JP2012256571A - Flat battery - Google Patents

Flat battery Download PDF

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JP2012256571A
JP2012256571A JP2011130057A JP2011130057A JP2012256571A JP 2012256571 A JP2012256571 A JP 2012256571A JP 2011130057 A JP2011130057 A JP 2011130057A JP 2011130057 A JP2011130057 A JP 2011130057A JP 2012256571 A JP2012256571 A JP 2012256571A
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positive electrode
side wall
electrode material
pedestal
flat battery
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JP5706763B2 (en
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Shoji Yabushita
昇志 薮下
Koji Yamaguchi
浩司 山口
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Hitachi Maxell Energy Ltd
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Hitachi Maxell Energy Ltd
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    • Y02E60/12

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  • Sealing Battery Cases Or Jackets (AREA)
  • Primary Cells (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain such a configuration, where one member is less likely to be removed from a base for holding any one member of a positive electrode material or a negative electrode material even if an impact is applied thereto, in a flat battery where the base is secured to an outer can.SOLUTION: The flat battery (1) comprises: a bottomed cylindrical positive electrode can (10) (outer can); a negative electrode can (20) (sealing can) disposed to cover the opening of the positive electrode can (10); a positive electrode material (41) and a negative electrode material (42) interposed between the positive electrode can (10) and the negative electrode can (20); and a positive electrode ring (44) (base) fixed onto the inner surface of the positive electrode can (10) while holding any one member of the positive electrode material (41) or negative electrode material (42). The positive electrode ring (44) has a sidewall (44a) covering a part of the one member, and at least one protrusion (44c) (engaging part) for holding the one member is provided on the sidewall (44a).

Description

本発明は、コイン形電池等の扁平形電池に関する。   The present invention relates to a flat battery such as a coin battery.

従来より、有底筒状の外装缶と該外装缶の開口を覆うように配置される封口缶との間に、正極材及び負極材を配置するとともに、該正極材及び負極材のいずれか一方を保持する台座を外装缶に対して固定した扁平形電池が知られている。このような扁平形電池として、例えば特許文献1に開示されるように、正極缶に対して、正極ペレットに固定された正極リングが抵抗溶接もしくはレーザー溶接によって正極缶の内側から溶着された構成が知られている。   Conventionally, a positive electrode material and a negative electrode material are arranged between a bottomed cylindrical outer can and a sealing can arranged to cover the opening of the outer can, and either the positive electrode material or the negative electrode material A flat battery in which a pedestal for holding the battery is fixed to an outer can is known. As such a flat battery, for example, as disclosed in Patent Document 1, a configuration in which a positive electrode ring fixed to a positive electrode pellet is welded to the positive electrode can from the inside of the positive electrode can by resistance welding or laser welding. Are known.

特開2008−103109号公報JP 2008-103109 A

ところで、上述の特許文献1に開示されている構成のように、外装缶(正極缶)に対して、正極材(正極ペレット)を保持する台座(正極リング)を固定する構成の場合、台座内に正極材を装着する前に、台座を外装缶に固定する必要がある。   By the way, in the structure which fixes the base (positive electrode ring) which hold | maintains a positive electrode material (positive electrode pellet) with respect to an exterior can (positive electrode can) like the structure currently disclosed by the above-mentioned patent document 1, Before mounting the positive electrode material on the base, it is necessary to fix the pedestal to the outer can.

一般的に、正極材は、型枠等を用いて台座内に成形されるが、上述のように台座を外装缶に固定した状態では、台座内での正極材の成形が難しい。そのため、例えば、外装缶に対して固定された台座内に、ブロック状に形成した正極材を配置し、該部材を押し潰すことによって、台座内に正極材を装着する方法が考えられる。   In general, the positive electrode material is molded in the pedestal using a mold or the like. However, in the state where the pedestal is fixed to the outer can as described above, it is difficult to mold the positive electrode material in the pedestal. Therefore, for example, a method of mounting the positive electrode material in the pedestal by placing the positive electrode material formed in a block shape in a pedestal fixed to the outer can and crushing the member is conceivable.

しかしながら、上述のような方法で台座内に正極材を装着した場合、型枠等を用いて台座内に正極材を成形した場合に比べて、台座に対する正極材の密着性が低下する。   However, when the positive electrode material is mounted in the pedestal by the method described above, the adhesion of the positive electrode material to the pedestal is lower than when the positive electrode material is molded in the pedestal using a mold or the like.

特に、扁平形電池を、タイヤの空気圧を検出するタイヤ空気圧検出装置用の電源のような強い衝撃が加わる環境下で用いる場合、扁平形電池が受けた衝撃によって、台座から正極材が外れる可能性がある。扁平形電池内で台座から正極材が外れると、正極材と外装缶との接触が不安定になり、扁平形電池の内部抵抗が増大するため、電池性能が大幅に低下する可能性がある。   In particular, when a flat battery is used in an environment where a strong impact is applied, such as a power supply for a tire air pressure detection device that detects the tire air pressure, the positive battery may be detached from the pedestal due to the impact received by the flat battery. There is. If the positive electrode material is detached from the pedestal in the flat battery, the contact between the positive electrode material and the outer can becomes unstable, and the internal resistance of the flat battery increases, so that the battery performance may be significantly lowered.

本発明の目的は、外装缶に対して、正極材及び負極材のいずれか一方の部材を保持するための台座を固定する扁平形電池において、衝撃を受けても台座から前記一方の部材が外れにくい構成を得ることにある。   An object of the present invention is to provide a flat battery for fixing a pedestal for holding either a positive electrode material or a negative electrode material with respect to an outer can. It is to obtain a difficult configuration.

本発明の一実施形態にかかる扁平形電池は、有底筒状の外装缶と、前記外装缶の開口を覆うように配置される封口缶と、前記外装缶と封口缶との間に配置される正極材及び負極材と、前記正極材及び負極材のいずれか一方の部材を保持しつつ前記外装缶の内面上に固定される台座と、を備え、前記台座は、前記一方の部材の一部を覆う側壁部を有し、前記側壁部には、前記一方の部材を保持するための係止部が少なくとも一つ設けられている(第1の構成)。   A flat battery according to an embodiment of the present invention is disposed between a bottomed cylindrical outer can, a sealing can disposed so as to cover an opening of the outer can, and the outer can and the sealing can. A positive electrode material and a negative electrode material, and a base fixed on the inner surface of the outer can while holding one member of the positive electrode material and the negative electrode material, and the base is one of the one member A side wall portion covering the first portion, and at least one locking portion for holding the one member is provided on the side wall portion (first configuration).

以上の構成により、外装缶に固定された台座内に、正極材及び負極材のいずれか一方の部材を保持することができる。すなわち、台座の側壁部には、前記一方の部材を保持するための係止部が設けられているため、該係止部によって、前記一方の部材が台座から外れるのを防止できる。   With the above configuration, either the positive electrode material or the negative electrode material can be held in the pedestal fixed to the outer can. That is, since the locking portion for holding the one member is provided on the side wall of the pedestal, the locking member can prevent the one member from coming off the pedestal.

したがって、上述の構成により、扁平形電池が衝撃を受けた場合でも、外装缶に固定された台座から前記一方の部材が外れて電池の内部抵抗が増大するのを防止できる。   Therefore, even when the flat battery is subjected to an impact, the above-described configuration can prevent the internal resistance of the battery from increasing due to the removal of the one member from the base fixed to the outer can.

前記第1の構成において、前記係止部は、前記側壁部の台座内方側の面に設けられた突出部及び凹部の少なくとも一方からなり、前記一方の部材は、その外周側で前記係止部と係合するように前記台座内に配置されている(第2の構成)。   In the first configuration, the locking portion includes at least one of a projecting portion and a concave portion provided on a surface of the side wall portion on the pedestal inward side, and the one member is locked on the outer peripheral side thereof. It arrange | positions in the said base so that a part may be engaged (2nd structure).

これにより、台座の側壁部における台座内方側の面に形成された係止部と、一方の部材の外周側とが係合して、該一方の部材を台座内に係止することができる。   Thereby, the latching | locking part formed in the surface inside the base in the side wall part of a base and the outer peripheral side of one member can engage, and this one member can be latched in a base. .

特に、前記第2の構成において、前記係止部は、前記台座の側壁部をその厚み方向に変形させることにより形成される(第3の構成)。こうすることで、台座の側壁部に係止部を容易に形成することができる。しかも、側壁部を厚み方向に変形させることにより、該側壁部に比較的大きな突出部または凹部が形成されるため、該側壁部に対して一方の部材をより確実に係止させることができる。   Particularly, in the second configuration, the locking portion is formed by deforming a side wall portion of the pedestal in a thickness direction thereof (third configuration). By carrying out like this, a latching | locking part can be easily formed in the side wall part of a base. And since a comparatively big protrusion part or recessed part is formed in this side wall part by deform | transforming a side wall part in the thickness direction, one member can be more reliably latched with respect to this side wall part.

また、前記第2または第3の構成において、前記一方の部材は、軸線方向に延びる柱状のブロック部材を、該軸線方向が台座の側壁部の高さ方向と一致するように該台座内に配置した状態で、該軸線方向に押し潰すことにより、前記台座内に装着され、前記突出部は、その突出高さが、前記ブロック部材を押し潰したときの該ブロック部材の前記軸線方向と直交する方向への変形量よりも小さい(第4の構成)。   Further, in the second or third configuration, the one member includes a columnar block member extending in the axial direction in the pedestal so that the axial direction coincides with the height direction of the side wall portion of the pedestal. In this state, it is mounted in the pedestal by being crushed in the axial direction, and the protruding portion has a protruding height perpendicular to the axial direction of the block member when the block member is crushed. It is smaller than the amount of deformation in the direction (fourth configuration).

これにより、ブロック部材が台座の側壁部に設けられた突出部と干渉するのを防止できる。したがって、台座内にブロック部材を容易に配置することができる。そして、台座内で、軸線方向に延びる柱状のブロック部材を該軸線方向に押し潰すことにより、該台座内に正極材及び負極材のいずれか一方の部材を装着することができる。   Thereby, it can prevent that a block member interferes with the protrusion part provided in the side wall part of the base. Therefore, the block member can be easily arranged in the pedestal. Then, by crushing the columnar block member extending in the axial direction in the pedestal in the axial direction, either the positive electrode material or the negative electrode material can be mounted in the pedestal.

しかも、上述のような形成方法により、台座の側壁部に設けられた突出部を前記一方の部材の外周側に食い込ませることができる。これにより、前記一方の部材を台座内により確実に保持することができる。   In addition, the projecting portion provided on the side wall portion of the pedestal can be caused to bite into the outer peripheral side of the one member by the forming method as described above. Thereby, the said one member can be hold | maintained more reliably in a base.

さらに、前記第1の構成において、前記係止部は、前記台座の側壁部に設けられた開口部によって構成され、前記台座内に装着される前記一方の部材は、その一部が前記開口部内に位置している(第5の構成)。   Furthermore, in the first configuration, the locking portion is configured by an opening provided in a side wall portion of the pedestal, and a part of the one member mounted in the pedestal is in the opening. (Fifth configuration).

このように開口部内に前記一方の部材の一部を位置付けることによっても、該一方の部材を台座内に保持することができる。   Thus, by positioning a part of the one member in the opening, the one member can be held in the pedestal.

本発明の一実施形態にかかる扁平形電池は、外装缶に固定される台座の側壁部に、正極材及び負極材のいずれか一方の部材を保持するための係止部を設けた。これにより、扁平形電池に衝撃が加わっても、台座から前記一方の部材が外れるのを抑制できる。   In the flat battery according to the embodiment of the present invention, a locking portion for holding either the positive electrode material or the negative electrode material is provided on the side wall portion of the base fixed to the outer can. Thereby, even if an impact is applied to the flat battery, it is possible to suppress the removal of the one member from the pedestal.

図1は、本発明の実施形態1に係る扁平形電池の概略構成を示す断面図である。FIG. 1 is a cross-sectional view showing a schematic configuration of a flat battery according to Embodiment 1 of the present invention. 図2は、正極リングの概略構成を示す斜視図である。FIG. 2 is a perspective view showing a schematic configuration of the positive electrode ring. 図3は、正極リング内にブロック部材を配置した状態を模式的に示す断面図である。FIG. 3 is a cross-sectional view schematically showing a state in which the block member is arranged in the positive electrode ring. 図4は、本発明の実施形態2に係る扁平形電池の正極リングの係止構造を拡大して示す断面図である。FIG. 4 is an enlarged cross-sectional view showing a positive ring locking structure of a flat battery according to Embodiment 2 of the present invention. 図5は、本発明の実施形態3に係る扁平形電池の正極リングの係止構造を拡大して示す断面図である。FIG. 5 is an enlarged cross-sectional view illustrating a positive ring locking structure of a flat battery according to Embodiment 3 of the present invention. 図6は、本発明の実施形態4に係る扁平形電池の正極リングの係止構造を拡大して示す断面図である。FIG. 6 is an enlarged cross-sectional view showing a positive ring locking structure of a flat battery according to Embodiment 4 of the present invention. 図7は、本発明の実施形態5に係る扁平形電池の概略構成を示す断面図である。FIG. 7 is a cross-sectional view showing a schematic configuration of a flat battery according to Embodiment 5 of the present invention.

以下、図面を参照し、本発明の実施の形態を詳しく説明する。図中の同一または相当部分については同一の符号を付してその説明は繰り返さない。   Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. The same or corresponding parts in the drawings are denoted by the same reference numerals and description thereof will not be repeated.

[実施形態1]
(全体構成)
図1は、本発明の一実施形態である扁平形電池1の概略構成を示す断面図である。この扁平形電池1は、有底円筒状の正極缶10(外装缶)と、該正極缶10の開口を覆う負極缶20(封口缶)と、正極缶10の外周側と負極缶20の外周側との間に配置されるガスケット30と、正極缶10及び負極缶20の間に形成される空間内に収納される発電要素40とを備えている。扁平形電池1は、正極缶10と負極缶20とを合わせることによって、全体が扁平なコイン状に形成されている。なお、正極缶10及び負極缶20の間に形成される空間内には、発電要素40以外に、非水電解液(図示省略)も封入されている。
[Embodiment 1]
(overall structure)
FIG. 1 is a cross-sectional view showing a schematic configuration of a flat battery 1 according to an embodiment of the present invention. The flat battery 1 includes a bottomed cylindrical positive electrode can 10 (exterior can), a negative electrode can 20 (sealing can) covering the opening of the positive electrode can 10, an outer peripheral side of the positive electrode can 10, and an outer periphery of the negative electrode can 20. And a power generation element 40 housed in a space formed between the positive electrode can 10 and the negative electrode can 20. The flat battery 1 is formed in a flat coin shape as a whole by combining the positive electrode can 10 and the negative electrode can 20 together. In addition to the power generation element 40, a non-aqueous electrolyte (not shown) is also enclosed in the space formed between the positive electrode can 10 and the negative electrode can 20.

正極缶10は、ステンレスなどの金属材料からなり、プレス成形によって有底円筒状に形成されている。正極缶10は、円形状の底部11と、その外周に該底部11と連続して形成される円筒状の周壁部12とを備えている。周壁部12は、縦断面視で、底部11に対して垂直に延びるように設けられている。正極缶10は、後述するように、負極缶20との間にガスケット30を挟んだ状態で、周壁部12の開口端側が内側に折り曲げられて、該負極缶20の外周部に対してかしめられている。   The positive electrode can 10 is made of a metal material such as stainless steel, and is formed into a bottomed cylindrical shape by press molding. The positive electrode can 10 includes a circular bottom portion 11 and a cylindrical peripheral wall portion 12 formed continuously with the bottom portion 11 on the outer periphery thereof. The peripheral wall portion 12 is provided so as to extend perpendicularly to the bottom portion 11 in a longitudinal sectional view. As described later, the positive electrode can 10 is crimped to the outer peripheral portion of the negative electrode can 20 by bending the opening end side of the peripheral wall portion 12 inward with the gasket 30 sandwiched between the positive electrode can 10 and the negative electrode can 20. ing.

負極缶20も、正極缶10と同様、ステンレスなどの金属材料からなり、プレス成形によって有底円筒状に形成されている。負極缶20は、円形状の平面部21と、その外周に該平面部21と連続して形成される円筒状の周壁部22とを備えている。この周壁部22も、正極缶10と同様、縦断面視で、平面部21に対して垂直に延びるように設けられている。周壁部22は、該周壁部22の基端部22aに対して径が段状に大きくなる拡径部22bを有している。すなわち、周壁部22には、基端部22aと拡径部22bとの間に段部22cが形成されている。図1に示すように、この段部22cに対して、正極缶10の周壁部12の開口端側が折り曲げられてかしめられている。これにより、正極缶10と負極缶20とが、それらの外周側で接続されている。   Similarly to the positive electrode can 10, the negative electrode can 20 is made of a metal material such as stainless steel and is formed in a bottomed cylindrical shape by press molding. The negative electrode can 20 includes a circular flat surface portion 21 and a cylindrical peripheral wall portion 22 formed continuously with the flat surface portion 21 on the outer periphery thereof. Similar to the positive electrode can 10, the peripheral wall portion 22 is also provided so as to extend perpendicularly to the flat portion 21 in a longitudinal sectional view. The peripheral wall portion 22 has an enlarged diameter portion 22b whose diameter increases stepwise with respect to the base end portion 22a of the peripheral wall portion 22. That is, the peripheral wall portion 22 is formed with a step portion 22c between the base end portion 22a and the enlarged diameter portion 22b. As shown in FIG. 1, the open end side of the peripheral wall portion 12 of the positive electrode can 10 is bent and caulked with respect to the step portion 22c. Thereby, the positive electrode can 10 and the negative electrode can 20 are connected on the outer peripheral side thereof.

ガスケット30は、ポリフェニレンサルファイド(PPS)を主成分としており、PPSにオレフィン系エラストマーを含有した樹脂組成物からなる。ガスケット30は、正極缶10の周壁部12と負極缶20の周壁部22との間に挟みこまれるように配置される。具体的には、ガスケット30は、リング状のベース部31と、該ベース部31の外周縁から突出する外筒壁32と、該ベース部31の内周縁から該外筒壁32と同じ方向に伸びる内筒壁33とを備えている。本実施形態では、ガスケット30は、ベース部31、外筒壁32及び内筒壁33が一体で形成されている。   The gasket 30 is mainly composed of polyphenylene sulfide (PPS), and is made of a resin composition containing an olefin elastomer in PPS. The gasket 30 is disposed so as to be sandwiched between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20. Specifically, the gasket 30 includes a ring-shaped base portion 31, an outer cylindrical wall 32 protruding from the outer peripheral edge of the base portion 31, and the outer peripheral wall 32 from the inner peripheral edge of the base portion 31 in the same direction. And an extending inner cylindrical wall 33. In the present embodiment, the gasket 30 is formed integrally with a base portion 31, an outer cylindrical wall 32, and an inner cylindrical wall 33.

ガスケット30は、図1に示すように、ベース部31が、正極缶10の底部11の外周側と負極缶20の拡径部22bの開口端との間に挟みこまれるように、正極缶20の内側の底部11上に配置されている。これにより、負極缶20の拡径部22bは、ガスケット30の外筒壁32と内筒壁33との間に位置づけられる。ガスケット30の外筒壁32は、正極缶10の周壁部12と負極缶20の周壁部22との間に挟みこまれている。ガスケット30のベース部31及び外筒壁32は、正極缶10の周壁部12と負極缶20の周壁部22との間に挟みこまれた状態で、該正極缶10の周壁部12と負極缶20の周壁部22との隙間をシールできるような厚みを有している。   As shown in FIG. 1, the gasket 30 is configured so that the base portion 31 is sandwiched between the outer peripheral side of the bottom portion 11 of the positive electrode can 10 and the open end of the enlarged diameter portion 22 b of the negative electrode can 20. It is arranged on the bottom 11 inside. Thereby, the enlarged diameter portion 22 b of the negative electrode can 20 is positioned between the outer cylinder wall 32 and the inner cylinder wall 33 of the gasket 30. The outer cylindrical wall 32 of the gasket 30 is sandwiched between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20. The base portion 31 and the outer cylindrical wall 32 of the gasket 30 are sandwiched between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20, and the peripheral wall portion 12 of the positive electrode can 10 and the negative electrode can It has a thickness that can seal a gap with 20 peripheral wall portions 22.

このように、正極缶10の周壁部12と負極缶20の周壁部22との間にガスケット30を配置することにより、該正極缶10と負極缶20とをそれらの外周側で絶縁することができる。また、正極缶10の周壁部12と負極缶20の周壁部22との間にガスケット30を挟みこんだ状態で、該正極缶10の周壁部12を折り曲げて負極缶20の周壁部22にかしめることにより、該ガスケット30によって正極缶10の周壁部12と負極缶20の周壁部22との間を封止することができる。すなわち、ガスケット30は、正極缶10の周壁部12と負極缶20の段部22cとの間に挟みこまれる外筒壁32、及び、負極缶20の周壁部22の開口端と正極缶10の底部11との間に挟みこまれるベース部31が、それぞれ、シールとして機能する。   Thus, by arranging the gasket 30 between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20, the positive electrode can 10 and the negative electrode can 20 can be insulated on the outer peripheral side thereof. it can. In addition, with the gasket 30 sandwiched between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20, the peripheral wall portion 12 of the positive electrode can 10 is folded and connected to the peripheral wall portion 22 of the negative electrode can 20. By tightening, the gasket 30 can seal between the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20. That is, the gasket 30 includes the outer cylindrical wall 32 sandwiched between the peripheral wall portion 12 of the positive electrode can 10 and the step portion 22 c of the negative electrode can 20, and the opening end of the peripheral wall portion 22 of the negative electrode can 20 and the positive electrode can 10. The base portions 31 sandwiched between the bottom portion 11 each function as a seal.

発電要素40は、正極活物質等を円盤状に成形した正極材41と、負極活物質の金属リチウムまたはリチウム合金を円盤状に形成した負極材42と、不織布製のセパレータ43とを備えている。図1に示すように、正極缶10の内方には正極材41が位置付けられている一方、負極缶20の内方には負極材42が位置付けられている。正極材41と負極材42との間にはセパレータ43が配置されている。   The power generation element 40 includes a positive electrode material 41 in which a positive electrode active material or the like is formed into a disk shape, a negative electrode material 42 in which a metal lithium or a lithium alloy as a negative electrode active material is formed in a disk shape, and a nonwoven fabric separator 43. . As shown in FIG. 1, the positive electrode material 41 is positioned inside the positive electrode can 10, while the negative electrode material 42 is positioned inside the negative electrode can 20. A separator 43 is disposed between the positive electrode material 41 and the negative electrode material 42.

正極材41は、正極活物質として二酸化マンガンを含有している。この正極材41は、次のようにして形成される。まず、二酸化マンガンに、黒鉛、テトラフルオロエチレン−ヘキサフルオロプロピレン共重合体及びヒドロキシプロピルセルロースを混合して正極合剤を調整する。そして、後述するように、正極リング44内に正極合剤からなる柱状のブロック部材45を配置した状態で、該ブロック部材45を押し潰すことにより、正極リング44内に正極材41を形成する。なお、正極材41の成形方法は、上述の限りではなく、正極合剤を正極リング44内に充填して加圧成形した後、成形された部材を加熱することによって形成するなど、どのような方法でもよい。   The positive electrode material 41 contains manganese dioxide as a positive electrode active material. The positive electrode material 41 is formed as follows. First, graphite, tetrafluoroethylene-hexafluoropropylene copolymer and hydroxypropylcellulose are mixed with manganese dioxide to prepare a positive electrode mixture. Then, as will be described later, in a state where the columnar block member 45 made of the positive electrode mixture is disposed in the positive electrode ring 44, the positive electrode material 41 is formed in the positive electrode ring 44 by crushing the block member 45. The method of forming the positive electrode material 41 is not limited to the above, and any method may be used such as forming the positive electrode mixture by filling the positive electrode ring 44 into the positive electrode ring 44 and performing pressure molding, and then heating the molded member. The method may be used.

正極材41には、該正極材41を保持するように、該正極材41の底面及び側面のそれぞれ一部を覆う正極リング44(台座)が装着されている。この正極リング44は、所定の剛性及び導電性を有するステンレス鋼等によって構成されている。正極リング44は、正極材41の側面に接する円筒状の側壁部44aと、側壁部44aの一端側から該側壁部44aの内方に向かって延びて正極材41の底面に接する円環状のフランジ部44bとが一体形成されたものである。このような構成の正極リング44によって、該正極リング44内の正極材41の径方向及び一端側への変形を規制することができる。そして、正極リング44の側壁部44aの他端側にはフランジ部を設けない構成にすることで、正極材41は、放電時に正極リング44の側壁部44aの他端側へ自由に膨張することができる。よって、放電時に、負極材42の厚みが小さくなっても、正極材41は正極リング44に沿って負極材42側へ膨張するため、該正極材41と負極材42とが離間するのを防止できる。   A positive electrode ring 44 (pedestal) is attached to the positive electrode material 41 so as to hold the positive electrode material 41 so as to cover a part of the bottom surface and side surfaces of the positive electrode material 41. The positive ring 44 is made of stainless steel or the like having predetermined rigidity and conductivity. The positive electrode ring 44 includes a cylindrical side wall portion 44 a that contacts the side surface of the positive electrode material 41, and an annular flange that extends from one end side of the side wall portion 44 a toward the inside of the side wall portion 44 a and contacts the bottom surface of the positive electrode material 41. The part 44b is integrally formed. With the positive electrode ring 44 having such a configuration, the deformation of the positive electrode material 41 in the positive electrode ring 44 in the radial direction and one end side can be restricted. The positive electrode material 41 can freely expand to the other end side of the side wall portion 44a of the positive electrode ring 44 during discharge by providing a configuration in which the flange portion is not provided on the other end side of the side wall portion 44a of the positive electrode ring 44. Can do. Therefore, even when the thickness of the negative electrode material 42 is reduced during discharge, the positive electrode material 41 expands toward the negative electrode material 42 along the positive electrode ring 44, thereby preventing the positive electrode material 41 and the negative electrode material 42 from separating. it can.

正極リング44は、溶接等によって正極缶10の底部11に固定されている。これにより、正極リング44が正極缶10の底部11から離れるのを防止でき、該正極リング44に保持された正極材41と正極缶10とをより確実に接触させることができる。正極リング44の詳しい構成については後述する。   The positive electrode ring 44 is fixed to the bottom 11 of the positive electrode can 10 by welding or the like. Thereby, it can prevent that the positive electrode ring 44 leaves | separates from the bottom part 11 of the positive electrode can 10, and the positive electrode material 41 hold | maintained at this positive electrode ring 44 and the positive electrode can 10 can be made to contact more reliably. A detailed configuration of the positive electrode ring 44 will be described later.

セパレータ43は、ポリブチレンテレフタート製の繊維を素材とする不織布を用いて構成される。このセパレータ43は、扁平形電池1内で非水電解液によって含浸されている。なお、セパレータ43の厚みは、例えば、約0.3〜0.4mm程度である。   The separator 43 is configured using a non-woven fabric made of a polybutylene terephthalate fiber. The separator 43 is impregnated with a non-aqueous electrolyte in the flat battery 1. In addition, the thickness of the separator 43 is about 0.3-0.4 mm, for example.

非水電解液は、プロピレンカーボネイトと1,2−ジメトキシエタンとを混合した溶液にLiClOを溶解した溶液である。 The non-aqueous electrolyte is a solution in which LiClO 4 is dissolved in a solution obtained by mixing propylene carbonate and 1,2-dimethoxyethane.

上述のような構成の扁平形電池1は、例えば、車両用のタイヤ空気圧センサの電力供給源として用いられる。このタイヤ空気圧センサは、例えばタイヤに設置される。   The flat battery 1 having the above-described configuration is used as a power supply source of a tire pressure sensor for a vehicle, for example. This tire pressure sensor is installed in a tire, for example.

このようなタイヤ空気圧センサに扁平形電池1を用いると、該扁平形電池1は、車両走行時にタイヤが受ける衝撃をほぼそのまま受けることになる。そのため、扁平形電池1は強い衝撃を受けることになる。そうすると、扁平形電池1内の正極リング44に保持されていた正極材41が該正極リング44から外れる可能性がある。正極材41が正極リング44から外れると、正極材41と正極缶10との接触が不安定になり、扁平形電池1の内部抵抗が増大する。そのため、本実施形態では、扁平形電池1の正極リング44を以下のような構成とする。   When the flat battery 1 is used for such a tire pressure sensor, the flat battery 1 receives the impact received by the tire when the vehicle travels as it is. Therefore, the flat battery 1 receives a strong impact. Then, the positive electrode material 41 held by the positive electrode ring 44 in the flat battery 1 may be detached from the positive electrode ring 44. When the positive electrode material 41 is detached from the positive electrode ring 44, the contact between the positive electrode material 41 and the positive electrode can 10 becomes unstable, and the internal resistance of the flat battery 1 increases. Therefore, in this embodiment, the positive electrode ring 44 of the flat battery 1 is configured as follows.

なお、本実施形態では、扁平形電池1の適用例として、タイヤ空気圧センサを挙げているが、これ以外の機器の電力供給源として扁平形電池1を用いてもよい。   In the present embodiment, a tire pressure sensor is cited as an application example of the flat battery 1, but the flat battery 1 may be used as a power supply source for other devices.

(正極リングの構成)
正極リング44の詳しい構成を図1及び図2を用いて以下で説明する。
(Configuration of positive ring)
A detailed configuration of the positive electrode ring 44 will be described below with reference to FIGS. 1 and 2.

図1に示すように、正極リング44は、円筒状の側壁部44aと、該側壁部44aの一端側から内方に向かって延びるフランジ部44bとを有している。これらの側壁部44a及びフランジ部44bは、一体に形成されている。すなわち、正極リング44は、有底円筒状の部材の底面に開口部が形成されたような形状を有している。正極リング44をこのような形状にすることで、内部に正極材41を保持することができる。   As shown in FIG. 1, the positive electrode ring 44 includes a cylindrical side wall portion 44 a and a flange portion 44 b extending inward from one end side of the side wall portion 44 a. The side wall portion 44a and the flange portion 44b are integrally formed. That is, the positive electrode ring 44 has a shape in which an opening is formed on the bottom surface of a bottomed cylindrical member. By making the positive electrode ring 44 into such a shape, the positive electrode material 41 can be held inside.

正極リング44の側壁部44aには、該正極リング44の内方側に位置する内面に、該正極リング44の内方に向かって突出する突出部44c(係止部)が設けられている。この突出部44cは、正極リング44の側壁部44aに周方向に複数(本実施形態では6箇所)設けるのが好ましいが、該側壁部44aに1つだけ設けてもよい。なお、正極リング44の側壁部44aに、複数の突出部44cを設ける場合、該側壁部44aの周方向に均等に突出部44cを設けるのが好ましい。また、正極リング44の側壁部44aを軸線方向に潰して該側壁部44aの内周面に全周に亘って突出部を形成してもよい。   The side wall portion 44 a of the positive electrode ring 44 is provided with a protruding portion 44 c (an engaging portion) that protrudes inward of the positive electrode ring 44 on the inner surface located on the inner side of the positive electrode ring 44. It is preferable to provide a plurality of protrusions 44c in the circumferential direction on the side wall 44a of the positive electrode ring 44 (six locations in the present embodiment), but only one may be provided on the side wall 44a. In addition, when providing the some protrusion part 44c in the side wall part 44a of the positive electrode ring 44, it is preferable to provide the protrusion part 44c uniformly in the circumferential direction of this side wall part 44a. Further, the side wall portion 44a of the positive electrode ring 44 may be crushed in the axial direction to form a protruding portion over the entire circumference on the inner peripheral surface of the side wall portion 44a.

突出部44cは、正極リング44の側壁部44aの一部を、該正極リング44の内方へ押し込むことにより形成される。すなわち、本実施形態の場合には、側壁部44aの外周面の周方向6箇所に、突出部44cを形成するために側壁部44aの外周面が内方(側壁部44aの厚み方向)に押し込まれた凹部44dが形成されている。   The protruding portion 44 c is formed by pushing a part of the side wall portion 44 a of the positive electrode ring 44 inward of the positive electrode ring 44. That is, in the case of this embodiment, the outer peripheral surface of the side wall 44a is pushed inward (in the thickness direction of the side wall 44a) in order to form the protruding portion 44c at six locations in the peripheral direction of the outer peripheral surface of the side wall 44a. A recessed portion 44d is formed.

上述の凹部44dは、例えば、正極リング44の内側にピン状のジグを挿入した状態で、該正極リング44の側壁部44aの外周面を該側壁部44aの厚み方向に押圧することにより、形成される。これにより、正極リング44の側壁部44aに、該正極リング44の内方に向かって突出する突出部44cが形成される。なお、前記ジグの外表面には、凹部44dに対応する窪みが形成されていてもよい。これにより、正極リング44の側壁部44aに凹部44dを容易に形成できる。   The concave portion 44d is formed, for example, by pressing the outer peripheral surface of the side wall portion 44a of the positive electrode ring 44 in the thickness direction of the side wall portion 44a in a state where a pin-shaped jig is inserted inside the positive electrode ring 44. Is done. As a result, a protruding portion 44 c that protrudes inward of the positive electrode ring 44 is formed on the side wall portion 44 a of the positive electrode ring 44. In addition, the hollow corresponding to the recessed part 44d may be formed in the outer surface of the said jig. Thereby, the concave portion 44 d can be easily formed in the side wall portion 44 a of the positive electrode ring 44.

図3に示すように、突出部44cは、突出高さが、後述するように、正極リング44内で円柱状のブロック部材45を正極リング44内で軸線方向に押し潰す際の該ブロック部材45の半径の変形量(軸線方向に直交する方向の変形量)よりも小さくなるように形成されている。なお、前記半径の変形量は、図3における一点鎖線と実線との径方向の間隔に対応するが、この図3は、突出部44cを分かり易く図示するために、実際の寸法比率よりも側壁部44aの厚みや突出部44cのサイズを大きく図示している。   As shown in FIG. 3, the protrusion 44 c has a protrusion height when the cylindrical block member 45 is crushed in the positive ring 44 in the axial direction in the positive ring 44, as will be described later. It is formed so as to be smaller than the deformation amount of the radius (the deformation amount in the direction orthogonal to the axial direction). Note that the amount of deformation of the radius corresponds to the radial distance between the alternate long and short dash line and the solid line in FIG. 3, but FIG. 3 shows the side wall rather than the actual dimensional ratio in order to easily show the protrusion 44 c. The thickness of the portion 44a and the size of the protruding portion 44c are greatly illustrated.

ここで、正極リング44内に正極材41を装着する場合、例えば、正極リング44の側壁部44aに凹部44d及び突出部44cを形成した後に、軸線方向が側壁部44の高さ方向と一致するように正極リング44内にブロック部材45を配置する。そして、該正極リング44内でブロック部材45を軸線方向に押し潰すことにより正極材41を正極リング44内に装着する。上述のように、正極リング44の側壁部44aに設ける突出部44cを、突出高さがブロック部材45の半径の変形量よりも小さくなるように形成することで、該突出部44cの突出端部がブロック部材45と干渉するのを防止できる。   Here, when the positive electrode material 41 is mounted in the positive electrode ring 44, for example, the axial direction coincides with the height direction of the side wall portion 44 after the concave portion 44 d and the protruding portion 44 c are formed in the side wall portion 44 a of the positive electrode ring 44. Thus, the block member 45 is disposed in the positive electrode ring 44. Then, the positive electrode material 41 is mounted in the positive electrode ring 44 by crushing the block member 45 in the axial direction in the positive electrode ring 44. As described above, the protruding portion 44c provided on the side wall portion 44a of the positive electrode ring 44 is formed such that the protruding height is smaller than the deformation amount of the radius of the block member 45, whereby the protruding end portion of the protruding portion 44c. Can be prevented from interfering with the block member 45.

具体的には、突出部44cは、その突出高さが、ブロック部材45の直径に対して0.5〜5%の値であるのが好ましい。なお、一般的な正極材を構成するペレット状のブロック部材であれば、押し潰した際の直径の変形量は0.5%以上になる。また、上限の5%は、ブロック部材の直径に対する一般的な正極リングの厚み寸法の比率である。   Specifically, the protrusion 44 c preferably has a protrusion height of 0.5 to 5% with respect to the diameter of the block member 45. In addition, if it is a pellet-shaped block member which comprises a general positive electrode material, the deformation amount of the diameter at the time of crushing will be 0.5% or more. The upper limit of 5% is the ratio of the thickness dimension of a general positive electrode ring to the diameter of the block member.

上述のように、側壁部44aに内方に突出する突出部44cが設けられた正極リング44内にブロック部材45を配置して、該ブロック部材45を押し潰すことにより、正極材41の外周側を突出部44cに食い込ませることができる。これにより、正極材41を正極リング44の側壁部44aに対してより確実に係止することができる。   As described above, the block member 45 is disposed in the positive electrode ring 44 provided with the projecting portion 44c projecting inwardly on the side wall portion 44a, and the block member 45 is crushed, whereby the outer peripheral side of the positive electrode material 41 is obtained. Can bite into the protrusion 44c. Thereby, the positive electrode material 41 can be more reliably locked to the side wall portion 44 a of the positive electrode ring 44.

したがって、上述の構成により、扁平形電池1に大きな衝撃が加わった場合でも、正極リング44の側壁部44aに設けられた突出部44cによって正極材41をより確実に保持することができる。よって、扁平形電池1に大きな衝撃が加わった場合に、正極リング44から正極材41が外れて該扁平形電池1の内部抵抗が大きくなるのを防止できる。   Therefore, with the above-described configuration, even when a large impact is applied to the flat battery 1, the positive electrode material 41 can be more reliably held by the protruding portion 44 c provided on the side wall portion 44 a of the positive electrode ring 44. Therefore, when a large impact is applied to the flat battery 1, it can be prevented that the positive electrode material 41 is detached from the positive electrode ring 44 and the internal resistance of the flat battery 1 is increased.

(実施形態1の効果)
以上より、この実施形態によれば、正極材41を保持する正極リング44の側壁部44aに、内方に向かって突出する突出部44cを設けたため、扁平形電池1に衝撃が加わった場合でも、正極リング44から正極材41が外れるのを防止できる。これにより、正極リング44から正極材41が外れることによる扁平形電池1の内部抵抗の増大を防止できる。
(Effect of Embodiment 1)
As described above, according to this embodiment, since the projecting portion 44 c projecting inward is provided on the side wall portion 44 a of the positive electrode ring 44 that holds the positive electrode material 41, even when an impact is applied to the flat battery 1. The positive electrode material 41 can be prevented from coming off from the positive electrode ring 44. Thereby, an increase in the internal resistance of the flat battery 1 due to the positive electrode material 41 being detached from the positive electrode ring 44 can be prevented.

また、突出部44cは、正極リング44の側壁部44aの外周面を該側壁部44aの厚み方向に押圧して凹部44dを設けることにより形成される。これにより、正極リング44の側壁部44aに突出部44cを容易に形成することができる。   The protruding portion 44c is formed by pressing the outer peripheral surface of the side wall portion 44a of the positive electrode ring 44 in the thickness direction of the side wall portion 44a to provide a concave portion 44d. Thereby, the protruding portion 44 c can be easily formed on the side wall portion 44 a of the positive electrode ring 44.

さらに、突出部44cは、その突出高さが、押し潰されるブロック部材45の半径の変形量よりも小さい。これにより、ブロック部材45を正極リング44内に配置する際に、該ブロック部材45と突出部44cとが干渉するのを防止できる。また、上述の構成にすることで、正極リング44内でブロック部材45を押し潰して正極材41を形成することが可能になるため、該正極材41の外周側に突出部44cを食い込ませることが可能になる。これにより、正極材41を正極リング44の側壁部44aにより確実に係止することができる。   Furthermore, the protrusion 44c has a protrusion height smaller than the deformation amount of the radius of the block member 45 to be crushed. Thereby, when the block member 45 is disposed in the positive electrode ring 44, it is possible to prevent the block member 45 and the protruding portion 44c from interfering with each other. Further, with the above-described configuration, the block member 45 can be crushed in the positive electrode ring 44 to form the positive electrode material 41, so that the protruding portion 44 c is bitten on the outer peripheral side of the positive electrode material 41. Is possible. Thereby, the positive electrode material 41 can be reliably locked by the side wall portion 44 a of the positive electrode ring 44.

[実施形態2]
図4に、本発明の実施形態2に係る扁平形電池の正極リング51の係止部分の構成を示す。この実施形態2の構成は、扁平形電池の正極リング51の内周面に凹部51bを設けた点で実施形態1の構成と異なる。この実施形態2において、実施形態1の構成と同一の部分には同一の符号を付し、以下で異なる部分についてのみ説明する。
[Embodiment 2]
In FIG. 4, the structure of the latching | locking part of the positive electrode ring 51 of the flat battery which concerns on Embodiment 2 of this invention is shown. The configuration of the second embodiment is different from the configuration of the first embodiment in that a recess 51b is provided on the inner peripheral surface of the positive electrode ring 51 of the flat battery. In the second embodiment, the same parts as those in the first embodiment are denoted by the same reference numerals, and only different parts will be described below.

具体的には、図4に示すように、正極リング51の側壁部51aには、内周面に凹部51b(係止部)が形成されている。この凹部51bも、上述の実施形態1と同様、側壁部51aの内周面に周方向に等間隔で複数(例えば6箇所)設けるのが好ましい。なお、この実施形態でも、実施形態1と同様、側壁部51aの内周面に凹部51bを1つだけ設けてもよい。また、側壁部51aの内周面全周に亘って凹部を設けてもよい。   Specifically, as shown in FIG. 4, the side wall 51 a of the positive ring 51 has a recess 51 b (locking portion) formed on the inner peripheral surface. As in the first embodiment, it is preferable to provide a plurality of recesses 51b (for example, six locations) at equal intervals in the circumferential direction on the inner peripheral surface of the side wall 51a. In this embodiment as well, like the first embodiment, only one recess 51b may be provided on the inner peripheral surface of the side wall 51a. Moreover, you may provide a recessed part over the inner peripheral surface whole periphery of the side wall part 51a.

上述の凹部51bは、正極リング51の側壁部51aの内周面を該側壁部51aの厚み方向に押圧することによって形成される。そのため、該側壁部51aの外周面には突出部51cが形成される。なお、側壁部51aの内周面全周に亘って凹部を設ける場合には、正極リング51の側壁部51aを軸線方向に潰してもよい。   The above-described recess 51b is formed by pressing the inner peripheral surface of the side wall 51a of the positive electrode ring 51 in the thickness direction of the side wall 51a. Therefore, a protrusion 51c is formed on the outer peripheral surface of the side wall 51a. In addition, when providing a recessed part over the inner peripheral surface whole periphery of the side wall part 51a, you may crush the side wall part 51a of the positive electrode ring 51 in an axial direction.

上述の構成により、実施形態1と同様、正極リング51内に円柱状のブロック部材を配置して該ブロック部材を軸線方向に押し潰すことで、正極リング51の側壁部51aに設けられた凹部51a内に正極材52の一部が位置する。すなわち、正極リング51内では、突出部52aを有する正極材52が形成される。この突出部52aが、正極リング51の側壁部51aの凹部51bに係止されることで、該正極リング51から正極材52が外れにくくなる。   With the above-described configuration, as in the first embodiment, a cylindrical block member is disposed in the positive electrode ring 51, and the block member is crushed in the axial direction, whereby the concave portion 51a provided in the side wall portion 51a of the positive electrode ring 51. A part of the positive electrode material 52 is located inside. That is, in the positive electrode ring 51, the positive electrode material 52 having the protruding portion 52a is formed. The protruding portion 52 a is locked to the concave portion 51 b of the side wall portion 51 a of the positive electrode ring 51, so that the positive electrode material 52 is not easily detached from the positive electrode ring 51.

しかも、上述の構成では、正極リング51に内方に突出する部分がないため、該正極リング51内にブロック部材を配置する際に、該ブロック部材と正極リング51とが干渉するのを防止できる。   In addition, in the above-described configuration, since the positive ring 51 does not have a portion protruding inward, it is possible to prevent the block member and the positive ring 51 from interfering when the block member is disposed in the positive ring 51. .

(実施形態2の効果)
以上より、この実施形態によれば、上述の実施形態1と同様、扁平形電池に衝撃が加わった場合でも、正極材52が正極リング51から外れるのを抑制することができる。これにより、正極材52が正極リング51から外れることによる扁平形電池の内部抵抗の増大を防止できる。
(Effect of Embodiment 2)
As described above, according to this embodiment, it is possible to prevent the positive electrode material 52 from coming off the positive electrode ring 51 even when an impact is applied to the flat battery, as in the first embodiment. Thereby, the increase in the internal resistance of the flat battery due to the positive electrode material 52 being detached from the positive electrode ring 51 can be prevented.

また、本実施形態のように、正極リング51の側壁部51aの内周面に凹部51bを有する構成とすることで、正極リング51内へのブロック部材の配置が容易になり、該正極リング51内に正極材52を容易に装着することができる。   Further, as in the present embodiment, the configuration having the concave portion 51b on the inner peripheral surface of the side wall portion 51a of the positive electrode ring 51 facilitates the arrangement of the block member in the positive electrode ring 51, and the positive electrode ring 51. The positive electrode material 52 can be easily mounted therein.

[実施形態3]
図5に、本発明の実施形態3に係る扁平形電池の正極リング61の係止部分の構成を示す。この実施形態3の構成は、正極リング61の側壁部61aに開口部61bを設けた点で上述の実施形態1、2の構成とは異なる。この実施形態3において、実施形態1、2の構成と同一の部分には同一の符号を付し、以下で異なる部分についてのみ説明する。
[Embodiment 3]
In FIG. 5, the structure of the latching | locking part of the positive electrode ring 61 of the flat battery which concerns on Embodiment 3 of this invention is shown. The configuration of the third embodiment differs from the configurations of the first and second embodiments described above in that an opening 61b is provided in the side wall portion 61a of the positive electrode ring 61. In the third embodiment, the same parts as those in the first and second embodiments are denoted by the same reference numerals, and only different parts will be described below.

具体的には、図5に示すように、正極リング61の側壁部61aには、開口部61b(係止部)が形成されている。この開口部61bも、上述の実施形態1と同様、側壁部51aの周方向に複数(例えば6箇所)設けるのが好ましい。なお、この実施形態でも、実施形態1と同様、側壁部61aの内周面に開口部61bを1つだけ設けてもよい。   Specifically, as shown in FIG. 5, an opening 61 b (locking portion) is formed in the side wall portion 61 a of the positive electrode ring 61. It is preferable to provide a plurality (for example, six locations) of the openings 61b in the circumferential direction of the side wall 51a as in the first embodiment. In this embodiment as well, as in the first embodiment, only one opening 61b may be provided on the inner peripheral surface of the side wall 61a.

正極リング61の側壁部61aに上述のような開口部61bを設けることにより、上述の実施形態1と同様に正極リング61内でブロック部材を押し潰して正極材62を形成する際に、開口部61b内に正極材62の突出部62aが形成される。これにより、正極材61の突出部62aが、正極リング61の側壁部61aの開口部61bの周縁部分に係止され、正極材61が正極リング61から外れにくくなる。   By providing the opening 61b as described above in the side wall portion 61a of the positive electrode ring 61, when the block member is crushed in the positive electrode ring 61 to form the positive electrode material 62 as in the first embodiment, the opening portion is formed. A protrusion 62a of the positive electrode material 62 is formed in 61b. As a result, the protruding portion 62 a of the positive electrode material 61 is locked to the peripheral edge portion of the opening 61 b of the side wall portion 61 a of the positive electrode ring 61, and the positive electrode material 61 is unlikely to be detached from the positive electrode ring 61.

また、上述の実施形態2と同様、上述の構成では、正極リング61に内方に突出する部分がないため、該正極リング61内にブロック部材を配置する際に、正極リング61とブロック部材とが干渉するのを防止できる。   Similarly to the above-described embodiment 2, in the above-described configuration, the positive ring 61 has no portion projecting inward, and therefore when the block member is disposed in the positive ring 61, the positive ring 61 and the block member Can be prevented from interfering.

なお、開口部61bは、側壁部61aの一部に切り込みを設けて外方へ折り曲げることにより形成してもよい。   In addition, you may form the opening part 61b by providing a notch in a part of side wall part 61a, and bending outward.

(実施形態3の効果)
以上より、この実施形態によれば、上述の実施形態1,2と同様、扁平形電池に衝撃が加わった場合でも、正極材62が正極リング61から外れるのを抑制することができる。これにより、正極材62が正極リング61から外れることによる扁平形電池の内部抵抗の増大を防止できる。
(Effect of Embodiment 3)
As described above, according to this embodiment, the positive electrode material 62 can be prevented from coming off from the positive electrode ring 61 even when an impact is applied to the flat battery as in the first and second embodiments. Thereby, an increase in the internal resistance of the flat battery due to the positive electrode material 62 being detached from the positive electrode ring 61 can be prevented.

また、本実施形態のように、正極リング61の側壁部61aに開口部61bを有する構成とすることで、正極リング61内へのブロック部材の配置が容易になり、該正極リング61内に正極材62を容易に形成することができる。   In addition, as in the present embodiment, the configuration in which the side wall 61a of the positive electrode ring 61 has the opening 61b facilitates the arrangement of the block member in the positive electrode ring 61, and the positive electrode ring 61 has the positive electrode in the positive electrode ring 61. The material 62 can be easily formed.

[実施形態4]
図6に、本発明の実施形態4に係る扁平形電池の正極リング71の係止部分の構成を示す。この実施形態4の構成は、正極リング71の側壁部71aの一部が内方に折り曲げられて突出している点で上述の実施形態1〜3の構成とは異なる。この実施形態4において、実施形態1〜3の構成と同一の部分には同一の符号を付し、以下で異なる部分についてのみ説明する。
[Embodiment 4]
In FIG. 6, the structure of the latching | locking part of the positive electrode ring 71 of the flat battery which concerns on Embodiment 4 of this invention is shown. The configuration of the fourth embodiment is different from the configurations of the first to third embodiments in that a part of the side wall 71a of the positive electrode ring 71 is bent inward and protrudes. In this Embodiment 4, the same code | symbol is attached | subjected to the part same as the structure of Embodiment 1-3, and only a different part is demonstrated below.

具体的には、図6に示すように、正極リング71の側壁部71aには、該側壁部71aの一部が正極リング71の内方に突出した突出部71b(係止部)が形成されている。この突出部71bは、側壁部71aの一部に切り込みを設けて、内方へ折り曲げることにより形成される。よって、側壁部71aにおいて、折り曲げられて突出部71bとなる部分には、開口部71c(係止部)が形成される。これらの突出部71b及び開口部71cも、上述の実施形態1と同様、側壁部71aに周方向に複数(例えば6箇所)設けるのが好ましい。なお、この実施形態でも、実施形態1と同様、側壁部71aに突出部71b及び開口部71cを1つずつ設けてもよい。   Specifically, as shown in FIG. 6, the side wall 71 a of the positive electrode ring 71 is formed with a protrusion 71 b (locking portion) in which a part of the side wall 71 a protrudes inward of the positive electrode ring 71. ing. This protrusion 71b is formed by providing a cut in a part of the side wall 71a and bending it inward. Therefore, an opening 71c (locking portion) is formed in a portion of the side wall portion 71a that is bent to become the protruding portion 71b. It is preferable to provide a plurality (for example, six places) of the protrusions 71b and the openings 71c in the circumferential direction on the side wall 71a as in the first embodiment. In this embodiment as well, as in the first embodiment, one protrusion 71b and one opening 71c may be provided on the side wall 71a.

正極リング71の側壁部71aに上述のような突出部71b及び開口部71cを設けることにより、上述の実施形態1と同様に正極リング71内でブロック部材を押し潰して正極材72を形成する際に、正極材72の外周側に突出部71bが食い込むとともに、開口部71c内に正極材72の突出部72aが形成される。これにより、正極材72は、その外周側が突出部71bによって係止されるとともに、突出部72aが正極リング71の側壁部71aの開口部71cの周縁部分に係止される。したがって、正極材72は、正極リング71からより確実に外れにくくなる。   When the protruding portion 71b and the opening 71c as described above are provided on the side wall portion 71a of the positive electrode ring 71, the block member is crushed in the positive electrode ring 71 to form the positive electrode material 72 as in the first embodiment. In addition, the protruding portion 71b bites into the outer peripheral side of the positive electrode material 72, and the protruding portion 72a of the positive electrode material 72 is formed in the opening 71c. As a result, the positive electrode material 72 has its outer peripheral side locked by the protruding portion 71 b, and the protruding portion 72 a is locked by the peripheral portion of the opening 71 c of the side wall portion 71 a of the positive electrode ring 71. Accordingly, the positive electrode material 72 is less likely to be detached from the positive electrode ring 71 more reliably.

(実施形態4の効果)
以上より、この実施形態によれば、扁平形電池に衝撃が加わった場合でも、正極リング71の突出部71b及び正極材72の突出部72aによって、正極材72が正極リング71から外れるのをより確実に防止できる。これにより、正極材72が正極リング71から外れることによる扁平形電池の内部抵抗の増大をより確実に防止できる。
(Effect of Embodiment 4)
As described above, according to this embodiment, even when an impact is applied to the flat battery, the positive electrode material 72 is prevented from being detached from the positive electrode ring 71 by the protruding portion 71b of the positive electrode ring 71 and the protruding portion 72a of the positive electrode material 72. It can be surely prevented. Thereby, the increase in the internal resistance of the flat battery due to the positive electrode material 72 being detached from the positive electrode ring 71 can be prevented more reliably.

[実施形態5]
図7に、本発明の実施形態5に係る扁平形電池の概略構成を示す。この実施形態5の構成は、正極リング81の一部が、ガスケット30と正極缶10との間に狭持されている点で上述の実施形態1の構成とは異なる。この実施形態5において、実施形態1の構成と同一の部分には同一の符号を付し、以下で異なる部分についてのみ説明する。
[Embodiment 5]
FIG. 7 shows a schematic configuration of a flat battery according to Embodiment 5 of the present invention. The configuration of the fifth embodiment is different from the configuration of the first embodiment described above in that a part of the positive electrode ring 81 is sandwiched between the gasket 30 and the positive electrode can 10. In the fifth embodiment, the same parts as those in the first embodiment are denoted by the same reference numerals, and only different parts will be described below.

具体的には、正極リング81は、円筒状の側壁部81aの一端側から径方向外方へ突出するフランジ部81bを有している。このフランジ部81bは、側壁部81aの全周から径方向外方へ突出するように、平面視で略円形の外形を有している。   Specifically, the positive electrode ring 81 has a flange portion 81b that protrudes radially outward from one end side of the cylindrical side wall portion 81a. The flange portion 81b has a substantially circular outer shape in plan view so as to protrude radially outward from the entire circumference of the side wall portion 81a.

フランジ部81bの外周側部分は、ガスケット30のベース部31と正極缶10の底部11との間に挟みこまれている。すなわち、正極缶10の周壁部12と負極缶20の周壁部22とをかしめ固定する際に、正極リング81のフランジ部81bの外周側も一緒に固定される。これにより、正極リング81を正極缶10及び負極缶20に対して固定することができる。   The outer peripheral side portion of the flange portion 81 b is sandwiched between the base portion 31 of the gasket 30 and the bottom portion 11 of the positive electrode can 10. That is, when the peripheral wall portion 12 of the positive electrode can 10 and the peripheral wall portion 22 of the negative electrode can 20 are caulked and fixed, the outer peripheral side of the flange portion 81 b of the positive electrode ring 81 is also fixed together. Thereby, the positive electrode ring 81 can be fixed to the positive electrode can 10 and the negative electrode can 20.

上述のような構成の正極リング81にも、上述の実施形態1と同様、側壁部81aの内周面に、正極リング81の内方に向かって突出する突出部81c(係止部)を設ける。この突出部81cに関する説明は、上述の実施形態と同様なので、詳しい説明を省略する。なお、本実施形態では、正極リング81の側壁部81aに、実施形態1と同様の突出部81cを設けているが、この限りではなく、上述の実施形態2〜4の構成を適用してもよい。   Similarly to the first embodiment, the positive electrode ring 81 configured as described above is provided with a protruding portion 81c (locking portion) that protrudes inward of the positive electrode ring 81 on the inner peripheral surface of the side wall portion 81a. . Since the description regarding this protrusion part 81c is the same as that of the above-mentioned embodiment, detailed description is abbreviate | omitted. In the present embodiment, the protruding portion 81c similar to that of the first embodiment is provided on the side wall 81a of the positive electrode ring 81. However, the present invention is not limited to this, and the configurations of the above-described second to fourth embodiments may be applied. Good.

(実施形態5の効果)
以上より、この実施形態によれば、正極リング81のフランジ部81bを、径方向外方へ突出させるように設けて、ガスケット30と正極缶10の底部11との間に挟み込んだ。これにより、正極リング81を、溶接を用いることなく、正極缶10に対して固定することができる。そして、このような構成においても、実施形態1と同様の突出部81cを設けることにより、実施形態1と同様の作用効果を得ることができる。
(Effect of Embodiment 5)
As described above, according to this embodiment, the flange portion 81 b of the positive electrode ring 81 is provided so as to protrude outward in the radial direction, and is sandwiched between the gasket 30 and the bottom portion 11 of the positive electrode can 10. Thereby, the positive electrode ring 81 can be fixed to the positive electrode can 10 without using welding. Even in such a configuration, the same effects as those of the first embodiment can be obtained by providing the protrusions 81 c similar to those of the first embodiment.

(その他の実施形態)
以上、本発明の実施の形態を説明したが、上述した実施の形態は本発明を実施するための例示に過ぎない。よって、本発明は上述した実施の形態に限定されることなく、その趣旨を逸脱しない範囲内で上述した実施の形態を適宜変形して実施することが可能である。
(Other embodiments)
While the embodiments of the present invention have been described above, the above-described embodiments are merely examples for carrying out the present invention. Therefore, the present invention is not limited to the above-described embodiment, and can be implemented by appropriately modifying the above-described embodiment without departing from the spirit thereof.

前記実施形態1では、正極リング44の側壁部44aの外周面を押圧して凹部44dを形成することにより、該側壁部44aの内周面から内方に向かって突出する突出部44cを形成している。しかしながら、凹部44dを形成することなく側壁部44aの内周面から内方に向かって突出する突出部44cのみを形成してもよい。   In the first embodiment, the concave portion 44d is formed by pressing the outer peripheral surface of the side wall portion 44a of the positive electrode ring 44, thereby forming the protruding portion 44c that protrudes inward from the inner peripheral surface of the side wall portion 44a. ing. However, you may form only the protrusion part 44c which protrudes inward from the internal peripheral surface of the side wall part 44a, without forming the recessed part 44d.

前記実施形態1、2では、正極リング44,51の側壁部44a,51aの内周面に、突出部44cまたは凹部51bを形成している。しかしながら、正極リングの側壁部の内周面に凹凸を設けてもよいし、凹凸を微細化して該側壁部の表面粗さを、正極材41を保持可能な粗さとしてもよい。正極リングの側壁部の内周面上に凹凸を形成する場合には、それらの凹凸が係止部に対応する。また、側壁部の表面粗さを、正極材41を保持可能な粗さとする場合には、当該表面粗さを有する側壁部の内周面が係止部に対応する。   In the said Embodiment 1, 2, the protrusion part 44c or the recessed part 51b is formed in the internal peripheral surface of the side wall parts 44a and 51a of the positive electrode rings 44 and 51. FIG. However, unevenness may be provided on the inner peripheral surface of the side wall portion of the positive electrode ring, or the surface roughness of the side wall portion may be made rough enough to hold the positive electrode material 41 by making the unevenness fine. When unevenness is formed on the inner peripheral surface of the side wall portion of the positive electrode ring, the unevenness corresponds to the locking portion. Moreover, when making the surface roughness of a side wall part into the roughness which can hold | maintain the positive electrode material 41, the internal peripheral surface of the side wall part which has the said surface roughness respond | corresponds to a latching | locking part.

前記各実施形態では、正極缶10及び負極缶20をそれぞれ有底円筒状に形成するとともに、正極リング44,51,61,71,81の側壁部44a,51a,61a,71a,81aを円筒状に形成している。しかしながら、正極缶及び負極缶を有底円筒状以外の有底筒状に形成してもよいし、正極リングの側壁部を円筒以外の筒状に形成してもよい。   In each of the above embodiments, the positive electrode can 10 and the negative electrode can 20 are each formed in a bottomed cylindrical shape, and the side wall portions 44a, 51a, 61a, 71a, 81a of the positive electrode rings 44, 51, 61, 71, 81 are cylindrical. Is formed. However, the positive electrode can and the negative electrode can may be formed in a bottomed cylindrical shape other than the bottomed cylindrical shape, and the side wall portion of the positive electrode ring may be formed in a cylindrical shape other than the cylindrical shape.

前記各実施形態では、係止部の例として、側壁部44a,51a,61a,71a,81aに、突出部44c,71b,81c、凹部51b及び開口部61b,71cを形成している。しかしながら、側壁部に対して正極材を係止できる構成であれば、どのような構成であってもよい。   In each of the embodiments described above, the protruding portions 44c, 71b, 81c, the recess 51b, and the openings 61b, 71c are formed on the side walls 44a, 51a, 61a, 71a, 81a as examples of the locking portions. However, any configuration may be used as long as the positive electrode material can be locked to the side wall portion.

前記各実施形態では、正極材41の正極活物質として二酸化マンガンを含有した材料を用いていて、負極材42の負極活物質として金属リチウムまたはリチウム合金を用いている。しかしながら、正極活物質または負極活物質として機能する材料であれば、これ以外のものを正極材41及び負極材42として用いてもよい。   In each of the above embodiments, a material containing manganese dioxide is used as the positive electrode active material of the positive electrode material 41, and metallic lithium or a lithium alloy is used as the negative electrode active material of the negative electrode material 42. However, any other material that functions as a positive electrode active material or a negative electrode active material may be used as the positive electrode material 41 and the negative electrode material 42.

前記各実施形態では、正極缶10を外装缶としていて、負極缶20を封口缶としているが、逆に正極缶が封口缶で、負極缶が外装缶であってもよい。この場合には、正極材と負極材の配置も逆になるため、負極材を保持する負極リングが外装缶である負極缶に固定される。   In each of the above embodiments, the positive electrode can 10 is used as an outer can and the negative electrode can 20 is used as a sealed can. Conversely, the positive electrode can may be a sealed can and the negative electrode can may be an outer can. In this case, since the arrangement of the positive electrode material and the negative electrode material is reversed, the negative electrode ring holding the negative electrode material is fixed to the negative electrode can which is an outer can.

本発明による扁平形電池は、例えばタイヤ空気圧センサなど、強い衝撃を受ける環境下で使用される機器の電池として利用可能である。   The flat battery according to the present invention can be used as a battery for equipment used in an environment subject to strong impact, such as a tire pressure sensor.

1:扁平形電池、10:正極缶(外装缶)、20:負極缶(封口缶)、40:発電要素、41,52,62,72:正極材、42:負極材、44,51,61,71,81:正極リング(台座)、44a,51a,61a,71a,81a:側壁部、44c,71b,81c:突出部(係止部)、45:ブロック部材、51b:凹部(係止部)、61b,71c:開口部(係止部) 1: flat battery, 10: positive electrode can (exterior can), 20: negative electrode can (sealing can), 40: power generation element, 41, 52, 62, 72: positive electrode material, 42: negative electrode material, 44, 51, 61 , 71, 81: Positive electrode ring (pedestal), 44a, 51a, 61a, 71a, 81a: Side wall portion, 44c, 71b, 81c: Projection portion (locking portion), 45: Block member, 51b: Recessed portion (locking portion) ), 61b, 71c: Opening portion (locking portion)

Claims (5)

有底筒状の外装缶と、
前記外装缶の開口を覆うように配置される封口缶と、
前記外装缶と封口缶との間に配置される正極材及び負極材と、
前記正極材及び負極材のいずれか一方の部材を保持しつつ前記外装缶の内面上に固定される台座と、を備え、
前記台座は、前記一方の部材の一部を覆う側壁部を有し、
前記側壁部には、前記一方の部材を保持するための係止部が少なくとも一つ設けられている、扁平形電池。
A bottomed cylindrical outer can,
A sealing can arranged to cover the opening of the outer can;
A positive electrode material and a negative electrode material disposed between the outer can and the sealing can;
A pedestal fixed on the inner surface of the outer can while holding any one member of the positive electrode material and the negative electrode material,
The pedestal has a side wall covering a part of the one member,
A flat battery, wherein the side wall is provided with at least one engaging portion for holding the one member.
請求項1に記載の扁平形電池において、
前記係止部は、前記台座の側壁部における台座内方側の面に設けられた突出部及び凹部の少なくとも一方からなり、
前記一方の部材は、その外周側で前記係止部と係合するように前記台座内に配置されている、扁平形電池。
The flat battery according to claim 1,
The locking portion is composed of at least one of a protruding portion and a recessed portion provided on the surface on the pedestal inward side of the side wall portion of the pedestal,
The one member is a flat battery arranged in the pedestal so as to engage with the engaging portion on the outer peripheral side thereof.
請求項2に記載の扁平形電池において、
前記係止部は、前記台座の側壁部をその厚み方向に変形させることにより形成される、扁平形電池。
The flat battery according to claim 2,
The locking portion is a flat battery formed by deforming a side wall portion of the pedestal in a thickness direction thereof.
請求項2または3に記載の扁平形電池において、
前記一方の部材は、軸線方向に延びる柱状のブロック部材を、該軸線方向が台座の側壁部の高さ方向と一致するように該台座内に配置した状態で、該軸線方向に押し潰すことにより、前記台座内に装着され、
前記突出部は、その突出高さが、前記ブロック部材を押し潰したときの該ブロック部材の前記軸線方向と直交する方向への変形量よりも小さい、扁平形電池。
The flat battery according to claim 2 or 3,
The one member is formed by crushing a columnar block member extending in the axial direction in the axial direction in a state where the block is disposed in the pedestal so that the axial direction coincides with the height direction of the side wall of the pedestal. Mounted in the pedestal,
The projecting portion is a flat battery in which a projecting height is smaller than a deformation amount of the block member in a direction perpendicular to the axial direction when the block member is crushed.
請求項1に記載の扁平形電池において、
前記係止部は、前記台座の側壁部に設けられた開口部によって構成され、
前記台座内に配置される前記一方の部材は、その一部が前記開口部内に位置している、扁平形電池。
The flat battery according to claim 1,
The locking portion is constituted by an opening provided in a side wall portion of the pedestal,
The one member arranged in the pedestal is a flat battery, a part of which is located in the opening.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015002019A (en) * 2013-06-13 2015-01-05 日立マクセル株式会社 Manufacturing apparatus and manufacturing method of flat battery

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JPS5851572U (en) * 1981-10-01 1983-04-07 株式会社ユアサコーポレーション flat battery
JPH03226970A (en) * 1990-01-31 1991-10-07 Matsushita Electric Ind Co Ltd Button alkaline battery
JPH03112871U (en) * 1990-03-05 1991-11-19
JPH0475259A (en) * 1990-07-18 1992-03-10 Sony Corp Organic electrolytic battery
JPH0566874U (en) * 1992-02-13 1993-09-03 富士電気化学株式会社 Flat type non-aqueous electrolyte battery
JPH10255773A (en) * 1997-03-12 1998-09-25 Toshiba Battery Co Ltd Manufacture of flat-type lithium battery and its positive electrode ring
JP2001135308A (en) * 1999-11-09 2001-05-18 Toshiba Battery Co Ltd Flat battery and method for preparing pellet ring of flat battery

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5851572U (en) * 1981-10-01 1983-04-07 株式会社ユアサコーポレーション flat battery
JPH03226970A (en) * 1990-01-31 1991-10-07 Matsushita Electric Ind Co Ltd Button alkaline battery
JPH03112871U (en) * 1990-03-05 1991-11-19
JPH0475259A (en) * 1990-07-18 1992-03-10 Sony Corp Organic electrolytic battery
JPH0566874U (en) * 1992-02-13 1993-09-03 富士電気化学株式会社 Flat type non-aqueous electrolyte battery
JPH10255773A (en) * 1997-03-12 1998-09-25 Toshiba Battery Co Ltd Manufacture of flat-type lithium battery and its positive electrode ring
JP2001135308A (en) * 1999-11-09 2001-05-18 Toshiba Battery Co Ltd Flat battery and method for preparing pellet ring of flat battery

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015002019A (en) * 2013-06-13 2015-01-05 日立マクセル株式会社 Manufacturing apparatus and manufacturing method of flat battery

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