設備をそのまま適用出来ない場合がある。また、ヤーコン又はキクイモの塊根部及び抽出物を混合する方法(特開2006−67824号公報)、マンナンを添加する方法(特開平9−84535号公報)等も開示されているが、それぞれ米飯の呈味性及び食感に悪影響を及ぼすことは避けられない。   As a technique for improving the looseness of retort cooked rice, for example, a method for producing retort cooked rice that extends the heating time (Japanese Patent Laid-Open No. 2006-158233), partly gelatinized raw material rice, cooled, and then retort sterilized Although a method (Japanese Patent Laid-Open No. 6-303926) and the like are disclosed, there are cases where the process is complicated and existing equipment cannot be applied as it is. In addition, a method of mixing yacon or Jerusalem artichoke root and extract (Japanese Patent Laid-Open No. 2006-67824), a method of adding mannan (Japanese Patent Laid-Open No. 9-84535), etc. are also disclosed. It is unavoidable to adversely affect the taste and texture.

このように各種のほぐれ剤が開示されているが、これらのほぐれ剤は、そのまま食品にふりかけるものや、水に懸濁後麺表面にコーティングする使用法が例示されている。しかしながら、これらの従来のほぐれ剤は、油脂組成物のように、食品自体の本来の味覚に影響を及ぼすものや、大豆由来の水溶性多糖類とたんぱく質の酵素分解物のように、乾燥により色が褐変したり、アレルゲンを含有しているため、そのことが問題となるような場合がある。更に、食品の風味や食味を劣化させるという問題を抱えている。また、ほぐれ剤の成分として生澱粉を分解したデキストリンを用いたものでは、十分なほぐれ性を示さず、満足のいく品質とはいえないものもある。加工澱粉を酵素等で分解することからなるα化麺用ほぐれ剤は、風味の点から非常に良いものであるが、その製造において、添加した酵素等の除去が必要であり、煩雑な工程を必要とする為にコスト面に問題がある。したがって、従来のほぐれ剤は、簡便に製造出来、コスト面で従来のほぐれ剤と同等以上のメリットがあり、かつα化麺本来の風味や食味を損なうことなく、α化麺のほぐれ性を効果的に改良するという観点からは、必ずしも満足のいくものではなかった。   As described above, various loosening agents have been disclosed, and these loosening agents are exemplified by those that are sprinkled on food as they are, or the usage of coating the noodle surface after suspending in water. However, these conventional loosening agents are colored by drying, such as those that affect the original taste of the food itself, such as oil and fat compositions, and the enzymatic degradation products of soybean-derived water-soluble polysaccharides and proteins. May turn brown or contain allergens, which may cause problems. Furthermore, it has a problem of deteriorating the flavor and taste of food. Further, those using dextrin obtained by decomposing raw starch as a component of a loosening agent do not show sufficient loosening properties and may not be satisfactory. The loosening agent for pregelatinized noodles, which consists of decomposing processed starch with enzymes etc., is very good in terms of flavor, but in its production, it is necessary to remove the added enzymes etc. There is a problem in cost because it is necessary. Therefore, the conventional loosening agent can be easily manufactured, has the same or better merit as the conventional loosening agent in terms of cost, and has the effect of unraveling the α-noodle without sacrificing the original flavor and taste of the α-noodle. From the point of view of improvement, it was not always satisfactory.

特開昭63−283547号公報。Japanese Patent Laid-Open No. 63-283547. 特開平3−247249号公報。JP-A-3-247249. 特開平6−121647号公報。JP-A-6-121647. 特開平6−303926号公報。JP-A-6-303926. 特開平6−327427号公報。JP-A-6-327427. 特開平9−75022号公報。JP-A-9-75022. 特開平9−84535号公報。Japanese Patent Laid-Open No. 9-84535. 特開2000−139386号公報。JP 2000-139386 A. 特開2000−342209号公報。JP 2000-342209 A. 特開2001−238622号公報。JP 2001-238622 A. 特開2001−275589号公報。JP 2001-275589 A. 特開2001−352926号公報。JP 2001-352926 A. 特開2002−65184号公報。JP 2002-65184 A. 特開2002−65191号公報。JP 2002-65191 A. 特開2003−52319号公報。JP2003-52319A. 特開2003−265128号公報。JP2003-265128A. 特開2004−41046号公報。Japanese Patent Application Laid-Open No. 2004-41046. 特開2004−49065号公報。Japanese Patent Application Laid-Open No. 2004-49065. 特開2004−65216号公報。Japanese Patent Application Laid-Open No. 2004-65216. 特開2004−242570号公報。Japanese Patent Application Laid-Open No. 2004-242570. 特開2005−13135号公報。JP-A-2005-13135. 特開2005−295957号公報。JP 2005-295957 A. 特開2005−328728号公報。JP 2005-328728 A. 特開2006−6132号公報。JP 2006-6132 A. 特開2006−51012号公報。Japanese Patent Application Laid-Open No. 2006-51012. 特開2006−67824号公報。Japanese Patent Laid-Open No. 2006-67824. 特開2006−158233号公報。JP 2006-158233 A. 特開2006−238758号公報。JP, 2006-238758, A. 特開2006−296259号公報。JP 2006-296259 A. 特開2006−311849号公報。JP 2006-311849 A. 特開2006−333796号公報。JP 2006-333796 A. 特開2007−228834号公報。JP 2007-228834 A. 特開2008−283888号公報。Japanese Patent Application Laid-Open No. 2008-283888. 特開2009−11313号公報。JP 2009-11313 A. 特開2009−82025号公報。JP 2009-82025 A. 特開2009−136230号公報。JP 2009-136230 A. 特開2010−187655号公報。JP 2010-187655 A. 特開2011−19412号公報。JP 2011-19412 A. 特開2011−83210号公報。JP, 2011-83210, A.

本発明の課題は、茹でや蒸煮或いは炊飯等によって食品中の澱粉をα化させて喫食する食品のほぐれ性を改良する食品用ほぐれ剤、及び該食品用ほぐれ剤を用いたほぐれの良好な食品の製造方法を提供すること、特に、食品本来の風味や食味を損なうことなく、食品のほぐれ性を効果的に改良し、また、低コストでの食品のほぐれ性の改良が可能な食品用ほぐれ剤を提供すること、及び該食品用ほぐれ剤を用いて、ほぐれ性に優れ、味覚の良好な食品を製造する方法を提供することにある。   An object of the present invention is to provide a loosening agent for foods that improves the looseness of foods to be eaten by boiled, steamed or cooked rice, etc. A method for the production of foods, in particular, the looseness of foods can be effectively improved without impairing the original flavor and taste of foods, and the looseness of foods can be improved at low cost. It is to provide an agent, and to provide a method for producing a food having excellent looseness and good taste using the food loosening agent.

本発明者は、上記の課題を解決するために、食品本来の風味や食味を損なうことなく、食品のほぐれ性を効果的に改良し、また、実用上の要求から低コストでの食品のほぐれ性の改良が可能な食品用ほぐれ剤を提供すべく鋭意検討する中で、加工澱粉を超音波処理により、所定粘度以下にその粘度を低減化した加工澱粉超音波処理物をほぐれ剤として用いることにより、該ほぐれ剤を表面にコーティングした食品が、食品本来の風味や食味を損なうことなく、食品のほぐれ性が効果的に改良されることを見出し、本発明を完成するに至った。   In order to solve the above-mentioned problems, the present inventor has improved the looseness of the food effectively without impairing the original flavor and taste of the food, and the food can be loosened at a low cost due to practical requirements. In order to provide a food-use loosening agent capable of improving the properties, the processed starch sonicated product, whose viscosity has been reduced to a predetermined viscosity or lower by sonication, is used as a loosening agent. Thus, the present invention has been completed by finding that the food having the surface coated with the loosening agent can effectively improve the looseness of the food without impairing the original flavor and taste of the food.

すなわち、本発明は、加工澱粉を超音波処理し、5質量%水溶液における粘度が100mPa・s以下とした加工澱粉超音波処理物を含有することを特徴とする食品用ほぐれ剤、及び、該ほぐれ剤を用いた優れたほぐれ性と本来の風味や食味を保持した味覚の良好な食品の製造方法からなる。本発明のほぐれ剤は、加工澱粉の超音波処理という手段によって調製することができることから、低コストで提供することが可能であり、煩雑な処理を要求された従来のほぐれ剤提供の不具合を改良することが可能となった。   That is, the present invention comprises a processed starch sonication product, wherein the processed starch is sonicated and the viscosity in a 5% by mass aqueous solution is 100 mPa · s or less, and the loosening agent for food, It consists of a method for producing a food with excellent taste and good taste that retains its original flavor and taste. Since the loosening agent of the present invention can be prepared by means of ultrasonic treatment of processed starch, it can be provided at low cost and improves the problems of providing conventional loosening agents that require complicated processing. It became possible to do.

本発明の食品用ほぐれ剤において、含有される加工澱粉超音波処理物は、加工澱粉を超音波処理し、5質量%水溶液における粘度が100mPa・s以下とすることにより調製されるが、通常、その粘度は、5〜100mPa・sの範囲に調整されるのが好ましい。ここで、本発明において規定する粘度は、加工澱粉の分解度の度合を表示し、該粘度の表示において、「5質量%水溶液の粘度」は、「固形分換算で10gの該当試料と添加する水の合計量で200gにしたものを、内容量200mlのビーカーに秤取し、試料が冷水可溶の場合はそのまま溶解し、熱水可溶の場合は90℃まで昇温後冷却し、蒸発水分補正後、B型回転粘度計によって30℃の粘度を測定した値」として定義されるものである。   In the food loosening agent of the present invention, the processed starch sonication product to be contained is prepared by sonicating the processed starch and adjusting the viscosity in a 5% by mass aqueous solution to 100 mPa · s or less. The viscosity is preferably adjusted to a range of 5 to 100 mPa · s. Here, the viscosity defined in the present invention indicates the degree of degradation of the processed starch, and in the indication of the viscosity, “viscosity of 5% by mass aqueous solution” is “added with 10 g of the corresponding sample in terms of solid content”. What weighed 200 g in total is weighed into a 200 ml beaker. If the sample is soluble in cold water, it is dissolved as it is. If it is soluble in hot water, it is heated to 90 ° C. and then cooled and evaporated. It is defined as “a value obtained by measuring a viscosity at 30 ° C. with a B-type rotational viscometer after moisture correction”.

本発明に用いられる加工澱粉としては、タピオカ澱粉及び/又はワキシ種澱粉を原料澱粉として加工して得られる加工澱粉が特に好ましく、該加工澱粉としては、ヒドロキシプロピル化澱粉、ヒドロキシプロピル化リン酸架橋澱粉、リン酸モノエステル化澱粉、及びリン酸モノエステル化リン酸架橋澱粉のうちの一種類以上を用いることが特に好ましい。本発明の食品用ほぐれ剤において、加工澱粉超音波処理物の含量は、固形分換算で0.1%〜100質量%であることが好ましい。   As the processed starch used in the present invention, a processed starch obtained by processing tapioca starch and / or waxy seed starch as a raw material starch is particularly preferred, and as the processed starch, hydroxypropylated starch, hydroxypropylated phosphate cross-linked It is particularly preferable to use one or more of starch, phosphate monoesterified starch, and phosphate monoesterified phosphate cross-linked starch. In the food loosening agent of the present invention, the content of the processed starch sonication product is preferably 0.1% to 100% by mass in terms of solid content.

本発明は、本発明の食品用ほぐれ剤を食品の表面に塗布するか、或いは本発明の食品用ほぐれ剤を含有する溶液に食品を浸漬するかして、該食品用ほぐれ剤を食品の表面にコーティングすることにより、ほぐれ性の良好な食品を製造する方法を包含する。かかるほぐれ剤をコーティングし、そのほぐれ性を改良する食品としては、α化麺又は米飯のような食品を挙げることができる。本発明により、ほぐれ剤をコーティングし、ほぐれ性の良好な食品を製造するには、食品への加工澱粉超音波処理物の添加量が、食品の重量に対して、α化麺の場合は、固形物換算量で0.05〜3.0質量%になるように、又は、米飯の場合は、固形物換算量で0.05〜3.0質量%になるように、添加することが好ましい。   In the present invention, the food loosening agent of the present invention is applied to the surface of a food, or the food is immersed in a solution containing the food loosening agent of the present invention, and the food loosening agent is applied to the surface of the food. And a method for producing a food with good loosening properties by coating on the surface. Foods such as pregelatinized noodles or cooked rice can be mentioned as foods that are coated with such a loosening agent to improve the looseness. According to the present invention, in order to produce a food with good loosening properties by coating a loosening agent, the amount of processed starch sonication product to the food is pregelatinized noodles with respect to the weight of the food, It is preferable to add so that it may become 0.05-3.0 mass% in solid substance conversion amount, or in the case of cooked rice, it may become 0.05-3.0 mass% in solid substance conversion amount. .

すなわち具体的には本発明は、(1)加工澱粉を超音波処理し、5質量%水溶液における粘度が100mPa・s以下とした加工澱粉超音波処理物を含有することを特徴とする食品用ほぐれ剤や、(2)加工澱粉が、ヒドロキシプロピル化澱粉、ヒドロキシプロピル化リン酸架橋澱粉、リン酸モノエステル化澱粉、及びリン酸モノエステル化リン酸架橋澱粉からなる群から選択される一種類以上であることを特徴とする前記(1)に記載の食品用ほぐれ剤や、(3)加工澱粉の原料澱粉がタピオカ澱粉及び/又はワキシスターチであることを特徴とする前記(1)又は(2)に記載の食品用ほぐれ剤からなる。   Specifically, the present invention includes (1) a processed starch sonication product, and a processed starch sonication product having a viscosity in a 5% by mass aqueous solution of 100 mPa · s or less. One or more agents selected from the group consisting of an agent and (2) a hydroxypropylated starch, a hydroxypropylated phosphate-crosslinked starch, a phosphate monoesterified starch, and a phosphate monoesterified phosphate-crosslinked starch (1) or (2), wherein the food loosening agent according to (1) above, or (3) the raw starch of the processed starch is tapioca starch and / or waxy starch It consists of the loosening agent for foods of description.

また、本発明は、(4)加工澱粉超音波処理物の含量が、固形分換算で0.1%〜100質量%であることを特徴とする上記(1)〜(3)のいずれか記載の食品用ほぐれ剤や、(5)上記(1)〜(4)のいずれか1項に記載の食品用ほぐれ剤を、食品の表面に塗布するか、或いは、上記(1)〜(4)のいずれか1項に記載の食品用ほぐれ剤を含有する溶液に食品を浸漬するかして、食品の表面に食品用ほぐれ剤をコーティングすることを特徴とするほぐれ性の良好な食品の製造方法や、(6)食品が、α化麺又は米飯であることを特徴とする上記(5)記載のほぐれ性の良好な食品の製造方法や、(7)食品への加工澱粉超音波処理物の添加量が、食品の重量に対して、α化麺の場合は、固形物換算量で0.05〜3.0質量%になるように、又は、米飯の場合は、固形物換算量で0.05〜3.0質量%になるように、添加することを特徴とする上記(6)記載のほぐれ性の良好な食品の製造方法からなる。   In addition, the present invention provides (4) any one of the above (1) to (3), wherein the content of the processed starch sonication product is 0.1% to 100% by mass in terms of solid content. (5) The food loosening agent according to any one of (1) to (4) above is applied to the surface of the food, or (1) to (4) above. A method for producing a food with good loosening properties, wherein the food is immersed in a solution containing the food loosening agent according to any one of the above, and the food surface is coated with the food loosening agent. (6) The method for producing a food with good looseness as described in (5) above, wherein the food is pregelatinized noodles or cooked rice, or (7) a processed starch sonication product for food In the case of pregelatinized noodles based on the weight of the food, the amount added will be 0.05-3.0% by mass in terms of solids Or in the case of cooked rice, it is added so as to be 0.05 to 3.0% by mass in terms of solid matter, and the method for producing a food with good loosening properties as described in (6) above Consists of.

本発明により、茹でや蒸煮或いは炊飯等によって食品中の澱粉をα化させて喫食する麺類や、米飯等の食品のほぐれ性を改良する食品用ほぐれ剤、及び該食品用ほぐれ剤を用いたほぐれの良好な食品の製造方法を提供することにより、α化された麺類或いは炊飯米等の食品の製造の段階、又は流通、販売、喫食の段階でのほぐれ性を有効に改善し、食品本来の風味や食味を損なうことなく、良好なほぐれ性と高い味覚とを有するほぐれ性の良好な食品を提供することができる。また、本発明のほぐれ剤は、ほぐれ剤の調製に際して煩雑な工程を必要とすることなく、簡便、安価な方法で提供できることから、本発明は、実用性に富んだ食品用ほぐれ剤を提供することができる。   According to the present invention, noodles to be eaten by boiled, boiled, cooked rice, etc. by starching in food, a food loosening agent for improving the looseness of food such as cooked rice, and a loosening using the food loosening agent By providing a method for producing a good food, it is possible to effectively improve the looseness at the stage of production of food, such as pregelatinized noodles or cooked rice, or at the stage of distribution, sales, and eating. It is possible to provide a food with good looseness and good looseness and high taste without impairing the flavor and taste. In addition, since the loosening agent of the present invention can be provided by a simple and inexpensive method without the need for complicated steps in the preparation of the loosening agent, the present invention provides a loosening agent for foods that is highly practical. be able to.

すなわち、本発明により、茹、蒸煮で或いは炊飯等によってα化した麺類や、米飯等のα化食品のほぐれ性を効果的に改良することにより、ほぐれの良好なα化食品を製造し、該ほぐれ性の改善により、喫食時の味覚に優れたα化食品を提供することができることのみならず、該ほぐれ剤をインスタント食品の場合に適用して、湯戻しのような調理における復元性を改善して、商品価値の高いα化食品を提供することができる。特に、本発明の加工澱粉超音波処理物からなるほぐれ剤は、加工澱粉超音波処理物の特性から、α化食品本来の風味や食味を損なうことなく食品にほぐれ性を付与することができ、また、本発明の加工澱粉超音波処理物からなるほぐれ剤は、α化食品のほぐれ性を効果的に改良することができることから、低コストでのα化食品のほぐれ性の改善が可能であり、コストパフォーマンスの観点からも優れたα化食品のほぐれ性を提供することができる。   That is, according to the present invention, by effectively improving the looseness of the noodles that have been pregelatinized by rice bran, steaming or rice cooking, etc. By improving the looseness, not only can we provide pre-gelatinized foods with excellent taste when eating, but also apply the loosening agent to instant foods to improve resilience in cooking such as hot water reconstitution Thus, it is possible to provide a pregelatinized food product with high commercial value. In particular, the loosening agent comprising the processed starch ultrasonicated product of the present invention can impart a loosening property to the food without impairing the original flavor and taste of the pregelatinized food from the properties of the processed starch ultrasonicated product, In addition, the loosening agent comprising the processed starch ultrasonicated product of the present invention can effectively improve the looseness of the pregelatinized food, so that the looseness of the pregelatinized food can be improved at low cost. In addition, from the viewpoint of cost performance, it is possible to provide excellent looseness of pregelatinized food.

また、本発明の食品用ほぐれ剤を用いて、例えば、α化冷凍麺を製造することにより、冷凍麺の喫食時の解凍を著しく促進することができ、例えば、家庭用の火力が弱い解凍系でも短時間で十分な解凍ができ、より一層手軽になった冷凍麺を供給することができる。更に、米飯においては同様に、ほぐれ性の改善により喫食事の味覚や見栄えを向上させ商品価値の高い食品を提供することが出来る。無菌包装米飯及びレトルト米飯の製造にも適用でき、特に、従来、その製造が困難であった、生米を直接加圧加熱するレトルト米飯を容易に製造することが可能となる。このようにして得られる長期保存可能な無菌包装米飯やレトルト米飯は、レンジや湯煎等で再加熱して喫食でき、また、温水、調味液、スープ等を加えてほぐすことで手軽にお茶漬け、雑炊等への加工が可能であり、非常食としても有用である。   Further, by using the food loosening agent of the present invention, for example, by producing pregelatinized frozen noodles, it is possible to remarkably accelerate the thawing of the frozen noodles during eating, for example, a thawing system with a weak domestic thermal power However, it is possible to supply frozen noodles that can be thawed sufficiently in a short time and become even easier. Furthermore, in the case of cooked rice, it is also possible to provide food with high commercial value by improving the taste and appearance of eating by improving the looseness. The present invention can also be applied to the production of aseptically packaged cooked rice and retort cooked rice, and in particular, it is possible to easily produce retort cooked rice that has been difficult to produce in the past and directly pressurizes and heats raw rice. The long-term sterilized packaged rice and retort cooked rice obtained in this way can be reheated in a range or a hot water bath, etc., and can be easily cooked and cooked by adding hot water, seasoning liquid, soup, etc. Can be processed into a food, and is also useful as an emergency food.

本発明は、加工澱粉を超音波処理し、5質量%水溶液における粘度が100mPa・s以下とした加工澱粉超音波処理物を含有することを特徴とする食品用ほぐれ剤、及び、該ほぐれ剤を用いた優れたほぐれ性と本来の風味や食味を保持した味覚の良好な食品の製造方法からなる。   The present invention includes a processed starch sonication product characterized by containing a processed starch sonication product in which a processed starch is sonicated and the viscosity in a 5% by mass aqueous solution is 100 mPa · s or less. It consists of a method for producing a food with good taste that retains its excellent looseness and original flavor and taste.

(原料澱粉)
本発明において、用いる加工澱粉超音波処理物を調製するための加工澱粉の原料澱粉としては、自然界に見出される天然澱粉、或いは、交雑育種、転座、逆位、形質転換、またはそれらの変形を含むあらゆる他の遺伝子工学又は染色体工学の手法を含む標準的育種技術により得られた植物に由来する澱粉、或いは、人工的突然変異、及び既知の標準的な突然変異育種方法により生産することが可能な植物により得られた澱粉も、本発明に使用する原料澱粉に適している。澱粉への代表的な供給源は、穀類、塊茎、根、豆果及び果物である。天然源の具体例として、トウモロコシ、エンドウ、ジャガイモ、サツマイモ、バナナ、オオムギ、コムギ、米、サゴ、アマランス、タピオカ、カンナ、モロコシ、及びそれらのワキシ種又は高アミロース品種が挙げられるが、特に好ましい原料澱粉としては、タピオカ澱粉及びワキシ種澱粉を挙げることができる。
(Raw material starch)
In the present invention, the raw starch of the processed starch for preparing the processed starch sonication product to be used is a natural starch found in nature, or cross breeding, translocation, inversion, transformation, or a modification thereof. Starch derived from plants obtained by standard breeding techniques including any other genetic engineering or chromosomal engineering techniques, or can be produced by artificial mutation and known standard mutation breeding methods Starch obtained from various plants is also suitable for the raw material starch used in the present invention. Typical sources for starch are cereals, tubers, roots, legumes and fruits. Specific examples of natural sources include corn, peas, potatoes, sweet potatoes, bananas, barley, wheat, rice, sago, amaranth, tapioca, canna, sorghum, and their waxy or high amylose varieties. Examples of the starch include tapioca starch and waxy seed starch.

(加工澱粉超音波処理物)
本発明で使用する加工澱粉超音波処理物とは、加工澱粉を水に懸濁後、加熱して糊化後、超音波を糊液に照射して、粘度を低下させたもの及びこれを水素添加した還元物を指称する。形態的には液状でも、要すれば噴霧乾燥、凍結乾燥、或いはドラム乾燥した粉末状であってもよい。更に、溶解性を向上させるために造粒などの物理的処理等によって溶解しやすい形態に加工されたものでもよい。
(Processed starch sonication product)
The processed starch sonication product used in the present invention is a product obtained by suspending processed starch in water, heating to gelatinize, irradiating the paste with ultrasonic waves to reduce the viscosity, and hydrogenating this. The reduced product added is designated. It may be liquid in form or spray-dried, freeze-dried, or drum-dried if necessary. Furthermore, in order to improve solubility, what was processed into the form which is easy to melt | dissolve by physical treatments, such as granulation, etc. may be used.

(加工澱粉超音波処理物の調製)
本発明で用いられる加工澱粉超音波処理物を製造するために用いられる加工澱粉としては、エーテル化澱粉、エステル化澱粉、リン酸架橋澱粉等のいずれの加工澱粉でも良いが、特に好ましくは、ヒドロキシプロピル化澱粉、ヒドロキシプロピル化リン酸架橋澱粉、リン酸モノエステル化澱粉、及びリン酸モノエステル化リン酸架橋澱粉のうちの一種類又は二種類以上を含有するものを挙げることができる。
(Preparation of processed starch sonication product)
The processed starch used for producing the processed starch sonicated product used in the present invention may be any processed starch such as etherified starch, esterified starch, phosphoric acid cross-linked starch, etc., particularly preferably hydroxy Mention may be made of those containing one or more of propylated starch, hydroxypropylated phosphoric acid crosslinked starch, phosphoric acid monoesterified starch, and phosphoric acid monoesterified phosphoric acid crosslinked starch.

(加工澱粉超音波処理物の粘度)
本発明における食品用ほぐれ剤には、加工澱粉超音波処理物の粘度が、5質量%水溶液において100mPa・s以下の範囲に属する加工澱粉超音波処理物を使用する。粘度がこの範囲にない加工澱粉超音波処理物では本発明の効果が十分に発揮し得ない。すなわち、粘度が5質量%水溶液において100mPa・s以上の加工澱粉超音波処理物を用いた場合には、α化された食品の表面にコーティングされても、加工澱粉超音波処理物の粘度が高い為に逆に結着力を増し、ほぐれ効果とは逆の効果を示す傾向となる。
(Viscosity of processed starch sonication product)
As the food loosening agent in the present invention, a processed starch sonication product having a viscosity of the processed starch sonication product in the range of 100 mPa · s or less in a 5% by mass aqueous solution is used. The processed starch sonication product having a viscosity not in this range cannot sufficiently exhibit the effects of the present invention. That is, when a processed starch sonication product having a viscosity of 100 mPa · s or more in a 5% by mass aqueous solution is used, the processed starch sonication product has a high viscosity even when coated on the surface of a pregelatinized food. For this reason, the binding force is increased, and the effect is opposite to the loosening effect.

(粘度の測定)
本発明において、加工澱粉の分解度の度合として用いる粘度は、固形分換算で10gの該当試料と添加する水の合計量で200gにしたものを、内容量200mlのビーカーに秤取し、試料が冷水可溶の場合はそのまま溶解し、熱水可溶の場合は90℃まで昇温後冷却し、蒸発水分補正後、B型回転粘度計によって30℃の粘度を測定した値として表示される。
(Measurement of viscosity)
In the present invention, the viscosity used as the degree of degradation of the processed starch is 10 g in terms of solid content and the total amount of water added to 200 g, and weighed into a 200 ml beaker. In the case of being soluble in cold water, it is dissolved as it is, and in the case of being soluble in hot water, the temperature is raised to 90 ° C. and then cooled, and after correcting for evaporated water, it is displayed as a value measured by a B-type rotational viscometer.

(α化麺)
本発明でいうα化麺とは、茹で或いは蒸煮処理された麺類を指称し、具体的には、うどん、そば、中華麺、スパゲッティ、マカロニ、はるさめ、ビーフン、フォーなどの麺類を茹で或いは蒸煮によってα化処理されたものを意味し、常温、チルド、冷凍、或いは即席麺の状態で流通し、何も手を加えないか、水さばきのみをするか、解凍するか或いは湯もどしなどの再加熱後喫食されるものをいう。
(Alpha noodle)
The α-noodle as used in the present invention refers to noodles that have been boiled or steamed, and specifically, noodles such as udon, buckwheat, Chinese noodles, spaghetti, macaroni, harusame, rice noodles, pho, etc. It means a product that has been pre-gelatinized and is distributed at room temperature, chilled, frozen, or instant noodles, and is reheated with no modification, watering only, thawing, or thawing. This is what will be eaten later.

(米飯)
本発明において、米飯に使用される米は粳米が望ましいが、粳米の一部、若しくは全部を糯米に置き換えて、強米としても良い。また、稗、粟、麦、大麦、胡麻といった米飯の栄養強化を主な目的として使用されている各種雑穀類を適宜加えても差し支えない。
(Rice rice)
In the present invention, the rice used for the cooked rice is preferably sticky rice, but some or all of the sticky rice may be replaced with sticky rice to make strong rice. Moreover, various cereals that are used mainly for the purpose of enhancing the nutrition of cooked rice such as rice bran, straw, barley, barley and sesame may be added as appropriate.

本発明でいう米飯には、味付けをしない白飯、塩やふりかけ等を用いて塩味をつけた塩飯、加水量を増加した白粥、梅、シャケ、玉子等を加えた各種お粥、酢、砂糖、みりん、出汁等が添加されたすし飯等に加え、出汁、醤油、酒、みりん、酢、香料等の各種調味液、塩、砂糖、コショウ等の各種粉末調味料や小豆やササゲ豆といった豆類、野菜、山菜、魚介類、玉子、肉類、加工肉類など各種具材を適宜、炊飯前、もしくは炊飯後に混ぜた炊き込みご飯や混ぜご飯、ピラフ、チャーハン、リゾット類、赤飯や各種おこわ類、更には炊飯後の白飯に前述の各種調味液、各種粉末調味料、各種具材を適宜加え、加熱調理した調理米飯、お茶漬け、雑炊等が含まれる。これらの米飯類の形態としては、給食、弁当、無菌包装パック、レトルトパック、缶詰等が例示されるが、これらに限定されない。この際、各種ふりかけ、お茶漬けの素、雑炊の素等を予め混合するか別添として添えることもできる。   In the rice referred to in the present invention, non-seasoned white rice, salted rice with salt or sprinkles, etc., white rice with increased water content, plums, salmon, eggs, etc. In addition to sushi rice to which mirin, broth, etc. are added, various seasonings such as broth, soy sauce, sake, mirin, vinegar, fragrance, various powder seasonings such as salt, sugar, pepper, and beans such as red beans and cowpeas, Rice, mixed rice, pilaf, fried rice, risotto, red rice and various kinds of rice, as well as rice The above-mentioned various seasoning liquids, various powder seasonings, various ingredients are added as appropriate to the cooked white rice, and cooked cooked rice cooked by cooking, tea pickles, miscellaneous cooking, etc. are included. Examples of these cooked rice include, but are not limited to, lunch, lunch box, aseptic packaging pack, retort pack, and canned food. At this time, various kinds of sprinkles, Ochazuke elements, cooking ingredients, etc. can be mixed in advance or attached as an attachment.

また、各種の栄養強化剤や市販の米飯改良剤を併用することもできる。例えば、食物繊維を増強する目的で、難消化性デキストリンやポリデキストロース等を炊飯前、もしくは炊飯後に加えてもよい。また、マンナンライス等のこんにゃく米や、スターライス等の人造米、アルファー化米等に用いても差し支えない。このようにして得られる米飯類は常温、冷蔵及び冷凍のいずれの形態でも保存可能であり、喫食時には必要に応じてレンジアップ等の再加熱を行うことも可能である。   Moreover, various nutrient fortifiers and commercially available cooked rice improvers can be used in combination. For example, for the purpose of enhancing dietary fiber, indigestible dextrin, polydextrose and the like may be added before or after cooking. Moreover, it may be used for konjac rice such as mannan rice, artificial rice such as star rice, and alpha rice. The cooked rice thus obtained can be stored in any form of room temperature, refrigerated, and frozen, and can be reheated as necessary, such as range up, when eating.

(ほぐれ剤調製品)
本発明のほぐれ剤は、5質量%水溶液における粘度が100mPa・s以下の加工澱粉超音波処理物を単独又はこれに他の成分を併用して調製することができる。たとえば、本発明の加工澱粉超音波処理物に、更に、大豆多糖類、デキストリン、デキストラン、サイクロデキストリン、高度分岐環状デキストリン、イソマルトオリゴ糖、卵白粉末、卵黄粉末、全卵粉末、カゼイン、カゼインナトリウム、乳蛋白、コラーゲン、ゼラチン、血漿蛋白、小麦蛋白、大豆蛋白、エンドウ豆蛋白、キサンタンガム、グァーガム、タマリンドシードガム、ローカストビーンガム、カラギーナン、グルコマンナン、カードラン、アラビアガム、カラヤガム、サイリウムシードガム、ジェランガム、タラガム、プルラン、ペクチン、フコイダン、アガロペクチン、アルギン酸、アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル、カルボキシメチルセルロースナトリウム、カルボキシメチルセルロースカルシウム、難消化性デキストリン、ポリデキストロース、水溶性大豆多糖類、大豆食物繊維、グリセリン脂肪酸エステル、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、ステアロイル乳酸カルシウム、レシチン、ポリアクリル酸ナトリウム、乳化油脂、油脂、上記以外の乳化剤、及びそれらの酵素分解などの処理によって派生して得られた物質等の中から少なくとも1種以上を適量併用してもよい。また、本発明のほぐれ剤は、造粒した形態で調製することができる。かかる造粒の際には、加工澱粉超音波処理物を単品で造粒しただけでなく、該物質を他の物質と混合後造粒してもよい。
(Feeling agent preparation)
The loosening agent of the present invention can be prepared by using a processed starch sonication product having a viscosity of 100 mPa · s or less in a 5% by mass aqueous solution alone or in combination with other components. For example, in the processed starch sonicated product of the present invention, soybean polysaccharide, dextrin, dextran, cyclodextrin, highly branched cyclic dextrin, isomaltooligosaccharide, egg white powder, egg yolk powder, whole egg powder, casein, casein sodium, Milk protein, collagen, gelatin, plasma protein, wheat protein, soy protein, pea protein, xanthan gum, guar gum, tamarind seed gum, locust bean gum, carrageenan, glucomannan, curdlan, gum arabic, karaya gum, psyllium seed gum, gellan gum , Tara gum, pullulan, pectin, fucoidan, agaropectin, alginic acid, sodium alginate, propylene glycol alginate, sodium carboxymethylcellulose, carboxymethylcellulose Sium, resistant dextrin, polydextrose, water-soluble soybean polysaccharide, soybean dietary fiber, glycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester At least one or more of sugar fatty acid esters, stearoyl calcium lactate, lecithin, sodium polyacrylate, emulsified oils and fats, oils and fats, emulsifiers other than those mentioned above, and substances obtained by processing such as enzymatic degradation thereof. An appropriate amount may be used in combination. The loosening agent of the present invention can be prepared in a granulated form. In such granulation, not only the processed starch sonication product is granulated as a single product, but also the material may be granulated after being mixed with other materials.

(ほぐれ性α化麺の製造)
本発明において、本発明のほぐれ剤を適用するα化麺の製造は、従来のα化麺の製造法に従って行うことができる。すなわち、小麦粉又はソバ粉、及び必要に応じて澱粉類を主原料として、水、食塩、かんすい等の副原料、及び必要に応じて重合リン酸塩、色素、卵粉、カゼイン、天然ガム、有機酸などのように通常用いられる添加物を使用して製麺した麺類を、沸騰浴中で茹でてα化、或いは、蒸煮によってα化、或いはその両方を用いてα化し、製造することができる。
(Manufacture of loosening pregelatinized noodle)
In the present invention, the production of pregelatinized noodles to which the loosening agent of the present invention is applied can be performed according to a conventional method for producing pregelatinized noodles. That is, wheat flour or buckwheat flour, and if necessary, starches as the main ingredients, auxiliary ingredients such as water, salt, citrus and the like, polymerized phosphate, pigment, egg powder, casein, natural gum, organic Noodles made with noodles using commonly used additives such as acids can be boiled in a boiling bath and then α-ized by steaming, or α-ized by steaming, or both. .

ほぐれ剤は、該α化した麺類の表面に塗布するか、或いは、α化麺用ほぐれ剤を含有する溶液に、α化麺を浸漬することにより、麺の表面にコーティングして、添加することができる。この時、麺類の最終形態によっては、麺類を沸騰浴中で茹でてα化し、或いは、蒸煮によってα化した後の冷却中、或いは、冷却後に加工澱粉超音波処理物を添加してもよい。   The loosening agent is applied to the surface of the pregelatinized noodles, or added to the surface of the noodles by immersing the pregelatinized noodles in a solution containing the loosening agent for pregelatinized noodles. Can do. At this time, depending on the final form of the noodles, the processed starch sonication product may be added during the cooling after the noodles are boiled in a boiling bath and then converted into α by steaming or after cooling.

α化した麺類をそのまま包装してチルド流通或いは、常温流通される形態において、又は、α化した麺類を冷凍して流通させる形態においては、麺類を茹で或いは蒸煮によってα化した後水洗いし、水切りした麺に加工澱粉超音波処理物の水溶液を均一に噴霧する方法によって、或いは、加工澱粉超音波処理物の水溶液に麺を浸漬させて吸着させる方法によって、又は、冷水に溶解する粉末状の加工澱粉超音波処理物を、水切りした麺にふりかける方法によって、ほぐれ剤をα化麺に適用することができる。更に、蒸煮殺菌前に有機酸処理されるロングライフ麺には、この有機酸溶液に溶解して添加する方法も実施することができる。   In a form in which α-noodles are packaged as they are and chilled or distributed at room temperature, or in a form in which α-noodles are frozen and distributed, the noodles are gelatinized by boiling or steaming, then washed with water and drained. The processed noodles are uniformly sprayed with an aqueous solution of the processed starch sonication product, or the noodles are immersed in the aqueous solution of the processed starch sonication product, or the powdered processing is dissolved in cold water. The loosening agent can be applied to the pregelatinized noodles by a method in which the ultrasonically treated starch is sprinkled on the drained noodles. Furthermore, it is also possible to carry out a method of dissolving and adding this organic acid solution to long-life noodles that are treated with an organic acid prior to steam sterilization.

また、α化後熱風乾燥或いは油フライ乾燥して流通する即席麺においては、蒸煮或いは茹で或いはその併用によってα化された直後に、加工澱粉超音波処理物を含有したほぐれ剤を麺線に均一に噴霧する方法、加工澱粉超音波処理物を含有したほぐれ剤に浸漬させて表面にコーティングする方法によって、ほぐれ剤を麺に適用することができる。   In addition, in instant noodles that are circulated by hot-air drying or oil-fried drying after pregelatinization, the loosening agent containing the processed starch sonication product is uniformly applied to the noodle strings immediately after being pregelatinized by steaming, boiling, or a combination thereof. The loosening agent can be applied to the noodles by a method of spraying on the surface and a method of immersing in a loosening agent containing a processed starch sonication product and coating the surface.

加工澱粉超音波処理物をα化麺に添加する量としては、麺に使用される原材料、麺線の太さや形状、或いは貯蔵や流通期間の長短などによって、一概には言えないが、一般にはα化した麺重量に対して、加工澱粉超音波処理物の固形分換算量が0.05から3.0質量%程度の範囲になる様に添加する事が望ましい。固形分換算量が0.05質量%未満では本発明の効果が乏しくなる傾向を示し、3.0質量%を超えて添加しても麺線のほぐれ効果に差は見られずコストパフォーマンスに劣る。   The amount of processed starch sonicated product added to pregelatinized noodles cannot be generally stated, depending on the raw materials used in the noodles, the thickness and shape of the noodle strings, or the length of the storage and distribution period. It is desirable to add so that the solid content conversion amount of the processed starch sonication product is in the range of about 0.05 to 3.0% by mass with respect to the weight of the pre-gelatinized noodles. If the amount in terms of solid content is less than 0.05% by mass, the effect of the present invention tends to be poor, and even if added over 3.0% by mass, there is no difference in the loosening effect of the noodle strings and the cost performance is inferior. .

このようにして製造されたα化麺は、常温やチルド・冷凍という従来と全く変わらない形態を取って流通させることができ、保存中或いは流通段階での麺線の付着が改善され、湯もどしする場合にも麺線のほぐれが容易であるα化麺が得られる。   The pregelatinized noodles produced in this way can be distributed in a form that is completely different from conventional ones such as normal temperature, chilled and frozen, and the adhesion of the noodle strings during storage or distribution is improved, so In this case, pregelatinized noodles can be obtained in which the noodle strings are easily loosened.

以下に、実施例、参考例を挙げて、本発明を更に具体的に説明するが、本発明の技術的範囲はこれらの例示に限定されるものではない。なお、以下の実施例、参考例に於ける部は、質量部を表す。   Hereinafter, the present invention will be described more specifically with reference to examples and reference examples. However, the technical scope of the present invention is not limited to these examples. In addition, the part in a following example and a reference example represents a mass part.

(澱粉及び加工澱粉の超音波処理物の調製)
(1)ワキシコーン澱粉100部に対してオキシ塩化リン0.1部を添加し、常法に従って反応させた。得られた試料にプロピレンオキサイド10部を加え、同様に常法に従って反応させた後、水洗、脱水、乾燥して比較試料1(ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉)を得た。
(2)比較試料1の5質量%濃度スラリーを加熱して糊化後、超音波分散機((株)ギンセン GSD600HAT)に供し、流速0.5L/minで1回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉の超音波処理物を得た。5質量%粘度は633mPa・sであり、これを比較試料2とした。
(Preparation of sonicated starch and processed starch)
(1) 0.1 part of phosphorus oxychloride was added to 100 parts of waxy corn starch, and reacted according to a conventional method. 10 parts of propylene oxide was added to the obtained sample and reacted in the same manner in the same manner, followed by washing with water, dehydration, and drying to obtain Comparative Sample 1 (hydroxypropylated phosphate cross-linked waxy corn starch).
(2) After heating and gelatinizing the 5 mass% slurry of the comparative sample 1, it was subjected to an ultrasonic disperser (Ginsen GSD600HAT) and processed once at a flow rate of 0.5 L / min. Got. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate cross-linked waxy corn starch. The 5 mass% viscosity was 633 mPa · s, and this was designated as Comparative Sample 2.

(3)比較試料1の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで2回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉の超音波処理物を得た。5質量%粘度は298mPa・sであり、これを比較試料3とした。
(4)比較試料1の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで4回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉の超音波処理物を得た。5質量%粘度は38mPa・sであり、これを試料1とした。
(3) After heating and gelatinizing the 5 mass% concentration slurry of the comparative sample 1, it was subjected to an ultrasonic disperser and processed twice at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate cross-linked waxy corn starch. The 5 mass% viscosity was 298 mPa · s, and this was designated as Comparative Sample 3.
(4) After heating and gelatinizing the 5 mass% concentration slurry of the comparative sample 1, it was subjected to an ultrasonic disperser and processed four times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate cross-linked waxy corn starch. The 5 mass% viscosity was 38 mPa · s.

(5)比較試料1の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで15回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉の超音波処理物を得た。5質量%粘度は8mPa・sであり、これを試料2とした。
(6)比較試料1の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで30回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋ワキシコーン澱粉の超音波処理物を得た。5質量%粘度は7mPa・sであり、これを試料3とした。
(5) After heating and gelatinizing the 5 mass% slurry of the comparative sample 1, it was subjected to an ultrasonic disperser and processed 15 times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate cross-linked waxy corn starch. The 5 mass% viscosity was 8 mPa · s.
(6) After heating and gelatinizing the 5 mass% concentration slurry of the comparative sample 1, it was subjected to an ultrasonic disperser and processed 30 times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate cross-linked waxy corn starch. The 5 mass% viscosity was 7 mPa · s.

(7)タピオカ澱粉100部に対してオキシ塩化リン0.1部を添加し、常法に従って反応させた。得られた試料にプロピレンオキサイド10部を加え、同様に常法に従って反応させた後、水洗、脱水、乾燥して比較試料4(ヒドロキシプロピル化リン酸架橋タピオカ澱粉)を得た。
(8)比較試料4の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで2回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋タピオカ澱粉の超音波処理物を得た。5質量%粘度は118mPa・sであり、これを比較試料5とした。
(7) 0.1 part of phosphorus oxychloride was added to 100 parts of tapioca starch and reacted according to a conventional method. 10 parts of propylene oxide was added to the obtained sample and reacted in the same manner in the same manner, followed by washing with water, dehydration and drying to obtain Comparative Sample 4 (hydroxypropylated phosphate cross-linked tapioca starch).
(8) After heating and gelatinizing the 5 mass% concentration slurry of the comparative sample 4, it was subjected to an ultrasonic disperser and processed twice at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate-crosslinked tapioca starch. The 5 mass% viscosity was 118 mPa · s, and this was designated as Comparative Sample 5.

(9)比較試料4の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで4回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化リン酸架橋タピオカ澱粉の超音波処理物を得た。5質量%粘度は27mPa・sであり、これを試料4とした。
(10)タピオカ澱粉5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで1回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、タピオカ澱粉の超音波処理物を得た。5質量%粘度は、376mPa・sであり、これを比較試料6とした。
(9) After heating and gelatinizing the 5 mass% concentration slurry of the comparative sample 4, it was subjected to an ultrasonic disperser and processed four times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated phosphate-crosslinked tapioca starch. The 5 mass% viscosity was 27 mPa · s.
(10) A tapioca starch 5% by mass concentration slurry was heated to gelatinize, then subjected to an ultrasonic disperser and processed once at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of tapioca starch. The 5 mass% viscosity was 376 mPa · s, and this was designated as Comparative Sample 6.

(11)タピオカ澱粉5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで2回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、タピオカ澱粉の超音波処理物を得た。5質量%粘度は、114mPa・sであり、これを比較試料7とした。
(12)タピオカ澱粉5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで4回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、タピオカ澱粉の超音波処理物を得た。5質量%粘度は、34mPa・sであり、これを比較試料8とした。
(11) A 5 mass% slurry of tapioca starch was heated and gelatinized, then subjected to an ultrasonic disperser and treated twice at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of tapioca starch. The 5 mass% viscosity was 114 mPa · s, and this was designated as Comparative Sample 7.
(12) A tapioca starch 5 mass% concentration slurry was heated and gelatinized, and then subjected to an ultrasonic disperser, and processed 4 times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of tapioca starch. The 5 mass% viscosity was 34 mPa · s.

(13)タピオカ澱粉100部に対してプロピレンオキシドを5部添加し、常法に従って反応させ、水洗、脱水、乾燥して比較試料9(ヒドロキシプロピル化タピオカ澱粉)を得た。
(14)比較試料9の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで4回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化タピオカ澱粉の超音波処理物を得た。5質量%粘度は35mPa・sであり、これを試料5とした。
(13) 5 parts of propylene oxide was added to 100 parts of tapioca starch, reacted according to a conventional method, washed with water, dehydrated and dried to obtain comparative sample 9 (hydroxypropylated tapioca starch).
(14) After heating and gelatinizing the 5 mass% slurry of the comparative sample 9, it was subjected to an ultrasonic disperser and processed four times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated tapioca starch. The 5 mass% viscosity was 35 mPa · s.

(15)比較試料9の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで15回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、ヒドロキシプロピル化タピオカ澱粉の超音波処理物を得た。5質量%粘度は22mPa・sであり、これを試料6とした。
(16)ワキシコーン澱粉100部に対して無水オクテニルコハク酸を3部添加し、常法に従って反応させた後、水洗、脱水、乾燥して比較試料10(オクテニルコハク酸ワキシコーン澱粉ナトリウム)を得た。
(15) After heating and gelatinizing the 5 mass% slurry of the comparative sample 9, it was subjected to an ultrasonic disperser and processed 15 times at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain a sonicated product of hydroxypropylated tapioca starch. The 5 mass% viscosity was 22 mPa · s.
(16) 3 parts of octenyl succinic anhydride was added to 100 parts of waxy corn starch, reacted according to a conventional method, washed with water, dehydrated and dried to obtain comparative sample 10 (sodium octenyl succinate waxy corn starch).

(17)比較試料10の5質量%濃度スラリーを加熱して糊化後、超音波分散機に供し、流速0.5L/minで1回処理して超音波処理液を得た。これをドラムドライヤーにて粉末化し、オクテニルコハク酸ワキシコーン澱粉ナトリウムの超音波処理物を得た。5質量%粘度は779mPa・sであり、これを比較試料11とした。   (17) A 5% by weight concentration slurry of Comparative Sample 10 was heated and gelatinized, then subjected to an ultrasonic disperser, and processed once at a flow rate of 0.5 L / min to obtain an ultrasonic treatment liquid. This was pulverized with a drum dryer to obtain an ultrasonically treated product of sodium octenyl succinate waxycorn starch. The 5 mass% viscosity was 779 mPa · s, and this was designated as Comparative Sample 11.

(澱粉及び加工澱粉の酵素処理物の調製)
(1)ワキシコーンスターチ澱粉固形物100部に対して、大和化成株式会社製のαアミラーゼ(製品名:クライスターゼKM)0.15部を常法によって作用させ、ワキシコーンスターチ澱粉の酵素処理物を得た。5質量%粘度は、4mPa・sであり、これを比較試料12とした。
(2)比較試料1の固形物100部に対して、大和化成株式会社製のαアミラーゼ
(製品名:クライスターゼKM)0.15部を常法によって作用させ、ヒドロキシプロピル化リン酸架橋ワキシコーンスターチの酵素処理物を得た。5質量%粘度は4mPa・sであり、これを比較試料13とした。
(Preparation of enzyme-treated starch and processed starch)
(1) 0.15 parts of α-amylase (product name: Christase KM) manufactured by Daiwa Kasei Co., Ltd. is allowed to act on 100 parts of waxy corn starch starch solids by a conventional method to produce an enzyme-treated product of waxy corn starch Got. The 5 mass% viscosity was 4 mPa · s.
(2) 0.15 part of α-amylase (product name: Christase KM) manufactured by Daiwa Kasei Co., Ltd. is allowed to act on 100 parts of the solid material of Comparative Sample 1 by a conventional method, and hydroxypropylated phosphate cross-linked waxy An enzyme-treated product of corn starch was obtained. The 5 mass% viscosity was 4 mPa · s.

(チルド麺でのほぐれ評価方法)
ほぐれの評価には、市販のチルド麺(ゆでうどん)を用いた。チルド麺200gを熱湯で3分間茹で、冷水にて冷却して茹で麺とした。表1に示すほぐれ液を茹で麺重量100部に対して3部噴霧したものをポリエチレン袋に200g量りとり、密封した状態で冷蔵庫にて1日保存した後、ほぐれ効果を評価した。すなわち、箸でほぐした時のほぐれ易さを10点満点て評価した。
(Method for evaluating loosening with chilled noodles)
Commercial chilled noodles (boiled udon) were used for evaluation of loosening. 200 g of chilled noodles were boiled with hot water for 3 minutes and cooled with cold water to make boiled noodles. 200 g of a solution obtained by spraying 3 parts of the loosening liquid shown in Table 1 with 100 parts by weight of noodles was boiled in a polyethylene bag, stored in a refrigerator in a sealed state for 1 day, and then evaluated for the loosening effect. That is, the ease of unraveling when unraveling with chopsticks was evaluated with a maximum of 10 points.

(チルド麺での評価結果)
ほぐれ液配合及びほぐれ評価の結果を表1に示す。なお、表中、ソヤファイブは、不二製油株式会社製の水溶性大豆多糖類を示す。加工澱粉の超音波処理物は、生澱粉の分解物や加工澱粉の酵素処理物よりもほぐれ効果の評価が高く、特にその中でも試料2及び3のほぐれ効果の評価が高かった。
(Evaluation results with chilled noodles)
Table 1 shows the results of the loosening liquid formulation and the loosening evaluation. In the table, “Soya Five” represents a water-soluble soybean polysaccharide manufactured by Fuji Oil Co., Ltd. The sonicated processed starch was higher in evaluation of the unraveling effect than the decomposed product of raw starch and the processed enzyme of processed starch, and in particular, the evaluation of the unraveling effect of Samples 2 and 3 was higher.

Figure 2013034414
Figure 2013034414

(ノンフライ麺でのほぐれ評価方法)
ほぐれの評価には、小麦粉80部、松谷桜2(松谷化学工業製アセチル化澱粉)20部、食塩1部及び水38部をミキサーで混練し、複合・圧延して麺帯を1.00mmにした後、切り刃♯10角で切り出し蒸煮した。この蒸煮した後の麺に、表2に示すほぐれ液を、蒸煮した麺に対して30%添加混合して枠形成し、熱風乾燥してノンフライ麺を試作した。このノンフライ麺をカップに移して熱湯で4分間湯戻しして評価を行った。評価はチルド麺の評価と同様に行った。
(Method for evaluating loosening with non-fried noodles)
For the evaluation of loosening, 80 parts of wheat flour, 20 parts of Matsutani Sakura 2 (acetylated starch made by Matsutani Chemical Industry), 1 part of salt and 38 parts of water were kneaded with a mixer, combined and rolled to a noodle band of 1.00 mm. Then, it was cut out and steamed with a cutting blade # 10 square. The steamed noodles shown in Table 2 were added to and mixed with 30% of the steamed noodles in the steamed noodles to form a frame, which was dried with hot air to make a non-fried noodle. The non-fried noodles were transferred to a cup and reconstituted with hot water for 4 minutes for evaluation. Evaluation was performed in the same manner as for chilled noodles.

(ノンフライ麺での評価結果)
ほぐれ液配合及びほぐれ評価の結果を表2に示す。なお、表中、ソヤファイブは、不二製油株式会社製の水溶性大豆多糖類を示す。加工澱粉の超音波処理物は、生澱粉の分解物や加工澱粉の酵素処理物よりもほぐれ効果の評価が高く、特にその中でも試料2及び3でほぐれ効果の評価が高かった。
(Evaluation results with non-fried noodles)
Table 2 shows the results of the unraveling liquid formulation and the unraveling evaluation. In the table, “Soya Five” represents a water-soluble soybean polysaccharide manufactured by Fuji Oil Co., Ltd. The sonicated processed starch was higher in the evaluation of the loosening effect than the decomposed product of raw starch and the processed product of the processed starch, and in particular, the evaluation of the unraveling effect was higher in Samples 2 and 3.

Figure 2013034414
Figure 2013034414

(米飯での評価方法)
市販の無洗米(きらら397)2合(300g)を手早く洗米し、十分量の水で30分浸漬した。得られた米の水分をザルで切り、ほぐれ剤を1.5g添加混合して加水し、総重量を810gとして家庭用の電気炊飯器で自動炊飯を行った。得られた白飯は釜から取り出し、しゃもじで全体をほぐしつつ均質になるようにかき混ぜた。水分が飛ばないようにラップをし、常温で冷ましてから、米飯の評価を行った。評価は手でほぐした時のほぐれ易さを10点満点で評価した。
(Evaluation method with cooked rice)
Commercially washed rice (Kirara 397) 2 go (300 g) was quickly washed and immersed in a sufficient amount of water for 30 minutes. Moisture of the obtained rice was cut with a colander, 1.5 g of a loosening agent was added and mixed, and hydrated, and the total weight was 810 g. The obtained white rice was taken out from the kettle and stirred until it became homogeneous while loosening the whole with rice scoop. The rice was evaluated after wrapping so that moisture did not fly and cooling at room temperature. In the evaluation, the ease of unraveling when unraveled by hand was evaluated with a maximum of 10 points.

(米飯での評価結果)
ほぐれ評価の結果を表3に示す。なお、表中、SM700は、市販の米飯改良剤である三栄源エフ・エフ・アイ株式会社製の大豆食物繊維を示す。加工澱粉の超音波処理物は、生澱粉の分解物や加工澱粉の酵素処理物よりもほぐれ効果の評価が高く、特にその中でも試料2及び3でほぐれ効果の評価が高かった。
(Evaluation results with cooked rice)
The results of the loosening evaluation are shown in Table 3. In the table, SM700 indicates soybean dietary fiber manufactured by San-Ei Gen FFI Co., Ltd., which is a commercially available rice improver. The sonicated processed starch was higher in the evaluation of the loosening effect than the decomposed product of raw starch and the processed product of the processed starch, and in particular, the evaluation of the unraveling effect was higher in Samples 2 and 3.

Figure 2013034414
Figure 2013034414

(レトルト米飯での評価方法)
市販の米を手早く洗米し、生米に対して1.4倍重の水を加え、ほぐれ剤を対生米5%又は10%添加し、パウチに封入した後、120℃30分の条件でレトルト処理を行った。得られたレトルト製品をパウチから出し、かぶる程度のお湯をかけてお湯漬けごはんとし、ほぐれ性を評価した。評価は箸でほぐした時のほぐれ易さを10点満点で評価した。
(Evaluation method with retort rice)
Quickly wash commercially available rice, add 1.4 times the weight of fresh rice, add 5% or 10% loosening agent to the rice, enclose it in a pouch, and then retort at 120 ° C for 30 minutes Processed. The obtained retort product was taken out from the pouch, covered with hot water so that it could be cooked in hot water, and the looseness was evaluated. The evaluation was based on a 10-point scale for ease of unraveling when unraveling with chopsticks.

(レトルト米飯での評価結果)
ほぐれ評価の結果を表4に示す。本発明の加工澱粉の超音波処理物は、ほぐれ効果の評価が高かった。
(Evaluation results with retort rice)
Table 4 shows the results of the loosening evaluation. The ultrasonic treatment product of the processed starch of the present invention had a high evaluation of the loosening effect.

Figure 2013034414
Figure 2013034414

本発明により、茹でや蒸煮或いは炊飯等によって食品中の澱粉をα化させて喫食する麺類や、米飯等の食品のほぐれ性を改良する食品用ほぐれ剤、及び該食品用ほぐれ剤を用いたほぐれの良好な食品の製造方法を提供することにより、α化された麺類或いは炊飯米等の食品の製造の段階、又は流通、販売、喫食の段階でのほぐれ性を有効に改善し、食品本来の風味や食味を損なうことなく、良好なほぐれ性と高い味覚とを有するほぐれ性の良好な食品を提供することができる。また、本発明のほぐれ剤は、ほぐれ剤の調製に際して煩雑な工程を必要とすることなく、簡便、安価な方法で提供できることから、本発明は、実用性に富んだ食品用ほぐれ剤を提供することができる。
According to the present invention, noodles to be eaten by boiled, boiled, cooked rice, etc. by starching in food, a food loosening agent for improving the looseness of food such as cooked rice, and a loosening using the food loosening agent By providing a method for producing a good food, it is possible to effectively improve the looseness at the stage of production of food, such as pregelatinized noodles or cooked rice, or at the stage of distribution, sales, and eating. It is possible to provide a food with good looseness and good looseness and high taste without impairing the flavor and taste. In addition, since the loosening agent of the present invention can be provided by a simple and inexpensive method without the need for complicated steps in the preparation of the loosening agent, the present invention provides a loosening agent for foods that is highly practical. be able to.

Claims (7)

加工澱粉を超音波処理し、5質量%水溶液における粘度が100mPa・s以下とした加工澱粉超音波処理物を含有することを特徴とする食品用ほぐれ剤。   A loosening agent for foods, comprising a processed starch sonication product obtained by sonicating the processed starch and having a viscosity in a 5% by mass aqueous solution of 100 mPa · s or less. 加工澱粉が、ヒドロキシプロピル化澱粉、ヒドロキシプロピル化リン酸架橋澱粉、リン酸モノエステル化澱粉、及びリン酸モノエステル化リン酸架橋澱粉からなる群から選択される一種類以上であることを特徴とする請求項1に記載の食品用ほぐれ剤。   The modified starch is at least one selected from the group consisting of hydroxypropylated starch, hydroxypropylated phosphate cross-linked starch, phosphate monoesterified starch, and phosphate monoesterified phosphate cross-linked starch The food loosening agent according to claim 1. 加工澱粉の原料澱粉がタピオカ澱粉及び/又はワキシスターチであることを特徴とする請求項1又は2に記載の食品用ほぐれ剤。   The raw material starch of processed starch is tapioca starch and / or waxy starch, The loosening agent for foodstuffs of Claim 1 or 2 characterized by the above-mentioned. 加工澱粉超音波処理物の含量が、固形分換算で0.1〜100質量%であることを特徴とする請求項1〜3のいずれか記載の食品用ほぐれ剤。   The food loosening agent according to any one of claims 1 to 3, wherein the content of the processed starch sonication product is 0.1 to 100% by mass in terms of solid content. 請求項1〜4のいずれか1項に記載の食品用ほぐれ剤を、食品の表面に塗布するか、或いは、請求項1〜4のいずれか1項に記載の食品用ほぐれ剤を含有する溶液に食品を浸漬するかして、食品の表面に食品用ほぐれ剤をコーティングすることを特徴とするほぐれ性の良好な食品の製造方法。   The food loosening agent of any one of Claims 1-4 is apply | coated to the surface of a foodstuff, or the solution containing the food loosening agent of any one of Claims 1-4 A method for producing a food with good loosening properties, characterized by immersing the food in a surface and coating the surface of the food with a loosening agent for food. 食品が、α化麺又は米飯であることを特徴とする請求項5記載のほぐれ性の良好な食品の製造方法。   The method for producing a food with good loosening properties according to claim 5, wherein the food is pregelatinized noodles or cooked rice. 食品への加工澱粉超音波処理物の添加量が、食品の重量に対して、α化麺の場合は、固形物換算量で0.05〜3.0質量%になるように、又は、米飯の場合は、固形物換算量で0.05〜3.0質量%になるように、添加することを特徴とする請求項6記載のほぐれ性の良好な食品の製造方法。
In the case where the amount of processed starch sonicated product to food is alpha-noodles with respect to the weight of the food, it is 0.05 to 3.0% by mass in terms of solid matter or cooked rice In the case of, the method for producing a food with good loosening property according to claim 6, wherein the amount is added so as to be 0.05 to 3.0 mass% in terms of solid matter.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016067336A (en) * 2014-10-02 2016-05-09 グリコ栄養食品株式会社 Texture improving composition
JP2018085959A (en) * 2016-11-29 2018-06-07 理研ビタミン株式会社 Quality improvement agent for noodle
JP2018093819A (en) * 2016-12-15 2018-06-21 亀田製菓株式会社 New production method of dried cooked rice, and dried cooked rice
CN110770258A (en) * 2016-12-15 2020-02-07 泰特&莱尔组分美国公司 Stable waxy starches and methods of use thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06327427A (en) * 1993-05-19 1994-11-29 Matsutani Chem Ind Ltd Production of boiled noodle
JPH07135914A (en) * 1993-11-15 1995-05-30 Matsutani Chem Ind Ltd Production of food of boiled rice
JP2002065184A (en) * 2000-08-31 2002-03-05 Taiyo Kagaku Co Ltd Improver for cooked rice and method for producing cooked rice
JP2006333796A (en) * 2005-06-03 2006-12-14 Dainippon Sumitomo Pharma Co Ltd Agent for improving loosening property of grain processed food
JP2008142045A (en) * 2006-12-13 2008-06-26 Dainippon Sumitomo Pharma Co Ltd Boiled rice modifier
JP2009011313A (en) * 2007-06-05 2009-01-22 Matsutani Chem Ind Ltd Unfolding agent for gelatinized noodle

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06327427A (en) * 1993-05-19 1994-11-29 Matsutani Chem Ind Ltd Production of boiled noodle
JPH07135914A (en) * 1993-11-15 1995-05-30 Matsutani Chem Ind Ltd Production of food of boiled rice
JP2002065184A (en) * 2000-08-31 2002-03-05 Taiyo Kagaku Co Ltd Improver for cooked rice and method for producing cooked rice
JP2006333796A (en) * 2005-06-03 2006-12-14 Dainippon Sumitomo Pharma Co Ltd Agent for improving loosening property of grain processed food
JP2008142045A (en) * 2006-12-13 2008-06-26 Dainippon Sumitomo Pharma Co Ltd Boiled rice modifier
JP2009011313A (en) * 2007-06-05 2009-01-22 Matsutani Chem Ind Ltd Unfolding agent for gelatinized noodle

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JPN6015016009; 澱粉科学, 1984 31(3), p.127-133 *
JPN6015016011; 澱粉科学, 1978 25(1), p.30-47 *
JPN6015016013; Cereal Chem, 1994 71(6), 636-639 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016067336A (en) * 2014-10-02 2016-05-09 グリコ栄養食品株式会社 Texture improving composition
JP2018085959A (en) * 2016-11-29 2018-06-07 理研ビタミン株式会社 Quality improvement agent for noodle
JP2018093819A (en) * 2016-12-15 2018-06-21 亀田製菓株式会社 New production method of dried cooked rice, and dried cooked rice
CN110770258A (en) * 2016-12-15 2020-02-07 泰特&莱尔组分美国公司 Stable waxy starches and methods of use thereof
JP2020514435A (en) * 2016-12-15 2020-05-21 テイト アンド ライル イングリーディエンツ アメリカス エルエルシーTate & Lyle Ingredients Americas LLC Suppressed waxy starch and method of use thereof
US11129402B2 (en) 2016-12-15 2021-09-28 Tate & Lyle Ingredients Americas Llc Inhibited waxy starches and methods of using them
CN110770258B (en) * 2016-12-15 2023-07-07 泰特&莱尔解决方案美国公司 Stable waxy starch and method of use thereof
US11896038B2 (en) 2016-12-15 2024-02-13 Tate & Lyle Solutions Usa Llc Inhibited waxy starches and methods of using them

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