JP2012246000A - Plastic container - Google Patents

Plastic container Download PDF

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Publication number
JP2012246000A
JP2012246000A JP2011118283A JP2011118283A JP2012246000A JP 2012246000 A JP2012246000 A JP 2012246000A JP 2011118283 A JP2011118283 A JP 2011118283A JP 2011118283 A JP2011118283 A JP 2011118283A JP 2012246000 A JP2012246000 A JP 2012246000A
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resin
plastic container
gas barrier
film
container
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JP2011118283A
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JP5938853B2 (en
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Kentaro Uchihashi
健太郎 内橋
Takashi Sano
尊 佐野
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Kyoraku Co Ltd
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Kyoraku Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a thin-walled plastic container having an excellent barrier property.SOLUTION: The plastic container 1 has a multilayered structure including an intermediate layer made of a gass-barrier resin, and inner and outer layers made of a humidity-resistant resin. A barrel part 5 of the plastic container 1 is formed in a thinner wall than other sections constituting the container, and its outer circumferential surface is covered with a gas barrier property film 8. A resin having the barrier property such as an ethylene-vinyl alcohol copolymer resin (EVOH), a nylon resin, or a cyclic olefin, may be used for the gass-barrier resin of the intermediate layer. An olefin resin such as polypropylene (PP) or polyethylene (PE) is favorably used for the humidity-resistant resin of the inner layer and the outer layer 4.

Description

本発明は、バリア性に優れたプラスチック容器に関するものである。   The present invention relates to a plastic container having excellent barrier properties.

従来よりバリア層を有するプラスチック容器として内層および外層にオレフィン系樹脂、中間層としてエチレン−ビニルアルコール共重合体(EVOH)を配置した多層構成の容器が知られている。この内層および外層にオレフィン系樹脂を配置した多層プラスチック容器は耐湿性が高く、比較的軟質で成形性に優れているため、所要の形状にブロー成形しやすく、各種食品、飲料または薬液用の容器として用いられている。   Conventionally, as a plastic container having a barrier layer, a container having a multilayer structure in which an olefin resin is disposed in an inner layer and an outer layer and an ethylene-vinyl alcohol copolymer (EVOH) is disposed as an intermediate layer is known. This multi-layer plastic container with olefin resin in the inner and outer layers has high moisture resistance, is relatively soft and has excellent moldability, so it can be easily blow-molded into the required shape, and is a container for various foods, beverages or chemicals It is used as.

また、バリア性を向上させた容器としては、たとえば引用文献1には無機質薄膜からなるガスバリア性薄膜を容器本体の全面に設けたプラスチック製容器が開示されている。また引用文献2には、プラスチックフィルムに無機化合物の薄膜層を設けたバリア性の高いフィルムを積層したバリア性の高いカップが開示されている。
特許第4448241号公報 特許第3690089号公報
As a container having improved barrier properties, for example, cited document 1 discloses a plastic container in which a gas barrier thin film made of an inorganic thin film is provided on the entire surface of the container body. Reference 2 discloses a cup having a high barrier property in which a film having a high barrier property in which a thin film layer of an inorganic compound is provided on a plastic film.
Japanese Patent No. 4448241 Japanese Patent No. 3690089

ところで、近年では、その環境に対する負荷を低減させることと低廉化を主な目的として、プラスチックの使用量を減らして薄肉化し軽量化することが行なわれている。しかし、薄肉化にともなってバリア性も含め、容器自体の各種物性が低下することの問題も生じている。   By the way, in recent years, for the main purpose of reducing the burden on the environment and reducing the cost, the amount of plastic used is reduced to make it thinner and lighter. However, there is a problem that various physical properties of the container itself, including the barrier property, are reduced as the thickness is reduced.

そこで本発明は、バリア性に優れた薄肉なプラスチック容器を提供することを目的とする。   Then, an object of this invention is to provide the thin plastic container excellent in barrier property.

本発明のプラスチック容器は、請求項1に記載するように、胴部は容器を構成する他の部分より薄肉に形成されており、前記胴部の外周面をガスバリア性フィルムで被覆されていることを特徴とするものである。   In the plastic container of the present invention, as described in claim 1, the body portion is formed thinner than other portions constituting the container, and the outer peripheral surface of the body portion is covered with a gas barrier film. It is characterized by.

本発明によれば、バリア性に優れ、薄肉で軽量なプラスチック容器を得ることができる。   According to the present invention, it is possible to obtain a plastic container which is excellent in barrier properties, thin and lightweight.

また、多層構成とし、中間層にガスバリア性樹脂を配置することにより、ガスバリア性を有するフィルムに欠損部が生じてもそれを補うことができ、安定したバリア性能を備えることができる。   Further, by adopting a multi-layer structure and disposing a gas barrier resin in the intermediate layer, even if a defect portion is generated in the gas barrier film, it can be compensated for, and stable barrier performance can be provided.

本発明に係るプラスチック容器1はブロー成形されたものであり、主に化粧品および医療容器として用いられるものである。このプラスチック容器1は、ガスバリア性樹脂からなる中間層2と、耐湿性樹脂からなる内層3および外層4とを備えた多層構造である。中間層2のガスバリア性樹脂としてはエチレン−ビニルアルコール共重合樹脂(EVOH)、ナイロン樹脂、環状オレフィンなどバリア性を有する樹脂を用いることができる。また、内層3および外層4の耐湿性樹脂としてはポリプロピレン(PP)またはポリエチレン(PE)などのオレフィン系樹脂が好適に用いられる。   The plastic container 1 according to the present invention is blow molded, and is mainly used as a cosmetic and medical container. The plastic container 1 has a multilayer structure including an intermediate layer 2 made of a gas barrier resin, and an inner layer 3 and an outer layer 4 made of a moisture resistant resin. As the gas barrier resin of the mid layer 2, a resin having a barrier property such as ethylene-vinyl alcohol copolymer resin (EVOH), nylon resin, cyclic olefin can be used. As the moisture resistant resin for the inner layer 3 and the outer layer 4, an olefin resin such as polypropylene (PP) or polyethylene (PE) is preferably used.

プラスチック容器1は全体に薄肉であり、その胴部5は容器を構成する他の部分よりさらに薄肉に形成されている。すなわち、胴部5はそれに連なる肩部6および底部7よりさらに薄肉に形成されており、肩部6および底部7は胴部5より相対的に厚肉となっている。ここで、胴部5は、容器の中央部に位置し、曲率の変化する箇所を境とした部分であり、それより上方が肩部6、下方が底部7である。そして胴部5にはその外周面全体にガスバリア性フィルム8を密に巻いてある。ガスバリア性フィルム8は、上述のブロー成形後に、容器と接する内面側に公知の粘着剤を用いることで貼り付けることができる。なお、ブロー成形において、金型キャビティ面に配置しておき、インサート成形することも可能である。胴部5はこのガスバリア性フィルム8による被覆効果により、薄肉であっても高いバリア性を保持することができる。また、フィルムのシワなどなしに貼り付けることが困難な肩部6および底部7は肉厚にすることで全体的に高いバリア性を保持している。なお、肩部6や底部7の厚みはたとえばブロー成形であればパリソン押出時にパリソンの厚みをコントロールすることで厚くすることができる。なお、胴部5はガスバリア性フィルム8を全体にわたって密着させることが容易な形状であることが好ましい(図示の例では円筒形である)。本構成により、可能な限り薄肉で軽量且つバリア性の高いプラスチック容器を得ることができる。なお、本発明は多層容器に限定されるものではなく、単層容器であってもよく、その場合にも肩部6及び底部7は胴部5に比べ厚い形状となっており、胴部5の最大厚みに対して、肩部6及び底部7の最も薄い部分の厚みが1.3倍以上であることが高いバリア性を保持する上で好ましい。   The plastic container 1 is thin as a whole, and its body part 5 is formed to be thinner than other parts constituting the container. That is, the body part 5 is formed thinner than the shoulder part 6 and the bottom part 7 connected to the body part 5, and the shoulder part 6 and the bottom part 7 are relatively thicker than the body part 5. Here, the trunk | drum 5 is located in the center part of a container, and is a part on the boundary where the curvature changes, The upper part is the shoulder part 6, and the lower part is the bottom part 7. A gas barrier film 8 is tightly wound around the entire outer peripheral surface of the body portion 5. The gas barrier film 8 can be attached by using a known pressure-sensitive adhesive on the inner surface side in contact with the container after the above blow molding. In blow molding, it is also possible to insert mold by placing on the mold cavity surface. Due to the covering effect of the gas barrier film 8, the body 5 can maintain high barrier properties even if it is thin. Further, the shoulder portion 6 and the bottom portion 7 which are difficult to be attached without wrinkles of the film are made thick so that the entire barrier property is maintained. In addition, if the thickness of the shoulder part 6 or the bottom part 7 is blow molding, for example, it can be made thick by controlling the thickness of a parison at the time of parison extrusion. In addition, it is preferable that the trunk | drum 5 is a shape where it is easy to adhere | attach the gas barrier film 8 over the whole (it is a cylindrical shape in the example of illustration). With this configuration, a plastic container that is as thin as possible, lightweight, and has high barrier properties can be obtained. The present invention is not limited to a multi-layer container, and may be a single-layer container. In that case, the shoulder 6 and the bottom 7 are thicker than the body 5, and the body 5 It is preferable that the thickness of the thinnest portion of the shoulder portion 6 and the bottom portion 7 is 1.3 times or more with respect to the maximum thickness in order to maintain high barrier properties.

前記ガスバリア性フィルム8は、バリア性を有するフィルムであり、酸素バリア性が必要である場合は、ナイロン、エチレン−エチレンビニルアルコール共重合体、ポリ塩化ビニリデン、ポリエステル等からなるフィルムを使用し、水蒸気バリアが必要である場合、延伸ポリピロピレン、高密度ポリエチレン、ポリ塩化ビニリデン等からなるフィルムを使用すればよい。また、酸素バリアと水蒸気バリアの両方が必要である場合には、前述のフィルムを組み合わせるか、またはポリ塩化ビニリデンをコートした、延伸ナイロン、延伸ポリプロピレン、または延伸ポリエステル、のいずれかのフィルムを使用すればよい。また、プラスチックフィルムの他、前記プラスチックフィルムに酸化珪素、酸化アルミニウム、酸化マグネシウムのような無機化合物の薄膜層を設けたフィルムも用いることができる。中でも、酸化アルミニウムを薄膜上に薄く蒸着させたフィルムを用いることで、バリア性が非常に高く、透明性を損なわずに好適である。ガスバリア性フィルム8はガスバリア性にすぐれていればアルミニウム蒸着フィルムでなくてもよいが、アルミニウム蒸着フィルムはガスバリア性はもとより耐湿性にもすぐれているので最も好適である。またガスバリア性フィルム8は一部ないしは全部を表示ラベルとして所要の表示を施すことも可能である。9は口部であって肩部6に連なった他の部分より厚肉となっている。   The gas barrier film 8 is a film having a barrier property, and when oxygen barrier property is required, a film made of nylon, ethylene-ethylene vinyl alcohol copolymer, polyvinylidene chloride, polyester, or the like is used. When a barrier is required, a film made of stretched polypyropylene, high density polyethylene, polyvinylidene chloride, or the like may be used. If both an oxygen barrier and a water vapor barrier are required, use a stretched nylon, stretched polypropylene, or stretched polyester film coated with polyvinylidene chloride in combination with the aforementioned films. That's fine. In addition to the plastic film, a film in which a thin film layer of an inorganic compound such as silicon oxide, aluminum oxide, or magnesium oxide is provided on the plastic film can also be used. Among these, the use of a film in which aluminum oxide is thinly deposited on a thin film is preferable because the barrier property is very high and the transparency is not impaired. The gas barrier film 8 may not be an aluminum vapor-deposited film as long as it has excellent gas barrier properties, but an aluminum vapor-deposited film is most suitable because it has excellent moisture resistance as well as gas barrier properties. Further, the gas barrier film 8 can be displayed as required by using a part or all of the gas barrier film 8 as a display label. Reference numeral 9 denotes a mouth portion which is thicker than other portions connected to the shoulder portion 6.

ガスバリア性フィルム8は、変形歪みによって折れやシワなどのピンホール状のガスバリア性欠損部の発生が避けられないが、胴部5の中間層2としてガスバリア性を有する樹脂をその他の樹脂でサンドイッチした状態で配置しているため、ガスバリア性フィルム8の欠損部を補うことができ、常に安定したガスバリア性を保持することができる。   In the gas barrier film 8, the occurrence of pinhole-like gas barrier defects such as folds and wrinkles due to deformation strain is unavoidable, but a resin having gas barrier properties is sandwiched with other resins as the intermediate layer 2 of the body portion 5. Since it arrange | positions in the state, the defect | deletion part of the gas barrier film 8 can be supplemented, and the stable gas barrier property can always be hold | maintained.

さらに、ガスバリア性フィルム8がアルミニウム蒸着フィルムのように耐湿性にもすぐれているものでは、中間層2を構成するガスバリア性樹脂が外部からの水蒸気の影響を受けることなく高いガスバリア性を保持することができるので、プラスチック容器1をガスバリア性を損なうことなく一層の薄肉化を図ることが可能となる。   Furthermore, when the gas barrier film 8 is excellent in moisture resistance such as an aluminum vapor deposition film, the gas barrier resin constituting the intermediate layer 2 can maintain high gas barrier properties without being affected by water vapor from the outside. Therefore, it is possible to further reduce the thickness of the plastic container 1 without impairing the gas barrier property.

本発明に係るプラスチック容器の一実施形態を示す断面図である。It is sectional drawing which shows one Embodiment of the plastic container which concerns on this invention. 本発明に係るプラスチック容器の全体斜視図である。1 is an overall perspective view of a plastic container according to the present invention. 図1に示すプラスチック容器の一部拡大断面図である。It is a partially expanded sectional view of the plastic container shown in FIG.

1 プラスチック容器
2 中間層
3 内層
4 外層
5 胴部
6 肩部
7 底部
8 ガスバリア性フィルム
9 口部
DESCRIPTION OF SYMBOLS 1 Plastic container 2 Middle layer 3 Inner layer 4 Outer layer 5 Trunk part 6 Shoulder part 7 Bottom part 8 Gas barrier film 9 Mouth part

Claims (4)

胴部は容器を構成する他の部分より薄肉に形成されており、
前記胴部の外周面をガスバリア性フィルムで被覆されていること
を特徴とするプラスチック容器。
The trunk is formed thinner than other parts that make up the container,
A plastic container, wherein the outer peripheral surface of the body is covered with a gas barrier film.
前記胴部の最大厚みに対して、前記他の部分の最小厚みが1.3倍以上あることを特徴とする請求項1記載のプラスチック容器。   The plastic container according to claim 1, wherein the minimum thickness of the other portion is 1.3 times or more of the maximum thickness of the body portion. ガスバリア性樹脂からなる中間層と、耐湿性樹脂からなる内層および外層とを備えることを特徴とする請求項1または2記載のプラスチック容器。   3. The plastic container according to claim 1, further comprising an intermediate layer made of a gas barrier resin, and an inner layer and an outer layer made of a moisture resistant resin. 前記ガスバリア性フィルムは、酸化アルミニウムを蒸着させたフィルムであることを特徴とする請求項1から3のいずれか1項に記載のプラスチック容器。   The plastic container according to any one of claims 1 to 3, wherein the gas barrier film is a film on which aluminum oxide is deposited.
JP2011118283A 2011-05-26 2011-05-26 Plastic container Expired - Fee Related JP5938853B2 (en)

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JP2012246000A true JP2012246000A (en) 2012-12-13
JP5938853B2 JP5938853B2 (en) 2016-06-22

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61232156A (en) * 1985-04-03 1986-10-16 サントリー株式会社 Plastic vessel with label
JPH02139327A (en) * 1988-11-17 1990-05-29 Ueno Hiroshi Hollow labeled container and its manufacture
JPH07329947A (en) * 1994-06-09 1995-12-19 Toppan Printing Co Ltd Plastic thin-wall container
JPH09132241A (en) * 1995-11-08 1997-05-20 Toppan Printing Co Ltd Composite container
JP2005029211A (en) * 2003-07-04 2005-02-03 Fuji Seal International Inc Gas barrier container
JP2010126231A (en) * 2008-11-28 2010-06-10 Yoshino Kogyosho Co Ltd Bottle
JP2010184999A (en) * 2009-02-12 2010-08-26 Toppan Printing Co Ltd Coating agent and molded product
JP2011042397A (en) * 2009-08-24 2011-03-03 Dainippon Printing Co Ltd Plastic vessel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61232156A (en) * 1985-04-03 1986-10-16 サントリー株式会社 Plastic vessel with label
JPH02139327A (en) * 1988-11-17 1990-05-29 Ueno Hiroshi Hollow labeled container and its manufacture
JPH07329947A (en) * 1994-06-09 1995-12-19 Toppan Printing Co Ltd Plastic thin-wall container
JPH09132241A (en) * 1995-11-08 1997-05-20 Toppan Printing Co Ltd Composite container
JP2005029211A (en) * 2003-07-04 2005-02-03 Fuji Seal International Inc Gas barrier container
JP2010126231A (en) * 2008-11-28 2010-06-10 Yoshino Kogyosho Co Ltd Bottle
JP2010184999A (en) * 2009-02-12 2010-08-26 Toppan Printing Co Ltd Coating agent and molded product
JP2011042397A (en) * 2009-08-24 2011-03-03 Dainippon Printing Co Ltd Plastic vessel

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