JP2013018185A - Conductive multilayer structure and touch panel including the same - Google Patents

Conductive multilayer structure and touch panel including the same Download PDF

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JP2013018185A
JP2013018185A JP2011153009A JP2011153009A JP2013018185A JP 2013018185 A JP2013018185 A JP 2013018185A JP 2011153009 A JP2011153009 A JP 2011153009A JP 2011153009 A JP2011153009 A JP 2011153009A JP 2013018185 A JP2013018185 A JP 2013018185A
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multilayer structure
conductive
touch panel
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zhao-jie Zhu
朱兆杰
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Innovation and Infinity Global Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a conductive multilayer structure and its touch panel, having a small thickness of the conductive multilayer structure and high hardness and wear resistance or the like, and having high sensitivity relative to a contact pressure applied by a user.SOLUTION: This conductive multilayer structure comprises: a substrate 10 which has facing first and second surfaces 101 and 102, into which inorganic powder is mixed, and which has a thickness of 100 to 125 μm; a transparent conductive film 11 formed on the first surface 101; a hard coat layer 12 formed on the second surface 102; and a protective film 13 formed on the hard coat layer 12. The transparent conductive film 11 is transparent conductive oxide. The transparent conductive film 11 is indium tin oxide. The transparent conductive film 11 is amorphous indium tin oxide. The thickness of the hard coat layer 12 is 6 to 10 μm. The protective film 13 is a silicon dioxide film. The touch panel includes the conductive multilayer structure.

Description

本発明は、多層構造(薄膜の多層構造とも称する)及びそれを有するタッチパネルに関し、特に、導電性多層構造(conductive multilayer structure、導電性薄膜の多層構造とも称する)及びそれを有するタッチパネルに関する。   The present invention relates to a multilayer structure (also referred to as a thin film multilayer structure) and a touch panel having the multilayer structure, and more particularly to a conductive multilayer structure (also referred to as a conductive multilayer structure) and a touch panel having the same.

近年、タッチ式のマンマシンインタフェース(例えば、タッチパネル)は、様々な電子製品(例えば、グローバル・ポジショニング・システム(GPS)、パーソナル・デジタル・アシスタント(PDA)、携帯電話(cellular phone)、タブレットコンピュータ(Table PC)など)に幅広く利用されている。携帯式電子製品において、従来の入力装置からタッチ式のマンマシンインタフェースに変更されてきている。このマンマシンインタフェースを利用すると、電子装置をユーザフレンドリー(即ち、ヒューマン的に)かつ直感的に操作することができる上、従来の入力装置による占有空間が小さくなるため、携帯式電子製品の軽量化及び薄型化を達成することができる。   In recent years, touch-type man-machine interfaces (e.g., touch panels) have been used in various electronic products (e.g., global positioning system (GPS), personal digital assistant (PDA), cellular phones, tablet computers ( Table PC)). In portable electronic products, a conventional input device has been changed to a touch-type man-machine interface. By using this man-machine interface, the electronic device can be operated in a user-friendly (ie, human-like) manner and intuitively, and the space occupied by the conventional input device is reduced, so that the weight of the portable electronic product is reduced. And thinning can be achieved.

タッチパネルは、感知方式の違いに応じて抵抗式、容量式、電磁式、赤外線式、超音波式などに分けられる。例えば、抵抗式タッチパネルでは、2つの導電薄膜を上下の電極(即ち、上電極と下電極)として用い、ユーザが圧力(即ち、タッチの力又は接触力)を加えることにより上下の電極を導通させることで、パネルの電圧変化を測定するだけで接触点の位置を算出することができる。一方、容量式タッチパネルでは、基板上に導電材料を配置することで導電基板を形成する。導電基板の四隅が放電されると、その表面に均一な電界が形成され、導電物体(例えば、ユーザの指など)が触れることにより導電物体が微量の電流を吸収し、この僅かな変化を制御装置へ送信して分析することで、導電物体が接触された位置を検出する。   The touch panel is classified into a resistance type, a capacitance type, an electromagnetic type, an infrared type, an ultrasonic type and the like according to a difference in sensing method. For example, in a resistive touch panel, two conductive thin films are used as upper and lower electrodes (ie, an upper electrode and a lower electrode), and a user applies pressure (ie, touch force or contact force) to make the upper and lower electrodes conductive. Thus, the position of the contact point can be calculated simply by measuring the voltage change of the panel. On the other hand, in a capacitive touch panel, a conductive substrate is formed by disposing a conductive material on a substrate. When the four corners of the conductive substrate are discharged, a uniform electric field is formed on the surface, and when the conductive object (for example, a user's finger) touches, the conductive object absorbs a small amount of current and controls this slight change. By transmitting to the apparatus and analyzing it, the position where the conductive object is touched is detected.

従来技術の基板に利用されていたガラス基板又はプラスチック基板は、例えば従来の基板がPET基板である場合、構造強度及び耐摩耗性を向上させるために、一定の厚さを有する必要があるため、タッチパネル構造の厚さが大きくなることにより、軽量化及び薄型化に不利になる。一方、基板は厚さが大きなPET基板である場合、タッチでタッチパネルを作動させるように、ユーザはタッチパネルにより大きな圧力を加えなければいけないため、使用に不便となる。そのため、厚さが小さく、ユーザが操作しやすいタッチパネルが求められている。   For example, when the conventional substrate is a PET substrate, the glass substrate or the plastic substrate used for the substrate of the prior art needs to have a certain thickness in order to improve the structural strength and wear resistance. The increase in the thickness of the touch panel structure is disadvantageous for weight reduction and thickness reduction. On the other hand, when the substrate is a PET substrate having a large thickness, the user must apply a large pressure to the touch panel so that the touch panel is operated by touch, which is inconvenient to use. Therefore, a touch panel having a small thickness and easy for the user to operate is desired.

特開2011−016264号公報JP 2011-016264 A

本発明の目的は、導電性多層構造の薄型化が図れる上に、硬度、耐摩耗性などが応用の仕様に応じることができ、ユーザのタッチに対する感度を向上させるように作動に必要なタッチの圧力を低減することができる導電性多層構造及びそれを有するタッチパネルを提供することにある。   The object of the present invention is to reduce the thickness of the conductive multi-layer structure and to meet the application specifications such as hardness and wear resistance, and to improve the sensitivity of the touch required by the user. An object is to provide a conductive multilayer structure capable of reducing pressure and a touch panel having the same.

上記課題を解決するために、本発明の第1の実施形態に係る導電性多層構造は、対向する第1の表面及び第2の表面を有し、無機粉末が混入され、厚さが100μm〜125μmである基板と、前記第1の表面に形成された透明導電膜と、前記第2の表面に形成された硬質被覆層(ハードコーティング層とも称する)と、前記硬質被覆層上に形成された保護膜と、を備えることを特徴とする。   In order to solve the above-described problem, the conductive multilayer structure according to the first embodiment of the present invention has a first surface and a second surface facing each other, mixed with an inorganic powder, and has a thickness of 100 μm to A substrate having a thickness of 125 μm, a transparent conductive film formed on the first surface, a hard coating layer (also referred to as a hard coating layer) formed on the second surface, and formed on the hard coating layer And a protective film.

上記課題を解決するために、本発明の第2の実施形態に係るタッチパネルは、第1の実施形態に係る導電性多層構造を含むことを特徴とする。   In order to solve the above problem, a touch panel according to a second embodiment of the present invention includes the conductive multilayer structure according to the first embodiment.

本発明に係る導電性多層構造及びそれを有するタッチパネルは、無機微粒子が添加されていることにより、厚さを小さくしても依然として良好な物理特性を有する。言い換えれば、本発明に係る導電性多層構造及びそれを有するタッチパネルは、導電性多層構造の厚さを小さくすることができるとともに、タッチパネルに応用する際に求められる耐摩耗特性、硬度に対する要求を満足させることもできる。   The conductive multilayer structure and the touch panel having the same according to the present invention still have good physical properties even when the thickness is reduced due to the addition of inorganic fine particles. In other words, the conductive multilayer structure and the touch panel having the conductive multilayer structure according to the present invention can reduce the thickness of the conductive multilayer structure and satisfy the requirements for wear resistance and hardness required when applied to a touch panel. It can also be made.

本発明の一実施形態に係る導電性多層構造を示す断面図である。It is sectional drawing which shows the electroconductive multilayer structure which concerns on one Embodiment of this invention.

本発明の特徴及び技術内容をさらに理解するため、以下本発明に係る詳細な説明及び添付図面を参照することにより、深く且つ具体的な理解を得ることするが、それらの添付図面は参考及び説明のみに使用され、本発明の範囲を狭義的に制限するものではないことは言うまでもないことである。   In order to further understand the features and technical contents of the present invention, a detailed and detailed understanding of the present invention will be obtained by referring to the following detailed description of the present invention and the accompanying drawings. It is needless to say that the scope of the present invention is not strictly limited.

本発明に係る導電性多層構造は、薄型化及び軽量化を達成し、ユーザのタッチに対する作動に必要なタッチの圧力を低減することができる。   The conductive multilayer structure according to the present invention can achieve a reduction in thickness and weight, and can reduce the pressure of the touch necessary for the user's touch operation.

図1を参照する。図1に示すように、本発明の一実施形態に係る導電性多層構造は、少なくとも基板10、透明導電膜11、硬質被覆層(hard coat layer、ハードコーティング層とも称する)12及び保護膜13を備える。   Please refer to FIG. As shown in FIG. 1, a conductive multilayer structure according to an embodiment of the present invention includes at least a substrate 10, a transparent conductive film 11, a hard coating layer (also referred to as a hard coat layer) 12, and a protective film 13. Prepare.

本実施形態に係る基板10は、透光板(transparent plate)である。この透光板10は、例えば、可撓性、軽量、耐衝撃性、耐スポール性を有するポリカーボネート(polycarbonate:PC)、ポリメチルメタクリレート(polymethylmethacrylate:PMMA)、ポリエチレンテレフタレート(polyethylene terephthalate:PET)などからなることが好ましいが、これらの材料に限定されるものではなく、例えば、ポリエステル系樹脂(polyester resin)、メンチルアセテート系樹脂、ポリエーテルスルホン(Poly Ether Sulfone、PES)系樹脂、ポリカーボネート(polycarbonate)系樹脂、ポリアミド(Polyamide、PA)系樹脂、ポリイミド(Polyimide、PI)系樹脂、ポリオレフィン(polyolefin)系樹脂、メタアクリル酸系樹脂、ポリ塩化ビニル(Polyvinyl chloride、PVC)系樹脂、ポリ塩化ビニリデン系樹脂(polyvinylidene chloride resin)、ポリスチレン(polystyrene)系樹脂、ポリビニルアルコール(polyvinyl alcohol)系樹脂、ポリアリルスルホン系樹脂、ポリフェニレンスルフィド系樹脂などからなってもよい。   The substrate 10 according to the present embodiment is a transparent plate. The translucent plate 10 is made of, for example, polycarbonate (polycarbonate: PC), polymethylmethacrylate (PMMA), polyethylene terephthalate (PET) having flexibility, light weight, impact resistance, and spall resistance. However, the present invention is not limited to these materials, and examples thereof include polyester resins, menthyl acetate resins, polyether ether sulfones (PES) resins, and polycarbonate resins. Resin, Polyamide (PA) resin, Polyimide (PI) resin, Polyolefin resin, Methacrylic acid resin, Polyvinyl chloride (PVC) resin, Polyvinylidene chloride resin (Polyvinylidene chloride resin), police Ren (POLYSTYRENE) resins, polyvinyl alcohol (polyvinyl alcohol) resins, polyallyl sulfone resins may be composed of such polyphenylene sulfide-based resin.

本実施形態に係るポリエチレンテレフタレート(PET)からなる基板10中には、無機粉末が混入されている。この無機粉末は、平均粒径が0.5μm〜20μmの二酸化ケイ素、酸化カルシウム、酸化アルミニウム、酸化チタン、酸化ジルコニウム、酸化スズ、酸化インジウム、酸化カドミウム、酸化アンチモンなどの導電性無機微粒子でもよいし、ポリメチルメタクリレート、ポリウレタンなどを含む適宜なポリマーからなる架橋又は非架橋の有機系微粒子などの物質からなってもよい。   An inorganic powder is mixed in the substrate 10 made of polyethylene terephthalate (PET) according to the present embodiment. This inorganic powder may be conductive inorganic fine particles such as silicon dioxide, calcium oxide, aluminum oxide, titanium oxide, zirconium oxide, tin oxide, indium oxide, cadmium oxide, and antimony oxide having an average particle size of 0.5 μm to 20 μm. Further, it may be made of a substance such as a crosslinked or non-crosslinked organic fine particle made of an appropriate polymer including polymethyl methacrylate and polyurethane.

本実施形態に係る導電性多層構造は、基板10に混合する無機粉末の含有率を50%以上にすることで、耐摩耗性を向上させることができる。このように無機粉末を添加することで、本実施形態に係る基板10の厚さD1を約100μm〜125μmに低減ことができる。そのため、約188μmである従来のPET膜と比較すると、本実施形態に係る導電性多層構造は、薄型化及び軽量化を達成することができる。   The conductive multilayer structure according to this embodiment can improve the wear resistance by setting the content of the inorganic powder mixed in the substrate 10 to 50% or more. Thus, by adding inorganic powder, thickness D1 of the board | substrate 10 which concerns on this embodiment can be reduced to about 100 micrometers-125 micrometers. Therefore, the conductive multilayer structure according to this embodiment can achieve a reduction in thickness and weight as compared with a conventional PET film having a thickness of about 188 μm.

本実施形態の透明導電膜11は、基板10の第1の表面101(例えば、底面)に形成される。透明導電膜11は、透明導電酸化物(Transparent Conducting Oxide:TCO)でもよい。この透明導電酸化物は、例えば、非結晶型又は結晶型のインジウムスズ酸化物(Indium Tin Oxide:ITO)、インジウム亜鉛酸化物(Indium Zinc Oxide:IZO)、酸化クロム(chrome oxide)、酸化亜鉛(ZnO)、酸化チタン(TiO)などの導電膜又は有機透明導電材料でもよいが、これらに限定されるものではない。透明導電膜11は、例えば、真空蒸着法、スパッタ法、イオンビーム蒸着法、ゾルゲル法などの工程により製造してもよい。   The transparent conductive film 11 of the present embodiment is formed on the first surface 101 (for example, the bottom surface) of the substrate 10. The transparent conductive film 11 may be a transparent conductive oxide (TCO). Examples of the transparent conductive oxide include amorphous or crystalline indium tin oxide (ITO), indium zinc oxide (IZO), chrome oxide, and zinc oxide ( A conductive film such as ZnO) or titanium oxide (TiO) or an organic transparent conductive material may be used, but is not limited thereto. The transparent conductive film 11 may be manufactured by a process such as a vacuum deposition method, a sputtering method, an ion beam deposition method, or a sol-gel method, for example.

本実施形態に係る硬質被覆層12は、第1の表面101に対向する第2の表面102(例えば、上面)上に形成されている。具体的には、硬質被覆層12は、メラミン樹脂(melamine resin)、ウレタン系樹脂、アルキド系樹脂(alkyd resin)、アクリル酸(acrylic acid)樹脂、シリコーン系樹脂などの硬化型樹脂からなり、好ましい厚さは6μm〜10μmの範囲であり、耐摩耗性、耐化学薬品性、耐UV性などの機能を有する。例えば、硬質被覆層12は、上述のPETの基板10が光線照射(特に、紫外線(UV))の影響を受けて劣化することを防ぐために用いる。   The hard coating layer 12 according to the present embodiment is formed on the second surface 102 (for example, the upper surface) facing the first surface 101. Specifically, the hard coating layer 12 is preferably made of a curable resin such as a melamine resin, a urethane resin, an alkyd resin, an acrylic acid resin, or a silicone resin. The thickness ranges from 6 μm to 10 μm and has functions such as wear resistance, chemical resistance, and UV resistance. For example, the hard coating layer 12 is used to prevent the PET substrate 10 described above from being deteriorated by the influence of light irradiation (particularly, ultraviolet (UV)).

本実施形態に係る保護膜13は硬質被覆層12上に形成される。本実施形態において、保護膜13は、真空スパッタ方法、電子ビーム蒸着法又は化学気相成長法により形成された二酸化ケイ素(SiO)フィルムであり、その厚さ約1μm〜4μmである。変形例として、保護膜13は窒化ケイ素、フォトレジストなどからなってもよい。 The protective film 13 according to the present embodiment is formed on the hard coating layer 12. In the present embodiment, the protective film 13 is a silicon dioxide (SiO 2 ) film formed by a vacuum sputtering method, an electron beam evaporation method, or a chemical vapor deposition method, and has a thickness of about 1 μm to 4 μm. As a modification, the protective film 13 may be made of silicon nitride, photoresist or the like.

上述の構造及び組成により、本発明に係る導電性多層構造は、厚さが非常に薄くなるが、厚さが薄くなることによりその特性に問題が生じることはない。例えば、実際の検証結果によれば、基板10には無機微粒子を混合した場合、導電性多層構造全体の耐摩耗性は20万回以上となり、全体の硬度が3H以上を超えることが分かった。即ち、本発明に係る導電性多層構造は、規格で求められている要求を満足させることができる。   Although the conductive multilayer structure according to the present invention is very thin due to the structure and composition described above, there is no problem in its characteristics due to the thin thickness. For example, according to the actual verification results, it was found that when inorganic fine particles were mixed in the substrate 10, the wear resistance of the entire conductive multilayer structure was 200,000 times or more, and the overall hardness exceeded 3H or more. That is, the conductive multilayer structure according to the present invention can satisfy the requirements required by the standards.

本発明に係る導電性多層構造は、タッチパネル、液晶表示装置、エレクトロルミネッセンス表示装置などの様々な表示装置に適用し、特に、タッチパネルの透明電極板に用いるのに適している。   The conductive multilayer structure according to the present invention is applied to various display devices such as a touch panel, a liquid crystal display device, and an electroluminescence display device, and is particularly suitable for use as a transparent electrode plate of a touch panel.

例えば、抵抗式タッチパネルは、スペーサを介して互いに対向して配置するように、導電性多層構造を有するタッチ側の電極板と、透明導電性フィルムを有する表示側の電極板と、を備える。また、本発明に係る導電性多層構造は、タッチ側、表示側のいずれの電極板に用いてもよい。ユーザがタッチ側の電極板にスタイラスペンなどで圧力を加えることで、タッチ側の電極板と表示側の電極板とを接触させてタッチパネルを導通(on)状態にする一方、スタイラスペンを離すと元の非導通(off)状態を戻す。   For example, a resistive touch panel includes a touch-side electrode plate having a conductive multilayer structure and a display-side electrode plate having a transparent conductive film so as to be disposed to face each other with a spacer interposed therebetween. The conductive multilayer structure according to the present invention may be used for any electrode plate on the touch side or the display side. When the user applies pressure to the touch-side electrode plate with a stylus pen or the like, the touch-side electrode plate and the display-side electrode plate are brought into contact with each other to turn on the touch panel, while the stylus pen is released. Return the original off state.

(1)本発明に係る導電性多層構造は、タッチパネルに適用する場合、膜厚全体を薄くすることができるため、ユーザが加える圧力に対する感度が高まり、軽い(小さい)接触力(touch force)だけで作動させることができる。実際に行ったテストによると、本発明に適用したタッチパネルは僅か5g〜15gの圧力でタッチパネルのタッチ制御を行うことができた。
(2)本発明に係る導電性多層構造は、少なくとも3Hの硬度を維持し、クロスハッチテスト(cross hatch test)に合格したものであるため、タッチパネルを有する様々な画像表示装置(例えば、TFT−LCD、LCD−TVなど)に応用することができる。
(1) When the conductive multilayer structure according to the present invention is applied to a touch panel, the entire film thickness can be reduced, so that the sensitivity to the pressure applied by the user is increased, and only a light (small) touch force is applied. Can be operated with. According to actual tests, the touch panel applied to the present invention was able to perform touch control of the touch panel with a pressure of only 5 to 15 g.
(2) Since the conductive multilayer structure according to the present invention maintains at least 3H hardness and passes the cross hatch test, various image display devices having a touch panel (for example, TFT- LCD, LCD-TV, etc.).

以上の説明は、単に本発明の好ましい具体的な実施例の詳細説明及び図面を例示するもので、本発明の特許請求の範囲を制限するものではなく、当該分野における通常の知識を有する者は、本発明の主旨と領域を逸脱しない範囲内で行われる各種の変更や修正などを実施でき、それらの実施内容が、本発明の特許請求の範囲に含まれるべきことは言うまでもないことである。   The above description is merely illustrative of the detailed description of the preferred specific embodiment of the present invention and the drawings, and is not intended to limit the scope of the claims of the present invention. Needless to say, various changes and modifications can be made without departing from the spirit and scope of the present invention, and the contents of those modifications should be included in the scope of the claims of the present invention.

10 基板
11 透明導電膜
12 硬質被覆層
13 保護膜
101 第1の表面
102 第2の表面
10 substrate 11 transparent conductive film 12 hard coating layer 13 protective film 101 first surface 102 second surface

Claims (10)

対向する第1の表面及び第2の表面を有し、無機粉末が混入され、厚さが100μm〜125μmである基板と、
前記第1の表面に形成された透明導電膜と、
前記第2の表面に形成された硬質被覆層と、
前記硬質被覆層上に形成された保護膜と、
を備えることを特徴とする導電性多層構造。
A substrate having opposing first and second surfaces, mixed with inorganic powder and having a thickness of 100 μm to 125 μm;
A transparent conductive film formed on the first surface;
A hard coating layer formed on the second surface;
A protective film formed on the hard coating layer;
A conductive multilayer structure comprising:
前記透明導電膜は透明導電酸化物であることを特徴とする請求項1に記載の導電性多層構造。   The conductive multilayer structure according to claim 1, wherein the transparent conductive film is a transparent conductive oxide. 前記透明導電膜はインジウムスズ酸化物であることを特徴とする請求項2に記載の導電性多層構造。   The conductive multilayer structure according to claim 2, wherein the transparent conductive film is indium tin oxide. 前記透明導電膜は非結晶型インジウムスズ酸化物であることを特徴とする請求項3に記載の導電性多層構造。   The conductive multilayer structure according to claim 3, wherein the transparent conductive film is an amorphous indium tin oxide. 前記硬質被覆層の厚さは6μm〜10μmであることを特徴とする請求項1に記載の導電性多層構造。   The conductive multilayer structure according to claim 1, wherein the hard coating layer has a thickness of 6 μm to 10 μm. 前記保護膜は二酸化ケイ素フィルムであることを特徴とする請求項1に記載の導電性多層構造。   The conductive multilayer structure according to claim 1, wherein the protective film is a silicon dioxide film. 前記保護膜の厚さは1μm〜4μmであることを特徴とする請求項6に記載の導電性多層構造。   The conductive multilayer structure according to claim 6, wherein the protective film has a thickness of 1 μm to 4 μm. 請求項1に記載の導電性多層構造を含むタッチパネル。   A touch panel comprising the conductive multilayer structure according to claim 1. 前記導電性多層構造の前記硬質被覆層の厚さは6μm〜10μmであることを特徴とする請求項8に記載のタッチパネル。   The touch panel according to claim 8, wherein a thickness of the hard coating layer of the conductive multilayer structure is 6 μm to 10 μm. 前記保護膜は厚さが1μm〜4μmである二酸化ケイ素フィルムであることを特徴とする請求項8に記載のタッチパネル。   The touch panel as set forth in claim 8, wherein the protective film is a silicon dioxide film having a thickness of 1 μm to 4 μm.
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