JP2012206011A - Water purifying material and method for production thereof - Google Patents

Water purifying material and method for production thereof Download PDF

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JP2012206011A
JP2012206011A JP2011073094A JP2011073094A JP2012206011A JP 2012206011 A JP2012206011 A JP 2012206011A JP 2011073094 A JP2011073094 A JP 2011073094A JP 2011073094 A JP2011073094 A JP 2011073094A JP 2012206011 A JP2012206011 A JP 2012206011A
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water purification
charcoal
carbonized
purification material
oxygen
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Senshin Umeki
千真 梅木
Nobukazu Taguchi
信和 田口
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GAIA KANKYO GIJUTSU KENKYUSHO KK
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GAIA KANKYO GIJUTSU KENKYUSHO KK
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02E50/10—Biofuels, e.g. bio-diesel

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Abstract

PROBLEM TO BE SOLVED: To provide a water purifying material of a high water purifying effect using rice hull charcoal, paulownia charcoal, or cedar charcoal which has been carbonized with a carbonizing apparatus where carbonization is performed in an oxygen-free atmosphere with agitation, to provide a method for the use thereof, and to provide a method for the production thereof.SOLUTION: There is provided a method for using a water purifying agent comprising packing, into a cartridge 21C, a water purifying agent 1 based on paulownia charcoal which has been carbonized with a carbonizing apparatus where carbonization is performed in an oxygen-free atmosphere with agitation and fitting the cartridge to the front part of a drip coffee filter 81.

Description

本発明は、浄水材に関し、特に、無酸素雰囲気中にて攪拌しながら炭化される炭化装置によって炭化された炭化物を主成分とする浄水材及びその使用方法、ならびにその製造方法に関する。 TECHNICAL FIELD The present invention relates to a water purification material, and more particularly, to a water purification material mainly composed of carbides carbonized by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere, a method for using the same, and a method for manufacturing the same.

従来の浄水材に関しては、例えば、特許文献１に記載されている。
特許文献１には、活性炭と、それを用いた浄水器について記載されている。特に応用例として水道水の浄水に応用した例が開示されている。 For example, Patent Document 1 discloses a conventional water purification material.
Patent Document 1 describes activated carbon and a water purifier using the activated carbon. As an application example, an example applied to the purification of tap water is disclosed.

特開２０００−３５１６１３JP 2000-351613 A

従来の浄水材に用いられる炭化物は、バッチ式の炭化炉によって炭化された炭化物であって、賦活工程などを行わなければ比表面積が小さいため、浄水効果が弱く、一定の浄水能力に留まっていた。また、賦活を行って活性炭とした場合には、浄水効果は高まるがコストも高く、利用範囲が限られていた。   Carbides used in conventional water purification materials are carbides carbonized by a batch-type carbonization furnace, and since the specific surface area is small unless an activation process or the like is performed, the water purification effect was weak and the water purification ability remained constant. . Moreover, when activated and made into activated carbon, although the water purification effect increased, cost was also high and the utilization range was limited.

本発明の課題は、無酸素雰囲気で撹拌を加えながら炭化される炭化装置によって炭化されたもみ殻炭、あるいは桐炭、あるいは杉炭を使用した浄水効果の高い浄水材及びその使用方法、ならびにその製造方法を提供することである。   An object of the present invention is to provide a water purification material having a high water purification effect using rice husk charcoal, paulownia charcoal, or cedar charcoal carbonized by a carbonizer that is carbonized while stirring in an oxygen-free atmosphere, and a method for using the same. It is to provide a manufacturing method.

本発明の浄水材に使用される、もみ殻炭、桐炭あるいは杉炭は、被炭化物を、無酸素雰囲気中で、攪拌しながら炭化される炭化装置にて炭化されたものであり、素材の天然構造を維持したまま炭化していることから、ミクロ孔からマクロ孔まで幅広く細孔が分布しており、活性炭と比較して吸着速度に優れていることを特徴とする。また、廃棄物を原料に低消費エネルギーで連続的に製造できることから、活性炭よりも安価に提供することができる。
本発明の浄水材は、カートリッジに充填し、容器に浸漬、または水道の蛇口の先端部、またはペットボトルの飲み口の先端部、またはろ過フィルター、あるいはドリップコーヒーのフイルタの前段に装着する用途にて使用される。 The rice husk charcoal, paulownia charcoal, or cedar charcoal used in the water purification material of the present invention is carbonized in a carbonization device that is carbonized while stirring in an oxygen-free atmosphere. Since carbonization is performed while maintaining the natural structure, pores are widely distributed from micropores to macropores, and the adsorption rate is superior to that of activated carbon. In addition, since waste can be continuously produced from raw materials with low energy consumption, it can be provided at a lower cost than activated carbon.
The water-purifying material of the present invention is filled in a cartridge and immersed in a container, or attached to the front end of a tap faucet, the tip of a drinking tap of a plastic bottle, a filtration filter, or a drip coffee filter. Used.

請求項１に係る発明は、無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化されたもみ殻炭を主成分とすることを特徴とする浄水材である。   The invention according to claim 1 is a water purifying material characterized in that the main component is rice husk charcoal carbonized in a carbonizer that is carbonized while stirring in an oxygen-free atmosphere.

請求項２に係る発明は、前記もみ殻炭は、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項１記載の浄水材である。   The invention according to claim 2 is the water purification material according to claim 1, wherein the rice husk charcoal is carbonized in a temperature condition of 300 ° C. to 700 ° C.

請求項３に係る発明は、無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化された桐炭を主成分とすることを特徴とする浄水材である。   The invention according to claim 3 is a water purification material characterized in that paulownia charcoal carbonized by a carbonization device that is carbonized while stirring in an oxygen-free atmosphere is a main component.

請求項４に係る発明は、前記桐炭が、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項３記載の浄水材である。   The invention according to claim 4 is the water purification material according to claim 3, wherein the temperature condition at which the charcoal is carbonized is 300 ° C to 700 ° C.

請求項５に係る発明は、無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化された杉炭を主成分とすることを特徴とする浄水材である。   The invention according to claim 5 is a water purification material characterized in that the main component is cedar charcoal carbonized in a carbonizer that is carbonized while stirring in an oxygen-free atmosphere.

請求項６に係る発明は、前記杉炭が、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項５記載の浄水材。   The invention according to claim 6 is the water purification material according to claim 5, wherein a temperature condition for carbonizing the cedar charcoal is 300 ° C to 700 ° C.

請求項７に係る発明は、請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、水道の蛇口の先端部に装着することを特徴とする浄水材の使用方法である。   The invention according to claim 7 is a method of using the water purification material, wherein the water purification material according to any one of claims 1 to 6 is filled in a cartridge and attached to a tip end of a water tap. .

請求項８に係る発明は、請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、ペットボトルの飲み口の先端部に装着することを特徴とする浄水材の使用方法。   The invention according to claim 8 is a method of using the water purification material, wherein the water purification material according to any one of claims 1 to 6 is filled in a cartridge and attached to a tip of a drinking mouth of a plastic bottle. .

請求項９に係る発明は、請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、ドリップコーヒーのフイルタの前段に装着することを特徴とする浄水材の使用方法である。   The invention according to claim 9 is a method of using the water purification material, wherein the water purification material according to any one of claims 1 to 6 is filled in a cartridge and attached to a front stage of a drip coffee filter. .

請求項１０に係る発明は、もみ殻を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化したもみ殻炭をカートリッジに充填することを特徴とする浄水材の製造方法である。   The invention according to claim 10 is characterized in that the rice husk is carbonized at a temperature in the range of 300 ° C. to 700 ° C. with stirring in an oxygen-free atmosphere, and the carbonized rice husk charcoal is filled in the cartridge. It is a manufacturing method of water purification material.

請求項１１に係る発明は、桐を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化した桐炭をカートリッジに充填することを特徴とする浄水材の製造方法である。   The invention according to claim 11 is characterized in that the paulownia is carbonized at a temperature in the range of 300 ° C. to 700 ° C. while stirring in an oxygen-free atmosphere, and the carbonized paulownia charcoal is filled in the cartridge. It is a manufacturing method of water purification material.

請求項１２に係る発明は、杉を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化した杉炭をカートリッジに充填することを特徴とする浄水材の製造方法である。   The invention according to claim 12 is characterized in that the cedar is carbonized at a temperature in the range of 300 ° C. to 700 ° C. while stirring in an oxygen-free atmosphere, and the carbonized cedar charcoal is filled in the cartridge. It is a manufacturing method of water purification material.

請求項１、２、３，４，５，６に係る浄水材によれば、無酸素囲気中にて、撹拌しながら炭化される炭化される炭化装置によって炭化された浄水効果の高いもみ殻炭、桐炭、杉炭を得ることができる。   According to the water purification material which concerns on Claim 1, 2, 3, 4, 5 and 6, the rice husk charcoal with the high water purification effect carbonized by the carbonization apparatus carbonized by stirring in an oxygen-free atmosphere , Paulownia charcoal, cedar charcoal can be obtained.

請求項７，８、９に係る浄水材の使用方法によれば、無酸素囲気中にて、撹拌しながら炭化することによって得られる、浄水効果の高いもみ殻炭、桐炭、杉炭を利用することができる。   According to the method of using the water purification material according to claims 7, 8, and 9, the use of rice husk charcoal, paulownia charcoal, and cedar charcoal having a high water purification effect obtained by carbonization while stirring in an oxygen-free atmosphere. can do.

請求項１０、１１、１２に係る浄水材の製造方法によれば、無酸素囲気中にて、撹拌しながら炭化することによって、浄水効果の高いもみ殻炭、桐炭、杉炭を製造することができる。   According to the manufacturing method of the water purification material which concerns on Claim 10,11,12, it manufactures rice husk charcoal, paulownia charcoal, and cedar charcoal with a high water purification effect by carbonizing with stirring in an oxygen-free atmosphere. Can do.

本発明によれば、無酸素雰囲気で撹拌を加えながら炭化される炭化装置によって炭化されたもみ殻炭、あるいは桐炭、あるいは杉炭を使用した浄水効果の高い浄水材及びその使用方法、ならびにその製造方法を提供することができる。   According to the present invention, a water purification material having a high water purification effect using rice husk charcoal, paulownia charcoal, or cedar charcoal carbonized by a carbonizer that is carbonized while stirring in an oxygen-free atmosphere, and a method for using the same, and its A manufacturing method can be provided.

本発明の浄水材であるもみ殻炭（３００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of rice husk charcoal (carbonized at 300 ° C.) which is a water purification material of the present invention. 本発明の浄水材であるもみ殻炭（４００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of rice husk charcoal (carbonized at 400 ° C.) which is the water purification material of the present invention. 本発明の浄水材であるもみ殻炭（５００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of rice husk charcoal (carbonized at 500 ° C.) which is a water purification material of the present invention. 本発明の浄水材であるもみ殻炭（６００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of rice husk charcoal (carbonized at 600 ° C.) which is the water purification material of the present invention. 本発明の浄水材である桐炭（５００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of paulownia charcoal (carbonization at 500 ° C) which is a water purification material of the present invention. 本発明の浄水材である杉炭（５００℃で炭化）のＳＥＭ写真である。It is a SEM photograph of cedar charcoal (carbonization at 500 ° C) which is a water purification material of the present invention. 本発明の調湿材に使用されるもみ殻炭、あるいは桐炭、あるいは杉炭を炭化するための、炭化装置の１例の構成図である。It is a block diagram of an example of the carbonization apparatus for carbonizing the rice husk charcoal, paulownia charcoal, or cedar charcoal used for the humidity control material of this invention. 本発明の浄水材を水道水の浄水に用いた使用方法の図。The figure of the usage method which used the water purification material of this invention for the purification of tap water. 本発明の浄水材をペットボトル内飲料水の浄水に用いた使用方法の図。The figure of the usage method which used the water purification material of this invention for the purification of the drinking water in a PET bottle. 本発明の浄水材をドリップコーヒーのフイルター前段装着した使用方法の図。The figure of the usage method which attached the water purifier of this invention to the filter front stage of drip coffee.

本発明の浄水材に使用される炭化物である、もみ殻炭、あるいは桐炭、または杉炭は、無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化されることを特徴としている。
使用する炭化装置としては、被炭化物が、無酸素雰囲気中にて炭化される炭化装置であれば、その形式は問わない。 Charcoal used in the water purification material of the present invention, rice husk charcoal, paulownia charcoal, or cedar charcoal is characterized by being carbonized in a carbonization device that is carbonized while stirring in an oxygen-free atmosphere. Yes.
As the carbonization apparatus to be used, any form may be used as long as the carbonized object is carbonized in an oxygen-free atmosphere.

炭化装置の一例としては、図７に本発明のもみ殻、あるいは桐、または杉を炭化するための、炭化装置の１例の構成図を示した。図７に示すように、本発明で使用される炭化装置（還元炭化処理装置）は、内部に螺旋羽と攪拌羽１を配置した回転する一つのキルン２と、この一つのキルン２の内部に投入された廃棄物を含む有機物等を無酸素雰囲気の還元状態で間接加熱しつつ有機物等に蓄熱して一つのキルン２の内部全体に熱を供給する燃焼室３と、燃焼室３内に臨むバーナー等の加熱源４と、キルン２の内部に投入された有機物等に含まれる水分を燃焼室３の間接加熱によって蒸発させるようにキルン２の内部にエリア設定された乾燥部２ａと、乾燥部２ａで乾燥処理された有機物等を間接加熱分解させることで炭化させるようにキルン２の内部にエリア設定された炭化部２ｂと、を備えている。
本装置は還元滅菌炭化加工機SUMIX（株式会社ガイア環境技術研究所製）と称し、本装置によって製造される炭化物を以後SUMIX炭と称する。もみ殻炭に関しては、SUMIXもみ殻炭と称し、桐炭に関しては、SUMIX桐炭と称し、杉炭に関しては、SUMIX杉炭と称する。 As an example of the carbonization apparatus, FIG. 7 shows a configuration diagram of an example of the carbonization apparatus for carbonizing the chaff, paulownia, or cedar of the present invention. As shown in FIG. 7, the carbonization apparatus (reduction carbonization processing apparatus) used in the present invention includes a rotating kiln 2 in which a spiral blade and a stirring blade 1 are disposed, and an interior of the one kiln 2. Combustion chamber 3 that stores the organic matter, etc., including the input waste, in an organic material etc. while indirectly heating in a reduced state in an oxygen-free atmosphere and supplies heat to the entire interior of one kiln 2, and the combustion chamber 3 A heating unit 4 such as a burner, a drying unit 2a having an area set inside the kiln 2 so as to evaporate water contained in the organic matter and the like introduced into the kiln 2 by indirect heating of the combustion chamber 3, and a drying unit A carbonized portion 2b having an area set inside the kiln 2 so as to be carbonized by indirectly heating and decomposing the organic matter dried by 2a.
This apparatus is referred to as a reduction sterilization carbonization machine SUMIX (manufactured by Gaia Environmental Technology Laboratory Co., Ltd.), and the carbide produced by this apparatus is hereinafter referred to as SUMIX charcoal. Rice husk charcoal is called SUMIX rice husk charcoal, paulownia charcoal is called SUMIX paulownia charcoal, and cedar charcoal is called SUMIX cedar charcoal.

図１は、本発明の浄水材であるもみ殻炭（３００℃で炭化）のＳＥＭ写真である。
図２は、本発明の浄水材であるもみ殻炭（４００℃で炭化）のＳＥＭ写真である。
図３は、本発明の浄水材であるもみ殻炭（５００℃で炭化）のＳＥＭ写真である。
図４は、本発明の浄水材であるもみ殻炭（６００℃で炭化）のＳＥＭ写真である。
図５は、本発明の浄水材である桐炭（５００℃で炭化）のＳＥＭ写真である。
図６は、本発明の浄水材である杉炭（５００℃で炭化）のＳＥＭ写真である。 FIG. 1 is an SEM photograph of rice husk charcoal (carbonized at 300 ° C.) which is a water purification material of the present invention.
FIG. 2 is an SEM photograph of rice husk charcoal (carbonized at 400 ° C.) which is a water purification material of the present invention.
FIG. 3 is an SEM photograph of rice husk charcoal (carbonized at 500 ° C.), which is the water purification material of the present invention.
FIG. 4 is an SEM photograph of rice husk charcoal (carbonized at 600 ° C.) which is the water purification material of the present invention.
FIG. 5 is an SEM photograph of paulownia charcoal (carbonized at 500 ° C.) which is a water purification material of the present invention.
FIG. 6 is an SEM photograph of cedar charcoal (carbonized at 500 ° C.) which is a water purification material of the present invention.

SUMIX炭は、素材の天然構造を維持したままで、高純度の炭素固定がなされており、且つ一部ガス賦活がなされているため、ミクロ孔からマクロ孔まで幅広く分布している。
これは主にミクロ孔が発達した活性炭と比較して、吸着速度において優れた特徴を有する。
また、活性炭よりもずっと安価であるため、大量使用するのにも適している。 SUMIX charcoal is widely distributed from micropores to macropores because it retains the natural structure of the material and is fixed with high purity carbon and partially activated with gas.
This has an excellent feature in the adsorption rate compared to activated carbon with mainly developed micropores.
Also, it is much cheaper than activated carbon, so it is suitable for mass use.

このようなSUMIX炭の特徴は、使い捨ての簡易浄水利用に好適である。例えば、ボトルにおける浄水利用の他、ペットボトルに装着したり、ドリップコーヒーのフイルター前段に装着したりする用途がある。   Such characteristics of SUMIX charcoal are suitable for disposable simple water purification. For example, in addition to the use of purified water in bottles, there are applications such as mounting on PET bottles and mounting on the front stage of drip coffee filters.

本発明の浄水材の実施例、使用方法について、以下説明する。
（実施例１） Examples and usage methods of the water purification material of the present invention will be described below.
Example 1

図８は、本発明の浄水材を水道水の浄水に用いた使用方法の図である。
図８にて、浄水器１００は、カートリッジ２１Ａ内に、SUMIX炭１が充填されており、水道の蛇口５１から導入部４１を介して、前記浄水器１００の入り口に接続され、浄水器１００からの出口には、排出口３１が配置されている。 FIG. 8 is a diagram of a method of using the water purification material of the present invention for tap water purification.
In FIG. 8, a water purifier 100 is filled with SUMIX charcoal 1 in a cartridge 21 </ b> A, connected to an inlet of the water purifier 100 from a water faucet 51 through an introduction part 41, and from the water purifier 100. A discharge port 31 is arranged at the outlet.

ここで、SUMIX炭１は、（００２４）〜（００２６）にて説明した、もみ殻炭、あるいは桐炭、または杉炭のいずれかが用いられる。
（実施例２） Here, as the SUMIX charcoal 1, any one of rice husk charcoal, paulownia charcoal, or cedar charcoal described in (0024) to (0026) is used.
(Example 2)

図９は、本発明の浄水材をペットボトル内飲料水の浄水に用いた使用方法の図である。
図９にて、浄水器２００は、カートリッジ２１Ｂ内に、SUMIX炭１が充填されており、浄水器２００の一方の側は、ペットボトル７１の飲み口に固定されている。６１は、排出口であり、ペットボトル７１を傾けることによって、浄水された飲み物が、供給される。 FIG. 9 is a diagram of a method of using the water purification material of the present invention for the purification of drinking water in a PET bottle.
In FIG. 9, the water purifier 200 is filled with the SUMIX charcoal 1 in the cartridge 21 </ b> B, and one side of the water purifier 200 is fixed to the drinking mouth of the plastic bottle 71. Reference numeral 61 denotes a discharge port, and a purified drink is supplied by tilting the PET bottle 71.

ここで、SUMIX炭１は、（００２４）〜（００２６）にて説明した、もみ殻炭、あるいは桐炭、または杉炭のいずれかが用いられる。
（実施例３） Here, as the SUMIX charcoal 1, any one of rice husk charcoal, paulownia charcoal, or cedar charcoal described in (0024) to (0026) is used.
(Example 3)

図１０は、本発明の浄水材をドリップコーヒーのフイルター前段装着した使用方法の図である。図１０にて、浄水器３００は、ドリップコーヒーのフイルター８１の上部にて、仮固定されており、浄水器３００は、カートリッジ２１Ｃ内に、SUMIX炭１が充填されており、上から注がれたお湯を、浄水し、ドリップコーヒーのフイルター８１に注がれる。
なお、浄水器３００は、１回ごとに、使い捨てとすることが好ましい。 FIG. 10 is a diagram of a usage method in which the water purification material of the present invention is attached to the drip coffee filter upstream. In FIG. 10, the water purifier 300 is temporarily fixed at the upper part of the drip coffee filter 81, and the water purifier 300 is filled with SUMIX charcoal 1 in the cartridge 21C and poured from above. The hot water is purified and poured into a drip coffee filter 81.
In addition, it is preferable to make the water purifier 300 disposable once.

ここで、SUMIX炭１は、（００２４）〜（００２６）にて説明した、もみ殻炭、あるいは桐炭、または杉炭のいずれかが用いられる。   Here, as the SUMIX charcoal 1, any one of rice husk charcoal, paulownia charcoal, or cedar charcoal described in (0024) to (0026) is used.

なお、SUMIX炭を、直接、ドリップコーヒーのフイルターに入れても、浄水効果が確認された。以下説明する。
SUMIX炭：SUMIX桐炭（炭化温度：５００℃）、１０ｇ
サンプル水：熊谷市水道水（北部浄水場）→全硬度：１５６ｍｇ／Ｌ ２００ｍＬ
測定：ポータブル吸光光度計ｐＨｏｔｏＦｌｅｘ In addition, even if SUMIX charcoal was put directly into the drip coffee filter, the water purification effect was confirmed. This will be described below.
SUMIX charcoal: SUMIX paulownia charcoal (carbonization temperature: 500 ° C), 10g
Sample water: Kumagaya City tap water (North water purification plant) → Total hardness: 156 mg / L 200 mL
Measurement: Portable absorptiometer pHoFlex

前記SUMIX炭を市販のコーヒーのフイルターに１０ｇ入れ、その上からサンプル水を自然通水し、ろ過水の全硬度を測定した。ろ過前のサンプル水の全硬度が１５６ｍｇ／Ｌであった数値が、ろ過水は、８８ｍｇ／Ｌへ低下した。
参考として、厚生労働省による「おいしい水」の目安値（１９８５年調査）は、全硬度１０〜１００ｍｇ／Ｌである。 10 g of the SUMIX charcoal was put into a commercially available coffee filter, sample water was naturally passed from above, and the total hardness of the filtrate was measured. The numerical value that the total hardness of the sample water before filtration was 156 mg / L, the filtrate water decreased to 88 mg / L.
For reference, the standard value of “delicious water” by the Ministry of Health, Labor and Welfare (Survey in 1985) is 10 to 100 mg / L in total hardness.

本発明の浄水材は、もみ殻炭、あるいは桐炭、あるいは杉炭の浄水効果を利用した各種の用途、カートリッジに充填し、水道の蛇口の先端部に装着する、あるいはペットボトルの飲み口の先端部に装着する、あるいはドリップコーヒーのフイルタの前段に装着する、その他の用途に使用することができる。使用する形体は、カートリッジに充填する、あるいはシールする形体、あるいは、その他形体でも良い。   The water purification material of the present invention can be used for various purposes utilizing the water purification effect of rice husk charcoal, paulownia charcoal, or cedar charcoal, and can be filled into a cartridge and attached to the tip of a water tap or can be used for drinking from a PET bottle. It can be used for other applications such as mounting at the tip or mounting in front of a drip coffee filter. The shape to be used may be a shape that fills or seals the cartridge, or another shape.

２…キルン
２ａ 乾燥部
２ｂ 炭化部
２ｄ 蓄熱部
２ｃ 内部空間
２in 入口
２out 出口
３…燃焼室
３ａ…排気管
４…加熱源
５…配管部
６…冷却部
７…脱臭部
８…乾留ガス回収部
９…補助加熱源
１０…蒸気煙経路
１１…油化部
１２…配水管
１３…ファン
１４…ホッパ
１５…原料供給配管
１６…供給スクリュー
１７…第２排出配管
１８…冷却装置
１９…接続管（下流側排ガス管）
１９ａ 下流側排ガス管上管
１９b 下流側排ガス管下管
２０…搬送スクリュー
２１…搬送スクリュー
２２…蒸気抜きパイプ（上流側排ガス管）
２２ａ 上流側排ガス管上管
２２b 上流側排ガス管下管
２３ 煙突部
２４ 循環管
２５ ガス抜きパイプ
３０ 接続部
６０ 回収部
Ｐ 投入素材
Ｑ 炭化された素材
１ SUMIX炭
２１Ａ、２１Ｂ、２１Ｃ カートリッジ
３１、６１ 排出口
４１ 導入部
５１ 水道の蛇口
７１ ペットボトル
８１ ドリップコーヒーのフイルター
９１ コーヒーカップ
１００，２００，３００ 浄水器 DESCRIPTION OF SYMBOLS 2 ... Kiln 2a Drying part 2b Carbonization part 2d Heat storage part 2c Internal space 2in Inlet 2out Outlet 3 ... Combustion chamber 3a ... Exhaust pipe 4 ... Heat source 5 ... Piping part 6 ... Cooling part 7 ... Deodorizing part 8 ... Dry distillation gas recovery part 9 ... Auxiliary heating source 10 ... Steam smoke path 11 ... Oilification section 12 ... Water distribution pipe 13 ... Fan 14 ... Hopper 15 ... Raw material supply pipe 16 ... Supply screw 17 ... Second discharge pipe 18 ... Cooling device 19 ... Connection pipe (downstream side) Exhaust pipe)
19a Downstream exhaust pipe upper pipe
19b Downstream exhaust pipe
20 ... Conveying screw 21 ... Conveying screw 22 ... Steam vent pipe (upstream exhaust gas pipe)
22a Upper side exhaust pipe upper pipe
22b Upstream exhaust pipe lower pipe
23 Chimney 24 Recirculation pipe 25 Degassing pipe 30 Connection part 60 Collection part P Input material Q Carbonized material 1 SUMIX charcoal 21A, 21B, 21C Cartridges 31, 61 Discharge port 41 Introduction part 51 Water tap 71 Pet bottle 81 Drip Coffee filter 91 Coffee cup 100, 200, 300 Water purifier

Claims (12)

無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化されたもみ殻炭を主成分とすることを特徴とする浄水材。 A water purification material comprising, as a main component, rice husk charcoal carbonized in a carbonizer that is carbonized while stirring in an oxygen-free atmosphere. 前記もみ殻炭は、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項１記載の浄水材。 The water purification material according to claim 1, wherein a temperature condition for carbonizing the rice husk charcoal is 300 ° C to 700 ° C. 無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化された桐炭を主成分とすることを特徴とする浄水材。 A water purification material comprising paulownia charcoal carbonized in a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere as a main component. 前記桐炭は、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項３記載の浄水材。 The water purification material according to claim 3, wherein a temperature condition for carbonizing the paulownia charcoal is 300 ° C. to 700 ° C. 無酸素囲気中にて、撹拌しながら炭化される炭化装置にて炭化された杉炭を主成分とすることを特徴とする浄水材。 A water purification material comprising cedar charcoal carbonized in a carbonizer that is carbonized while stirring in an oxygen-free atmosphere as a main component. 前記杉炭は、炭化される温度条件が、３００℃〜７００℃であることを特徴とする請求項５記載の浄水材。 The water purification material according to claim 5, wherein a temperature condition for carbonizing the cedar charcoal is 300 ° C to 700 ° C. 請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、水道の蛇口の先端部に装着することを特徴とする浄水材の使用方法。 A method for using a water purification material, comprising filling the cartridge with the water purification material according to any one of claims 1 to 6 and attaching the water purification material to a tip of a tap. 請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、ペットボトルの飲み口の先端部に装着することを特徴とする浄水材の使用方法。 A method for using a water purification material, comprising filling the cartridge with the water purification material according to any one of claims 1 to 6 and attaching the water purification material to a tip of a drinking port of a plastic bottle. 請求項１ないし６のいずれか１項記載の浄水材を、カートリッジに充填し、ドリップコーヒーのフイルタの前段に装着することを特徴とする浄水材の使用方法。 A method for using a water purification material, wherein the water purification material according to any one of claims 1 to 6 is filled in a cartridge and attached to a front stage of a drip coffee filter. もみ殻を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化したもみ殻炭をカートリッジに充填することを特徴とする浄水材の製造方法。 A method for producing a water purification material, comprising carbonizing rice husk at a temperature in the range of 300 ° C. to 700 ° C. while stirring the rice husk in an oxygen-free atmosphere, and filling the carbonized rice husk charcoal into the cartridge. 桐を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化した桐炭をカートリッジに充填することを特徴とする浄水材の製造方法。 A method for producing a water-purifying material, characterized in that paulownia is carbonized at a temperature in a range of 300 ° C. to 700 ° C. while stirring in an oxygen-free atmosphere, and the carbonized paulownia charcoal is filled in a cartridge. 杉を、無酸素囲気中にて、撹拌しながら、３００℃〜７００℃の範囲の温度にて炭化し、炭化した杉炭をカートリッジに充填することを特徴とする浄水材の製造方法。 A method for producing a water purification material, characterized by carbonizing cedar in an oxygen-free atmosphere while stirring at a temperature in the range of 300 ° C. to 700 ° C., and filling the carbonized cedar charcoal into a cartridge.
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JP2014104375A (en) * 2012-11-22 2014-06-09 Gaia Institute Of Environmental Technology Inc Water treatment apparatus with which coagulation and filtration of suspension water is conducted with one tank, and water treatment method
JP2014132166A (en) * 2013-01-07 2014-07-17 Toyota Motor Corp Internal combustion engine
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PL440211A1 (en) * 2022-01-24 2023-07-31 Politechnika Rzeszowska im. Ignacego Łukasiewicza Method of biosorbent production and biosorbent produced by this method

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JPH0924366A (en) * 1995-07-07 1997-01-28 Kitagawa Iron Works Co Ltd Floating body structure for purification of drinking water
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JP2014104375A (en) * 2012-11-22 2014-06-09 Gaia Institute Of Environmental Technology Inc Water treatment apparatus with which coagulation and filtration of suspension water is conducted with one tank, and water treatment method
JP2014132166A (en) * 2013-01-07 2014-07-17 Toyota Motor Corp Internal combustion engine
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