JP2012526813A - Bactericidal active compounds and compositions for turf treatment - Google Patents
Bactericidal active compounds and compositions for turf treatment Download PDFInfo
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- JP2012526813A JP2012526813A JP2012510815A JP2012510815A JP2012526813A JP 2012526813 A JP2012526813 A JP 2012526813A JP 2012510815 A JP2012510815 A JP 2012510815A JP 2012510815 A JP2012510815 A JP 2012510815A JP 2012526813 A JP2012526813 A JP 2012526813A
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- Prior art keywords
- active compound
- fungicide
- composition
- turfgrass
- compound combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Toxicology (AREA)
- Catching Or Destruction (AREA)
Abstract
本発明は、QoI部位においてミトコンドリア呼吸を阻害する殺菌剤(QoI阻害薬)、接触殺菌剤、脱メチル化反応阻害薬及び顔料を含んでいる、望ましくない植物病原性菌類防除するのに非常に適している新規組成物に関する。さらに、該殺菌性組成物は、イネ科植物〔特に、芝草(turf grass)〕における菌類(mold)及び菌類(fungus)による感染を防除することができる。 The present invention is very suitable for controlling unwanted phytopathogenic fungi containing fungicides (QoI inhibitors) that inhibit mitochondrial respiration at the QoI site, contact fungicides, demethylation inhibitors and pigments The new composition. Further, the bactericidal composition can control infection by fungi (mold) and fungus in grasses (particularly turf grass).
Description
本発明は、QoI部位においてミトコンドリア呼吸を阻害する殺菌剤(QoI阻害薬)、接触殺菌剤、脱メチル化反応阻害薬及び顔料を含んでいる、望ましくない植物病原性菌類防除するのに非常に適している新規組成物に関する。さらに、該殺菌性組成物は、イネ科植物〔特に、芝草(turf grass)〕における菌類(mold)及び菌類(fungus)による感染を防除することができる。 The present invention is very suitable for controlling unwanted phytopathogenic fungi containing fungicides (QoI inhibitors) that inhibit mitochondrial respiration at the QoI site, contact fungicides, demethylation inhibitors and pigments The new composition. Further, the bactericidal composition can control infection by fungi (mold) and fungus in grasses (particularly turf grass).
品質の優れた芝草種は、ゴルフコースのグリーン、フェアウェイ及びティーボックスに植えられており、さらに、芝生育成場(turf farm)や他の多くの場所で栽培されている。晩夏及び初秋には気候が温暖であって、晩秋及び初冬には積雪条件下にある、カナダや米国北部などの北部地域においては、ダラースポット〔スクレロチニア・ホメオカルパ(Sclerotinia homeocarpa)〕及び雪腐病菌類〔例えば、ミクロドキウム・ニバレ(Microdochium nivale)、チフラ・インカルナタ(Typhula incarnata)、及び、チフラ・イシカリエンシス(Typhula ishikariensis)〕などの特定の菌類(mold)が、芝草栽培者にとって慢性的な問題となっている。 High quality turfgrass species are planted in golf course greens, fairways and tee boxes, and are also cultivated in turf farms and many other places. In northern regions such as Canada and the northern United States, where the climate is warm in late summer and early autumn, and in snowy conditions in late autumn and early winter, dollar spots (Sclerotinia homeocarpa) and snow rot fungi Certain fungi (molds, such as, for example, Microdochium nivare, Typhra incarnata, and Typhula ishikariensis) are chronic problems and to turfgrass growers. ing.
芝草は、晩夏及び秋に処理されないままに放置された場合、晩夏及び秋には、スクレロチニア・ホメオカルパ(Sclerotinia homeocarpa)に起因する損傷を受けやすくなり、晩秋及び冬を通して春までは、雪腐病菌類に起因する損傷を受けやすくなる。スクレロチニア・ホメオカルパ(Sclerotinia homeocarpa)は、南部で栽培される殆どの芝草を攻撃する。ベントグラス、コモンバミューダグラス、ハイブリッドバーミューダグラス及びシバ属多年草は、スクレロチニア・ホメオカルパ(Sclerotinia homeocarpa)の攻撃に対して最も感受性が高い。ダラースポット病は、春から秋の終わりまで発生し、春、初夏及び秋の温暖な日中(約70°F〜約85°F)及び低温の夜間(約60°F)の湿度が高い期間にもっとも活性が高い。 Turfgrass, when left untreated in late summer and autumn, is susceptible to damage due to Sclerotinia homeocarpa in late summer and autumn, and through the fall and winter until spring, snow rot fungi It is more susceptible to damage caused by. Sclerotinia homeocarpa attacks most turfgrass grown in the south. Bentgrass, common Bermudagrass, hybrid Bermudagrass and perennial perennials are most susceptible to attack by Sclerotinia homeocarpa. Dollar spot disease occurs from spring to the end of autumn and is a period of high humidity during warm days (about 70 ° F. to about 85 ° F.) and cold nights (about 60 ° F.) in spring, early summer and autumn. Is the most active.
菌類の感染が広範囲に及ぶ場合、当該芝草の回復は、かなり遅れて成育期間にまで入る可能性があり、また、その芝草の回復する能力に対して著しい影響を与え得る。その結果、デッドパッチ(dead patch)の領域が残る。さらに、これらの菌類によって弱体化された又は損傷を受けた芝草は、春には回復するのが極めて遅く、そして、しばしば、クリーピングベントグラス(Agrostis palustris)及びスズメノカタビラ(Poa annua)などの望ましくない日和見雑草のイネ科植物種が侵入する。 If the fungal infection is widespread, the recovery of the turfgrass can be delayed until it reaches the growing season and can have a significant impact on the ability of the turfgrass to recover. As a result, a dead patch area remains. In addition, turfgrass weakened or damaged by these fungi is very slow to recover in the spring and are often undesired opportunistics such as creeping bentgrass (Agrostis palustris) and sparrow annua (Poa annua) Invasion of weed grass species.
雪腐病を予防するための典型的なプログラムでは、冬季の万年雪に覆われる前に菌類を阻害する殺菌剤を芝草に施用することが必要である。典型的なプログラムは、万年雪に覆われる前の3回の施用と春にその万年雪の覆いがなくなった後における追加の施用からなる。数種類の商業的な殺菌剤製品が、ダラースポット及び雪腐病菌種に対する使用に関して認可されている。 A typical program for preventing snow rot involves applying a fungicide to turfgrass that inhibits fungi before being covered with snow in winter. A typical program consists of three applications before being covered by perpetual snow and additional applications after the perpetual snow cover is removed in the spring. Several commercial disinfectant products have been approved for use against dollar spots and snow rot species.
COMPASSTM(トリフロキシストロビン;(αE)−α(メトキシイミノ)−2−[[[(E)−[1−[3−(トリフルオロメチルフェニル]エチリジン]−アミノ]オキシ]メチル]ベンゼン酢酸メチルエステル)は、芝草における斑点病、フザリウムパッチ病及びブラウンパッチ病の防除に関して認可されている芳香族ジオキシム系殺菌剤である。トリフロキシストロビンは、キノン外部阻害薬(quinone outside inhibitor)(QoI)であって、米国特許第5,238,956号に記載されている芳香族ジオキシム系殺菌剤の部類の一員である。 COMPASS ™ (Trifloxystrobin; (αE) -α (methoxyimino) -2-[[[(E)-[1- [3- (trifluoromethylphenyl] ethylidene] -amino] oxy] methyl] benzeneacetic acid Methyl ester) is an aromatic dioxime fungicide approved for the control of spot disease, fusarium patch disease and brown patch disease in turfgrass Trifloxystrobin is a quinone outside inhibitor (QoI). And a member of the class of aromatic dioxime fungicides described in US Pat. No. 5,238,956.
ROVRAL GREEN GTTM(イプロジオン;3−(3,5−ジクロロフェニル)−N−(1−メチルエチル)−2,4−ジオキソ−1−イミダゾリジンカルボキシイミド)は、250mL/100m2の薬量で紅色雪腐病(pink snow mold)を防除するための、及び、375mL/100m2の薬量で雪腐褐色小粒菌核病(gray snow mould)を防除するための、ジカルボキシイミド系殺菌剤である。イプロジオンは、米国特許第3,755,350号に記載されている3−フェニルヒダントイン化合物の部類の一員である。 ROVRAL GREEN GT ™ (Iprodione; 3- (3,5-dichlorophenyl) -N- (1-methylethyl) -2,4-dioxo-1-imidazolidinecarboximide) is red at a dose of 250 mL / 100 m 2 It is a dicarboximide fungicide for controlling snow scab (pink snow mold) and for controlling snow smoldering brown mold sclerosis (grey snow mold) at a dose of 375 mL / 100 m 2. . Iprodione is a member of the class of 3-phenylhydantoin compounds described in US Pat. No. 3,755,350.
芝草における雪腐病〔特に、雪腐褐色小粒菌核病 チフラ・インカルナタ(Typhula incarnata)、及び、チフラ・イシカリエンシス(Typhula ishikariensis)〕の蔓延を防除するイプロジオンの効力は、菌類接種源の変動する量、雪腐病接種菌がその下で増殖する積雪の変動する期間及び全国各地の毎年の変動する冬季気温に起因して、非常に変わりやすい。かくして、ある範囲の雪腐病菌類を効果的に防除するためには、比較的高い薬量及び複数回の施用が必要とされ得る。 The efficacy of iprodione to control the spread of snow rot in turfgrass (especially the snow rot brown sclerotia nuclear disease Typhula incarnata and Typhula ishikariensis) varies with the inoculum of the fungus Due to the amount, the period of snow accumulation under which the snow rot inoculum grows, and the yearly changing winter temperatures throughout the country, it is highly variable. Thus, a relatively high dosage and multiple applications may be required to effectively control a range of snow rot fungi.
フタロシアニン類は、インク用及びコーティング用の顔料や芝草塗料用の顔料など、多くの用途を有する既知顔料である。例えば、DE 2,511,077及びJP 03/221576を参照されたい。銅フタロシアニンは、芝生の品質を高めるために使用されてきたが、それは、別の特定の活性成分との組合せにおいてのみ使用されてきた。例えば、米国特許第5,599,804号には、特定のフタロシアニン類を特定の比率で亜リン酸若しくはそのアルカリ土類金属塩と組み合わせて又は亜リン酸の特定のモノエステル塩と組み合わせて施用することによって芝草における菌類と闘う方法及び芝生の品質を高める方法が記載されている。米国特許第5,643,852号には、特定のフタロシアニン類を特定の比率で(i)亜リン酸若しくはそのアルカリ土類金属塩又は亜リン酸の特定のモノエステル塩及び(ii)特定のエチレンビスジチオカルバメート系接触殺菌剤と組み合わせて施用することによって芝草における芝生の品質を高める方法が記載されている。米国特許第5,336,661号には、(i)亜リン酸の特定のモノエステル塩及び(ii)金属性エチレンビスジチオカルバメート系接触殺菌剤を特定の比率で施用することによってベントグラスを処理する方法及び芝生の品質を高める方法が記載されている。この特許には、さらにまた、アルミニウムトリス(O−エチルホスホネート)(ホセチル−Al)とマンガン−亜鉛エチレンビスジチオカルバメート錯体(マンゼブ)の組合せを含んでいて特定の形態(FORE殺菌剤)で使用される特定の組成物も記載されており、ここで、この組成物は、未知量のフタロシアニン化合物「Pigment Blue 15」を含んでいたものと考えられる。 Phthalocyanines are known pigments that have many uses, such as pigments for inks and coatings and pigments for turfgrass paints. See, for example, DE 2,511,077 and JP 03/221576. Copper phthalocyanine has been used to enhance the quality of grass, but it has been used only in combination with another specific active ingredient. For example, US Pat. No. 5,599,804 applies certain phthalocyanines in a specific ratio in combination with phosphorous acid or its alkaline earth metal salt or in combination with a specific monoester salt of phosphorous acid. A method for combating fungi in turfgrass and a method for enhancing the quality of the lawn is described. U.S. Pat. No. 5,643,852 includes specific phthalocyanines in specific ratios (i) phosphorous acid or its alkaline earth metal salts or certain monoester salts of phosphorous acid and (ii) certain A method is described for enhancing the quality of turf in turfgrass by applying it in combination with an ethylene bisdithiocarbamate contact fungicide. US Pat. No. 5,336,661 treats bentgrass by applying (i) a specific monoester salt of phosphorous acid and (ii) a metallic ethylenebisdithiocarbamate-based contact fungicide in a specific ratio. And methods for improving the quality of the lawn are described. This patent also includes a combination of aluminum tris (O-ethylphosphonate) (fosetyl-Al) and a manganese-zinc ethylenebisdithiocarbamate complex (manzeb) and is used in a specific form (FORE fungicide). Specific compositions are also described, where it is believed that the composition contained an unknown amount of the phthalocyanine compound “Pigment Blue 15”.
例えば、活性スペクトル、毒性、選択性、施用量、残留物の形成及び望ましい製造などに関して、現在の殺菌剤に対する生態学的要請及び経済学的要請は絶えず増えているので、並びに、さらに、例えば、抵抗性に関する問題も存在し得るので、少なくとも幾つかの領域において上記不利点を克服するのに役立つ新規殺菌剤を開発することが絶えず求められている。 For example, the current ecological and economic demands on fungicides regarding activity spectrum, toxicity, selectivity, application rate, residue formation and desirable manufacturing etc. are constantly increasing, and in addition, for example, Since resistance problems can also exist, there is an ongoing need to develop new fungicides that help overcome the above disadvantages in at least some areas.
本発明は、少なくとも幾つかの局面で上記目的を達成する活性化合物組合せ又は組成物を提供する。 The present invention provides active compound combinations or compositions that achieve the above objectives in at least some aspects.
驚くべきことに、本発明による活性化合物組合せ又は組成物が、個々の成分の活性の相加効果を示すのみではなく、相乗効果も示すということが分かった。従って、第1に、個々の物質の慣習的な施用量を低減させることが可能である。第2に、本発明による活性化合物組合せは、個々の化合物が、それらに関する限りもはや(充分な)活性を示さないような量で使用された場合でさえ、植物病原体に対して高い活性を示す。原理上は、これによって、第1に、活性スペクトルを拡大することが可能となり、及び、第2に、取扱い中の安全性が向上し得る。 Surprisingly, it has been found that the active compound combinations or compositions according to the invention show not only an additive effect of the activity of the individual components but also a synergistic effect. Thus, firstly, it is possible to reduce the customary application rates of the individual substances. Secondly, the active compound combinations according to the invention show high activity against phytopathogens, even when the individual compounds are used in such an amount that they no longer show (sufficient) activity as far as they are concerned. In principle, this makes it possible firstly to expand the activity spectrum and secondly to improve safety during handling.
本発明の活性化合物組合せは、相乗的な殺菌活性に加えて、例えば以下のような広い意味で同様に相乗的と呼ぶことが可能な驚くべきさらなる特性も有している:例えば植物病害の抵抗性病原体に対する、活性スペクトルの拡大;活性化合物の低減された施用量;当該個々の化合物が全く活性を示さないか又は実質的に活性を示さない施用量であっても、本発明の活性化合物組合せを用いて害虫が充分に防除されること;製剤中又は使用中(例えば、粉砕中、篩い分け中、乳化中、溶解中又は施用中など)における有利な挙動;向上した貯蔵安定性及び/又は光安定性;有利な残留物形成;改善された毒物学的又は環境毒物学的な挙動;植物の改善された特性、例えば、向上された成長、増加した収穫高、より良好に発達した根系、大きくなった葉面積、より緑色になった葉、より強くなった苗条、少なくなった必要とされる種子、低減された植物毒性、植物の防御システムの動員、植物との良好な適合性。かくして、本発明による活性化合物組合せ又は組成物を使用することは、幼植物の茎を健康に維持することに大きく貢献する。このことは、例えば、処理された穀物種子が冬季に生き残るのを増大させ、さらに、品質及び収量も保護する。さらに、本発明による活性化合物組合せは、浸透移行性の増強に寄与し得る。たとえ当該組合せの個々の化合物が充分な浸透移行特性を有していなくても、本発明による活性化合物組合せは、この浸透移行特性を有し得る。同様に、本発明による活性化合物組合せは、その殺菌作用のより高い持続性ももたらし得る。 In addition to the synergistic fungicidal activity, the active compound combinations according to the invention also have the surprising additional property which can be called synergistic in the broad sense as well, for example: resistance to plant diseases Broadening of the spectrum of activity against sexual pathogens; reduced application rates of active compounds; active compound combinations according to the invention even if the individual compounds show no activity or substantially no activity To control pests sufficiently; advantageous behavior during formulation or use (eg during grinding, sieving, emulsifying, dissolving or applying); improved storage stability and / or Light stability; advantageous residue formation; improved toxicological or environmental toxicological behavior; improved characteristics of the plant, eg improved growth, increased yield, better developed root system, Big Leaves the area, more leaves turned green, more strongly turned shoots, seeds are needed becomes small, reduced phytotoxicity, mobilization of plant defense systems, good compatibility with plants. Thus, the use of the active compound combinations or compositions according to the invention greatly contributes to maintaining the seedling stalks healthy. This, for example, increases the survival of the treated cereal seeds in winter, and also protects quality and yield. Furthermore, the active compound combinations according to the invention can contribute to the enhancement of osmotic migration. Even if the individual compounds of the combination do not have sufficient osmotic properties, the active compound combinations according to the invention can have this osmotic properties. Likewise, the active compound combinations according to the invention can also lead to a higher persistence of their bactericidal action.
(A)少なくとも1種類のフタロシアニン顔料;
並びに、
(B)
(i)少なくとも1種類のQoI阻害薬殺菌剤;及び、
(ii)接触殺菌剤と
(iii)DMI−殺菌剤からなる群から選択される少なくとも1種類の殺菌剤;
を含んでいる活性化合物組合せが同種の殺菌剤を含んでいるが当該顔料は含んでいない組成物よりも優れた菌類防除能力を示すということが見いだされた。
(A) at least one phthalocyanine pigment;
And
(B)
(I) at least one QoI inhibitor fungicide; and
(Ii) a contact fungicide and (iii) at least one fungicide selected from the group consisting of DMI-bactericides;
It has been found that active compound combinations containing a fungicide exhibit superior ability to control fungi than compositions containing the same type of fungicide but not the pigment.
QoI阻害薬 殺菌剤(i)としては、アゾキシストロビン、エネストロビン、ピコキシストロビン、ピラクロストロビン、クレソキシム−メチル、トリフロキシストロビン、ジモキシストロビン、メトミノストロビン、オリサストロビン、ファモキサドン、フルオキサストロビン、フェンアミドン、ピリベンカルブなどがあり、好ましいのは、アゾキシストロビン、ピラクロストロビン、トリフロキシストロビン及びフルオキサストロビンであり、特に好ましいのは、トリフロキシストロビンである。 QoI Inhibitors The bactericides (i) include azoxystrobin, enestrobine, picoxystrobin, pyraclostrobin, cresoxime-methyl, trifloxystrobin, dimoxystrobin, metminostrobin, oryastrostrobin, famoxadone, flu There are oxastrobin, phenamidon, pyribencarb, and the like, and azoxystrobin, pyraclostrobin, trifloxystrobin and fluoxastrobin are preferable, and trifloxystrobin is particularly preferable.
接触殺菌剤(ii)としては、PP−殺菌剤〔例えば、フルジオキシニル〕、ジカルボイミド系〔例えば、イプロジオン、クロゾリネート、プロシミドン、及び、ビンクロゾリン〕、AH−殺菌剤〔例えば、ビフェニル、クロロネブ、ジクロラン、キントゼン(PCNB)、テクナゼン(TCNB)、及び、トルクロホス−メチル〕、ジチオカーバメート系〔例えば、ファーバム、マンゼブ、マンネブ、メチラム、プロピネブ、チウラム、ジネブ、及び、ジラム〕、フタルイミド系〔例えば、キャプタン、カプタホール、及び、ホルペット〕、クロロニトリル系〔例えば、クロロタロニル〕、スルファミド系〔例えば、ジクロフルアニド、及び、トリルフルアニド〕、グアニジン系〔例えば、ドジン、グアザチン、及び、イミノクタジン〕、トリアジン系〔例えば、アニラジン〕、キノン系〔例えば、ジチアノン〕、ペンシクロン(pencyuron)、バリダマイシン、無機殺菌剤〔例えば、銅及び硫黄製品〕などがある。好ましい接触殺菌剤は、イプロジオン、フルジオキシニル及びクロロタロニルであり、特に好ましいのは、それらの作用機序がシグナル伝達に関与するイプロジオン、及び、フルジオキシニルである。 Examples of the contact bactericides (ii) include PP-bactericides (for example, fludioxinil), dicarbomides (for example, iprodione, clozolinate, procymidone, and vinclozolin), AH-bactericides (for example, biphenyl, chloroneb, dichlorane, quintozene ( PCNB), technazen (TCNB), and torquelophos-methyl], dithiocarbamate systems (eg, farbum, manzeb, manneb, methylam, propineb, thiuram, dineb, and diram), phthalimide systems (eg, captan, captahol, and , Phorpet], chloronitriles (for example, chlorothalonil), sulfamides (for example, dichlorofluanid and tolylfluanid), guanidines (for example, dodine, guazatine, and iminotadine), Triazine-based [e.g., Anirajin], quinone [for example, dithianon], pencycuron (pencyuron), validamycin, inorganic fungicides [e.g., copper and sulfur products] and the like. Preferred contact bactericides are iprodione, fludioxinyl and chlorothalonil, particularly preferred are iprodione and fludioxinil whose mechanism of action is involved in signal transduction.
DMI−殺菌剤(脱メチル化反応阻害薬)としては、トリアゾール系、例えば、アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、ジニコナゾール−M、エポキシコナゾール、エタコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホール、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメホン、トリアジメノール及びトリチコナゾールなどがあり、好ましいのは、プロチオコナゾール、テブコナゾール、プロピコナゾール及びトリチコナゾールであり、特に好ましいのは、プロピコナゾール及びトリチコナゾールである。 DMI-bactericides (demethylation inhibitors) include triazoles such as azaconazole, viteltanol, bromconazole, cyproconazole, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, etaconazole, fenbuconazole, Fluquinconazole, flusilazole, flutriazole, hexaconazole, imibenconazole, ipconazole, metconazole, microbutanyl, penconazole, propiconazole, prothioconazole, cimeconazole, tebuconazole, tetraconazole, triadimethone, triadimenol and tritico And preferred are prothioconazole, tebuconazole, propiconazole and triticonazole, particularly preferred Is a propiconazole and triticonazole.
好ましくは、本発明による組成物は、化合物(B)として、(i)トリフロキシストロビン(QoI阻害薬 殺菌剤として)、(ii)イプロジオン(接触殺菌剤として)及び(iii)トリチコナゾール(DMI−殺菌剤として)を含んでいる。最も好ましくは、本発明による組成物は、(i)トリフロキシストロビン(QoI阻害薬 殺菌剤として)及び(ii)イプロジオン(接触殺菌剤として)を含んでいる。 Preferably, the composition according to the invention comprises as compound (B): (i) trifloxystrobin (as a QoI inhibitor fungicide), (ii) iprodione (as a contact fungicide) and (iii) triticonazole ( DMI-as a disinfectant). Most preferably, the composition according to the invention comprises (i) trifloxystrobin (as a QoI inhibitor fungicide) and (ii) iprodione (as a contact fungicide).
適切な顔料(A)としては、フタロシアニン類などがある。 Suitable pigments (A) include phthalocyanines.
適切なフタロシアニン類は、各イソインドール基が独立して1〜4回置換され得る置換銅フタロシアニン類である。銅フタロシアニン染料のイソインドール基に対して適している置換基の例としては、限定するものではないが、ハロゲン、置換されているか又は置換されていない低級アルキル、低級アルコキシ、アルキルアミノ、アルキルチオ、アンモニウム、スルホナト、スルホナトアルキル、スルフェート、ホスフェート、ホスホネート及びカルボキシレートなどを挙げることができる。イオン性置換基又はイオン化可能な置換基は、対イオンとして、アルカリ金属(好ましくは、リチウム、ナトリウム、又は、カリウム)、アルカリ土類金属(好ましくは、ベリリウム、マグネシウム、カルシウム、ストロンチウム、及び、バリウム)及び種々のアンモニウムイオンを有することができる。用語「低級アルキル」及び「低級アルコキシ」は、一般に、1〜6個の炭素原子からなるアルキル基及び1〜6個の炭素原子からなるアルコキシ基を意味する。 Suitable phthalocyanines are substituted copper phthalocyanines in which each isoindole group can be independently substituted 1 to 4 times. Examples of suitable substituents for the isoindole group of a copper phthalocyanine dye include, but are not limited to, halogen, substituted or unsubstituted lower alkyl, lower alkoxy, alkylamino, alkylthio, ammonium Sulphonate, sulphonatoalkyl, sulphate, phosphate, phosphonate and carboxylate. Ionic substituents or ionizable substituents can be used as counter ions with alkali metals (preferably lithium, sodium or potassium), alkaline earth metals (preferably beryllium, magnesium, calcium, strontium and barium). ) And various ammonium ions. The terms “lower alkyl” and “lower alkoxy” generally mean an alkyl group consisting of 1 to 6 carbon atoms and an alkoxy group consisting of 1 to 6 carbon atoms.
適切な銅フタロシアニン類は、市販されている。そのような適切な銅フタロシアニン類としては、限定するものではないが、「Pigment Blue 16」、「Vat Blue 29」、「Pigment Blue 15」、「Heliogen Green GG」、「Ingrain Blue 14」、「Ingrain Blue 5」、「Ingrain Blue 1」、「Pigment Green 37」及び「Pigment Green 7」などを挙げることができる。好ましい一実施形態では、該銅フタロシアニンは、「Pigment Blue 15」(これは、フタロシアニンブルーとしても知られている)及び「Green pigment」(Green 7)である。 Suitable copper phthalocyanines are commercially available. Such suitable copper phthalocyanines include, but are not limited to, “Pigment Blue 16,” “Vat Blue 29,” “Pigment Blue 15,” “Helogen Green GG,” “Ingrain Blue 14,” “Ingrain.” Blue 5 ”,“ Ingrain Blue 1 ”,“ Pigment Green 37 ”,“ Pigment Green 7 ”, and the like. In one preferred embodiment, the copper phthalocyanine is “Pigment Blue 15” (also known as phthalocyanine blue) and “Green pigment” (Green 7).
好ましくは、本発明による組成物は、成分(A)として、「Green pigment」(Green 7)を含んでいる。 Preferably, the composition according to the invention comprises “Green pigment” (Green 7) as component (A).
本発明によれば、用語「活性化合物組合せ」は、上記で示されている活性化合物の可能なさまざまな組合せ、例えば、レディーミックス、タンクミックス(これは、施用に先立って個々の活性化合物の製剤から、混合及び希釈によって調製される噴霧用混合物を意味するものと理解される)又はそれらの組合せ(例えば、上記で記載されている活性化合物のうちの2種類からなる2成分レディーミックスを別個の第3の物質の製剤を用いてタンクミックスに変換する)。本発明によれば、個々の活性化合物は、数時間又は数日という適切に期間内に、連続的に(即ち、順次に)使用してもよく、また、種子処理の場合には、例えば、異なった活性化合物を含んでいる複数の層を塗布することによっても使用することができる。好ましくは、当該個々の活性化合物を使用し得る順番は、重要ではない。 According to the present invention, the term “active compound combination” refers to the various possible combinations of the active compounds indicated above, eg ready mixes, tank mixes (this is the formulation of individual active compounds prior to application). Are understood to mean spray mixtures prepared by mixing and dilution) or combinations thereof (eg two component ready mixes of two of the active compounds described above are separated Convert to tank mix using third substance formulation). According to the invention, the individual active compounds may be used continuously (ie sequentially) within a suitable period of hours or days, and in the case of seed treatment, for example, It can also be used by applying a plurality of layers containing different active compounds. Preferably, the order in which the individual active compounds can be used is not critical.
本発明は、さらに、本発明による活性化合物組合せを含んでいる組成物にも関する。好ましくは、該組成物は、農業上適切な担体又は増量剤を含んでいる殺菌剤組成物である。 The invention further relates to a composition comprising an active compound combination according to the invention. Preferably, the composition is a fungicide composition comprising an agriculturally suitable carrier or bulking agent.
本発明によれば、担体は、特に植物又は植物の部分又は種子への施用に関して、適用性を良好にするために、当該活性化合物と混合されるか又は組み合わされる天然又は合成の有機物質又は無機物質を意味するものと理解される。このような担体は、固体又は液体であり得るが、一般に、不活性であり、そして、農業において使用するのに適しているべきである。 According to the invention, the carrier can be a natural or synthetic organic or inorganic substance mixed or combined with the active compound in order to improve its applicability, in particular with regard to application to plants or plant parts or seeds. It is understood to mean a substance. Such carriers can be solid or liquid, but are generally inert and should be suitable for use in agriculture.
適切な固体担体は、以下のものである:例えば、アンモニウム塩、及び、粉砕された天然鉱物、例えば、カオリン、クレー、タルク、チョーク、石英、アタパルジャイト、モンモリロナイト又はケイ藻土、及び、粉砕された合成鉱物、例えば、微粉砕シリカ、アルミナ、及び、天然シリケート又は合成シリケート、樹脂、蝋、固形肥料、水、アルコール(特に、ブタノール)、有機溶媒、鉱油及び植物油、並びに、さらに、それらの誘導体。上記担体の混合物を使用することも可能である。粒剤に適している固体担体は、以下のものである:例えば、粉砕して分別した天然鉱物、例えば、方解石、大理石、軽石、海泡石及び苦灰岩、並びに、さらに、無機及び有機の粗挽き粉からなる合成顆粒、並びに、さらに、有機材料、例えば、おがくず、ココナッツ殻、トウモロコシ穂軸及びタバコの葉柄などからなる顆粒。適切な乳化剤及び/又は泡形成剤は、以下のものである:例えば、非イオン性及びアニオン性の乳化剤、例えば、ポリオキシエチレン脂肪酸エステル類、ポリオキシエチレン脂肪アルコールエーテル類、例えば、アルキルアリールポリグリコールエーテル類、アルキルスルホネート類、アルキルスルフェート類、アリールスルホネート類、及び、さらに、タンパク質加水分解物。適切な分散剤は、以下のものである:例えば、リグノスルファイト廃液及びメチルセルロース。 Suitable solid carriers are, for example, ammonium salts and ground natural minerals such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground Synthetic minerals such as finely divided silica, alumina, and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohols (particularly butanol), organic solvents, mineral and vegetable oils, and also derivatives thereof. It is also possible to use mixtures of the above carriers. Suitable solid carriers for granules are: for example, pulverized and separated natural minerals such as calcite, marble, pumice, ganolite and dolomite, and also inorganic and organic Synthetic granules made of coarsely ground flour, and granules made of organic materials such as sawdust, coconut shell, corn cobs and tobacco petiole. Suitable emulsifiers and / or foam formers are, for example, nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers such as alkylaryl poly Glycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, and further protein hydrolysates. Suitable dispersants are: for example lignosulfite waste liquor and methylcellulose.
適切な液化ガス増量剤又は担体は、周囲温度及び大気圧下では気体である液体、例えば、エーロゾル噴射剤、例えば、ブタン、プロパン、窒素及び二酸化炭素などである。 Suitable liquefied gas extenders or carriers are liquids that are gaseous at ambient temperature and atmospheric pressure, such as aerosol propellants such as butane, propane, nitrogen and carbon dioxide.
上記製剤において、粘着付与剤、例えば、カルボキシメチルセルロース、並びに、粉末及び顆粒及びラテックスの形態にある天然ポリマー及び合成ポリマー、例えば、アラビアゴム、ポリビニルアルコール及びポリ酢酸ビニル、又は、天然のリン脂質、例えば、セファリン及びレシチン、及び、合成リン脂質などを使用することができる。可能な別の添加剤は、鉱油及び植物油である。 In the above formulations, tackifiers such as carboxymethylcellulose, and natural and synthetic polymers in the form of powders and granules and latex such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or natural phospholipids such as Sephaline and lecithin, synthetic phospholipids, and the like can be used. Another possible additive is mineral oil and vegetable oil.
使用する増量剤が水である場合、例えば有機溶媒を補助溶媒として使用することもできる。適する液体溶媒は、本質的に以下のものである:芳香族化合物、例えば、キシレン、トルエン又はアルキルナフタレン類、塩素化芳香族化合物又は塩素化脂肪族炭化水素、例えば、クロロベンゼン類、クロロエチレン類又は塩化メチレン、脂肪族炭化水素、例えば、シクロヘキサン又はパラフィン類、例えば、鉱油留分、鉱油及び植物油、アルコール類、例えば、ブタノール又はグリコールとそれらのエーテル及びエステル、ケトン類、例えば、アセトン、メチルエチルケトン、メチルイソブチルケトン又はシクロヘキサノン、強極性溶媒、例えば、ジメチルホルムアミド及びジメチルスルホキシド、並びに、さらに、水。 When the extender used is water, for example, an organic solvent can be used as an auxiliary solvent. Suitable liquid solvents are essentially the following: aromatic compounds such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or Methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins such as mineral oil fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl Isobutyl ketone or cyclohexanone, strong polar solvents such as dimethylformamide and dimethyl sulfoxide, and also water.
本発明の組成物には、例えば界面活性剤などの、さらなる成分も付加的に含有させることができる。適切な界面活性剤は、イオン特性若しくは非イオン特性を有する乳化剤、分散剤又は湿潤剤であるか、又は、そのような界面活性剤の混合物である。これらのものの例は、ポリアクリル酸の塩、リグノスルホン酸の塩、フェノールスルホン酸若しくはナフタレンスルホン酸の塩、エチレンオキシドと脂肪アルコールの重縮合物若しくはエチレンオキシドと脂肪酸の重縮合物若しくはエチレンオキシドと脂肪アミンの重縮合物、置換されているフェノール(好ましくは、アルキルフェノール又はアリールフェノール)、スルホコハク酸エステルの塩、タウリン誘導体(好ましくは、アルキルタウレート)、ポリエトキシル化アルコールのリン酸エステル若しくはポリエトキシル化フェノールのリン酸エステル、ポリオールの脂肪酸エステル、並びに、硫酸アニオン、スルホン酸アニオン及びリン酸アニオンを含んでいる該化合物の誘導体である。該活性化合物のうちの1種類及び/又は該不活性担体のうちの1種類が水不溶性であり及び施用が水で行われる場合は、界面活性剤を存在させることが必要である。界面活性剤の割合は、本発明組成物の5重量%〜40重量%である。 The composition according to the invention can additionally contain further components, for example surfactants. Suitable surfactants are emulsifiers, dispersants or wetting agents having ionic or non-ionic properties, or mixtures of such surfactants. Examples of these are polyacrylic acid salts, lignosulfonic acid salts, phenolsulfonic acid or naphthalenesulfonic acid salts, ethylene oxide and fatty alcohol polycondensates or ethylene oxide and fatty acid polycondensates or ethylene oxide and fatty amines. Polycondensates, substituted phenols (preferably alkylphenols or arylphenols), salts of sulfosuccinates, taurine derivatives (preferably alkyltaurates), phosphates of polyethoxylated alcohols or of polyethoxylated phenols Derivatives of the compounds containing phosphate esters, fatty acid esters of polyols, and sulfate, sulfonate and phosphate anions. If one of the active compounds and / or one of the inert carriers is water insoluble and the application is carried out in water, it is necessary to have a surfactant present. The proportion of the surfactant is 5% to 40% by weight of the composition of the present invention.
着色剤、例えば、無機顔料、例えば、酸化鉄、酸化チタン及びプルシアンブルー(Prussian blue)、並びに、有機染料、例えば、アリザリン染料、アゾ染料及び金属フタロシアニン染料、並びに、微量栄養素、例えば、鉄塩、マンガン塩、ホウ素塩、銅塩、コバルト塩、モリブデン塩及び亜鉛塩などを使用することができる。 Colorants such as inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and micronutrients such as iron salts, Manganese, boron, copper, cobalt, molybdenum, zinc, and the like can be used.
適切な場合には、付加的な別の成分、例えば、保護コロイド、結合剤、粘着剤、増粘剤、揺変物質、浸透剤、安定化剤、金属イオン封鎖剤、錯体形成物質なども存在させることができる。一般的に、該活性化合物は、製剤目的で慣習的に使用される固体又は液体の任意の添加剤と組み合わせることが可能である。 Where appropriate, additional additional components are also present, such as protective colloids, binders, adhesives, thickeners, thixotropic substances, penetrants, stabilizers, sequestering agents, complexing substances, etc. Can be made. In general, the active compounds can be combined with any solid or liquid additive conventionally used for pharmaceutical purposes.
一般に、本発明による組成物は、0.05〜99重量%、好ましくは、5〜60重量%、特に好ましくは、10〜40重量%、極めて特に好ましくは、20〜30重量%の本発明による活性化合物組合せを含有する。 In general, the composition according to the invention is 0.05 to 99% by weight, preferably 5 to 60% by weight, particularly preferably 10 to 40% by weight, very particularly preferably 20 to 30% by weight. Contains active compound combination.
別の態様によれば、本発明による組成物は、2〜10重量%、好ましくは、4〜9重量%、特に好ましくは、5〜7重量%の化合物(A)、1〜3.3重量%、好ましくは、1.0〜2.5重量%、特に好ましくは、1.2〜2.0重量%の化合物(Bi)、並びに、20〜50重量%、好ましくは、20〜40重量%、特に好ましくは、20〜30重量%の化合物(Bii)及び/又は化合物(Biii)を含有する(ここで、これら化合物の合計は100重量%になる)。 According to another aspect, the composition according to the invention comprises 2 to 10% by weight, preferably 4 to 9% by weight, particularly preferably 5 to 7% by weight of compound (A), 1 to 3.3% by weight. %, Preferably 1.0-2.5% by weight, particularly preferably 1.2-2.0% by weight of compound (Bi), and 20-50% by weight, preferably 20-40% by weight Particularly preferably, it contains 20 to 30% by weight of compound (Bii) and / or compound (Biii) (wherein the sum of these compounds is 100% by weight).
本発明による殺菌剤組成物は、植物病原性菌類を治療的に又は保護的に防除するために使用することができる。本発明による組成物は、健康な芝生又は病気にかかっている芝生に施用することができる。健康な芝生への予防的な施用は、芝生の病害の防除において有用であり得る。1以上の芝生病害を含んでいる芝生への施用は、当該1以上の芝生病害の治療において有用である。本発明によって治療することが可能な菌類病の数種類の病原体について例として挙げることができるが、限定するものではない:
春季、夏期及び秋期の病害:ダラースポット〔ランジア属種(Lanzia.spp.)、及び、モエレロディスクス属種(Moelleiodiscus spp.)〕、ブラウンパッチ〔リゾクトニア・ソラニイ(Rhizoctonia solalii)〕、ラージパッチ〔リゾクトニア・ソラニ(Rhizoctonia solani)〕、ラピッドブライト、さび病〔プッシニア属種(Puccinia spp.)〕、フザリウムブライト〔フザリウム属種(Fusarium spp.)〕、ピンクパッチ、カーブラリア〔クルブラリア属種(Curvularia sp.)〕、及び、壊疽輪紋病〔レプトスファエリア・コラエ(Leptosphaeria korrae)〕、葉枯病、例えば、ドレクスレラ属種(Drechslera spp.)病原菌に起因するヘルミントスポリウム葉枯病、コルチクム(Corticum)赤葉腐病〔ラエチサリア・フシホルミス(Laetisaria fuciformis)〕、及び、炭疽病〔コレトトリクム(Colletotrichum)〕;
冬季の病害:フザリウムパッチ(紅色雪腐病〔ミクロドキウム・ニバリス(Microdochium nivalis)〕)、及び、雪腐褐色小粒菌核病〔チフラ属種(Typhula spp.)〕、紅色雪腐病〔フザリウム・ニバレ(Fusarium nivale)〕。
The fungicidal composition according to the present invention can be used to control phytopathogenic fungi therapeutically or protectively. The composition according to the invention can be applied to healthy or diseased lawns. Prophylactic application to a healthy lawn can be useful in controlling lawn diseases. Application to a lawn containing one or more lawn diseases is useful in the treatment of the one or more lawn diseases. Some examples of several pathogens of fungal diseases that can be treated according to the present invention may be mentioned, but are not limited to:
Diseases in spring, summer and autumn: dollar spots (Landia spp. And Moelleiodiscus spp.), Brown patches (Rhizoctonia solalii), large patches [Rhizoctonia solani], rapid bright, rust disease [Puccinia spp.], Fusarium bright [Fusarium spp.], Pink patch, curvularia [Curbular sp. )], And gangrene ring disease (Leptosphaeria korae), leaf blight, such as Drechella species (Drech) sella spp.) pathogens of Helmintosporium leaf blight, Corticum red leaf rot [Laetisaria fuciformis], and anthracnose (Colletotrichum);
Diseases in winter: Fusarium patch (red snow rot (Microdochium nivalis)) and snow rot brown granule nuclei (Typhula spp.), Red snow rot (Fusarium nibale) (Fusarium nivale)].
記載されている該組成物は、春に積雪から解放された後における芝生の品質を改善させるのにも有用である。 The described composition is also useful for improving the quality of the lawn after being released from snow in the spring.
本発明による殺菌剤組成物は、ゴルフコース、芝農園(sod farm)及び高品質の芝生が栽培されている施設の区域における芝草の病害を防除するために使用することができる。 The fungicide composition according to the present invention can be used to control turfgrass diseases in areas of golf courses, sod farms and facilities where high quality lawns are grown.
本発明による活性化合物組合せ又は組成物は、そのままで使用することが可能であるか、又は、それらのそれぞれの物理的及び/若しくは化学的特性に応じて、以下のようなそれらの製剤の形態若しくはその製剤から調製される使用形態で使用することが可能である:エーロゾル、カプセル懸濁液剤、冷煙霧濃厚剤(cold−fogging concentrate)、温煙霧濃厚剤(warm−fogging concentrate)、カプセル化粒剤、細粒剤、種子処理用フロアブル剤、即時使用可能な溶液剤(ready−to−use solution)、散粉性粉剤、乳剤、水中油型エマルション剤、油中水型エマルション剤、大型粒剤、微粒剤、油分散性粉剤、油混和性フロアブル剤、油混和性液剤、泡剤(foam)、ペースト剤、農薬粉衣種子、懸濁製剤(suspension concentrate)、サスポエマルション製剤、可溶性濃厚剤(soluble concentrate)、懸濁液剤(suspension)、水和剤(wettable powder)、可溶性粉剤(soluble powder)、粉剤及び粒剤、水溶性顆粒剤及び錠剤、種子処理用水溶性粉剤、水和剤(wettable powder)、活性化合物が含浸されている天然生成物及び合成物質、並びに、さらに、ポリマー物質中にマイクロカプセル化したもの及び種子用のコーティング物質中にマイクロカプセル化したもの、並びに、さらに、ULV冷煙霧製剤(ULV cold−fogging formulation)及びULV温煙霧製剤(ULV warm−fogging formulation)。 The active compound combinations or compositions according to the invention can be used as such or, depending on their respective physical and / or chemical properties, in the form of their formulations or It can be used in use forms prepared from the formulation: aerosols, capsule suspensions, cold-fogging concentrates, warm-fogging concentrates, encapsulated granules , Fine granules, seedable flowables, ready-to-use solutions, dustable powders, emulsions, oil-in-water emulsions, water-in-oil emulsions, large granules, fine granules Agent, oil-dispersible powder, oil-miscible flowable agent, oil-miscible liquid agent, foam Paste, agrochemical seeds, suspension concentrate, suspension emulsion, soluble concentrate, suspension, wettable powder, soluble powder , Powders and granules, water-soluble granules and tablets, water-soluble powders for seed treatment, wettable powders, natural products and synthetic materials impregnated with active compounds, and further in the polymer materials Encapsulated and microencapsulated in seed coating materials, as well as ULV cold-fogging formulations and ULV hot fumes (UL) V warm-fogging formulation).
上記製剤は、自体公知の方法で、例えば、当該活性化合物又は当該活性化合物組合せを少なくとも1種類の溶媒又は希釈剤、乳化剤、分散剤及び/又は結合剤又は固着剤、撥水剤、適切な乾燥剤並びに紫外線安定剤、並びに、適切な場合には、染料及び顔料、並びに、さらに、さらなる加工助剤と混合させることによって、調製することができる。 The preparation is prepared in a manner known per se, for example, the active compound or the active compound combination with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixing agent, water repellent, suitable drying. And UV stabilizers, and, where appropriate, dyes and pigments, and can be prepared by further mixing with further processing aids.
上記活性化合物組合せ又は組成物を用いた植物及び植物の部分の本発明による処理は、慣習的な処理方法を用いて、例えば、浸漬、散布、噴霧、灌漑、気化、散粉、煙霧、ばらまき、泡状化、塗布、拡散(spreading−on)、灌水(灌注(drenching))、点滴潅漑などによって、直接的に行うか、又は、該活性化合物組合せ又は該組成物を植物及び植物の部分の周囲、生息環境若しくは貯蔵空間に作用させることにより行い、また、繁殖器官(propagation material)の場合、特に種子の場合は、さらに、乾燥種子処理用粉末、種子処理用溶液、スラリー処理用水溶性粉末として、被覆することによって、1層以上のコーティングを施すことなどによっても行う。 The treatment according to the invention of plants and plant parts with the active compound combinations or compositions described above is carried out using customary treatment methods, for example immersion, spraying, spraying, irrigation, vaporization, dusting, fumes, scattering, foaming. Directly, by shaping, spreading, spreading-on, irrigation (drenching), drip irrigation, etc., or the active compound combination or the composition around plants and plant parts, In the case of propagation material, especially in the case of seeds, it is further coated as dry seed treatment powder, seed treatment solution, slurry treatment water-soluble powder. This is also done by applying one or more layers of coating.
本発明による組成物には、適切な装置を用いて植物又は種子に対して施用可能な即時使用可能な(ready−to−use)組成物のみではなく、使用前に水で希釈することが必要な商業的な濃厚物も包含される。 The composition according to the invention needs to be diluted with water before use, as well as ready-to-use compositions that can be applied to plants or seeds using suitable equipment. Commercial commercial concentrates are also included.
本発明による活性化合物組合せは、商業用製剤の中に、及び、そのような製剤から調製された使用形態の中に、殺虫剤、誘引剤、不妊剤、殺細菌剤、殺ダニ剤、殺線虫剤、殺菌剤、成長調節剤又は除草剤などの別の活性化合物との混合物として存在することができる。 The active compound combinations according to the invention can be used in commercial formulations and in use forms prepared from such formulations in insecticides, attractants, fertility agents, bactericides, acaricides, nematicides. It can be present as a mixture with another active compound such as an insecticide, fungicide, growth regulator or herbicide.
本発明は、寒地型芝草と暖地型芝草を包含する全ての芝草で実施可能である。寒地型芝草の例は、以下のものである:イチゴツナギ類(イチゴツナギ属種(Poa spp.))、例えば、ナガハグサ(Poa pratensis L)、オオスズメノカタビラ(Poa trivialis L.)、コイチゴツナギ(Poa compressa L.)、スズメノカタビラ(Poa annua L.)、アップランドブルーグラス(upland bluegrass)(Poa glaucantha Gaudin)、ウッドブルーグラス(wood bluegrass)(Poa nemoralis L.)、及び、ムカゴイチゴツナギ(bulbous bluegrass)(Poa bulbosa L.);ベントグラス類及びコヌカグサ(コヌカグサ属種(Agrostis spp.))、例えば、クリーピングベントグラス(Agrostis palustris Huds.)、イトコヌカグサ(Agrostis tenuis Sibth.)、ベルベットベントグラス(Agrostis canina L.)、サウスジャーマンミックスドベントグラス(South German Mixed Bentgrass)(コヌカグサ属種(Agrostis spp.)〔これは、イトコヌカグサ(Agrostis tenuis Sibth.)、ベルベットベントグラス(Agrostis canina L.)及びクリーピングベントグラス(Agrostis palustris Huds.)を含んでいる〕、及び、コヌカグサ(Agrostis alba L.);ウシノケグサ類(fescues)(フェスツク属種(Festucu spp.))、例えば、レッドフェスク(red fescue)(Festuca rubra L. spp. rubra)、クリーピングフェスク(creeping fescue)(Festuca rubra L.)、チューイングスフェスク(chewings fescue)(Festuca rubra commutata Gaud.)、シープフェスク(sheep fescue)(Festuca ovina L.)、ハードフェスク(hard fescue)(Festuca longifolia Thuill.)、ヘアフェスク(hair fescue)(Festucu capillata Lam.)、オニウシノケグサ(Festuca arundinacea Schreb.)、及び、メドウフェスク(meadow fescue)(Festuca elanor L.);ライグラス類(ドクムギ属種(Lolium spp.))、例えば、1年生ライグラス(annual ryegrass)(Lolium multiflorum Lam.)、ホソムギ(Lolium perenne L.)、及び、ネズミムギ(Lolium multiflorum Lam.);並びに、カモジグサ類(カモジグサ属種(Agropyron spp.))、例えば、フェアウェイウィートグラス(fairway wheatgrass)(Agropyron cristatum(L.)Gaertn.)、ニセコムギダマシ(crested wheatgrass)(Agropyron desertorum(Fisch.)Schult.)、及び、ウェスタンウィートグラス(western wheatgrass)(Agropyron smithii Rydb.)。他の寒地型芝草としては、以下のものを挙げることが出来る:オオハマガヤ(beachgrass)(Ammophila breviligulata Fern.)、コスズメノチャヒキ(Bromus inermis Leyss.)、ガマ類、例えば、オオアワガエリ(Phleum pratense L.)、サンドカットテイル(sand cattail)(Phleum subulatum L.)、カモガヤ(Dactylis glomerata L.)、アレチタチドジョウツナギ(weeping alkaligrass)(Puccinellia distans(L.)Parl.)、及び、クシガヤ(crested dog’s−tail)(Cynosurus cristatus L.)。 The present invention can be implemented in all turfgrasses including cold region turfgrass and warmland turfgrass. Examples of coldland turfgrass are the following: strawberry jumpweed (Poa spp.), For example, Poa privacyis L, Poa tribalis L., Kostrawberry jumper (Poa) Compressa L.), Poa annua L., upland bluegrass (Poa glaucantha Gaudin), wood bluegrass (wood lou sul, Poa nemoraris b. (Poa bulbosa L.); bentgrass and konukagusa (Agrostis spp.), For example Creeping bentgrass (Agrostis palistris Huds.), Agrotis tenuis Sibth., Velvet bentgrass (Agrostis canina L.), South German mixed bentgrass (South German Mixed genus sp.) Includes Agrostis tenuis Sibth, velvet bentgrass (Agrostis canina L.) and creeping ventgrass (Agrostis palustris Huds.), And Agrostis alba es f. (Fests Species such as red fescue (Festuka rubra L. spp. Rubra), creeping fescue (Festuka rubra L.), chews fescue Festuka rubra commutata Gaud., Sheep fescue (Festuka ovina L.), hard fescue (Hestuka longifolia Tuhill. ), Hair fescue (Festuca capilata Lam.), Streptomyces (Festuca arundinacea Schreb.), And Meadow fescue (L). Annual ryegrass (Lolium multiflorum Lam.), Barley (Lolium perenne L.), and barley (Lolium multiflorum Lam.); And the genus sp. Fairway wheatgrass (fairway wheatgr ss) (Agropyron cristatum (L.) Gaertn.), Niseko wheat damascene (crested wheatgrass) (Agropyron desertorum (Fisch.) Schult.), and, Western Wheatgrass (western wheatgrass) (Agropyron smithii Rydb.). Other cold turfgrass can include the following: beechgrass (Ammophila breviligula Fern.), Bromus inermis Leys., Catfish, for example, Phaeum L. .), Sand cattail (Phlum subbulatum L.), camo gay (Dactylis glomerata L.), wetting alkaligras (edc.), Puccinella dia. dog's-tail) (Cynosurus critus L.).
暖地型芝草の例としては、以下のものを挙げることが出来る:ギョウギシバ(Cynodon spp. L. C. Rich)、シバ(Zoysia spp. Willd.)、イヌシバ(St. Augustinegrass)(Stenotaphrum secundatum Walt Kuntze)、チャボウシノシッペイ(Eremochloa ophiuroides Munro Hack.)、ホソバツルメヒシバ(Axonopus affinis Chase)、アメリカスズメノヒエ(Paspalum notatum Flugge)、キクユグラス(Pennisetum clandestinum Hochst. ex Chiov.)、ヤギュウシバ(Buchloe dactyloids(Nutt.)Engelm.)、メダカスゲ(Blue gramma)(Bouteloua gracilis(H.B.K.)Lag. ex Griffiths)、サワスズメノヒエ(Paspalum vaginatum Swartz)、及び、アゼガヤモドキ(sideoats grama)(Bouteloua curtipendula(Michx. Torr.)。寒地型芝草が、一般に、本発明によって処理するのが好ましい。イチゴツナギ、ベントグラス及びコヌカグサ、フェスク並びにライグラスがさらに好ましい。ベントグラスが最も好ましい。 Examples of warm turfgrass include the following: Cynodon spp. LC Rich, Zoysia spp. Wildd., St. Augustine sundum sundum , Eremochloa opiurooids Munro Hack., Axonopus affinis Chase, Paplum notium Flag. t.) Engelm.), Blue gramma (Boueloua gracilis (H. B. K.), Lag. Torr.) Cold field turfgrass is generally preferably treated according to the present invention, strawberry jumpweed, bentgrass and euglena, fescue and ryegrass are more preferred, with bentgrass being most preferred.
本発明による活性化合物組合せの施用量は、葉を処理する場合、以下のとおりである:100〜10000g/ha、好ましくは、1000〜5500g/ha、特に好ましくは、1000〜3500g/ha(当該施用が、灌水又は滴下によって行われる場合、施用量を低減することが可能であり、特に、ロックウール又はパーライトなどの不活性底土が使用される場合は、施用量を低減することが可能である)。 The application rates of the active compound combinations according to the invention are as follows when treating leaves: 100 to 10000 g / ha, preferably 1000 to 5500 g / ha, particularly preferably 1000 to 3500 g / ha (the application concerned) Can be reduced if done by irrigation or dripping, especially if an inert bottom such as rock wool or perlite is used) .
これらの施用量は、例としてのみ挙げられており、本発明の意味において限定を目的とするものではない。 These application rates are given as examples only and are not intended to be limiting in the sense of the present invention.
本発明による活性化合物組合せ又は組成物は、かくして、処理後特定の期間、上記病原体による攻撃に対して植物を保護するために使用することができる。保護がもたらされる期間は、当該活性化合物で植物を処理した後、一般に、1〜28日、好ましくは、1〜14日に及び、又は、種子処理後、最大で200日間に及ぶ。 The active compound combinations or compositions according to the invention can thus be used to protect plants against attack by the pathogen for a certain period after treatment. The period during which protection is brought about generally ranges from 1 to 28 days, preferably from 1 to 14 days, after treatment of the plants with the active compound, or up to 200 days after seed treatment.
本発明による活性化合物組合せの良好な殺菌活性について、下記実施例によって実証する。個々の活性化合物の殺菌活性は弱いが、該組合せは、活性を単に加えたものを超えた活性を示す。 The good fungicidal activity of the active compound combinations according to the invention is demonstrated by the following examples. Although the individual active compounds have weak bactericidal activity, the combination exhibits activity beyond that which is simply the addition of activity.
殺菌剤において、2種又は3種の活性化合物の所与の組合せの殺菌活性が当該活性化合物組合せに関してS.R.Colby(”Calculating Synergistic and Antagonistic Responses of Herbicide Combination”, Weeds 1967, 15, 20−22)に従って以下のように計算された期待される活性よりも高い場合、相乗効果が常に存在している:
Xは、活性化合物Aをm(g/ha)の施用量で使用した場合の効力であり;
Yは、活性化合物Bをn(g/ha)の施用量で使用した場合の効力であり;
E1は、活性化合物A及び活性化合物Bをそれぞれm(g/ha)及びn(g/ha)の施用量で使用した場合の効力である;
とした場合、
E2は、活性化合物A、B及びCをそれぞれm(g/ha)、n(g/ha)、及びr(g/ha)の施用量で使用した場合の効力である;
In a fungicide, the fungicidal activity of a given combination of two or three active compounds is S. cerevisiae for that active compound combination. R. A synergistic effect is always present if it is higher than the expected activity calculated according to Colby ("Calculating Synthetic Responses and Antagonistic Responses of Herbicide Combination", Weeds 1967 , 15 , 20-22):
X is the potency when active compound A is used at an application rate of m (g / ha);
Y is the potency when active compound B is used at an application rate of n (g / ha);
E 1 is the efficacy when active compound A and active compound B are used at application rates of m (g / ha) and n (g / ha), respectively;
If
E 2 is the potency when active compounds A, B and C are used at application rates of m (g / ha), n (g / ha) and r (g / ha), respectively;
実際の殺菌活性が計算された活性よりも高い場合、当該組合せの活性は相加的なものを超えていてる。即ち、相乗効果が存在している。この場合、実際に観察された効力は、期待される効力E1について上記式を用いて計算した値よりも高くなければならない。 If the actual bactericidal activity is higher than the calculated activity, the activity of the combination is more than additive. That is, a synergistic effect exists. In this case, the efficacy which was actually observed must be greater than the value calculated using the above formula for efficacy E 1 to be expected.
本発明について、下記実施例によって例証する。(しかしながら、本発明は、該実施例に限定されない。) The invention is illustrated by the following examples. (However, the present invention is not limited to the examples.)
顔料と一緒にQoI阻害薬殺菌剤及び接触殺菌剤及び脱メチル化反応阻害薬を含んでいる種々の組成物が含量を含まずに3種類の殺菌剤を含んでいる組成物よりも優れていることを確認するために、以下の場所において試験を行った:1.マサチューセッツ大学(場所:Vermont);2.ウィスコンシン大学(場所:Sentry);3.ウィスコンシン大学(場所:Iron Mountain);4.ウィスコンシン大学(場所:Champion MI);5.ウィスコンシン大学(場所:Edina MN);6.オレゴン州立大学(場所:Sun River);7.ワシントン州立大学(場所:McCall);8.ワシントン州立大学(場所:Chewelah);及び、9.ワシントン州立大学(場所:Pullman)。 Various compositions containing QoI inhibitor bactericides and contact bactericides and demethylation inhibitors together with pigments are superior to compositions containing three types of fungicides without content To confirm this, tests were conducted at the following locations: University of Massachusetts (location: Vermont); 2. University of Wisconsin (Location: Sentry); 3. University of Wisconsin (Location: Iron Mountain); 4. 4. University of Wisconsin (location: Champion MI); University of Wisconsin (location: Edina MN); 6. Oregon State University (location: Sun River); Washington State University (Location: McCall); 8. 8. Washington State University (location: Chewelah); Washington State University (Pullman).
記載されている組成物を施用するための一般的な手順は、次の通りである。処理区画は、例えば、無作為完全乱塊法における、6フィート×7フィート(3.8m2)の3反復であった。処理は、10月下旬から11月中旬にかけて実施した。幾つかの例では、該組成物は、11008フラットファンTeeJetノズルを有する二輪自走式CO2加圧(40psi=2.8バール)スプレーヤーを用いて、80GPAで施用した。 The general procedure for applying the described composition is as follows. The treatment section was, for example, 3 iterations of 6 feet x 7 feet (3.8 m 2 ) in a random complete block method. The treatment was carried out from late October to mid November. In some examples, the composition was applied at 80 GPA using a two-wheel self-propelled CO 2 pressurized (40 psi = 2.8 bar) sprayer with a 11008 flat fan TeeJet nozzle.
幾つかの場所は、冬季を通して断続的な積雪が有り、連続的な積雪の期間もあった。雪が溶けた直後、又は、雪を機械的に除去した直後、紅色雪腐病(M.nivale)及び/又は雪腐褐色小粒菌核病(Typhula spp.)の発病度(感染面積(%))並びに芝草品質(1〜9の尺度に基づいた評価:9が最も優れている)について、個々の区画を評価した。 Some locations had intermittent snowfall throughout the winter, and there were periods of continuous snowfall. Immediately after the snow melts or after the snow has been mechanically removed, the severity of red snow rot (M. nivale) and / or snow rot brown flora (Typhula spp.) (Infectious area (%)) As well, individual compartments were evaluated for turfgrass quality (evaluation based on a scale of 1-9: 9 being the best).
表1は、雪腐病を防除するために組み合わされた3種類の殺菌剤の顔料を全く含んでいない標準的な組合せ〔SYNGENTA製INSTRATA(登録商標)〕との比較で、種々の量のQoI阻害薬殺菌剤(トリフロキシストロビン)及び接触殺菌剤(イプロジオン)及び脱メチル化反応阻害薬(トリチコナゾール)並びに顔料(フタロシアニン Green pigment)を含んでいる組成物の芝生の品質(TQ)又は芝生の色(TC)に対する効果について示している。尺度は、1〜9(1=劣っている、及び、9=優れている)。INSTRATA(登録商標)は、顔料を全く含まずに3種類の殺菌剤を含んでいる雪腐病用の製品であるので、対照として使用した。 Table 1 shows various amounts of QoI in comparison with a standard combination [INSTRATA® from SYNGENTA] that does not contain any of the three fungicide pigments combined to control snow rot. Lawn quality (TQ) of a composition comprising an inhibitor fungicide (trifloxystrobin) and a contact fungicide (iprodione) and a demethylation inhibitor (triticonazole) and a pigment (phthalocyanine green pigment ) or It shows the effect on the lawn color (TC) . The scale is 1-9 (1 = poor and 9 = excellent). INSTRATA (R) was used as a control because it is a snow rot product that contains three fungicides without any pigment.
A+B+C+Dを含んでいる組成物は、INSTRATA(登録商標)+顔料の等価物である。言い換えれば、そのような組成物を使用することで、3種類の殺菌剤のみを含んでいる(即ち、含量を含んでいない)組成物に対する顔料と一緒に3種類の殺菌剤を含んでいる組成物の優れた効果を実証するために、直接的な比較を実施することができる。結果は、顔料と一緒に3種類の殺菌剤を含んでいる組成物が使用された全ての場所において、TQ及びTCがINSTRATA(登録商標)よりも優れているということを示している。このことは、顔料と一緒に3種類の殺菌剤を含んでいる組成物を使用する場合、INSTRATA(登録商標)を使用する場合よりも、芝生の回復が良好であり及び良い状態に見えるということを意味している。 A composition containing A + B + C + D is the equivalent of INSTRATA® + pigment. In other words, using such a composition, a composition containing three fungicides together with a pigment for a composition containing only three fungicides (ie, no content). A direct comparison can be performed to demonstrate the superior effect of the object. The results show that TQ and TC are superior to INSTRATA (R) wherever a composition containing three types of fungicides along with the pigment was used. This means that lawn recovery looks better and looks better when using a composition containing three types of fungicides along with the pigment than when using INSTRATA®. Means.
場所9(組成物は、2種類の殺菌剤(A+B)とCを含んでいる)の結果は、2種類の殺菌剤と顔料からなる組成物が、INSTRATA(登録商標)よりも僅かに優れているとまではいかないが、INSTRATA(登録商標)と少なくとも同様に良好であるということを示している。このことは、INSTRATA(登録商標)が3種類の殺菌剤を含んでいる(顔料は含んでいない)ので、驚くべきことである。言い換えれば、2種類の殺菌剤と顔料を使用することにより、3種類の殺菌剤を使用した場合と同様の効果を達成することができる。 The result of location 9 (the composition contains two fungicides (A + B) and C) is that the composition of the two fungicides and pigments is slightly better than INSTRATA®. Although it is not, it shows that it is at least as good as INSTRATA®. This is surprising because INSTRATA® contains three types of fungicides (no pigments). In other words, the use of two types of fungicides and pigments can achieve the same effect as when three types of fungicides are used.
表2は、INSTRATA(登録商標)との比較で、種々の量のQoI阻害薬殺菌剤(トリフロキシストロビン)及び接触殺菌剤(イプロジオン)及び脱メチル化反応阻害薬(トリチコナゾール)並びに顔料(フタロシアニン Green pigment)を含んでいる組成物の%病害発生(disease infestation)に対する効果について、場所毎に示している。 Table 2 shows various amounts of QoI inhibitor fungicide (trifloxystrobin) and contact fungicide (iprodione) and demethylation inhibitor (triticonazole) and pigments in comparison to INSTRATA®. effect% disease incidence of a composition comprising (phthalocyanine Green Pigment) for (disease infestation), are shown for each location.
表2の結果は、顔料と一緒に3種類の殺菌剤を含んでいる組成物がINSTRATA(登録商標)とほぼ同様の病害発生割合(%)を治療することを示している。言い換えれば、開示されている組成物は、菌類の駆除において、INSTRATA(登録商標)と同程度に有効である。フタロシアニンなどの顔料を付加的に含んでいる組成物の優れた利点としては、以下のものを挙げることができる:冬季が終わって春季の深緑の期間における芝生のより良好な回復;芝生のより良好な健康状態;及び、より良好な美観(芝生が視覚的により良好に見える)。 The results in Table 2 show that a composition containing three types of fungicides along with a pigment treats a disease incidence (%) that is similar to INSTRATA®. In other words, the disclosed composition is as effective as INSTRATA® in controlling fungi. The superior benefits of a composition additionally containing a pigment such as phthalocyanine include the following: better recovery of the lawn in the dark green period of spring after the end of the winter; better of the lawn Good health; and better aesthetics (lawn looks visually better).
該QoI阻害薬殺菌剤、接触殺菌剤、脱メチル化反応阻害薬及び顔料は、組成物の中で任意の比率で存在させることができる。適切な比率の例が表3に示されている。 The QoI inhibitor fungicide, contact fungicide, demethylation inhibitor and pigment can be present in the composition in any ratio. Examples of suitable ratios are shown in Table 3.
トリフロキシストロビンとイプロジオンとフタロシアニン Green pigmentの代表的な別の組成としては、表4に示されている組成などがある(これらは、水に懸濁されている)。 Other representative compositions of trifloxystrobin, iprodione, and phthalocyanine Green pigment include those shown in Table 4 (these are suspended in water).
表5は、1.47g/Lのトリフロキシストロビンと29.41g/Lのイプロジオンと3.14g/Lのトリチコナゾールと6g/Lのフタロシアニンを含んでいる組成物の市販されているINSTRATA(登録商標)の溶液よりも優れた効果について示している。上記4成分組成物及びINSTRATA(登録商標)は、「Westmount Golf & Country Club」(Kitchener, Ontario, Canada)において、ベントグラス/Poa区画に施用した。 Table 5 shows the commercially available INSTRATA for a composition comprising 1.47 g / L trifloxystrobin, 29.41 g / L iprodione, 3.14 g / L triticonazole and 6 g / L phthalocyanine. It shows the effect superior to the solution of (registered trademark). The above four-component composition and INSTRATA® were applied to the bentgrass / Poa compartment in “Westmount Golf & Country Club” (Kitchener, Ontario, Canada).
上記結果に示されているように、トリフロキシストロビンとイプロジオンとトリチコナゾールとフタロシアニンからなる4成分組成物の施用は、INSTRATA(登録商標)よりも優れている。当該4成分組成物は、INSTRATA(登録商標)よりも優れた病害防除(病害に冒された面積(%)により測定)を提供する〔2%に対して0%〕のみではなく、TQも6.6に対して8.7〜9と優れている。さらに、INSTRATA(登録商標)(300mL/m2)に対して著しく少ない量の当該組成物(100mL/100m2〜177.5mL/m2)を使用して、優れた結果を達成することができる。このことは、土壌中に施用される化学物質がより少ないという点で環境の観点から重要であるばかりではなく、費用がより少ないという点で経済的な観点からも重要である。 As shown in the above results, the application of a four-component composition consisting of trifloxystrobin, iprodione, triticonazole, and phthalocyanine is superior to INSTRATA®. The quaternary composition provides better disease control (measured by disease affected area (%)) than INSTRATA® [0% versus 2%], as well as a TQ of 6 .6 to 8.7-9. Further, by using the INSTRATA (TM) significantly less amount of the composition with respect to (300mL / m 2) (100mL / 100m 2 ~177.5mL / m 2), it is possible to achieve good results . This is not only important from an environmental point of view in that less chemicals are applied to the soil, but also from an economic point of view because of lower costs.
理論に縛られるものではないが、さまざまな殺菌剤が顔料と相乗効果的に作用し、それによって、優れた効果が観察されるものと考えられる。 Without being bound by theory, it is believed that various fungicides act synergistically with the pigment, thereby observing superior effects.
さらなる試験を欧州で実施した。データは、以下に示されている。 Further testing was conducted in Europe. The data is shown below.
試験は、2種類の活性成分〔トリフロキシストロビン(QoI阻害薬殺菌剤)、及び、イプロジオン(接触殺菌剤)〕と顔料(フタロシアニン)の組合せの芝生の品質に対する効力及び効果について評価するために設計した。殺菌活性化合物は、2種類の異なった濃度で、個別的に施用したか、又は、組み合わせて(顔料は非含有)施用したか、又は、顔料も含ませて組み合わせて施用した。これらの処理を、市販されている標準的な製品と比較した。 The test is to evaluate the efficacy and effect on the lawn quality of the combination of two active ingredients [Trifloxystrobin (QoI inhibitor fungicide) and Iprodione (contact fungicide)] and pigment (phthalocyanine) Designed. The bactericidal active compounds were applied individually at two different concentrations, or in combination (pigment free) or in combination with pigments. These treatments were compared to standard products that are commercially available.
試験は、個々の病害に応じて、2008年にUK及びドイツのさまざまな場所で、7月末から12月初めの間に実施した。試験設計は、無作為完全乱塊法(4反復、及び、区画面積:4〜6.25m2)であった。製品は、1ha当たり400〜500Lの水量での噴霧施用として施用した。施用には、ティージェットノズル又はフラットファンノズルを有する空気加圧噴霧器を使用し、2.2〜3.0バールで作動させた。28日間隔で、2回の施用を実施した。 The tests were conducted between the end of July and the beginning of December in 2008 in various locations in the UK and Germany, depending on the specific disease. The test design was a random complete block method (4 iterations and compartment area: 4-6.25 m 2 ). The product was applied as a spray application with a water volume of 400-500 L per ha. For application, an air pressure sprayer with a tee jet nozzle or a flat fan nozzle was used and operated at 2.2-3.0 bar. Two applications were performed at 28 day intervals.
試験は、最初の施用後72日目まで、14〜28日間隔で評価した。芝生の病害:紅色雪腐病〔ミクロドキウム・ニバレ(Microdochium nivale)〕、さび病〔プッシニア属種(Puccinia spp.)〕、赤葉腐病〔ラエチサリア・フシホルミス(Laetisaria fuciformis)〕について、区画当たりの感染した草冠面積(%)として評価した。芝生の品質(色及び/又は密度)は、順序尺度に基づいて判断した。データは、全ての評価の平均として示される。 The test was evaluated at 14-28 day intervals up to 72 days after the first application. Lawn's Disease: Red Snow Rot (Microdocium nivale), Rust (Puccinia spp.), Red Leaf Rot (Laetisaria ficiformis per compartment) The crown area (%) was evaluated. Lawn quality (color and / or density) was judged on the basis of an ordinal scale. Data are presented as the average of all evaluations.
表6は、顔料を全く含んでいない市販されている標準品〔SYNGENTA製DACONIL、及び、SYNGENTA製AMISTAR〕との比較で、種々の量のQoI阻害薬殺菌剤(トリフロキシストロビン)及び接触殺菌剤(イプロジオン)及び顔料(フタロシアニン Green pigment)を含んでいる組成物の芝生の品質(TQ)及び/又は芝生の色(TC)に対する効果について示している。データは、1〜9の尺度(1=劣っている、及び、9=優れている)で示されている。 Table 6 shows various amounts of QoI inhibitor fungicide (trifloxystrobin) and contact sterilization compared to commercially available standards (DACONIL from SYNGENTA and AMISTAR from SYNGENTA) that do not contain any pigment. Figure 2 shows the effect of a composition comprising an agent (iprodione) and a pigment (phthalocyanine green pigment) on lawn quality (TQ) and / or lawn color (TC) . Data are shown on a scale of 1-9 (1 = poor and 9 = excellent).
表6のデータは、化合物Aと化合物Bが化合物Cと組み合わされている区画において芝生の品質が改善されていることを示している。化合物Aと化合物Bの単独による処理及び組合せA+Bによる処理で達成された品質についての点数は、A+B+Cについての点数よりも低かった。この結果は、化合物Cを含有せず、達成された点数が同様に低い市販されている標準品についての点数によって支持される。 The data in Table 6 shows that grass quality is improved in the compartment where Compound A and Compound B are combined with Compound C. The score for quality achieved by treatment with Compound A and Compound B alone and with the combination A + B was lower than the score for A + B + C. This result is supported by the score for a commercially available standard that does not contain Compound C and the score achieved is similarly low.
表7は、DACONIL(登録商標)及びAMISTAR(登録商標)との比較で、種々の量のQoI阻害薬殺菌剤(トリフロキシストロビン)及び接触殺菌剤(イプロジオン)及び顔料(フタロシアニン Green pigment)を含んでいる組成物の%病害発生(disease infestation)に対する効果について、場所毎に示している。 Table 7 shows various amounts of QoI inhibitor fungicide (trifloxystrobin) and contact fungicide (iprodione) and pigment (phthalocyanine green pigment) in comparison to DACONIL® and AMISTAR®. for effects on% disease incidence of compositions comprise (disease infestation), it is shown for each location.
表7のデータは、化合物A+B+Cの組合せが、化合物A+Bのみの組合せ(顔料非含有)と比較して、芝生の病原菌〔プッシニア属種(Puccinia spp.)〕を良好に防除したことを示している。この効果は、化合物A+B+Cの組合せが低いa.i.濃度においてさえ化合物A+Bのみの組合せよりも優れているということが見いだされたことによって強調された。 The data in Table 7 show that the combination of Compound A + B + C better controlled the lawn pathogen [Puccinia spp.] Compared to the combination of Compound A + B alone (no pigment). . This effect is due to the low combination of compounds A + B + C a. i. It was emphasized by the fact that it was found to be superior to the combination of compound A + B alone even in concentration.
Claims (14)
(A)少なくとも1種類のフタロシアニン顔料;
並びに、
(B)
(i)少なくとも1種類のQoI阻害薬殺菌剤;及び、
(ii)接触殺菌剤と
(iii)DMI−殺菌剤からなる群から選択される少なくとも1種類の殺菌剤;
を含んでいる、前記活性化合物組合せ。 An active compound combination comprising:
(A) at least one phthalocyanine pigment;
And
(B)
(I) at least one QoI inhibitor fungicide; and
(Ii) a contact fungicide and (iii) at least one fungicide selected from the group consisting of DMI-bactericides;
The active compound combination comprising:
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US9357768B2 (en) | 2006-10-05 | 2016-06-07 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
ES2619731T3 (en) | 2008-06-26 | 2017-06-26 | Suncor Energy Inc. | Fungicidal formulation for improved grass with pigment |
AU2011301171C1 (en) | 2010-09-09 | 2015-09-10 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
CN103732071A (en) | 2011-06-03 | 2014-04-16 | 桑科能源股份有限公司 | Paraffinic oil-in-water emulsions for controlling infection of crop plants by fungal pathogens |
CN102405930A (en) * | 2011-10-20 | 2012-04-11 | 迈克斯(如东)化工有限公司 | Bactericide combination capable of beautifying color for lawns and preparation method |
US9820490B2 (en) | 2011-11-03 | 2017-11-21 | Bayer Cropscience Lp | Compositions and methods for enhancing plant quality |
CA2999012A1 (en) | 2013-11-26 | 2015-06-04 | Upl Limited | A composition comprising a multisite fungicide and two systemic fungicides, and a method thereof |
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