JP2012207348A - Dyeing method for aramid fiber - Google Patents
Dyeing method for aramid fiber Download PDFInfo
- Publication number
- JP2012207348A JP2012207348A JP2011075069A JP2011075069A JP2012207348A JP 2012207348 A JP2012207348 A JP 2012207348A JP 2011075069 A JP2011075069 A JP 2011075069A JP 2011075069 A JP2011075069 A JP 2011075069A JP 2012207348 A JP2012207348 A JP 2012207348A
- Authority
- JP
- Japan
- Prior art keywords
- dyeing
- aramid
- weight
- aramid fiber
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 48
- 229920006231 aramid fiber Polymers 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical group OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 42
- 239000004760 aramid Substances 0.000 claims description 35
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 14
- 238000007447 staining method Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 description 29
- 229920003235 aromatic polyamide Polymers 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 239000000975 dye Substances 0.000 description 10
- 238000005406 washing Methods 0.000 description 7
- 125000002091 cationic group Chemical group 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- LEBQTCCCNMTXSF-UHFFFAOYSA-N (2,5-dimethylphenyl)methanol Chemical compound CC1=CC=C(C)C(CO)=C1 LEBQTCCCNMTXSF-UHFFFAOYSA-N 0.000 description 4
- 235000011054 acetic acid Nutrition 0.000 description 4
- 239000002759 woven fabric Substances 0.000 description 4
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- BWRBVBFLFQKBPT-UHFFFAOYSA-N (2-nitrophenyl)methanol Chemical compound OCC1=CC=CC=C1[N+]([O-])=O BWRBVBFLFQKBPT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- -1 p-isopropylbenzyl Chemical group 0.000 description 2
- ICJVQAHPHKYCNU-UHFFFAOYSA-N (2-ethoxyphenyl)methanol Chemical compound CCOC1=CC=CC=C1CO ICJVQAHPHKYCNU-UHFFFAOYSA-N 0.000 description 1
- WYLYBQSHRJMURN-UHFFFAOYSA-N (2-methoxyphenyl)methanol Chemical compound COC1=CC=CC=C1CO WYLYBQSHRJMURN-UHFFFAOYSA-N 0.000 description 1
- ZSRDNPVYGSFUMD-UHFFFAOYSA-N (3-chlorophenyl)methanol Chemical compound OCC1=CC=CC(Cl)=C1 ZSRDNPVYGSFUMD-UHFFFAOYSA-N 0.000 description 1
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
- WMAVHUWINYPPKT-UHFFFAOYSA-M (e)-3-methyl-n-[(e)-(1-methyl-2-phenylindol-1-ium-3-ylidene)amino]-1,3-thiazol-2-imine;chloride Chemical compound [Cl-].C12=CC=CC=C2N(C)C(C=2C=CC=CC=2)=C1N=NC=1SC=C[N+]=1C WMAVHUWINYPPKT-UHFFFAOYSA-M 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KWHVBVJDKLSOTB-UHFFFAOYSA-N 2-(3-methylphenyl)ethanol Chemical compound CC1=CC=CC(CCO)=C1 KWHVBVJDKLSOTB-UHFFFAOYSA-N 0.000 description 1
- DAVFJRVIVZOKKS-UHFFFAOYSA-N 2-(4-methylphenyl)ethanol Chemical compound CC1=CC=C(CCO)C=C1 DAVFJRVIVZOKKS-UHFFFAOYSA-N 0.000 description 1
- QGCCNWSXJHGUNL-UHFFFAOYSA-N 3-iodo-benzyl alcohol Chemical compound OCC1=CC=CC(I)=C1 QGCCNWSXJHGUNL-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 description 1
- WVUKFQBBZVBJRZ-UHFFFAOYSA-N 4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]-n,n-dimethylaniline Chemical compound S1C2=CC(OC)=CC=C2[N+](C)=C1N=NC1=CC=C(N(C)C)C=C1 WVUKFQBBZVBJRZ-UHFFFAOYSA-N 0.000 description 1
- SPWPAFQLIZTXFN-UHFFFAOYSA-M 4-methoxy-n-methyl-n-[(1,3,3-trimethylindol-1-ium-2-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(OC)=CC=C1N(C)\N=C\C1=[N+](C)C2=CC=CC=C2C1(C)C SPWPAFQLIZTXFN-UHFFFAOYSA-M 0.000 description 1
- XURABDHWIADCPO-UHFFFAOYSA-N 4-prop-2-enylhepta-1,6-diene Chemical compound C=CCC(CC=C)CC=C XURABDHWIADCPO-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001483078 Phyto Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- IURGIPVDZKDLIX-UHFFFAOYSA-M [7-(diethylamino)phenoxazin-3-ylidene]-diethylazanium;chloride Chemical compound [Cl-].C1=CC(=[N+](CC)CC)C=C2OC3=CC(N(CC)CC)=CC=C3N=C21 IURGIPVDZKDLIX-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- OORRQYZWSVJKSO-UHFFFAOYSA-N bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene Chemical compound C1=CC=C(C2)C=CC=CC2=C1 OORRQYZWSVJKSO-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- QILSFLSDHQAZET-UHFFFAOYSA-N diphenylmethanol Chemical compound C=1C=CC=CC=1C(O)C1=CC=CC=C1 QILSFLSDHQAZET-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 150000004060 quinone imines Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
本発明は、アラミド繊維の染色方法に関するものであり、さらに詳しくは、アラミド繊維の液流染色を行った後の洗浄方法に関するものである。 The present invention relates to a method for dyeing aramid fibers, and more particularly to a washing method after liquid flow dyeing of aramid fibers.
アラミド繊維は、高い機械強度と耐熱性、並びに難燃性を有し、それらは特に、消防士、宇宙飛行士、及びパイロットのための服のデザインにおいて、火災又は高温と接触する事を意図した織物繊維として広く使用される。
また前記アラミド繊維は、結晶性が高く分子間結合力が強固な分子構造を有しており、そのため難染性を示し、たとえば染色できても洗濯などですぐに染料が脱落してしまうなど、従来の染色技術では着色することが難しいという問題があった。
Aramid fibers have high mechanical strength and heat resistance, as well as flame retardancy, and they are intended to come into contact with fire or high temperatures, especially in the design of clothes for firefighters, astronauts, and pilots Widely used as textile fiber.
In addition, the aramid fiber has a molecular structure with high crystallinity and a strong intermolecular bonding force, and therefore exhibits a difficult dyeing property. There is a problem that it is difficult to color with conventional dyeing techniques.
このような問題を解決する方法として、特許文献1には、カチオン系染料によってパラ系アラミド繊維を染色する場合において繊維膨潤剤（キャリアー）を用いる方法が開示されている。
しかしながら、上記従来の染色方法において、キャリアとしてベンジルアルコールを使用した場合、染色性は向上するものの、染色後のアラミド繊維布帛の難燃性が著しく低下するという問題があった。
As a method for solving such a problem, Patent Document 1 discloses a method in which a fiber swelling agent (carrier) is used when para-aramid fibers are dyed with a cationic dye.
However, in the above conventional dyeing method, when benzyl alcohol is used as a carrier, although the dyeability is improved, there is a problem that the flame retardancy of the aramid fiber fabric after dyeing is significantly reduced.
本発明は、上記問題に鑑みなされたもので、染色が難しいアラミド繊維において、アラミド繊維の難燃性を低下させることなく染色する際の洗浄方法を提供することを目的とする。 This invention is made | formed in view of the said problem, and it aims at providing the washing | cleaning method at the time of dyeing, without reducing the flame retardance of an aramid fiber in the aramid fiber which is difficult to dye.
本発明者らは、上記問題を解決するために鋭意検討した結果、以下の方法により上記の課題を解決できることを見出した。すなわち本発明によれば、が提供される。 As a result of intensive studies to solve the above problems, the present inventors have found that the above problems can be solved by the following method. That is, according to the present invention, is provided.
本発明によれば、アラミド繊維を、液流染色する際に残存するキャリア剤、特にベンジルアルコールが存在することにより懸念されていた、燃焼性低下の問題が解決されたアラミド繊維を得ることができる。 According to the present invention, it is possible to obtain an aramid fiber in which the problem of a decrease in combustibility, which has been a concern due to the presence of a carrier agent, particularly benzyl alcohol, remaining when liquid-dyeing the aramid fiber is solved. .
以下に本発明を詳細に説明する。本発明は、アラミド繊維を染色する方法に関するものである。本発明で用いるアラミド繊維は、合成ポリアミド鎖を含み、鎖中ではアミド基の少なくとも８５％が芳香族基に直接結合しているものである。また、本発明で用いるアラミド繊維は、編物、織物、不織布等いずれの形状で使用されても良い。さらに、アラミド繊維は単体で用いても、または、羊毛、ポリエステル、セルロース、ポリアクリロニトリル、絹等と混紡、交織、交編等して用いても差し支えない。 The present invention is described in detail below. The present invention relates to a method for dyeing aramid fibers. The aramid fiber used in the present invention includes a synthetic polyamide chain in which at least 85% of the amide groups are directly bonded to the aromatic group. Moreover, the aramid fiber used in the present invention may be used in any shape such as a knitted fabric, a woven fabric, and a nonwoven fabric. Furthermore, the aramid fiber may be used alone, or may be used by blending, knitting, knitting or the like with wool, polyester, cellulose, polyacrylonitrile, silk or the like.
本発明に用いる、キャリア剤としては、例えば、ＤＬ−β−エチルフェネチルアルコール、２−エトキシベンジルアルコール、３−クロロベンジルアルコール、２，５−ジメチルベンジルアルコール、２−ニトロベンジルアルコール、ｐ−イソプロピルベンジルアルコール、２−メチルフェネチルアルコール、３−メチルフェネチルアルコール、４−メチルフェネチルアルコール、２−メトキシベンジルアルコール、３−ヨードベンジルアルコール、ケイ皮アルコール、ｐ−アニシルアルコールおよびベンズヒドロールの中から選ばれる少なくとも一種であることが好ましい。 Examples of the carrier agent used in the present invention include DL-β-ethylphenethyl alcohol, 2-ethoxybenzyl alcohol, 3-chlorobenzyl alcohol, 2,5-dimethylbenzyl alcohol, 2-nitrobenzyl alcohol, p-isopropylbenzyl. Selected from alcohol, 2-methylphenethyl alcohol, 3-methylphenethyl alcohol, 4-methylphenethyl alcohol, 2-methoxybenzyl alcohol, 3-iodobenzyl alcohol, cinnamic alcohol, p-anisyl alcohol and benzhydrol At least one kind is preferred.
また具体的な商品としては、ベンジルアルコール、ダウケミカル製ダワノールＰＰＨ、ＢＯＺＺＥＴＴＯ製ＣＩＮＤＹＥＤＮＫが望ましい。また、白度をより向上させる点で、ベンジルアルコール、中でも、２，５−ジメチルベンジルアルコールまたは２−ニトロベンジルアルコールを用いることが好ましい。 As specific products, benzyl alcohol, Dowanol PPH manufactured by Dow Chemical, and CINDYEDNK manufactured by BOZZETTO are desirable. Moreover, it is preferable to use benzyl alcohol, especially 2, 5- dimethyl benzyl alcohol or 2-nitro benzyl alcohol from the point which improves whiteness more.
本発明においては、液流染色を行う際の洗浄条件としてキャリア剤であるベンジルアルコール残存量を低減させることが肝要である。
本発明者らは、布帛の残存ベンジルアルコール量を低減させる方法として洗浄条件の検討をしたが、アラミド繊維染色上がり布帛では残存ベンジルアルコール量が多く、十分な難燃性が得られなかった。そこで、さらに検討を進め、染色後にハイドロサルファイトとソーダ灰、界面活性剤を使用した還元洗浄処理することで、液流染色によって布帛残存ベンジルアルコール量の低減が可能となることを見出したものである。
In the present invention, it is important to reduce the residual amount of benzyl alcohol, which is a carrier agent, as a washing condition when performing liquid flow dyeing.
The present inventors examined the washing conditions as a method for reducing the amount of residual benzyl alcohol in the fabric. However, the amount of residual benzyl alcohol was large in the aramid fiber dyed fabric, and sufficient flame retardancy was not obtained. Therefore, further investigation was conducted, and it was found that the amount of benzyl alcohol remaining in the fabric can be reduced by liquid flow dyeing by reducing and washing using hydrosulfite, soda ash, and a surfactant after dyeing. is there.
アラミド繊維の染色後、還元洗浄を施す事によりアラミド繊維からベンジルアルコールを抽出するのに最も効果的な洗浄処理条件である。
また、本発明によれば、アラミド繊維自身が持つ難燃性を染色後も維持することも可能となる。しかもこの方法によれば、液流染色の特徴もそのまま生かすことができる。
This is the most effective washing treatment condition for extracting benzyl alcohol from aramid fibers by performing reduction washing after dyeing of aramid fibers.
Moreover, according to this invention, it becomes possible to maintain the flame retardance which an aramid fiber itself has after dyeing | staining. In addition, according to this method, the characteristics of liquid flow dyeing can be utilized as they are.
本発明に用いる洗浄剤としては、ハイドロサルファイト、ソーダ灰、乳化剤などの還元洗浄を例示することができ、中でも乳化剤としてアミラジンＤが好ましい。
一方、洗浄剤濃度として高い程、キャリア剤であるベンジルアルコールの除去に最適だと考えられるが、布帛の変色性の面から十分な染色性を得られない傾向にあり、洗浄剤濃度としてハイドロサルファイト１ｇ／ｌ、ソーダ灰１ｇ／ｌ、アミラジンＤ１ｇ／ｌが好ましいと考える。
Examples of the cleaning agent used in the present invention include reductive cleaning such as hydrosulfite, soda ash, and emulsifier. Among them, amylazine D is preferable as the emulsifier.
On the other hand, the higher the detergent concentration, the more optimal the removal of benzyl alcohol, which is a carrier agent, but there is a tendency that sufficient dyeability cannot be obtained in terms of discoloration of the fabric. Phyto 1 g / l, soda ash 1 g / l, and amylazine D 1 g / l are considered preferable.
本発明においては、染色に用いる染料は、カチオン染料を用いることができる。カチオン染料としては、ジおよびトリアリルメタン系、アゾ系、キノンイミン系、キサンテン系、ポリメチン系などが例示でき、中でもアゾ系が望ましい。例えば、アゾ系としてＣ．Ｉ．Ｂａｓｉｃ Ｂｌｕｅ５４、Ｃ．Ｉ．Ｂａｓｉｃ Ｂｌｕｅ３、Ｃ．Ｉ．Ｂａｓｉｃ Ｒｅｄ２９、Ｃ．Ｉ．Ｂａｓｉｃ Ｙｅｌｌｏｗ２８などを例示することができる。 In the present invention, a cationic dye can be used as the dye used for dyeing. Examples of the cationic dye include di- and triallylmethane-based, azo-based, quinoneimine-based, xanthene-based, and polymethine-based. Among them, azo-based dyes are preferable. For example, C.I. I. Basic Blue 54, C.I. I. Basic Blue 3, C.I. I. Basic Red 29, C.I. I. Basic Yellow 28 can be exemplified.
染色条件は、ｐＨ３〜７の酸性付近の範囲で行うことが好ましい、ｐＨ調整するために必要に応じて、燐酸、硫酸、塩酸等の無機酸や酢酸、蟻酸、酒石酸等の有機酸または硫安、酢酸アンモニウム、蟻酸アンモニウム等の酸性塩を単独または２種以上を混合しても良い。また、染色は、温度８０〜１３０℃、時間１０〜９０分の範囲で行うことができ、温度１１０〜１２０℃、時間６０〜８０分の範囲がより好ましい。 The dyeing conditions are preferably carried out in the acidic range of pH 3 to 7, if necessary for adjusting pH, inorganic acids such as phosphoric acid, sulfuric acid, hydrochloric acid, etc., organic acids such as acetic acid, formic acid, tartaric acid, or ammonium sulfate, Acid salts such as ammonium acetate and ammonium formate may be used alone or in combination of two or more. The dyeing can be performed at a temperature of 80 to 130 ° C. and a time of 10 to 90 minutes, and more preferably at a temperature of 110 to 120 ° C. and a time of 60 to 80 minutes.
以下、実施例により本発明を具体的に説明するが、本発明はこれら実施例に限定されるものではない。なお、実施例中の物性は以下の方法により測定した。
（１）燃焼性
ISO13506（２００８）に準拠した燃焼試験機（PLIFF）にて火傷率を測定した。なお、火傷率が高い程、人体への火傷が高い事を示している。
（２）残存ベンジルアルコール量
残存ベンジルアルコール量は、GC-MSにて評価した。
EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples. In addition, the physical property in an Example was measured with the following method.
(1) Flammability
The burn rate was measured with a combustion tester (PLIFF) compliant with ISO13506 (2008). In addition, it has shown that the burn rate to a human body is so high that a burn rate is high.
(2) Residual benzyl alcohol amount The residual benzyl alcohol amount was evaluated by GC-MS.
［実施例１］
３６番手のメタアラミド紡績糸（帝人テクノプロダクツ（株）製コーネックス）を製織して、秤量２００ｇ／ｍ２のアラミド織物（平織物）を得た。
投入するアラミド織物１００重量部に対して６重量部のカチオン染料（日本化薬（株）製Ｃ．Ｉ．Ｂａｓｉｃ Ｂｌｕｅ５４）と、水１００重量部に対して、ｐＨ調整剤（酢酸８０%水溶液）０．０３重量部、分散剤（明成化学（株）製ディスパーＴＬ）０．０５重量部、硝酸ナトリウム２５重量部、ベンジルアルコール６０重量部とを、水に溶解し総量２００ｍｌの染色浴を調整した。この染色浴にアラミド織物１０ｇを投入し、日阪製作所（株）製液流染色機である高温サーキュラー染色機にセットし、撹拌しながら温度を常温〜１２０℃まで昇温速度２℃／分で昇温し、さらに、１２０℃で６０分間保持した。染色浴を冷却した後、青色に染色されたアラミド織物を取り出し、水洗した。
さらに、ハイドロサルファイト１ｇ／Ｌ、ソーダ灰１ｇ／Ｌ、界面活性剤（明成化学（株）製アミラジンＤ）１ｇ／Ｌを水に溶解し総量２００ｍｌの後処理浴を調整した。この後処理浴に上記の染色後のアラミド織物を投入し、上記液流染色機にセットし、撹拌しながら温度を常温〜８０℃まで昇温速度２℃／分で昇温し、さらに、８０℃で２０分間保持した。後処理浴を冷却した後、アラミド織物を取り出し、水洗し、風乾して仕上げた。さらに加熱処理した後、水洗、乾燥する。加熱処理は、温度１９０℃、時間２分にて、乾燥は、温度１０５℃、時間３分にて行った。
得られた織物は、均一で、極めて鮮明かつ濃色に染色されており、全火傷率（２度＋３度）は１２．４％であった。残留ベンジルアルコールは１．８６重量部、マネキンテスト前後のトータル寸法変化率が３２．８％であった。
[Example 1]
The 36th meta-aramid spun yarn (Conex manufactured by Teijin Techno Products Co., Ltd.) was woven to obtain an aramid fabric (plain fabric) with a weight of 200 g / m 2 .
6 parts by weight of cationic dye (Nippon Kayaku Co., Ltd. CI Basic Blue 54) with respect to 100 parts by weight of the aramid fabric to be added, and 100 parts by weight of water with a pH adjuster (80% aqueous solution of acetic acid) 0.03 parts by weight, 0.05 parts by weight of a dispersant (Meisei Chemical Co., Ltd. Disper TL), 25 parts by weight of sodium nitrate and 60 parts by weight of benzyl alcohol were dissolved in water to prepare a dyeing bath having a total amount of 200 ml. . 10 g of aramid fabric is put into this dyeing bath and set in a high-temperature circular dyeing machine which is a liquid dyeing machine manufactured by Nisaka Manufacturing Co., Ltd. The temperature is raised from room temperature to 120 ° C while stirring at a heating rate of 2 ° C / min. The temperature was raised, and the temperature was further maintained at 120 ° C. for 60 minutes. After cooling the dyeing bath, the aramid fabric dyed in blue was taken out and washed with water.
Further, hydrosulfite 1 g / L, soda ash 1 g / L, and surfactant (Amiradine D manufactured by Meisei Chemical Co., Ltd.) 1 g / L were dissolved in water to prepare a post-treatment bath having a total amount of 200 ml. The aramid fabric after dyeing is put into this post-treatment bath, set in the liquid flow dyeing machine, the temperature is raised from room temperature to 80 ° C. at a heating rate of 2 ° C./min with stirring, and further 80 Hold at 20 ° C. for 20 minutes. After cooling the post-treatment bath, the aramid fabric was removed, washed with water, and air-dried to finish. After further heat treatment, it is washed with water and dried. The heat treatment was performed at a temperature of 190 ° C. for 2 minutes, and the drying was performed at a temperature of 105 ° C. for a time of 3 minutes.
The obtained woven fabric was uniform, dyed in a very clear and dark color, and the total burn rate (2 degrees + 3 degrees) was 12.4%. The residual benzyl alcohol was 1.86 parts by weight, and the total dimensional change rate before and after the mannequin test was 32.8%.
［比較例１］
３６番手のメタアラミド紡績糸（帝人テクノプロダクツ（株）製コーネックス）を製織して、秤量２００ｇ／ｍ２のアラミド織物（平織物）を得た。
投入するアラミド織物１００重量部に対して６重量部のカチオン染料（日本化薬（株）製Ｃ．Ｉ．Ｂａｓｉｃ Ｂｌｕｅ５４）と、水１００重量部に対して、ｐＨ調整剤（酢酸８０%水溶液）０．０３重量部、分散剤（明成化学（株）製ディスパーＴＬ）０．０５重量部、硝酸ナトリウム２５重量部とを、水に溶解し総量２００ｍｌの染色浴を調整した。この染色浴にアラミド織物１０ｇを投入し、日阪製作所（株）製液流染色機である高温サーキュラー染色機にセットし、撹拌しながら温度を常温〜１２０℃まで昇温速度２℃／分で昇温し、さらに、１２０℃で６０分間保持した。染色浴を冷却した後、青色に染色されたアラミド織物を取り出し、水洗した。
さらに、界面活性剤（北広ケミカル（株）製スコアロール＃４００）１ｇ／Ｌ、ソーダ灰１ｇ／Ｌを水に溶解し総量２００ｍｌの後処理浴を調整した。この後処理浴に上記の染色後のアラミド織物を投入し、上記液流染色機にセットし、撹拌しながら温度を常温〜８０℃まで昇温速度２℃／分で昇温し、さらに、８０℃で２０分間保持した。後処理浴を冷却した後、アラミド織物を取り出し、水洗し、風乾して仕上げた。さらに加熱処理した後、水洗、乾燥する。加熱処理は、温度１９０℃、時間２分にて、乾燥は、温度１０５℃、時間３分にて行った。
得られた織物は、均一で、極めて鮮明かつ濃色に染色されており、全火傷率（２度＋３度）は１８．２％であった。残留ベンジルアルコールは２．４３重量部、マネキンテスト前後のトータル寸法変化率が４１．９％であった。
[Comparative Example 1]
The 36th meta-aramid spun yarn (Conex manufactured by Teijin Techno Products Co., Ltd.) was woven to obtain an aramid fabric (plain fabric) with a weight of 200 g / m 2 .
6 parts by weight of cationic dye (Nippon Kayaku Co., Ltd. CI Basic Blue 54) with respect to 100 parts by weight of the aramid fabric to be added, and 100 parts by weight of water with a pH adjuster (80% aqueous solution of acetic acid) 0.03 parts by weight, a dispersant (Disper TL manufactured by Meisei Chemical Co., Ltd.) 0.05 parts by weight, and sodium nitrate 25 parts by weight were dissolved in water to prepare a dyeing bath having a total amount of 200 ml. 10 g of aramid fabric is put into this dyeing bath and set in a high-temperature circular dyeing machine which is a liquid dyeing machine manufactured by Nisaka Manufacturing Co., Ltd. The temperature is raised from room temperature to 120 ° C while stirring at a heating rate of 2 ° C / min. The temperature was raised, and the temperature was further maintained at 120 ° C. for 60 minutes. After cooling the dyeing bath, the aramid fabric dyed in blue was taken out and washed with water.
Further, 1 g / L of a surfactant (Score Roll # 400 manufactured by Kitahiro Chemical Co., Ltd.) and 1 g / L of soda ash were dissolved in water to prepare a post-treatment bath having a total amount of 200 ml. The aramid fabric after dyeing is put into this post-treatment bath, set in the liquid flow dyeing machine, the temperature is raised from room temperature to 80 ° C. at a heating rate of 2 ° C./min with stirring, and further 80 Hold at 20 ° C. for 20 minutes. After cooling the post-treatment bath, the aramid fabric was removed, washed with water, and air-dried to finish. After further heat treatment, it is washed with water and dried. The heat treatment was performed at a temperature of 190 ° C. for 2 minutes, and the drying was performed at a temperature of 105 ° C. for a time of 3 minutes.
The obtained woven fabric was uniform, dyed in a very clear and dark color, and the total burn rate (2 degrees + 3 degrees) was 18.2%. The residual benzyl alcohol was 2.43 parts by weight, and the total dimensional change rate before and after the mannequin test was 41.9%.
［比較例２］
３６番手のメタアラミド紡績糸（帝人テクノプロダクツ（株）製コーネックス）を製織して、秤量２００ｇ／ｍ２のアラミド織物（平織物）を得た。
投入するアラミド織物１００重量部に対して６重量部のカチオン染料（日本化薬（株）製Ｃ．Ｉ．Ｂａｓｉｃ Ｂｌｕｅ５４）と、水１００重量部に対して、ｐＨ調整剤（酢酸８０％水溶液）０．０３重量部、分散剤（明成化学（株）製ディスパーＴＬ）０．０５重量部、硝酸ナトリウム２５重量部とを、水に溶解し総量２００ｍｌの染色浴を調整した。この染色浴にアラミド織物１０ｇを投入し、日阪製作所（株）製液流染色機である高温サーキュラー染色機にセットし、撹拌しながら温度を常温〜１２０℃まで昇温速度２℃／分で昇温し、さらに、１２０℃で６０分間保持した。染色浴を冷却した後、青色に染色されたアラミド織物を取り出し、水洗した。
さらに、水総量２００ｍｌの後処理浴を調整した。この後処理浴に上記の染色後のアラミド織物を投入し、上記液流染色機にセットし、撹拌しながら温度を常温〜８０℃まで昇温速度２℃／分で昇温し、さらに、８０℃で２０分間保持した。後処理浴を冷却した後、アラミド織物を取り出し、水洗し、風乾して仕上げた。さらに加熱処理した後、水洗、乾燥する。加熱処理は、温度１９０℃、時間２分にて、乾燥は、温度１０５℃、時間３分にて行った。
得られた織物は、均一で、極めて鮮明かつ濃色に染色されており、全火傷率（２度＋３度）は２６．０％であった。残留ベンジルアルコールは５．８０重量部であった。マネキンテスト前後のトータル寸法変化率が４５．５％であった。
[Comparative Example 2]
The 36th meta-aramid spun yarn (Conex manufactured by Teijin Techno Products Co., Ltd.) was woven to obtain an aramid fabric (plain fabric) with a weight of 200 g / m 2 .
6 parts by weight of cationic dye (Nippon Kayaku Co., Ltd. CI Basic Blue 54) with respect to 100 parts by weight of the aramid fabric to be added, and 100 parts by weight of water with a pH adjuster (80% aqueous solution of acetic acid) 0.03 parts by weight, a dispersant (Disper TL manufactured by Meisei Chemical Co., Ltd.) 0.05 parts by weight, and sodium nitrate 25 parts by weight were dissolved in water to prepare a dyeing bath having a total amount of 200 ml. 10 g of aramid fabric is put into this dyeing bath and set in a high-temperature circular dyeing machine which is a liquid dyeing machine manufactured by Nisaka Manufacturing Co., Ltd. The temperature is raised from room temperature to 120 ° C while stirring at a heating rate of 2 ° C / min. The temperature was raised and the temperature was further maintained at 120 ° C. for 60 minutes. After cooling the dyeing bath, the aramid fabric dyed in blue was taken out and washed with water.
Furthermore, a post-treatment bath having a total water volume of 200 ml was prepared. The aramid fabric after dyeing is put into this post-treatment bath, set in the liquid flow dyeing machine, the temperature is raised from room temperature to 80 ° C. at a heating rate of 2 ° C./min with stirring, and further 80 Hold at 20 ° C. for 20 minutes. After cooling the post-treatment bath, the aramid fabric was removed, washed with water, and air-dried to finish. After further heat treatment, it is washed with water and dried. The heat treatment was performed at a temperature of 190 ° C. for 2 minutes, and the drying was performed at a temperature of 105 ° C. for a time of 3 minutes.
The obtained woven fabric was uniform, dyed in a very vivid and dark color, and the total burn rate (2 ° + 3 °) was 26.0%. Residual benzyl alcohol was 5.80 parts by weight. The total dimensional change rate before and after the mannequin test was 45.5%.
本発明によれば、液流染色により難燃性素材であるアラミド繊維布帛の燃焼性を低下させずに染色することが可能となるため、多様で、鮮明、濃色、燃焼性といった色相に優れた染色されたアラミド繊維布帛を得ることができ、その産業上の利用価値が極めて高いものである。 According to the present invention, it becomes possible to dye without reducing the flammability of the flame-retardant material aramid fiber cloth by liquid flow dyeing, and therefore various, excellent hues such as vivid, dark color, and flammability. A dyed aramid fiber fabric can be obtained, and its industrial utility value is extremely high.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011075069A JP2012207348A (en) | 2011-03-30 | 2011-03-30 | Dyeing method for aramid fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011075069A JP2012207348A (en) | 2011-03-30 | 2011-03-30 | Dyeing method for aramid fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2012207348A true JP2012207348A (en) | 2012-10-25 |
Family
ID=47187324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011075069A Withdrawn JP2012207348A (en) | 2011-03-30 | 2011-03-30 | Dyeing method for aramid fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2012207348A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160140951A (en) | 2014-04-14 | 2016-12-07 | 데이진 가부시키가이샤 | Colored organic fiber, fabric and clothing and method for manufacturing fabric |
-
2011
- 2011-03-30 JP JP2011075069A patent/JP2012207348A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160140951A (en) | 2014-04-14 | 2016-12-07 | 데이진 가부시키가이샤 | Colored organic fiber, fabric and clothing and method for manufacturing fabric |
| CN106232898A (en) * | 2014-04-14 | 2016-12-14 | 帝人株式会社 | Organic fiber, cloth and silk and the dress material of coloring and the manufacture method of cloth and silk |
| JPWO2015159749A1 (en) * | 2014-04-14 | 2017-04-13 | 帝人株式会社 | COLORED ORGANIC FIBER AND FABRIC, AND METHOD FOR PRODUCING APPAREL AND FABRIC |
| JP2018138713A (en) * | 2014-04-14 | 2018-09-06 | 帝人株式会社 | Colored organic fiber, fabric and garment, and method for producing fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Avinc et al. | Overview of poly (lactic acid)(PLA) fibre: Part II: Wet processing; pretreatment, dyeing, clearing, finishing, and washing properties of poly (lactic acid) fibres | |
| TWI539046B (en) | Fluorescent fibre, its use and processes for its production | |
| JP2007247116A (en) | Natural fiber product and dyeing method for the same | |
| JP5844537B2 (en) | Aramid fiber dyeing method | |
| US10655273B2 (en) | Dyed fibers and methods of dyeing using N,N′-diacetyl indigo | |
| CN102660877B (en) | Dyeing process for dacron cotton blending shining weaving fabric | |
| JP5774896B2 (en) | Dyeing fabric containing aramid fiber and dyeing method | |
| Yuen et al. | Enhancing textile ink‐jet printing with chitosan | |
| JP7418942B2 (en) | Chlorine-resistant fabric and manufacturing method thereof | |
| CN102182079A (en) | Industrial dyeing process of chitosan fiber and cellulose fiber blended fabric | |
| JP2012207348A (en) | Dyeing method for aramid fiber | |
| Baig | Effect of pH on the coloration of synthetic fibres with indigo blue | |
| JP4061392B2 (en) | Twisted yarn and dyeing method thereof | |
| JP5650410B2 (en) | Method for dyeing aramid fiber fabric | |
| WO2014100841A2 (en) | Flame retardant lyocell article dyed to give good light and washing fastness | |
| JP2013204210A (en) | Dyed aramid fiber and method for dyeing aramid fiber | |
| JP2008291384A (en) | Method for dyeing wholly aromatic polyamide fiber | |
| JP5629104B2 (en) | Method for dyeing polyetherimide fiber and dyed product thereof | |
| JP2011252247A (en) | Aramid fiber with improved brightness and producing method of the same | |
| JP5480991B1 (en) | Fluorescent whitening highly cross-linked polyacrylate fiber, method for producing the same, and fiber structure including the same | |
| CN108442134B (en) | Dye for milk yarn non-woven fabric lace and dyeing process thereof | |
| RU2591936C1 (en) | Method of dyeing polyurethane fibres | |
| KR20120077240A (en) | Dyeing method of meta aramid staple fiber | |
| CN104294677B (en) | One helps dye compositions | |
| JP2010163719A (en) | Method for mercerization on composite fiber structure of polylactic acid fiber and cotton or cellulosic fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20121119 |
|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20140603 |