JP2012218065A - Flux-cored wire for two-electrode horizontal fillet co2 gas-shielded arc welding - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a flux-cored wire for two-electrode horizontal fillet CO2 gas-shielded arc welding which causes neither an undercut nor an overlap and provides a sound bead through construction under welding conditions of a high current and high speed, and facilitates removal of slag.SOLUTION: The flux-cored wire for gas-shielded arc welding contains in a flux in mass% to the total mass of the wire, 3.0-4.0 mass% of Ti oxide in terms of TiO, 1.0-1.8 mass% of Si oxide in terms of Si, 0.6-1.2 mass% of Zr oxide in terms of ZrO, 0.1-0.5 mass% of Mg, 0.10-0.30% of oxide and a compound of Na and K in terms of NaO and KO in total; 0.05-0.20 mass% of a fluorine compound in terms of F, 0.010-0.030 mass% of Bi and Bi oxide in terms of Bi in total, 0.05-0.3 mass% of Al oxide in terms of AlO, and 0.05-0.3 mass% of Fe oxide in terms of FeO.

Description

The present invention relates to a flux-cored wire for gas shielded arc welding used for horizontal fillet welding of various steel sheets such as mild steel and 490 N / mm class ² high-strength steel. For long electrode fillet CO ₂ gas shielded arc welding with a long, medium-length bead (leg length 6 to 7 mm) that can be obtained under high work efficiency by applying long fillet welding under high current and high speed welding conditions The present invention relates to a flux-cored wire (hereinafter referred to as a flux-cored wire).

  Recently, the fillet leg length standard has been revised to strengthen the structure of the ship, and fillet welding is also used in longage welding performed by the two-electrode, one-pool, high-speed horizontal fillet welding method proposed in Patent Document 1. The leg length of the club is being promoted. Increasing the length of the leg inevitably involves an increase in the amount of welding, and even if the current conditions are the same, it can be handled by reducing the welding speed. There is a strong demand for the development of a flux-cored wire that provides a predetermined leg length under high current welding conditions.

  The problem that arises when forming a long leg with a long leg (leg length of 6-7 mm) under high current and high speed welding conditions (both electrodes with a welding current of 400 A or more and a welding speed of 1.0 m / min or more) is stable between the two electrodes. The hot water pool to be formed becomes unstable due to the strong arc force, and the bead shape is disturbed. In addition, since long welding is generally performed by simultaneous welding on both sides, the amount of heat input to the weld increases under high current welding conditions, resulting in insufficient slag encapsulation, resulting in undercuts and overlaps. The slag peelability is also deteriorated and it is difficult to remove.

  The flux-cored wire for fillet welding described in Patent Document 2 and Patent Document 3 corresponding to an unpainted steel sheet (hereinafter referred to as a black skin steel sheet) with the hot-rolled scale previously proposed by the present inventors attached thereto is used. Then, for example, when trying to construct a leg length of 6 mm at a welding speed of 1.3 m / min, both electrodes must have high current welding conditions of 400 A or more (wire diameter 1.6 mm) in order to ensure the amount of welding. At this time, the hot water pool between the two electrodes was shaken back and forth and was unstable, and the bead shape and slag peelability were poor. In addition, with the flux-cored wire for horizontal fillet described in Patent Document 4, a good fillet bead was obtained even with high current welding conditions with an inorganic zinc primer coated steel sheet, but with a black skin steel sheet, the effect of the wire surface scale Thus, the bead shape and slag peelability were poor, and it was necessary to improve the stability of the hot water pool between the two electrodes and the slag encapsulation.

JP 63-235077 A JP 2006-224178 A JP 2008-212231 A JP 2010-284682 A

In the present invention, horizontal fillet welding of inorganic zinc primer coated steel plate and black skin steel plate is undercut or over even when both poles are applied at a high current of 400 A or higher and high speed welding conditions of 1.0 m / min or higher. An object of the present invention is to provide a flux-cored wire for two-electrode horizontal fillet CO ₂ gas shielded arc welding in which a bead having a healthy leg length of 6 to 7 mm without wrapping is obtained and slag peelability is good.

The gist of the present invention is, in a flux-cored wire for gas shielded arc welding, in which a steel sheath is filled with a flux, in mass% with respect to the total mass of the wire, and the flux is converted to a TiO ₂ equivalent value of Ti oxide: 3.0 to 4.0% SiO ₂ converted value of Si oxide: 1.0 to 1.8% ZrO ₂ conversion value of Zr oxide: 0.6 to 1.2%, however, SiO ₂ in terms of value and ZrO ₂ Total of converted values: 2.4% or less, and (total of SiO ₂ converted value and ZrO ₂ converted value) / TiO ₂ converted value: 0.45 to 0.70, Mg: 0.1 to 0.5% , Na and K oxides and compounds, Na ₂ O equivalent value and K ₂ O equivalent value: 0.10 to 0.30%, fluorine compound F equivalent value: 0.05 to 0.20%, Bi And the sum of Bi equivalents of Bi oxide: 0.010 to 0.030%, Al acid Terms of Al ₂ O ₃ value of goods: from 0.05 to 0.3 percent, FeO converted value of Fe oxide: containing 0.05 to 0.3 percent, further, the sum of the steel sheath and flux, C : 0.04 to 0.08%, Si: 0.3 to 0.7%, Mn: 2.8 to 3.8%, Al: 0.05 to 0.4%, the balance is made of steel It consists of Fe content of outer skin, Fe content of flux iron powder, iron alloy, etc. and inevitable impurities.
Furthermore, the flux, Ni: is .3 to 0.9 percent in the second electrode horizontal fillet CO ₂ gas shielded arc welding flux cored wire also characterized by containing.

According to the two-electrode horizontal fillet gas shielded arc welding flux-cored wire of the present invention, the two-electrode horizontal fillet CO ₂ gas of inorganic zinc primer coated steel plate and black leather plate such as mild steel and 490 N / mm ² grade high strength steel Because shield arc welding is performed on both poles at a high current of 400 A or higher and high speed welding conditions of 1.0 m / min or higher, a sound bead with a leg length of 6 to 7 mm can be obtained, and slag removal work can be greatly reduced. In addition, it is possible to improve the work efficiency as well as improving the quality of the welded portion.

It is a schematic diagram which shows the condition of 2 pool horizontal fillet gas shield arc welding of 1 pool system. It is the schematic diagram which showed the example of the bead-shaped defect generate | occur | produced in 2 electrode horizontal fillet gas shield arc welding.

  FIG. 1 shows the status of a 1 pool type 2-electrode horizontal fillet gas shielded arc welding. It is an essential condition for obtaining a good bead shape to form a stable puddle 3 between the leading electrode wire 1 having the electrode angle θ1 and the trailing electrode wire 2 having the electrode angle θ2. is there. As the welding current is increased in order to obtain a 6 to 7 mm middle leg long bead by high-speed welding of 1 m / min or more, the arc force of the leading electrode wire 1 and the trailing electrode wire 2 becomes stronger. The puddle 3 becomes unstable, and eventually it is impossible to blow away and form a bead. Further, if the slag encapsulation state formed by solidification of the molten pool 4 behind the trailing electrode is insufficient, an undercut 11 and an overlap 12 are generated as shown in FIG. Become. Further, the occurrence of pores 13 due to red rust, adhering moisture, and the primer 8 on the surfaces of the standing plate 9 and the lower plate 10 becomes remarkable. In FIG. 1, 5 indicates molten slag, 6 indicates solidified slag, and 7 indicates weld beads.

First, the inventors of the present invention are the main slag forming agents such as Ti oxide (TiO ₂ equivalent), Si oxidation, for stabilization of the hot water pool, which is the most problematic in the construction of welding conditions at high current. By examining the content and ratio of the material (SiO ₂ converted value) and the Zr oxide (ZrO ₂ converted value), and by increasing the ratio of the Si oxide compared to the conventional flux-cored wire for fillet welding, The hot water pool between the two electrodes can be held stably. In addition, with regard to slag encapsulation, which has become a problem particularly with black-skinned steel sheets, the Zr oxide is increased together with the Si oxide, and further, by reducing the Fe oxide, there is no undercut or overlap, and the bead toe portion A smooth bead shape having good compatibility with the steel plate was obtained. Regarding slag peelability, as the ratio of Si oxide and Zr oxide increased, the slag became dense and hard and difficult to remove, but the slag became brittle at a proper amount of Ti oxide, and a small amount of Bi was added. It was found that removal can be made extremely easy by adding effects such as reduction of Fe oxide.

  Based on these findings, the arc stability to be provided as a flux-cored wire, porosity resistance to primer-coated steel sheets, mechanical properties in weld metal testing, and application to low-temperature steel in detail with various prototype wires The purpose was achieved by studying and limiting the content of each wire component.

  Hereinafter, the reasons for limiting the components of the flux-cored wire of the present invention will be described. Hereinafter, the mass% in the composition is simply described as%.

TiO ₂ conversion value of Ti oxide: 3.0 to 4.0%
Ti oxides such as rutile and titanium slag have the effect of increasing the viscosity of molten slag and improving the slag encapsulation. However, if the TiO ₂ conversion value of the Ti oxide is less than 3.0%, the slag encapsulation is insufficient due to insufficient slag amount and insufficient slag encapsulation, resulting in poor bead shape and slag peelability. . On the other hand, if the TiO ₂ equivalent value exceeds 4.0%, the amount of slag increases and the pore resistance becomes poor. Therefore, the TiO ₂ equivalent value of the Ti oxide is set to 3.0 to 4.0%.

SiO ₂ conversion value of Si oxide: 1.0 to 1.8%
Si oxides such as silica sand and zircon sand have the effect of increasing the viscosity of molten slag, forming a stable puddle between the two electrodes even when applied under high current welding conditions, and improving slag encapsulation. . However, when the SiO ₂ equivalent value of Si oxide is less than 1.0%, the viscosity of the molten slag becomes insufficient and the puddle becomes unstable, the slag encapsulation is insufficient, and the bead shape and slag peelability are low. It becomes defective. On the other hand, if the SiO ₂ conversion value exceeds 1.8%, the slag is hard and difficult to remove, the pore resistance is poor, and the impact toughness of the weld metal test is lowered. Therefore, the SiO ₂ equivalent value of the Si oxide is 1.0 to 1.8%.

ZrO ₂ conversion value of Zr oxide: 0.6 to 1.2%
Zr oxides such as zircon sand and zircon oxide have the effect of suppressing the extreme retreat of the molten pool and making the slag encapsulation sufficient to form a smooth bead even when applied under high current welding conditions. However, if the ZrO ₂ conversion value of the Zr oxide is less than 0.6%, a convex bead with poor conformability at the toe end of the bead is formed, resulting in poor slag removability due to uneven slag encapsulation. On the other hand, when the ZrO ₂ conversion value exceeds 1.2%, the slag is firmly fixed to the bead and it is very difficult to remove the slag. Therefore, the ZrO ₂ conversion value of the Zr oxide is set to 0.6 to 1.2%.

Total of SiO ₂ converted value and ZrO ₂ converted value: 2.4% or less, and (total of SiO ₂ converted value and ZrO ₂ converted value) / TiO ₂ converted value: 0.45 to 0.70
Stability of the puddle between two electrodes and slag separation when the welding is performed under high current welding conditions within the above-described range of the sum of the SiO ₂ equivalent value and the ZrO ₂ equivalent value and the ratio of the TiO ₂ equivalent value and the above sum. It becomes possible to improve the performance. However, if the sum of the SiO ₂ converted value and the ZrO ₂ converted value exceeds 2.4%, the hard and dense slag is in close contact with the bead and cannot be removed unless it is struck with a hammer or the like.

Further, when the (SiO ₂ converted value and ZrO ₂ converted value) / TiO ₂ converted value is less than 0.45, the bead toe portion swells and becomes incompatible with the lower plate. If it exceeds 70, the slag does not become brittle, and the slag is hard and difficult to remove.

Mg: 0.1-0.5%
Mg from Mg and Al—Mg has the effect of reducing the oxygen content of the weld metal and increasing the impact toughness as a strong deoxidizer. However, when Mg is less than 0.1%, impact toughness is lowered. On the other hand, if Mg exceeds 0.5%, the slag encapsulation becomes worse and the bead shape becomes poor. Therefore, Mg is set to 0.1 to 0.5%.

Total of Na ₂ K equivalent value and K ₂ O equivalent value of oxide and compound of Na and K: 0.10 to 0.30%
Na and K from sodium silicate, potassium silicate, cryolite, potassium feldspar and the like have an action of improving droplet transfer as an arc stabilizer. However, if the total of Na ₂ K oxide and compound Na ₂ O equivalent value and K ₂ O equivalent value is less than 0.10%, the arc becomes unstable and a stable sump is not formed between the two electrodes. Slag encapsulation is also insufficient, and the bead shape and slag peelability are poor. On the other hand, if the total of Na ₂ O converted value and K ₂ O converted value exceeds 0.30%, the viscosity of the molten slag is too low, the slag encapsulation is insufficient, and the bead shape and slag peelability are poor. It becomes. Accordingly, the total of Na ₂ O converted values and K ₂ O converted values of Na and K oxides and compounds is 0.10 to 0.30%.

F conversion value of fluorine compound: 0.05 to 0.20%
F from fluorine compounds such as sodium fluoride and potassium silicofluoride has the effect of improving the pore resistance. However, when the F-converted value of the fluorine compound is less than 0.05%, the pore resistance of the inorganic zinc primer steel plate becomes poor. On the other hand, when the F converted value exceeds 0.20%, the viscosity of the molten slag is excessively reduced, and a stable puddle is not formed between the two electrodes, resulting in a poor bead shape. Therefore, the F converted value of the fluorine compound is set to 0.05 to 0.20%.

Sum of Bi equivalent value of Bi and Bi oxide: 0.010 to 0.030%
Bi and Bi oxide have a function of dissociating slag from the bead surface as a slag remover. However, if the sum of Bi and Bi oxides in terms of Bi is less than 0.010%, the slag peelability is poor with the slag fixed to the bead surface. On the other hand, if the sum of Bi converted values exceeds 0.030%, the oxygen content of the weld metal increases and impact toughness decreases. Therefore, the sum of Bi and Bi oxide in terms of Bi is set to 0.010 to 0.030%.

Terms of Al ₂ O ₃ value of Al oxide: .05 to 0.3%
Al oxides such as alumina have the effect of enhancing slag encapsulation as a slag forming agent and improving the bead shape and slag peelability. However, in terms of Al ₂ O ₃ value of Al oxide is less than 0.05%, the effect can not be obtained. On the other hand, if it exceeds 0.3%, uneven slag encapsulation occurs, resulting in poor bead shape and slag peelability. Therefore, the Al ₂ O ₃ equivalent value of the Al oxide is set to 0.05 to 0.3%.

FeO equivalent value of Fe oxide: 0.05-0.3%
Fe oxides such as iron oxide and mill scale have the effect of adjusting the viscosity and solidification temperature of the molten slag and improving the conformability of the toe portion at the lower leg side of the bead. However, when the FeO equivalent value of the Fe oxide is less than 0.05%, the above effect cannot be obtained. On the other hand, if it exceeds 0.3%, the hot water pool between the two electrodes in the case of construction under high current welding conditions becomes unstable, the slag encapsulation is poor, and the bead shape and slag peelability are poor. Accordingly, the FeO equivalent value of the Fe oxide is set to 0.05 to 0.3%.

C: 0.04 to 0.08%
In order to obtain the weld metal strength and impact toughness required for the welded structure, C is 0.04 to 0.08% in total of the steel outer shell and the flux. When C is less than 0.04%, impact toughness is low. On the other hand, if C exceeds 0.08%, the strength increases and impact toughness decreases. The C of the flux is C containing a trace amount of iron alloy powder such as Fe-Si, Fe-Mn, and Fe-Si-Mn, or C powder.

Si: 0.3-0.7%
If the total of the steel outer shell and the flux is less than 0.3%, the bead shape and slag peelability are poor. On the other hand, if Si exceeds 0.7%, the strength of the weld metal increases and impact toughness decreases. The Si of the flux is Si from metal Si, Fe—Si, Fe—Si—Mn, and the like.

Mn: 2.8 to 3.8%
In order to obtain the strength and impact toughness of the weld metal, Mn is also 2.8 to 3.8% in total of the steel outer shell and the flux. When Mn is less than 2.8%, impact toughness is lowered. On the other hand, if Mn exceeds 3.8%, the strength increases and impact toughness decreases. The Mn of the flux is Mn from metal Mn, Fe—Mn, Fe—Si—Mn and the like.

Al: 0.05 to 0.4%
Al has a function of reducing the oxygen content of the weld metal and increasing the impact toughness as a strong deoxidizer, but the above effect cannot be obtained when the total amount of the steel shell and the flux is less than 0.05%. On the other hand, if it exceeds 0.4%, the strength of the weld metal increases and the impact toughness decreases. The Al in the flux is Al from metal Al, Fe—Al, Al—Mg, or the like.

Ni: 0.3-0.9%
Ni from Ni and Fe-Ni, etc. is contained in a flux-cored wire used for construction of a welded structure requiring low temperature impact toughness (test temperature -20 ° C) of the weld metal to be contained in an amount of 0.3 to 0.9%. Thus, stable impact toughness can be obtained. However, when Ni is less than 0.3%, variations in absorbed energy are recognized. On the other hand, if Ni exceeds 0.9%, high-temperature horizontal fillet welding with high current tends to cause hot cracks in the bead.

The reasons for limiting the constituent requirements of the flux-cored wire of the present invention have been described above. The balance is the Fe content of the steel outer shell, the Fe content of the flux iron powder, the iron alloy, etc. (excluding Fe of Fe oxide) And inevitable impurities.
As for the steel outer shell, mild steel with good wire drawing workability after flux filling is optimal. Furthermore, C with 0.01 to 0.03% is effective in reducing spatter generation and reducing fume. It is. The wire diameter is preferably 1.4 to 1.6 mm, which is general for two-electrode welding, and the flux filling ratio with respect to the total mass of the wire is preferably about 13 to 20% in consideration of high weldability and productivity.

  In addition, the cross-sectional shape of the wire may be either seamless, caulking, or butt-type as with commercially available flux-cored wires, but the seamless type with Cu plating on the wire surface has less wear on the welding tip and long arc stability. Can continue during operation. The amount of hydrogen and the amount of nitrogen contained in the flux-cored wire are preferably set to 40 ppm or less with respect to the total mass of the wire so as not to lower the pore resistance and impact toughness, respectively.

  Although it is effective to intentionally add S such as FeS as a slag remover, if S exceeds 0.030%, the slag encapsulation becomes insufficient and the bead shape becomes poor. Addition of B is extremely effective for stabilizing the impact toughness of the weld metal test. However, if B exceeds 0.0080%, the bead is hot cracked in the construction under high current and high speed contact conditions. The occurrence of is remarkable.

The shielding gas used in combination with the flux-cored wire of the present invention is CO ₂ gas.

  Hereinafter, the effect of the present invention will be described in more detail with reference to examples.

  After filling the mild steel skin (C: 0.02%, Si: 0.01%, Mn: 0.35%, Al: 0.02%, N: 0.0015%) with a flux, Various prototypes of flux-cored wires with a flux filling rate of 17% and a wire diameter of 1.6 mm were produced. The wire cross-sectional shape is a seamless type, and there is no Cu plating on the wire surface. Table 1 shows each prototype wire.

Each of these prototype wires was used for both electrodes, and a two-electrode one-pool horizontal fillet welding test (both sides simultaneous welding) was performed. Further, a weld metal test was performed in accordance with JIS Z 3313 and JIS Z3111. The shield gas is CO ₂ gas. Table 2 shows the welding conditions.

The T-shaped fillet specimen of the two-electrode horizontal fillet welding test (hereinafter referred to as fillet welding) is a 490 N / mm grade ² high-strength steel plate thickness of 12 mm, plate width of 150 mm, and length of 1.0 m. Steel plate (Oxide scale due to hot rolling adheres thickly on the entire surface of the lower plate and the standing plate, the standing plate end surface remains gas-cut) and inorganic zinc primer coated steel plate (hereinafter referred to as primer steel plate. Primer film thickness: side surface and end surface) Both are about 20 μm), and there was no gap between the lower plate and the standing plate.

  For each prototype wire, the measured leg length, bead shape, slag peelability and porosity resistance were evaluated, as well as arc stability, stability of the puddle between the two electrodes, and slag encapsulation.

  The evaluation results of each test show that the arc stability is ◯: stable and x: unstable. The stability of the hot water pool between the two electrodes indicates ◯: stable and x: unstable. The slag encapsulation property indicates a state where ◯: the entire surface of the bead is encapsulated, and X: a state where the bead exposed part is partially present. Measured leg length: ◯: Satisfy target leg length, x: Insufficient leg length. Bead shape: ○: Undercut, no overlap, good conformability of bead toe, ×: Defect. Slag peelability: ○: Lightly bumped with an iron pipe with a diameter of 12 mm, wall thickness of 2 mm, and a length of about 1 m, and the entire bead is peeled off and removed very easily. Even removal is difficult. Porosity resistance indicates ◯: no generation of pores such as pits and gas grooves, and x: presence of generation of pores. Hot cracking resistance indicates ◯: no cracking including the crater part, x: cracking occurred.

  In the weld metal test, the average value of three pieces with a tensile strength of 490 to 670 MPa and an absorbed energy of 0 ° C. was determined to be 47 J or more. For some prototype wires, the absorbed energy at a test temperature of −20 ° C. was also examined. The results are summarized in Table 3.

表１および表３中ワイヤ記号Ｗ１〜Ｗ８が本発明例、ワイヤ記号Ｗ９〜Ｗ２５は比較例である。

In Tables 1 and 3, wire symbols W1 to W8 are examples of the present invention, and wire symbols W9 to W25 are comparative examples.

Wire Symbol W1~W8 an invention example, TiO ₂ converted value of Ti oxides in the flux cored wire, SiO ₂ conversion value of Si oxide, ZrO ₂ conversion value of Zr oxide, Mg, oxides of Na and K Total of Na ₂ O conversion value and K ₂ O conversion value of compound and compound, F conversion value of fluorine compound, Bi conversion value of Bi and Bi oxide, Al ₂ O ₃ conversion value of Al oxide Fe oxide FeO equivalent value of C, Si, Mn, and Al are contained in appropriate amounts, so that the arc stability in two-electrode horizontal fillet welding of black leather plate and primer steel plate (hereinafter referred to as both steel plates) is between the two electrodes. The hot-water pool stability, slag encapsulation, measured leg length, bead shape, slag peelability, porosity resistance and hot crack resistance were all good, and the strength and absorbed energy in the weld metal test were also good. In addition, the wire symbols W7 and W8 containing Ni also had high absorption energy at −20 ° C.

Since the wire symbol W9 in the comparative example has a small TiO ₂ conversion value, the slag encapsulation in fillet welding of both steel sheets was insufficient, and the bead shape and slag peelability were poor. Moreover, since there was little Al, the absorbed energy of the weld metal test was low.

Since the wire symbol W10 has many TiO ₂ converted values, the porosity resistance in fillet welding of the primer steel plate was poor. Moreover, since there was much Bi, the absorbed energy of the weld metal test was low.

Since the wire symbol W11 has a small SiO ₂ conversion value, the puddle between the two electrodes in the fillet welding of both steel sheets is not stable, the slag encapsulation is insufficient, and the bead shape and slag peelability are poor. . In addition, the leg length also had a large variation and could not be secured.

Since the wire symbol W12 has a large SiO ₂ conversion value, the slag peelability in fillet welding of black steel plate is poor, and the slag peelability and porosity resistance in fillet welding of primer steel plate are poor, and the absorbed energy of the weld metal test Was also low.

Since the wire symbol W13 has a small value in terms of ZrO ₂ , the slag encapsulation in fillet welding of both steel plates was insufficient, and the bead shape and slag peelability were poor. Moreover, since Mn was high, the tensile strength of the weld metal test was high and the absorbed energy was low.

Since the wire symbol W14 has many ZrO ₂ converted values, the slag removability in fillet welding of both steel plates was poor. Moreover, since there were few FeO conversion values, the conformity of the bead toe part was bad and the shape was bad.

Since the wire symbol W15 has a large sum of the SiO ₂ converted value and the ZrO ₂ converted value, the slag peelability in fillet welding of both steel plates was poor.

Since the wire symbol W16 has a small equivalent value of Al ₂ O _3, the slag encapsulation in fillet welding of both steel plates was insufficient, and the bead shape and slag peelability were poor. Moreover, since C was high, the tensile strength of the weld metal test was high and the absorbed energy was low.

In the wire symbol W17, since the total ratio of the SiO ₂ converted value and the ZrO ₂ converted value to the TiO ₂ converted value is large, the slag peelability in fillet welding of both steel sheets was poor. Moreover, since there was much Mg, the slag encapsulation in fillet welding of both steel plates was insufficient, and the bead shape was also poor.

Since the wire symbol W18 has a large sum of Na ₂ O converted value and K ₂ O converted value, the slag enveloping property in fillet welding of both steel plates was insufficient, and the bead shape and slag peelability were poor. Moreover, since it does not contain Mg, the absorbed energy of the weld metal test was low.

In the wire symbol W19, since the sum of Na ₂ O converted value and K ₂ O converted value is small, the arc state and the puddle in the fillet welding of both steel plates are unstable, and the slag encapsulation is insufficient and the bead shape and slag The peelability was poor. In addition, the leg length also had a large variation and could not be secured. Furthermore, since there was much Ni, the hot crack occurred in the crater part of the fillet welding of both steel plates. Therefore, the weld metal test was discontinued.

The wire symbol 20 had a poor bead shape in fillet welding of both steel plates because the ratio of the total of the SiO ₂ converted value and the ZrO ₂ converted value to the TiO ₂ converted value was small. Moreover, since there were few F conversion values, the porosity resistance in the fillet welding of a primer steel plate was unsatisfactory. Furthermore, since there is much Al, the tensile strength of the weld metal test was high and the absorbed energy was low.

  Since the wire symbol W21 has many F-converted values, the puddle in fillet welding of both steel plates is unstable and the bead shape is poor. Moreover, since there was much Si, the tensile strength of the weld metal test was high, and the absorbed energy was low.

  Since the wire symbol W22 has a small Bi-converted value, both steel sheet slag peelability was poor. Moreover, since the amount of Mn was small, the absorbed energy in the weld metal test was low.

Since the wire symbol W23 has many converted values for Al ₂ O _3, the slag encapsulation in fillet welding of both steel plates was insufficient, and the bead shape and slag peelability were poor. Moreover, since there was little C, the absorbed energy of the weld metal test was low. Since the wire symbol W24 has many FeO equivalent values, the hot water pool in fillet welding of both steel plates is unstable, the slag encapsulation is insufficient, and the bead shape and slag peelability are poor.

  Since the wire symbol W25 has little Si, the bead shape and slag peelability in fillet welding of both steel plates were poor. Moreover, since there was little Ni, the absorbed energy in -20 degreeC of a weld metal test was low.

DESCRIPTION OF SYMBOLS 1 Lead electrode wire 2 Subsequent electrode wire 3 Hot water pool 4 Molten pool 5 Molten slag 6 Solidified slag 7 Weld bead 8 Primer 9 Standing plate 10 Lower plate 11 Undercut 12 Overlap 13 Pore

Claims (2)

In a flux-cored wire for gas shielded arc welding that is formed by filling a steel outer shell with flux, the flux in mass% with respect to the total mass of the wire,
TiO ₂ conversion value of Ti oxide: 3.0 to 4.0%,
SiO ₂ conversion value of Si oxide: 1.0 to 1.8%,
ZrO ₂ conversion value of Zr oxide: 0.6 to 1.2%,
However, the total of SiO ₂ converted value and ZrO ₂ converted value: 2.4% or less,
And (total of SiO ₂ converted value and ZrO ₂ converted value) / TiO ₂ converted value: 0.45 to 0.70,
Mg: 0.1-0.5%
Na ₂ K equivalent value of oxides and compounds of Na and K and the sum of K ₂ O equivalent value: 0.10 to 0.30%,
F conversion value of fluorine compound: 0.05 to 0.20%,
Sum of Bi converted values of Bi and Bi oxide: 0.010 to 0.030%,
Al ₂ O ₃ conversion value of Al oxide: 0.05 to 0.3%,
FeO conversion value of Fe oxide: 0.05 to 0.3%,
In addition, the sum of the steel shell and flux,
C: 0.04 to 0.08%,
Si: 0.3-0.7%,
Mn: 2.8 to 3.8%,
A two-electrode horizontal corner characterized by containing Al: 0.05 to 0.4%, and the balance consisting of Fe content in steel outer shell, Fe content from flux iron powder, iron alloy, etc. and inevitable impurities Flux-cored wire for meat CO ₂ gas shielded arc welding. The flux-cored wire for two-electrode horizontal fillet CO ₂ gas shielded arc welding according to claim 1, wherein the flux contains Ni: 0.3 to 0.9%.

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